WO1993015960A2 - Self-cooling fluid container - Google Patents

Self-cooling fluid container Download PDF

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Publication number
WO1993015960A2
WO1993015960A2 PCT/BB1993/000001 BB9300001W WO9315960A2 WO 1993015960 A2 WO1993015960 A2 WO 1993015960A2 BB 9300001 W BB9300001 W BB 9300001W WO 9315960 A2 WO9315960 A2 WO 9315960A2
Authority
WO
WIPO (PCT)
Prior art keywords
chamber
refrigerant
self
accordance
region
Prior art date
Application number
PCT/BB1993/000001
Other languages
French (fr)
Other versions
WO1993015960A3 (en
Inventor
Gary Reid Aitchison
Michael Warnett Hetherington
Original Assignee
Envirochill International Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DK93901073T priority Critical patent/DK0632877T3/en
Priority to BR9305807A priority patent/BR9305807A/en
Priority to AT93901073T priority patent/ATE196684T1/en
Priority to RU94045991A priority patent/RU2110023C1/en
Priority to AU45155/93A priority patent/AU660230B2/en
Priority to EP93901073A priority patent/EP0632877B1/en
Application filed by Envirochill International Ltd filed Critical Envirochill International Ltd
Priority to DE69329492T priority patent/DE69329492T2/en
Priority to JP51361393A priority patent/JP3176924B2/en
Priority to KR1019940702552A priority patent/KR100264826B1/en
Publication of WO1993015960A2 publication Critical patent/WO1993015960A2/en
Publication of WO1993015960A3 publication Critical patent/WO1993015960A3/en
Priority to GR20000402829T priority patent/GR3035141T3/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • F25D3/10Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air
    • F25D3/107Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air portable, i.e. adapted to be carried personally
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D79/00Kinds or details of packages, not otherwise provided for
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2331/00Details or arrangements of other cooling or freezing apparatus not provided for in other groups of this subclass
    • F25D2331/80Type of cooled receptacles
    • F25D2331/805Cans

Definitions

  • This invention relates generally to self-cooling fluid containers and specifically to an internal self-cooling beverage container.
  • HFCs hydrofluorocarbons
  • a beverage container of conventional exterior dimensions, readily adaptable to existing packaging, stacking, transporting and handling needs.
  • An upper chamber containing the beverage to be cooled is axially provided with a refrigerant chamber affixed to the base of the upper chamber and extending at least partially into the upper chamber.
  • the interior region of the refrigerant chamber is fluidicly isolated from the interior region of the upper chamber.
  • the pressurized refrigerant chamber contains an environmentally friendly refrigerant of a determined quantity in liquid form and is provided at its lower end by a sealed aperture integral with the base of the upper chamber.
  • a third chamber serves several functions. Firstly, it provides a means for conveniently venting the refrigerant chamber by delivering a seal opening member to the sealed aperture. Secondly, it provides a venting chamber, or refrigerant dispersal assembly, wherein the volatile evaporating refrigerant is vented and decelerated, thus eliminating the risk of a blast of spray being directed at the consumer. Further, the third chamber increases refrigeration efficiency by maximizing the surface area of cooling to include not only the refrigerant chamber, but also the lower portion of the surface of the upper beverage container. This third unpressurized chamber may be formed as a separate generally cup-shaped cap in preferably threaded engagement to the base of the upper chamber.
  • the inner surface of the base of the cap is further provided with a seal opening member (for example, a perforation member) spaced in alignment with the sealed aperture.
  • a seal opening member for example, a perforation member
  • Rotation of the cap in threaded engagement with the upper chamber results in an upward movement of the perforation member which perforates the seal of the aperture of the refrigeration chamber, thus venting and dispersing the evaporating refrigerant into the third chamber at atmospheric pressure.
  • the ensuing cooling effect of evaporation and the adiabatic expansion of refrigerant vapor cools the walls of the refrigerant chamber and the base of the upper chamber, cooling the beverage by thermal conduction.
  • the upward movement of the seal opening member may be facilitated by a bead-and-groove engagement between the cap and the exterior wall of the upper chamber.
  • the base of the cap may be provided as to be sufficiently flexible to permit upward displacement of the seal opening member by upward manipulation of the cap base as a means of venting the refrigerant.
  • FIG. 1 A perspective view which has been partially cut away of an embodiment of the invention.
  • FIG. 2 A sectional view taken along line
  • FIG. 1 2-2 of FIG. 1 illustrating the perforation of the sealing means of the embodiment shown in FIG. 1.
  • FIG. 3. A sectional view of an alternative embodiment of the present invention prior to refrigerant dispersal.
  • FIG. 4. A sectional view of the embodiment shown in FIG. 3. after refrigerant dispersal.
  • FIG. 5 A sectional view of a third embodiment of the present invention.
  • FIG. 6 An enlarged sectional plan view of the perforation member of any of the described embodiments after perforation of the seal of the refrigerant chamber.
  • FIG.l shows a self-cooling container for carbonated soft drinks, beer and the like indicated at reference numeral 10.
  • the container is shown having a conventional opening tab 15 on its upper end wall 11 and conforms generally to conventional exterior dimensions and shape of such containers.
  • Each structural component of the invention is of a composition preferably selected from aluminum, steel, aluminum and steel or other metal or metal alloy, plastic or any other material of sufficient strength, heat conductivity and recyclability.
  • the container 10 is divided into three generally cylindrical chambers: an upper chamber providing a fluid (typically a beverage) vessel 12; a lower chamber providing a refrigerant vapor dispersal vessel 21, and a refrigerant capsule 30 axially disposed within and concentric to the beverage vessel 12.
  • the beverage vessel 12 of the upper chamber is defined by the walls of cylindrical side wall 16 and generally disc-like top wall 11 and base wall 13.
  • the cylindrical side wall 16 has a reduced diameter portion 17 at its lowermost end.
  • the base wall 13 of the beverage vessel is axially provided with an aperture 19.
  • the dispersal vessel 21 of the lower chamber is defined by a separate generally cup-shaped cap 20 having preferably a generally concave base portion 27 and a cylindrical side wall 22.
  • the sidewall 25L of the cap 20 fits radially around the annular reduced portion 17 of the upper chamber.
  • An annular sealing member 99a about the upper open edge of the cap 20 is in slidable, rotatable, sealing engagement with the annular reduced portion 17 of the sidewall 16.
  • the sidewall 22 of the cap is in additional engagement with the annular reduced portion 17 of the upper chamber 12 by way of vertical displacement members described in detail below.
  • the refrigerant capsule 30 is fixed at its lower end by welding or the like, to the base wall 13 of the beverage vessel 12.
  • the capsule includes an interior refrigerant region which contains a predetermined quantity of a refrigerant, under pressure and in liquid form, preferably selected from the group of HFC's developed by DuPont and others.
  • the capsule 30 is axially provided at its lower end with an aperture 19a which aligns with the aperture 19 of the beverage vessel base 13.
  • the apertures are sealed by a sealing element 32 - for example, a perforatable foil seal of sufficient strength to maintain the pressurized refrigerant within the closed region interior to the refrigerant capsule 30.
  • the cavity, or fluid region, defined by the interior walls of the beverage vessel 12 and the exterior walls of the refrigerant capsule contains the beverage to be cooled and is accessible to the consumer via a conventional die-cut pull tab device (openable port) 15.
  • the sealing element 32 thus forms a common wall (or coupling portion of the walls) between the refrigerant region and the dispersal region.
  • a cooling activator which includes a seal opening member.
  • the seal opening member is aligned vertically with the sealing element 32 (i.e., coupling portion) covering aperture 19, 19a.
  • FIGS. 2-6 show the seal opening member as a perforation member 26, preferably an acute cone in shape with fluted grooves 26a vertically aligned about its circumference.
  • a valve could be substituted for the perforable sealing element 32 and the perforation member 26.
  • the cap 20 is moved upward relative to the beverage vessel 12 guided by the vertical displacement members
  • the perforation member 26 is thus vertically displaced within the aligned apertures 19, 19a, perforating the sealing element 32, shown in FIG. 6.
  • the refrigerant upon exposure to normal atmospheric pressure, rapidly evaporates and expands through the apertures 19, 19a into the vapor dispersal vessel 21, wherein the volatile vapor is decelerated.
  • the refrigerant capsule 30 and the base wall 13 of the beverage vessel 12 become cooled by conduction as a result of the cooling effect of evaporation and the adiabatic expansion of the refrigerant vapor. This cooling is accordingly conducted to the beverage in vessel 12 which is subsequently cooled.
  • the expanding and evaporating refrigerant is vented from the vapor dispersal vessel through the venting pores 29 indicated by the arrows 29a in FIGS. 2 and 4.
  • the rate that the refrigerant vapor is vented regulates the efficiency of the cooling effect and is actuated by the size of apertures 19, 19a, the size of the vapor dispersal vessel 21 and the size of the venting pores 29.
  • an arrangement of vertically aligned baffles may be affixed to the cap base 27 within the vapor dispersal cavity to further decelerate the rate of refrigerant vapor dispersal to maximize cooling efficiency.
  • the aforesaid vertical displacement members guide the sliding vertical displacement of cap 20 about the annular portion 17 of the beverage vessel 12.
  • thread members 23a are provided on the interior side wall 22 in threaded, rotatable engagement with the corresponding thread members 23b of the exterior wall of annular portion 17.
  • vertical displacement of the perforation member 26 is achieved by rotation of the cap 20 about the beverage vessel 12.
  • "bayonet"-type sliding engagement between the cap 20 and vessel 12 may be provided whereby a plurality of beads 24a fixed to interior side wall 22 are slidable with plurality of corresponding grooves 24b located on the exterior wall of annular portion 17.
  • the device is activated by an upward manipulation of the cap 20 with the beads 24a guided vertically within grooves 24b.
  • a horizontal portion of the grooves 24b is provided to allow for a rotational locking step to prevent accidental discharge occurring (for example, owing to rough handling).
  • the cap portion 20 may be a separate unit, with the beverage vessel 12 being vended separately.
  • the cap 20 may be integral of the vending machine, for example, and provide a sealed vapor dispersal cavity and perforation member 26 for multiple use in association with each separately vended beverage vessel, in the same manner as described above.
  • the cap 20 is integral of the side walls 16 of beverage vessel 12. Upward displacement of the perforation member 26 as to perforate the refrigerant capsule sealing member 22 is achieved by an upward flexing of the base portion 27 of the vapor dispersal vessel 21.
  • the base portion 27, shown in FIG. 5, is designed to be sufficiently deformable in its centre portion 27a to achieve such a displacement, yet sufficiently rigid in its annular outer portion 27b to support the weight of the container 10 with minimal deformation.

Abstract

A self-cooling fluid container (10) includes a fluid chamber (12) for containing the fluid-to-be-cooled. A refrigerant chamber is affixed to the base (13) of the fluid chamber (12) and extends at least partially into the fluid chamber (12). The interior region of the refrigerant chamber (30) is fluidicly isolated from and thermally coupled to the interior region of the fluid chamber (12). A refrigerant dispersal assembly defines a vented dispersal region including a portion adjacent to the refrigerant chamber (30) and separated from the interior of that chamber by a perforatable wall. A cooling activator is adapted to selectively form a fluidic path from the interior of the refrigerant chamber (30) to the dispersal region through the perforatable wall (32), permitting release and expansion of the pressurized refrigerant.

Description

SELF-COOLING FLUID CONTAINER
FIELD OF THE INVENTION
This invention relates generally to self-cooling fluid containers and specifically to an internal self-cooling beverage container.
BACKGROUND OF THE INVENTION
Heretofore, self-cooling beverage containers have not met with widespread commercial success owing to a variety of design deficiencies. Complexity of design structure has rendered many known devices as impractical. Safety, in some cases, has presented a concern. The opportunity for contact between the refrigerant and beverage creates a risk of altering beverage quality at best and toxicity to the consumer at worst. Further, other known devices wherein the refrigerant is vented in association with the tab opening of the container presented a serious safety hazard. When vented, the evaporating refrigerant was expelled upwards towards the face of the consumer with liquid particles of refrigerant being borne within the refrigerant vapor. This problem was addressed in U.S. Pat. No. 3,852,975 to Beck which teaches a container provided with a safety shield to protect the consumer from the upwardly expelled spray. Inefficiency of refrigeration and/or environmental concerns have been other deficiencies of known devices. SUMMARY OF THE INVENTION
Accordingly, it is an object of the present invention to provide an efficient, simple, consumer-convenient and economical self-cooling fluid container which will overcome the aforesaid problems of the prior art.
It is a further object of the present invention to provide a self-cooling beverage container, not only well-adapted for the "outdoorsmen", but as an economical alternative to the use of auxiliary ref igeration.
It is a further object of the present invention to provide an "ecology-friendly", self-cooling beverage container which is adapted for the use of new, non-toxic and ozone-neutral hydrofluorocarbons (HFCs) and which is readily recyclable after use.
These and other objects are realized in one embodiment of the present invention comprising a beverage container of conventional exterior dimensions, readily adaptable to existing packaging, stacking, transporting and handling needs. An upper chamber containing the beverage to be cooled is axially provided with a refrigerant chamber affixed to the base of the upper chamber and extending at least partially into the upper chamber. The interior region of the refrigerant chamber is fluidicly isolated from the interior region of the upper chamber. The pressurized refrigerant chamber contains an environmentally friendly refrigerant of a determined quantity in liquid form and is provided at its lower end by a sealed aperture integral with the base of the upper chamber.
A third chamber serves several functions. Firstly, it provides a means for conveniently venting the refrigerant chamber by delivering a seal opening member to the sealed aperture. Secondly, it provides a venting chamber, or refrigerant dispersal assembly, wherein the volatile evaporating refrigerant is vented and decelerated, thus eliminating the risk of a blast of spray being directed at the consumer. Further, the third chamber increases refrigeration efficiency by maximizing the surface area of cooling to include not only the refrigerant chamber, but also the lower portion of the surface of the upper beverage container. This third unpressurized chamber may be formed as a separate generally cup-shaped cap in preferably threaded engagement to the base of the upper chamber. The inner surface of the base of the cap is further provided with a seal opening member (for example, a perforation member) spaced in alignment with the sealed aperture. Rotation of the cap in threaded engagement with the upper chamber results in an upward movement of the perforation member which perforates the seal of the aperture of the refrigeration chamber, thus venting and dispersing the evaporating refrigerant into the third chamber at atmospheric pressure. The ensuing cooling effect of evaporation and the adiabatic expansion of refrigerant vapor cools the walls of the refrigerant chamber and the base of the upper chamber, cooling the beverage by thermal conduction.
In an alternative embodiment, the upward movement of the seal opening member may be facilitated by a bead-and-groove engagement between the cap and the exterior wall of the upper chamber.
In a further embodiment, the base of the cap may be provided as to be sufficiently flexible to permit upward displacement of the seal opening member by upward manipulation of the cap base as a means of venting the refrigerant.
Further objects and advantages of the invention will become apparent from consideration of the drawings and description thereof.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1. A perspective view which has been partially cut away of an embodiment of the invention.
FIG. 2. A sectional view taken along line
2-2 of FIG. 1 illustrating the perforation of the sealing means of the embodiment shown in FIG. 1.
FIG. 3. A sectional view of an alternative embodiment of the present invention prior to refrigerant dispersal. FIG. 4. A sectional view of the embodiment shown in FIG. 3. after refrigerant dispersal.
FIG. 5. A sectional view of a third embodiment of the present invention.
FIG. 6. An enlarged sectional plan view of the perforation member of any of the described embodiments after perforation of the seal of the refrigerant chamber.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring to the drawings, FIG.l shows a self-cooling container for carbonated soft drinks, beer and the like indicated at reference numeral 10. The container is shown having a conventional opening tab 15 on its upper end wall 11 and conforms generally to conventional exterior dimensions and shape of such containers. Each structural component of the invention is of a composition preferably selected from aluminum, steel, aluminum and steel or other metal or metal alloy, plastic or any other material of sufficient strength, heat conductivity and recyclability.
The container 10 is divided into three generally cylindrical chambers: an upper chamber providing a fluid (typically a beverage) vessel 12; a lower chamber providing a refrigerant vapor dispersal vessel 21, and a refrigerant capsule 30 axially disposed within and concentric to the beverage vessel 12. The beverage vessel 12 of the upper chamber is defined by the walls of cylindrical side wall 16 and generally disc-like top wall 11 and base wall 13. In two of the preferred embodiments, shown in FIGS. 2-5, the cylindrical side wall 16 has a reduced diameter portion 17 at its lowermost end. The base wall 13 of the beverage vessel is axially provided with an aperture 19.
The dispersal vessel 21 of the lower chamber is defined by a separate generally cup-shaped cap 20 having preferably a generally concave base portion 27 and a cylindrical side wall 22. The sidewall 25L of the cap 20 fits radially around the annular reduced portion 17 of the upper chamber. An annular sealing member 99a about the upper open edge of the cap 20 is in slidable, rotatable, sealing engagement with the annular reduced portion 17 of the sidewall 16. The sidewall 22 of the cap is in additional engagement with the annular reduced portion 17 of the upper chamber 12 by way of vertical displacement members described in detail below.
The refrigerant capsule 30 is fixed at its lower end by welding or the like, to the base wall 13 of the beverage vessel 12. The capsule includes an interior refrigerant region which contains a predetermined quantity of a refrigerant, under pressure and in liquid form, preferably selected from the group of HFC's developed by DuPont and others. The capsule 30 is axially provided at its lower end with an aperture 19a which aligns with the aperture 19 of the beverage vessel base 13.
The apertures are sealed by a sealing element 32 - for example, a perforatable foil seal of sufficient strength to maintain the pressurized refrigerant within the closed region interior to the refrigerant capsule 30.
The cavity, or fluid region, defined by the interior walls of the beverage vessel 12 and the exterior walls of the refrigerant capsule contains the beverage to be cooled and is accessible to the consumer via a conventional die-cut pull tab device (openable port) 15.
The cavity, or dispersal region, defined by the interior walls of the cap 20, the exterior of the base wall 13 of the beverage vessel 13, the annular sealing member 22a and the perforatable sealing element 32, is exposed to normal atmospheric pressure through venting pores 29 at the base or sides of the cap 20. The sealing element 32 thus forms a common wall (or coupling portion of the walls) between the refrigerant region and the dispersal region. Within the dispersal region, affixed axially to the interior of the cap base portion 27, is a cooling activator which includes a seal opening member. The seal opening member is aligned vertically with the sealing element 32 (i.e., coupling portion) covering aperture 19, 19a. FIGS. 2-6 show the seal opening member as a perforation member 26, preferably an acute cone in shape with fluted grooves 26a vertically aligned about its circumference. A valve could be substituted for the perforable sealing element 32 and the perforation member 26.
In the operation of cooling the beverage contained in the present invention, the cap 20 is moved upward relative to the beverage vessel 12 guided by the vertical displacement members
(discussed below) and slidably sealing the annular sealing member 22a about the circumference of the annular portion 17 of the beverage vessel 12. The perforation member 26 is thus vertically displaced within the aligned apertures 19, 19a, perforating the sealing element 32, shown in FIG. 6. The refrigerant, upon exposure to normal atmospheric pressure, rapidly evaporates and expands through the apertures 19, 19a into the vapor dispersal vessel 21, wherein the volatile vapor is decelerated. The refrigerant capsule 30 and the base wall 13 of the beverage vessel 12 become cooled by conduction as a result of the cooling effect of evaporation and the adiabatic expansion of the refrigerant vapor. This cooling is accordingly conducted to the beverage in vessel 12 which is subsequently cooled.
The expanding and evaporating refrigerant is vented from the vapor dispersal vessel through the venting pores 29 indicated by the arrows 29a in FIGS. 2 and 4. The rate that the refrigerant vapor is vented regulates the efficiency of the cooling effect and is actuated by the size of apertures 19, 19a, the size of the vapor dispersal vessel 21 and the size of the venting pores 29. Preferably, an arrangement of vertically aligned baffles (not shown) may be affixed to the cap base 27 within the vapor dispersal cavity to further decelerate the rate of refrigerant vapor dispersal to maximize cooling efficiency.
The aforesaid vertical displacement members guide the sliding vertical displacement of cap 20 about the annular portion 17 of the beverage vessel 12. In a preferred embodiment, thread members 23a are provided on the interior side wall 22 in threaded, rotatable engagement with the corresponding thread members 23b of the exterior wall of annular portion 17. Thus, vertical displacement of the perforation member 26 is achieved by rotation of the cap 20 about the beverage vessel 12.
In an alternative embodiment, "bayonet"-type sliding engagement between the cap 20 and vessel 12 may be provided whereby a plurality of beads 24a fixed to interior side wall 22 are slidable with plurality of corresponding grooves 24b located on the exterior wall of annular portion 17. The device is activated by an upward manipulation of the cap 20 with the beads 24a guided vertically within grooves 24b. Preferably, a horizontal portion of the grooves 24b is provided to allow for a rotational locking step to prevent accidental discharge occurring (for example, owing to rough handling).
With regard to both of the above-described embodiments, it is contemplated by the inventor that the cap portion 20 may be a separate unit, with the beverage vessel 12 being vended separately. In such a case, the cap 20 may be integral of the vending machine, for example, and provide a sealed vapor dispersal cavity and perforation member 26 for multiple use in association with each separately vended beverage vessel, in the same manner as described above.
In a further embodiment of the invention shown in FIG. 5, the cap 20 is integral of the side walls 16 of beverage vessel 12. Upward displacement of the perforation member 26 as to perforate the refrigerant capsule sealing member 22 is achieved by an upward flexing of the base portion 27 of the vapor dispersal vessel 21. The base portion 27, shown in FIG. 5, is designed to be sufficiently deformable in its centre portion 27a to achieve such a displacement, yet sufficiently rigid in its annular outer portion 27b to support the weight of the container 10 with minimal deformation.
While the above description contains many specificities, these should not be construed as limitations of the scope of the invention but rather as an exemplification of preferred embodiments thereof. While the described embodiment is for a beverage container, it will be understood that it applies as well to any fluid container. Many variations are possible. Accordingly, the scope of the invention should be determined not by the embodiments illustrated but by the appended claims and their legal equivalent.
What is claimed is:

Claims

1. A self-cooling container for fluids, comprising:
A. a first chamber including walls for defining a fluid region interior thereto,
B. a second chamber including walls for defining a refrigerant region interior thereto, said refrigerant region extending at least partially into said fluid region and being thermally coupled to said fluid region, and said refrigerant region being fluidicly isolated from said fluid region,
C. refrigerant dispersal assembly including:
i. means for forming a third chamber including walls for defining a dispersal region interior thereto, said dispersal region including a portion adjacent to said refrigerant region and separated therefrom by a coupling portion of said walls of said refrigerant region, said third chamber being vented to regions exterior to said container,
ii. cooling activation means for selectively forming a fluidic path from said refrigerant region to said dispersal region through said coupling portion of said walls.
2. A self-cooling container in accordance with claim 1 wherein said cooling activation means includes a perforation member supported by one of said walls defining said dispersal region and extending therefrom into said dispersal region toward said coupling portion of said walls, and
wherein said wall supporting said perforation member is displaceable in response to an externally, selectively applied force to establish motion of said perforation member, thereby piercing said coupling portion and forming said fluidic path.
3. A self-cooling container in accordance with claim 2 wherein said fluid is a beverage.
4. A self-cooling container in accordance with claim 3 wherein said first chamber is cylindrical and said second chamber is located axially within said first chamber at one end thereof and wherein said first chamber includes an openable port at the end opposite said one end for dispensing said beverage therefrom.
5. A self-cooling container in accordance with claim 2 wherein said coupling portion is a perforatable seal.
6. A self-cooling container in accordance with claim 2 wherein said first chamber is substantially cylindrical and said second chamber extends from one end of said first chamber.
7. A self-cooling container in accordance with claim 6 wherein said second chamber is substantially cylindrical and is substantially coaxial with said first chamber.
8. A self-cooling container in accordance with claim 2 wherein said displacement of said perforation member is guided by a threaded connection between said first chamber and said third chamber.
9. A self-cooling container in accordance with claim 2 wherein said displacement of said perforation member is guided by a bead-and-groove connection between said first chamber and second chamber.
10. A self-cooling container in accordance with claim 2 wherein said displacement of said perforation member is established by deformation of said wall of said third chamber supporting said perforation member.
11. A self-cooling container in accordance with claim 2 wherein said third chamber forming means includes a cup-shaped member and means for detachably coupling said cup-shaped member to said first chamber, whereby an exterior surface of said walls of said first chamber and an interior surface of said cup-shaped member cooperatively establish said third chamber.
12. A self-cooling container in accordance with claim 1 further comprising a predetermined amount of pressurized refrigerant in said refrigerant region.
5 13. A self-cooling container in accordance with claim 12 wherein said cooling activation means includes a perforation member supported by one of said walls defining said dispersal region and having a tapered pointed portion extending therefrom into 0 said dispersal region toward said coupling portion of said walls, and
wherein said wall supporting said perforation member is displaceable in response to an externally, 15 selectively applied force to establish motion of said tapered, pointed portion through said coupling portion of said walls, thereby piercing said coupling portion and forming said fluidic path.
20 14. A self-cooling container in accordance with claim 13 wherein said fluid is a beverage.
15. A self-cooling container in accordance with claim 14 wherein said first chamber is cylindrical 25 and said second chamber is located axially within said first chamber at one end thereof and wherein said first chamber includes an openable port at the end opposite said one end for dispensing said beverage therefrom.
30
16. A self-cooling container in accordance with claim 13 wherein said coupling portion is a perforatable seal.
17. A self-cooling container in accordance with claim 13 wherein said first chamber is substantially cylindrical and said second chamber extends from one end of said first chamber.
18. A self-cooling container in accordance with claim 17 wherein said second chamber is substantially cylindrical and is substantially coaxial with said first chamber.
19. A self-cooling container in accordance with claim 13 wherein said displacement of said perforation member is guided by a threaded connection between said first chamber and said third chamber.
20. A self-cooling container in accordance with claim 13 wherein said displacement of said perforation member is guided by a bead-and-groove connection between said first chamber and second chamber.
21. A self-cooling container in accordance with claim 13 wherein said displacement of said perforation member is established by deformation of said wall of said third chamber supporting said perforation member.
22. A self-cooling container in accordance with claim 13 wherein said third chamber forming means includes a cup-shaped member and means for detachably coupling said cup-shaped member to said first chamber, whereby an exterior surface of said walls of said first chamber and an interior surface of said cup-shaped member cooperatively establish said third chamber.
23. A self-cooling container in accordance with claim 1 wherein said third chamber forming means includes a cup-shaped member and means for detachably coupling said cup-shaped member to said first chamber, whereby an exterior surface of said walls of said first chamber and an interior surface of said cup-shaped member cooperatively form said third chamber.
24. A refrigerant dispersal assembly for attachment to a closed refrigerant chamber containing a pressurized refrigerant, comprising:
A. a cup-shaped member defining a dispersal region interior thereto, and including means for venting said dispersal region to regions external to said cup-shaped member,
B. a perforation member disposed on said cup-shaped member and extending therefrom into said dispersal region, and
C. means for coupling said cup-shaped member to said refrigerant chamber whereby said perforation member is adjacent said refrigerant chamber and said perforation member is selectively displaceable toward and into said refrigerant chamber.
25. A container for fluids comprising:
A. a first chamber including walls for defining a closed fluid region interior thereto for containing a fluid-to-be-cooled therein, said first chamber being substantially cylindrical,
B. a second chamber including walls for defining a closed refrigerant region interior thereto for containing a pressurized refrigerant therein, said refrigerant region extending at least partially into said fluid region and being thermally coupled to said fluid region, said second chamber being substantially cylindrical and extending from one end of said first chamber, said first chamber and said second chamber being coaxial,
C. means for receiving a refrigerant dispersal assembly for selectively forming a fluidic path from said refrigerant region to regions exterior to said container.
26. A container in accordance with claim 25 further comprising said refrigerant dispersal assembly, wherein said refrigerant dispersal assembly includes means for perforating a wall defining said refrigerant region.
27. A self-cooling container in accordance with claim 26 wherein said fluid is a beverage.
28. A container in accordance with claim 27 wherein said.first chamber further includes an openable port at the end opposite said one end for dispersing said beverage therefrom.
29. A self-cooling container in accordance with claim 25 wherein said fluid is a beverage.
30. A container in accordance with claim 29 wherein said first chamber further includes a selectively openable port at the end opposite said one end for dispersing said beverage therefrom.
PCT/BB1993/000001 1992-01-29 1993-01-15 Self-cooling fluid container WO1993015960A2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
BR9305807A BR9305807A (en) 1992-01-29 1993-01-15 Self-cooling container for fluids
AT93901073T ATE196684T1 (en) 1992-01-29 1993-01-15 SELF-COOLING LIQUID TANK
RU94045991A RU2110023C1 (en) 1992-01-29 1993-01-15 Self-cooling container for liquids; cooling agent discharge unit for such container and container proper
AU45155/93A AU660230B2 (en) 1992-01-29 1993-01-15 Self-cooling fluid container
EP93901073A EP0632877B1 (en) 1992-01-29 1993-01-15 Self-cooling fluid container
DK93901073T DK0632877T3 (en) 1992-01-29 1993-01-15 Self-propelled fluid container
DE69329492T DE69329492T2 (en) 1992-01-29 1993-01-15 SELF-COOLING LIQUID TANK
JP51361393A JP3176924B2 (en) 1992-01-29 1993-01-25 Self-cooling fluid container
KR1019940702552A KR100264826B1 (en) 1992-01-29 1993-01-25 Self-cooling fluid container
GR20000402829T GR3035141T3 (en) 1992-01-29 2000-12-27 Self-cooling fluid container.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/827,464 1992-01-29
US07/827,464 US5214933A (en) 1992-01-29 1992-01-29 Self-cooling fluid container

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WO1993015960A2 true WO1993015960A2 (en) 1993-08-19
WO1993015960A3 WO1993015960A3 (en) 1993-11-25

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US (1) US5214933A (en)
EP (1) EP0632877B1 (en)
JP (1) JP3176924B2 (en)
KR (1) KR100264826B1 (en)
AT (1) ATE196684T1 (en)
AU (1) AU660230B2 (en)
BR (1) BR9305807A (en)
CA (1) CA2128687A1 (en)
DE (1) DE69329492T2 (en)
DK (1) DK0632877T3 (en)
ES (1) ES2152245T3 (en)
GR (1) GR3035141T3 (en)
IL (1) IL104541A (en)
NZ (1) NZ246318A (en)
PT (1) PT632877E (en)
RU (1) RU2110023C1 (en)
WO (1) WO1993015960A2 (en)
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2786715A1 (en) * 1998-12-02 2000-06-09 Eurekan Method of making packaging container has sheet folded to form container with sealed base wall having gas reservoir
KR200477067Y1 (en) * 2013-05-23 2015-05-04 진광혁 Carbonated beverage container of minimization a effusion

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX9201422A (en) * 1992-03-30 1993-09-01 Francisco Javier Barroso Lujan IMPROVED CAN TYPE CONTAINER FOR STORAGE AND BEVERAGE ASSORTMENT, WHICH HAS AN INTEGRATED COOLING SYSTEM
EG20382A (en) * 1993-10-07 1999-02-28 Envirochill Int Ltd Self cooling fluid container
US6230501B1 (en) 1994-04-14 2001-05-15 Promxd Technology, Inc. Ergonomic systems and methods providing intelligent adaptive surfaces and temperature control
WO1996009506A1 (en) * 1994-09-22 1996-03-28 Scottish & Newcastle Plc Chilling device for beverage container
GB2307543B (en) * 1994-09-22 1998-08-26 Scottish & Newcastle Plc Chilling device for beverage container
GB2300468B (en) * 1995-03-31 1999-06-09 Cold Pack Technologies Ltd Refrigerating apparatus and method
US5655384A (en) * 1995-05-24 1997-08-12 The Joseph Company Self-cooling container including liner member
BR9607150A (en) 1995-05-24 1997-11-11 Joseph Co Self-cooling container including heat exchange unit for cooling
US5636522A (en) * 1995-11-06 1997-06-10 Ramos; John F. Cooling device for a beverage mug
IL126417A0 (en) 1996-04-04 1999-05-09 Joseph Co Combined valve cup and bottom assembly for self-cooling container
GB9614023D0 (en) * 1996-07-04 1996-09-04 Davidson Paul Sealed liquid container
US5943875A (en) * 1997-12-08 1999-08-31 Envirochill International, Ltd. Self-cooling fluid container with nested refrigerant and fluid chambers
NL1008077C2 (en) 1998-01-21 1999-07-22 Hoogovens Staal Bv Method for the manufacture of a metal can with insert for packaging, for example, a foodstuff and such a can.
US6253440B1 (en) * 1999-01-13 2001-07-03 Chill-Can International, Inc. Method of manufacturing self cooling beverage container
US6105384A (en) 1999-01-19 2000-08-22 Chill-Can International, Inc. Self-cooling or self-heating food or beverage container having heat exchange unit with external protective coating
US6102108A (en) * 1999-01-27 2000-08-15 Chill-Can International, Inc. Heat exchange unit having thermally conductive discs having preferential flow paths
US6128906A (en) * 1999-02-10 2000-10-10 Chill-Can International, Inc. Non-metallic food or beverage container having a heat exchange unit contained therein
US6487766B2 (en) * 1999-02-10 2002-12-03 Chill-Can International, Inc. Manufacturing process for container including a heat exchange unit as an integral part thereof
WO2001090666A1 (en) * 2000-04-22 2001-11-29 Jung Min Lee Self-cooling liquid container
FR2810015B1 (en) * 2000-06-13 2004-05-28 Thermagen METHOD FOR MANUFACTURING A SELF-REFRIGERATING BEVERAGE PACKAGE AND EQUIPMENT FOR CARRYING OUT SAID METHOD
FR2810021B1 (en) 2000-06-13 2004-05-21 Thermagen SELF-REFRIGERATING BEVERAGE PACKAGING
KR20030008637A (en) * 2001-07-19 2003-01-29 황익현 Container having self-cooling function
FR2832325B1 (en) * 2001-11-16 2004-09-10 Thermagen LIQUID-GAS STATE SEPARATOR
FR2832495B1 (en) * 2001-11-16 2004-02-20 Thermagen HEAT EXCHANGER
EP1562009A1 (en) * 2004-02-06 2005-08-10 Thermagen S.A. Actuating device for self cooling packaging
DE102005030040B4 (en) * 2005-06-27 2007-10-11 Morich, Guido B. cooler
WO2007139429A1 (en) * 2006-05-26 2007-12-06 Vladimir Anatolevich Matveev Self-cooling beverage tin
US20080271476A1 (en) * 2007-02-09 2008-11-06 Elias Langguth Endothermic beverage cooler
JP5551180B2 (en) * 2008-12-09 2014-07-16 カールスバーグ・ブルワリーズ・エー/エス System and method for providing a self-cooling vessel
ITTV20100109A1 (en) * 2010-07-28 2012-01-29 Luca Cominotto CONTAINER FOR BEVERAGES
WO2016154025A1 (en) * 2015-03-20 2016-09-29 Joseph Company International, Inc. Self-cooling food or beverage container having a heat exchange unit using liquid carbon dioxide and having a dual function valve
WO2019168492A1 (en) * 2018-03-02 2019-09-06 Anthony Michael Mark Humidification and dehumidification process and apparatus for chilling beverages and other food products and process of manufacture

Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR513015A (en) * 1916-07-29 1921-02-05 Theodore Dory Sterne Mechanical-chemical process for the instantaneous production of cold and heat in hermetically sealed containers
US2881321A (en) * 1957-08-30 1959-04-07 Walter J Dauksher Variable frequency crystal controlled oscillator
US2898747A (en) * 1958-01-07 1959-08-11 Ind Patent Corp Self-refrigerating container
US3257821A (en) * 1965-08-24 1966-06-28 John M Warner Self-contained beverage cooler
US3338067A (en) * 1966-06-28 1967-08-29 Combined beverage and refrigerant containers
US3417573A (en) * 1963-11-06 1968-12-24 John M. Warner Method of making a self-contained refrigeration system
US3494142A (en) * 1968-04-23 1970-02-10 Wray Jr John Robert End closure and coolant insert for self-cooling container
US3696633A (en) * 1970-12-21 1972-10-10 Evan D Mills Container cooling device
US3759060A (en) * 1972-06-28 1973-09-18 Marian Cax Disposable refrigerated container that can be refilled, reused or recycled
US3852975A (en) * 1973-04-06 1974-12-10 W Beck Self-chilling container with safety device and method of making same
JPS523758A (en) * 1975-06-25 1977-01-12 Tamotsu Kawabata Drink container equiped with an instantaneous refrigerating device
US4584848A (en) * 1983-11-03 1986-04-29 Barnett Eugene R Container
US4656838A (en) * 1985-11-11 1987-04-14 Shen Hwang K Cooling device for a can containing a beverage
US4669273A (en) * 1986-05-07 1987-06-02 Liquid Co2 Engineering Inc. Self-cooling beverage container
US4688395A (en) * 1985-10-03 1987-08-25 Superior Marketing Research Corp. Self-contained cooling device for food containers
US4791789A (en) * 1987-11-06 1988-12-20 Wilson John J Automatic self-cooling device for beverage containers
US4925470A (en) * 1989-04-14 1990-05-15 Chou Tien Fa Bottom ejection type instant cooling easy-opener with amusement effect
US4941328A (en) * 1989-07-07 1990-07-17 Sheu Lai Fa Metal can ends with metal pull tabs bonded thereto
US4993236A (en) * 1987-11-06 1991-02-19 Wilson John J Sensitive pressure actuated automatic self-cooling device for beverage containers
US4993237A (en) * 1989-09-21 1991-02-19 Heritage Ventures U.S., Ltd. Self-cooling containers
US5201183A (en) * 1992-04-29 1993-04-13 Ramos John F Cooling device for beverage cans

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2082381A (en) * 1935-03-19 1937-06-01 James M W Chamberlain Shipping and/or storing perishable commodities
US3369369A (en) * 1964-12-21 1968-02-20 Joseph F. Weiss Food container
US3309890A (en) * 1965-03-15 1967-03-21 Eugene R Barnett Refrigerated disposable container
US3320767A (en) * 1965-09-23 1967-05-23 George J Whalen Self-chilling disposable container
US3373581A (en) * 1966-08-31 1968-03-19 Wray Jr John Robert Container arrangement with coolant therein
US3494143A (en) * 1968-04-26 1970-02-10 Eugene R Barnett Disposable container
AU4281768A (en) * 1968-08-30 1971-02-25 ROSENFELD and STUART FREDERICK FOX NATHAN Method of cooling containers
US3881321A (en) * 1970-02-24 1975-05-06 Drackett Co Self-cooling disposable liquid container
US3990613A (en) * 1975-06-30 1976-11-09 Chill-Can International, Ltd. Aerosol container closure
US4838242A (en) * 1986-07-28 1989-06-13 Oblon Ronald P Device for changing temperature of material therein
CA1294191C (en) * 1986-12-22 1992-01-14 Thomas George Smith Sawmill carriage
ZA871417B (en) * 1987-02-27 1987-09-16 Huang Kin-Shen Beverage can cooling device
US4802343A (en) * 1987-07-01 1989-02-07 The Coca-Cola Company Self-cooling container
US4928495A (en) * 1989-06-22 1990-05-29 Israel Siegel Self cooling and self heating container
US5042258A (en) * 1989-08-07 1991-08-27 Sundhar Shaam P Drinking container
US5079932A (en) * 1991-01-30 1992-01-14 Israel Siegel Direct sorption self-cooling beverage container

Patent Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR513015A (en) * 1916-07-29 1921-02-05 Theodore Dory Sterne Mechanical-chemical process for the instantaneous production of cold and heat in hermetically sealed containers
US2881321A (en) * 1957-08-30 1959-04-07 Walter J Dauksher Variable frequency crystal controlled oscillator
US2898747A (en) * 1958-01-07 1959-08-11 Ind Patent Corp Self-refrigerating container
US3417573A (en) * 1963-11-06 1968-12-24 John M. Warner Method of making a self-contained refrigeration system
US3257821A (en) * 1965-08-24 1966-06-28 John M Warner Self-contained beverage cooler
US3338067A (en) * 1966-06-28 1967-08-29 Combined beverage and refrigerant containers
US3494142A (en) * 1968-04-23 1970-02-10 Wray Jr John Robert End closure and coolant insert for self-cooling container
US3696633A (en) * 1970-12-21 1972-10-10 Evan D Mills Container cooling device
US3759060A (en) * 1972-06-28 1973-09-18 Marian Cax Disposable refrigerated container that can be refilled, reused or recycled
US3852975A (en) * 1973-04-06 1974-12-10 W Beck Self-chilling container with safety device and method of making same
JPS523758A (en) * 1975-06-25 1977-01-12 Tamotsu Kawabata Drink container equiped with an instantaneous refrigerating device
US4584848A (en) * 1983-11-03 1986-04-29 Barnett Eugene R Container
US4688395A (en) * 1985-10-03 1987-08-25 Superior Marketing Research Corp. Self-contained cooling device for food containers
US4656838A (en) * 1985-11-11 1987-04-14 Shen Hwang K Cooling device for a can containing a beverage
US4669273A (en) * 1986-05-07 1987-06-02 Liquid Co2 Engineering Inc. Self-cooling beverage container
US4791789A (en) * 1987-11-06 1988-12-20 Wilson John J Automatic self-cooling device for beverage containers
US4993236A (en) * 1987-11-06 1991-02-19 Wilson John J Sensitive pressure actuated automatic self-cooling device for beverage containers
US4925470A (en) * 1989-04-14 1990-05-15 Chou Tien Fa Bottom ejection type instant cooling easy-opener with amusement effect
US4941328A (en) * 1989-07-07 1990-07-17 Sheu Lai Fa Metal can ends with metal pull tabs bonded thereto
US4993237A (en) * 1989-09-21 1991-02-19 Heritage Ventures U.S., Ltd. Self-cooling containers
US5201183A (en) * 1992-04-29 1993-04-13 Ramos John F Cooling device for beverage cans

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0632877A1 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2786715A1 (en) * 1998-12-02 2000-06-09 Eurekan Method of making packaging container has sheet folded to form container with sealed base wall having gas reservoir
KR200477067Y1 (en) * 2013-05-23 2015-05-04 진광혁 Carbonated beverage container of minimization a effusion

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DE69329492D1 (en) 2000-11-02
GR3035141T3 (en) 2001-04-30
CA2128687A1 (en) 1993-08-19
JPH08509540A (en) 1996-10-08
ATE196684T1 (en) 2000-10-15
AU660230B2 (en) 1995-06-15
KR100264826B1 (en) 2000-09-01
ES2152245T3 (en) 2001-02-01
RU94045991A (en) 1997-03-27
WO1993015960A3 (en) 1993-11-25
IL104541A (en) 1995-10-31
AU4515593A (en) 1993-09-03
EP0632877A4 (en) 1995-04-19
NZ246318A (en) 1996-06-25
EP0632877B1 (en) 2000-09-27
DE69329492T2 (en) 2001-05-10
KR950700524A (en) 1995-01-16
EP0632877A1 (en) 1995-01-11
US5214933A (en) 1993-06-01
DK0632877T3 (en) 2001-02-05
PT632877E (en) 2001-03-30
JP3176924B2 (en) 2001-06-18
ZA93617B (en) 1993-08-30
BR9305807A (en) 1997-02-18
IL104541A0 (en) 1993-05-13
RU2110023C1 (en) 1998-04-27

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