WO1995024180A1 - Hair conditioning composition - Google Patents
Hair conditioning composition Download PDFInfo
- Publication number
- WO1995024180A1 WO1995024180A1 PCT/EP1995/000717 EP9500717W WO9524180A1 WO 1995024180 A1 WO1995024180 A1 WO 1995024180A1 EP 9500717 W EP9500717 W EP 9500717W WO 9524180 A1 WO9524180 A1 WO 9524180A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- emulsion
- silicone
- dimethiconol
- weight
- conditioning
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
Definitions
- This invention relates to hair conditioning compositions intended to be rinsed off and containing non-volatile insoluble silicone gum, particularly dimethiconol gum.
- Emulsion polymerised silicones are known from US 2 891 920 (Hyde), US 3 294 725 (Findlay) , and Uf " 360 491 (Axon) .
- Emulsion polymerised dimethylpolysiloxane microemulsic' - are described in EP 0 268 982 (Toray) . Dimethiconol mater.--is are taught as one of a range of possibilities.
- Dimethiconol can be prepared in various ways, one of which is emulsion polymerisation.
- Silicone oils are often added to hair conditioning compositions in the form of aqueous emulsions. These emulsions are usually formed by mechanical shearing of the oil. Sometimes they are formed by chemical emulsification but this is not the same as emulsion polymerisation and does not provide the unexpected advantages of the present invention.
- a problem with prior hair conditioning compositions has been that they either provide inadequate conditioning; or the use of high viscosity gums leads to processing difficulties. The latter problem has in the past been partially solved by the use of solvent for the gum. Such solvents are undesirable for the consumer and affect the conditioning properties of the gum.
- n 2700 or more to give a molecular weight of over 200 000, and (c) water.
- Substantially free from anionic surfactant means that the composition contains less than 1% of anionic surfactant.
- the composition preferably also comprises about 0.2 to about 20% by weight of a long chain fatty alcohol.
- the average particle size of the dimethiconol polymer is less than 20 microns and more preferably it is less than 2 microns. Small particle size enables a more uniform distribution of silicone conditioning agent on the hair for the same concentration of silicone in the shampoo.
- the polymer can be cross-linked.
- the viscosity of the dimethiconol lies in the range 1-20 million cst because higher viscosity increases the conditioning effect obtainable from the silicone.
- the cationic surfactant is preferably present in an amount of 0.1 to 1% by weight.
- Mono-, di- and tri-alkyl substituted quaternary ammonium cationic surfactants may be used; also ethoxylated quaternary ammonium cationic surfactants.
- Suitable cationic surfactants include: Cetyl trimethyl ammonium chloride, Behenyl trimethyl ammonium chloride, Stearyl dimethylbenzyl ammonium chloride, cetylpyridinium chloride, and materials given the CTFA designations: Quaternium-5, Quaternium-31, Quaternium-18, and mixtures thereof.
- the preferred cationic surfactants are Cetyl trimethyl ammonium chloride and behenyl trimethyl ammonium chloride.
- Long chain fatty alcohols may have fatty alkyl or alkenyl chains with 14 to 22 carbon atoms, preferably 16 to 20.
- Fatty alcohol which is particularly suitable for use in conjunction with cationic surfactant is a mixture of cetyl and stearyl alcohols.
- the composition comprises 0.5 to 10% by weight of long chain fatty alcohol, most preferably from 1 to 5% by weight.
- composition may also contain optional nonionic and amphoteric surfactant.
- the nonionic surfactants suitable for use in the composition of the invention may include condensation products of aliphatic (C 8 -C 18 ) primary or secondary linear or branched chain alcohols or phenols with alkylene oxides, usually ethylene oxide and generally 6-30 EO.
- Other suitable nonionics include mono or di alkyl alkanolamides or alkyl polyglucosides. Examples include coco mono or diethanolamide, coco mono isopropanolamide, and coco di glucoside.
- amphoteric surfactants suitable for use in the composition of the invention may include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines, alkyl glycinates, alkyl carboxyglycinates, alkyl amphopropionates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutameates wherein the alkyl and acyl groups have from 8 to 18 carbon atoms.
- Examples include lauryl amine oxide, cocodimethyl sulphopropyl betaine and preferably lauryl betaine, cocamidopropyl betaine and sodium cocamphopropionate.
- composition may also include minor amounts of other ingredients such as antibacterial agents, foam boosters, pearlescers, perfumes, dyes, colouring agents, preservatives, thickeners, proteins, polymers, phosphate esters and buffering agents
- the invention also comprises a method for preparation of a conditioning composition which contains insoluble silicone having a molecular weight above 200 000 and a viscosity of greater than 1 million cst as the conditioning agent comprising the steps of forming the silicone into an emulsion, the emulsion having a viscosity of less than lOOOcps, then mixing the emulsion with the other ingredients.
- a conditioning composition which contains insoluble silicone having a molecular weight above 200 000 and a viscosity of greater than 1 million cst as the conditioning agent comprising the steps of forming the silicone into an emulsion, the emulsion having a viscosity of less than lOOOcps, then mixing the emulsion with the other ingredients.
- the emulsion comprises greater than 40% by weight of the silicone.
- the silicone is emulsion polymerised because such a material is able to combine small particle size with high viscosity.
- Dimethiconol silicone is particularly preferred.
- the dimethiconol silicone can either be used as such or it can be end-capped with a further methyl group.
- CTAC 1 0.7 0.7 0.7 0.7 0.5 0.7
- compositions detailed in Table 1 were used to treat identical hair switches which were then subjected to a series of paired comparison tests by trained panellists.
- the two attributes considered to be most indicative of conditioning benefit are (a) ease of dry combing and (b) smooth feel of the hair when dry.
- Comparative Example B containing a mechanical emulsion of silicone conditioning agent according to the prior art, did not give rise to any statistically significant differences. Whereas all the compositions according to the invention were statistically preferred over Comparative Example A. From these comparative tests it can be concluded that compositions according to the invention and prepared according to the method of the invention give superior results to the mechanical silicone emulsion composition B.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9507041A BR9507041A (en) | 1994-03-09 | 1995-02-25 | Composition of hair conditioning without rinsing and process for preparing it |
DE69513958T DE69513958T2 (en) | 1994-03-09 | 1995-02-25 | HAIR CARE PRODUCTS |
CA002184177A CA2184177C (en) | 1994-03-09 | 1995-02-25 | Hair conditioning composition |
AU18920/95A AU702782B2 (en) | 1994-03-09 | 1995-02-25 | Hair conditioning composition |
EP95911274A EP0749299B9 (en) | 1994-03-09 | 1995-02-25 | Hair conditioning composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9404550A GB9404550D0 (en) | 1994-03-09 | 1994-03-09 | Hair conditioning composition |
GB9404550.7 | 1994-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995024180A1 true WO1995024180A1 (en) | 1995-09-14 |
Family
ID=10751545
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1995/000717 WO1995024180A1 (en) | 1994-03-09 | 1995-02-25 | Hair conditioning composition |
Country Status (11)
Country | Link |
---|---|
US (1) | US6274130B1 (en) |
EP (1) | EP0749299B9 (en) |
JP (1) | JP2931671B2 (en) |
CN (1) | CN1092953C (en) |
AU (1) | AU702782B2 (en) |
BR (1) | BR9507041A (en) |
CA (1) | CA2184177C (en) |
DE (1) | DE69513958T2 (en) |
ES (1) | ES2139888T3 (en) |
GB (1) | GB9404550D0 (en) |
WO (1) | WO1995024180A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998020848A1 (en) * | 1996-11-12 | 1998-05-22 | S.C. Johnson & Son, Inc. | Method of soap-free shaving |
EP0845975A1 (en) * | 1995-08-23 | 1998-06-10 | The Procter & Gamble Company | Hair treatment composition |
US5980877A (en) * | 1996-10-25 | 1999-11-09 | The Procter & Gamble Company | Conditioning shampoo composition |
US6004544A (en) * | 1996-10-25 | 1999-12-21 | The Procter & Gamble Co. | Conditioning shampoo composition |
GB2357972A (en) * | 1999-09-16 | 2001-07-11 | Ansell Jayne | Optionally substituted siloxane containing liquid composition for the eradication of head lice |
WO2009074465A2 (en) * | 2007-12-13 | 2009-06-18 | Henkel Ag & Co. Kgaa | Hair-conditioning products containing cationic behenyl compounds and selected silicones and/or cosmetic oils |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6495498B2 (en) * | 1999-05-27 | 2002-12-17 | Johnson & Johnson Consumer Companies, Inc. | Detergent compositions with enhanced depositing, conditioning and softness capabilities |
PL202068B1 (en) * | 1999-09-16 | 2009-05-29 | Durminster Ltd | Method and composition for the control of arthropods |
GB0016807D0 (en) * | 2000-07-07 | 2000-08-30 | Unilever Plc | Shampoo compositions |
WO2002088253A1 (en) * | 2001-04-27 | 2002-11-07 | Dow Corning Toray Silicone Co., Ltd. | Polyorganosiloxane emulsion composition and a cosmetic material made therefrom |
US7208144B2 (en) * | 2002-12-10 | 2007-04-24 | Cognis Corporation | Stabilized dispersion of behenyl alcohol |
KR100516954B1 (en) * | 2002-12-13 | 2005-09-23 | 여수시 | Hair oil composition comprising camellia oil and method for preparation thereof |
US20040146475A1 (en) * | 2003-01-17 | 2004-07-29 | Peffly Marjorie Mossman | Personal care composition containing a cationic cellulose polymer and an anionic surfactant system |
JP4579032B2 (en) * | 2005-03-31 | 2010-11-10 | モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 | Silicone emulsion and hair cosmetic composition |
JP4683203B2 (en) * | 2005-05-31 | 2011-05-18 | 信越化学工業株式会社 | Cationic emulsion composition of highly polymerized organosiloxane and process for producing the same |
EP2160181B1 (en) * | 2007-07-02 | 2016-08-17 | Unilever PLC | Hair care compositions |
JP5615510B2 (en) * | 2009-04-06 | 2014-10-29 | 株式会社ミルボン | Hair cosmetic composition |
KR102610439B1 (en) * | 2016-09-20 | 2023-12-06 | (주)아모레퍼시픽 | Hair conditioning composition |
CN107668810A (en) * | 2017-11-10 | 2018-02-09 | 义乌市丝黛文化创意有限公司 | A kind of high temperature resistance wig and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891920A (en) * | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
EP0268982A2 (en) * | 1986-11-18 | 1988-06-01 | Toray Silicone Company, Ltd. | Cosmetic compositions containing microemulsions of dimethylpolysiloxane |
US4950468A (en) * | 1987-03-11 | 1990-08-21 | Sunstar Kabushiki Kaisha | Hair treating composition |
WO1992009264A2 (en) * | 1990-11-30 | 1992-06-11 | Richardson-Vicks, Inc. | Leave-on facial emulsion compositions |
WO1993019723A1 (en) * | 1992-03-31 | 1993-10-14 | Alberto-Culver Company | Emulsifier compositions for applying silicone oil to hair |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1024024A (en) | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
NL124881C (en) | 1964-05-18 | |||
JPS60141634A (en) | 1983-12-28 | 1985-07-26 | Shin Etsu Chem Co Ltd | Parent material for optical fiber and its preparation |
US4902499A (en) * | 1986-04-04 | 1990-02-20 | The Procter & Gamble Company | Hair care compositions containing a rigid silicone polymer |
US4724851A (en) * | 1986-11-04 | 1988-02-16 | Dow Corning Corporation | Hair fixative composition containing cationic organic polymer and polydiorganosiloxane |
EP0285364B1 (en) | 1987-03-30 | 1993-12-15 | Shiseido Company Limited | Use of a hair cosmetic composition for preventing generation of split hair or torn hair and for repairing damaged hair |
US4983418A (en) * | 1989-10-31 | 1991-01-08 | The Procter & Gamble Company | Silicone hairspray compositions |
EP0432951B2 (en) * | 1989-12-04 | 2004-06-30 | Unilever Plc | Hair treatment composition |
CA2042693A1 (en) | 1990-06-07 | 1991-12-08 | Daniel J. Halloran | Silicone mechanical emulsions for hair care |
GB9016100D0 (en) * | 1990-07-23 | 1990-09-05 | Unilever Plc | Shampoo composition |
GB9117740D0 (en) | 1991-08-16 | 1991-10-02 | Unilever Plc | Cosmetic composition |
US5334376A (en) * | 1993-08-13 | 1994-08-02 | Colgate-Palmolive Company | Compositions for conditioning hair |
-
1994
- 1994-03-09 GB GB9404550A patent/GB9404550D0/en active Pending
-
1995
- 1995-02-25 ES ES95911274T patent/ES2139888T3/en not_active Expired - Lifetime
- 1995-02-25 CA CA002184177A patent/CA2184177C/en not_active Expired - Lifetime
- 1995-02-25 AU AU18920/95A patent/AU702782B2/en not_active Expired
- 1995-02-25 DE DE69513958T patent/DE69513958T2/en not_active Revoked
- 1995-02-25 CN CN95192023A patent/CN1092953C/en not_active Expired - Lifetime
- 1995-02-25 EP EP95911274A patent/EP0749299B9/en not_active Revoked
- 1995-02-25 WO PCT/EP1995/000717 patent/WO1995024180A1/en active IP Right Grant
- 1995-02-25 BR BR9507041A patent/BR9507041A/en not_active IP Right Cessation
- 1995-02-25 JP JP7523197A patent/JP2931671B2/en not_active Expired - Lifetime
- 1995-03-06 US US08/399,395 patent/US6274130B1/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2891920A (en) * | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
EP0268982A2 (en) * | 1986-11-18 | 1988-06-01 | Toray Silicone Company, Ltd. | Cosmetic compositions containing microemulsions of dimethylpolysiloxane |
US4950468A (en) * | 1987-03-11 | 1990-08-21 | Sunstar Kabushiki Kaisha | Hair treating composition |
WO1992009264A2 (en) * | 1990-11-30 | 1992-06-11 | Richardson-Vicks, Inc. | Leave-on facial emulsion compositions |
WO1993019723A1 (en) * | 1992-03-31 | 1993-10-14 | Alberto-Culver Company | Emulsifier compositions for applying silicone oil to hair |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0845975A1 (en) * | 1995-08-23 | 1998-06-10 | The Procter & Gamble Company | Hair treatment composition |
EP0845975A4 (en) * | 1995-08-23 | 2000-05-10 | Procter & Gamble | Hair treatment composition |
US5980877A (en) * | 1996-10-25 | 1999-11-09 | The Procter & Gamble Company | Conditioning shampoo composition |
US6004544A (en) * | 1996-10-25 | 1999-12-21 | The Procter & Gamble Co. | Conditioning shampoo composition |
US6174522B1 (en) | 1996-10-25 | 2001-01-16 | The Procter & Gamble Company | Conditioning shampoo composition |
WO1998020848A1 (en) * | 1996-11-12 | 1998-05-22 | S.C. Johnson & Son, Inc. | Method of soap-free shaving |
GB2357972A (en) * | 1999-09-16 | 2001-07-11 | Ansell Jayne | Optionally substituted siloxane containing liquid composition for the eradication of head lice |
WO2009074465A2 (en) * | 2007-12-13 | 2009-06-18 | Henkel Ag & Co. Kgaa | Hair-conditioning products containing cationic behenyl compounds and selected silicones and/or cosmetic oils |
WO2009074465A3 (en) * | 2007-12-13 | 2010-07-01 | Henkel Ag & Co. Kgaa | Hair-conditioning products containing cationic behenyl compounds and selected silicones and/or cosmetic oils |
Also Published As
Publication number | Publication date |
---|---|
US6274130B1 (en) | 2001-08-14 |
CA2184177A1 (en) | 1995-09-14 |
DE69513958D1 (en) | 2000-01-20 |
BR9507041A (en) | 1997-08-12 |
JPH09508419A (en) | 1997-08-26 |
AU702782B2 (en) | 1999-03-04 |
DE69513958T2 (en) | 2000-04-20 |
ES2139888T3 (en) | 2000-02-16 |
CN1092953C (en) | 2002-10-23 |
CA2184177C (en) | 2000-05-16 |
AU1892095A (en) | 1995-09-25 |
JP2931671B2 (en) | 1999-08-09 |
EP0749299B1 (en) | 1999-12-15 |
GB9404550D0 (en) | 1994-04-20 |
EP0749299B9 (en) | 2006-11-15 |
CN1143316A (en) | 1997-02-19 |
EP0749299A1 (en) | 1996-12-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6274130B1 (en) | Hair conditioning composition | |
EP0674898B1 (en) | Shampoo composition | |
US6355234B1 (en) | Shampoo compositions and method | |
US5776443A (en) | Hair care compositions | |
CA2075767C (en) | Cosmetic composition | |
CA2022901C (en) | Shampoo composition | |
US5990059A (en) | Shampoo composition | |
EP1035827B1 (en) | Hair treatment composition | |
MXPA01012363A (en) | Mousse-forming shampoo compositions. | |
US5554313A (en) | Conditioning shampoo containing insoluble, nonvolatile silicone | |
US20020081274A1 (en) | Personal cleansing compositions that contain surfactants, co-surfactants, water insoluble solids and/or liquids and cationic conditioning polymers | |
US20030133899A1 (en) | Personal cleansing compositions that contain surfactants, co-surfactants, water insoluble solids and/or liquids and cationic conditioning polymers | |
AU5524600A (en) | Hair treatment compositions | |
AU5505399A (en) | Hair treatment compositions | |
WO2000006096A1 (en) | Hair care compositions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 95192023.5 Country of ref document: CN |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AM AT AU BB BG BR BY CA CH CN CZ DE DK EE ES FI GB GE HU JP KE KG KP KR KZ LK LR LT LU LV MD MG MN MW MX NL NO NZ PL PT RO RU SD SE SG SI SK TJ TT UA UG UZ VN |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): KE MW SD SZ UG AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1995911274 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2184177 Country of ref document: CA |
|
WWP | Wipo information: published in national office |
Ref document number: 1995911274 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 1995911274 Country of ref document: EP |