WO1996022579A1 - Durable security laminate with hologram - Google Patents

Durable security laminate with hologram Download PDF

Info

Publication number
WO1996022579A1
WO1996022579A1 PCT/US1995/002196 US9502196W WO9622579A1 WO 1996022579 A1 WO1996022579 A1 WO 1996022579A1 US 9502196 W US9502196 W US 9502196W WO 9622579 A1 WO9622579 A1 WO 9622579A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
adhesive
adhesion enhancing
embossed
bond
Prior art date
Application number
PCT/US1995/002196
Other languages
French (fr)
Inventor
Lynn E. Faykish
Original Assignee
Minnesota Mining And Manufacturing Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining And Manufacturing Company filed Critical Minnesota Mining And Manufacturing Company
Priority to AU19679/95A priority Critical patent/AU688879B2/en
Priority to JP8507635A priority patent/JPH10512818A/en
Priority to KR1019970704872A priority patent/KR100344086B1/en
Publication of WO1996022579A1 publication Critical patent/WO1996022579A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06KGRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K19/00Record carriers for use with machines and with at least a part designed to carry digital markings
    • G06K19/06Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
    • G06K19/08Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means
    • G06K19/10Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means at least one kind of marking being used for authentication, e.g. of credit or identity cards
    • G06K19/16Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code using markings of different kinds or more than one marking of the same kind in the same record carrier, e.g. one marking being sensed by optical and the other by magnetic means at least one kind of marking being used for authentication, e.g. of credit or identity cards the marking being a hologram or diffraction grating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/302Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B42BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
    • B42DBOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
    • B42D25/00Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
    • B42D25/20Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof characterised by a particular use or purpose
    • B42D25/29Securities; Bank notes
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/32Holograms used as optical elements
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F3/0291Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
    • G09F3/0292Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2325/00Polymers of vinyl-aromatic compounds, e.g. polystyrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00Polyvinylhalogenides
    • B32B2327/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2333/00Polymers of unsaturated acids or derivatives thereof
    • B32B2333/04Polymers of esters
    • B32B2333/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2250/00Laminate comprising a hologram layer
    • G03H2250/12Special arrangement of layers
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2250/00Laminate comprising a hologram layer
    • G03H2250/35Adhesive layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24364Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.] with transparent or protective coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851Intermediate layer is discontinuous or differential
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851Intermediate layer is discontinuous or differential
    • Y10T428/2486Intermediate layer is discontinuous or differential with outer strippable or release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851Intermediate layer is discontinuous or differential
    • Y10T428/24868Translucent outer layer
    • Y10T428/24876Intermediate layer contains particulate material [e.g., pigment, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24917Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including metal layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797Next to addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31935Ester, halide or nitrile of addition polymer

Definitions

  • This invention relates to security laminates such as are used to protect documents from tampering or alteration.
  • Security laminates are traditionally used to protect documents or packages to ensure that the underlying items are not altered. Security laminates are particularly useful on identification cards such as driver's licenses and passports, and on other important documents such as certificates of title. Security laminates are also useful as tamper proof seals on medications, video cassettes, and compact discs. Five features are particularly important when producing and using security laminates. First, once applied to an article it is important that the laminate is difficult to remove to ensure that the underlying item is not altered or subjected to tampering. Second, a desirable laminate is difficult if not impossible to duplicate by counterfeiters. Third, if tampering occurs it is important to quickly and accurately recognize an altered or counterfeit laminate. Fourth, it is important that manufacturing costs of the laminates are not prohibitively expensive. Fifth, when used on articles such as identification cards, it is important that the laminate has sufficient durability to withstand harsh treatment.
  • Security laminates are constructed of various materials. In order to overcome the problem of counterfeit documents, manufacturers have made it exceedingly difficult for counterfeiters to duplicate the security laminate used on a particular document. Some constructions require special viewing devices to discern whether or not the laminate was subjected to tampering. Such laminates are disclosed in U.S. Patent Numbers 4,630,891, 5,080,463, and 5, 169,707. These laminates consist of a multilayer film with one of the layers comprised of a binder embedded with microspheres to impart a retroreflective appearance to the
  • the microsphere-containing layer is typically printed with a customer- specified logo.
  • the retroreflective laminate is adhesively bound to the document.
  • Multilayer film constructions containing intermediate layers having optical properties such as holograms or kinegrams are often used in security laminates.
  • European Patent Publication Nos. EP-A-253 and EP-A-401 describe such laminate constructions. If the security laminate in these constructions is disturbed due to tampering, the holograms are destroyed. Tampering is therefore readily apparent when viewing the document with the naked eye.
  • the film layer containing the holographic optical pattern is not transparent and is also quite expensive.
  • German Patent Application No. DE-C-25 11 367 discloses laminating a document between two films and further including a pattern of adhesion-reducing coating either on the film or on the document before laminating. Once the layers are laminated, little or no bond exists in those places coated with the adhesion-reducing coating. Attempts to tamper with a document laminated with such a construction ordinarily results in destruction of the article to which the laminate is adhered. However, skilled tamperers are capable of removing the film without damaging the underlying article by using heat.
  • U.S. Patent Nos. 4,876,123 and 5,082,702 disclose tamper-proof multilayer films which are not transparent. During attempts to tamper, the multilayer constructions are destroyed and both sides of the separated film layers display an originally concealed colored print. Tampering with these constructions is apparent to the unaided eye and the films are also impossible to relaminate without visible damage. However, laminates having these constructions are not useful on identification documents because they are not transparent.
  • U.S. Patent No. 5,153,042 discloses a tamper-indicating labelstock or security laminate comprised of a transparent facestock, a release coating attached to one surface of the facestock for providing an indicia, a polymer coated on the facestock and release coating, a frangible metal layer, and an adhesive layer.
  • the labelstock is easily broken when tampering occurs which reveals the indicia printed by the release coating. Construction of this laminate requires flood coating primer over the release coating. Since the laminate is intended for use as a labelstock, it is easily delaminated. Such a construction is not ideal for security laminates used to protect documents because the laminate is not durable enough and would split prematurely under everyday abuse. Also, this type of construction is easily delaminated with heat, rendering tampering possible.
  • a transparent self-adhesive film which includes printing is described in German Patent Application No. DE-A-28 03 434.
  • the printing remains on the document. If a photograph is exchanged for the original, the tamperer must only reproduce the printing on the new photograph which is a relatively easy task for a skilled tamperer. Constructions such as those described do not overcome the problem of imitation by counterfeiters.
  • Security laminates have also included an intermediate layer of ink- containing microcapsules as described in French Publication No. FR-A-2-451-081. The capsules break during tampering which results in discoloration of the document.
  • microcapsules create at least two disadvantages which are unacceptable in the field of transparent security laminates.
  • the microcapsules reduce the transparency of the film and the microcapsules frequently tend to break during normal use of the document. Thus, such a laminate is too fragile for use on identification cards subjected to daily abuses which would cause the microcapsules to fracture.
  • a document is coated with a polyethylene film coated with an adhesive which requires cross-linking by ultraviolet irradiation.
  • the resultant laminate provides a high degree of security, however, it is again prohibitively expensive to place irradiation equipment and the corresponding protection equipment at every document distribution location.
  • a security laminate comprising a (1) protective layer having a first and a second surface, (2) an embossed layer comprising either embossing directly into the second surface of the protective layer or comprising a separate embossed layer or bonded to at least a portion of the second surface of the protective layer, (3) a reflective layer bonded to at least a portion of the embossed layer/protective layer composite, (4) an adhesion enhancing layer bonded to a portion of the reflective layer/embossed layer/protective layer composite, and (5) an adhesive bonded to at least a portion of the adhesion enhancing layer/reflective layer/embossed layer/protective layer composite wherein the bond between the reflective layer and the adhesion enhancing layer and the bond between the adhesion enhancing layer and the adhesive are each more tenacious than the bond between the reflective layer and the embossed layer, further wherein the bond between the adhesive and the adhesion enhancing layer is more tenacious than the bond between the adhesive and the reflective layer.
  • FIG. 1 is an exploded sectional side view of the security laminate of the present invention adhered to a document.
  • FIG. 2 is a section view of the security laminate of the present invention after an attempt to delaminate the document to which the security laminate was adhered under ambient conditions.
  • FIG. 3 is a top view of the laminate of Fig. 2
  • FIG. 4 is a top view of the document from which the laminate of Fig. 3 was removed.
  • FIG. 5 is a section view of the security laminate of the present invention after an attempt to delaminate the document using heat.
  • the laminate of the present invention is shown generally in Figure 1 as 26.
  • the laminate of the invention is comprised of the following layers designated as the protective layer 10, embossed layer 14, reflective layer 20, adhesion enhancing layer 12, and the adhesive layer 16.
  • the protective layer 10 embossed layer 14
  • the reflective layer 20 reflective layer 20
  • adhesion enhancing layer 12 adhesion enhancing layer 16
  • the adhesive layer 16 Each of the layers is first described in detail followed by a discussion of the interaction of the layers by the corresponding tenacities of the bonds between the layers.
  • the term "delaminate” refers to removing or attempting to remove a laminate from the document or article to which the laminate is adhered.
  • a protective layer 10 is provided.
  • the protective layer 10 provides protection for the security laminate and document, protecting the article against cuts, scratches or other similar abuse.
  • the protective layer 10 ultimately covers the underlying article or document 18 such that one must lift the protective layer 10, along with the rest of the laminate, in order to tamper with the article 18.
  • the protective layer 10 is preferably transparent, allowing use of the security laminate 26 on identification documents such as driver's licenses and passports.
  • the protective layer 10 is preferably substantially impervious to scratches. This characteristic permits use of the laminate 26 on articles which are subjected to daily abuse.
  • suitable materials for the protective layer of the invention include polyethylene terephthalate (polyester), polyvinyl chloride, polyolefin, or cellulose acetate films.
  • polyester is used if the invention is intended for use on identification documents, whereas polyvinyl chloride is the preferred protective layer material if the laminate is intended for use on lower value documents or items in order to limit material costs.
  • the protective layer 10 is coated with a deformable material 14 which readily deforms when subjected to heat and pressure.
  • a material suitable for embossing is a resin which readily adheres to the protective layer 10. If the protective layer 10 is polyester, some preferred materials for the embossing resin are polystyrene, polymethyl methacrylate, or nitrocellulose-based resins.
  • the embossing layer 14 is preferably embossed with a micro-structured relief pattern of holographic or diffraction grating images in the form of logos or patterns which reflect light.
  • embossing is preferably done by contacting a non- deformable embossing plate to the embossing layer 14 using heat and pressure
  • an alternate embodiment includes curing polyacrylate or polyurethane-based embossing resins using ultraviolet light during embossing.
  • logos are embossed directly into the second side of the protective layer 10 using heat and pressure.
  • Reflective Laver The reflective layer 20 is coated on the embossed layer 14 either before or after embossing.
  • Reflective layer 20 preferably has a higher refractive index than the embossed layer 14.
  • the reflective layer 20 is substantially transparent and colorless.
  • suitable reflective layer materials include but are not limited to bismuth trioxide, zinc sulfide, titanium dioxide and zirconium oxide which are described in U.S.
  • Patent No. 4,856,857 The reflective layer 20 enhances the reflection of light through the embossed 14 and protective layers 10 due to the difference in refractive index between the embossed 14 and reflective layers 20.
  • the embossing is more readily visible to the naked eye once the reflective layer 20 is coated on the embossing, and an adhesive can be applied without diminishing the visibility of the embossed pattern.
  • Suitable holographic films with embossed and reflective layers are available from Crown Roll Leaf of Paterson, NJ, Transfer Print Foils of East Brunswick, NJ, or Optical Security Industries of London, England.
  • Adhesion Enhancing Laver An adhesion enhancing layer 12 which is preferably transparent is next applied to the reflective layer 20.
  • the adhesion enhancing layer 12 is preferably printed on the reflective layer 20 in a repetitive or easily recognizable pattern such that the adhesion enhancing layer 12 only partially covers the reflective layer 20. Examples of some preferred patterns for printing the adhesion enhancing layer 12 include, but are not limited to, checkerboards, dots, legible messages such as "VOID" and logos.
  • the adhesion enhancing layer 12 prohibits removal of the reflective layer 20 from the document 18 in those areas printed with the adhesion enhancing layer 12.
  • the adhesion enhancing layer 12 in part allows for controlled failure of the laminate composite 26.
  • Fig. 3 depicts a laminate which was removed from an article having an adhesion enhancing layer 12 printed in a checkerboard fashion.
  • suitable materials for the adhesion enhancing layer are water-based vinyl acetate or preferably ethylene acrylic acid resins.
  • the purpose of the adhesion enhancing layer 12 is more fully described below when interaction of the layers and corresponding bonds between the adjacent layers of the present invention are discussed.
  • Adhesive Layer An adhesive 16 is bonded to the adhesion enhancing layer 12/reflective layer 20/embossed layer 14/protective layer 10 composite.
  • the adhesive allows adherence of the laminate composite to an article or document 18.
  • Heat-activated adhesives or pressure sensitive adhesives can be used in the present invention.
  • suitable heat- activated adhesives are polyethylene based copolymers such as ethylene acrylic acid, ethylene ethyl acrylate, and preferably, ethylene vinyl acetate. Due to the construction of the present laminate, the reflective layer splits in the pattern of the adhesion enhancing layer, pulling apart the reflective layer and evidencing tampering when delaminated.
  • a laminate of the present invention which uses pressure sensitive adhesive will evidence tampering if the document is delaminated under heated conditions.
  • Pressure sensitive adhesives do soften when heated; however, due to the construction of the present invention, the adhesive splits and pulls apart in the pattern of the adhesion enhancing coating even when heated, evidencing tampering.
  • suitable pressure sensitive adhesives are PSA 966 Scotch Brand High Temperature Acrylic adhesive and IsotacTM acrylic adhesive, both available from Minnesota Mining and Manufacturing Company of St. Paul, MN.
  • the relative bond tenacities between the adjacent layers of the laminate are important to the present invention.
  • a controlled failure is preferred when an attempt is made to delaminate documents laminated with the present invention. Separation of the layers due to delamination is first discussed followed by a discussion of the relative bond tenacities between the layers required to obtain such a controlled failure of the laminate.
  • the laminate of the invention splits substantially in a manner depicted in Figure 2 when the adhesive 16 is a heat-activated adhesive.
  • the protective layer 10 lifts, bringing with it the embossed layer 14 and the reflective layer 20 in the areas where the adhesion enhancing layer 12 is absent.
  • the adhesion enhancing layer 12 only partially covers the reflective layer 20 which causes the reflective layer 20 to split. Due to the different tenacities of the bonds between the reflective layer 20 and its adjacent layers, the reflective layer 20 splits substantially in the pattern of the printing of the adhesion enhancing layer 12.
  • Fig. 3 depicts a top view of a laminate of the invention removed from a document to which it was previously adhered.
  • Fig. 4 depicts a top view of the document from which the laminate of Fig. 3 was removed.
  • the cross-hatched areas 32 and 42 in Figures 3 and 4 depict areas where the reflective layer is adhered.
  • the cross-hatched areas in Figure 3 are complementary to the cross-hatched areas in Figure 4.
  • the areas represented as 32 (cross-hatched) on Fig. 4 show where the adhesion enhancing layer was printed and the reflective layer therefore adhered upon delamination. Areas depicted as 34 (not cross-hatched) on the document in Fig.
  • FIG. 4 show where the adhesion enhancing coating was absent and the reflective layer did not adhere.
  • areas depicted as 42 show where the adhesive enhancing coating was absent and the reflective layer 42 therefore adhered to the embossed layer 14 shown in Fig. 3 in a checkerboard pattern complementary to the areas which the reflective layer is adhered to the document in Fig. 4.
  • the embossed layer is visible in the shape of emblems 44 in Fig. 3.
  • the embossed layer 14 (as shown in Fig. 2) remains substantially adhered to the protective coating 10 after delamination, leaving the emblems 44 (as shown in Fig. 3) substantially intact.
  • the reflective layer 20 splits and adheres to the embossed layer 14/protective layer 10 composite in a checkerboard pattern.
  • the reflective layer 20 also adheres to the adhesive 16 and the document 18 in a checkerboard pattern. This controlled failure renders it very difficult to reach the underlying document 18 in order to alter the document without evidencing the tampering.
  • the laminate It is not possible to adhere the laminate back together on the document without detection because it is impossible to match the split reflector layer 20 in order to reconstruct the continuous reflection of the embossed layer 14.
  • the peeled laminate is not reusable on a different document because the areas of missing reflector create a discontinuous reflection of the embossed layer 14 when relaminated.
  • the bond between the reflective layer 20 and the adhesion enhancing layer 12 and the bond between the adhesion enhancing layer 12 and the adhesive 16 are each more tenacious then the bond between the reflective layer 20 and the embossed layer 14.
  • the laminate of the invention splits substantially in a manner depicted in Figure 5 when heat is used in an attempt to delaminate the document 18.
  • the protective layer 10 lifts, bringing with it the embossed layer 14, the reflective layer 20, the adhesion enhancing layer 12, and the adhesive 16 in the areas where the adhesion enhancing layer 12 is present. Due to different tenacities of the bonds between the adhesive 16 and its adjacent layers, the adhesive 16 splits substantially in the pattern of the adhesion enhancing layer 12 when heat is used for delamination. In order to obtain such controlled failures upon delaminating, the bond between the adhesive 16 and the adhesion enhancing layer 12 is more tenacious than the bond between the adhesive 16 and the reflective layer 20. However, all of the bonds between all layers are preferably still be strong enough to provide a durable laminate for ID cards.
  • Durability testing includes (1) exposing a security laminated document to a laundry and to a drying cycle, (2) flexing the document, and (3) shaking the document in a paint shaker with sand and water.
  • Laminates with the constructions described above can withstand such durability testing, described more fully below. By withstanding durability testing it is meant that if the security laminate of the invention is adhered to a standard identification card, the laminate will show substantially no premature release between any layers.
  • the selection of the protective layer 10, the embossed layer 14, the adhesion enhancing coating 12, the reflective layer 20 and the adhesive 16 is made as a combination to provide suitable bond tenacities between the adjacent layers.
  • Illustrative examples of combinations providing suitable bond tenacity differentials are presented in the Examples below. It is contemplated that many other combinations will also satisfy the requirements for constructing a security laminate according to the present invention.
  • Example 1 Laminate Preparation
  • a transparent hologram film type XPT as purchased from Crown Roll Leaf of Paterson, NJ, was used in the present Example. It is believed that the Crown Roll Leaf hologram was prepared by embossing a holographic image into polystyrene-based embossing resin with a high index reflector, such as zinc sulfide, which were coated on a polyester film.
  • the reflector side of the purchased hologram film was flexographically printed with a checkerboard pattern of adhesion enhancing coating.
  • Adcote 50T4983 water-based ethylene acrylic acid as manufactured by Morton International, Inc. of Chicago, IL was used as the adhesion enhancing coating.
  • the adhesion enhancing printed side was treated using corona discharge.
  • a film of ethylene vinyl acetate heat activated adhesive was corona treated, then hot laminated at 270°F (132°C) to the adhesion enhancing printed side to form a laminate using Desk Top Heat Laminator Model No. 5000 as manufactured by Thermal Laminating Corporation of Chicago, IL.
  • the holographic laminate was then applied to photographic- based identification cards using the same laminator.
  • the photographic-based identification cards were dry gelatin-based photos with a picture and personal data photographically imaged onto the document.
  • the laminate was peeled from a card at room temperature in an attempt to reach and alter the underlying identification card.
  • the protective layer of the laminate was lifted along with the embossed layer and the reflective layer in the areas which were not adhered to the adhesion enhancing patterned layer. Because the adhesion enhancing layer was originally printed on the reflective layer in a checkerboard pattern, the reflective layer was caused to split in a checkerboard fashion complementary to the pattern of the adhesion enhancing layer due to the differential bond tenacity between each of the layers.
  • a laminated card was soaked in water for 24 hours. Upon an attempt to remove the laminate from the document, the reflective layer split in the pattern of adhesion enhancing coating. Due to the damage rendered to the reflector, it was impossible to relaminate the same card or to use the laminate on a different card without evidence of tampering.
  • a laminated card was placed in a washing machine filled with clothes and placed on the permanent press cycle followed by drying for 30 minutes on the permanent press cycle. The laminate and card were not damaged.
  • a laminated card was flexed back and forth at 90 degree angles for 1000 cycles using a Getty Fatigue Flex Tester model #0 manufactured by Getty Machine and Mold Company of Clifton, NJ. The laminate and card were not damaged.
  • Example 2 The protocol of Example 1 for the laminate preparation was followed except that a pressure-sensitive adhesive was used to adhere the laminate to the document in place of the corona treatment and heat activated adhesive.
  • PSA 966 Scotch Brand High Temperature Acrylic adhesive coated on a silicone release liner available from 3M Company of St. Paul, MN was laminated to the polyester/embossing layer/reflective layer/adhesion enhancing layer composite using a hand squeegee.
  • the laminate was applied to a photo adhered to a paper document also using a hand squeegee.
  • Another laminated document was heated to between about 210°F (99°C) and about 250°F (121 °C) on a hot plate and the laminate was peeled from the document at the elevated temperature to determine whether it was possible to heat delaminate the document.
  • the adhesive layer split in the pattern of the adhesion enhancing coating, causing some adhesive to adhere to the document where the adhesion enhancing pattern was not present and some adhesive to adhere to the laminate where the adhesion enhancing pattern was present. Due to the textured damage of the adhesive, it was impossible to relaminate the same document or to use the laminate on a different document without evidence of tampering.
  • a transparent hologram film was purchased from Transfer Print Foils of East Brunswick, NJ. It is believed that the hologram was prepared by embossing a holographic image into nitrocellulose-based embossing resin with a high index reflector, such as zinc sulfide, which were coated on a polyester film. The protocol of Example 1 was then followed to print the adhesion enhancing pattern and to laminate the heat activated adhesive. Two pieces of the laminate were heat laminated together with the adhesive sides facing each other. The pieces were pulled apart by hand. The adhesive and reflector layers split in the adhesion enhancing pattern which caused damage to both pieces of laminate.
  • Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention.

Abstract

A security laminate comprising a protective layer having first and second surfaces, an embossing layer bonded to at least a portion of the second surface of the protective layer, a reflective layer bonded to at least a portion of the embossed layer/protective layer composite, an adhesion enhancing layer bonded to a portion of the reflective layer/embossed layer/protective layer composite, an adhesive bonded to at least a portion of the adhesion enhancing layer/reflective layer/embossed layer/protective layer composite wherein the bond between the reflective layer and the adhesion enhancing layer and the bond between the adhesion enhancing layer and the adhesive are each more tenacious than the bond between the reflective layer and the embossed layer and further wherein the bond between the adhesive and the adhesion enhancing layer is more tenacious than the bond between the adhesive and the reflective layer.

Description

DURABLE SECURITY LAMINATE WITH HOLOGRAM
Field of the Invention
This invention relates to security laminates such as are used to protect documents from tampering or alteration.
Background of the Invention
Security laminates are traditionally used to protect documents or packages to ensure that the underlying items are not altered. Security laminates are particularly useful on identification cards such as driver's licenses and passports, and on other important documents such as certificates of title. Security laminates are also useful as tamper proof seals on medications, video cassettes, and compact discs. Five features are particularly important when producing and using security laminates. First, once applied to an article it is important that the laminate is difficult to remove to ensure that the underlying item is not altered or subjected to tampering. Second, a desirable laminate is difficult if not impossible to duplicate by counterfeiters. Third, if tampering occurs it is important to quickly and accurately recognize an altered or counterfeit laminate. Fourth, it is important that manufacturing costs of the laminates are not prohibitively expensive. Fifth, when used on articles such as identification cards, it is important that the laminate has sufficient durability to withstand harsh treatment.
Security laminates are constructed of various materials. In order to overcome the problem of counterfeit documents, manufacturers have made it exceedingly difficult for counterfeiters to duplicate the security laminate used on a particular document. Some constructions require special viewing devices to discern whether or not the laminate was subjected to tampering. Such laminates are disclosed in U.S. Patent Numbers 4,630,891, 5,080,463, and 5, 169,707. These laminates consist of a multilayer film with one of the layers comprised of a binder embedded with microspheres to impart a retroreflective appearance to the
- l - laminate. The microsphere-containing layer is typically printed with a customer- specified logo. The retroreflective laminate is adhesively bound to the document. These constructions are difficult to imitate by counterfeiters because it is difficult to imitate the customer-specific retroreflective printing. However, in order to determine authenticity of the laminates, special retroreflective viewing equipment is required to view the customer-specific printing. Tampering is indicated by damage to the continuity of the retroreflective layer, visible as dark lines or discoloration which does not retroreflect. Therefore, it is difficult to detect authenticity of the document with the naked eye. This type of laminate is also expensive to manufacture due to multiple layers and a sophisticated process control which is necessary to manufacture the laminate.
Multilayer film constructions containing intermediate layers having optical properties such as holograms or kinegrams are often used in security laminates. European Patent Publication Nos. EP-A-253 and EP-A-401 describe such laminate constructions. If the security laminate in these constructions is disturbed due to tampering, the holograms are destroyed. Tampering is therefore readily apparent when viewing the document with the naked eye. However, the film layer containing the holographic optical pattern is not transparent and is also quite expensive. These laminate constructions do not overcome all of the problems associated with security laminates because it is undesirable to cover an entire document or package with an opaque, expensive multilayer film. Further, it is necessary to properly register the opaque hologram on the document so as not to obscure any underlying data.
One relatively inexpensive laminate construction is described in German Patent Application No. DE-C-25 11 367. This reference discloses laminating a document between two films and further including a pattern of adhesion-reducing coating either on the film or on the document before laminating. Once the layers are laminated, little or no bond exists in those places coated with the adhesion-reducing coating. Attempts to tamper with a document laminated with such a construction ordinarily results in destruction of the article to which the laminate is adhered. However, skilled tamperers are capable of removing the film without damaging the underlying article by using heat.
U.S. Patent Nos. 4,876,123 and 5,082,702 disclose tamper-proof multilayer films which are not transparent. During attempts to tamper, the multilayer constructions are destroyed and both sides of the separated film layers display an originally concealed colored print. Tampering with these constructions is apparent to the unaided eye and the films are also impossible to relaminate without visible damage. However, laminates having these constructions are not useful on identification documents because they are not transparent.
U.S. Patent No. 5,153,042 discloses a tamper-indicating labelstock or security laminate comprised of a transparent facestock, a release coating attached to one surface of the facestock for providing an indicia, a polymer coated on the facestock and release coating, a frangible metal layer, and an adhesive layer. The labelstock is easily broken when tampering occurs which reveals the indicia printed by the release coating. Construction of this laminate requires flood coating primer over the release coating. Since the laminate is intended for use as a labelstock, it is easily delaminated. Such a construction is not ideal for security laminates used to protect documents because the laminate is not durable enough and would split prematurely under everyday abuse. Also, this type of construction is easily delaminated with heat, rendering tampering possible.
A transparent self-adhesive film which includes printing is described in German Patent Application No. DE-A-28 03 434. When the film is lifted during tampering, the printing remains on the document. If a photograph is exchanged for the original, the tamperer must only reproduce the printing on the new photograph which is a relatively easy task for a skilled tamperer. Constructions such as those described do not overcome the problem of imitation by counterfeiters. Security laminates have also included an intermediate layer of ink- containing microcapsules as described in French Publication No. FR-A-2-451-081. The capsules break during tampering which results in discoloration of the document. Although tampering is readily apparent to the unaided eye, the microcapsules create at least two disadvantages which are unacceptable in the field of transparent security laminates. The microcapsules reduce the transparency of the film and the microcapsules frequently tend to break during normal use of the document. Thus, such a laminate is too fragile for use on identification cards subjected to daily abuses which would cause the microcapsules to fracture.
Another method of manufacturing tamper-proof documents is described in German Patent No. DE-C-29 52 322. A document is coated with a polyethylene film coated with an adhesive which requires cross-linking by ultraviolet irradiation. The resultant laminate provides a high degree of security, however, it is again prohibitively expensive to place irradiation equipment and the corresponding protection equipment at every document distribution location.
None of the references described above solve the above-mentioned problems with security laminates. That is, a security laminate which is transparent, inexpensive to manufacture, difficult to imitate by counterfeiters, readily evidences tampering, and is sufficiently durable to use on identification cards.
Summary of the Invention
A security laminate comprising a (1) protective layer having a first and a second surface, (2) an embossed layer comprising either embossing directly into the second surface of the protective layer or comprising a separate embossed layer or bonded to at least a portion of the second surface of the protective layer, (3) a reflective layer bonded to at least a portion of the embossed layer/protective layer composite, (4) an adhesion enhancing layer bonded to a portion of the reflective layer/embossed layer/protective layer composite, and (5) an adhesive bonded to at least a portion of the adhesion enhancing layer/reflective layer/embossed layer/protective layer composite wherein the bond between the reflective layer and the adhesion enhancing layer and the bond between the adhesion enhancing layer and the adhesive are each more tenacious than the bond between the reflective layer and the embossed layer, further wherein the bond between the adhesive and the adhesion enhancing layer is more tenacious than the bond between the adhesive and the reflective layer.
Brief Description of the Drawings The invention is further explained with reference to the drawings wherein:
FIG. 1 is an exploded sectional side view of the security laminate of the present invention adhered to a document.
FIG. 2 is a section view of the security laminate of the present invention after an attempt to delaminate the document to which the security laminate was adhered under ambient conditions.
FIG. 3 is a top view of the laminate of Fig. 2 FIG. 4 is a top view of the document from which the laminate of Fig. 3 was removed. FIG. 5 is a section view of the security laminate of the present invention after an attempt to delaminate the document using heat.
These figures, which are idealized and are not to scale, are intended as merely illustrative and nonlimiting.
Detailed Description of the Invention
The laminate of the present invention is shown generally in Figure 1 as 26. The laminate of the invention is comprised of the following layers designated as the protective layer 10, embossed layer 14, reflective layer 20, adhesion enhancing layer 12, and the adhesive layer 16. Each of the layers is first described in detail followed by a discussion of the interaction of the layers by the corresponding tenacities of the bonds between the layers. For purposes of this disclosure, the term "delaminate" refers to removing or attempting to remove a laminate from the document or article to which the laminate is adhered.
Protective Laver
A protective layer 10 is provided. The protective layer 10 provides protection for the security laminate and document, protecting the article against cuts, scratches or other similar abuse. In addition, the protective layer 10 ultimately covers the underlying article or document 18 such that one must lift the protective layer 10, along with the rest of the laminate, in order to tamper with the article 18. The protective layer 10 is preferably transparent, allowing use of the security laminate 26 on identification documents such as driver's licenses and passports. Additionally, the protective layer 10 is preferably substantially impervious to scratches. This characteristic permits use of the laminate 26 on articles which are subjected to daily abuse. Illustrative examples of suitable materials for the protective layer of the invention include polyethylene terephthalate (polyester), polyvinyl chloride, polyolefin, or cellulose acetate films. Preferably, polyester is used if the invention is intended for use on identification documents, whereas polyvinyl chloride is the preferred protective layer material if the laminate is intended for use on lower value documents or items in order to limit material costs.
Embossed Laver
In one embodiment of the invention, the protective layer 10 is coated with a deformable material 14 which readily deforms when subjected to heat and pressure. An example of a material suitable for embossing is a resin which readily adheres to the protective layer 10. If the protective layer 10 is polyester, some preferred materials for the embossing resin are polystyrene, polymethyl methacrylate, or nitrocellulose-based resins. In one embodiment the embossing layer 14 is preferably embossed with a micro-structured relief pattern of holographic or diffraction grating images in the form of logos or patterns which reflect light. Although embossing is preferably done by contacting a non- deformable embossing plate to the embossing layer 14 using heat and pressure, an alternate embodiment includes curing polyacrylate or polyurethane-based embossing resins using ultraviolet light during embossing. In yet an alternate embodiment, logos are embossed directly into the second side of the protective layer 10 using heat and pressure.
Reflective Laver The reflective layer 20 is coated on the embossed layer 14 either before or after embossing. Reflective layer 20 preferably has a higher refractive index than the embossed layer 14. In a preferred embodiment, the reflective layer 20 is substantially transparent and colorless. Illustrative examples of suitable reflective layer materials include but are not limited to bismuth trioxide, zinc sulfide, titanium dioxide and zirconium oxide which are described in U.S.
Patent No. 4,856,857. The reflective layer 20 enhances the reflection of light through the embossed 14 and protective layers 10 due to the difference in refractive index between the embossed 14 and reflective layers 20. Thus, the embossing is more readily visible to the naked eye once the reflective layer 20 is coated on the embossing, and an adhesive can be applied without diminishing the visibility of the embossed pattern. Suitable holographic films with embossed and reflective layers are available from Crown Roll Leaf of Paterson, NJ, Transfer Print Foils of East Brunswick, NJ, or Optical Security Industries of London, England.
Adhesion Enhancing Laver An adhesion enhancing layer 12 which is preferably transparent is next applied to the reflective layer 20. The adhesion enhancing layer 12 is preferably printed on the reflective layer 20 in a repetitive or easily recognizable pattern such that the adhesion enhancing layer 12 only partially covers the reflective layer 20. Examples of some preferred patterns for printing the adhesion enhancing layer 12 include, but are not limited to, checkerboards, dots, legible messages such as "VOID" and logos.
During delamination, the adhesion enhancing layer 12 prohibits removal of the reflective layer 20 from the document 18 in those areas printed with the adhesion enhancing layer 12. The adhesion enhancing layer 12 in part allows for controlled failure of the laminate composite 26. Fig. 3 depicts a laminate which was removed from an article having an adhesion enhancing layer 12 printed in a checkerboard fashion. Illustrative examples of suitable materials for the adhesion enhancing layer are water-based vinyl acetate or preferably ethylene acrylic acid resins. The purpose of the adhesion enhancing layer 12 is more fully described below when interaction of the layers and corresponding bonds between the adjacent layers of the present invention are discussed.
Adhesive Layer An adhesive 16 is bonded to the adhesion enhancing layer 12/reflective layer 20/embossed layer 14/protective layer 10 composite. Among other things, the adhesive allows adherence of the laminate composite to an article or document 18. Heat-activated adhesives or pressure sensitive adhesives can be used in the present invention. Illustrative examples of suitable heat- activated adhesives are polyethylene based copolymers such as ethylene acrylic acid, ethylene ethyl acrylate, and preferably, ethylene vinyl acetate. Due to the construction of the present laminate, the reflective layer splits in the pattern of the adhesion enhancing layer, pulling apart the reflective layer and evidencing tampering when delaminated.
A laminate of the present invention which uses pressure sensitive adhesive will evidence tampering if the document is delaminated under heated conditions. Pressure sensitive adhesives do soften when heated; however, due to the construction of the present invention, the adhesive splits and pulls apart in the pattern of the adhesion enhancing coating even when heated, evidencing tampering. Illustrative examples of suitable pressure sensitive adhesives are PSA 966 Scotch Brand High Temperature Acrylic adhesive and Isotac™ acrylic adhesive, both available from Minnesota Mining and Manufacturing Company of St. Paul, MN.
Bond Tenacities
The relative bond tenacities between the adjacent layers of the laminate are important to the present invention. A controlled failure is preferred when an attempt is made to delaminate documents laminated with the present invention. Separation of the layers due to delamination is first discussed followed by a discussion of the relative bond tenacities between the layers required to obtain such a controlled failure of the laminate.
Upon an attempt to remove the laminate 26 from a document 18, the laminate of the invention splits substantially in a manner depicted in Figure 2 when the adhesive 16 is a heat-activated adhesive. The protective layer 10 lifts, bringing with it the embossed layer 14 and the reflective layer 20 in the areas where the adhesion enhancing layer 12 is absent. The adhesion enhancing layer 12 only partially covers the reflective layer 20 which causes the reflective layer 20 to split. Due to the different tenacities of the bonds between the reflective layer 20 and its adjacent layers, the reflective layer 20 splits substantially in the pattern of the printing of the adhesion enhancing layer 12.
Fig. 3 depicts a top view of a laminate of the invention removed from a document to which it was previously adhered. Fig. 4 depicts a top view of the document from which the laminate of Fig. 3 was removed. Upon an attempt to delaminate a document, the reflective layer 20 of the security laminate splits. The cross-hatched areas 32 and 42 in Figures 3 and 4 depict areas where the reflective layer is adhered. The cross-hatched areas in Figure 3 are complementary to the cross-hatched areas in Figure 4. The areas represented as 32 (cross-hatched) on Fig. 4 show where the adhesion enhancing layer was printed and the reflective layer therefore adhered upon delamination. Areas depicted as 34 (not cross-hatched) on the document in Fig. 4 show where the adhesion enhancing coating was absent and the reflective layer did not adhere. In Fig. 3 areas depicted as 42 (cross-hatched) show where the adhesive enhancing coating was absent and the reflective layer 42 therefore adhered to the embossed layer 14 shown in Fig. 3 in a checkerboard pattern complementary to the areas which the reflective layer is adhered to the document in Fig. 4.
The embossed layer is visible in the shape of emblems 44 in Fig. 3. The embossed layer 14 (as shown in Fig. 2) remains substantially adhered to the protective coating 10 after delamination, leaving the emblems 44 (as shown in Fig. 3) substantially intact. Referring now to Fig. 2, the reflective layer 20 splits and adheres to the embossed layer 14/protective layer 10 composite in a checkerboard pattern. The reflective layer 20 also adheres to the adhesive 16 and the document 18 in a checkerboard pattern. This controlled failure renders it very difficult to reach the underlying document 18 in order to alter the document without evidencing the tampering. It is not possible to adhere the laminate back together on the document without detection because it is impossible to match the split reflector layer 20 in order to reconstruct the continuous reflection of the embossed layer 14. The peeled laminate is not reusable on a different document because the areas of missing reflector create a discontinuous reflection of the embossed layer 14 when relaminated. In order to obtain such a controlled failure upon delaminating, the bond between the reflective layer 20 and the adhesion enhancing layer 12 and the bond between the adhesion enhancing layer 12 and the adhesive 16 are each more tenacious then the bond between the reflective layer 20 and the embossed layer 14.
When the adhesive 16 is a pressure sensitive adhesive, the laminate of the invention splits substantially in a manner depicted in Figure 5 when heat is used in an attempt to delaminate the document 18. The protective layer 10 lifts, bringing with it the embossed layer 14, the reflective layer 20, the adhesion enhancing layer 12, and the adhesive 16 in the areas where the adhesion enhancing layer 12 is present. Due to different tenacities of the bonds between the adhesive 16 and its adjacent layers, the adhesive 16 splits substantially in the pattern of the adhesion enhancing layer 12 when heat is used for delamination. In order to obtain such controlled failures upon delaminating, the bond between the adhesive 16 and the adhesion enhancing layer 12 is more tenacious than the bond between the adhesive 16 and the reflective layer 20. However, all of the bonds between all layers are preferably still be strong enough to provide a durable laminate for ID cards.
Durability testing includes (1) exposing a security laminated document to a laundry and to a drying cycle, (2) flexing the document, and (3) shaking the document in a paint shaker with sand and water. Laminates with the constructions described above can withstand such durability testing, described more fully below. By withstanding durability testing it is meant that if the security laminate of the invention is adhered to a standard identification card, the laminate will show substantially no premature release between any layers.
The selection of the protective layer 10, the embossed layer 14, the adhesion enhancing coating 12, the reflective layer 20 and the adhesive 16 is made as a combination to provide suitable bond tenacities between the adjacent layers. Illustrative examples of combinations providing suitable bond tenacity differentials are presented in the Examples below. It is contemplated that many other combinations will also satisfy the requirements for constructing a security laminate according to the present invention.
Examples The invention is further explained by the following illustrative examples which are intended as non-limiting.
Each Example includes a discussion of how the particular laminate was manufactured, how the laminate was applied to a document, and finally, how the laminate appeared after delamination. Example 1 Laminate Preparation
A transparent hologram film type XPT, as purchased from Crown Roll Leaf of Paterson, NJ, was used in the present Example. It is believed that the Crown Roll Leaf hologram was prepared by embossing a holographic image into polystyrene-based embossing resin with a high index reflector, such as zinc sulfide, which were coated on a polyester film. The reflector side of the purchased hologram film was flexographically printed with a checkerboard pattern of adhesion enhancing coating. Adcote 50T4983 water-based ethylene acrylic acid as manufactured by Morton International, Inc. of Chicago, IL was used as the adhesion enhancing coating. The adhesion enhancing printed side was treated using corona discharge. A film of ethylene vinyl acetate heat activated adhesive was corona treated, then hot laminated at 270°F (132°C) to the adhesion enhancing printed side to form a laminate using Desk Top Heat Laminator Model No. 5000 as manufactured by Thermal Laminating Corporation of Chicago, IL. The holographic laminate was then applied to photographic- based identification cards using the same laminator. The photographic-based identification cards were dry gelatin-based photos with a picture and personal data photographically imaged onto the document.
Tampering Ambient Temperature
The laminate was peeled from a card at room temperature in an attempt to reach and alter the underlying identification card. The protective layer of the laminate was lifted along with the embossed layer and the reflective layer in the areas which were not adhered to the adhesion enhancing patterned layer. Because the adhesion enhancing layer was originally printed on the reflective layer in a checkerboard pattern, the reflective layer was caused to split in a checkerboard fashion complementary to the pattern of the adhesion enhancing layer due to the differential bond tenacity between each of the layers.
Water
A laminated card was soaked in water for 24 hours. Upon an attempt to remove the laminate from the document, the reflective layer split in the pattern of adhesion enhancing coating. Due to the damage rendered to the reflector, it was impossible to relaminate the same card or to use the laminate on a different card without evidence of tampering.
Durability Testing Additional laminated cards were subjected to the following tests to evaluate the durability of the construction:
A. Washing Machine
A laminated card was placed in a washing machine filled with clothes and placed on the permanent press cycle followed by drying for 30 minutes on the permanent press cycle. The laminate and card were not damaged.
B. Flexing
A laminated card was flexed back and forth at 90 degree angles for 1000 cycles using a Getty Fatigue Flex Tester model #0 manufactured by Getty Machine and Mold Company of Clifton, NJ. The laminate and card were not damaged.
C. Severe Durability Test A laminated card was placed in a 1 gallon paint can with 20 milliliters of water and 10 grams of sand and shaken in a paint shaker for 15 minutes. Minimal delamination of the adhesive from the card occurred only at the comers of the card. Durability was acceptable when compared to standard identification card laminates such as 3M Scotchpak Brand polyester laminate with hot melt adhesive.
Example 2 The protocol of Example 1 for the laminate preparation was followed except that a pressure-sensitive adhesive was used to adhere the laminate to the document in place of the corona treatment and heat activated adhesive. PSA 966 Scotch Brand High Temperature Acrylic adhesive coated on a silicone release liner available from 3M Company of St. Paul, MN was laminated to the polyester/embossing layer/reflective layer/adhesion enhancing layer composite using a hand squeegee. The laminate was applied to a photo adhered to a paper document also using a hand squeegee.
Tampering Ambient Temperature
When an attempt was made to peel the laminate from the document at room temperature, the paper document and photo were torn and it was impossible to remove the laminate from the document.
Heated Delamination
Another laminated document was heated to between about 210°F (99°C) and about 250°F (121 °C) on a hot plate and the laminate was peeled from the document at the elevated temperature to determine whether it was possible to heat delaminate the document. The adhesive layer split in the pattern of the adhesion enhancing coating, causing some adhesive to adhere to the document where the adhesion enhancing pattern was not present and some adhesive to adhere to the laminate where the adhesion enhancing pattern was present. Due to the textured damage of the adhesive, it was impossible to relaminate the same document or to use the laminate on a different document without evidence of tampering.
Example 3
A transparent hologram film was purchased from Transfer Print Foils of East Brunswick, NJ. It is believed that the hologram was prepared by embossing a holographic image into nitrocellulose-based embossing resin with a high index reflector, such as zinc sulfide, which were coated on a polyester film. The protocol of Example 1 was then followed to print the adhesion enhancing pattern and to laminate the heat activated adhesive. Two pieces of the laminate were heat laminated together with the adhesive sides facing each other. The pieces were pulled apart by hand. The adhesive and reflector layers split in the adhesion enhancing pattern which caused damage to both pieces of laminate. Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention.

Claims

What is claimed is:
1. A security laminate, comprising:
(a) protective layer having first and second surfaces; (b) embossed layer bonded to at least a portion of the second surface of the protective layer;
(c) reflective layer bonded to at least a portion of the embossed layer/protective layer composite;
(d) adhesion enhancing layer bonded to a portion of the reflective layer/embossed layer/protective layer composite; and
(e) adhesive bonded to at least a portion of the adhesion enhancing layer/reflective layer/embossed layer/protective layer composite wherein the bond between the reflective layer and the adhesion enhancing layer and the bond between the adhesion enhancing layer and the adhesive are each more tenacious than the bond between the reflective layer and the embossed layer and further wherein the bond between the adhesive and the adhesion enhancing layer is more tenacious than the bond between the adhesive and the reflective layer.
2. The security laminate of claim 1 wherein said adhesion enhancing layer comprises of ethylene acrylic acid.
3. The security laminate of claim 1 wherein said adhesion enhancing layer is invisible to the unaided eye.
4. The security laminate of claim 1 wherein said embossed layer has a visible image to the unaided eye.
5. The security laminate of claim 1 wherein said embossed layer is selected from the group of a polystyrene, polymethyl methacrylate, and nitrocellulose based resin.
6. The security laminate of claim 1 wherein said protective layer is transparent.
7. The security laminate of claim 1 wherein said protective layer is selected from the group of polyester, polyvinyl chloride, polyolefin, and cellulose acetate films.
8. The security laminate of claim 1 wherein said adhesive layer comprises heat activated adhesive.
9. The security laminate of claim 1 wherein said adhesive layer comprises pressure sensitive adhesive.
10. The security laminate of claim 9 further comprising a release liner bonded to said adhesive layer.
11. The security laminate of claim 1 wherein said reflective layer has a higher refractive index than said embossed layer.
12. The security laminate of claim 1 wherein said reflective layer is selected from the group of bismuth trioxide, zinc sulfide, titanium dioxide and zirconium oxide.
13. The security laminate of claim 1 wherein said reflective layer is transparent.
14. An article with a security laminate adhered thereto, said security laminate comprising: (a) protective layer having first and second surfaces; (b) embossed layer bonded to at least a portion of the second surface of the protective layer;
(c) reflective layer bonded to at least a portion of the embossed layer/protective layer composite; (d) adhesion enhancing layer bonded to a portion of the reflective layer/embossed layer/protective layer composite; and
(e) adhesive bonded to at least a portion of the adhesion enhancing layer/reflective layer/embossed layer/protective layer composite wherein the bond between the reflective layer and the adhesion enhancing layer and the bond between the adhesion enhancing layer and the adhesive are each more tenacious than the bond between the reflective layer and embossed layer and further wherein the bond between the adhesive and the adhesion enhancing layer is more tenacious than the bond between the adhesive and the reflective layer.
15. A method of rendering an article tamper resistant comprising adhering a security laminate to the article wherein said security laminate comprises:
(a) protective layer having first and second surfaces;
(b) embossed layer bonded to at least a portion of the second surface of the protective layer;
(c) reflective layer bonded to at least a portion of the embossed layer;
(d) adhesion enhancing layer bonded to a portion of the reflective layer; and
(e) adhesive bonded to at least a portion of the adhesion enhancing layer wherein the bond between the reflective layer and the adhesion enhancing layer and the bond between the adhesion enhancing layer and the adhesive are each more tenacious than the bond between the reflective layer and embossed layer and further wherein the bond between the adhesive and the adhesion enhancing layer is more tenacious than the bond between the adhesive and the reflective layer.
- l i
16. The method of claim 15 wherein said adhesion enhancing layer is comprised of ethylene acrylic acid.
17. The method claim 15 wherein said embossed layer has a visible image to the unaided eye.
18. The method of claim 15 wherein said embossed layer is selected from the group consisting of a polystyrene, polymethyl methacrylate and nitrocellulose-based resin.
19. The method of claim 15 wherein said protective layer and said reflective layer are transparent.
20. The method of claim 15 wherein said adhesive layer comprises heat activated adhesive.
21. The method of claim 15 wherein said adhesive layer comprises pressure sensitive adhesive.
22. The method of claim 15 wherein said reflective layer has a higher refractive index than the embossed layer.
23. The method of claim 15 wherein said reflective layer is selected from the group of bismuth trioxide, zinc sulfide, titanium dioxide and zirconium oxide.
24. The method of claim 15 wherein said protective layer is selected from the group consisting essentially of polyester, polyvinyl chloride, polyolefin, or cellulose actetate films.
25. The method of claim 15 wherein said adhesion enhancing layer is invisible to the unaided eye.
PCT/US1995/002196 1995-01-19 1995-02-21 Durable security laminate with hologram WO1996022579A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AU19679/95A AU688879B2 (en) 1995-01-19 1995-02-21 Durable security laminate with hologram
JP8507635A JPH10512818A (en) 1995-01-19 1995-02-21 Durable security laminate with hologram
KR1019970704872A KR100344086B1 (en) 1995-01-19 1995-02-21 Durable security laminate with hologram

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/375,531 1995-01-19
US08/375,531 US5510171A (en) 1995-01-19 1995-01-19 Durable security laminate with hologram

Publications (1)

Publication Number Publication Date
WO1996022579A1 true WO1996022579A1 (en) 1996-07-25

Family

ID=23481246

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/002196 WO1996022579A1 (en) 1995-01-19 1995-02-21 Durable security laminate with hologram

Country Status (6)

Country Link
US (2) US5510171A (en)
JP (1) JPH10512818A (en)
KR (1) KR100344086B1 (en)
AU (1) AU688879B2 (en)
CA (1) CA2209914A1 (en)
WO (1) WO1996022579A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005120859A1 (en) * 2004-06-03 2005-12-22 Datacard Corporation Identification documents with enhanced security
CN108864970A (en) * 2018-06-29 2018-11-23 山东泰宝包装制品有限公司 One kind taking off aobvious holographic color printing anti-counterfeit adhesive tape and preparation method thereof

Families Citing this family (120)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5683774A (en) 1994-12-09 1997-11-04 Minnesota Mining And Manufacturing Company Durable, tamper resistant security laminate
US5656360A (en) * 1996-02-16 1997-08-12 Minnesota Mining And Manufacturing Company Article with holographic and retroreflective features
US6086707A (en) * 1996-02-29 2000-07-11 Raytheon Company Method for making an identification document
US5742411A (en) * 1996-04-23 1998-04-21 Advanced Deposition Technologies, Inc. Security hologram with covert messaging
US20040247823A1 (en) * 2000-12-08 2004-12-09 Hansen Roger A. Decal organization tool
US6159569A (en) * 1996-10-22 2000-12-12 Hansen; Roger A. Decal organization tool
US6053535A (en) 1997-01-07 2000-04-25 The Standard Register Company Business form including a label
US5946781A (en) * 1997-05-09 1999-09-07 Kuo; Weiwu A. Multi-layer packaging foil and method for manufacturing the foil
US6004656A (en) * 1997-11-14 1999-12-21 3M Innovative Properties Company Color changeable device
US6788463B2 (en) * 1998-01-13 2004-09-07 3M Innovative Properties Company Post-formable multilayer optical films and methods of forming
US6214443B1 (en) * 1998-06-15 2001-04-10 American Bank Note Holographics, Inc. Tamper evident holographic devices and methods of manufacture
US6269169B1 (en) 1998-07-17 2001-07-31 Imaging Automation, Inc. Secure document reader and method therefor
US6087940A (en) * 1998-07-28 2000-07-11 Novavision, Inc. Article surveillance device and method for forming
US6351537B1 (en) 1998-10-05 2002-02-26 3M Innovative Properties Company Verifiable holographic article
ATE358827T1 (en) 1998-10-30 2007-04-15 Avery Dennison Corp METHOD FOR PRODUCING A RETROREFLECTIVE FILM WITH AN IMAGE FOR AUTHENTICITY CHECK
EP1169179B2 (en) * 1999-04-07 2012-11-14 Trüb AG Data carrier and method for producing same
FR2796184B1 (en) * 1999-07-09 2001-11-02 Thomson Csf SECURE DOCUMENT, MANUFACTURING SYSTEM, AND SYSTEM FOR READING THE DOCUMENT
DE19932902A1 (en) 1999-07-12 2001-01-25 Beiersdorf Ag Data storage
HN2000000165A (en) * 1999-08-05 2001-07-09 Dimensional Foods Corp EDIBLE HOLOGRAPHIC PRODUCTS, PARTICULARLY PHARMACEUTICALS, AND METHODS AND APPLIANCES FOR PRODUCERS.
US6428867B1 (en) 1999-12-14 2002-08-06 Prime Label & Screen, Inc. Resealable tamper indicating label flap including printer indicia
US6589622B1 (en) 1999-12-14 2003-07-08 Prime Label & Screen, Inc. Resealable label flap including tamper evident tab
DE19963709A1 (en) 1999-12-29 2002-12-05 Tesa Ag Security adhesive tape to prove unauthorized opening of a packaging
US6537634B2 (en) * 1999-12-29 2003-03-25 Tesa Ag Adhesive security tape for detecting unauthorized broaching of a package
DE10007916A1 (en) 2000-02-21 2001-08-23 Giesecke & Devrient Gmbh Multilayer laminated card with interposed security element having relief structures
DE10008328A1 (en) * 2000-02-23 2002-01-31 Tesa Ag Data memory used for storing data has a lacquer layer arranged as an adhesion layer between neighboring polymer film layers
GB0013379D0 (en) * 2000-06-01 2000-07-26 Optaglio Ltd Label and method of forming the same
CZ200324A3 (en) * 2000-06-05 2007-01-31 Optaglio Limited Product verification, system for and method of product authentication
DE10028113A1 (en) * 2000-06-07 2001-12-20 Beiersdorf Ag Data memory used in a running gear comprises an optically readable and writable information carrier having a polymer film, and an absorber assigned to the polymer film
US6555213B1 (en) 2000-06-09 2003-04-29 3M Innovative Properties Company Polypropylene card construction
US6506478B1 (en) 2000-06-09 2003-01-14 3M Innovative Properties Company Inkjet printable media
AU2001222589A1 (en) 2000-06-09 2001-12-24 3M Innovative Properties Company Materials and methods for creating waterproof, durable aqueous inkjet receptive media
US6979480B1 (en) 2000-06-09 2005-12-27 3M Innovative Properties Company Porous inkjet receptor media
DE10030596A1 (en) * 2000-06-21 2003-01-23 Tesa Ag Security adhesive tape to prove unauthorized opening of a packaging
GB0016356D0 (en) * 2000-07-03 2000-08-23 Optaglio Ltd Optical structure
GB0016358D0 (en) 2000-07-03 2000-08-23 Optaglio Ltd Optical device
GB0016359D0 (en) * 2000-07-03 2000-08-23 Optaglio Ltd Optical apparatus
GB0016354D0 (en) * 2000-07-03 2000-08-23 Optaglio Ltd Optical security device
US20100085642A1 (en) * 2000-07-18 2010-04-08 Optaglio Limited Diffractive device
EP1303795B1 (en) * 2000-07-18 2006-08-30 Optaglio Limited Achromatic diffractive device
DE10039372C2 (en) * 2000-08-11 2003-05-15 Tesa Scribos Gmbh Holographic data storage
DE10039374A1 (en) * 2000-08-11 2002-02-21 Eml Europ Media Lab Gmbh Holographic data storage
DE10039370A1 (en) * 2000-08-11 2002-02-28 Eml Europ Media Lab Gmbh Holographic data storage
US6500526B1 (en) 2000-09-28 2002-12-31 Avery Dennison Corporation Retroreflective sheeting containing a validation image and methods of making the same
DE10060235A1 (en) * 2000-12-05 2002-06-13 Tesa Ag Use of a packing tape as a holographic data carrier
EP1225554A1 (en) * 2001-01-19 2002-07-24 3M Innovative Properties Company Tamper indicating retroreflective article
NL1017307C2 (en) 2001-02-07 2002-08-08 Enschede Sdu Bv Successfully laminated structure.
US20020163179A1 (en) * 2001-05-01 2002-11-07 Dubner Andrew D. Transparent tamper-indicating data sheet
DE10128902A1 (en) * 2001-06-15 2003-10-16 Tesa Scribos Gmbh Holographic data storage
DE10128901A1 (en) * 2001-06-15 2002-12-19 Tesa Ag A process for giving information to an optically writable and readable data store with a polymer film for information storage and an absorbing colorant useful for providing information to a data storage device
GB0117096D0 (en) * 2001-07-13 2001-09-05 Qinetiq Ltd Security label
US7143950B2 (en) * 2001-10-02 2006-12-05 Digimarc Corporation Ink with cohesive failure and identification document including same
DE10156793A1 (en) 2001-11-19 2003-10-09 Tesa Scribos Gmbh security tape
US7694887B2 (en) 2001-12-24 2010-04-13 L-1 Secure Credentialing, Inc. Optically variable personalized indicia for identification documents
WO2003056408A2 (en) * 2001-12-24 2003-07-10 Digimarc Id Systems, Llc Ink with cohesive failure and identification document including same
EP1459246B1 (en) 2001-12-24 2012-05-02 L-1 Secure Credentialing, Inc. Method for full color laser marking of id documents
AU2002364036A1 (en) 2001-12-24 2003-07-15 Digimarc Id Systems, Llc Laser etched security features for identification documents and methods of making same
EP1459239B1 (en) 2001-12-24 2012-04-04 L-1 Secure Credentialing, Inc. Covert variable information on id documents and methods of making same
US20030180541A1 (en) * 2002-02-04 2003-09-25 Naik Kirit N. Topcoat compositions, substrates coated therewith and method of making and using the same
AU2003221894A1 (en) 2002-04-09 2003-10-27 Digimarc Id Systems, Llc Image processing techniques for printing identification cards and documents
ES2257615T3 (en) * 2002-05-02 2006-08-01 Bayer Materialscience Ag SANDWICH ELEMENTS AND ITS USE.
US7824029B2 (en) 2002-05-10 2010-11-02 L-1 Secure Credentialing, Inc. Identification card printer-assembler for over the counter card issuing
FR2841823B1 (en) * 2002-07-04 2004-08-20 Sequoias METHOD FOR SECURING LAMINATED DOCUMENTS BY BINDING THE DOCUMENT TO ITS LAMINATE
US7804982B2 (en) 2002-11-26 2010-09-28 L-1 Secure Credentialing, Inc. Systems and methods for managing and detecting fraud in image databases used with identification documents
US7102522B2 (en) * 2002-12-24 2006-09-05 3M Innovative Properties Company Tamper-indicating radio frequency identification antenna and sticker, a radio frequency identification antenna, and methods of using the same
US20040229065A1 (en) * 2003-02-28 2004-11-18 Toray Plastics (America), Inc. High refractive index coated embossable film
US6816125B2 (en) * 2003-03-01 2004-11-09 3M Innovative Properties Company Forming electromagnetic communication circuit components using densified metal powder
EP1457320A1 (en) * 2003-03-14 2004-09-15 Trüb AG Card-shaped data carrier, method for producing the same and apparatus for producing such a card-shaped data carrier
ATE491190T1 (en) 2003-04-16 2010-12-15 L 1 Secure Credentialing Inc THREE-DIMENSIONAL DATA STORAGE
JP2006526551A (en) 2003-06-03 2006-11-24 プライアント・コーポレイション Disposable container
US7223015B2 (en) * 2003-06-25 2007-05-29 Superior Bag Manufacturing Corporation Tamper-evident closure
DE602004005351T2 (en) * 2003-08-29 2007-11-29 Nippon Carbide Kogyo K.K. RETROREFLECTION LEAF WITH A BREAKABLE LAYER
US7266917B2 (en) * 2003-09-05 2007-09-11 The Boeing Company Image/advertising apparatus and method
US7389939B2 (en) * 2003-09-26 2008-06-24 Digimarc Corporation Optically variable security features having covert forensic features
US7588657B2 (en) * 2003-09-29 2009-09-15 Princeton University Pattern-free method of making line gratings
WO2005083661A1 (en) * 2004-02-27 2005-09-09 Nippon Carbide Kogyo Kabushiki Kaisha Display device with theft prevention structure
US7744002B2 (en) 2004-03-11 2010-06-29 L-1 Secure Credentialing, Inc. Tamper evident adhesive and identification document including same
US20050247794A1 (en) * 2004-03-26 2005-11-10 Jones Robert L Identification document having intrusion resistance
US7157135B2 (en) * 2004-06-09 2007-01-02 Toray Plastics (America), Inc. Co-extruded high refractive index coated embossable film
US7856116B2 (en) 2004-11-09 2010-12-21 Digimarc Corporation Authenticating identification and security documents
US7383999B2 (en) 2004-12-28 2008-06-10 Digimarc Corporation ID document structure with pattern coating providing variable security features
ES2403124T3 (en) * 2005-02-10 2013-05-14 Nippon Carbide Kogyo Kabushiki Kaisha Retroreflective coating
US7939465B2 (en) * 2005-03-30 2011-05-10 L-1 Secure Credentialing Image destruct feature used with image receiving layers in secure documents
US7833937B2 (en) * 2005-03-30 2010-11-16 L-1 Secure Credentialing, Inc. Image destruct feature used with image receiving layers in secure documents
WO2006115089A1 (en) * 2005-04-19 2006-11-02 Kyodo Printing Co., Ltd. Method for adhering sticker for forgery prevention and medium for adhering sticker
US20070218258A1 (en) * 2006-03-20 2007-09-20 3M Innovative Properties Company Articles and methods including patterned substrates formed from densified, adhered metal powders
US20080143519A1 (en) * 2006-12-19 2008-06-19 3M Innovative Properties Company Tamper-indicating radio frequency identification tag and methods of indicating tampering of a radio frequency identification tag
US9624008B2 (en) 2007-03-23 2017-04-18 Selig Sealing Products, Inc. Container seal with removal tab and security ring seal
US8703265B2 (en) * 2007-03-23 2014-04-22 Selig Sealing Products, Inc. Container seal with removal tab and piercable holographic security seal
US8522990B2 (en) * 2007-03-23 2013-09-03 Selig Sealing Products, Inc. Container seal with removal tab and holographic security ring seal
WO2009029247A2 (en) 2007-08-24 2009-03-05 Selig Sealing Products, Inc. Multi-purpose covering and method of hygienically covering a container top
DE102007052174A1 (en) * 2007-10-30 2009-05-07 Ovd Kinegram Ag Foil element for securing an object
EP2252459B1 (en) * 2008-02-18 2013-04-17 Hologram Industries Research GmbH Method for the individual application of hot embossing film and security documents produced therewith
JP5343384B2 (en) * 2008-03-26 2013-11-13 凸版印刷株式会社 Security devices and labeled items
WO2009133876A1 (en) * 2008-04-30 2009-11-05 共同印刷株式会社 Retroreflector label sheet and article to which retroreflector label sheet is bonded
DE102008024023A1 (en) * 2008-05-16 2009-11-19 Tesa Scribos Gmbh Multilayer film assembly and use of a multilayer film assembly
EP2313800A4 (en) 2008-07-10 2014-03-19 3M Innovative Properties Co Viscoelastic lightguide
EP2307914A4 (en) 2008-07-10 2014-03-19 3M Innovative Properties Co Retroreflective articles and devices having viscoelastic lightguide
TW201007647A (en) 2008-07-10 2010-02-16 3M Innovative Properties Co Retroreflective articles and devices having viscoelastic lightguide
CN102171593A (en) * 2008-08-08 2011-08-31 3M创新有限公司 Lightguide having a viscoelastic layer for managing light
GB0902000D0 (en) * 2009-02-09 2009-03-11 Optaglio Sro Micro-relief structures
US20100206953A1 (en) * 2009-02-19 2010-08-19 O'boyle Lily Durable washable label having a visible diffraction grating pattern
SI2234091T1 (en) * 2009-03-27 2015-07-31 Hueck Folien Ges. M.B.H. Safety element, in particular safety label with manipulation verification
FR2943800A1 (en) * 2009-03-30 2010-10-01 Arjowiggins Security SECURITY ELEMENT COMPRISING ELEMENTARY REFLECTING STRUCTURES.
EP2343198A1 (en) * 2010-01-12 2011-07-13 3M Innovative Properties Company Security laminate, method of making a security laminate, and article comprising a security laminate
CN102754003B (en) 2010-02-10 2014-06-18 3M创新有限公司 Illumination device having viscoelastic layer
AT510505B1 (en) * 2010-08-13 2013-02-15 Hueck Folien Gmbh SAFETY LABEL WITH MANIPULATION DETECTION
AT510520B1 (en) * 2010-08-13 2013-02-15 Hueck Folien Gmbh SAFETY LABEL WITH MANIPULATION DETECTION
JP2012113077A (en) * 2010-11-24 2012-06-14 Sony Corp Hologram laminate and manufacturing method of hologram laminate
JP5722108B2 (en) * 2011-04-19 2015-05-20 大王製紙株式会社 Verification information separation sheet
FR2984002B1 (en) * 2011-12-07 2014-01-10 Hologram Ind MULTILAYER SECURE LABEL AND METHOD OF MANUFACTURING THE SAME
GB2498383B (en) * 2012-01-13 2014-04-16 Andrew Richard Parker Security device
US10259626B2 (en) 2012-03-08 2019-04-16 Selig Sealing Products, Inc. Container sealing member with protected security component and removal tab
KR101441532B1 (en) * 2012-05-10 2014-09-17 주식회사 잉크테크 Continuous plating apparatus
GB2510381B (en) * 2013-02-01 2015-11-04 Rue De Int Ltd Security devices and methods of manufacture thereof
MX346259B (en) * 2015-02-24 2017-03-10 Validation Security Tech Identification S De R L De C V Intelligent label system.
TWM506831U (en) * 2015-03-31 2015-08-11 Seal King Ind Co Ltd Unsealing indication structure of anti-counterfeit tape
JP6589165B2 (en) * 2015-04-03 2019-10-16 福岡丸本株式会社 Sealing label
US11701298B2 (en) * 2016-10-26 2023-07-18 Holographyx Inc. Pharmaceutical packs comprising holographic lidding material, and method of making the same
US10543667B2 (en) * 2016-12-30 2020-01-28 Toray Plastics (America), Inc. Easy opening metalized hermetic films and methods to manufacture the same
SG11202100103YA (en) * 2019-07-01 2021-02-25 Arun Agarwal A smart and secure label stock

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4630891A (en) * 1984-09-14 1986-12-23 Minnesota Mining And Manufacturing Company Tamper resistant security film
WO1991018377A2 (en) * 1990-05-22 1991-11-28 De La Rue Holographics Limited Tamper resisting security seal
US5104471A (en) * 1989-06-05 1992-04-14 Landis & Gyr Betriebs Ag Interlaminar sandwich with diffraction structure
US5153042A (en) * 1989-05-16 1992-10-06 Minnesota Mining And Manufacturing Company Tamper-indicating labelstock
WO1993016888A1 (en) * 1992-02-20 1993-09-02 De La Rue Holographics Limited Transfer method and device

Family Cites Families (74)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1003443A (en) * 1911-09-19 William Thorne Erickson Stamp and label.
US2181252A (en) * 1933-10-10 1939-11-28 Vogel Max Safety envelope
CA677797A (en) * 1955-11-18 1964-01-14 Minnesota Mining And Manufacturing Company Sheet material having a pressure-sensitive adhesive coating of acrylate ester copolymer
US3239478A (en) * 1963-06-26 1966-03-08 Shell Oil Co Block copolymer adhesive compositions and articles prepared therefrom
US3487567A (en) * 1967-11-20 1970-01-06 Liberal Auto Club Information emblem
US3631617A (en) * 1969-10-27 1972-01-04 Avery Products Corp Tamperproof label construction
US3864855A (en) * 1969-12-08 1975-02-11 Avery Products Corp Destructible label system
US4068028A (en) * 1971-06-09 1978-01-10 Unical Corporation Apparatus and method of producing transparent labels with printing on the adhesive and product produced thereby
AU5597173A (en) * 1972-05-24 1974-11-28 Letraset International Limited Transfer materials
US3925584A (en) * 1972-08-24 1975-12-09 Daiichi Seiyaku Co Adhesive seal and tape for sealing
US3802724A (en) * 1972-09-11 1974-04-09 Burroughs Corp Protection system for computerized negotiable document printouts
US3801183A (en) * 1973-06-01 1974-04-02 Minnesota Mining & Mfg Retro-reflective film
US3923198A (en) * 1973-09-17 1975-12-02 Minnesota Mining & Mfg Stress-opacifiable tamper indicator
US3935960A (en) * 1973-09-17 1976-02-03 Minnesota Mining And Manufacturing Company Tamper indicator tape
US3933304A (en) * 1974-02-22 1976-01-20 Decoflex Limited Bags for containing bank notes
AT333064B (en) * 1974-04-02 1976-11-10 Gao Ges Automation Org MULTIPLE-LAYERED, FALSE-PROOF RECORDERING MEDIA, IN PARTICULAR ID CARD
US4028165A (en) * 1976-06-14 1977-06-07 Rosenfeld Jerome E Dry transfer product and process
US4082873A (en) * 1976-11-02 1978-04-04 Monarch Marking Systems, Inc. Switch-proof label
US4121003A (en) * 1977-04-22 1978-10-17 Monarch Marking Systems, Inc. Tamper indicating labels
DE2732639A1 (en) * 1977-07-19 1979-02-01 Istvan Majoros DEVICE FOR TRANSFERRING HEAT FROM A HEAT SOURCE TO CONSUMER CIRCUITS
US4246307A (en) * 1977-12-23 1981-01-20 Trautwein Hansjoerg Tamper-proof laminated sticker or card
US4180929A (en) * 1978-01-23 1980-01-01 Minnesota Mining And Manufacturing Company Tamper indicating label
DE2803434A1 (en) * 1978-01-26 1979-08-02 Koenig Kg Claus SELF-ADHESIVE CLEAR FILM
US4184701A (en) * 1978-02-10 1980-01-22 Monarch Marking Systems, Inc. Tamper proof label
FR2451081A1 (en) * 1979-03-08 1980-10-03 Solaic Sa Laminated PVC card with internal inscription system - to protect individual markings from damage
DE2952322A1 (en) * 1979-12-24 1981-07-02 Agfa-Gevaert Ag, 5090 Leverkusen Documents resistant to falsification - are coated with a transparent plastic film bonded with radiation curable adhesive
JPS5988780A (en) * 1982-11-08 1984-05-22 アメリカン・バンク・ノ−ト・カムパニ− Making of optical refraction recording body and optical refraction pattern
US4913504A (en) * 1982-11-08 1990-04-03 American Bank Note Holographics, Inc. Documents or like articles bearing holograms
US4475661A (en) * 1982-12-03 1984-10-09 Griffin Robert B Tamper-indicating container assembly
US4588465A (en) * 1983-02-04 1986-05-13 Minnesota Mining And Manufacturing Company Method for forming a sealed container
US4557505A (en) * 1984-01-05 1985-12-10 Minnesota Mining And Manufacturing Company Stress-opacifying tamper indicating tape
US4505399A (en) * 1984-06-21 1985-03-19 Weiner Robert C Tamper-indicating device and method
EP0167379A3 (en) * 1984-07-02 1987-08-19 Techsearch Incorporated Security bag
US4608288A (en) * 1984-08-21 1986-08-26 Joachim Dudzik Tamper proof label or seal
FR2570101B1 (en) * 1984-09-07 1987-09-25 Sotimag ANTI-FRAUD PROCESS FOR VALUE DOCUMENTS
US4763931A (en) * 1984-10-01 1988-08-16 Daimatsu Kagaku Kogyo Co., Ltd. Adhesive material for preventing reuse
DE3534558A1 (en) * 1984-10-01 1986-04-17 Daimatsu Kagaku Kogyo Co. Ltd., Osaka STICKING MATERIAL TO PREVENT RE-STICKING
US4652473A (en) * 1984-12-10 1987-03-24 Minnesota Mining And Manufacturing Company Tamper-resistant packaging tape
GB2173150B (en) * 1985-03-28 1989-06-21 Daimatsu Kagaku Kogyo Kk An easily breakable sticking material
US4684554A (en) * 1985-04-12 1987-08-04 Minnesota Mining And Manufacturing Company Polymeric coating for container induction innerseal
US4772650A (en) * 1985-04-12 1988-09-20 Minnesota Mining And Manufacturing Co. Polymeric coating for container induction innerseal
KR860009325A (en) * 1985-05-07 1986-12-22 기다지마 요시도시 Transparent Hologram
DE3527412A1 (en) * 1985-07-31 1987-02-12 Kurz Leonhard Fa MULTI-LAYER FILM, ESPECIALLY HOT-IMPRESSION FILM AND METHOD FOR THE PRODUCTION THEREOF
GB8521363D0 (en) * 1985-08-28 1985-10-02 De La Rue Co Plc Security card
US4709396A (en) * 1985-12-24 1987-11-24 John H. Harland Company Tamper-evident envelope with indicia underlying cohesive layers
US4709397A (en) * 1985-12-24 1987-11-24 John H. Harland Company Tamper-evident envelope with indicia-forming cohesive layers
US4737559A (en) * 1986-05-19 1988-04-12 Minnesota Mining And Manufacturing Co. Pressure-sensitive adhesive crosslinked by copolymerizable aromatic ketone monomers
US4721217A (en) * 1986-08-07 1988-01-26 Optical Coating Laboratory, Inc. Tamper evident optically variable device and article utilizing the same
GB2200337A (en) * 1987-01-28 1988-08-03 Metal Box Plc Plastic bags
US4718553A (en) * 1987-02-11 1988-01-12 Ivy Hill Corporation Tamper-evident packaging, method of making same, and intermediate therein
US4773677A (en) * 1987-05-13 1988-09-27 Polaroid Corporation Unitary laminated identification card and insignia
US4908285A (en) * 1987-05-18 1990-03-13 Canon Kabushiki Kaisha Hologram member
US4760919A (en) * 1987-07-30 1988-08-02 Minnesota Mining And Manufacturing Company Tamper-indicating package
JP2657965B2 (en) * 1987-10-31 1997-09-30 日本カーバイド工業 株式会社 Pressure-sensitive adhesive layer
US4937040A (en) * 1988-03-07 1990-06-26 Minnesota Mining And Manufacturing Company Security deposit bag
US4838708A (en) * 1988-03-07 1989-06-13 Minnesota Mining And Manufacturing Company Security deposit bag
US4804096A (en) * 1988-04-22 1989-02-14 Harding Claude J Tamper resistant container
US5294470A (en) * 1988-05-13 1994-03-15 Ewan Frederick R Tamper indicating containers and seals
US4998666A (en) * 1988-05-13 1991-03-12 Frederick R. Ewan Tamper indicating containers and seals
US4876123A (en) * 1988-06-27 1989-10-24 Minnesota Mining And Manufacturing Company Tamper indicating tape and delaminating film therefore
US4915994A (en) * 1988-10-24 1990-04-10 York Tape And Label Company Dimensionally stable pressure sensitive label
US4941196A (en) * 1988-11-01 1990-07-10 Kcl Corporation Tamper evident bag
GB8910242D0 (en) * 1989-05-04 1989-06-21 Lawson Mardon Cambridge Ltd Improvements in or relating to bags
US4988547A (en) * 1989-05-19 1991-01-29 Minnesota Mining And Manufacturing Company Security deposit bag
US4972953A (en) * 1989-06-14 1990-11-27 Ivy Hill Corporation Tamper-evident packaging, method of making same and intermediate therein
US4980222A (en) * 1989-06-21 1990-12-25 Minnesota Mining And Manufacturing Company Tamper indicating tape
US5080463A (en) * 1989-06-21 1992-01-14 Minnesota Mining And Manufacturing Company Retroreflective security laminates with protective cover sheets
US5104719A (en) * 1989-08-30 1992-04-14 Revlon, Inc. Heat activated, quick release decals and associated methods
US5082702A (en) * 1990-08-20 1992-01-21 Minnesota Mining And Manufacturing Company Tamper-indicating tape
EP0491099B1 (en) * 1990-12-19 1996-08-28 The Kendall Company Tamper evident closure and tamper evident method
US5169707A (en) * 1991-05-08 1992-12-08 Minnesota Mining And Manufacturing Company Retroreflective security laminates with dual level verification
US5277971A (en) * 1992-05-22 1994-01-11 Tredegar Industries, Inc. Tamper-evident pressure sensitive facestock labels
US5346259A (en) * 1992-07-16 1994-09-13 Avery Dennison Corporation Anti-theft label construction
US5358281A (en) * 1993-02-10 1994-10-25 Moore Business Forms, Inc. Security pressure sensitive label

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4630891A (en) * 1984-09-14 1986-12-23 Minnesota Mining And Manufacturing Company Tamper resistant security film
US5153042A (en) * 1989-05-16 1992-10-06 Minnesota Mining And Manufacturing Company Tamper-indicating labelstock
US5104471A (en) * 1989-06-05 1992-04-14 Landis & Gyr Betriebs Ag Interlaminar sandwich with diffraction structure
WO1991018377A2 (en) * 1990-05-22 1991-11-28 De La Rue Holographics Limited Tamper resisting security seal
WO1993016888A1 (en) * 1992-02-20 1993-09-02 De La Rue Holographics Limited Transfer method and device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005120859A1 (en) * 2004-06-03 2005-12-22 Datacard Corporation Identification documents with enhanced security
US7594680B2 (en) 2004-06-03 2009-09-29 Datacard Corporation Identification documents with enhanced security
CN108864970A (en) * 2018-06-29 2018-11-23 山东泰宝包装制品有限公司 One kind taking off aobvious holographic color printing anti-counterfeit adhesive tape and preparation method thereof

Also Published As

Publication number Publication date
KR100344086B1 (en) 2002-09-18
US5510171A (en) 1996-04-23
KR19980701481A (en) 1998-05-15
US5658411A (en) 1997-08-19
JPH10512818A (en) 1998-12-08
CA2209914A1 (en) 1996-07-25
AU688879B2 (en) 1998-03-19
AU1967995A (en) 1996-08-07

Similar Documents

Publication Publication Date Title
AU688879B2 (en) Durable security laminate with hologram
US6284337B1 (en) Durable security laminate with heat-shrinkable layer
US5104471A (en) Interlaminar sandwich with diffraction structure
AU708736B2 (en) Article with holographic and retroreflective features
US6955839B2 (en) Laminated composite, information recording medium, and member of imparting forgery-preventing characteristic
US4968063A (en) Transparent tamper-indicating document overlay
KR0172599B1 (en) Retroreflective security laminates with protective cover sheets
JP4900150B2 (en) Brittle label and manufacturing method thereof
WO2012035546A2 (en) A tamper evident multiple metallized and demetallized security device and process for preparing the same
EP0349537A1 (en) Adhesive sheet material
JP4892775B2 (en) Unauthorized use prevention label
KR200353146Y1 (en) Hologram Ultra violet curing system label
KR100451917B1 (en) Hologram Ultra violet curing system label
JP2002366038A (en) Ovd seal, producing method thereof and sticking method thereof
JP2005316212A (en) Pattern expression object
JPH07146650A (en) Brittle seal
JPH0895491A (en) Brittle seal
JPH08328455A (en) Hologram brittle seal
JPH08201622A (en) Concealing seal
JPH07191604A (en) Transparent hologram seal
JP2011022236A (en) Re-sticking prevention sticker

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU CA JP KR

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
ENP Entry into the national phase

Ref document number: 2209914

Country of ref document: CA

Ref country code: CA

Ref document number: 2209914

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 1019970704872

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: 1019970704872

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 1019970704872

Country of ref document: KR