WO1994011170A1 - Non-reusable, peel off covered ice tray - Google Patents

Non-reusable, peel off covered ice tray Download PDF

Info

Publication number
WO1994011170A1
WO1994011170A1 PCT/US1993/011145 US9311145W WO9411170A1 WO 1994011170 A1 WO1994011170 A1 WO 1994011170A1 US 9311145 W US9311145 W US 9311145W WO 9411170 A1 WO9411170 A1 WO 9411170A1
Authority
WO
WIPO (PCT)
Prior art keywords
cavity
cover
ice
ice tray
tray according
Prior art date
Application number
PCT/US1993/011145
Other languages
French (fr)
Inventor
Christer Cederroth Sture
Original Assignee
Arctic Icewater, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arctic Icewater, Inc. filed Critical Arctic Icewater, Inc.
Publication of WO1994011170A1 publication Critical patent/WO1994011170A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/28Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
    • B65D75/30Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
    • B65D75/32Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents
    • B65D75/325Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil
    • B65D75/327Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil and forming several compartments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D77/00Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
    • B65D77/10Container closures formed after filling
    • B65D77/20Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers
    • B65D77/2024Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers the cover being welded or adhered to the container
    • B65D77/2028Means for opening the cover other than, or in addition to, a pull tab
    • B65D77/2032Means for opening the cover other than, or in addition to, a pull tab by peeling or tearing the cover from the container
    • B65D77/2044Means for opening the cover other than, or in addition to, a pull tab by peeling or tearing the cover from the container whereby a layer of the container or cover fails, e.g. cohesive failure
    • B65D77/2048Means for opening the cover other than, or in addition to, a pull tab by peeling or tearing the cover from the container whereby a layer of the container or cover fails, e.g. cohesive failure whereby part of the container or cover has been weakened, e.g. perforated or precut
    • B65D77/2052Means for opening the cover other than, or in addition to, a pull tab by peeling or tearing the cover from the container whereby a layer of the container or cover fails, e.g. cohesive failure whereby part of the container or cover has been weakened, e.g. perforated or precut the container being weakened
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25CPRODUCING, WORKING OR HANDLING ICE
    • F25C1/00Producing ice
    • F25C1/22Construction of moulds; Filling devices for moulds
    • F25C1/24Construction of moulds; Filling devices for moulds for refrigerators, e.g. freezing trays
    • F25C1/243Moulds made of plastics e.g. silicone
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/80Packaging reuse or recycling, e.g. of multilayer packaging
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/11Methods of delaminating, per se; i.e., separating at bonding face
    • Y10T156/1153Temperature change for delamination [e.g., heating during delaminating, etc.]

Definitions

  • the present invention relates generally to an enclosed ice tray. More particularly, it relates to a non-reusable, enclosed ice cube tray in which individual ice receptacles or cavities for forming ice cubes are filled with a desired liquid when the ice cavities are enclosed. Once the cover of a cavity is peeled away, it can not be resecured to the body of the cavity so that a user has a positive indication that the contents of the cavity has been exposed to the outside.
  • the cover of each cavity is made so that it will support stacking of one ice tray on another during shipping and storage.
  • the ice cube tray is made so that when a cover area over one cavity is peeled off the cover acts to prohibit the inadvertent ejection of an ice cube in another cavity.
  • the cover areas are areas on a single cover sheet.
  • ice cube tray in which the receptacles for forming the ice cubes are enclosed.
  • ice cube trays that include a cover or lid to enclose the ice forming receptacles.
  • covers can be removed so that a formed cube can be ejected and the receptacle can be refilled with liquid and the cover reattached to form a new ice cube.
  • Some such trays include those shown in U.S. Patent Nos. 4,432,529 to McMillian, which issued on February 21, 1984; 3,414,229 to Norberg, which issued on December 3, 1968; 3,374,982 to Sallade, which issued on March 26, 1968; 3,019,617 to
  • trays include an upper portion for forming the individual ice cubes, a lower portion adapted to receive the formed ice cubes, and a divider to separate the upper portion from the lower portion of the tray.
  • U.S. Patent No. 3,135,101 to Nigro which issued on June 2, 1964.
  • Other enclosed structures or devices for forming individual ice cubes include a bag or other resilient structure separated into individual compartments. Some such devices are shown in U.S. Patent Nos. Re.31,890 to Vangedal-Nielsen, which issued on May 21, 1985;
  • U.S. Patent No. 2,955,044 which issued on October 4, 1960 to E.S. Tupper, is directed to an ice tray that has a peel off cover that can be reused or discarded after its first use.
  • the body of this tray is formed of plastic, such as polyethylene, and the cover is made of a flexible and deformable material, such as latex.
  • the tray of this patent provides a container formed of a high density polyethylene and a peelable sealing sheet that is formed by laminating or otherwise joining a polyamide substrate, namely nylon-6, and a thin film of a low density polyethylene.
  • the laminate is heat sealed on the container and the thermoplastic polymers include polyesters.
  • U.S. Patent No. 3,380,578, which issued on April 30, 1968 to G.C. Sparks, is directed to a strip package assembly that includes a body of relatively stiff, thermoplastic material and a cover or strip formed of an aluminum foil with a thermoplastic coating on one face thereof.
  • the thermoplastic body and the thermoplastic coat of the cover mate to form a heat seal therebetween.
  • French reference No. 2,040,845 to Wagner is directed to an ice cube tray that includes a thermoplastic body that forms a plurality of cavities and an aluminum film cover. The body and cover are fastened together by glue.
  • French reference No. 2,169,491 to Henry is also directed to an ice cube tray that has a cover and a body that forms a plurality of cavities.
  • the body is made of plastic, such as, polyethylene, and the cover is made of plastic alone or in combination with aluminum and paper. The body and cover are heat sealed together.
  • the present ice cube tray offers a unique cover that is light in weight, yet has sufficient weight to provide stacking of ice cube trays for shipment and storage. Still further, the present ice cube tray provides individual sealing of each cavity that keeps oxygen out of the cavity thereby avoiding or preventing bacteria, which is not found in the above prior art.
  • the present ice cube trays provide individually accessible cavities that indicate once the cavity has been disturbed.
  • the present invention in brief summary. comprises an ice tray having a body and a cover that includes means for securing together the body and the cover.
  • the body includes a plurality of individual cavities for receiving liquid therein. Each cavity has a lip formed about each upper edge of each cavity.
  • the cover is sized to mate with the body. The cover is sealed along each lip of each cavity to provide a liquid tight seal for each cavity.
  • the body and cover are each, preferably, formed of a single sheet of material.
  • the body is made of polyvinyl chloride
  • the cover is made of a laminate that contains adhesive between the polyester and the polyamide layers, and a plastic coat on the free side of the polyester layer.
  • the plastic at a desired temperature, affixes the cover to the lip or upper edge about each cavity of the body to form the liquid tight seal for each cavity.
  • FIG. 1 is a perspective view of the ice tray of the present invention
  • FIG. 2 is a perspective view of the ice tray of Fig. 1 with one section removed;
  • FIG. 3 is a perspective view of a section of the ice tray of Fig. 1 with the cover being removed;
  • FIG. 4 is a cross-sectional view taken along line 4-4 of Fig. 1;
  • FIG. 5 is a bottom view taken along line 5-5 of Fig. 1;
  • FIG. 6 is an exploded view of the cover depicted in Fig. 4; and FIG. 7 is a perspective view illustrating the stacking of three ice trays of the present invention shown in Fig. 1.
  • an ice cube tray generally represented by reference numeral 1, includes a base or body 10 and a cover or lid 30.
  • the body 10 when formed, has a plurality of receptacles or cavities 12 each adapted to receive a liquid, such as water, therein.
  • Each cavity 12 has an upper edge or lip 22, shown more clearly in Figs. 3 and 4, formed at the upper edge of each wall 18 and, thus, about the entire perimeter of the ice tray 1.
  • the cover 30, which is sized complementary to the body 10, is adapted to cover the body so that the ice tray 1 forms a completely closed structure.
  • the ice tray 1 in the preferred ice tray 1 shown in Fig 2, the ice tray 1 includes three sections 2, 4 and 6.
  • each section 2, 4 and 6 includes four cavities 12 (only three are shown) of the body 10 and the corresponding portion of the cover 30.
  • Each section 2, 4 and 6 is adapted to be separated from the other sections by a perforation line 8 that pierces the lip 22 of the body 10, and the cover 30.
  • the perforation line 8 is formed by a long knife or other cutting means that under pressure cuts into and through intermittent parts of the cover 30 and the lip 22 of the body 10.
  • the perforation line 8 is strong enough to maintain the sections in place until physical pulled apart by the user. It has been found that a few thousand kilos of pressure is needed to pull apart a single section, such as section 2 shown in Fig. 2, from the remainder of the ice tray 1.
  • the strength needed to make the perforation line 8 between each section is 10,500 Newtons. During production, a total of 84,000 Newtons is used to make the perforation lines for four trays at the same time.
  • each section 2, 4 and 6 preferably, has at least one perforated corner 9 that perforates both the cover 30 and the lip 22 of the body 10 in order to facilitate removal of the cover from the body. In the most preferred embodiment shown in the drawings, each section 2, 4 and 6 has two perforated corners 9 positioned on the same side of the cavity section.
  • the body 10 can be formed on conventional thermoforming equipment from a roll of flat stock.
  • the flat stock is passed through the thermoforming equipment to punch out or form the plurality of cavities 12.
  • each cavity 12 is formed with a lip 22.
  • the size of each lip 22 between the walls 18 of two contiguous cavities 12 is about 3.5 millimeters (mm). However, due to the taper of each side wall of each cavity 12, the distance between the bottoms 14 of each cavity is about 10 mm.
  • Each cavity 12 can be of any size however, in view of the size of normal refrigerator and normal drinking glasses, it is recommended that each cavity 12 be sized to form ice cubes having a mean size of approximately 27 by 27 by 27 mm and with each cube holding about two liters of liquid, such as water.
  • ice cube as used in this application means the formation of a block of ice into any size and any shape.
  • the ice cube and each cavity of the ice tray can have any shape, such as an oval, circular, square, or rectangular, or it may have a combination of such shapes, or it may also some surfaces of the ice cube flat while other surfaces have sharp angles or grooves.
  • each cavity 12 it is preferable that the thickness of the bottom 14 and the four walls 18 of each cavity 12 be as thin as possible to minimize the amount of material, and thus the cost and the weight of the ice tray 1, yet permit desired deformation to eject the formed ice cube from the cavity.
  • each cavity 12 must be thick enough to cause the ice cube therein to freeze properly, to withstand unintentional piercing, and to maintain its shape or integrity during freezing and thereafter.
  • each cavity 12 is strong enough to maintain its shape should several other ice trays be stacked thereon, such as, for example, two other ice trays of the present invention as shown in Fig. 7.
  • the bottom wall 14 of each cavity 12 of the ice tray 1 may include embossments 16 that may form weakened areas to assist in the flexing of the bottom wall and thus ejection of the ice cube.
  • the thickness of the bottom 14 should, preferably, be less than the thickness of each wall 18 in order to provide for easy ejection of the ice cube formed therein.
  • the thickness of the bottom 14 of the ice tray 1 should be between about 70 micrometers (um) and about 200 micrometers, while the thickness of each wall 18 should be between about 100 micrometers and about 300 micrometers. In a preferred embodiment, the thickness of the bottom is about 100 micrometers and each wall is about 200 micrometers.
  • the walls 18 of the cavity be tapered downward from the top to the bottom 14 of the cavity as shown in Figs. 4 and 5.
  • the taper assists in permitting the formed ice cube to slide out of the cavity 12.
  • the taper should be as minimal as possible in order to increase the volume of the formed ice cube, however it is believed that the taper needs to be at least one degree.
  • the body 10 of the ice tray 1 is made of pure polyvinyl chloride (PVC) plastic. This differs from the related priority applications named above in which the more preferred embodiment had a base film made of polyvinyl chloride (PVC) that was first coated polyvinylidene chloride (PVDC) and polyethylene (PE) was then laminated onto the PDVC coating of the PVC.
  • PVC polyvinyl chloride
  • the pure PVC has been found to be relatively inexpensive and is readily available, yet pure PVC is strong enough so that it will not be unintentionally pierced, thus protecting and insuring the purity of the liquid therein.
  • Pure PVC provides a moisture vapor barrier that basically prevents the water sealed in the cavity 12 from evaporating prior to and during freezing, and can withstand both the high temperature that emanates during the thermoforming process and the sub-freezing temperature needed to form the ice cubes. Further, this material is clear so that the user can readily determine whether the ice cube is fully formed, i.e. fully frozen and, of course, it meets federal government regulations concerning ingestion. Referring to Fig.
  • the present cover 30 is unlike the aluminum based, PVD-polyvinylidene chloride (PVDC) coated cover of the priority applications.
  • the present cover 30 is a laminate that is formed of polyamide and polyester with an adhesive therebetween.
  • a plastic peel coat or coat layer is provided on the polyester.
  • the cover 30 has a layer 32 of 60 parts polyamide and a layer 36 of 25 parts polyester with the plastic peel coat layer 38 on one side thereof.
  • a layer 34 of adhesive is positioned on the polyester layer 32, but on the side without the plastic coat layer 38.
  • the polyamide layer 32 is then applied onto the adhesive 34.
  • the polyamide layer 32 is the top of the cover 30, and provides for printing on the cover.
  • the adhesive 34 binds together, at an appropriate temperature, the polyamide and the polyester layers 32, 34 to form the laminated cover 30.
  • the adhesive 34 is applied onto the polyester layer 36 by a rolling cylinder, and then the polyamide layer 32 is applied onto the adhesive.
  • the plastic layer 38 is on one side of the polyester layer 36, which side is opposite the polyamide layer 32.
  • the polyester layer 36 with the plastic peel coat layer 38 are provided together from a supplier.
  • the polyester film with plastic coat is Mylar 25 OL polyester film sold by DuPont de Nemours Int. S.A. This polyester film with plastic coat has a yield value 29.2 m2/kg; unit weight 43.2 g/m2; thickness 25 micrometers; stiffness modulus 3790 MPa; tear strength 4.9 N; oxygen permeability 75 cc/m2/day/atm; and heat seal 4.4 N/15mm or 173g/in.
  • the plastic layer 38 affixes the body 10 and the cover 30 together in a liquid tight sealing engagement.
  • the plastic coat side of the cover 30 has a melting point of about 120 degrees Centigrade (C), whereas the melting point of the other or polyamide side of the cover is about 190 degrees C.
  • the plastic coat side of the cover 30 has a coefficient of friction between about 0.20 and about 0.25, whereas the polyamide side of the cover 30 has a coefficient of friction between about 0.15 and about 0.20.
  • the adhesive used to laminate together the polyester and polyamide layers is a solvent resin on a polyurethane base with an adhesive component and a hardener component.
  • the preferred adhesive is made by Herberts GmbH of West Germany and is sold under the name Herberts Kaschierharz 2-K-LF 500 A/424.
  • the adhesive is 100 parts adhesive component to 60 parts hardener component.
  • the thickness of the adhesive component at 20 degrees C is about 1.14, while the thickness of the hardener component at 20 degrees C is about 1.24.
  • the viscosity of the adhesive component is 450+/-1000mPas at 25 degrees C, and the viscosity of the hardener component is about 5000+/-1000mPas at 25 degrees C.
  • the binding strength of each component is 100 percent.
  • polyamide 6 is the least expensive polyamide that also has the characteristics needed included, but not limited to, strength, the ability to receive print thereon, the ability to adhere, and the ability to withstand freezing temperatures of the refrigerator, the preferred polyamide 6 is sold by SNIA and BASF companies.
  • the laminated cover 30 has a thickness between about 60 micrometers and about 100 micrometers. In a preferred embodiment, the thickness of the laminated cover 30 is about 85 micrometers. The cover 30 weighs about 104.6 g/m2.
  • Fig. 7 illustrates the stacking of three ice trays of the present invention.
  • the intended commercial package shall include three such stacked ice trays.
  • the laminated cover 30 has characteristics that it can support a number of stacked trays, as many as ten, for periods of time as long as one year.
  • the laminated cover 30 provides enough structural support to permit the stacking of the ice trays during shipment in ships, planes and rail cars, from state to state and country to country.
  • the ice trays can be stacked for storage for prolonged periods of time, yet the cover 30 is flexible enough so that an ice cube can be peeled-off.
  • the ice tray 1 is formed and filled as follows.
  • the rolled stock goes through the forming die of a thermoforming machine and forms the body 10 having the plurality of cavities 12.
  • the cavities are then filled with the desired liquid, such as "pure" spring water, and the cover 30 is secured to the body 10 simultaneously with the filling of the cavities by heating the covered body, to further assure that no contaminants enter the cavities.
  • the cover 30 is heated while the cover and body are being pressed together so that the plastic coat 38 will affix the cover to the body and, in particular, the lips 22 of each cavity 12.
  • the cover 30 and body 10 are pressed together as tightly as possible to keep oxygen from the inside of the enclosed ice tray 1. This feature minimizes or avoids bacteria in the ice tray 1.
  • the present invention provides that the edge of each cover area is entirely sealed to all lips 22 of each cavity 12. As shown in Fig. 3, when the cover area over one cavity 12 is peeled off, the remainder of the cover remains over parts of the other cavities thereby preventing the other formed ice cubes from releasing from the ice tray 1. Significantly, once the first ice cube is ejected, the cover 30 will not tack back onto the lip 22 of the ejected ice cube cavity. The reason for this is that a new heat seal would be needed to tack the cover 30 back onto the lips 22 of the cavity 12.
  • the laminated cover 30 is strong enough to withstand stacking of other ice trays, yet it is flexible and elastic enough so that when it is removed from the lip of a cavity, the laminated cover starts to roll onto itself to form a coil as partially shown in Fig. 3.
  • This feature is significant since it prevents ejection of the ice cubes from adjacent cavities. Specifically, when the cover 30 is removed from over a single cavity 12, it rolls back onto itself and a portion of the formed ice cube of the adjacent cavities are exposed, yet the formed ice cubes cannot eject from their cavities until virtually the entire cover area of that cavity is removed. Thus, the ice cubes can not be ejected from the adjacent cavities until the cover 30 is intentionally removed therefrom so that the coiling of the cover 30 of the present invention prevents unintentional ejection of the ice cubes from the ice tray.
  • the overall size and shape of the cover 30 is preferably established to mate with the overall size and shape of the body 10. It is preferred that the cover 30 be sized and shaped exactly complementary to the perimeter edges of the body 10 to minimize the amount of material and the overall size of the ice tray 1. It is preferable that as much liquid as possible be included in the each separate enclosed cavity, however some space must be left to provide for expansion of the water that occurs during the freezing process. It has been found that in the preferred cavity, i.e. the cavity having 27 by 27 by 27 mm dimensions, the expansion is approximately 6% so that approximately 6% of the cavity must not be filled with liquid.
  • the ice tray 1 insures that only a desired liquid, such as "pure" spring water, is used to form the resultant ice cubes by the features that the cavities are filled by the manufacturer and one can not gain access to the cavity without permanently removing the cover area over the cavity. If a customer or user notes that a cover area is not sealed to the cavity, the customer has a positive or visual indication that the contents of the cavity has been exposed and, thus, may be contaminated.
  • a desired liquid such as "pure" spring water

Abstract

There is provided an ice tray (1) that includes a body (10) and a laminated cover (30) that has a plastic coat for securing together the body (10) and the cover (30). The body (10) includes a plurality of individual cavities (12) for receiving liquid therein. Each wall (18) of each cavity (12) has an upper edge that forms a lip (22). The lower (30) is sealed along each lip (22) of each cavity (12) to provide a liquid tight seal for each cavity. The body (10) and cover (30) are each, preferably, formed of a single sheet of material. The body is made of pure polyvinyl chloride plastic, and the cover is made of a laminate of polyester (36) and polyamide (32) with adhesive (34) therebetween and the plastic coat (38) on the side of the polyester opposite the adhesive.

Description

TITLE: NON-REUSABLE. PEEL OFF COVERED ICE TRAY
RELATED APPLICATIONS
This application is a continuation-in-part of application Serial No. 07/930,185, filed August 17, 1992, still pending, which in turn is a continuation of application Serial No. 07/778,286, filed October 17, 1991, now abandoned, which in turn is a continuation of application Serial No. 07/458,572, filed December 29, 1989, now abandoned, which in turn is a continuation of application Serial No. 07/188,278, filed April 29, 1988, now U.S. Patent No. 4,899,976, which issued on February 13, 1990.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to an enclosed ice tray. More particularly, it relates to a non-reusable, enclosed ice cube tray in which individual ice receptacles or cavities for forming ice cubes are filled with a desired liquid when the ice cavities are enclosed. Once the cover of a cavity is peeled away, it can not be resecured to the body of the cavity so that a user has a positive indication that the contents of the cavity has been exposed to the outside.
Significantly, the cover of each cavity is made so that it will support stacking of one ice tray on another during shipping and storage. In addition, the ice cube tray is made so that when a cover area over one cavity is peeled off the cover acts to prohibit the inadvertent ejection of an ice cube in another cavity. In the preferred embodiment, the cover areas are areas on a single cover sheet.
In the present environment, one is concerned about the contaminants found in water supplies. Many people desire to drink fluid from a filtered or controlled source, such as "pure" spring water. It is believed that many liquids, such as liquor, is enhanced by mixing that liquid only with "pure" spring water instead of tap water. Thus, the ice cubes used in such drinks should be made of "pure" spring water.
To assure a customer that the ice cubes will only be made of "pure" spring water, it is necessary that there be a way of assuring, from the time the liquid that forms the ice cubes leaves a production facility to the time it reaches the customer, that the less costly or undesired tap water will not be included.
Thus, there is a need to provide an ice cube tray that permits the manufacturer or producer to seal the tray with the desired liquid, such as "pure" spring water, at the time the manufacturer fills the tray so that the ice cubes formed therein cannot be contaminated, and to construct the tray so that once an ice cube is removed or the contents of a cavity tampered with the customer is immediately notified.
2. Description of The Prior Art
It is known in the art to provide an ice cube tray in which the receptacles for forming the ice cubes are enclosed. Specifically, there are known ice cube trays that include a cover or lid to enclose the ice forming receptacles. However, such covers can be removed so that a formed cube can be ejected and the receptacle can be refilled with liquid and the cover reattached to form a new ice cube. Some such trays include those shown in U.S. Patent Nos. 4,432,529 to McMillian, which issued on February 21, 1984; 3,414,229 to Norberg, which issued on December 3, 1968; 3,374,982 to Sallade, which issued on March 26, 1968; 3,019,617 to
Malthaner, et al., which issued on February 6, 1962;
2,804,755 to Ansel, which issued on September 3, 1957; 2,769,316 to Candor, which issued on November 6, 1956;
2,629,987 to Chase, which issued on March 4, 1953;
2,613,512 to Gaugler, which issued on October 14, 1952;
2,503,306 to Storer, which issued on April 11, 1950;
2,069,195 to Chilton, which issued on February 2, 1937; 2,011,849 to Chilton, which issued on August 20, 1935;
2,011289 to Klyce, Jr., which issued on August 13, 1935;
Re.19,322 to Tanger; which issued on September 18, 1934;
1,896,849 to Newman, which issued on February 7, 1933; and the commercial ice tray product sold by Cooly International, Inc., and the commercial ice tray product called Kwik Kubes sold by Hyman Products Inc. of St.
Louis, Missouri.
Other trays include an upper portion for forming the individual ice cubes, a lower portion adapted to receive the formed ice cubes, and a divider to separate the upper portion from the lower portion of the tray. One such tray is shown in U.S. Patent No. 3,135,101 to Nigro, which issued on June 2, 1964. Other enclosed structures or devices for forming individual ice cubes include a bag or other resilient structure separated into individual compartments. Some such devices are shown in U.S. Patent Nos. Re.31,890 to Vangedal-Nielsen, which issued on May 21, 1985;
3,306,567 to Frei, St., which issued on February 28, 1967; 2,966,041 to Zearfoss, Jr., et al. which issued on December 17, 1960; and 2,964,920 to Steabler, which issued on December 20, 1960. The Vangedal-Nielsen patent permits the ice cube to form a circular shape instead of the conventional square shape cube. Other such ice trays having covers or lids permit the cubes to form a shape other than a square or rectangular shape include U.S. Patent Nos. 4,417,716 to Penna, et al., which issued on November 29, 1983 and 2,049,902 to Fischer, which issued on August 4, 1936, and a commercial product sold by Hello Productions, Inc. of Elk Grove Village Illinois under the mark Ice Shapers.
One prior art patent, U.S. Patent No. 2,955,044, which issued on October 4, 1960 to E.S. Tupper, is directed to an ice tray that has a peel off cover that can be reused or discarded after its first use. The body of this tray is formed of plastic, such as polyethylene, and the cover is made of a flexible and deformable material, such as latex.
Other patents disclose enclosed structures and materials commonly used to form same.
U.S. Patent No. 3,783,089, which issued on
January 1, 1974 to A.R. Hurst, et al., is directed to a heat sealed, readily peelable or tearable structure suitable for closures, labels, packaging and the like. The tray of this patent provides a container formed of a high density polyethylene and a peelable sealing sheet that is formed by laminating or otherwise joining a polyamide substrate, namely nylon-6, and a thin film of a low density polyethylene. The laminate is heat sealed on the container and the thermoplastic polymers include polyesters.
U.S. Patent No. 3,380,578, which issued on April 30, 1968 to G.C. Sparks, is directed to a strip package assembly that includes a body of relatively stiff, thermoplastic material and a cover or strip formed of an aluminum foil with a thermoplastic coating on one face thereof. The thermoplastic body and the thermoplastic coat of the cover mate to form a heat seal therebetween. French reference No. 2,040,845 to Wagner is directed to an ice cube tray that includes a thermoplastic body that forms a plurality of cavities and an aluminum film cover. The body and cover are fastened together by glue.
French reference No. 2,169,491 to Henry is also directed to an ice cube tray that has a cover and a body that forms a plurality of cavities. The body is made of plastic, such as, polyethylene, and the cover is made of plastic alone or in combination with aluminum and paper. The body and cover are heat sealed together.
All of the above fail to provide the laminated cover of the present ice tray. None of the above patents provide the combination of materials found in the present ice cube tray. Also, none of the above provides for a single sheet of cover having an individual portion or area over each cavity that can be peeled off in order to provide for removal of the ice cube from one cavity while the cover prevents the other ice cubes from ejecting from their cavity.
Further, the present ice cube tray offers a unique cover that is light in weight, yet has sufficient weight to provide stacking of ice cube trays for shipment and storage. Still further, the present ice cube tray provides individual sealing of each cavity that keeps oxygen out of the cavity thereby avoiding or preventing bacteria, which is not found in the above prior art.
In addition, the present ice cube trays provide individually accessible cavities that indicate once the cavity has been disturbed.
SUMMARY OF THE INVENTION
Against the foregoing background, it is a primary object of the present invention to provide an enclosed, non-reusable ice cube tray in which individual ice cubes formed in each cavity can be removed while prohibiting ejection of the ice cubes from the other cavities.
It is another object of the present invention to provide such an ice tray in which the cover is made of light weight material that has sufficient strength to maintain its sealing engagement with the cavity when supporting other trays during storage and shipping. It is still another object of the present invention to provide such an ice tray in which the cover is laminated into a single sheet of material.
It is yet another object of the present invention to provide such an ice tray in which the cover is a laminate of polyamide and polyester.
It is yet still another object of the present invention to provide such an ice tray that provides an affirmative indication should the seal between the cavity and the cover be broken.
It is a further object of the present invention to provide such an ice tray that forms as tight as possible seal between the cover and each cavity to minimize or prevent oxygen from entering the sealed cavity and thereby avoid bacteria therein.
It is a still further object of the present invention to provide such an ice tray that is relatively inexpensive.
To the accomplishment of the foregoing objects and advantages, the present invention, in brief summary. comprises an ice tray having a body and a cover that includes means for securing together the body and the cover. The body includes a plurality of individual cavities for receiving liquid therein. Each cavity has a lip formed about each upper edge of each cavity. The cover is sized to mate with the body. The cover is sealed along each lip of each cavity to provide a liquid tight seal for each cavity.
The body and cover are each, preferably, formed of a single sheet of material. The body is made of polyvinyl chloride, and the cover is made of a laminate that contains adhesive between the polyester and the polyamide layers, and a plastic coat on the free side of the polyester layer. The plastic, at a desired temperature, affixes the cover to the lip or upper edge about each cavity of the body to form the liquid tight seal for each cavity.
BRIEF DESCRIPTION OF THE DRAWINGS
The foregoing and still the objects and advantages of the present invention will be more apparent from the following detailed explanation of the preferred embodiments of the invention in connection with the accompanying drawings wherein:
FIG. 1 is a perspective view of the ice tray of the present invention;
FIG. 2 is a perspective view of the ice tray of Fig. 1 with one section removed;
FIG. 3 is a perspective view of a section of the ice tray of Fig. 1 with the cover being removed;
FIG. 4 is a cross-sectional view taken along line 4-4 of Fig. 1;
FIG. 5 is a bottom view taken along line 5-5 of Fig. 1;
FIG. 6 is an exploded view of the cover depicted in Fig. 4; and FIG. 7 is a perspective view illustrating the stacking of three ice trays of the present invention shown in Fig. 1.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring to the drawings and, in particular, to Fig. 1, an ice cube tray, generally represented by reference numeral 1, includes a base or body 10 and a cover or lid 30. The body 10, when formed, has a plurality of receptacles or cavities 12 each adapted to receive a liquid, such as water, therein. Each cavity 12 has an upper edge or lip 22, shown more clearly in Figs. 3 and 4, formed at the upper edge of each wall 18 and, thus, about the entire perimeter of the ice tray 1.
As shown in Figs. 1 through 3, the cover 30, which is sized complementary to the body 10, is adapted to cover the body so that the ice tray 1 forms a completely closed structure.
in the preferred ice tray 1 shown in Fig 2, the ice tray 1 includes three sections 2, 4 and 6. In this preferred embodiment, each section 2, 4 and 6 includes four cavities 12 (only three are shown) of the body 10 and the corresponding portion of the cover 30. Each section 2, 4 and 6 is adapted to be separated from the other sections by a perforation line 8 that pierces the lip 22 of the body 10, and the cover 30.
The perforation line 8 is formed by a long knife or other cutting means that under pressure cuts into and through intermittent parts of the cover 30 and the lip 22 of the body 10. The perforation line 8 is strong enough to maintain the sections in place until physical pulled apart by the user. It has been found that a few thousand kilos of pressure is needed to pull apart a single section, such as section 2 shown in Fig. 2, from the remainder of the ice tray 1. The strength needed to make the perforation line 8 between each section is 10,500 Newtons. During production, a total of 84,000 Newtons is used to make the perforation lines for four trays at the same time.
it should be understood that perforation lines 8 could be placed about each cavity 12 so that each individual cavity could be separated from the remainder of the ice tray 1. It should be further understood that each section could be any number of cavities, although an even number is preferred. However, perforation lines 8 would be needed to provide for such desired separation. Each section 2, 4 and 6, preferably, has at least one perforated corner 9 that perforates both the cover 30 and the lip 22 of the body 10 in order to facilitate removal of the cover from the body. In the most preferred embodiment shown in the drawings, each section 2, 4 and 6 has two perforated corners 9 positioned on the same side of the cavity section.
The body 10 can be formed on conventional thermoforming equipment from a roll of flat stock. The flat stock is passed through the thermoforming equipment to punch out or form the plurality of cavities 12. However, each cavity 12 is formed with a lip 22. The lip 22 of two contiguous cavities 12, preferably, are one and the same lip as clearly shown in Fig. 4. The size of each lip 22 between the walls 18 of two contiguous cavities 12 is about 3.5 millimeters (mm). However, due to the taper of each side wall of each cavity 12, the distance between the bottoms 14 of each cavity is about 10 mm.
Each cavity 12 can be of any size however, in view of the size of normal refrigerator and normal drinking glasses, it is recommended that each cavity 12 be sized to form ice cubes having a mean size of approximately 27 by 27 by 27 mm and with each cube holding about two liters of liquid, such as water.
The term ice cube as used in this application means the formation of a block of ice into any size and any shape. The ice cube and each cavity of the ice tray can have any shape, such as an oval, circular, square, or rectangular, or it may have a combination of such shapes, or it may also some surfaces of the ice cube flat while other surfaces have sharp angles or grooves.
Referring to Figs. 3 through 5, it is preferable that the thickness of the bottom 14 and the four walls 18 of each cavity 12 be as thin as possible to minimize the amount of material, and thus the cost and the weight of the ice tray 1, yet permit desired deformation to eject the formed ice cube from the cavity. However, each cavity 12 must be thick enough to cause the ice cube therein to freeze properly, to withstand unintentional piercing, and to maintain its shape or integrity during freezing and thereafter. In addition, each cavity 12 is strong enough to maintain its shape should several other ice trays be stacked thereon, such as, for example, two other ice trays of the present invention as shown in Fig. 7. As shown in one preferred embodiment illustrated in Fig. 4, the bottom wall 14 of each cavity 12 of the ice tray 1 may include embossments 16 that may form weakened areas to assist in the flexing of the bottom wall and thus ejection of the ice cube.
The thickness of the bottom 14 should, preferably, be less than the thickness of each wall 18 in order to provide for easy ejection of the ice cube formed therein. The thickness of the bottom 14 of the ice tray 1 should be between about 70 micrometers (um) and about 200 micrometers, while the thickness of each wall 18 should be between about 100 micrometers and about 300 micrometers. In a preferred embodiment, the thickness of the bottom is about 100 micrometers and each wall is about 200 micrometers.
To facilitate the release of the formed ice cube from a cavity 12 of the ice tray 1, it is preferred that the walls 18 of the cavity be tapered downward from the top to the bottom 14 of the cavity as shown in Figs. 4 and 5. The taper assists in permitting the formed ice cube to slide out of the cavity 12. The taper should be as minimal as possible in order to increase the volume of the formed ice cube, however it is believed that the taper needs to be at least one degree.
The body 10 of the ice tray 1 is made of pure polyvinyl chloride (PVC) plastic. This differs from the related priority applications named above in which the more preferred embodiment had a base film made of polyvinyl chloride (PVC) that was first coated polyvinylidene chloride (PVDC) and polyethylene (PE) was then laminated onto the PDVC coating of the PVC.
The pure PVC has been found to be relatively inexpensive and is readily available, yet pure PVC is strong enough so that it will not be unintentionally pierced, thus protecting and insuring the purity of the liquid therein. Pure PVC provides a moisture vapor barrier that basically prevents the water sealed in the cavity 12 from evaporating prior to and during freezing, and can withstand both the high temperature that emanates during the thermoforming process and the sub-freezing temperature needed to form the ice cubes. Further, this material is clear so that the user can readily determine whether the ice cube is fully formed, i.e. fully frozen and, of course, it meets federal government regulations concerning ingestion. Referring to Fig. 6, the present cover 30 is unlike the aluminum based, PVD-polyvinylidene chloride (PVDC) coated cover of the priority applications. The present cover 30 is a laminate that is formed of polyamide and polyester with an adhesive therebetween. In addition, a plastic peel coat or coat layer is provided on the polyester. In particular, the cover 30 has a layer 32 of 60 parts polyamide and a layer 36 of 25 parts polyester with the plastic peel coat layer 38 on one side thereof. A layer 34 of adhesive is positioned on the polyester layer 32, but on the side without the plastic coat layer 38. Lastly, the polyamide layer 32 is then applied onto the adhesive 34. The polyamide layer 32 is the top of the cover 30, and provides for printing on the cover.
The adhesive 34 binds together, at an appropriate temperature, the polyamide and the polyester layers 32, 34 to form the laminated cover 30. The adhesive 34 is applied onto the polyester layer 36 by a rolling cylinder, and then the polyamide layer 32 is applied onto the adhesive.
The plastic layer 38 is on one side of the polyester layer 36, which side is opposite the polyamide layer 32. In a preferred embodiment, the polyester layer 36 with the plastic peel coat layer 38 are provided together from a supplier. In a most preferred embodiment, the polyester film with plastic coat is Mylar 25 OL polyester film sold by DuPont de Nemours Int. S.A. This polyester film with plastic coat has a yield value 29.2 m2/kg; unit weight 43.2 g/m2; thickness 25 micrometers; stiffness modulus 3790 MPa; tear strength 4.9 N; oxygen permeability 75 cc/m2/day/atm; and heat seal 4.4 N/15mm or 173g/in.
At a desired temperature, the plastic layer 38 affixes the body 10 and the cover 30 together in a liquid tight sealing engagement. The plastic coat side of the cover 30 has a melting point of about 120 degrees Centigrade (C), whereas the melting point of the other or polyamide side of the cover is about 190 degrees C. The plastic coat side of the cover 30 has a coefficient of friction between about 0.20 and about 0.25, whereas the polyamide side of the cover 30 has a coefficient of friction between about 0.15 and about 0.20.
The adhesive used to laminate together the polyester and polyamide layers is a solvent resin on a polyurethane base with an adhesive component and a hardener component. The preferred adhesive is made by Herberts GmbH of West Germany and is sold under the name Herberts Kaschierharz 2-K-LF 500 A/424. The adhesive is 100 parts adhesive component to 60 parts hardener component. The thickness of the adhesive component at 20 degrees C is about 1.14, while the thickness of the hardener component at 20 degrees C is about 1.24. The viscosity of the adhesive component is 450+/-1000mPas at 25 degrees C, and the viscosity of the hardener component is about 5000+/-1000mPas at 25 degrees C. The binding strength of each component is 100 percent.
It is believed that any polyamide can be used as the material for the body. However, polyamide 6 and polyamide 6.6 are preferred with the polyamide 6 the most preferred. The reason for the preference is that polyamide 6 is the least expensive polyamide that also has the characteristics needed included, but not limited to, strength, the ability to receive print thereon, the ability to adhere, and the ability to withstand freezing temperatures of the refrigerator, the preferred polyamide 6 is sold by SNIA and BASF companies.
The laminated cover 30 has a thickness between about 60 micrometers and about 100 micrometers. In a preferred embodiment, the thickness of the laminated cover 30 is about 85 micrometers. The cover 30 weighs about 104.6 g/m2.
Fig. 7 illustrates the stacking of three ice trays of the present invention. The intended commercial package shall include three such stacked ice trays.
The laminated cover 30 has characteristics that it can support a number of stacked trays, as many as ten, for periods of time as long as one year. The laminated cover 30 provides enough structural support to permit the stacking of the ice trays during shipment in ships, planes and rail cars, from state to state and country to country. In addition, the ice trays can be stacked for storage for prolonged periods of time, yet the cover 30 is flexible enough so that an ice cube can be peeled-off.
The ice tray 1 is formed and filled as follows. The rolled stock goes through the forming die of a thermoforming machine and forms the body 10 having the plurality of cavities 12. The cavities are then filled with the desired liquid, such as "pure" spring water, and the cover 30 is secured to the body 10 simultaneously with the filling of the cavities by heating the covered body, to further assure that no contaminants enter the cavities.
To secure the cover 30 to the body 10 and the cover 30, the cover is heated while the cover and body are being pressed together so that the plastic coat 38 will affix the cover to the body and, in particular, the lips 22 of each cavity 12. The cover 30 and body 10 are pressed together as tightly as possible to keep oxygen from the inside of the enclosed ice tray 1. This feature minimizes or avoids bacteria in the ice tray 1.
Along these same lines, the present invention provides that the edge of each cover area is entirely sealed to all lips 22 of each cavity 12. As shown in Fig. 3, when the cover area over one cavity 12 is peeled off, the remainder of the cover remains over parts of the other cavities thereby preventing the other formed ice cubes from releasing from the ice tray 1. Significantly, once the first ice cube is ejected, the cover 30 will not tack back onto the lip 22 of the ejected ice cube cavity. The reason for this is that a new heat seal would be needed to tack the cover 30 back onto the lips 22 of the cavity 12. The laminated cover 30 is strong enough to withstand stacking of other ice trays, yet it is flexible and elastic enough so that when it is removed from the lip of a cavity, the laminated cover starts to roll onto itself to form a coil as partially shown in Fig. 3. This feature is significant since it prevents ejection of the ice cubes from adjacent cavities. Specifically, when the cover 30 is removed from over a single cavity 12, it rolls back onto itself and a portion of the formed ice cube of the adjacent cavities are exposed, yet the formed ice cubes cannot eject from their cavities until virtually the entire cover area of that cavity is removed. Thus, the ice cubes can not be ejected from the adjacent cavities until the cover 30 is intentionally removed therefrom so that the coiling of the cover 30 of the present invention prevents unintentional ejection of the ice cubes from the ice tray.
The overall size and shape of the cover 30 is preferably established to mate with the overall size and shape of the body 10. It is preferred that the cover 30 be sized and shaped exactly complementary to the perimeter edges of the body 10 to minimize the amount of material and the overall size of the ice tray 1. It is preferable that as much liquid as possible be included in the each separate enclosed cavity, however some space must be left to provide for expansion of the water that occurs during the freezing process. It has been found that in the preferred cavity, i.e. the cavity having 27 by 27 by 27 mm dimensions, the expansion is approximately 6% so that approximately 6% of the cavity must not be filled with liquid.
Thus, the ice tray 1 insures that only a desired liquid, such as "pure" spring water, is used to form the resultant ice cubes by the features that the cavities are filled by the manufacturer and one can not gain access to the cavity without permanently removing the cover area over the cavity. If a customer or user notes that a cover area is not sealed to the cavity, the customer has a positive or visual indication that the contents of the cavity has been exposed and, thus, may be contaminated.
Having thus described the invention with particular reference to the preferred forms thereof, it will be obvious that various changes and modifications may be made therein while retaining the advantages and benefits of the present invention and without departing from the spirit of the invention as defined by the appended claims.

Claims

WHEREFORE, I CLAIM:
1. An ice cube tray for containing a liquid that forms into a plurality of ice cubes, said ice tray comprising:
a body having a plurality of cavities each for receiving a portion of the liquid, each of said plurality of cavities having a bottom and a plurality of side walls with each side wall having an upper lip;
a laminated cover adapted to be permanently secured to said body, wherein said laminated cover includes polyamide and polyester and means for securing said laminated cover to said lip of each wall of each cavity; and
wherein the liquid is entirely enclosed in each cavity, and wherein once a formed ice cube is removed from a cavity the portion of said laminated cover that had covered that cavity can not be reattached to that cavity.
2. The ice tray according to claim 1, wherein said laminated cover is made of one piece of material that has a plurality of cover areas each for a different one of said plurality of cavities.
3. The ice tray according to claim 1, wherein said laminated cover is formed of 60 parts polyamide and 25 parts polyester with adhesive therebetween.
4. The ice tray according to claim 3, wherein said laminated cover further includes a plastic coat formed on the polyester layer, and wherein said plastic coat when heated sufficiently affixes said cover to said body of said ice tray.
5. The ice tray according to claim 1, wherein said laminated cover has a thickness between about 15 micrometers and about 100 micrometers.
6. The ice tray according to claim 5, wherein said laminated cover has a thickness about 85 micrometers.
7. The ice tray according to claim 6, wherein said laminated cover weighs about 104.6 g/m2.
8. The ice tray according to claim 4, wherein said laminated cover is adapted to support one or more additional ice trays stacked thereon.
9. The ice tray according to claim 1, wherein said body is made of pure polyvinyl chloride (PVC) plastic.
10. The ice tray according to claim 9, wherein each side wall of each cavity has a thickness between about 100 micrometers and about 300 micrometers, and wherein the thickness of the bottom of each cavity has a thickness between about 50 micrometers and 200 micrometers.
11. The ice tray according to claim 10, wherein each side wall of each cavity has a thickness about 200 micrometers, and wherein the thickness of the bottom of each cavity is about 100 micrometers.
12. The ice tray according to claim 1, wherein the bottom of each cavity has a plurality of embossments to facilitate the flexing of the bottom and thereby ejection of a formed ice cube.
13. The ice tray according to claim 4, wherein said plastic coat disburses at 120 degrees C. 14. The ice tray according to claim 1, wherein said ice tray includes three sections with each section being adapted to be separated from the other two sections by a perforation line.
15. The ice tray according to claim 14, wherein each section includes four enclosed cavities.
16. An ice cube tray for containing a liquid that forms into a plurality of ice cubes, said tray comprising:
a body having a plurality of cavities each for receiving a portion of the liquid, each of said plurality of cavities having a bottom and a plurality of side walls with each side wall having an upper lip, said body being formed of pure polyvinyl chloride plastic;
a cover being adapted to be permanently secured to said body and having a plurality of cover areas, said cover being formed of a laminate of a polyester layer, an adhesive on said polyester layer, a polyamide layer on said adhesive, and a plastic coat on a side of said polyester layer opposite said adhesive, wherein said plastic coat affixes said cover to each lip of each cavity when heated to a sufficient melting point; and wherein each cavity forms a liquid tight seal that prevents oxygen from entering into an enclosed cavity, and wherein once a formed ice cube is removed from a cavity said cover portion of that cavity can not be reattached to that cavity.
17. The ice tray according to claim 16, wherein the sufficient melting point is 120 degrees C.
18. The ice tray according to claim 17, wherein said liquid tight seal prevents bacteria from entering into said enclosed cavity.
19. The ice tray according to claim 16, wherein said cover has sufficient strength to support at least tow other stacked ice trays.
20. The ice tray according to claim 16, wherein a cover area is removed from over a first cavity said cover rolls onto itself and prevents ejection of ice cubes from adjacent cavities. AMENDED CLAIMS
[received by the International Bureau on 1 April 1994 (01.04.94); original claims 1,3,7,16,18-20 amended; other claims unchanged (5 pages)]
1. An ice cube tray for containing a liquid that forms into a plurality of ice cubes, said ice tray comprising:
5 a body having a plurality of cavities each for receiving a portion of the liquid, each of said plurality of cavities having a bottom and a plurality of side walls with each side wall having an upper lip;
a laminated cover adapted to be permanently 10 secured to said body, wherein said laminated cover includes a polyamide layer, a polyester layer and means for securing said laminated cover to said lip of each wall of each cavity;
a first portion of said laminated cover that is 15 detached from said body rolls onto a second portion of said laminated cover that is still attached to said body; and
wherein the liquid is entirely enclosed in each cavity, and wherein once a formed ice cube is removed 20 from a cavity the portion of said laminated cover that had covered that cavity can not be reattached to that cavity.
2. The ice tray according to claim 1, wherein said laminated cover is made of one piece of material that has a plurality of cover areas each for a different one of said plurality of cavities.
3. The ice tray according to claim 1, wherein said laminated cover is formed of a polyamide part being 60 parts by weight of said laminated cover and a polyester part being 25 parts by weight of said laminated cover with adhesive therebetween.
4. The ice tray according to claim 3, wherein said laminated cover further includes a plastic coat formed on the polyester layer, and wherein said plastic coat when heated sufficiently affixes said cover to said body of said ice tray.
5. The ice tray according to claim 1, wherein said laminated cover has a thickness between about 15 micrometers and about 100 micrometers.
6. The ice tray according to claim 5, wherein said laminated cover has a thickness about 85 micrometers. 7. The ice tray according to claim 6, wherein said laminated cover has a weight per unit area of about 104.6 g/m2.
8. The ice tray according to claim 4, wherein said laminated cover is adapted to support one or more additional ice trays stacked thereon.
9. The ice tray according to claim 1, wherein said body is made of pure polyvinyl chloride (PVC) plastic.
10. The ice tray according to claim 9, wherein each side wall of each cavity has a thickness between about 100 micrometers and about 300 micrometers, and wherein the thickness of the bottom of each cavity has a thickness between about 50 micrometers and 200 micrometers.
11. The ice tray according to claim 10, wherein each side wall of each cavity has a thickness about 200 micrometers, and wherein the thickness of the bottom of each cavity is about 100 micrometers.
12. The ice tray according to claim 1, wherein the bottom of each cavity has a plurality of embossments to facilitate the flexing of the bottom and thereby ejection of a formed ice cube.
13. The ice tray according to claim 4, wherein said plastic coat disburses at 120 degrees C.
14. The ice tray according to claim 1, wherein said ice tray includes three sections with each section being adapted to be separated from the other two sections by a perforation line.
15. The ice tray according to claim 14, wherein each section includes four enclosed cavities.
16. An ice cube tray for containing a liquid that forms into a plurality of ice cubes, said tray comprising:
a body having a plurality of cavities each for receiving a portion of the liquid, each of said plurality of cavities having a bottom and a plurality of side walls with each side wall having an upper lip, said body being formed of pure polyvinyl chloride plastic;
a cover being adapted to be secured to said body and having a plurality of cover areas, said cover being formed of a laminate of a polyester layer, an adhesive on said polyester layer, a polyamide layer on said adhesive, and a plastic coat on a side of said polyester layer opposite said adhesive, wherein said plastic coat affixes said cover to each lip of each cavity when heated to a sufficient melting point; and
wherein each cavity forms a liquid tight seal that prevents oxygen from entering into an enclosed cavity, and wherein once a formed ice cube is removed from a cavity said cover portion of that cavity can not be reattached to that cavity.
17. The ice tray according to claim 16, wherein the sufficient melting point is 120 degrees C.
18. The ice tray according to claim 16, wherein said liquid tight seal prevents bacteria from entering into said enclosed cavity.
19. The ice tray according to claim 16, wherein said cover has sufficient strength to support at least tow other stacked ice trays.
20. The ice tray according to claim 16, wherein upon removal from over a first cavity, said laminated cover being effective to roll onto itself and prevents ejection of ice cubes from adjacent cavities.
PCT/US1993/011145 1992-11-16 1993-11-16 Non-reusable, peel off covered ice tray WO1994011170A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/977,507 US5393032A (en) 1988-04-29 1992-11-16 Non-reusable, peel off covered ice tray
US07/977,507 1992-11-16

Publications (1)

Publication Number Publication Date
WO1994011170A1 true WO1994011170A1 (en) 1994-05-26

Family

ID=25525207

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1993/011145 WO1994011170A1 (en) 1992-11-16 1993-11-16 Non-reusable, peel off covered ice tray

Country Status (2)

Country Link
US (1) US5393032A (en)
WO (1) WO1994011170A1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2292928A (en) * 1994-09-06 1996-03-13 Torben Bodtker Packing for edible ice
EP0881162A1 (en) * 1997-04-22 1998-12-02 Omni-Pac Ekco GmbH Verpackungsmittel Method for closing a tray composed of natural fibres and/or starch with a sealable foil, tray closed in such a way and package unit formed therewith
GB2334570A (en) * 1998-02-20 1999-08-25 Diamond Bloom Limited Individual ice system
WO2000008395A2 (en) * 1998-08-05 2000-02-17 Fleurfontein Mountain Estates (Proprietary) Limited Ice block apparatus
WO2001014806A1 (en) * 1999-08-19 2001-03-01 Diamondbloom Limited Ice tray and ice cubes formed therein
WO2003104729A1 (en) * 2002-06-11 2003-12-18 Mariagrazia Frattini Packaging for ice in cubes
WO2010103148A1 (en) * 2009-03-11 2010-09-16 Viviendas De Primera Mano, S.L. Ice cube tray
GB2471028A (en) * 2010-01-08 2010-12-15 Linpac Packaging Ltd Tray with adhesively sealed lid film
EP2925623A1 (en) * 2012-12-03 2015-10-07 WM. Wrigley Jr. Company Unitary flexible package
WO2020041393A3 (en) * 2018-08-23 2020-03-26 Illinois Tool Works Inc. Ice maker with thermoformed ice tray providing heating and phase change sensing
WO2020084174A1 (en) * 2018-10-24 2020-04-30 Capdevila Gali Albert Container for producing ice cubes

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5785180A (en) * 1995-06-22 1998-07-28 G. D. Searle & Co. Child-resistant package
ES2102324B1 (en) * 1995-07-31 1998-03-01 Payro Jose Ramon Costa LIQUID PACKAGING SYSTEM ITS APPLICATION TO THE FORMATION OF FROZEN CUBES AND THE CORRESPONDING CONTAINER TRAY.
US6516949B2 (en) 1995-10-31 2003-02-11 Mcneil-Ppc, Inc. Blister pill package with safety backing
US5775505A (en) * 1996-02-27 1998-07-07 Vasquez; William M. Blister card package
US5976588A (en) 1996-09-05 1999-11-02 Dreyer's Grand Ice Cream, Inc. Food package with filling nozzle
US6196518B1 (en) 1997-08-08 2001-03-06 World Kitchen, Inc. Ice cube having a slidable cover
US5975304A (en) * 1998-08-25 1999-11-02 Unipac Corporation Sealed containers with tabs and method of making the same
IT245543Y1 (en) * 1998-12-10 2002-03-22 Annita Brugnera SEALED PACKAGING OF ONE OR MORE PRE-FIXED DOSES OF WATER OR OTHER FOODSTUFFS FOR THEIR FREEZING
USD434427S (en) * 1998-12-29 2000-11-28 Hernan J. Garrido-Lecca Ice cube tray having a slidable cover
US6112548A (en) * 1999-02-22 2000-09-05 Moenickheim; Peter Packaging and delivery system for aqueous-based products
US6311500B1 (en) 1999-09-16 2001-11-06 Ian Fraenkel Method and apparatus for preparing ice cubes
CA2401140A1 (en) * 2000-02-29 2001-09-07 Robert A. Zoss Packaging system for frozen storage and transportation of food product pucks such as muffin batter
IT251473Y1 (en) * 2000-04-13 2003-11-19 Annita Brugnera IMPROVEMENT IN SEALED PACKAGES OF PREFIXED DOSES OF FROZEN LIQUIDS WITH MEASURES TO FACILITATE THE EXPULSION OF THE MASS
FR2813384B1 (en) * 2000-08-30 2003-09-19 Colbert Foncier SEALED CONTAINER FILLED WITH WATER FOR THE MANUFACTURE OF GLACONS AND PACKAGING INCLUDING SAME
US6869059B2 (en) * 2000-11-30 2005-03-22 The Pillsbury Company Bakeable muffin pan, and use thereof
JP3935677B2 (en) * 2001-01-30 2007-06-27 大和グラビヤ株式会社 Package
US6655174B2 (en) * 2001-05-29 2003-12-02 Pamela R. Moore Method and apparatus for individual disposable packages for freezable substances and a container thereof
WO2002100740A1 (en) * 2001-06-08 2002-12-19 Harman, Robert Individual prepackaged ice cubes
DE10222009A1 (en) * 2002-05-17 2003-12-04 Henkel Kgaa Device for receiving a gel-like active substance preparation to be dispensed into the interior of a toilet bowl or the like
EP1369649A1 (en) * 2002-06-07 2003-12-10 UniGreen International A/S Pre-filled ice cube bag
ES2253013B1 (en) * 2003-03-14 2007-07-16 Jose F. Martin Alvarez INTEGRAL HERMETIC CUBITERA.
US7014162B2 (en) * 2004-01-09 2006-03-21 Mastrad S.A. Ice cube tray with server cover
US20050163892A1 (en) * 2004-01-28 2005-07-28 Robert Breslow Frozen additive for use with a heated beverage
US7210307B2 (en) 2005-02-08 2007-05-01 Whirlpool Corporation Refrigerator ice storage bin with lid
US7395928B2 (en) * 2005-07-14 2008-07-08 Abbott Laboratories Child-resistant blister package
US20070107447A1 (en) * 2005-11-14 2007-05-17 Langlotz Bennet K Sealed water-filled container with ice cube features
US20080113070A1 (en) * 2006-11-15 2008-05-15 Mansour Nagi A Fresh ready onion and spice mix
US20080245800A1 (en) * 2007-04-06 2008-10-09 Moore Pamela R Disposable container for frozen liquid
US7900471B2 (en) * 2008-05-27 2011-03-08 S. I. Incorporated Pre-packaged, flexible container of ice and air
US20090293434A1 (en) * 2008-05-27 2009-12-03 S. I. Incorporated, Dba "Serv-Ice" Method of forming a pre-packaged, flexible container of ice and air
US20090297691A1 (en) * 2008-05-27 2009-12-03 S. I. Incorporated, Dba "Serv-Ice" Method of serving a drink to a person
JP2008207882A (en) * 2008-06-10 2008-09-11 Moenickheim Peter New packaging and delivery system for product composed primarily of water
US20110005242A1 (en) * 2009-07-11 2011-01-13 Sciortino Ronald R Ice Mold
US8794293B2 (en) 2010-08-10 2014-08-05 S.C. Johnson & Son, Inc. Single dose applicator and method
PL2637532T3 (en) * 2010-11-09 2016-07-29 La Vit Tech Llc Capsule based system for preparing and dispensing a beverage
US20150079240A1 (en) 2010-11-09 2015-03-19 Gian Matteo Lo Foro Capsule based system for preparing and dispensing a beverage
ES2363431B1 (en) * 2011-05-03 2012-04-20 Ulma Packaging Technological Center S. Coop. THERMOFORMED CONTAINER
US10034570B2 (en) 2011-11-09 2018-07-31 LaVit Technology LLC Capsule based system for preparing and dispensing a beverage
US10080459B2 (en) 2011-11-09 2018-09-25 La Vit Technology Llc Capsule-based system for preparing and dispensing a beverage
US9795153B2 (en) * 2012-07-18 2017-10-24 Paulette Suzanne Fox Bite-sized ices composed of natural ingredients and method for processing and apparatus for packaging the same
EP2931626B1 (en) * 2012-12-01 2018-04-04 Malinowski, Thomas Rainer A disposable cup with a plurality of compartments
US9303910B2 (en) 2013-02-22 2016-04-05 Arctico Holdings, LLC Apparatus for forming a frozen liquid product
US20140322396A1 (en) * 2013-04-30 2014-10-30 J.R. Simplot Company System and method for packaging a frozen product
US9320382B2 (en) 2013-07-15 2016-04-26 La Vit Technology Llc Capsule based system for preparing and dispensing a beverage
US20160023841A1 (en) * 2014-07-25 2016-01-28 Nestor Charles Villalobos Single use sealed container assembly for a large format ice unit
US10111554B2 (en) 2015-03-20 2018-10-30 Meltz, LLC Systems for and methods of controlled liquid food or beverage product creation
US20180283759A1 (en) * 2015-04-17 2018-10-04 David Bess Ice Tray Assembly
US20170225828A1 (en) * 2016-02-06 2017-08-10 Jacqueline Carson Apparatus and method for evenly storing equivalent amounts of a solution pertaining to a food
US10260789B2 (en) 2016-04-13 2019-04-16 Whirlpool Corporation Ice making assembly with twist ice tray and directional cooling
US10501248B2 (en) 2016-11-02 2019-12-10 Tekni-Plex, Inc. Blister package and method of manufacture
CA2964569A1 (en) * 2017-04-18 2018-10-18 Dube, Dominic Evive container
US9963265B1 (en) * 2017-05-08 2018-05-08 Medi-Dose, Inc. Multi-compartment article dispensing package
GB2572030A (en) 2018-01-26 2019-09-18 Ne Innovations Ltd System for filtering liquid
KR102008289B1 (en) * 2018-06-21 2019-08-08 이정미 A food freezer
US11085687B2 (en) * 2018-07-12 2021-08-10 Carlos Leal Flexible tray and method of transporting and storing manufactured ice shapes
USD879163S1 (en) 2018-12-18 2020-03-24 Can't Live Without It, LLC Ice tray
WO2020168169A1 (en) * 2019-02-15 2020-08-20 Kraft Foods Group Brands Llc Food products for multifunction pressure cookers
US11724849B2 (en) * 2019-06-07 2023-08-15 Cometeer, Inc. Packaging and method for single serve beverage product
GB2594259B (en) * 2020-04-20 2022-04-13 Medi Clear Ltd Cover sheets
USD949935S1 (en) 2020-06-17 2022-04-26 Bingbing Cao Ice tray
USD942515S1 (en) * 2021-04-23 2022-02-01 Shenzhen Benhaida Rubber & Plastic Products Co., Ltd. Ice tray
USD997214S1 (en) * 2023-04-12 2023-08-29 Lina WU Ice tray

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955044A (en) * 1956-12-18 1960-10-04 Tupper Corp Membranous shape-sustaining receptacles
US3380578A (en) * 1964-03-04 1968-04-30 George C. Sparks Strip package assembly
US3689458A (en) * 1970-03-23 1972-09-05 Hellstrom Harold R Quick-opening fulcrum package
US3759379A (en) * 1972-02-24 1973-09-18 Packaging Laminators Inc Flexible halogen package
US3783089A (en) * 1971-07-28 1974-01-01 Phillips Petroleum Co Heat sealed,readily peelable or tearable structure suitable for closures,labels,packaging,etc.
US4011949A (en) * 1975-06-18 1977-03-15 The Lehigh Press, Inc. Package construction for opening only by a predetermined procedure
US4023768A (en) * 1975-02-24 1977-05-17 Herrera Casasus Crisogono Ice cube mold
US4105118A (en) * 1976-06-10 1978-08-08 Eastman Kodak Company Laminates useful as packaging materials and container having alkaline fluid means
US4287171A (en) * 1978-06-10 1981-09-01 Degesch Gmbh Storage stable quickly acting tablets for combatting vertebrates preponderantly in underground structures
US4305502A (en) * 1977-07-20 1981-12-15 John Wyeth & Brother Limited Pharmaceutical dosage form packges

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2235964A (en) * 1938-03-28 1941-03-25 Gus C Meyer Mold for ice cream or the like
US2537915A (en) * 1948-10-26 1951-01-09 Columbus Plastic Products Inc Cube forming tray for refrigerators
GB1019552A (en) * 1961-09-12 1966-02-09 Arnot Alfred E R Improvements in or relating to foodstuff packaging
FR1537903A (en) * 1967-07-19 1968-08-30 S E F Process for obtaining packaged frozen ice cream and products obtained by this process
FR2040845A5 (en) * 1969-04-15 1971-01-22 Wagner Roger Disposable thermoplastic ice block packs
US3661353A (en) * 1970-08-24 1972-05-09 Monogram Ice Co Inc Tray having containers for forming ice cubes and the like
FR2159549A5 (en) * 1971-11-02 1973-06-22 Hanquet Bernard
US3837782A (en) * 1971-12-15 1974-09-24 Filper Corp Apparatus for forming containers
FR2169491A5 (en) * 1972-01-27 1973-09-07 Henry Jean Aseptic ice cubes - frozen and kept in covered plastic compartments
DE2410427A1 (en) * 1974-03-05 1975-09-25 Kaiser & Co Gmbh W F Aluminium or steel ice tray for refrigerators - design allows easy removal of insert from dish and of individual ice cubes from insert
US4913307A (en) * 1986-09-30 1990-04-03 Idemitsu Petrochemical Co., Ltd. Easily openable packaging container and method for producing the same
US4807787A (en) * 1987-05-12 1989-02-28 The Procter & Gamble Company Easy-open/reclosure device having deformable pour spout

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955044A (en) * 1956-12-18 1960-10-04 Tupper Corp Membranous shape-sustaining receptacles
US3380578A (en) * 1964-03-04 1968-04-30 George C. Sparks Strip package assembly
US3689458A (en) * 1970-03-23 1972-09-05 Hellstrom Harold R Quick-opening fulcrum package
US3783089A (en) * 1971-07-28 1974-01-01 Phillips Petroleum Co Heat sealed,readily peelable or tearable structure suitable for closures,labels,packaging,etc.
US3759379A (en) * 1972-02-24 1973-09-18 Packaging Laminators Inc Flexible halogen package
US4023768A (en) * 1975-02-24 1977-05-17 Herrera Casasus Crisogono Ice cube mold
US4011949A (en) * 1975-06-18 1977-03-15 The Lehigh Press, Inc. Package construction for opening only by a predetermined procedure
US4105118A (en) * 1976-06-10 1978-08-08 Eastman Kodak Company Laminates useful as packaging materials and container having alkaline fluid means
US4305502A (en) * 1977-07-20 1981-12-15 John Wyeth & Brother Limited Pharmaceutical dosage form packges
US4287171A (en) * 1978-06-10 1981-09-01 Degesch Gmbh Storage stable quickly acting tablets for combatting vertebrates preponderantly in underground structures

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2292928A (en) * 1994-09-06 1996-03-13 Torben Bodtker Packing for edible ice
GB2292928B (en) * 1994-09-06 1998-03-04 Torben Bodtker Packing for edible ice
EP0881162A1 (en) * 1997-04-22 1998-12-02 Omni-Pac Ekco GmbH Verpackungsmittel Method for closing a tray composed of natural fibres and/or starch with a sealable foil, tray closed in such a way and package unit formed therewith
GB2334570A (en) * 1998-02-20 1999-08-25 Diamond Bloom Limited Individual ice system
WO2000008395A2 (en) * 1998-08-05 2000-02-17 Fleurfontein Mountain Estates (Proprietary) Limited Ice block apparatus
WO2000008395A3 (en) * 1998-08-05 2001-03-01 Fleurfontein Mountain Estates Ice block apparatus
WO2001014806A1 (en) * 1999-08-19 2001-03-01 Diamondbloom Limited Ice tray and ice cubes formed therein
WO2003104729A1 (en) * 2002-06-11 2003-12-18 Mariagrazia Frattini Packaging for ice in cubes
WO2010103148A1 (en) * 2009-03-11 2010-09-16 Viviendas De Primera Mano, S.L. Ice cube tray
GB2471028A (en) * 2010-01-08 2010-12-15 Linpac Packaging Ltd Tray with adhesively sealed lid film
GB2478028A (en) * 2010-01-08 2011-08-24 Linpac Packaging Ltd Tray with adhesively sealed lid film
GB2478028B (en) * 2010-01-08 2012-12-05 Linpac Packaging Ltd Container
EP2925623A1 (en) * 2012-12-03 2015-10-07 WM. Wrigley Jr. Company Unitary flexible package
EP2925623A4 (en) * 2012-12-03 2016-05-25 Wrigley W M Jun Co Unitary flexible package
RU2665615C2 (en) * 2012-12-03 2018-08-31 Вм. Ригли Джр. Компани Package (options)
WO2020041393A3 (en) * 2018-08-23 2020-03-26 Illinois Tool Works Inc. Ice maker with thermoformed ice tray providing heating and phase change sensing
US11435126B2 (en) 2018-08-23 2022-09-06 Illinois Tool Works Inc. Icemaker with thermoformed ice tray providing heating and phase change sensing
WO2020084174A1 (en) * 2018-10-24 2020-04-30 Capdevila Gali Albert Container for producing ice cubes

Also Published As

Publication number Publication date
US5393032A (en) 1995-02-28

Similar Documents

Publication Publication Date Title
US5393032A (en) Non-reusable, peel off covered ice tray
US7960001B2 (en) Container seal with integral promotional token and method
AU628811B2 (en) Ice tray and ice cubes formed therein
US7819266B2 (en) Container sealing material having a heat-releasable interlayer
US7713605B2 (en) Container seal with integral, heat-releasable promotional token and method
EP2183106B1 (en) Multi-purpose covering for hygienically covering a container top
US4588099A (en) Film seal for container
US6708735B1 (en) Dispensing lid closure for confections and methods of making and using the closure
US6976578B1 (en) Dispensing lid closure for beverage container and method of making and using the closure
US6620281B1 (en) Method for making insulating label and wrap for beverage container
US20080073308A1 (en) Tabbed container seal and method of manufacture
ES2219369T3 (en) PLASTIC CONTAINER WITH A FILM OF STRATIFIED OBTURATION.
JP4814104B2 (en) Tear-resistant peelable container seal
JPS59199463A (en) Packing vessel
US5470594A (en) Paper pouch for food products
JP2000025067A (en) Label for in-mold labeling and in-mold label molding container using the same
EP1724205A2 (en) A container and method for forming a container
WO2013126621A1 (en) Unitized package and method of making same
JPS5836685Y2 (en) Inner seal material for sealing the container mouth
CN215882808U (en) Lid laminate, lid, and package
JP4043590B2 (en) Cup composite container with sauce
JP2770294B2 (en) Lid with pull tab
JP2000025068A (en) Label for in-mold labeling and in-mold label molding container using the same
JPH06297656A (en) Highly permeable material resistant container
JPH09254987A (en) Packaging container

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): BR CA JP

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA