WO1995013149A1 - Slab caster and inline strip and plate apparatus - Google Patents

Slab caster and inline strip and plate apparatus Download PDF

Info

Publication number
WO1995013149A1
WO1995013149A1 PCT/US1994/012997 US9412997W WO9513149A1 WO 1995013149 A1 WO1995013149 A1 WO 1995013149A1 US 9412997 W US9412997 W US 9412997W WO 9513149 A1 WO9513149 A1 WO 9513149A1
Authority
WO
WIPO (PCT)
Prior art keywords
slab
mill
plate
inline
inches
Prior art date
Application number
PCT/US1994/012997
Other languages
French (fr)
Inventor
Milan Kosanovich
Original Assignee
Milan Kosanovich
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Milan Kosanovich filed Critical Milan Kosanovich
Priority to AU12549/95A priority Critical patent/AU1254995A/en
Publication of WO1995013149A1 publication Critical patent/WO1995013149A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/46Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
    • B21B1/466Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting in a non-continuous process, i.e. the cast being cut before rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/30Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a non-continuous process
    • B21B1/32Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a non-continuous process in reversing single stand mills, e.g. with intermediate storage reels for accumulating work
    • B21B1/34Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a non-continuous process in reversing single stand mills, e.g. with intermediate storage reels for accumulating work by hot-rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0081Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/54Furnaces for treating strips or wire
    • C21D9/68Furnace coilers; Hot coilers

Definitions

  • This invention relates to the continuous casting and rolling of slabs and more particularly to an
  • the typical multistand hot strip mill likewise requires a substantive amount of work in a short time which must be provided for by larger horsepower rolling stands which, in some cases, can exceed the energy capabilities of a given area, particularly in the case of emerging countries.
  • Thin slab casters likewise are limited as to product width because of the inability to use vertical edgers on a 2 inch slab. In addition, such casters are currently limited to a single width.
  • this thin strip process can only operate in a continuous manner, which means that a breakdown anywhere in the process stops the entire line often causing scrapping of the entire product then being processed.
  • Our invention provides for a versatile integrated caster and mini-mill capable of producing on the order of 650,000 finished tons a year and higher. Such a facility can produce product 24" to 120" wide and can routinely produce a product of 800 PIW with 1000 PIW being possible. This is accomplished using a casting facility having a fixed and adjustable width mold with a straight rectangular cross section without the trumpet type mold.
  • the caster has a mold which contains enough liquid volume to provide sufficient time to make flying tundish changes, thereby not limiting the -caster run to a single tundish life.
  • Our invention provides a slab approximately twice as thick as the thin cast slab thereby losing much less heat and requiring a lesser input of BTU' s of energy.
  • Our invention provides a slab having a lesser scale loss due to reduced surface area per volume and permits the use of a reheat or equalizing furnace with minimal maintenance required. Further, our invention provides a caster which can operate at
  • Our invention has the ability to separate the casting from the rolling if there is a delay in either end.
  • our invention provides for the easy removal of transitional slabs formed when molten metal chemistry changes or width changes are made in the caster.
  • Our invention provides an intermediate thickness slab caster integrated with a hot strip and plate line which includes a reheat or equalizing furnace capable of receiving slabs directly from the caster from a slab collection and storage area positioned adjacent the slab conveyor table exiting the continuous caster or from another area.
  • a feed and run-out table is positioned at the exit end of the reheat furnace and inline with a hot reversing mill having a coiler furnace positioned on either side thereof.
  • the mill must have the capability of reducing the cast slab to a thickness of about 1 inch or less in 3 f lat passes .
  • the combination coil , coiled plate , sheet in coil form or discrete plate f inishing line extends inline and downstream of the hot reversing mill with its integral coiler furnaces .
  • the finishing facilities include a cooling station , a down coiler , a plate table , a shear , a cooling bed crossover , a plate side and end shear and a piler .
  • slabs having a thickness between 3.5 inches to 5.5 inches, preferably between 3.75 inches to 4.5 inches, and most preferably to about 4 inches.
  • the slabs are reduced to about 1 inch or less in 3 flat passes on the hot reversing mill before starting the coiling of the intermediate product between the coiler furnaces as it is further reduced to the desired
  • slab width may vary from 24 to 120 inches.
  • a preferred method of operation includes feeding sheared or torch cut slab from the caster onto a slab table which either feeds directly into a reheat or equalizing furnace or into a slab collection and storage area adjacent to the slab table.
  • the preferred method further includes feeding the slab directly into the furnace from the slab table.
  • the method allows for the feeding of a previously collected and stored slab into the furnace for further processing.
  • Figure 1 is a schematic of the prior art thin strip caster and continuous hot mill
  • Figure 2 is a schematic illustrating the
  • Figure 3 is a time-temperature graph for a two inch thick slab from solidification to rolling
  • Figure 4 is a time-temperature graph for a four inch thick slab from solidification to rolling.
  • Figure 5 is a bar chart comprising the peak power demands of the subject invention to a thin strip caster and continuous rolling mill.
  • Figure 6-8 are schematics illustrating the
  • the slab caster 10 consists of a curved trumpet mold 12 into which molten metal is fed through entry end 14. An electric furnace, the ladle station and the tundish (not shown) which feeds the continuous caster 10 are also conventional.
  • the slab caster 10 casts a strand on the order of 2 inches or less which is cut into slabs of appropriate length by a shear or a torch cut 16 which is spaced an appropriate distance from the curved mold 12 to assure proper solidification before shearing.
  • the thin slab then enters an elongated tunnel furnace 18 where the appropriate amount of thermal input takes place to insure that the slab is at the appropriate temperature throughout its mass for introduction into the continuous hot strip 20 located downstream of the tunnel furnace.
  • the typical continuous hot strip 20 includes five roll stands 21 each consisting of a pair of work rolls 23 and a pair of backup rolls 24. Roll stands 21 are spaced and synchronized to continuously work the slab through all five roll stands.
  • resultant strip of the desired thickness is coiled on a downcoiler 22 and is thereafter further processed into the desired finished steel mill product.
  • the thin strip caster and continuous hot strip mill enjoy many advantages but have certain fundamental disadvantages, such as no room for error in that the continuous hot strip mill is directly integrated with the caster with no buffer therebetween to accommodate for operating problems in either the caster or the continuous hot strip mill.
  • thermal decay is substantially greater for a two inch slab as compared to a four inch slab. This then requires a long tunnel furnace for the two inch slab to assure the appropriate rolling
  • Such a furnace must provide the heat energy of approximately 120,000 BTU per ton to bring the steel up to a mean body temperature of 2000°F for hot rolling and in addition, provide additional energy to establish the necessary heat gradient required to drive the heat energy into the slab in the time dictated by the two inch caster/rolling mill process.
  • mill scale is detrimental to the quality of the finished sheet and most difficult to remove prior to rolling.
  • mill scale is rolled into the slab by the multistand continuous mill.
  • mill scale can be removed by the aggressive application of high pressure water sprays.
  • high pressure water sprays With the two inch thick slab, such sprays will tend to quench the steel to an unacceptable temperature for rolling defeating the reheating process.
  • the four inch slab is, of course, one half the length and has one half of the exposed surface and accordingly less of a build-up of scale. Further, this scale can be easily removed by the high pressure water sprays without affecting the slab temperature due to the reservoir of heat energy inside the four inch slab as discussed hereinafter.
  • the time required to do this is determined by the square of the distance the heat must diffuse (at most, half the slab thickness) and the thermal diffusivity of the solidified mass. Because the mean body temperature before equalization was 2300°F and the mean body temperature after equalization need only be 2000°F to permit the steel to be hot rolled, there is an excess enthalpy of about 120,000 BTU's per ton of steel. This heat energy can be used to maintain the integrity of the isothermal enclosure, that is, compensate for losses associated with establishing the isothermal environment within the enclosure and accordingly, little or no external heating of the enclosure is required.
  • Figure 5 illustrates this point by comparing the peak power surges (19,000 kilowatts) of the
  • Figure 5 illustrates four coils being rolled from a two inch slab at the high peak loads on a four stand
  • finishing mill in about the same time it takes to roll two coils from a four inch slab at the lower peak loads on the hot reversing mill in nine passes each.
  • This invention is directed to solving this problem, by providing emerging countries with a low capital cost productive mini-mill steel plant compatible with their present power systems and existing infrastructure. Even in sophisticated systems where demand gets averaged over say 15 minute intervals, the demand for a four or five stand continuous finishing mill receiving a two inch slab is still substantially greater than for a hot reversing mill receiving a four inch slab.
  • the intermediate thickness slab caster and inline hot strip and plate line of the present invention is illustrated in Figure 2.
  • One or more electric melting furnaces 26 provide the molten metal at the entry end of our combination caster and strip and plate line 25.
  • the molten metal is fed into a ladle furnace 28 prior to being fed into the caster 30.
  • the caster 30 feeds into a mold (curved or straight) 32 of rectangular cross section.
  • a torch cutoff (or shear) 34 is positioned at the exit end of the mold 32 to cut the strand of now
  • solidified metal into a 3.5 to 5.5 inch thick slab of the desired length which also has a width of 24 to 120 inches.
  • the slab then feeds on a table conveyor 36 to a slab takeoff area where it is directly charged into a furnace 42 or is removed from the inline processing and stored in a slab collection and storage area 40.
  • the preferred furnace is of the walking beam type although a roller hearth furnace could also be utilized in certain applications.
  • Full size slabs 44 and discrete length slabs 46 for certain plate products are shown within walking beam furnace 42.
  • Slabs 38 which are located in the slab collection and storage area 40 may also be fed into the furnace 42 by means of slab pushers 48 or charging arm devices located for indirect charging of walking beam furnace 42 with slabs 38. It is also possible to charge slabs from other slab yards or storage areas.
  • the various slabs are fed through the furnace 42 in conventional manner and are removed by slab extractors 50 and placed on a feed and run back table 52.
  • Descaler 53 and/or a vertical edger 54 can be utilized on the slabs.
  • a vertical edger normally could not be used with a slab of only 2 inches or less.
  • Cooling station 62 Downstream of feed and run back table 52 and vertical edger 54 is a hot reversing mill 56 having an upstream and a downstream coiler furnace 58 and 60, respectively.
  • Cooling station 62 is downstream of coiler furnace 60. Downstream of cooling station 62 is a coiler 66 operated in conjunction with a coil car 67 followed by a plate table 64 operated in conjunction with a shear 68.
  • the final product is either coiled on coiler 66 and removed by coil car 67 as sheet in strip or coil plate form or is sheared into plate form for further processing inline.
  • a plate product is
  • the final processing line 71 includes a plate side shear 72, plate end shear 74 and plate piler 76.
  • the advantages of the subject invention come about as the result of the operating parameters employed.
  • the cast strand should have a thickness between 3.5 inches to 5.5 inches, preferably between 3.75 inches to 4.5 inches and most preferably to about 4 inches thick.
  • the width can generally vary between 24 inches and 100 inches to produce a product up to 1000 PIW and higher.
  • the slab after leaving walking beam furnace 42 is flat passed back and forth through hot reversing mill 56 in no more than three passes achieving a slab thickness of about 1 inch or less.
  • the intermediate product is then coiled in the appropriate coiler furnace, which in the case of three flat passes would be downstream coiler furnace 60. Thereafter, the intermediate product is passed back and forth through hot reversing mill 56 and between the coiler furnaces to achieve the desired thickness for the sheet in coil form, the coil plate or the plate product.
  • the number of passes to achieve the final product thickness may vary but normally may be done in nine passes which include the initial flat passes.
  • the strip of the desired thickness is rolled in the hot reversing mill and continues through the cooling station 62 where it is appropriately cooled for coiling on a coiler 66 or for entry onto a plate table 64. If the product is to be sheet or plate in coil form, it is coiled on coiler 66 and removed by coil car 67. If it is to go directly into plate form, it enters plate table 64 where it is sheared by shear 68 to the appropriate length. The plate thereafter enters a transfer table 70 which acts as a cooling bed so that the plate may be finished on finishing line 71 which includes descaler 73, side shear 72, end shear 74 and piler 76.
  • a 74 inch wide x .100 inch thick sheet in coil form is produced from a 4 inch slab of low carbon steel in accordance with the following rolling schedule:
  • a 52 inch wide x . 100 inch thick sheet in coil form is produced from a 4 inch slab of low carbon steel in accordance with the following rolling schedule :
  • a 98 inch wide x nominal .187 inch thick coil plate is produced from a 4 inch slab of low carbon steel to an actual thickness of .177 inch in accordance with the following rolling schedule:
  • An 84 inch wide x .140 inch thick coil plate is produced from a 4 inch slab of low carbon steel in accordance with he following rolling schedule:
  • the intermediate thickness continuous caser and hot strip and plate line provide many of the advantages of the thin strip caster without the disadvantages.
  • the basic design of the facility can be predicated on rolling 150 tons per hour on the rolling mill.
  • the market demand will obviously dictate the product mix, but for purposes of calculating the required caser speeds to achieve 150 tons per hour of rolling, one can assume the bulk of the product mix will be between 36 inches and 72 inches.
  • a 72 inch slab rolled at 150 tons per hour would require a casting speed of 61 inches per minute. At 60 inches of width, the casting speed increases to 73.2 inches per minute; at 48 inches, the casting speed increases to 91.5 inches per minute; and at 36 inches of width, the casting speed increases to 122 inches per minute. All of these speeds are within acceptable casting speeds.
  • the annual design tonnage can be based on 50 weeks of operation per year at 8 hours a turn and 15 turns per week for 6000 hours per year of available operating time assuming that 75% of the available operating time is utilized and assuming a 96% yield through the operating facility, the annual design tonnage will be

Abstract

A method and apparatus of making coiled plate, sheet in coiled form or discrete plate. The apparatus includes a continuous strip caster (25) forming a strand between 3.5 and 5.5 inches thick; a shear (34) for cutting the strand into a slab; a slab conveyor table (32) including a slab takeoff (40) operable transverse of the slab conveyor table (32); a slab collection and storage area (42) adjacent to the slab conveyor table (32) adapted to receive slabs from the slab takeoff (36); a reheat furnace (62) having an entry inline with both the slab conveyor table (32) and the slab collection and storage area (42) for receiving slabs from either; a feed and run back table (64) at the exit of the reheat furnace (62); a hot reversing mill (71) for reducing the slab to a thickness of 1 inch or less in no more than three flat passes; a pair of coiler furnaces (73, 74) located on opposite sides of the hot reversing mill; and a finishing line (76) downstream of the pair of coiler furnaces (73, 74).

Description

SLAB CASTER AND INLINE STRIP AND PLATE APPARATUS
Field of the Invention
This invention relates to the continuous casting and rolling of slabs and more particularly to an
integrated intermediate thickness caster and a hot reversing mill.
Background of the Invention
Since the advent of the continuous casting of slabs in the steel industry, companies have been trying to marry the hot strip mill to the continuous caster through an inline arrangement so as to maximize
production capability and minimize the equipment and capital investment required. The initial efforts in this regard consisted of integrating continuous casters producing slabs on the order of 6 inches to 10 inches with existing continuous or semi-continuous hot strip mills. These existing hot strip mills included a reheat furnace, a roughing train (or a reversing rougher) and a six or seven stand finishing mill with a capacity of 1- 1/2 to 5 million tons per year. This mill arrangement is the present day design of large steel company mills and it is unlikely that new hot strip mills of this design would ever be built due to the high capital cost. However, the quest for low cost integrated caster-hot strip mills is not solved by current designs. Further, such prior art integrated mills were extremely
inflexible as to product mix and thus market
requirements.
These difficulties gave rise to the development of the so-called thin slab continuous hot strip mill which typically produces 1,000,000 tons of steel per year as specialized products. These mills have been integrated with thin slab casters on the order of 2 inches or less. Such integrated thin slab casters are enjoying increased popularity but are not without serious drawbacks of their own. Significant drawbacks include the quality and quantity limitations associated with the so-called thin slab casters. Specifically, the trumpet type mold necessary to provide the metal for the thin slab can cause high frictional forces and stresses along the surface of the thin wall slab which leads to poor surface quality in the finished product. Further, the 2 inch strip casters are limited to a single tundish life of approximately 7 heats because of the limited metal capacity of the mold.
Most importantly, the thin casters by necessity have to cast at high speeds to prevent the metal from freezing in the current ladle arrangements. This, in turn, requires the tunnel furnace which is just
downstream of the slab caster to be extremely long, often on the order of 500 feet, to accommodate the speed of the slab and still be able to provide the heat input to a thin slab (2 inches) which loses heat at a very high rate. Since the slab also leaves the furnace at a high speed, one needs the multistand continuous hot strip mill to accommodate the rapidly moving strip and roll it to sheet and strip thicknesses. However, such a system is still unbalanced at normal widths since the caster has a capacity of about 800,000 tons per year and the continuous mill has a capacity of 2.4 million tons/year. The capital cost then approaches that of the earlier prior art systems that it was intended to replace.
In addition, the scale loss as a percentage of slab thickness is substantial for the 2 inch thin cast slab.
Because of the extremely large furnace, one must provide a long roller hearth which becomes very maintenance intensive because of the exposed rotating rollers.
The typical multistand hot strip mill likewise requires a substantive amount of work in a short time which must be provided for by larger horsepower rolling stands which, in some cases, can exceed the energy capabilities of a given area, particularly in the case of emerging countries. Thin slab casters likewise are limited as to product width because of the inability to use vertical edgers on a 2 inch slab. In addition, such casters are currently limited to a single width.
Further problems associated with the thin strip casters include the problems associated with keeping the various inclusions formed during steelmaking away from he surface of the thin slab where such inclusions can lead to surface defects if exposed. In addition, existing systems are limited in scale removal because thin slabs lose heat rapidly and are thus adversely effective by the high pressure water normally used to break up the scale.
In addition, this thin strip process can only operate in a continuous manner, which means that a breakdown anywhere in the process stops the entire line often causing scrapping of the entire product then being processed.
It is an object of our invention to integrate an intermediate thickness slab caster with a hot reversing mill. It is a further object to adopt a system which balances the rate of the caster to the rate of the rolling mill. It is also an object of our invention to adopt a system using less thermal and electrical energy. It is still a further object to adopt an automated system with small capital investment, reasonable floor space requirements, reasonably powered rolling equipment and low operating costs.
Summary of the Invention
Our invention provides for a versatile integrated caster and mini-mill capable of producing on the order of 650,000 finished tons a year and higher. Such a facility can produce product 24" to 120" wide and can routinely produce a product of 800 PIW with 1000 PIW being possible. This is accomplished using a casting facility having a fixed and adjustable width mold with a straight rectangular cross section without the trumpet type mold. The caster has a mold which contains enough liquid volume to provide sufficient time to make flying tundish changes, thereby not limiting the -caster run to a single tundish life. Our invention provides a slab approximately twice as thick as the thin cast slab thereby losing much less heat and requiring a lesser input of BTU' s of energy. Our invention provides a slab having a lesser scale loss due to reduced surface area per volume and permits the use of a reheat or equalizing furnace with minimal maintenance required. Further, our invention provides a caster which can operate at
conventional caster speeds and conventional descaling techniques. Our invention provides for the selection of the optimum thickness cast slab to be used in
conjunction with a hot reversing mill providing a balanced production capability. Our invention has the ability to separate the casting from the rolling if there is a delay in either end. In addition, our invention provides for the easy removal of transitional slabs formed when molten metal chemistry changes or width changes are made in the caster.
All of the above advantages are realized while maintaining the advantages of a thin caster which include low ferrostatic head, low weight of slab, straight molds, shorter length molds, smaller required mold radius, low cooling requirements, low burning costs or shear capacity, and simplified machine constructions.
Our invention provides an intermediate thickness slab caster integrated with a hot strip and plate line which includes a reheat or equalizing furnace capable of receiving slabs directly from the caster from a slab collection and storage area positioned adjacent the slab conveyor table exiting the continuous caster or from another area. A feed and run-out table is positioned at the exit end of the reheat furnace and inline with a hot reversing mill having a coiler furnace positioned on either side thereof. The mill must have the capability of reducing the cast slab to a thickness of about 1 inch or less in 3 f lat passes . The combination coil , coiled plate , sheet in coil form or discrete plate f inishing line extends inline and downstream of the hot reversing mill with its integral coiler furnaces . The finishing facilities include a cooling station , a down coiler , a plate table , a shear , a cooling bed crossover , a plate side and end shear and a piler .
To achieve the necessary balance between the hot reversing mill and the caster , it is necessary to produce slabs having a thickness between 3.5 inches to 5.5 inches, preferably between 3.75 inches to 4.5 inches, and most preferably to about 4 inches. The slabs are reduced to about 1 inch or less in 3 flat passes on the hot reversing mill before starting the coiling of the intermediate product between the coiler furnaces as it is further reduced to the desired
finished product thickness. In order to provide the capability of making coiled plate, discrete plate and sheet in coil form up to 1000 PIW and higher, slab width may vary from 24 to 120 inches.
A preferred method of operation includes feeding sheared or torch cut slab from the caster onto a slab table which either feeds directly into a reheat or equalizing furnace or into a slab collection and storage area adjacent to the slab table. The preferred method further includes feeding the slab directly into the furnace from the slab table. However, the method allows for the feeding of a previously collected and stored slab into the furnace for further processing. Brief Description of the Drawings
Figure 1 is a schematic of the prior art thin strip caster and continuous hot mill; Figure 2 is a schematic illustrating the
intermediate thickness strip caster and inline hot reversing mill and coiler furnace arrangement;
Figure 3 is a time-temperature graph for a two inch thick slab from solidification to rolling;
Figure 4 is a time-temperature graph for a four inch thick slab from solidification to rolling; and
Figure 5 is a bar chart comprising the peak power demands of the subject invention to a thin strip caster and continuous rolling mill.
Figure 6-8 are schematics illustrating the
steelmaking facilities useful in the methods of the invention. Description of the Preferred Embodiment
The prior art thin strip caster and inline
continuous hot strip mill is illustrated in Figure 1. The slab caster 10 consists of a curved trumpet mold 12 into which molten metal is fed through entry end 14. An electric furnace, the ladle station and the tundish (not shown) which feeds the continuous caster 10 are also conventional. The slab caster 10 casts a strand on the order of 2 inches or less which is cut into slabs of appropriate length by a shear or a torch cut 16 which is spaced an appropriate distance from the curved mold 12 to assure proper solidification before shearing. The thin slab then enters an elongated tunnel furnace 18 where the appropriate amount of thermal input takes place to insure that the slab is at the appropriate temperature throughout its mass for introduction into the continuous hot strip 20 located downstream of the tunnel furnace. The typical continuous hot strip 20 includes five roll stands 21 each consisting of a pair of work rolls 23 and a pair of backup rolls 24. Roll stands 21 are spaced and synchronized to continuously work the slab through all five roll stands. The
resultant strip of the desired thickness is coiled on a downcoiler 22 and is thereafter further processed into the desired finished steel mill product.
The thin strip caster and continuous hot strip mill enjoy many advantages but have certain fundamental disadvantages, such as no room for error in that the continuous hot strip mill is directly integrated with the caster with no buffer therebetween to accommodate for operating problems in either the caster or the continuous hot strip mill.
In addition, the thermal decay is substantially greater for a two inch slab as compared to a four inch slab. This then requires a long tunnel furnace for the two inch slab to assure the appropriate rolling
temperature. This is illustrated in Figure 3 wherein the energy requirements expressed through a temperature-time curve for a two inch slab is illustrated. With a two inch thick cast slab, the mean body temperature of the as-cast slab is only 150°F, which is too low a temperature to begin hot rolling . Since there is virtually no reservoir of thermal energy in the center of the slab due to its thin thickness , additional heat energy is required to attain the required mean body temperature of 2000 °F for hot rolling . Accordingly, since the thin slab is approximately 150 ft . long, it generally is heated in a long tunnel furnace. Such a furnace must provide the heat energy of approximately 120,000 BTU per ton to bring the steel up to a mean body temperature of 2000°F for hot rolling and in addition, provide additional energy to establish the necessary heat gradient required to drive the heat energy into the slab in the time dictated by the two inch caster/rolling mill process.
In addition, while the two inch thick slab is travelling slowly through the tunnel furnace, the atmosphere of the furnace is forming "mill scale" on the exposed surface of the thin slab. This mill scale is detrimental to the quality of the finished sheet and most difficult to remove prior to rolling. Often the mill scale is rolled into the slab by the multistand continuous mill. Ordinarily, mill scale can be removed by the aggressive application of high pressure water sprays. However, with the two inch thick slab, such sprays will tend to quench the steel to an unacceptable temperature for rolling defeating the reheating process. On the other hand, the four inch slab is, of course, one half the length and has one half of the exposed surface and accordingly less of a build-up of scale. Further, this scale can be easily removed by the high pressure water sprays without affecting the slab temperature due to the reservoir of heat energy inside the four inch slab as discussed hereinafter.
As with the two inch thick slab, during the casting process external cooling is used to create a solid shell to contain the liquid core, which is essentially at the tundish temperature of 2800°F. As the shell builds up, the liquid core is consumed and the slab becomes solid through its thickness. This established the
metallurgical length of the caster. For a four inch slab, there is a temperature gradient from the center of the slab (2800° to 2600°F) to the surface, with a mean temperature of 2300°F, see Figure 4. If the slab is now put into an isothermal enclosure, the high internal temperature gradient that was necessary to remove the solidification enthalpy, provides sufficient thermal energy to affect a mean slab body temperature of 2000°F. This equalization process, in the isothermal enclosure, is effected immediately after the cast slab has
solidified and is cut to length prior to the entry into the furnace.
The time required to do this is determined by the square of the distance the heat must diffuse (at most, half the slab thickness) and the thermal diffusivity of the solidified mass. Because the mean body temperature before equalization was 2300°F and the mean body temperature after equalization need only be 2000°F to permit the steel to be hot rolled, there is an excess enthalpy of about 120,000 BTU's per ton of steel. This heat energy can be used to maintain the integrity of the isothermal enclosure, that is, compensate for losses associated with establishing the isothermal environment within the enclosure and accordingly, little or no external heating of the enclosure is required.
One of the distinct advantages of this invention is the lower electric power costs of the subject invention as compared to the two inch thick caster/continuous rolling mill as previously described and similar
processes. Figure 5 illustrates this point by comparing the peak power surges (19,000 kilowatts) of the
multistand continuous rolling mill to the peak (9000 kilowatts) for the reversing mill of this invention. Since the power company's billing contract consists of two parts - "demand" and "consumed power", it is the "demand" portion that it the most costly when the process requires high peak loads over a short period of time. High demand equates to higher power costs.
Figure 5 illustrates four coils being rolled from a two inch slab at the high peak loads on a four stand
finishing mill in about the same time it takes to roll two coils from a four inch slab at the lower peak loads on the hot reversing mill in nine passes each.
Additionally, and perhaps of more importance, is the fact that many power companies cannot provide for the high peak loads, as illustrated in Figure 5, due to the limits of generator and line capacity. This is of particular concern to emerging countries where the power grids are weak and the transmission line are long.
This invention is directed to solving this problem, by providing emerging countries with a low capital cost productive mini-mill steel plant compatible with their present power systems and existing infrastructure. Even in sophisticated systems where demand gets averaged over say 15 minute intervals, the demand for a four or five stand continuous finishing mill receiving a two inch slab is still substantially greater than for a hot reversing mill receiving a four inch slab.
The intermediate thickness slab caster and inline hot strip and plate line of the present invention is illustrated in Figure 2. One or more electric melting furnaces 26 provide the molten metal at the entry end of our combination caster and strip and plate line 25. The molten metal is fed into a ladle furnace 28 prior to being fed into the caster 30. The caster 30 feeds into a mold (curved or straight) 32 of rectangular cross section.
A torch cutoff (or shear) 34 is positioned at the exit end of the mold 32 to cut the strand of now
solidified metal into a 3.5 to 5.5 inch thick slab of the desired length which also has a width of 24 to 120 inches.
The slab then feeds on a table conveyor 36 to a slab takeoff area where it is directly charged into a furnace 42 or is removed from the inline processing and stored in a slab collection and storage area 40. The preferred furnace is of the walking beam type although a roller hearth furnace could also be utilized in certain applications. Full size slabs 44 and discrete length slabs 46 for certain plate products are shown within walking beam furnace 42. Slabs 38 which are located in the slab collection and storage area 40 may also be fed into the furnace 42 by means of slab pushers 48 or charging arm devices located for indirect charging of walking beam furnace 42 with slabs 38. It is also possible to charge slabs from other slab yards or storage areas. Because the intermediate thickness slabs retain heat to a much greater extent than the thin slabs, temperature equalization is all that is required in many modes of operation. Of course, where slabs are introduced from off line locations, the furnace must have the capacity to add BTU' s to bring the slabs up to rolling temperatures.
The various slabs are fed through the furnace 42 in conventional manner and are removed by slab extractors 50 and placed on a feed and run back table 52. Descaler 53 and/or a vertical edger 54 can be utilized on the slabs. A vertical edger normally could not be used with a slab of only 2 inches or less.
Downstream of feed and run back table 52 and vertical edger 54 is a hot reversing mill 56 having an upstream and a downstream coiler furnace 58 and 60, respectively. Cooling station 62 is downstream of coiler furnace 60. Downstream of cooling station 62 is a coiler 66 operated in conjunction with a coil car 67 followed by a plate table 64 operated in conjunction with a shear 68. The final product is either coiled on coiler 66 and removed by coil car 67 as sheet in strip or coil plate form or is sheared into plate form for further processing inline. A plate product is
transferred by transfer table 70 which includes a cooling bed onto a final processing line 71. The final processing line 71 includes a plate side shear 72, plate end shear 74 and plate piler 76.
The advantages of the subject invention come about as the result of the operating parameters employed. The cast strand should have a thickness between 3.5 inches to 5.5 inches, preferably between 3.75 inches to 4.5 inches and most preferably to about 4 inches thick. The width can generally vary between 24 inches and 100 inches to produce a product up to 1000 PIW and higher.
The slab after leaving walking beam furnace 42 is flat passed back and forth through hot reversing mill 56 in no more than three passes achieving a slab thickness of about 1 inch or less. The intermediate product is then coiled in the appropriate coiler furnace, which in the case of three flat passes would be downstream coiler furnace 60. Thereafter, the intermediate product is passed back and forth through hot reversing mill 56 and between the coiler furnaces to achieve the desired thickness for the sheet in coil form, the coil plate or the plate product. The number of passes to achieve the final product thickness may vary but normally may be done in nine passes which include the initial flat passes. On the final pass, which normally originates from upstream coiler furnace 58, the strip of the desired thickness is rolled in the hot reversing mill and continues through the cooling station 62 where it is appropriately cooled for coiling on a coiler 66 or for entry onto a plate table 64. If the product is to be sheet or plate in coil form, it is coiled on coiler 66 and removed by coil car 67. If it is to go directly into plate form, it enters plate table 64 where it is sheared by shear 68 to the appropriate length. The plate thereafter enters a transfer table 70 which acts as a cooling bed so that the plate may be finished on finishing line 71 which includes descaler 73, side shear 72, end shear 74 and piler 76.
The following Examples illustrate the wide range of products that can be produced. It should be noted that the entry temperature into the rolling mill is
necessarily higher (2300°F) for the wider slabs than for the more narrow product widths (about 2000 °F) which more narrow widths in most facilities would represent the bulk of the product requirements. Example 1
A 74 inch wide x .100 inch thick sheet in coil form is produced from a 4 inch slab of low carbon steel in accordance with the following rolling schedule:
Figure imgf000015_0001
Example 2
A 52 inch wide x . 100 inch thick sheet in coil form is produced from a 4 inch slab of low carbon steel in accordance with the following rolling schedule :
Figure imgf000017_0001
Example 3
A 98 inch wide x nominal .187 inch thick coil plate is produced from a 4 inch slab of low carbon steel to an actual thickness of .177 inch in accordance with the following rolling schedule:
Figure imgf000019_0001
Example 4
An 84 inch wide x .140 inch thick coil plate is produced from a 4 inch slab of low carbon steel in accordance with he following rolling schedule:
Figure imgf000021_0001
The intermediate thickness continuous caser and hot strip and plate line provide many of the advantages of the thin strip caster without the disadvantages. The basic design of the facility can be predicated on rolling 150 tons per hour on the rolling mill. The market demand will obviously dictate the product mix, but for purposes of calculating the required caser speeds to achieve 150 tons per hour of rolling, one can assume the bulk of the product mix will be between 36 inches and 72 inches. A 72 inch slab rolled at 150 tons per hour would require a casting speed of 61 inches per minute. At 60 inches of width, the casting speed increases to 73.2 inches per minute; at 48 inches, the casting speed increases to 91.5 inches per minute; and at 36 inches of width, the casting speed increases to 122 inches per minute. All of these speeds are within acceptable casting speeds.
The annual design tonnage can be based on 50 weeks of operation per year at 8 hours a turn and 15 turns per week for 6000 hours per year of available operating time assuming that 75% of the available operating time is utilized and assuming a 96% yield through the operating facility, the annual design tonnage will be
approximately 650,000 finished tons.
Using the apparatus and methods of the paper:
Thinner Slab Casting having two parts, Part I: 4 Inch Slab Casting and Part II: Steckel Mill Rolling (which are expressly incorporated by reference herein for its teachings of the conditions and steps in casting and mill rolling), the data in Tables 5 and 6 reporting the results of steel working experiments of Examples 5 and 6 were produced.
Figure imgf000023_0001
Figure imgf000023_0002
Figure imgf000024_0001
Figure imgf000025_0002
Figure imgf000025_0001
Figure imgf000026_0002
Figure imgf000026_0001
Figure imgf000027_0001
Figure imgf000027_0002
Figure imgf000028_0001
Figure imgf000029_0001
Figure imgf000030_0001
Figure imgf000031_0001
Figure imgf000032_0001
Figure imgf000033_0001
Figure imgf000034_0001
Figure imgf000035_0001
Figure imgf000036_0002
Figure imgf000036_0003
Figure imgf000036_0001
Figure imgf000037_0001
Figure imgf000038_0002
Figure imgf000038_0001
Figure imgf000039_0002
Figure imgf000039_0001
Figure imgf000040_0002
Figure imgf000040_0003
Figure imgf000040_0001
Figure imgf000041_0001
Figure imgf000041_0002
Figure imgf000042_0001
Figure imgf000042_0002
Figure imgf000042_0003
Figure imgf000043_0001
Figure imgf000044_0001
Figure imgf000045_0002
Figure imgf000045_0001
Figure imgf000046_0001
Figure imgf000047_0002
Figure imgf000047_0001
Figure imgf000048_0001
Figure imgf000049_0001
Figure imgf000050_0001

Claims

WE CLAIM :
1. A method of making coiled plate, sheet in coil form or discrete plate comprising the steps of:
(a) continuously casting a strand having a thickness between 3.5 inches to 5.5 inches;
(b) shearing said strand into a slab of predetermined length;
(c) feeding the slab into an inline heating furnace;
(d) extracting said slab onto a continuous processing line including a hot reversing mill having a coiler furnace on each of an upstream side and downstream side thereof;
(e) flat passing said slab back and forth through said mill to form an intermediate product of about 1 inch or less in thickness after no more than three passes through the mill;
(f) passing said intermediate product through the mill to further reduce its thickness and coiling said intermediate product in one of said upstream or downstream coiler furnaces;
(g) passing said coiled intermediate product back and forth through said mill to reduce said coiled intermediate product to an end product of desired thickness, said intermediate product being collected in and fed out of each of said coiler furnaces on each pass through the mill; and
(h) finishing said end product into one of coiled plate, discrete plate or sheet in coil form.
2. The method of claim 1 further comprising the step of removing slabs from a slab takeoff located downstream of the caster and adjacent said heating furnace when delays are encountered downstream of the furnace and storing said slabs in a storage area
upstream of the furnace prior to charging said slabs into said furnace.
3. The method of claim 1 further comprising the step of passing said slab through a vertical edger prior to flat passing said slab.
4. The method of claim 1 including casting a strand to a thickness between 3.75 inches to 4.5 inches.
5. The method of claim 1 including casting a strand to a thickness of about 4 inches.
6. The method of claim 1 including reducing said intermediate product to said end product in six or less passes through said hot reversing mill.
7. The method of claim 1 wherein said finishing of said end product includes cooling said end product by passing it through an inline cooling station and
thereafter coiling it on an inline down coiler for removal as coiled plate or sheet in coil form.
8. The method of claim 1 wherein said finishing of said end product includes shearing inline to a plate of a discrete length, cooling said plate and finishing said plate through at least one of a side shear and end shear and a piler.
9. The method of claim 1 including casting a strand having a width between 24 inches and 120 inches.
10. An intermediate thickness slab caster and inline hot strip and plate line comprising:
(a) a continuous strip caster means for forming a strand of 3.5 inches to 5.5 inches thick;
(b) an inline shear downstream of said caster mans for cutting said strand to a slab of a desired length; (c) a slab conveyor table inline with said shear and including a slab takeoff operable transverse of said conveyor table;
(d) a slab collection and storage area adjacent the slab conveyor table adapted to receive slabs from said slab takeoff;
(e) a reheat furnace having an entry end inline with said slab conveyor table and said slab collection and storage area for receiving slabs from either;
(f) a feed and run back table positioned at an exit end of said reheat furnace;
(g) a hot reversing mill means inline with said feed and run back table for reducing said slab exiting the reheat furnace to an intermediate thickness product of 1 inch or less in no more than three flat passes;
(h) a pair of coiler furnaces, one located upstream of said hot reversing mill mans and the other located downstream, said coiler furnaces capable of receiving and paying out said
intermediate thickness product as it is passed between the coiler furnaces and through said hot reversing mill means so as to be reduced to an end product thickness; and
(i) a finishing line downstream of and inline with said pair of coiler furnaces and said hot reversing mill means.
11. The apparatus of claim 1 wherein said
finishing line includes in sequence a cooling station, a downcoiler, a plate table, a shear, a cooling bin crossover and plate side and end shears and a piler.
PCT/US1994/012997 1993-11-12 1994-11-10 Slab caster and inline strip and plate apparatus WO1995013149A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU12549/95A AU1254995A (en) 1993-11-12 1994-11-10 Slab caster and inline strip and plate apparatus

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15243693A 1993-11-12 1993-11-12
US08/152,436 1993-11-12

Publications (1)

Publication Number Publication Date
WO1995013149A1 true WO1995013149A1 (en) 1995-05-18

Family

ID=22542910

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1994/012997 WO1995013149A1 (en) 1993-11-12 1994-11-10 Slab caster and inline strip and plate apparatus

Country Status (2)

Country Link
AU (1) AU1254995A (en)
WO (1) WO1995013149A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996040456A1 (en) * 1995-06-07 1996-12-19 Ipsco Inc. Plant capacity optimizing method for use with steckel mill
US6264767B1 (en) 1995-06-07 2001-07-24 Ipsco Enterprises Inc. Method of producing martensite-or bainite-rich steel using steckel mill and controlled cooling
US6309482B1 (en) 1996-01-31 2001-10-30 Jonathan Dorricott Steckel mill/on-line controlled cooling combination
WO2018199187A1 (en) * 2017-04-25 2018-11-01 新日鐵住金株式会社 Scale composition determining system, scale composition determining method, and program
CN109858085A (en) * 2018-12-26 2019-06-07 钢铁研究总院 A kind of austenitizing measuring method in metal material heat treatment process
WO2019224305A1 (en) * 2018-05-23 2019-11-28 Sms Group Gmbh Casting-rolling system for batch and continuous operation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5156800A (en) * 1990-01-03 1992-10-20 Stein-Heurtey Installation for the thermal/treatment before rolling of thin slabs produced by continuous-casting
US5276952A (en) * 1992-05-12 1994-01-11 Tippins Incorporated Method and apparatus for intermediate thickness slab caster and inline hot strip and plate line

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5156800A (en) * 1990-01-03 1992-10-20 Stein-Heurtey Installation for the thermal/treatment before rolling of thin slabs produced by continuous-casting
US5276952A (en) * 1992-05-12 1994-01-11 Tippins Incorporated Method and apparatus for intermediate thickness slab caster and inline hot strip and plate line

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996040456A1 (en) * 1995-06-07 1996-12-19 Ipsco Inc. Plant capacity optimizing method for use with steckel mill
US5924318A (en) * 1995-06-07 1999-07-20 Ipsco Enterprises Inc. Plant capacity of optimizing method for use with Steckel mill
US6264767B1 (en) 1995-06-07 2001-07-24 Ipsco Enterprises Inc. Method of producing martensite-or bainite-rich steel using steckel mill and controlled cooling
US6309482B1 (en) 1996-01-31 2001-10-30 Jonathan Dorricott Steckel mill/on-line controlled cooling combination
WO2018199187A1 (en) * 2017-04-25 2018-11-01 新日鐵住金株式会社 Scale composition determining system, scale composition determining method, and program
JP6424998B1 (en) * 2017-04-25 2018-11-21 新日鐵住金株式会社 Scale composition determination system, scale composition determination method, and program
US11474032B2 (en) 2017-04-25 2022-10-18 Nippon Steel Corporation Scale composition determination system, scale composition determination method, and program
CN110312927A (en) * 2017-04-25 2019-10-08 日本制铁株式会社 Oxide skin forms decision-making system, oxide skin composition determination method and program
EP3617693A4 (en) * 2017-04-25 2021-01-27 Nippon Steel Corporation Scale composition determining system, scale composition determining method, and program
CN112218730A (en) * 2018-05-23 2021-01-12 西马克集团有限公司 Casting and rolling plant for batch and continuous operation
WO2019224305A1 (en) * 2018-05-23 2019-11-28 Sms Group Gmbh Casting-rolling system for batch and continuous operation
US20210121924A1 (en) * 2018-05-23 2021-04-29 Sms Group Gmbh Casting-rolling system for batch and continuous operation
CN112218730B (en) * 2018-05-23 2024-01-30 西马克集团有限公司 Casting and rolling plant for batch and continuous operation
CN109858085B (en) * 2018-12-26 2021-09-14 钢铁研究总院 Austenitization determination method in heat treatment process of metal material
CN109858085A (en) * 2018-12-26 2019-06-07 钢铁研究总院 A kind of austenitizing measuring method in metal material heat treatment process

Also Published As

Publication number Publication date
AU1254995A (en) 1995-05-29

Similar Documents

Publication Publication Date Title
EP0594828B1 (en) Method and apparatus for intermediate thickness slab caster and inline hot strip and plate line
WO1993023182A9 (en) Method and apparatus for intermediate thickness slab caster and inline hot strip and plate line
US5467519A (en) Intermediate thickness twin slab caster and inline hot strip and plate line
US5542165A (en) Line to produce strip and/or sheet
EP0726101A1 (en) Intermediate thickness and multiple furnace process line with slab storage and slab sequencing
EP0510147B1 (en) System and process for forming thin flat hot rolled steel strip
US4675974A (en) Method of continuous casting and rolling strip
US4630352A (en) Continuous rolling method and apparatus
RU2166387C2 (en) Line for making hot rolled steel band
US7152661B2 (en) Method and casting roller plant for the semi-endless or endlers rolling by casting of a metal in particular a steel strip which may be transversely separated as required after solidification
EP1117493B1 (en) Process and relative production line for the direct manufacture of finished pressed or deep drawn pieces from ultrathin hot rolled strip cast and rolled in-line
US6978531B1 (en) Method of manufacturing hot rolled steel sheet using mini mill process
US8322400B2 (en) Casting and continuous rolling method and plant to make long metal rolled products
US5544408A (en) Intermediate thickness slab caster and inline hot strip and plate line with slab sequencing
JPH044041B2 (en)
US5511303A (en) Intermediate thickness and multiple furnace process line
WO1995013149A1 (en) Slab caster and inline strip and plate apparatus
US5533248A (en) Method of steel processing using an inline grinder
US5579569A (en) Slab container
AU658993B2 (en) Method and apparatus for intermediate thickness slab caster and in-line hot strip and plate line
US9126263B2 (en) CSP-continuous casting plant with an additional rolling line
RU2491140C2 (en) Method of strip hot rolling and combination mill to this end
JPH1177111A (en) Manufacture of thin hot rolled steel strip
US20240100590A1 (en) Casting-rolling integrated plant and method for producing a hot strip with a final thickness < 1.2 mm on the casting-rolling integrated plant

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AM AT AU BB BG BR BY CA CH CN CZ DE DK EE ES FI GB GE HU JP KE KG KP KR KZ LK LR LT LU LV MD MG MN MW NL NO NZ PL PT RO RU SD SE SI SK TJ TT UA UZ VN

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): KE MW SD SZ AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: CA