WO1993017572A1 - Improved wax-free chewing gum base and chewing gums prepared therefrom - Google Patents

Improved wax-free chewing gum base and chewing gums prepared therefrom Download PDF

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Publication number
WO1993017572A1
WO1993017572A1 PCT/US1992/011317 US9211317W WO9317572A1 WO 1993017572 A1 WO1993017572 A1 WO 1993017572A1 US 9211317 W US9211317 W US 9211317W WO 9317572 A1 WO9317572 A1 WO 9317572A1
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WO
WIPO (PCT)
Prior art keywords
per cent
chewing gum
weight per
elastomer
wax
Prior art date
Application number
PCT/US1992/011317
Other languages
French (fr)
Inventor
Steven P. Synosky
Michael A. Reed
Gordon N. Mcgrew
Original Assignee
Wm. Wrigley Jr. Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to PCT/US1992/001686 priority Critical patent/WO1993017570A1/en
Priority to AU22925/92A priority patent/AU2292592A/en
Priority claimed from PCT/US1992/001686 external-priority patent/WO1993017570A1/en
Application filed by Wm. Wrigley Jr. Company filed Critical Wm. Wrigley Jr. Company
Priority to AU34265/93A priority patent/AU3426593A/en
Priority to DK93907161T priority patent/DK0652712T3/en
Priority to EP93907161A priority patent/EP0652712B1/en
Priority to DE69315329T priority patent/DE69315329T2/en
Priority to ES93907195T priority patent/ES2169039T3/en
Priority to DK93907177T priority patent/DK0627885T3/en
Priority to PCT/US1993/001904 priority patent/WO1993017575A1/en
Priority to CA002130571A priority patent/CA2130571A1/en
Priority to EP93908275A priority patent/EP0632696A4/en
Priority to DE69310727T priority patent/DE69310727T2/en
Priority to CA002130576A priority patent/CA2130576A1/en
Priority to PCT/US1993/001941 priority patent/WO1993017578A1/en
Priority to PCT/US1993/001943 priority patent/WO1993017579A1/en
Priority to AU37865/93A priority patent/AU3786593A/en
Priority to EP93907193A priority patent/EP0633729B1/en
Priority to PCT/US1993/001903 priority patent/WO1993017574A1/en
Priority to PCT/US1993/002222 priority patent/WO1993017580A1/en
Priority to CA002130569A priority patent/CA2130569C/en
Priority to AU39153/93A priority patent/AU3915393A/en
Priority to CA002130572A priority patent/CA2130572C/en
Priority to EP93908274A priority patent/EP0632695A4/en
Priority to JP5515875A priority patent/JPH08508156A/en
Priority to PCT/US1993/001922 priority patent/WO1993017576A1/en
Priority to EP93908281A priority patent/EP0633730B1/en
Priority to AU39152/93A priority patent/AU3915293A/en
Priority to CA002130573A priority patent/CA2130573C/en
Priority to DK93908281.4T priority patent/DK0633730T3/en
Priority to PCT/US1993/001940 priority patent/WO1993017577A1/en
Priority to AT93907193T priority patent/ATE152883T1/en
Priority to PCT/US1993/001900 priority patent/WO1993017573A1/en
Priority to EP93907195A priority patent/EP0627886B1/en
Priority to AU37886/93A priority patent/AU673163B2/en
Priority to CA002130568A priority patent/CA2130568C/en
Priority to AU37884/93A priority patent/AU673666B2/en
Priority to DE69330428T priority patent/DE69330428T2/en
Priority to DE69319126T priority patent/DE69319126T2/en
Priority to AU37877/93A priority patent/AU3787793A/en
Priority to DK93907193.2T priority patent/DK0633729T3/en
Priority to CA002130574A priority patent/CA2130574C/en
Priority to AU39158/93A priority patent/AU673353B2/en
Priority to EP93907424A priority patent/EP0661926B1/en
Priority to DE69331460T priority patent/DE69331460T2/en
Priority to EP93907177A priority patent/EP0627885B1/en
Priority to DK93907195T priority patent/DK0627886T3/en
Priority to DE69331413T priority patent/DE69331413T2/en
Priority to DK93907424T priority patent/DK0661926T3/en
Priority to CA002130575A priority patent/CA2130575C/en
Priority to AU38030/93A priority patent/AU3803093A/en
Publication of WO1993017572A1 publication Critical patent/WO1993017572A1/en
Priority to FI943830A priority patent/FI943830A/en
Priority to FI943824A priority patent/FI943824A/en
Priority to FI943831A priority patent/FI943831A/en
Priority to FI943828A priority patent/FI943828A/en
Priority to FI943825A priority patent/FI943825A/en
Priority to FI943826A priority patent/FI943826A/en
Priority to FI943829A priority patent/FI943829A/en
Priority to US08/306,027 priority patent/US5462754A/en
Priority to AU68173/96A priority patent/AU683805B2/en
Priority to AU70286/96A priority patent/AU7028696A/en
Priority to AU70292/96A priority patent/AU684435B2/en
Priority to AU70524/96A priority patent/AU693044B2/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/02Apparatus specially adapted for manufacture or treatment of chewing gum
    • A23G4/04Apparatus specially adapted for manufacture or treatment of chewing gum for moulding or shaping
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/066Chewing gum characterised by the composition containing organic or inorganic compounds characterised by the fat used
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G4/00Chewing gum
    • A23G4/06Chewing gum characterised by the composition containing organic or inorganic compounds
    • A23G4/08Chewing gum characterised by the composition containing organic or inorganic compounds of the chewing gum base

Abstract

A chewing gum base is provided which is devoid or substantially free of wax. The gum base includes about 20 to about 60 weight per cent synthetic elastomer, 0 to about 30 weight per cent natural elastomer, about 5 to about 55 weight per cent elastomer plasticizer, about 4 to about 35 weight per cent filler, about 5 to about 35 weight per cent softener, and optional minor amounts of miscellaneous ingredients such as colors, antioxydants, etc. Chewing gum compositions which contains the wax-free gum base are also provided.

Description

IMPROVED WAX-FREE CHEWING GUM BASE
AND CHEWING GUMS PREPARED THEREFROM
RELATED APPLICATIONS
This application is a continuation-in-part of International Application No. PCT/US92/09615, filed on November 6, 1992, which in turn is a continuation-in-part of PCT/US92/01686, filed on March 3, 1992.
FIELD OF THE INVENTION
The present invention relates to an improved chewing gum base of the type which does not contain wax, and to chewing gum products containing wax-free gum bases.
BACKGROUND OF THE INVENTION
U.S. Patent 3,984,574, issued to Comollo, discloses an abhesive chewing gum base in which the non-tack properties were achieved by eliminating conventional chewing gum base ingredients which were found to contribute to chewing gum tackiness, and by substituting non-tacky ingredients in place of the conventional ingredients. Specifically, it was
discovered that three classes of materials account for conventional chewing gum tackiness. These materials are elastomers, resins, and waxes.
Comollo eliminated natural and some synthetic elastomert from chewing gum base, and substituted in their place one or more non-tacky synthetic elastomers such as polyisobutylene, polyisoprene, isobutylene-isoprene copolymer and butadiene-styrene copolymer.
Comollo also eliminated the tack-producing natural resins and modified natural resins and used instead relatively high amounts of hydrogenated or partially hydrogenated vegetable oils or animal fats. Finally,
Comollo completely excluded waxes from the gum base, but included polyvinyl acetate, fatty acids, and mono and diglycerides of fatty acids.
SUMMARY OF THE INVENTION
The present invention is directed to a wax-free chewing gum base (i.e. a chewing gum base which is free of hydrocarbon-containing waxes) and chewing gums prepared therefrom. The gum base of the invention includes quantities of synthetic elastomer, elastomer plasticizer, filler and softener, and, like the gum base of Comollo, is substantially free of wax.
However, the gum base of the invention is not limited to use in a non-tack chewing gum and may, therefore, contain optional quantities of natural elastomer and/or natural resins. The gum base of the invention may also contain optional quantities of minor ingredients such as color and antioxidant.
The use of natural elastomers in the gum base compliments certain chewing gum flavors, such as mint oil, by rounding out the otherwise harsh or grassy notes in the flavor. The presence of natural
elastomers and natural resins in the gum base also contributes to improved chewing gum texture and flavor retention. There is currently a need or desire in the chewing gum industry for gum bases which are devoid or substantially free of hydrocarbon-containing waxes and which contain desired quantities of natural elastomers, natural resins, or both. With the foregoing in mind, it is a feature and advantage of the invention to provide a substantially wax-free chewing gum base.
It is also a feature and advantage of the invention to provide a suitably soft gum base in which wax is not needed to soften the gum base.
It is also a feature and advantage of the invention to improve the compatibility of gum base ingredients during the blending process, since no wax is present to cause incompatibility.
It is also a feature and advantage of the invention to provide improved chewing gums which contain the wax-free chewing gum base of the invention.
It is also a feature and advantage of the invention to provide improved chewing gums made from said inventive base which does not retain the amount of flavor typical sugarless gums retain after chewing.
It is also a feature and advantage of the invention to provide improved chewing gums that hydrate better during about one to three minutes of chewing.
It is also a feature and advantage of the invention to provide chewing gum products having desirable properties such as flavor quality and
strength, flavor and sweetness retention, breath freshening, dental and oral health properties and good shelf stability.
The foregoing and other features and advantages will become further apparent from the following detailed description of the presently preferred
embodiments, when read in conjunction with the accompanying examples. It should be understood that the detailed description and examples are illustrative rather than limitative, the scope of the present invention being defined by the appended claims and equivalents thereof. DETAILED DESCRIPTION OF THE
PRESENTLY PREFERRED EMBODIMENTS
In accordance with the invention, a chewing gum base is provided for use in either non-tack or conventional chewing gum, which may be either bubble gum or regular chewing gum. The chewing gum base of the invention contains about 20 to about 60 weight per cent synthetic elastomer, 0 to about 30 weight per cent natural elastomer, about 5 to about 55 weight per cent elastomer plasticizer, about 4 to about 35 weight per cent filler, about 5 to about 35 weight per cent softener, and optional minor amounts (about one per cent or less) of miscellaneous ingredients such as colorants, antioxidants, etc.
Synthetic elastomers may include, but are not limited to, polyisobutylene with GPC molecular weightof about 10,000 to about 95,000, isobutylene-isoprene copolymer (butyl elastomer), styrene-butadiene
copolymers having styrene-butadiene ratios of about 1:3 to about 3:1, polyvinyl acetate having GPC molecular weight of about 2,000 to about 90, 000, polyisoprene, polyethylene, vinyl acetate-vinyl laurate copolymer having vinyl laurate content of about 5 to about 50 percent by weight of the copolymer, and combinations thereof.
Preferred ranges are, for polyisobutylene, 50,000 to 80,000 GPC molecular weight, for styrene-butadiene, 1:1 to 1:3 bound styrene-butadiene, for polyvinyl acetate, 10,000 to 65,000 GPC molecular weight with the higher molecular weight polyvinyl acetates typically used in bubble gum base, and for vinyl acetate-vinyl laurate, vinyl laurate content of 10-45 percent.
Natural elastomers may include natural rubber such as smoked or liquid latex and guayule as well as natural gums such as jelutong, lechi caspi, perillo, sorva, massaranduba balata, massaranduba chocolate, nispero, rosindinha, chicle, gutta hang kang,
chiquibul, crown gum, pendare, venezuelau chicle, leche de vaca, niger gutta, tunu, chilte and combinations thereof. The preferred natural elastomers are
jelutong, chicle, sorva and massaranduba balata. The preferred elastomers and elastomer concentrations vary depending on whether the chewing gum in which the base is used is abhesive or conventional, bubble gum or regular gum, as discussed below.
Elastomer plasticizers may include, but are not limited to, natural rosin esters such as glycerol esters of partially hydrogenated rosin, glycerol esters of polymerized rosin, glycerol esters of partially dimerized rosin, glycerol esters of rosin, glycerol ester of tall oil rosin, pentaerythritol esters of partially hydrogenated rosin, methyl and partially hydrogenated methyl esters of rosin, pentaerythritol esters of rosin; synthetics such as terpene resins derived from alpha-pinene, beta-pinene, and/or d-limonene; natural terpene resin; and any suitable combinations of the foregoing. The preferred elastomer plasticizers will also vary depending on the specific application, and on the type of elastomer which is used. For example, use of terpene resin to wholly or partially replace ester gums will cause the gum base to be less tacky.
The term "wax- free" as used herein refers to the exclusion of waxes which contain mineral
hydrocarbons. Natural waxes such as carnauba wax, bees wax, rice bran wax, and candellila wax do not contain mineral hydrocarbons and are therefor acceptable for use in the chewing gum base and chewing gums prepared therefrom.
Fillers/texturizers may include magnesium and calcium carbonate, ground limestone, silicate types such as magnesium and aluminum silicate, cxay, alumina, talc, titanium oxide, mono-, di- and tri-calcium phosphate, cellulose polymers, such as wood, and combinations thereof.
Softeners/emulsifiers may include tallow, hydrogenated tallow, hydrogenated and partially
hydrogenated vegetable oils, cocoa butter, glycerol monostearate, glycerol triacetate, lecithin, mono-, di- and triglycerides, acetylated monoglycerides, fatty acids (e.g. stearic, palmitic, oleic and linoleic acids), lanolin, diacetin, and combinations thereof. Hydrogenated vegetable oils are generally preferred, either alone or in combination with other softeners.
Colorants and whiteners may include FD&C-type dyes and lakes, fruit and vegetable extracts, titanium dioxide, cocoa powder and combinations thereof.
The wax-free gum base of the invention may also contain optional ingredients such as antioxidants. Synthetic antioxidants may include butylated
hydroxyanisole (BHA), butylated hydroxy-toluene (BHT) and tertiary, butyl hydroquinone (TBHQ). Natural antioxidants may include tocopherols, mixed
tocopherols, eugenol, gum guaiac, thymol, carvacrol, and spice extracts of thyme, oregano, rosemary, nutmeg, ginger and mixtures thereof. The usage level will depend on the antioxidant selected but will generally be at or above the level of maximum effectiveness.
When the wax-free gum base of the invention is to be used in a regular (non-bubble) gum which has at least some abhesive (reduced tack) characteristics, the base should contain about 10 to about 40 weight per cent synthetic elastomer, about 15 to about 30 weight per cent elastomer plasticizer, about 5 to about 30 weight per cent filler, about 15 to about 35 weight per cent softener, 0 to about 1 weight per cent colorant and 0 to about 0.1 weight per cent antioxidant. Specific embodiments of the wax-free gum base are provided in Examples 1-35 below.
Figure imgf000009_0001
Figure imgf000010_0001
Figure imgf000011_0001
Figure imgf000012_0001
Figure imgf000013_0001
Figure imgf000014_0001
Figure imgf000015_0001
When the wax-free gum base of the invention is to be used in a regular (non-bubble) gum which does not have abhesive characteristics, the base should contain about 12 to about 30 weight per cent natural elastomer, about 20 to about 40 weight per cent synthetic elastomer, about 4 to about 25 weight per cent elastomer plasticizer, about 5 to about 25 weight per cent filler, about 15 to about 30 weight per cent softener, 0 to about 1 weight per cent colorant and 0 to about 0.1 weight per cent antioxidant. Specific embodiments of the wax-free gum base fitting this description are provided in Examples 36-60 below:
Figure imgf000017_0001
Figure imgf000018_0001
Figure imgf000019_0001
Figure imgf000020_0001
Figure imgf000022_0001
When the wax-free gum base of the invention is to be used in a bubble gum, the base should contain about 30 to about 60 weight per cent synthetic
elastomer, about 5 to about 55 weight per cent
elastomer plasticizer, about 10 to about 35 weight per cent filler, about 5 to about 25 weight per cent softener, 0 to about 1 weight per cent colorant and 0 to about 0.1 weight per cent antioxidant. Specific embodiments of the wax-free base for use in bubble gum are provided in Examples 61-79 below.
Figure imgf000023_0001
Figure imgf000024_0001
Figure imgf000025_0001
Figure imgf000026_0001
The wax-free gum base of the invention constitutes about 5-95 weight per cent of the chewing gum, more typically 10-50 weight per cent of the chewing gum, and most commonly 20-35 weight per cent of the chewing gum. The gum base is typically prepared by adding an amount of the elastomer, elastomer plasticizers and filler to a heated sigma blade mixer with a front to rear blade speed ratio of typically 2:1. The initial amounts of ingredients are determined by the working capacity of the mixing kettle in order to attain a proper consistency. After the initial
ingredients have massed homogeneously, the balance of the elastomer plasticizer, filler, softeners, etc. are added in a sequential manner until a completely homo geneous molten mass is attained. This can usually be achieved in one to four hours, depending on the
formulation. The final mass temperature can. be between 60°C and 150°C, more preferably between 80°C and 120°C. The completed molten mass is emptied from the mixing kettle into coated or lined pans, extruded or cast into any desirable shape and allowed to cool and solidify.
Although the above method for making base is typical and applies to both chewing and bubble bases, it has been found that there is a preferred method for making the bubble bases described in this invention.
First, all of the polyvinyl acetate and portions of the polyisobutylene and filler are added and blended in a heated sigma blade mixer. Softeners such as glyceryl triacetate and/or acetylated monoglyceride are then added along with a second portion of each of polyisobutylene and filler. The acetylated monoglyceride may be added at the end of the process if desired and still not alter the chewing texture of the gum made from the base.
Next, the rest of the polyisobutylene and filler are added along with the elastomer plasticizer. Finally, the remaining ingredients such as glycerol monostearate and antioxidants may be added. Colorant may be added at any time during the mixing process and is preferably added at the start.
There are some variations to the above described preferred method which in no way limits the method as described. Those skilled in the art of gum base manufacture may be able to appreciate any minor variations.
In producing wax-containing gum bases high in polyvinyl acetate, and particularly those high in high molecular weight polyvinyl acetate, it is necessary to improve blending of the ingredients by removing the heat applied to the sigma blade mixer at some point in the process. This reduces the temperature of the gum base and causes greater compatibility of its
ingredients. In the inventive gum base process for making the inventive gum base free of wax, there is no need to remove the heat applied. The degree of
incompatibility is greatly reduced since there is no wax present. Nevertheless, heat is preferably removed at about 30 minutes to about 90 minutes into the mixing time of the base production process.
In addition to the water-insoluble gum base, a typical chewing gum composition includes a water soluble bulk portion and one or more flavoring agents. The wax-free gum base of the invention can be used in any typical chewing gum composition.
The water soluble portion of the chewing gum may include softeners, bulk sweeteners, high intensity sweeteners, flavoring agents and combinations thereof. Softeners are added to the chewing gum in order to optimize the chewability and mouth feel of the gum. The softeners, which are also known as plasticizers or plasticizing agents, generally constitute between about .5-15% by weight of the chewing gum. The softeners may include glycerin, lecithin, glycerol monostearate, hydroxylated lecithin, agar, carrageenan, and
combinations thereof. Aqueous sweetener solutions such as those containing sorbitol, hydrogenated starch hydrolysates, corn syrup and combinations thereof, may also be used as softeners and binding agents in chewing gum.
Bulk sweeteners constitute between 5-95% by weight of the chewing gum, more typically 20-80% by weight of the chewing gum and most commonly 30-60% by weight of the chewing gum. Bulk sweeteners may include both sugar and sugarless sweeteners and components. Sugar sweeteners may include saccharide containing components including but not limited to sucrose, dextrose, maltose, dextrin, dried invert sugar,
fructose, levulose, galactose, corn syrup solids, high maltose syrup, invert/high fructose syrup, maltotriose, glyceraldehyde, erytrose, xylose, lactose, leucrose, -L sugars, fructooligosaccharide and low calorie bulking agents such as indigestible dextrin, guar gum
hydrolyzate, oligofructose, polydextrose, and the like, alone or in combination. Sugarless sweeteners include components with sweetening characteristics but are devoid of the commonly known sugars. Sugarless
sweeteners include but are not limited to sugar
alcohols such as sorbitol, mannitol, xylitol,
hydrogenated starch hydrolysates, maltitol, lactitol, erythritol, cellobiitol, and the like, alone or in combination.
High intensity sweeteners may also be present and are commonly used with sugarless sweeteners. When used, high intensity sweeteners typically constitute between .001-5% by weight of the chewing gum, preferably between .01-1% by weight of the chewing gum.
Typically, high intensity sweeteners are at least 20 times sweeter than sucrose. These may include but are not limited to sucralose, aspartame, salts of
acesulfame, alitame, saccharin and its salts, cyclamic acid and its salts, glycyrrhizin, dihydrochalcones, thaumatin, monellin, stevia and the like, alone or in 3 combination.
Sweeteners and other active ingredients can be incorporated into chewing gum after being
encapsulated in order to modify their release. The most common ways of modifying the release of the active ingredients include spray drying, spray chilling, fluid-bed coating, coacervation, absorption, extrusion encapsulation, and other standard encapsulating
techniques. The active ingredient may be modified in a multiple step process comprising any of the processes noted. Encapsulating agents that can be used include polyvinyl acetate, acrylic polymers and copolymers, carboxyvinyl polymer, polyamides, polystyrene,
polyvinyl pyrrolidone, natural waxes, zein, shellac, agar, alginates, a wide range of cellulose derivatives including ethyl cellulose, methyl cellulose, sodium hydroxymethyl cellulose, and hydroxypropylmethyl cellulose and sodium carboxy methyl cellulose, dextrin, gelatin, modified starches, acacia, maltodextrin, gum arabic, xanthan gum, relatin and pectin.
Combinations of sugar and/or sugarless sweeteners may be used in chewing gum. The sweetener may also function in the chewing gum in whole or in part as a water soluble bulking agent. Additionally, the softener may also provide additional sweetness such as with aqueous sugar or alditol solutions.
Flavoring agents should generally be present in the chewing gum in an amount within the range of about 0.1-15% by weight of the chewing gum, preferably between about 0.2-5% by weight of the chewing gum, most preferably between about 0.5-3% by weight of the chewing gum. Flavoring agents may include essential oils, synthetic flavors or mixtures thereof including but not limited to oils derived from plants and fruits such as citrus oils, fruit essences, peppermint oil, spearmint oil, other mint oils, clove oil, oil of wintergreen, anise and the like. Artificial flavoring agents and components may also be used. Natural and artificial flavoring agents may be combined in any sensorially acceptable fashion.
Optional ingredients such as colors, emulsifiers, pharmaceutical agents, vitamins, and additional flavoring agents may also be included in chewing gum. Additionally, food acidulants such as lactic acid, acetic acid, hydrochloric acid, fumaric acid, phosphoric acid, adipic acid, sulfuric acid, succinic acid, tannic acid and combinations thereof may be used.
Chewing gum is generally manufactured by sequentially adding the various chewing gum ingredients to any commercially available mixer known in the art. After the ingredients have been thoroughly mixed, the gum mass is discharged from the mixer and shaped into the desired form such as by rolling into sheets and cutting into sticks, extruding into chunks, or casting into pellets. Generally, the ingredients are mixed by first melting the gum base and adding it to the running mixer. The gum base may alternatively be melted in the mixer. Color and emulsifiers can be added at this time.
A softener such as glycerin can be added next along with syrup and part of the bulk portion. Further parts of the bulk portion may then be added to the mixer. Flavoring agents are typically added with the final part of the bulk portion. The entire mixing process typically takes from five to fifteen minutes, although longer mixing times are sometimes required. Those skilled in the art will recognize that variations of this mixing procedure, or other mixing procedures, may be followed.
The chewing gum can be dusted with various substances to reduce the stickiness and improve the initial taste of the gum. The material used to dust the chewing gum are referred to as "dusting compounds" or, alternatively "rolling compounds," because the compounds are used to make to the gum more manageable during processing including rolling and sheeting. The rolling compound used can be selected from the group consisting of sucrose, mannitol, starch, calcium carbonate, talc, lactitol, palatinit (hydrogenated isomaltulose), lactose, and combinations thereof. To improve the flavor impact and duration of the gum, flavor, gum base, and sweetener can be added to the rolling compound.
Chewing gum products contemplated as part of the present invention are generally similar to products using traditional wax-containing bases. Many general types of products can be produced including reduced tack gums, sugarless gums, bubble gums (sugarless or sugar-containing), coated ball or pellet gums (sugarless or sugar-containing), dental health gums, breath freshening gums, novelty gums, low calorie gums and pharmaceutical gums. The products may be of any flavor, and may be processed in a variety of ways in either batch or continuous processes, and formed into any final shape including sticks, tabs, chunks, tapes, coextruded products, molded shapes, etc.
The following formulas are illustrative of types of products which may be produced. All
ingredient levels are expressed in weight percent.
Examples 80-103 illustrate non-tack and reduced-tack chewing gums of the present invention. As can be seen, there is much latitude in the selection of flavors sweeteners and ingredient levels. Examples 80-91 illustrate use of the invention with sugar gums while Examples 92-103 describe sugarless gums.
Encapsulated sweeteners are used to extend sweetness and flavor and to protect the artificial sweetener from degradation during storage. Examples 94 and 96 are low moisture products having moisture levels below 2%.
Note that flavors which are subject to oxidation, particularly peppermint oil, should be protected through the use of antioxidants. For
instance, the peppermint flavor in Examples 80, 84, 85, 87, 88 and 89 should include an antioxidant or a combination of antioxidants to stabilize the flavor. The antioxidant can be selected from the group
consisting of BHA, BHT, TBHQ, Tocopherols, Propyl Gallate, Eugenol, Gum Guaiac, Tea extracts, spice extracts such as thyme, oregano, rosmary, nutmeg and ginger) and mixtures thereof. The usage level will depend on the antioxidant selected but will generally be at or above the level of maximum effectiveness as determined experimentally.
These antioxidants may be added to the flavor before incorporation into the gum product, or they may be added to the overall gum formula.
Figure imgf000034_0001
Figure imgf000035_0001
Figure imgf000036_0001
Figure imgf000037_0001
Examples 104-109 are sugarless products made with the non-reduced-tack bases of the present
invention. Examples 110-115 are equivalent sugar products.
Figure imgf000038_0001
Figure imgf000039_0001
Examples 116-127 are examples of inventive coated pellet gums made with non-wax bases. The gum products of these examples are formed into pellets or balls for subsequent coating. Examples 116-121 are sugar pellets which could be coated with sugar syrups. Such syrups may contain modified starch (0 to 6.0%), compatable flavors and colors (0 to 0.30%), vegetable gums such as gum arabic and cellulose derivatives such as hydroxypropyl methyl cellulose (0 to 20%) in
addition to sucrose or starch hydrolysate in an aqueous solution.
Examples 122-127 are sugarless pellets which can be coated with sugar alcohol solutions such as those of sorbitol, xylitol and palatinit. These syrups may also contain the same modifiers listed above for sugar syrups.
In both cases (sugar and sugarless) dry coating agent (sugar or sugar alcohol) may be added between layers of coating syrup, a process known as dry charging- or soft panning.
Coating may be carried out by any suitable process, most often using a conventional pan, side vented pans, high capacity pans such as those made by Driam or Dumouline, or by continuous panning
techniques.
Figure imgf000040_0001
Figure imgf000041_0001
Inventive bubble gums may be prepared using the bubble gum bases of the present invention such as those listed in Examples 61-79. Illustrative formulations are given as Examples 128-139. Examples 128-133 are sugar bubble gum formulas. Note that Examples 129 and 133 use blends of two inventive bases. This is a technique to optimize processing and texture properties while minimizing the necessity of maintaining different bases for each product and without having additional custom bases compounded. Examples 134-139 are
sugarless bubble gum formulas.
Figure imgf000042_0001
Figure imgf000043_0001
While the embodiments of the invention disclosed herein are presently considered to be
preferred, various modifications and improvements can be made without departing from the spirit and scope of the invention. The scope of the invention is indicated in the appended claims, and all changes that come within the meaning and range of equivalency of the claims are intended to be embraced therein.

Claims

I CLAIM:
1. A substantially wax-free chewing gum base consisting primarily of:
about 20 to about 60 weight per cent synthetic elastomer;
0 to about 30 weight per cent natural
elastomer;
about 5 to about 55 weight per cent elastomer plasticizer;
about 4 to about 35 weight per cent filler; and
about 5 to about 35 weight per cent softener.
2. The chewing gum base of claim 1, wherein the. elastomers comprises a natural elastomer selected from the group consisting of jelutong, lechi caspi, perillo, sorva, massaranduba balata, massaranduba chocolate, nispero, rosin dinha, chicle, gutta hang kang, smoked or liquid latex, guayule, chiquibul, crown gum,
pendare, venezuelau chicle, leche de vaca, niger gutta, tunu, chilte, and combinations thereof.
3. The chewing gum base of claim 1 wherein the elastomer comprises a synthetic elastomer selected from the group consisting of polyisobutylene, butadiene-styrene copolymer, polyvinyl acetate, vinyl acetate-vinyl laurate copolymer, polyisoprene, isobutylene-isoprene copolymer, and combinations thereof.
4. The chewing gum base of claim 1 wherein the elastomer plasticizer is selected from the group consisting of glycerol est-5?.3 of rosin, glycerol esters of partially hydrogenated rosin, glycerol esters of polymerized rosin, glycerol esters of partially dimerized rosin, partially hydrogenated methyl esters of rosin, glycerol esters of tal oil rosin, pentaerythritol esters of rosin, methyl esters of rosin, pentaerythritol esters of partially hydrogenated rosin, synthetic terpene resin, natural terpene resin, and combinations thereof.
5. The chewing gum base of claim 1 wherein the filler is selected from the group consisting of calcium carbonate, magnesium carbonate, talc, ground limestone, magnesium silicate, aluminum silicate, clay, alumina, titanium dioxide, mono-, di- and tri-calcium
phosphates, cellulose, and combinations thereof.
6. The chewing gum base of claim 1 wherein the softener is selected from the group consisting of tallow, hydrogenated tallow, hydrogenated vegetable oils, partially hydrogenated vegetable oils, cocoa butter, glyercol monostearate, mono-, di- and
triglycerides, acetylated monoglycerides, glyceryl triacetate, lecithin, fatty acids, diacetin, lanolin, and combinations thereof.
7. The chewing gum base of claim 1, consisting primarily of:
about 25 to about 45 weight per cent synthetic elastomer;
about 10 to about 40 weight per cent elastomer plasticizer;
about 5 to about 30 weight per cent filler; and
about 15 to about 35 weight per cent softener.
8. The chewing gum base of claim 1, consisting primarily of: about 12 to about 30 weight per cent natural elastomer;
about 20 to about 40 weight per cent synthetic elastomer;
about 5 to about 25 weight per cent elastomer plasticizer;
about 4 to about 25 weight per cent filler; and
about 15 to about 30 weight per cent softener.
9. The chewing gum base of claim 1, consisting primarily of:
about 30 to about 60 weight per cent synthetic elastomer;
about 5 to about 55 weight per cent elastomer plasticizer;
about 10 to about 35 weight per cent filler; and
about 5 to about 25 weight per cent softener.
10. A bubble gum base comprising the chewing gum base of claim 9.
11. The bubble gum base of claim 10, prepared by: adding a first portion of synthetic elastomer and a first portion of filler to a mixer;
adding softener to the mixer along with a second portion of synthetic elastomer and a second portion of filler;
adding elastomer plasticizer to the mixer along with a third portion of synthetic elastomer and a third portion of filler;
blending the ingredients together; and removing heat at about 30 minutes to about 90 minutes into the mixing time of the base production process.
12. The chewing gum base of claim 1 in a substantially wax-free chewing gum.
13. A wax-free chewing gum having reduced tack properties, comprising:
a water soluble bulk portion;
one or more flavoring agents; and
a water insoluble chewing gum base consisting primarily of about 25 to about 45 per cent synthetic elastomer, about 10 to about 40 per cent elastomer plasticizer, about 5 to about 30 per cent filler, and about 15 to about 35 per cent softener, by weight of the gum base.
14. The wax-free chewing gum of claim 13, wherein the synthetic elastomer is selected from the group consisting of styrene-butadiene copolymer, isoprene-isobutylene copolymer, polyisobutylene, polyvinyl acetate and combinations thereof.
15. The wax-free chewing gum of claim 13, wherein the elastomer plasticizer is selected from the group consisting of glycerol ester of wood rosin, glycerol ester of partially hydrogenated wood rosin, terpene resins and combinations thereof.
16. The wax-free chewing gum of claim 13, wherein the filler is selected from the group consisting of calcium carbonate, talc, and combinations thereof.
17. The wax-free chewing gum of claim 13, wherein the softener is selected from the group consisting of hydrogenated vegetable oils, glycerol monostearate, lecithin, and combinations thereof.
18. A wax-free chewing gum, comprising:
a water soluble bulk portion;
one or more flavoring agents; and
a water insoluble chewing gum base consisting primarily of about 12 to about 30 per cent natural elastomer, about 20 to about 40 per cent synthetic elastomer, about 5 to about 25 per cent elastomer plasticizer, about 4 to about 25 per cent filler, and about 15 to about 30 per cent softener, by weight of the chewing gum base.
19. The wax-free chewing gum of claim 18, wherein the natural elastomer is selected from the group consisting of jelutong, sorva, chicle, massaranduba balata, and combinations thereof.
20. The wax-free chewing gum of claim 18, wherein the synthetic elastomer is selected from the group consisting of styrene-butadiene elastomer, isoprene-isobutylene copolymer, polyisobutylene, polyvinyl acetate, and combinations thereof.
21. The wax- free chewing gum of claim 18, wherein the elastomer plasticizer is selected from the group consisting of glycerol esters of partially hydrogenated rosin, methyl esters of rosin, glycerol esters of rosin, terpene resin, and combinations thereof.
22. The wax-free chewing gum of claim 18, wherein the filler is selected from the group consisting of calcium carbonate, talc, and combinations thereof.
23. The wax-free chewing gum of claim 18, wherein the softener is selected from the group consisting of hydrogenated vegetable oils, glycerol monostearate, lecithin, and combinations thereof.
24. A wax-free bubble gum, comprising:
a water soluble bulk portion;
one or more flavoring agents; and
a water insoluble chewing gum base consisting primarily of about 30 to about 60 weight per cent synthetic elastomer, about 5 to about 55 weight per cent elastomer plasticizer, about 10 to about 35 weight per cent filler, and about 5 to about 25 weight per cent softener.
25. The wax-free bubble gum of claim 24, wherein the synthetic elastomer is selected from the group consisting of polyisobutylene, polyvinyl acetate, and combinations thereof.
26. The wax-free bubble gum of claim 24, wherein the elastomer plasticizer is selected from the group consisting of glycerol esters of partially hydrogenated rosin, glycerol esters of rosin, and combinations thereof.
27. The wax-free bubble gum of claim 24, wherein the filler is selected from the group consisting of calcium carbonate, talc, and combinations thereof.
28. The wax-free bubble gum of claim 24, wherein the softener is selected from the group consisting of glycerol monostearate, acetylated monoglyceride, glycerol triacetate, and combinations thereof.
29. A chewing gum comprising gum base, flavor and sweetener; said gum base consisting primarily of:
about 20 to about 60 weight per cent synthetic elastomer;
0 to about 30 weight per cent natural
elastomer;
about 5 to about 55 weight per cent elastomer plasticizer;
about 4 to about 35 weight per cent filler; and
about 5 to about 35 weight per cent softener.
30. The chewing gum of claim 29 wherein the gum has reduced tack to dental surfaces.
31. The chewing gum of claim 29 wherein the gum is sugarless.
32. The chewing gum of claim 29 wherein the gum is in the form of a coated pellet or ball.
33. The chewing gum of claim 29 wherein the gum is a bubble gum.
PCT/US1992/011317 1992-03-03 1992-12-30 Improved wax-free chewing gum base and chewing gums prepared therefrom WO1993017572A1 (en)

Priority Applications (62)

Application Number Priority Date Filing Date Title
PCT/US1992/001686 WO1993017570A1 (en) 1992-03-03 1992-03-03 Improved wax-free chewing gum base
AU22925/92A AU2292592A (en) 1992-03-03 1992-03-03 Improved wax-free chewing gum base
AU34265/93A AU3426593A (en) 1992-03-03 1992-12-30 Improved wax-free chewing gum base and chewing gums prepared therefrom
DK93907161T DK0652712T3 (en) 1992-03-03 1993-03-02 Improved low moisture wax-free chewing gum
EP93907161A EP0652712B1 (en) 1992-03-03 1993-03-02 Improved wax-free low moisture chewing gum
DE69315329T DE69315329T2 (en) 1992-03-03 1993-03-02 IMPROVED WAX-FREE CHEWING GUM WITH CONTROLLED SWEETER RELEASE
ES93907195T ES2169039T3 (en) 1992-03-03 1993-03-02 AN IMPROVED PROCESS FOR MANUFACTURING WAX-FREE GUMS, WITH QUICK HARNESS TIMES.
DK93907177T DK0627885T3 (en) 1992-03-03 1993-03-02 Wax-free chewing gum with improved processing properties
PCT/US1993/001904 WO1993017575A1 (en) 1992-03-03 1993-03-02 Petroleum wax-free chewing gums having improved flavor release
CA002130571A CA2130571A1 (en) 1992-03-03 1993-03-02 Low calorie, high base chewing gum
EP93908275A EP0632696A4 (en) 1992-03-03 1993-03-02 Petroleum wax-free chewing gums having improved flavor release.
DE69310727T DE69310727T2 (en) 1992-03-03 1993-03-02 WAX-FREE CHEWING GUM WITH SOFT BIT IN THE BEGINNING
CA002130576A CA2130576A1 (en) 1992-03-03 1993-03-02 A wax-free chewing gum including special oligosaccharide binders
PCT/US1993/001941 WO1993017578A1 (en) 1992-03-03 1993-03-02 A wax-free chewing gum with initial soft bite
PCT/US1993/001943 WO1993017579A1 (en) 1992-03-03 1993-03-02 An improved process for manufacturing wax-free chewing gums with fast set-up times
AU37865/93A AU3786593A (en) 1992-03-03 1993-03-02 Improved wax-free low moisture chewing gum
EP93907193A EP0633729B1 (en) 1992-03-03 1993-03-02 A wax-free chewing gum with initial soft bite
PCT/US1993/001903 WO1993017574A1 (en) 1992-03-03 1993-03-02 Low calorie, high base chewing gum
PCT/US1993/002222 WO1993017580A1 (en) 1992-03-03 1993-03-02 A wax-free chewing gum including special oligosaccharide binders
CA002130569A CA2130569C (en) 1992-03-03 1993-03-02 Improved wax-free low moisture chewing gum
AU39153/93A AU3915393A (en) 1992-03-03 1993-03-02 Petroleum wax-free chewing gums having improved flavor release
CA002130572A CA2130572C (en) 1992-03-03 1993-03-02 Wax-free chewing gum with improved processing properties
EP93908274A EP0632695A4 (en) 1992-03-03 1993-03-02 Low calorie, high base chewing gum.
JP5515875A JPH08508156A (en) 1992-03-03 1993-03-02 Wax-free chewing gum with a soft initial chew
PCT/US1993/001922 WO1993017576A1 (en) 1992-03-03 1993-03-02 Wax-free chewing gum with improved processing properties
EP93908281A EP0633730B1 (en) 1992-03-03 1993-03-02 Improved wax-free chewing gums with controlled sweetener release
AU39152/93A AU3915293A (en) 1992-03-03 1993-03-02 Low calorie, high base chewing gum
CA002130573A CA2130573C (en) 1992-03-03 1993-03-02 A wax-free chewing gum with initial soft bite
DK93908281.4T DK0633730T3 (en) 1992-03-03 1993-03-02 Enhanced wax-free chewing gum with controlled sweetener release
PCT/US1993/001940 WO1993017577A1 (en) 1992-03-03 1993-03-02 Improved wax-free chewing gums with controlled sweetener release
AT93907193T ATE152883T1 (en) 1992-03-03 1993-03-02 WAX-FREE CHEWING GUM WITH AN INITIAL SOFT BITE
PCT/US1993/001900 WO1993017573A1 (en) 1992-03-03 1993-03-02 Improved wax-free low moisture chewing gum
EP93907195A EP0627886B1 (en) 1992-03-03 1993-03-02 An improved process for manufacturing wax-free chewing gums with fast set-up times
AU37886/93A AU673163B2 (en) 1992-03-03 1993-03-02 An improved process for manufacturing wax-free chewing gums with fast set-up times
CA002130568A CA2130568C (en) 1992-03-03 1993-03-02 Improved wax-free chewing gums with controlled sweetener release
AU37884/93A AU673666B2 (en) 1992-03-03 1993-03-02 A wax-free chewing gum with initial soft bite
DE69330428T DE69330428T2 (en) 1992-03-03 1993-03-02 IMPROVED WAX-FREE LOW-MOISTURE CHEWING GUM
DE69319126T DE69319126T2 (en) 1992-03-03 1993-03-02 WAX-FREE CHEWING GUM COMPOSITION WITH SPECIAL BINDERS
AU37877/93A AU3787793A (en) 1992-03-03 1993-03-02 Wax-free chewing gum with improved processing properties
DK93907193.2T DK0633729T3 (en) 1992-03-03 1993-03-02 Wax-free chewing gum with initial soft bite
CA002130574A CA2130574C (en) 1992-03-03 1993-03-02 An improved process for manufacturing wax-free chewing gums with fast set-up times
AU39158/93A AU673353B2 (en) 1992-03-03 1993-03-02 Improved wax-free chewing gums with controlled sweetener release
EP93907424A EP0661926B1 (en) 1992-03-03 1993-03-02 A wax-free chewing gum including special oligosaccharide binders
DE69331460T DE69331460T2 (en) 1992-03-03 1993-03-02 AN IMPROVED METHOD FOR PRODUCING WAX-FREE CHEWING GUM WITH SHORT CURING TIMES
EP93907177A EP0627885B1 (en) 1992-03-03 1993-03-02 Wax-free chewing gum with improved processing properties
DK93907195T DK0627886T3 (en) 1992-03-03 1993-03-02 Improved process for making wax-free chewing gum with fast cure times
DE69331413T DE69331413T2 (en) 1992-03-03 1993-03-02 WAX-FREE CHEWING GUM WITH IMPROVED PROCESSING PROPERTIES
DK93907424T DK0661926T3 (en) 1992-03-03 1993-03-02 Wax-free chewing gum comprising special oligosaccharide binders
CA002130575A CA2130575C (en) 1992-03-03 1993-03-02 Petroleum wax-free chewing gums having improved flavor release
AU38030/93A AU3803093A (en) 1992-03-03 1993-03-02 A wax-free chewing gum including special oligosaccharide binders
FI943830A FI943830A (en) 1992-03-03 1994-08-19 An improved process for the production of non-waxed chewing gums with a fast completion time
FI943824A FI943824A (en) 1992-03-03 1994-08-19 Wax-free chewing gum with special oligosaccharide binders
FI943831A FI943831A (en) 1992-03-03 1994-08-19 Petroleum-based wax-free chewing gum with improved flavor release
FI943828A FI943828A (en) 1992-03-03 1994-08-19 Wax-free chewing gum with improved machining properties
FI943825A FI943825A (en) 1992-03-03 1994-08-19 Improved wax-free chewing gums with controlled release of sweeteners
FI943826A FI943826A (en) 1992-03-03 1994-08-19 Improved wax-free chewing gum with low moisture
FI943829A FI943829A (en) 1992-03-03 1994-08-19 Wax-free, chewing gum at the beginning
US08/306,027 US5462754A (en) 1992-03-03 1994-09-14 Abhesive chewing gum with improved sweetness profile
AU68173/96A AU683805B2 (en) 1992-03-03 1996-10-11 Improved wax-free low moisture chewing gum
AU70286/96A AU7028696A (en) 1992-03-03 1996-10-18 Low calorie, high base chewing gum
AU70292/96A AU684435B2 (en) 1992-03-03 1996-10-18 Petroleum wax-free chewing gums having improved flavor release
AU70524/96A AU693044B2 (en) 1992-03-03 1996-10-31 Wax-free chewing gum with improved processing properties

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
USPCT/US92/01686 1992-03-03
PCT/US1992/001686 WO1993017570A1 (en) 1992-03-03 1992-03-03 Improved wax-free chewing gum base
USPCT/US92/09615 1992-11-06
US9209615 1992-11-06

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US4387108A (en) * 1981-06-12 1983-06-07 Warner-Lambert Company Non-stick chewing gum composition and method of preparation
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