WO1995016563A1

WO1995016563A1 - Process for enhancing string properties

Info

Publication number: WO1995016563A1
Application number: PCT/US1994/014396
Authority: WO
Inventors: Harry M. Ferrari; Ronald H. Carr
Original assignee: Ferrari Importing Company
Priority date: 1993-12-14
Filing date: 1994-12-14
Publication date: 1995-06-22
Also published as: EP0802858A4; US5601762A; EP0802858A1; AU1436295A

Abstract

The invention relates to strings (10, 20) for stringed musical instruments, fishing equipment, and sports racquets which are exposed to a suitable solvent or suitable elasticizer compatible with the materials contained in the fibers (12, 22), bonding resins (24), or coating resins (26) in the strings (10, 20), such that partial dissolution of the material in the suitable solvent occurs or absorption of the suitable elasticizer occurs so as to increase the elasticity, increase the flexibility, increase the ductility, or increase the resiliency of the strings (10, 20).

Description

PROCESS FOR ENHANCING STRING PROPERTIES

Technical Field

The present invention relates to a method for increasing the elasticity, flexibility, and resiliency of fibers, and strings for musical instruments, fishing equipment, and sports racquets.

Background Art For fibers and strings used on stringed musical instruments, fishing equipment, and stringed sports racquets, it is advantageous that the fibers and strings have a high degree of elasticity (low modulus of elasticity or low dynamic modulus of elasticity) , flexibility, ductility, and toughness while having high breaking strength, resiliency (low internal dampening) , and abrasion resistance. In the case of a stringed musical instrument, these properties provide for a more durable string that can hold tension and a more consistent tone for a longer period of time. In the case of line for fishing equipment, these properties provide better feel, response, and durability. And in the case of sports racquets, these properties provide better feel, response, increased power, and lower shock resulting from the impact of the object being struck onto the bed of intersecting strings on the racquet. The current fibers and strings used in the field are of high strength metallic wires, natural gut fibers made from the intestines of animals, and synthetic fibers made from polymeric materials. The advantages and disadvantages of each are discussed in the following paragraphs. In general, strings which are made from high strength metallic fibers offer high break strength, high resiliency, and high abrasive resistance, however, they have the disadvantage of having high stiffness, low flexibility, and low ductility. As a result, when used for instance as strings for sports racquets, the low flexibility makes the strings difficult to install, the low ductility causes premature breakage, and the high stiffness (low elasticity) results in high impact forces transmitted to the hand and arm of the player. Strings made from natural gut fibers offer a high degree of elasticity and resiliency, however, they generally lack high breaking strengths and abrasive resistance, and when exposed to moisture in the form of water vapor contained in the air, they lose their strength and the ability to hold tension. Strings made from natural gut strings can be combined with synthetic materials in the form of fibers, bonding resins, and coating resins to improve strength and abrasive resistance, however, when synthetic materials are combined with the natural gut fibers there is in general a corresponding degradation in the elasticity and resiliency of the string. Since strings made from natural gut fibers are also generally more expensive, the performance value of the strings is greatly reduced with the addition of synthetic materials. Strings made from synthetic fibers are currently the most commonly used due to their relatively low cost and the availability of the material and because the materials can be formulated or engineered to achieve a wide variety of properties. Synthetic strings which are designed for high strength and high abrasion resistance are made from fibers engineered to have higher strengths, and incorporate high strength bonding resins and coating resins. However, these strings also generally have correspondingly high elastic modulus and high dynamic modulus as a result of the viscoelasticity of polymeric materials. Synthetic strings which are designed to have lower stiffness are also generally made from fibers which have high strength and stiffness, however, the construction of the string generally incorporates more fibers to build in more elasticity. Unfortunately, strings designed in this matter are generally less resilient, rapidly lose their elasticity over a short period of time, and can not hold tension for long periods of time.

It is also known that additives can be used to lower the stiffness properties of some synthetic polymeric materials at the polymerization stage. These additives also tend to reduce the strength of the bulk material. In addition, due to the extrusion process used to produce most synthetic fibers, additives which can be used to reduce the modulus of elasticity generally cannot be employed since they reduce the molecular weight of the material and adversely affect dimensional stability of the fiber as it is extruded.

Synthetic materials which can be extruded, which have a lower modulus of elasticity and lower dynamic modulus of elasticity, such as those listed in U.S. Patent No. 4,586,708, generally have lower strengths which limits their application for use as strings for musical instruments, fishing equipment, or sports racquets. It is also known that strings can be treated during or after manufacture of the string to alter the physical properties of the string. In U.S. Patent No. 4,015,133, Ferrari discovered that irradiation of strings made from synthetic polyamide materials resulted in strings having higher resiliency, however, there was only a minor effect on the modulus of elasticity of the material. It is also known that exposing some polymeric materials such as polyamides to water can soften strings, as a result of the water being absorbed into the material, however, the water also evaporates rapidly and the original properties of the material return.

Considering the current state of the art of strings for musical instruments, fishing equipment, and sports racquets there still is a need for an optimum string which provides an optimum combination of elasticity, strength, flexibility, abrasion resistance, ductility, and resiliency.

Disclosure of Invention

This invention arises from the discovery that exposing strings for stringed apparatus made in part of a polymer material (also commonly referred to as "synthetic strings") to a suitable solvent which can cause controlled partial dissolution of the polymer, or to a suitable elasticizer which can be absorbed into the material and cause a permanent weakening of the intermolecular forces between molecules, results in greater flexibility, lower stiffness (lower dynamic modulus of elasticity or greater elasticity) , and improved toughness (dynamic impact strength) of the strings. The invention also arises from the discovery that further subjecting the polymer strings which have undergone partial dissolution or have absorbed a suitable elasticizer, to irradiation produced by high energy particles, such as gamma rays, results in higher dynamic resiliency (lower internal dampening or dynamic loss modulus) , and greater strength. The greater flexibility, lower stiffness, improved toughness, lower internal dampening, greater dynamic elasticity, and higher strength provide improved performance for the stringed apparatus which employs strings of the present invention. In conventional synthetic strings, the polymer materials used are typically polyamide, polyester, or other polymer materials which are formed into fibers having long chain molecular structures typically aligned (oriented) in the long direction of the fiber. The highly oriented, long chain molecular structure results in fibers having relatively high strength and stiffness. However, for stringed apparatus, such as racquets used in tennis, squash, racquetball, badminton or the like, high stiffness is an undesirable property as it relates to the dynamics between the racquet, strings, and the item being struck.

By exposing the fibers used to construct the string, or the string constructed of the fibers, to a suitable solvent which will dissolve the polymer used to produce the fibers or string, a controlled dissolution of the polymer is initiated which breaks some of the intermolecular bonds to shorten the long chain molecules and reduce the intermolecular forces between molecules. The suitable solvents used are generally liquid in form, but can be gaseous or solid. The fiber or strings are immersed into the suitable solvent until the desired level of dissolution of the polymer has occurred. The suitable solvent can also be heated to increase the rate of dissolution. The reduction of the molecular forces permits slippage between the molecular chains and when combined with the shortened molecules promotes disentanglement of the molecules resulting in increased flexibility, lower stiffness, and greater ductility for greater dynamic toughness.

One can also exposed the fibers used to construct the string, or the string constructed of the fibers, to a suitable elasticizer, which is a material that is readily absorbed into the material and reacts with the molecules and atomic structure of the material to cause a permanent weakening of the intermolecular bonds in the material. The suitable elasticizer used are generally liquid in form, but can be gaseous or solid. The fiber or strings are immersed into the suitable elasticizer until the desired amount of suitable elasticizer is absorbed. The suitable elasticizer can also be heated to increase the rate of absorr ion. The reduction of molecular forces permits slippage between the molecular chains resulting in increased flexibility, lower stiffness, and greater ductility for greater dynamic toughness.

One disadvantage of the dissolution and elasticizing process is that it causes reduced breaking strength and reduced hardness which reduces the life and wear resistance of the string materials. This can render strings made from some polymer materials unusable due to their poor durability. To overcome this disadvantage of reduced strength and surface hardness in some polymer materials, the fibers used to construct the string, or the string constructed of the fibers can be further exposed to high energy irradiation produced by electrons, neutrons, gamma rays, protons, alpha particles or other sources or a combination of these sources, such that cross linkage between molecules is promoted to a point where the surface hardness and strength is increased without significantly affecting the flexibility, stiffness, and impact toughness. In cases where suitable elasticizers have been used, the irradiation further polymerizes the material and unexpectedly improves the flexibility and impact toughness of some polya ides which have absorbed the suitable elasticizer. The typical irradiation doses are between one thousand and one billion rads but can be more or less depending on the materials involved.

The strings so treated with the suitable solvent or suitable elasticizer, or the suitable solvent or suitable elasticizer plus irradiation are then used in stringed apparatus such as stringed musical instruments, stringed fishing equipment, or stringed sports racquets. Brief Description of Drawings

Fig. 1 is a cross sectional view of a monofilament string, treated in accordance with the principles of the present invention, for use in stringed musical instruments, fishing equipment, or sports racquets.

Fig. 2 is a cross sectional view of a multifilament string, treated in accordance with the principles of the present invention, for use in stringed musical instruments, fishing equipment, or sports racquets.

Best Mode for Carrying Out the Invention

Referring to Fig. 1, there is shown a cross sectional view of a monofilament string for stringed musical instruments, fishing equipment, or sports racquets, generally indicated by the numeral 10. The construction element of string 10 is comprised of a single fiber 12.

Referring now to Fig. 2, there is shown a cross sectional view of a multifilament string for stringed musical

^■ instruments, fishing equipment, or sports racquets, generally indicated by the numeral 20. The construction elements of string 20 are comprised of multiple fibers 22 arranged in a predetermined pattern, which are secured to one another with a bonding resin 24 to maintain their pattern. A coating resin 26 is applied to the arranged fibers 22, that are held together with the bonding resin 24, to protect the surface of the monofilaments from abrasion wear and from any ill effects caused by moisture, ultra violet light, or other environmental conditions.

It should be noted that the number of construction elements and the materials used in these construction elements to produce strings can vary both from string to string and within a string. Fig. 1 and Fig. 2 are shown merely as examples of string constructions and construction elements and in no way limits the scope of the present invention. The present invention relates to methods of processing or treating strings for stringed musical instruments, fishing equipment, or sports racquets so as to increase the elasticity (lower dynamic modulus of elasticity or lower dynamic stiffness) , flexibility, ductility or resiliency (lower internal dampening or lower dynamic loss modulus) , or a combination thereof, of the strings to improve or enhance the performance of the musical instrument, fishing equipment, or sports racquet. In the preferred embodiment, the fiber 12 of string 10, or at least one of the fibers 22, bonding resin 24, or coating resin 26 of string 20 are made from a polymeric material comprised of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination of these materials. The method involves immersing the string 10 or 20 into a suitable solvent, such as HOCH₂-CH₂OH for nylon 6, which will partially dissolve the polymeric material. The suitable solvent is preferably at a temperature above 100 degrees F to reduce the time required to partially dissolve the polymeric material. The result of the partial dissolution of the material is a permanent increase in the elasticity, flexibility, ductility, or resiliency, or a combination thereof, of the string 10 or 20. Suitable solvents for other polymeric materials are well known by those skilled in the art and have not been specifically listed.

In a further embodiment, the string 10 or 20, after being immersed in a suitable solvent, is further exposed to irradiation from energetic sources such as electrons, neutrons, gamma rays, alpha" particles, protons, or other sources, or a combination of these sources, to levels such that the strength and abrasion resistance of the string 10 or its fiber 12, or string 20 is also increased.

In another embodiment, the fiber 12 of string 10 or at least one of the fibers 22 of string 20 are made from a polymeric material comprised of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination of these materials. The method involves immersing the fibers into a suitable solvent which will partially dissolve the polymeric material. The suitable solvent is preferably at a temperature above 100 degrees F to reduce the time required to partially dissolve the polymeric material. The result of the partial dissolution of the material is a permanent increase in the elasticity, flexibility, ductility, or resiliency, or a combination thereof, of the fibers. The fibers are then used to construct the string 10 or string 20.

In a further embodiment, the fiber 12 or fibers 22, after being immersed in a suitable solvent, are further exposed to irradiation from energetic sources such as electrons, neutrons, gamma rays, alpha particles, protons, or other sources, or a combination of these sources, to levels such that the strength and abrasion resistance of the fiber 12 or the fibers 22 is also increased. The fiber 12 or the fibers 22 are then used to construct the string 10 or string 20.

In yet another embodiment, the string 10 or 20, wherein at least one of the construction elements of string 20, such as the fibers 22, bonding resin 24, or coating resin 26 are made from a polymeric material comprised of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination of these materials, is immersed into a suitable elasticizer, such as Di-2-ethylhexyl diphenyl phosphate for nylon 6, which is absorbed by the polymeric material of the string 10, or the fibers 22, bonding resin 24, or coating resin 26 of the string 20. The suitable elasticizer is preferably at a temperature above 100 degrees F to increase the rate of absorption. The result of the absorption of a suitable elasticizer by the polymeric material is a permanent increase in the elasticity, flexibility, ductility, or resiliency, or a combination thereof, of the string 10 or 20. Suitable elasticizers for other polymeric materials are well known by those skilled in the art and have not been specifically listed. In a further embodiment the string 10 or 20, after being immersed in a suitable elasticizer, is further exposed to irradiation from energetic sources such as electrons, neutrons, gamma rays, alpha particles, protons, or other sources, or a combination of these sources, to levels such that the strength and abrasion resistance of the string 10 or 20 is increased.

In another embodiment, the fiber 12 of string 10, or at least one of the fibers 22 of string 20 are made from a polymeric material comprised of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination of these materials, and are immersed into a suitable elasticizer which is absorbed by the polymeric material of fiber 12 or 22. The suitable elasticizer is preferably at a temperature above 100 degrees F to increase the rate of absorption. The result of the absorption of the suitable elasticizer by the polymeric material is a permanent increase in the elasticity, flexibility, ductility, or resiliency, or a combination thereof, of the fibers, which are then used to construct the string 20.

In a further embodiment the fibers 22, after being immersed in a suitable elasticizer, are further exposed to irradiation from energetic sources such as electrons, neutrons, gamma rays, alpha particles, protons, or other sources, or a combination of these sources, to levels such that the strength and abrasion resistance of fibers 22 is also increased. The fibers 22 are then used to construct the string 20.

Example - Laboratory tests and actual experience with a synthetic multifilament polyamide string, produced in accordance with the present invention, revealed that a racquet containing strings either immersed in a suitable solvent or a suitable elasticizer in accordance with the present invention performed superior to racquets containing untreated synthetic strings in terms of higher coefficient of restitution, longer dwell time (contact time between ball and strings) , and lower impact forces, and that racquets containing strings immersed in a suitable solvent or a suitable elasticizer followed by irradiation performed superior (higher coefficient of restitution, loner dwell time, and lower impact forces) to racquets containing strings which had only been immersed in a suitable solvent or a suitable elasticizer. In fact, the test racquets containing strings in accordance with the present invention performed superior (higher coefficient of restitution, longer dwell time, and lower impact forces) to racquets containing strings made from natural gut material, which historically has been considered to be the preferred racquet string material for performance by virtue of its high elasticity and high resiliency.

In the example presented, a 1.24 mm multifilament string made from fibers comprised of nylon 6 polyamide material, and suitable nylon 6 bonding resins, were immersed in a chemical mixture of HOCH₂-CH₂OH for over an hour at over 100 degrees F to cause partial dissolution of the nylon 6. After immersion in the solvent, the strings were exposed to irradiation levels of over 1 million rads.

The effect of the immersion in HOCH₂-CH₂OH, and the immersion in HOCH₂-CH₂ plus irradiation, on the material properties of the example string is given below in Table A.

Table A

Immersed in Immersion + Performance Property Untreated HOCH -CHoOH Irradiation

Tensile Strength (kεi) 83 77 79

Elongation @ 80 lbs (%) 8.8 14.2 23.8

Modulus @ 20. kεi (kεi) 1,270 700 619

Internal Damping @ 20 kεi (kεi) 147 85 98

As observed in the results presented in Table A, the materials properties of the string have been enhanced and improved by the present invention. The effect of the immersion in HOCH₂-CH20H and the immersion in HOCH₂-CH₂OH plus irradiation on the performance of the example string in a tennis racquet is given in Table B below.

Table B

Immersed in Immersion +

Performance Property Untreated HOCHT -CH₂OH Irradiation

Coefficient of

Restitution (%) 79.5 80.4 80.5 Dwell Time (millisecs) 4.15 4.26 4.32

Maximum Impact Force (lb >εs)) 416.1 414.7 408.8

Aε obεerved in the results presented in Table B, the performance of the sports racquet has been enhanced and improved by the present invention.

Claims

1. A string for use in a stringed device, said string comprising: (a) at least one fiber;

(b) said fiber including a material influencing the measurable physical properties of elasticity, flexibility, ductility, and resiliency of said fiber;

(c) said fiber being processed for increasing at least one of said measurable physical properties thereof by contacting said material of said fiber with a solvent that causes partial dissolution of said material of said fiber.

2. The string as recited in Claim 1, wherein said material of said fiber is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

3. The string as recited in Claim 1, wherein said fiber is processed by heating said solvent to a temperature above 100° F.

4. The string as recited in Claim 1, wherein said fiber is processed by irradiating said material of said fiber with an energetic source after contacting said material of said fiber with said solvent.

5. The string as recited in Claim 4, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion rads.

6. A string for use in a stringed device, εaid εtring compriεing:

(a) a plurality of fibers arranged in a predetermined pattern; and

(b) at least one of a bonding resin and a coating resin applied to said plurality of fibers, said bonding resin securing said plurality of fibers to one another to maintain said fibers in said predetermined pattern, said coating resin applied about said plurality of fibers to protect said fibers from external conditions, said plurality of fibers, said bonding resin and said coating resin thereby being construction elements of said string;

(c) at least one of said construction elements including a material influencing the measurable physical properties of elasticity, flexibility, ductility, and resiliency of said εtring;

(d) εaid string being procesεed for increaεing at leaεt one of εaid measurable physical properties thereof by contacting said material of said at least one construction element with a solvent that causes partial dissolution of said material of said at least one construction element.

7. The string as recited in Claim 6, wherein said material of said at leaεt one construction element is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

8. The string as recited in Claim 6, wherein said string is procesεed by heating said solvent to a temperature above 100° F.

9. The string as recited in Claim 6, wherein said string is processed by irradiating said material of said at least one construction element with an energetic source after contacting said material of said at leaεt one conεtruction element with εaid εolvent.

10. The εtring aε recited in Claim 19, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion rads.

11. The εtring aε recited in Claim 6, wherein both said bonding resin and said coating resin are applied to εaid plurality of fiberε, εaid coating resin being applied about said plurality of fibers and said bonding resin.

12. A εtring for uεe in a stringed device, said string comprising:

(a) at least one fiber;

(c) said fiber being processed for increasing at least one of said measurable physical properties thereof by contacting said material of said fiber with an elasticizer that is absorbed by said material of said fiber.

13. The string as recited in Claim 12, wherein said material of said fiber is a polymeric material, εaid polymeric material being εelected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

14. The string as recited in Claim 12, wherein said fiber iε processed by heating said elaεticizer to a temperature above 100° F.

15. The string as recited in Claim 12, wherein said fiber is processed by irradiating said material of said fiber with an energetic source after contacting said material of said fiber with said elasticizer.

16. The string aε recited in Claim 15, wherein εaid irradiating is performed at a level falling within a range of from one thousand to one billion radε.

17. A string for use in a stringed device, said string comprising: (a) a plurality of fibers arranged in a predetermined pattern; and

(b) at least one of a bonding resin and a coating reεin applied to said plurality of fibers, said bonding resin securing said plurality of fiberε to one another to maintain εaid fibers in said predetermined pattern, said coating resin applied about said plurality of fibers to protect said fibers from external conditions, said plurality of fibers, said bonding resin and said coating resin thereby being construction elements of said string;

(c) at least one of said construction elements including a material influencing the measurable physical properties of elasticity, flexibility, ductility, and resiliency of said string; (d) said string being processed for increasing at leaεt one of εaid measurable physical propertieε thereof by contacting said material of said at least one construction element with an elasticizer that is absorbed by εaid material of said at least one construction element.

18. The string as recited in Claim 17, wherein said material of said at least one construction element is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyeεter, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

19. The εtring aε recited in Claim 17, wherein said string is processed by heating said elasticizer to a temperature above 100° F.

20. The string aε recited in Claim 17, wherein εaid εtring is processed by irradiating said material of said at least one construction element with an energetic source after contacting said material of said at least one construction element with said elasticizer.

21. The string as recited in Claim 20, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion rads.

22. The εtring aε recited in Claim 17, wherein both εaid bonding reεin and said coating resin are applied to said plurality of fibers, said coating resin being applied about said plurality of fibers and said bonding resin.

23. A method for processing a string for use in a stringed device, said method comprising the stepε of:

(a) providing a string having at least one fiber, said fiber including a material influencing the measurable physical properties of elasticity, flexibility, ductility, and resiliency of said fiber; and (b) contacting said material of said fiber with a solvent that causes partial dissolution of said material of said fiber for increasing at least one of said measurable physical properties thereof.

24. The method as recited in Claim 23, wherein said material of said fiber is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

25. The method as recited in Claim 23, further comprising the step of: heating said solvent to a temperature above 100° F.

26. The method as recited in Claim 23, further comprising the step of: irradiating said material of said fiber with an energetic source after contacting said material of said fiber with said solvent.

27. The method as recited in Claim 26, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion rads.

28. A method for processing a string for use in a stringed device, said method comprising the steps of: (a) providing a string having a plurality of fibers arranged in a predetermined pattern, at least one of a bonding reεin and a coating reεin applied to said plurality of fiberε, εaid bonding resin securing said plurality of fibers to one another to maintain said fibers in said predetermined pattern, said coating resin applied about said plurality of fibers to protect said fibers from external conditions, said plurality of fibers, said bonding resin and said coating reεin thereby being conεtruction elementε of said string, at least one of said construction elements including a material influencing the measurable physical properties of elaεticity, flexibility, ductility, and reεiliency of said string; and

(b) contacting said material of said at least one construction element with a solvent that causes partial disεolution of εaid material of εaid at leaεt one construction element for increasing at least one of said measurable physical properties of said string.

29. The method as recited in Claim 28, wherein said material of said^' at leaεt one conεtruction element is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

30. The method aε recited in Claim 28, further compriεing the εtep of: heating said solvent to a temperature above 100° F.

33.. The method as recited in Claim 28, further comprising: irradiating said material of said at least one construction element with an energetic source after contacting said material of said at least one construction element with εaid solvent.

32. The method as recited in Claim 31, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion rads.

33. The method as recited in Claim 28, wherein both said bonding resin and said coating resin are applied to said plurality of fiberε, said coating resin being applied about said plurality of fibers and said bonding resin.

34. A method for processing a string for use in a stringed device, said method comprising the steps of:

(a) providing a string having at least one fiber, εaid fiber including a material influencing the measurable physical properties of elasticity, flexibility, ductility, and resiliency of said fiber; and

(b) contacting said material of said fiber with an elasticizer that iε abεorbed by said material of said fiber for increasing at least one of said measurable physical properties thereof.

35. The method as recited in Claim 34, wherein said material of said fiber is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

36. The method as recited in Claim 34, further comprising the step of: heating said elasticizer to a temperature above 100° F.

37. The method as recited in Claim 34, further comprising the step of: irradiating said material of said fiber with an energetic source after contacting said material of said fiber with εaid elasticizer.

38. The method aε recited in Claim 37, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion radε.

39. A method for processing a string for use in a stringed device, said method comprising the steps of:

(a) providing a string having a plurality of fibers arranged in a predetermined pattern, at least one of a bonding agent and a coating agent applied to εaid plurality of fibers, said bonding resin securing said plurality of fibers to one another to maintain εaid fibers in said predetermined pattern, said coating resin applied about said plurality of fibers to protect said fiberε from external conditions, said plurality of fibers, said bonding resin and said coating resin thereby being construction elements of said string, at least one of said construction elements including a material influencing the measurable physical properties of elasticity, flexibility, ductility, and resiliency of εaid string; and

(b) contacting said material of said at least one construction element with an elasticizer that is absorbed by said material of said at least one construction element for increasing at least one of said measurable physical properties of said string.

40. The method as recited in Claim 39, wherein said material of said at least one construction element is a polymeric material, said polymeric material being selected from the group consisting of a polyamide, polyester, polyetheretherketone, polyolefin, polyvinylidene fluoride, polyurethane, or a combination thereof.

41. The method as recited in Claim 39, further comprising the step of: heating said elasticizer to a temperature above 100° F.

42. The method as recited in Claim 59, further comprising: irradiating said material of said at least one construction element with an energetic source after contacting said material of said at least one construction element with said elasticizer.

43. The method as recited in Claim 42, wherein said irradiating is performed at a level falling within a range of from one thousand to one billion radε.

44. The method aε recited in Claim 39, wherein both εaid bonding reεin and said coating resin are applied to said plurality of fibers, said coating resin being applied about εaid plurality of fibers and said bonding resin.