WO1995024180A1 - Hair conditioning composition - Google Patents

Hair conditioning composition Download PDF

Info

Publication number
WO1995024180A1
WO1995024180A1 PCT/EP1995/000717 EP9500717W WO9524180A1 WO 1995024180 A1 WO1995024180 A1 WO 1995024180A1 EP 9500717 W EP9500717 W EP 9500717W WO 9524180 A1 WO9524180 A1 WO 9524180A1
Authority
WO
WIPO (PCT)
Prior art keywords
emulsion
silicone
dimethiconol
weight
conditioning
Prior art date
Application number
PCT/EP1995/000717
Other languages
French (fr)
Inventor
Andrew Malcolm Murray
Original Assignee
Unilever Plc
Unilever N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10751545&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1995024180(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Unilever Plc, Unilever N.V. filed Critical Unilever Plc
Priority to EP95911274A priority Critical patent/EP0749299B9/en
Priority to CA002184177A priority patent/CA2184177C/en
Priority to AU18920/95A priority patent/AU702782B2/en
Priority to DE69513958T priority patent/DE69513958T2/en
Priority to BR9507041A priority patent/BR9507041A/en
Publication of WO1995024180A1 publication Critical patent/WO1995024180A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol

Definitions

  • This invention relates to hair conditioning compositions intended to be rinsed off and containing non-volatile insoluble silicone gum, particularly dimethiconol gum.
  • Emulsion polymerised silicones are known from US 2 891 920 (Hyde), US 3 294 725 (Findlay) , and Uf " 360 491 (Axon) .
  • Emulsion polymerised dimethylpolysiloxane microemulsic' - are described in EP 0 268 982 (Toray) . Dimethiconol mater.--is are taught as one of a range of possibilities.
  • Dimethiconol can be prepared in various ways, one of which is emulsion polymerisation.
  • Silicone oils are often added to hair conditioning compositions in the form of aqueous emulsions. These emulsions are usually formed by mechanical shearing of the oil. Sometimes they are formed by chemical emulsification but this is not the same as emulsion polymerisation and does not provide the unexpected advantages of the present invention.
  • a problem with prior hair conditioning compositions has been that they either provide inadequate conditioning; or the use of high viscosity gums leads to processing difficulties. The latter problem has in the past been partially solved by the use of solvent for the gum. Such solvents are undesirable for the consumer and affect the conditioning properties of the gum.
  • n 2700 or more to give a molecular weight of over 200 000, and (c) water.
  • Substantially free from anionic surfactant means that the composition contains less than 1% of anionic surfactant.
  • the composition preferably also comprises about 0.2 to about 20% by weight of a long chain fatty alcohol.
  • the average particle size of the dimethiconol polymer is less than 20 microns and more preferably it is less than 2 microns. Small particle size enables a more uniform distribution of silicone conditioning agent on the hair for the same concentration of silicone in the shampoo.
  • the polymer can be cross-linked.
  • the viscosity of the dimethiconol lies in the range 1-20 million cst because higher viscosity increases the conditioning effect obtainable from the silicone.
  • the cationic surfactant is preferably present in an amount of 0.1 to 1% by weight.
  • Mono-, di- and tri-alkyl substituted quaternary ammonium cationic surfactants may be used; also ethoxylated quaternary ammonium cationic surfactants.
  • Suitable cationic surfactants include: Cetyl trimethyl ammonium chloride, Behenyl trimethyl ammonium chloride, Stearyl dimethylbenzyl ammonium chloride, cetylpyridinium chloride, and materials given the CTFA designations: Quaternium-5, Quaternium-31, Quaternium-18, and mixtures thereof.
  • the preferred cationic surfactants are Cetyl trimethyl ammonium chloride and behenyl trimethyl ammonium chloride.
  • Long chain fatty alcohols may have fatty alkyl or alkenyl chains with 14 to 22 carbon atoms, preferably 16 to 20.
  • Fatty alcohol which is particularly suitable for use in conjunction with cationic surfactant is a mixture of cetyl and stearyl alcohols.
  • the composition comprises 0.5 to 10% by weight of long chain fatty alcohol, most preferably from 1 to 5% by weight.
  • composition may also contain optional nonionic and amphoteric surfactant.
  • the nonionic surfactants suitable for use in the composition of the invention may include condensation products of aliphatic (C 8 -C 18 ) primary or secondary linear or branched chain alcohols or phenols with alkylene oxides, usually ethylene oxide and generally 6-30 EO.
  • Other suitable nonionics include mono or di alkyl alkanolamides or alkyl polyglucosides. Examples include coco mono or diethanolamide, coco mono isopropanolamide, and coco di glucoside.
  • amphoteric surfactants suitable for use in the composition of the invention may include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphopropionates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutameates wherein the alkyl and acyl groups have from 8 to 18 carbon atoms.
  • Examples include lauryl amine oxide, cocodimethyl sulphopropyl betaine and preferably lauryl betaine, cocamidopropyl betaine and sodium cocamphopropionate.
  • composition may also include minor amounts of other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, polymers, phosphate esters and buffering agents
  • the invention also comprises a method for preparation of a conditioning composition which contains insoluble silicone having a molecular weight above 200 000 and a viscosity of greater than 1 million cst as the conditioning agent comprising the steps of forming the silicone into an emulsion, the emulsion having a viscosity of less than lOOOcps, then mixing the emulsion with the other ingredients.
  • a conditioning composition which contains insoluble silicone having a molecular weight above 200 000 and a viscosity of greater than 1 million cst as the conditioning agent comprising the steps of forming the silicone into an emulsion, the emulsion having a viscosity of less than lOOOcps, then mixing the emulsion with the other ingredients.
  • the emulsion comprises greater than 40% by weight of the silicone.
  • the silicone is emulsion polymerised because such a material is able to combine small particle size with high viscosity.
  • Dimethiconol silicone is particularly preferred.
  • the dimethiconol silicone can either be used as such or it can be end-capped with a further methyl group.
  • CTAC 1 0.7 0.7 0.7 0.7 0.5 0.7
  • compositions detailed in Table 1 were used to treat identical hair switches which were then subjected to a series of paired comparison tests by trained panellists.
  • the two attributes considered to be most indicative of conditioning benefit are (a) ease of dry combing and (b) smooth feel of the hair when dry.
  • Comparative Example B containing a mechanical emulsion of silicone conditioning agent according to the prior art, did not give rise to any statistically significant differences. Whereas all the compositions according to the invention were statistically preferred over Comparative Example A. From these comparative tests it can be concluded that compositions according to the invention and prepared according to the method of the invention give superior results to the mechanical silicone emulsion composition B.

Abstract

A rinse off hair conditioning composition comprising: (a) about 0.05 to about 5 % by weight of cationic surfactant, (b) 0.01 to 10 % by weight of an emulsion polymerised dimethiconol nonionic conditioning polymer having the formula: HO-Si(CH3)2-O-[Si(CH3)2-O-]nSi(CH3)2-OH where n is greater than 2700, and (c) water. The invention also comprises a method of making a conditioning composition.

Description

Hair Conditioning Composition
This invention relates to hair conditioning compositions intended to be rinsed off and containing non-volatile insoluble silicone gum, particularly dimethiconol gum.
Use of high viscosity gums as hair conditioning agents is known and suitable gums are described in US 4 874 416 (Spitzer) . The gums are usually used in solution in a volatile silicone such as a eyelor-^ icone.
Emulsion polymerised silicones are known from US 2 891 920 (Hyde), US 3 294 725 (Findlay) , and Uf " 360 491 (Axon) .
Emulsion polymerised dimethylpolysiloxane microemulsic' - are described in EP 0 268 982 (Toray) . Dimethiconol mater.--is are taught as one of a range of possibilities.
Articles such as "Organofunctional Silicones for Personal Care Applications", Wendel, Samuel R and DiSapio, Alfred J. Cosmetics & Toiletri es vol 98 May 1983, pp 103-106 have taught away from the use of Dimethiconol in hair compositions.
Dimethiconol can be prepared in various ways, one of which is emulsion polymerisation.
Silicone oils are often added to hair conditioning compositions in the form of aqueous emulsions. These emulsions are usually formed by mechanical shearing of the oil. Sometimes they are formed by chemical emulsification but this is not the same as emulsion polymerisation and does not provide the unexpected advantages of the present invention. A problem with prior hair conditioning compositions has been that they either provide inadequate conditioning; or the use of high viscosity gums leads to processing difficulties. The latter problem has in the past been partially solved by the use of solvent for the gum. Such solvents are undesirable for the consumer and affect the conditioning properties of the gum.
According to the present invention a hair conditioning composition which is substantially free from anionic surfactant comprises:
(a) about 0.05 to about 5% by weight cationic surfactant,
(b) 0.01 to 10% by weight of an emulsion polymerised dimethiconol nonionic conditioning polymer having the formula:
HO-Si (CH3)2-0- [Si (CH3)2-0-]nSi (CH 3' 2 -OH
where n is 2700 or more to give a molecular weight of over 200 000, and (c) water.
Substantially free from anionic surfactant means that the composition contains less than 1% of anionic surfactant.
The composition preferably also comprises about 0.2 to about 20% by weight of a long chain fatty alcohol.
Preferably the average particle size of the dimethiconol polymer is less than 20 microns and more preferably it is less than 2 microns. Small particle size enables a more uniform distribution of silicone conditioning agent on the hair for the same concentration of silicone in the shampoo. The polymer can be cross-linked. Advantageously the viscosity of the dimethiconol lies in the range 1-20 million cst because higher viscosity increases the conditioning effect obtainable from the silicone.
The cationic surfactant is preferably present in an amount of 0.1 to 1% by weight. Mono-, di- and tri-alkyl substituted quaternary ammonium cationic surfactants may be used; also ethoxylated quaternary ammonium cationic surfactants. Suitable cationic surfactants include: Cetyl trimethyl ammonium chloride, Behenyl trimethyl ammonium chloride, Stearyl dimethylbenzyl ammonium chloride, cetylpyridinium chloride, and materials given the CTFA designations: Quaternium-5, Quaternium-31, Quaternium-18, and mixtures thereof. The preferred cationic surfactants are Cetyl trimethyl ammonium chloride and behenyl trimethyl ammonium chloride.
Long chain fatty alcohols may have fatty alkyl or alkenyl chains with 14 to 22 carbon atoms, preferably 16 to 20. Fatty alcohol which is particularly suitable for use in conjunction with cationic surfactant is a mixture of cetyl and stearyl alcohols. Preferably the composition comprises 0.5 to 10% by weight of long chain fatty alcohol, most preferably from 1 to 5% by weight.
The composition may also contain optional nonionic and amphoteric surfactant.
The nonionic surfactants suitable for use in the composition of the invention may include condensation products of aliphatic (C8-C18) primary or secondary linear or branched chain alcohols or phenols with alkylene oxides, usually ethylene oxide and generally 6-30 EO. Other suitable nonionics include mono or di alkyl alkanolamides or alkyl polyglucosides. Examples include coco mono or diethanolamide, coco mono isopropanolamide, and coco di glucoside.
The amphoteric surfactants suitable for use in the composition of the invention may include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphopropionates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutameates wherein the alkyl and acyl groups have from 8 to 18 carbon atoms. Examples include lauryl amine oxide, cocodimethyl sulphopropyl betaine and preferably lauryl betaine, cocamidopropyl betaine and sodium cocamphopropionate.
The composition may also include minor amounts of other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, polymers, phosphate esters and buffering agents
The invention also comprises a method for preparation of a conditioning composition which contains insoluble silicone having a molecular weight above 200 000 and a viscosity of greater than 1 million cst as the conditioning agent comprising the steps of forming the silicone into an emulsion, the emulsion having a viscosity of less than lOOOcps, then mixing the emulsion with the other ingredients. Preferably the emulsion comprises greater than 40% by weight of the silicone.
In a preferred method the silicone is emulsion polymerised because such a material is able to combine small particle size with high viscosity. Dimethiconol silicone is particularly preferred. The dimethiconol silicone can either be used as such or it can be end-capped with a further methyl group.
The invention will now be further described with reference to the following examples:
Table 1
A B 1 2 3 4 5
CTAC1 0.7 0.7 0.7 0.7 0.5 0.7
BTAC2 - - - - - - 0.7
Laurex CS3 1.9 1.9 1.9 3.5 1.0 1.9 1.9
Paraffin Wax 1.0 1.0 1.0 1.0 - 1.0 1.0
Glycerol 0.7 0.7 0.7 0.7 - 0.7 0.7 monostearate
Natrosol 250 HR4 - - - - 1.3 - -
Polysurf 675 - - - - - 0.2 -
X2-17666 - - 1.7 - 3.3 - 2.5
X2-17847 - - - 2.0 - 6.0 -
BY 22-0268 - 2.0 - - - - - minors as req uir ed water to 100 %
1 is Cetyl trimethyl ammonium chloride
2 is behenyl trimethyl ammonium chloride
3 is 2:1 hexadecanol:octadecanol ex Albright & Wilson 4 is hydroxy ethyl cellulose ex Hercules
5 is cetyl hydroxyethyl cellulose ex Hercules
6 is a 60% silicone emulsion polymer, mol wt 300,000
7 is a 50% silicone emulsion polymer, mol wt 240,000
8 is a 50% mechanical emulsion of silicone, mol wt 115,000
The compositions detailed in Table 1 were used to treat identical hair switches which were then subjected to a series of paired comparison tests by trained panellists. The two attributes considered to be most indicative of conditioning benefit are (a) ease of dry combing and (b) smooth feel of the hair when dry. In each case the comparison was with the comparative example A which contained no silicone conditioning agent. Comparative Example B, containing a mechanical emulsion of silicone conditioning agent according to the prior art, did not give rise to any statistically significant differences. Whereas all the compositions according to the invention were statistically preferred over Comparative Example A. From these comparative tests it can be concluded that compositions according to the invention and prepared according to the method of the invention give superior results to the mechanical silicone emulsion composition B.

Claims

1. A rinse off hair conditioning composition substantially free from anionic surfactant comprising:
(a) about 0.05 to about 5% by weight of cationic surfactant,
(b) 0.01 to 10% by weight of an emulsion polymerised dimethiconol nonionic conditioning polymer having the formula:
HO-Si (CH3)2-0- [Si (CH3)2-O-]nSi (CH3)2-OH
where n is greater than 2700, and (c) water.
2. A composition according to claim 1 wherein the average particle size of the dimethiconol polymer is less than 20 microns.
3. A composition according to claim 2 wherein the average particle size of the dimethiconol polymer is less than 2 microns.
4. A composition according to claim 1 wherein the viscosity of the dimethiconol lies in the range 1-20 million cst.
5. A composition according to any preceding claim which further comprises 0.2 to 20% by weight of a C14_22 alcohol.
6. A composition according to any preceding claim wherein the cationic surfactant is selected from the group comprising cetyl trimethyl ammonium chloride and behenyl trimethyl ammonium chloride.
7. A method for preparation of a rinse off conditioning composition which contains a cationic surfactant and insoluble silicone having a molecular weight above 200 000 and a viscosity of greater than 1 million cst as the conditioning agent comprising the steps of forming the silicone into an emulsion, the emulsion having a viscosity of less than lOOOcps, then mixing the emulsion with the other conditioner ingredients including the cationic surfactant.
8. A method as claimed in claim 7 wherein the emulsion comprises more than 40% by weight of the silicone.
9. A method according to claim 7 or 8 wherein the silicone is emulsion polymerised dimethiconol.
PCT/EP1995/000717 1994-03-09 1995-02-25 Hair conditioning composition WO1995024180A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP95911274A EP0749299B9 (en) 1994-03-09 1995-02-25 Hair conditioning composition
CA002184177A CA2184177C (en) 1994-03-09 1995-02-25 Hair conditioning composition
AU18920/95A AU702782B2 (en) 1994-03-09 1995-02-25 Hair conditioning composition
DE69513958T DE69513958T2 (en) 1994-03-09 1995-02-25 HAIR CARE PRODUCTS
BR9507041A BR9507041A (en) 1994-03-09 1995-02-25 Composition of hair conditioning without rinsing and process for preparing it

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9404550.7 1994-03-09
GB9404550A GB9404550D0 (en) 1994-03-09 1994-03-09 Hair conditioning composition

Publications (1)

Publication Number Publication Date
WO1995024180A1 true WO1995024180A1 (en) 1995-09-14

Family

ID=10751545

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/000717 WO1995024180A1 (en) 1994-03-09 1995-02-25 Hair conditioning composition

Country Status (11)

Country Link
US (1) US6274130B1 (en)
EP (1) EP0749299B9 (en)
JP (1) JP2931671B2 (en)
CN (1) CN1092953C (en)
AU (1) AU702782B2 (en)
BR (1) BR9507041A (en)
CA (1) CA2184177C (en)
DE (1) DE69513958T2 (en)
ES (1) ES2139888T3 (en)
GB (1) GB9404550D0 (en)
WO (1) WO1995024180A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998020848A1 (en) * 1996-11-12 1998-05-22 S.C. Johnson & Son, Inc. Method of soap-free shaving
EP0845975A1 (en) * 1995-08-23 1998-06-10 The Procter & Gamble Company Hair treatment composition
US5980877A (en) * 1996-10-25 1999-11-09 The Procter & Gamble Company Conditioning shampoo composition
US6004544A (en) * 1996-10-25 1999-12-21 The Procter & Gamble Co. Conditioning shampoo composition
GB2357972A (en) * 1999-09-16 2001-07-11 Ansell Jayne Optionally substituted siloxane containing liquid composition for the eradication of head lice
WO2009074465A2 (en) * 2007-12-13 2009-06-18 Henkel Ag & Co. Kgaa Hair-conditioning products containing cationic behenyl compounds and selected silicones and/or cosmetic oils

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6495498B2 (en) 1999-05-27 2002-12-17 Johnson & Johnson Consumer Companies, Inc. Detergent compositions with enhanced depositing, conditioning and softness capabilities
PL202068B1 (en) * 1999-09-16 2009-05-29 Durminster Ltd Method and composition for the control of arthropods
GB0016807D0 (en) * 2000-07-07 2000-08-30 Unilever Plc Shampoo compositions
WO2002088253A1 (en) * 2001-04-27 2002-11-07 Dow Corning Toray Silicone Co., Ltd. Polyorganosiloxane emulsion composition and a cosmetic material made therefrom
US7208144B2 (en) * 2002-12-10 2007-04-24 Cognis Corporation Stabilized dispersion of behenyl alcohol
KR100516954B1 (en) * 2002-12-13 2005-09-23 여수시 Hair oil composition comprising camellia oil and method for preparation thereof
US20040146475A1 (en) * 2003-01-17 2004-07-29 Peffly Marjorie Mossman Personal care composition containing a cationic cellulose polymer and an anionic surfactant system
JP4579032B2 (en) * 2005-03-31 2010-11-10 モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 Silicone emulsion and hair cosmetic composition
JP4683203B2 (en) * 2005-05-31 2011-05-18 信越化学工業株式会社 Cationic emulsion composition of highly polymerized organosiloxane and process for producing the same
US20100196301A1 (en) * 2007-07-02 2010-08-05 Andrew Richard Avery Hair care compositions
JP5615510B2 (en) * 2009-04-06 2014-10-29 株式会社ミルボン Hair cosmetic composition
KR102610439B1 (en) * 2016-09-20 2023-12-06 (주)아모레퍼시픽 Hair conditioning composition
CN107668810A (en) * 2017-11-10 2018-02-09 义乌市丝黛文化创意有限公司 A kind of high temperature resistance wig and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2891920A (en) * 1955-01-26 1959-06-23 Dow Corning Polymerization of organopolysiloxanes in aqueous emulsion
EP0268982A2 (en) * 1986-11-18 1988-06-01 Toray Silicone Company, Ltd. Cosmetic compositions containing microemulsions of dimethylpolysiloxane
US4950468A (en) * 1987-03-11 1990-08-21 Sunstar Kabushiki Kaisha Hair treating composition
WO1992009264A2 (en) * 1990-11-30 1992-06-11 Richardson-Vicks, Inc. Leave-on facial emulsion compositions
WO1993019723A1 (en) * 1992-03-31 1993-10-14 Alberto-Culver Company Emulsifier compositions for applying silicone oil to hair

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1024024A (en) 1963-04-08 1966-03-30 Dow Corning Improvements in or relating to polymerising or co-polymerising organosilicon compounds
NL124881C (en) 1964-05-18
JPS60141634A (en) 1983-12-28 1985-07-26 Shin Etsu Chem Co Ltd Parent material for optical fiber and its preparation
US4902499A (en) * 1986-04-04 1990-02-20 The Procter & Gamble Company Hair care compositions containing a rigid silicone polymer
US4724851A (en) * 1986-11-04 1988-02-16 Dow Corning Corporation Hair fixative composition containing cationic organic polymer and polydiorganosiloxane
DE3886247T2 (en) 1987-03-30 1994-03-31 Shiseido Co Ltd Use of a hair cosmetic for the prevention of split hair or broken hair and for the treatment of damaged hair.
US4983418A (en) * 1989-10-31 1991-01-08 The Procter & Gamble Company Silicone hairspray compositions
EP0432951B2 (en) * 1989-12-04 2004-06-30 Unilever Plc Hair treatment composition
CA2042693A1 (en) 1990-06-07 1991-12-08 Daniel J. Halloran Silicone mechanical emulsions for hair care
GB9016100D0 (en) * 1990-07-23 1990-09-05 Unilever Plc Shampoo composition
GB9117740D0 (en) 1991-08-16 1991-10-02 Unilever Plc Cosmetic composition
US5334376A (en) * 1993-08-13 1994-08-02 Colgate-Palmolive Company Compositions for conditioning hair

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2891920A (en) * 1955-01-26 1959-06-23 Dow Corning Polymerization of organopolysiloxanes in aqueous emulsion
EP0268982A2 (en) * 1986-11-18 1988-06-01 Toray Silicone Company, Ltd. Cosmetic compositions containing microemulsions of dimethylpolysiloxane
US4950468A (en) * 1987-03-11 1990-08-21 Sunstar Kabushiki Kaisha Hair treating composition
WO1992009264A2 (en) * 1990-11-30 1992-06-11 Richardson-Vicks, Inc. Leave-on facial emulsion compositions
WO1993019723A1 (en) * 1992-03-31 1993-10-14 Alberto-Culver Company Emulsifier compositions for applying silicone oil to hair

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0845975A1 (en) * 1995-08-23 1998-06-10 The Procter & Gamble Company Hair treatment composition
EP0845975A4 (en) * 1995-08-23 2000-05-10 Procter & Gamble Hair treatment composition
US5980877A (en) * 1996-10-25 1999-11-09 The Procter & Gamble Company Conditioning shampoo composition
US6004544A (en) * 1996-10-25 1999-12-21 The Procter & Gamble Co. Conditioning shampoo composition
US6174522B1 (en) 1996-10-25 2001-01-16 The Procter & Gamble Company Conditioning shampoo composition
WO1998020848A1 (en) * 1996-11-12 1998-05-22 S.C. Johnson & Son, Inc. Method of soap-free shaving
GB2357972A (en) * 1999-09-16 2001-07-11 Ansell Jayne Optionally substituted siloxane containing liquid composition for the eradication of head lice
WO2009074465A2 (en) * 2007-12-13 2009-06-18 Henkel Ag & Co. Kgaa Hair-conditioning products containing cationic behenyl compounds and selected silicones and/or cosmetic oils
WO2009074465A3 (en) * 2007-12-13 2010-07-01 Henkel Ag & Co. Kgaa Hair-conditioning products containing cationic behenyl compounds and selected silicones and/or cosmetic oils

Also Published As

Publication number Publication date
DE69513958T2 (en) 2000-04-20
GB9404550D0 (en) 1994-04-20
CN1092953C (en) 2002-10-23
ES2139888T3 (en) 2000-02-16
CA2184177C (en) 2000-05-16
AU1892095A (en) 1995-09-25
EP0749299A1 (en) 1996-12-27
US6274130B1 (en) 2001-08-14
AU702782B2 (en) 1999-03-04
JPH09508419A (en) 1997-08-26
EP0749299B1 (en) 1999-12-15
CN1143316A (en) 1997-02-19
CA2184177A1 (en) 1995-09-14
EP0749299B9 (en) 2006-11-15
DE69513958D1 (en) 2000-01-20
BR9507041A (en) 1997-08-12
JP2931671B2 (en) 1999-08-09

Similar Documents

Publication Publication Date Title
US6274130B1 (en) Hair conditioning composition
EP0674898B1 (en) Shampoo composition
US6355234B1 (en) Shampoo compositions and method
US5776443A (en) Hair care compositions
CA2022901C (en) Shampoo composition
KR960015951B1 (en) Cosmetic composition
US5990059A (en) Shampoo composition
EP1035827B1 (en) Hair treatment composition
MXPA01012363A (en) Mousse-forming shampoo compositions.
US5554313A (en) Conditioning shampoo containing insoluble, nonvolatile silicone
US20020081274A1 (en) Personal cleansing compositions that contain surfactants, co-surfactants, water insoluble solids and/or liquids and cationic conditioning polymers
US20030133899A1 (en) Personal cleansing compositions that contain surfactants, co-surfactants, water insoluble solids and/or liquids and cationic conditioning polymers
CA2337165C (en) Hair care compositions
AU5524600A (en) Hair treatment compositions
AU5505399A (en) Hair treatment compositions
WO2000006096A1 (en) Hair care compositions

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 95192023.5

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): AM AT AU BB BG BR BY CA CH CN CZ DE DK EE ES FI GB GE HU JP KE KG KP KR KZ LK LR LT LU LV MD MG MN MW MX NL NO NZ PL PT RO RU SD SE SG SI SK TJ TT UA UG UZ VN

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): KE MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1995911274

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2184177

Country of ref document: CA

WWP Wipo information: published in national office

Ref document number: 1995911274

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWG Wipo information: grant in national office

Ref document number: 1995911274

Country of ref document: EP