WO1994027539A1 - Absorbent article having anti-wicking crimp seal - Google Patents

Absorbent article having anti-wicking crimp seal Download PDF

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Publication number
WO1994027539A1
WO1994027539A1 PCT/US1994/004657 US9404657W WO9427539A1 WO 1994027539 A1 WO1994027539 A1 WO 1994027539A1 US 9404657 W US9404657 W US 9404657W WO 9427539 A1 WO9427539 A1 WO 9427539A1
Authority
WO
WIPO (PCT)
Prior art keywords
topsheet layer
seal
absorbent article
backsheet
absorbent
Prior art date
Application number
PCT/US1994/004657
Other languages
French (fr)
Inventor
Michael Edward Carrier
Robert E. Lee Marshall, Iii
Richard George Coe
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP7500640A priority Critical patent/JPH08510665A/en
Priority to EP94915921A priority patent/EP0699063A1/en
Priority to NZ266321A priority patent/NZ266321A/en
Priority to AU67763/94A priority patent/AU6776394A/en
Publication of WO1994027539A1 publication Critical patent/WO1994027539A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/47Sanitary towels, incontinence pads or napkins
    • A61F13/475Sanitary towels, incontinence pads or napkins characterised by edge leakage prevention means
    • A61F13/4751Sanitary towels, incontinence pads or napkins characterised by edge leakage prevention means the means preventing fluid flow in a transversal direction
    • A61F13/4757Sanitary towels, incontinence pads or napkins characterised by edge leakage prevention means the means preventing fluid flow in a transversal direction the means being located outside the perimeter of the absorbent core
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/5116Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/515Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers characterised by the interconnection of the topsheet and the backsheet
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/494Absorbent articles specially adapted to be worn around the waist, e.g. diapers characterised by edge leakage prevention means
    • A61F13/49406Absorbent articles specially adapted to be worn around the waist, e.g. diapers characterised by edge leakage prevention means the edge leakage prevention means being at the crotch region
    • A61F13/49413Absorbent articles specially adapted to be worn around the waist, e.g. diapers characterised by edge leakage prevention means the edge leakage prevention means being at the crotch region the edge leakage prevention means being an upstanding barrier
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/531Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having a homogeneous composition through the thickness of the pad
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F2013/51059Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers being sprayed with chemicals
    • A61F2013/51066Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers being sprayed with chemicals for rendering the surface hydrophilic
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/51121Topsheet, i.e. the permeable cover or layer facing the skin characterised by the material
    • A61F2013/51147Topsheet, i.e. the permeable cover or layer facing the skin characterised by the material being polymeric films
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/5116Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers
    • A61F2013/51165Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers with the combination of films and nonwovens
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/514Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • A61F13/51401Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
    • A61F2013/51409Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material being a film
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/514Backsheet, i.e. the impermeable cover or layer furthest from the skin
    • A61F13/51401Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material
    • A61F2013/51441Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material being a fibrous material
    • A61F2013/51452Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by the material being a fibrous material being nonwovens
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F2013/530481Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having superabsorbent materials, i.e. highly absorbent polymer gel materials

Definitions

  • the present invention relates generally to disposable absorbent articles and, more particularly, to the incorporation of an anti-wicking crimp seal into the peripheral border of a catamenial pad.
  • Disposable absorbent articles are commercially available in a wide variety of configurations for the specific purpose of absorbing and retaining discharged body fluids.
  • disposable diapers and incontinent briefs are intended to absorb and contain urine and feces
  • bandages are intended to absorb and contain blood and other body exudates
  • catamenial pads are intended to absorb and retain menstrual fluids and other vaginal discharges.
  • each absorbent article is intended to isolate the discharged fluids for preventing the undergarments, clothing, bedding etc. surrounding the disposable article from becoming soiled.
  • the basic structure for most disposable absorbent articles includes an absorbent core that is encased between a liquid permeable topsheet layer and a liquid impervious backsheet.
  • the absorbent core generally incorporates a number of Absorbent Gelling Material (AGM) particles.
  • AGM Absorbent Gelling Material
  • apertured film topsheet layers known in the art have generally failed to adequately retain the AGM particles, either before or after they have absorbed liquids. It is therefore desirable to provide an improved topsheet layer for more effectively retaining the AGM particles within the absorbent article.
  • the topsheet layer it is common for the topsheet layer to be affixed to the backsheet in a manner defining a continuous and relatively thin border segment which surrounds the perimeter of the thicker absorbent core.
  • the disposable article must exhibit good strikethrough and rewet characteristics for permitting the discharged fluid to rapidly penetrate the topsheet layer while preventing subsequent flow back through the topsheet layer.
  • the liquid impervious backsheet should isolate the fluid retained in die absorbent core from the wearer's undergarments or clothing.
  • the absorbent core is disposed between the backsheet and the second topsheet layer, and the second topsheet layer is disposed between the absorbent core and the first topsheet layer.
  • Each of the first and second topsheet layers and die backsheet extend laterally beyond the perimeter of the absorbent core to define a continuous border segment surrounding the absorbent core.
  • a liquid impermeable seal surrounds at least a portion of the perimeter of the absorbent core and is formed in the border segment to extend between the first and second topsheet layers and the backsheet.
  • the seal extends from an outer or top surface of the first topsheet layer to an outer or lower surface of the backsheet layer, and is adapted to prevent lateral migration of fluid from within the perimeter of the absorbent core beyond the seal.
  • Figure 1 is a perspective view of a disposable absorbent article incorporating the novel principles of the present invention
  • Figure 2 is a cross-sectional view taken along line 2-2 of Figure 1 ;
  • Figure 3 is an enlarged partial cross-sectional view of a portion of the absorbent article shown in Figure 2;
  • Figure 4 is a cross-sectional view of an alternative embodiment of me present invention.
  • Figure 5 is an enlarged partial cross-sectional view of a portion of die absorbent article shown in Figure 4;
  • Figure 6 is a cross-sectional view of another alternative embodiment of the present invention.
  • Figure 7 is an enlarged partial cross-sectional view of a portion of the absorbent article shown in Figure 6;
  • Figure 8 is a perspective view of a disposable absorbent article arranged according to an alternative embodiment of the present invention.
  • a preferred embodiment of the present invention is shown incorporated into a disposable absorbent article, and in particular, a catamenial pad. It should be noted mat the present invention may also be utilized in other absorbent articles, such as diapers, adult incontinent products and the like.
  • the term "disposable absorbent article” includes articles for absorbing and retaining liquids, such as tiiose discharged from the human body, and further, which articles are intended to be discarded after a single use.
  • a "catamenial pad” is an absorbent article worn by females externally to the urogenital region for absorbing and containing menstrual fluids and other vaginal discharges.
  • catamenial pad 10 is constructed of a first liquid permeable topsheet layer 12. a second liquid permeable topsheet layer 14, an absorbent core 16, and a liquid impermeable backsheet 18.
  • First and second topsheet layers 12 and 14 may be either formed as separate sheets or as multiple plies of one composite material.
  • Absorbent core 16 may be formed of a variety of absorbent materials, and preferably includes a predetermined amount of "Absorbent Gelling Material” particles 19, commonly referred to as AGM in the art.
  • Absorbent core 16 should be flexible, compressible, and comfortable to the wearer.
  • absorbent capacity of the material used in absorbent core 16 must be sufficient to absorb and retain the expected liquid loading on catamenial pad 10.
  • shape and dimensions of absorbent core 16 are selected to comfortably fit the urogenital region of the female wearer.
  • Figure 1 shows a generally hour-glass shaped absorbent core 16 that provides satisfactory fit and protection.
  • Liquid impermeable backsheet 18 prevents liquid which has penetrated first topsheet layer 12 and second topsheet layer 14 and has been absorbed by absorbent core 16 from soiling the undergarments of the wearer of catamenial pad 10.
  • Backsheet 18 is preferably formed of a hydrophobic polyethylene film having a thickness approximately within the range of 0.010 to 0.050 millimeters, although other flexible, liquid impermeable materials may be used.
  • hydrophobic is used herein to refer to a surface which is not wetted by contact with a liquid. The wetting of materials is generally defined in terms of contact angle and surface tension. These properties are discussed further in the publication of the American Chemical Society entitled “Contact Angle, Wettability, and Adhesion", edited by Robert F. Gould, copyright 1964, which is hereby incorporated by reference.
  • First topsheet layer 12 is liquid permeable and contacts the skin of the wearer of catamenial pad 10. It should therefore preferably be compliant, soft, and non- irritating to the skin of the wearer.
  • First topsheet layer 12 is preferably formed of polyediylene film that is treated with a surfactant to enhance liquid penetration.
  • the term "hydrophilic" is used herein to refer to a surface which is wetted by contact with a liquid.
  • First topsheet layer 12 preferably has a multiplicity of transversely extending capillaries for encouraging liquid to rapid penetrate or strike through first topsheet layer 12 for subsequent absorption and retention by absorbent core 16.
  • Second topsheet layer 14 is preferably formed of polypropylene which is initially hydrophobic and has been treated with wetting agents to become hydrophilic. Second topsheet layer 14 is disposed between first topsheet layer 12 and absorbent core 14 for the purposes of resisting passage and escape of die AGM particles, which would cause a variety of problems.
  • catamenial pad 10 When in use, catamenial pad 10 is preferably held in place by an undergarment (not shown).
  • a band of adhesive 20 is affixed to a lower or outer surface 22 of backsheet 18 for adhering to die undergarment (not shown) to resist movement of catamenial pad 10 out of proper alignment with the urogenital region of the female wearer's body.
  • a cover strip 24 may be initially provided for covering and protecting adhesive band 20, which is removed before use.
  • absorbent core 16 has a lower surface 28 and an upper surface 26 and which are respectively disposed adjacent to and contiguous with an upper surface 30 of backsheet 18 and a lower surface 32 of second topsheet layer 14.
  • second topsheet layer 14 has an upper surface 34 which is positioned adjacent to and contiguous with a lower surface 36 of first topsheet layer 12.
  • first topsheet layer 12 has an upper surface 38 which is placed against die user's body when catamenial pad 10 is worn.
  • First and second topsheet layers 12 and 14 and backsheet 18 are formed generally without macroscopic perforations, and each have a shape similar to but larger man absorbent core 16. Thus, each of first and second topsheet layers 12 and 14, respectively, and backsheet 18 have a portion which extends outwardly from e perimeter of absorbent core 16 to define a continuous border segment which encircles absorbent core 16.
  • Border segment 42 is generally relatively narrow, and may extend a distance of approximately 0.25 to 5 millimeters and preferably is approximately 3 millimeters wide. However, the width of border 42 may be uniform or vary about e perimeter of pad 10.
  • border segment 42 is relatively tiiin and flexible and is intended to provide improved protection against soiling of die vicinity surrounding the discharge region, as well as retain AGM particles within the absorbent article.
  • a liquid impermeable seal 44 is provided in border segment 42 which surrounds perimeter 40.
  • seal 44 is adapted to prevent lateral migration (i.e., "wicking") of liquid from perimeter 40 of absorbent core 16, or first and second topsheet layers 12 and 14, mrough border segment 42 toward the peripheral edges of catamenial pad 10, thereby inhibiting premature side soiling of the wearer's undergarments.
  • first topsheet layer 12, second topsheet layer 14 and backsheet 18 tend to remain relatively free of liquids, regardless of the amount of liquid contained in absorbent core 16.
  • Liquid impermeable seal 44 is preferably disposed laterally inwardly as close as possible to perimeter 40 so mat a greater portion of border segment 42 remains dry and unsoiled.
  • seal 44 in its preferred application, completely surrounds perimeter 40 wid out any gaps which would allow wicking and fluid leakage.
  • die improved seal 44 of the present invention is specifically directed to inhibiting wicking of fluid mrough liquid permeable second topsheet layer 14 which is sandwiched between first topsheet layer 12 and backsheet 18 in border segment 42.
  • Seal 44 is preferably formed by die simultaneous application of pressure, with or without heat, commonly referred to as a "crimping" operation.
  • a "crimping" operation an upper and lower crimp tool 46 and 48 are shown for concurrently compressing first and second topsheet layers 12 and 14 and backsheet 18.
  • Tools 46 and 48 should be wide enough so as not to cut, mar or tear first topsheet layer 12 or backsheet 18.
  • sufficient pressure possibly with heat, is transferred via crimping tools 46 and 48 to melt first topsheet layer 12 and backsheet 18, thereby forming a solid yet flexible liquid impermeable seal 44.
  • die pressure crushes second topsheet layer 14 to at least partially fill the remaining capillary spaces therein.
  • the portions of the border outside of seal 44 are crimped widi discrete spaced-apart bonds. This discrete bonding creates a reverse or negative capillary gradient, whereby any liquids inadvertently passing dirough seal 44 will tend to be attracted toward the more dense material in die seal 44 area, so any liquid movement outside seal 44 occurs along seal 44, as opposed to toward outer edge of border 42.
  • second topsheet layer 14 is formed of hydrophilic non-woven or apertured polyethylene film having a lower melting temperature than first topsheet layer 12 and backsheet 18.
  • polyethylene second topsheet layer 14 will melt before first topsheet layer 12 and backsheet 18 and will propagate and mingle widi die material of first topsheet layer 12 and backsheet 18, thus forming a liquid impermeable seal 44 which appears similar on a macroscopic level to the seal formed by the first preferred embodiment of the present invention, in which first topsheet layer 12 and backsheet 18 melt prior to second topsheet layer 14.
  • the crimping process may be varied to cause first and second topsheet layers 12 and 14, as well as backsheet 18, to melt to form seal 44.
  • FIG. 4 and 5 depict a catamenial pad 50 generally similar to catamenial pad 10 of Figures 1 through 3.
  • Pad 50 has a first or inner liquid impermeable seal 52 which is disposed as close as possible to perimeter 40 of absorbent core 16 and surrounds perimeter 40.
  • catamenial pad 50 is also provided wid a second or outer seal 54 for providing additional resistance against wicking of liquid diat enters border segment 42 beyond first seal 52.
  • the present invention contemplates the possibility of using three or even more seals.
  • second topsheet layer 12 may be formed preferably of hydrophobic polypropylene which is treated with wetting agents to become hydrophilic, or alternatively can be formed of hydrophilic non-woven or apertured polyethylene. Accordingly, first and second seals 52 and 54 will be formed by the melting of first topsheet layer 12 and backsheet 18 widi the preferred selection of polypropylene for second topsheet layer 14, or in die alternative, seals 52 and 54 will be formed by die melting of second topsheet layer 14 in d e case of selection of hydrophilic polyediylene for second topsheet layer 14.
  • FIG. 6 and 7 Another alternative embodiment of the present invention is depicted in Figures 6 and 7, in which a catamenial pad 56 is constructed substantially similar to catamenial pad 50 shown in Figures 4 and 5, and includes a first or inner seal 52 and a second or outer seal 58.
  • outer seal 58 is disposed at die laterally outermost edge of border segment 42 defined by first and second topsheet layers 12 and 14, as well as backsheet 18.
  • the alternative embodiments of the present invention provide for selectively positioning various liquid impervious seals in order to maximize their effectiveness while maintaining comfort and preventing irritation to the wearer.
  • Catamenial pad 62 is formed generally similar to pad 10, and has an anterior portion 64, posterior portion 66, and first and second sides edges 68 and 70.
  • Liquid impermeable seals 72 and 74 are similar to seal 44, but extend only along side edges 68 and 70. It has been found that seals 68 and 70 may be more easily manufactured than seal 44, which completely surrounds core 16.

Abstract

An absorbent article is disclosed for absorbing liquids, including body fluids such as menstrual discharges or urine. The absorbent article has a liquid impermeable backsheet on which is disposed an absorbent core, and first and second liquid permeable topsheet layers. The edge of the absorbent core defines a perimeter, and the first and second topsheet layers and the backsheet each extend laterally beyond the perimeter to define a continuous border segment surrounding the absorbent core. A liquid impermeable seal is formed in the border segment which surrounds the perimeter for preventing lateral migration of liquid from the absorbent core beyond the seal. The seal is formed to extend from an outer surface of the first topsheet layer to an outer surface of the backsheet, for establishing a capillary gradient in the second topsheet layer, thereby inhibiting wicking of fluid therethrough.

Description

ABSORBENT ARTICLE HAVING ANTI-WICKING CRIMP SEAL
BACKGROUND OF THE INVENTION
1. Technical Field
The present invention relates generally to disposable absorbent articles and, more particularly, to the incorporation of an anti-wicking crimp seal into the peripheral border of a catamenial pad.
2. Background Art
Disposable absorbent articles are commercially available in a wide variety of configurations for the specific purpose of absorbing and retaining discharged body fluids. For example, disposable diapers and incontinent briefs are intended to absorb and contain urine and feces, bandages are intended to absorb and contain blood and other body exudates while catamenial pads are intended to absorb and retain menstrual fluids and other vaginal discharges. Regardless of the specific application, each absorbent article is intended to isolate the discharged fluids for preventing the undergarments, clothing, bedding etc. surrounding the disposable article from becoming soiled.
As is known, the basic structure for most disposable absorbent articles includes an absorbent core that is encased between a liquid permeable topsheet layer and a liquid impervious backsheet. The absorbent core generally incorporates a number of Absorbent Gelling Material (AGM) particles. However, apertured film topsheet layers known in the art have generally failed to adequately retain the AGM particles, either before or after they have absorbed liquids. It is therefore desirable to provide an improved topsheet layer for more effectively retaining the AGM particles within the absorbent article.
In addition, it is common for the topsheet layer to be affixed to the backsheet in a manner defining a continuous and relatively thin border segment which surrounds the perimeter of the thicker absorbent core. Ideally, the disposable article must exhibit good strikethrough and rewet characteristics for permitting the discharged fluid to rapidly penetrate the topsheet layer while preventing subsequent flow back through the topsheet layer. Moreover, the liquid impervious backsheet should isolate the fluid retained in die absorbent core from the wearer's undergarments or clothing. As will be appreciated, numerous variations to the above-noted structure are known in the art for improving a particular functional or comfort characteristic of the disposable absorbent article.
Due to the rapid capillary-type action associated with the strikethrough characteristics of the liquid permeable topsheet layer, me potential exists for lateral migration (i.e., "wicking") of the discharged fluid from the absorbent core toward the peripheral edge of the absorbent article. Such wicking is undesirable in that it may cause soiling of the wearer's undergarments and/or clothing in the vicinity surrounding the absorbent article. In an attempt to prevent such lateral migration of discharged fluids, it is known to form a liquid impervious "seam" in the border segment of the disposable absorbent article. For example, commonly owned U.S. Pat. No. 4,321,924 issued to Ahr discloses incorporation of a pair of continuous seams into a channelled border segment of a catamenial pad which act as barriers against edge leakage. Thus, while such conventional products perform well for their intended purpose, a continuing need exists to develop improvements in the structure, method of manufacture, and cost of bordered disposable absorbent articles.
It is therefore an object of the present invention to provide a disposable absorbent article having an improved mechanism for preventing wicking of fluid from an absorbent core toward the edges of a border segment surrounding the absorbent core.
It is another object of the present invention to provide a second liquid permeable topsheet layer in the disposable absorbent article for improved containment of the absorbent fibers and/or absorbent gelling material particles within the absorbent core. Formation of an anti-wicking seal between the first topsheet layer, the second topsheet layer and the backsheet in the border segment of the disposable article is effective in inhibiting lateral migration of fluids from the absorbent core. SUMMARY OF THE INVENTION According to the present invention, a disposable absorbent article is provided having an absorbent core, a liquid impermeable backsheet, a first liquid permeable topsheet layer and a second liquid permeable topsheet layer. The absorbent core is disposed between the backsheet and the second topsheet layer, and the second topsheet layer is disposed between the absorbent core and the first topsheet layer. Each of the first and second topsheet layers and die backsheet extend laterally beyond the perimeter of the absorbent core to define a continuous border segment surrounding the absorbent core. A liquid impermeable seal surrounds at least a portion of the perimeter of the absorbent core and is formed in the border segment to extend between the first and second topsheet layers and the backsheet. Moreover, the seal extends from an outer or top surface of the first topsheet layer to an outer or lower surface of the backsheet layer, and is adapted to prevent lateral migration of fluid from within the perimeter of the absorbent core beyond the seal.
These and various other objects, advantages and features of the present invention will become apparent from the following description and claims, when considered in conjunction with the appended drawings.
BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a perspective view of a disposable absorbent article incorporating the novel principles of the present invention;
Figure 2 is a cross-sectional view taken along line 2-2 of Figure 1 ; Figure 3 is an enlarged partial cross-sectional view of a portion of the absorbent article shown in Figure 2;
Figure 4 is a cross-sectional view of an alternative embodiment of me present invention;
Figure 5 is an enlarged partial cross-sectional view of a portion of die absorbent article shown in Figure 4;
Figure 6 is a cross-sectional view of another alternative embodiment of the present invention;
Figure 7 is an enlarged partial cross-sectional view of a portion of the absorbent article shown in Figure 6; and
Figure 8 is a perspective view of a disposable absorbent article arranged according to an alternative embodiment of the present invention.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The following description of the preferred embodiments is merely exemplary in nature, and is in no way intended to limit me invention, its application or uses.
With reference to the drawings, a preferred embodiment of the present invention is shown incorporated into a disposable absorbent article, and in particular, a catamenial pad. It should be noted mat the present invention may also be utilized in other absorbent articles, such as diapers, adult incontinent products and the like. As used herein, the term "disposable absorbent article" includes articles for absorbing and retaining liquids, such as tiiose discharged from the human body, and further, which articles are intended to be discarded after a single use. A "catamenial pad" is an absorbent article worn by females externally to the urogenital region for absorbing and containing menstrual fluids and other vaginal discharges.
A perspective view of a catamenial pad incorporating the anti-wicking seal of the present invention is depicted in Figure 1. As best seen from Figure 2, catamenial pad 10 is constructed of a first liquid permeable topsheet layer 12. a second liquid permeable topsheet layer 14, an absorbent core 16, and a liquid impermeable backsheet 18. First and second topsheet layers 12 and 14 may be either formed as separate sheets or as multiple plies of one composite material. Absorbent core 16 may be formed of a variety of absorbent materials, and preferably includes a predetermined amount of "Absorbent Gelling Material" particles 19, commonly referred to as AGM in the art. Absorbent core 16 should be flexible, compressible, and comfortable to the wearer. Moreover, the absorbent capacity of the material used in absorbent core 16 must be sufficient to absorb and retain the expected liquid loading on catamenial pad 10. In addition, the shape and dimensions of absorbent core 16 are selected to comfortably fit the urogenital region of the female wearer. Figure 1 shows a generally hour-glass shaped absorbent core 16 that provides satisfactory fit and protection.
Liquid impermeable backsheet 18 prevents liquid which has penetrated first topsheet layer 12 and second topsheet layer 14 and has been absorbed by absorbent core 16 from soiling the undergarments of the wearer of catamenial pad 10. Backsheet 18 is preferably formed of a hydrophobic polyethylene film having a thickness approximately within the range of 0.010 to 0.050 millimeters, although other flexible, liquid impermeable materials may be used. The term "hydrophobic" is used herein to refer to a surface which is not wetted by contact with a liquid. The wetting of materials is generally defined in terms of contact angle and surface tension. These properties are discussed further in the publication of the American Chemical Society entitled "Contact Angle, Wettability, and Adhesion", edited by Robert F. Gould, copyright 1964, which is hereby incorporated by reference.
First topsheet layer 12 is liquid permeable and contacts the skin of the wearer of catamenial pad 10. It should therefore preferably be compliant, soft, and non- irritating to the skin of the wearer. First topsheet layer 12 is preferably formed of polyediylene film that is treated with a surfactant to enhance liquid penetration. The term "hydrophilic" is used herein to refer to a surface which is wetted by contact with a liquid. First topsheet layer 12 preferably has a multiplicity of transversely extending capillaries for encouraging liquid to rapid penetrate or strike through first topsheet layer 12 for subsequent absorption and retention by absorbent core 16.
Second topsheet layer 14 is preferably formed of polypropylene which is initially hydrophobic and has been treated with wetting agents to become hydrophilic. Second topsheet layer 14 is disposed between first topsheet layer 12 and absorbent core 14 for the purposes of resisting passage and escape of die AGM particles, which would cause a variety of problems.
When in use, catamenial pad 10 is preferably held in place by an undergarment (not shown). A band of adhesive 20 is affixed to a lower or outer surface 22 of backsheet 18 for adhering to die undergarment (not shown) to resist movement of catamenial pad 10 out of proper alignment with the urogenital region of the female wearer's body. A cover strip 24 may be initially provided for covering and protecting adhesive band 20, which is removed before use.
As best seen from Figure 2, absorbent core 16 has a lower surface 28 and an upper surface 26 and which are respectively disposed adjacent to and contiguous with an upper surface 30 of backsheet 18 and a lower surface 32 of second topsheet layer 14. Moreover, second topsheet layer 14 has an upper surface 34 which is positioned adjacent to and contiguous with a lower surface 36 of first topsheet layer 12. Finally, first topsheet layer 12 has an upper surface 38 which is placed against die user's body when catamenial pad 10 is worn.
The lateral edges of absorbent core 16 define a perimeter 40. First and second topsheet layers 12 and 14 and backsheet 18 are formed generally without macroscopic perforations, and each have a shape similar to but larger man absorbent core 16. Thus, each of first and second topsheet layers 12 and 14, respectively, and backsheet 18 have a portion which extends outwardly from e perimeter of absorbent core 16 to define a continuous border segment which encircles absorbent core 16. Border segment 42 is generally relatively narrow, and may extend a distance of approximately 0.25 to 5 millimeters and preferably is approximately 3 millimeters wide. However, the width of border 42 may be uniform or vary about e perimeter of pad 10. Moreover, border segment 42 is relatively tiiin and flexible and is intended to provide improved protection against soiling of die vicinity surrounding the discharge region, as well as retain AGM particles within the absorbent article.
In accordance widi the present invention, a liquid impermeable seal 44 is provided in border segment 42 which surrounds perimeter 40. Thus, seal 44 is adapted to prevent lateral migration (i.e., "wicking") of liquid from perimeter 40 of absorbent core 16, or first and second topsheet layers 12 and 14, mrough border segment 42 toward the peripheral edges of catamenial pad 10, thereby inhibiting premature side soiling of the wearer's undergarments. As a result, first topsheet layer 12, second topsheet layer 14 and backsheet 18 tend to remain relatively free of liquids, regardless of the amount of liquid contained in absorbent core 16. Liquid impermeable seal 44 is preferably disposed laterally inwardly as close as possible to perimeter 40 so mat a greater portion of border segment 42 remains dry and unsoiled. Seal 44, in its preferred application, completely surrounds perimeter 40 wid out any gaps which would allow wicking and fluid leakage. In this most preferred application, die improved seal 44 of the present invention is specifically directed to inhibiting wicking of fluid mrough liquid permeable second topsheet layer 14 which is sandwiched between first topsheet layer 12 and backsheet 18 in border segment 42.
Seal 44 is preferably formed by die simultaneous application of pressure, with or without heat, commonly referred to as a "crimping" operation. Referring to Figure 3, an upper and lower crimp tool 46 and 48 are shown for concurrently compressing first and second topsheet layers 12 and 14 and backsheet 18. Tools 46 and 48 should be wide enough so as not to cut, mar or tear first topsheet layer 12 or backsheet 18. During the "crimping" process, sufficient pressure, possibly with heat, is transferred via crimping tools 46 and 48 to melt first topsheet layer 12 and backsheet 18, thereby forming a solid yet flexible liquid impermeable seal 44. Thus, die pressure crushes second topsheet layer 14 to at least partially fill the remaining capillary spaces therein. First topsheet layer 12 and backsheet 18 melt around the material of second topsheet layer 14 creating a barrier for inhibiting wicking dierethrough. The portions of the border outside of seal 44 are crimped widi discrete spaced-apart bonds. This discrete bonding creates a reverse or negative capillary gradient, whereby any liquids inadvertently passing dirough seal 44 will tend to be attracted toward the more dense material in die seal 44 area, so any liquid movement outside seal 44 occurs along seal 44, as opposed to toward outer edge of border 42.
In an alternative embodiment of e present invention, second topsheet layer 14 is formed of hydrophilic non-woven or apertured polyethylene film having a lower melting temperature than first topsheet layer 12 and backsheet 18. Upon the application of localized pressure, during die "crimping" process, with or without heat, polyethylene second topsheet layer 14 will melt before first topsheet layer 12 and backsheet 18 and will propagate and mingle widi die material of first topsheet layer 12 and backsheet 18, thus forming a liquid impermeable seal 44 which appears similar on a macroscopic level to the seal formed by the first preferred embodiment of the present invention, in which first topsheet layer 12 and backsheet 18 melt prior to second topsheet layer 14. The crimping process may be varied to cause first and second topsheet layers 12 and 14, as well as backsheet 18, to melt to form seal 44.
A second alternative embodiment of die present invention is shown in Figures 4 and 5, which depict a catamenial pad 50 generally similar to catamenial pad 10 of Figures 1 through 3. For purposes of clarity, like reference numerals are used to designate those elements of catamenial pad 50 mat are similar to, or identical with, the above-noted elements of catamenial pad 10. Pad 50 has a first or inner liquid impermeable seal 52 which is disposed as close as possible to perimeter 40 of absorbent core 16 and surrounds perimeter 40. In addition, catamenial pad 50 is also provided wid a second or outer seal 54 for providing additional resistance against wicking of liquid diat enters border segment 42 beyond first seal 52. The present invention contemplates the possibility of using three or even more seals. As with the preferred embodiments shown in Figures 1 dirough 3, second topsheet layer 12 may be formed preferably of hydrophobic polypropylene which is treated with wetting agents to become hydrophilic, or alternatively can be formed of hydrophilic non-woven or apertured polyethylene. Accordingly, first and second seals 52 and 54 will be formed by the melting of first topsheet layer 12 and backsheet 18 widi the preferred selection of polypropylene for second topsheet layer 14, or in die alternative, seals 52 and 54 will be formed by die melting of second topsheet layer 14 in d e case of selection of hydrophilic polyediylene for second topsheet layer 14.
Another alternative embodiment of the present invention is depicted in Figures 6 and 7, in which a catamenial pad 56 is constructed substantially similar to catamenial pad 50 shown in Figures 4 and 5, and includes a first or inner seal 52 and a second or outer seal 58. In this embodiment, outer seal 58 is disposed at die laterally outermost edge of border segment 42 defined by first and second topsheet layers 12 and 14, as well as backsheet 18. The alternative embodiments of the present invention provide for selectively positioning various liquid impervious seals in order to maximize their effectiveness while maintaining comfort and preventing irritation to the wearer.
Yet another alternative embodiment of die present invention is depicted in Figure 8. Catamenial pad 62 is formed generally similar to pad 10, and has an anterior portion 64, posterior portion 66, and first and second sides edges 68 and 70. Liquid impermeable seals 72 and 74 are similar to seal 44, but extend only along side edges 68 and 70. It has been found that seals 68 and 70 may be more easily manufactured than seal 44, which completely surrounds core 16.
It should be understood that an unlimited number of configurations of the present invention can be realized. The foregoing discussion discloses and describes merely exemplary embodiments of the present invention. One skilled in die art will readily recognize from the discussion and from the accompanying drawings and claims mat various changes and modifications can be made wi out departing from die spirit and scope of the invention, as defined in d e following claims.

Claims

What is claimed is:
1. An absorbent article for absorbing liquids, comprising a first liquid permeable topsheet layer, a second liquid permeable topsheet layer, a liquid impermeable backsheet, an absorbent core having a perimeter and being disposed between said backsheet and said second topsheet layer, said second topsheet layer being disposed between said absorbent core and said first topsheet layer, wherein said first topsheet layer, second topsheet layer and backsheet each extend laterally beyond the perimeter of said absorbent core to define a continuous border segment surrounding said absorbent core, said absorbent article being characterized in that it comprises
a liquid impermeable seal formed in said border segment and surrounding a portion of said perimeter of said absorbent core, said seal extending from an outer surface of said first topsheet layer to an outer surface of said backsheet, wherein said seal is adapted to prevent migration of liquid from said absorbent core laterally outward beyond said seal.
2. The absorbent article of Claim 1 wherein said liquid impermeable seal comprises a first liquid impermeable seal and said absorbent article further comprises a second liquid impermeable seal surrounding and being spaced apart from said first liquid impermeable seal.
3. The absorbent article of Claim 1 wherein a portion of at least one of said first topsheet layer, said second topsheet layer, and said backsheet are melted to form said seal.
4. The absorbent article of claim 1 wherein said first topsheet layer, second topsheet layer and backsheet each extend laterally beyond said seal.
5. The absorbent article of Claim 2 wherein said second seal is disposed at an outer lateral edge of said border.
6. The absorbent article of Claim 1 wherein said seal is formed closer to said perimeter of said absorbent core than to an outer lateral edge of said border.
7. The absorbent article of Claim 1 wherein said seal is formed by applying localized pressure or by simultaneously applying pressure and heat during a crimping operation.
8. The absorbent article of Claim 1 wherein at least one of said first topsheet layer and said second topsheet layer is formed of a material treated by a process to become hydrophilic.
9. The absorbent article of Claim 1 wherein said absorbent core comprises a plurality of absorbent particles, and said second topsheet layer tends to prevent escape of said absorbent particles from within said article.
10. The absorbent article of Claim 1 wherein said absorbent article has an anterior portion, a posterior portion, a first and second side edge, and said seal extends along said first and second side edges.
PCT/US1994/004657 1993-05-21 1994-04-28 Absorbent article having anti-wicking crimp seal WO1994027539A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP7500640A JPH08510665A (en) 1993-05-21 1994-04-28 Absorbent article having crimped joint for preventing seepage of stain
EP94915921A EP0699063A1 (en) 1993-05-21 1994-04-28 Absorbent article having anti-wicking crimp seal
NZ266321A NZ266321A (en) 1993-05-21 1994-04-28 Absorbent article with a liquid-impermeable seal surrounding the absorbent core
AU67763/94A AU6776394A (en) 1993-05-21 1994-04-28 Absorbent article having anti-wicking crimp seal

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6587693A 1993-05-21 1993-05-21
US08/065,876 1993-05-21

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WO1994027539A1 true WO1994027539A1 (en) 1994-12-08

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EP (1) EP0699063A1 (en)
JP (1) JPH08510665A (en)
AU (1) AU6776394A (en)
CA (1) CA2163194A1 (en)
NZ (1) NZ266321A (en)
WO (1) WO1994027539A1 (en)

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US9233185B2 (en) 2012-03-30 2016-01-12 Unicharm Corporation Absorbent article
US9301885B2 (en) 2011-04-28 2016-04-05 Unicharm Corporation Absorbent article
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US20030163104A1 (en) * 2002-02-22 2003-08-28 Kimberly-Clark Worldwide, Inc. Method of securing an abosrbent article to a primary absorbent undergarment
US6934969B2 (en) * 2002-12-27 2005-08-30 Kimberly-Clark Worldwide, Inc. Anti-wicking protective workwear and methods of making and using same
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US7155746B2 (en) 2002-12-27 2007-01-02 Kimberly-Clark Worldwide, Inc. Anti-wicking protective workwear and methods of making and using same
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US8383875B2 (en) 2007-08-30 2013-02-26 Kimberly-Clark Worldwide, Inc. Wetness indicator with hydrophanous element for an absorbent article
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US10543132B2 (en) 2011-03-31 2020-01-28 Unicharm Corporation Absorbent article with blood modifying agent
US9301885B2 (en) 2011-04-28 2016-04-05 Unicharm Corporation Absorbent article
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US10278873B2 (en) 2011-12-28 2019-05-07 Unicharm Corporation Absorbent article having a domed section and method of manufacturing same
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NZ266321A (en) 1997-11-24
USH1746H (en) 1998-08-04
AU6776394A (en) 1994-12-20
JPH08510665A (en) 1996-11-12
CA2163194A1 (en) 1994-12-08
EP0699063A1 (en) 1996-03-06

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