WO1997023265A1 - High efficiency dust sock - Google Patents

High efficiency dust sock Download PDF

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Publication number
WO1997023265A1
WO1997023265A1 PCT/US1996/019851 US9619851W WO9723265A1 WO 1997023265 A1 WO1997023265 A1 WO 1997023265A1 US 9619851 W US9619851 W US 9619851W WO 9723265 A1 WO9723265 A1 WO 9723265A1
Authority
WO
WIPO (PCT)
Prior art keywords
filter medium
laminate
dust
dust sock
medium laminate
Prior art date
Application number
PCT/US1996/019851
Other languages
French (fr)
Inventor
James Page Brown
Original Assignee
Kimberly-Clark Worldwide, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kimberly-Clark Worldwide, Inc. filed Critical Kimberly-Clark Worldwide, Inc.
Priority to AU14182/97A priority Critical patent/AU1418297A/en
Publication of WO1997023265A1 publication Critical patent/WO1997023265A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/08Filter cloth, i.e. woven, knitted or interlaced material
    • B01D39/083Filter cloth, i.e. woven, knitted or interlaced material of organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/02Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02Types of fibres, filaments or particles, self-supporting or supported materials
    • B01D2239/0216Bicomponent or multicomponent fibres
    • B01D2239/0225Side-by-side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02Types of fibres, filaments or particles, self-supporting or supported materials
    • B01D2239/0216Bicomponent or multicomponent fibres
    • B01D2239/0233Island-in-sea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0457Specific fire retardant or heat resistant properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/0604Arrangement of the fibres in the filtering material
    • B01D2239/0622Melt-blown
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/0604Arrangement of the fibres in the filtering material
    • B01D2239/0627Spun-bonded
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065More than one layer present in the filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065More than one layer present in the filtering material
    • B01D2239/0654Support layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/06Filter cloth, e.g. knitted, woven non-woven; self-supported material
    • B01D2239/065More than one layer present in the filtering material
    • B01D2239/0668The layers being joined by heat or melt-bonding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12Special parameters characterising the filtering material
    • B01D2239/1233Fibre diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12Special parameters characterising the filtering material
    • B01D2239/1291Other parameters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/08Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns
    • B29K2105/0854Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts of continuous length, e.g. cords, rovings, mats, fabrics, strands or yarns in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/12Conjugate fibres, e.g. core/sheath or side-by-side
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/42Polarizing, birefringent, filtering
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/903Microfiber, less than 100 micron diameter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00Gas separation
    • Y10S55/05Methods of making filter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/614Strand or fiber material specified as having microdimensions [i.e., microfiber]
    • Y10T442/622Microfiber is a composite fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y10T442/638Side-by-side multicomponent strand or fiber material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y10T442/641Sheath-core multicomponent strand or fiber material

Definitions

  • This invention relates generally to a nonwoven fabric or web which is formed from spunbond fibers of a thermoplastic resin, and laminates using such a web as a component.
  • the fabric is used as a filter, particularly for industrial applications where the fabric is in the form of a sock.
  • thermoplastic resins have been extruded to form fibers, fabrics and webs for a number of years.
  • the most common thermoplastics for this application are polyolefins, particularly polypropylene.
  • Other materials such as polyesters, polyetheresters, polyamides and polyurethanes are also used to form nonwoven spunbond fabrics.
  • Nonwoven fabrics or webs are useful for a wide variety of applications such as diapers, feminine hygiene products, towels, recreational or protective fabrics and as geotextiles and filter media.
  • the nonwoven webs used in these applications may be simply spunbond fabrics but are often in the form of nonwoven fabric laminates like spunbond/spunbond (SS) laminates or spunbond/meltblown/spunbond (SMS) laminates.
  • SS spunbond/spunbond
  • SMS spunbond/meltblown/spunbond
  • High filtration efficiency is, of course, the main purpose for a filter and great efficiency and ability to maintain the efficiency at an acceptable level are key to filter performance.
  • a dust sock filter medium laminate which has at least two nonwoven webs of microfibers which have an average diameter (using a sample size of at least 10) between about 10 and 25 microns and which webs have been joined by a method comprising the steps of (a) directing the component layers to a separation zone, (b) applying water in the amount of from about 5% to 25% based on the weight of the combined layers, (c) combining the component layers, (d) passing the combination through a sonic bonder operating within the range of up to about 40,000 cps against a patterned anvil to produce a corresponding pattern of thermal bond areas over about 3% to 25% of the surface area of the combination, and, (e) drying the sonically bonded combination. While this invention is directed mainly to air filtration, other gasses may be filtered as well.
  • the dust socks of this invention desirably have a basis weight between about 85 and 205 gsm, a Frazier permeability of above 100
  • the Figure is a schematic drawing of a dust sock attached to a fan.
  • nonwoven fabric or web means a web having a structure of individual fibers or threads which are interlaid, but not in an identifiable manner as in a knitted fabric.
  • Nonwoven fabrics or webs have been formed from many processes such as, for example, meltblowing processes, spunbonding processes, and bonded carded web processes.
  • the basis weight of nonwoven fabrics is usually expressed in ounces of material per square yard (osy) or grams per square meter (gsm) and the fiber diameters useful are usually expressed in microns. (Note that to convert from osy to gsm, multiply osy by 33.91).
  • microfibers means small diameter fibers having an average diameter not greater than about 75 microns, for example, having an average diameter of from about 0.5 microns to about 50 microns, or more particularly, microfibers may have an average diameter of from about 2 microns to about 40 microns.
  • denier is defined as grams per 9000 meters of a fiber and may be calculated as fiber diameter in microns squared, multiplied by the density in grams/cc, multiplied by 0.00707. A lower denier indicates a finer fiber and a higher denier indicates a thicker or heavier fiber.
  • the diameter of a polypropylene fiber given as 15 microns may be converted to denier by squaring, multiplying the result by .89 g/cc and multiplying by .00707.
  • spunbonded fibers refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced as by, for example, in U.S. Patent no. 4,340,563 to Appel et al., and U.S. Patent no. 3,692,618 to Dorschner et al., U.S. Patent no. 3,802,817 to Matsuki et al., U.S. Patent nos. 3,338,992 and 3,341,394 to Kinney, U.S. Patent no. 3,502,763 to Hartman, and U.S. Patent no.
  • Spunbond fibers are generally not tacky when they are deposited onto a collecting surface. Spunbond fibers are generally continuous and have average diameters (using a sample size of at least 10) larger than 7 microns, more particularly, between about 10 and 25 microns.
  • meltblown fibers means fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually hot, gas (e.g. air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly disbursed meltblown fibers.
  • gas e.g. air
  • conjugate fibers refers to fibers which have been formed from at least two polymers extruded from separate extruders but spun together to form one fiber. Conjugate fibers are also sometimes referred to as multicomponent or bicomponent fibers.
  • the polymers are usually different from each other though conjugate fibers may be monocomponent fibers.
  • the polymers are arranged in substantially constantly positioned distinct zones across the cross- section of the conjugate fibers and extend continuously along the length of the conjugate fibers.
  • the configuration of such a conjugate fiber may be, for example, a sheath/core arrangement wherein one polymer is surrounded by another or may be a side by side arrangement, a segmented configuration or an "islands-in-the-sea" arrangement.
  • Conjugate fibers are taught in U.S. Patent 5,108,820 to Kaneko et al., U.S. Patent 5,336,552 to Strack et al., and U.S. Patent 5,382,400 to Pike et al.
  • the polymers may be present in ratios of 75/25, 50/50, 25/75 or any other desired ratios.
  • thermal point bonding involves passing a fabric or web of fibers to be bonded between a heated calender roll and an anvil roll.
  • the calender roll is usually, though not always, patterned in some way so that the entire fabric is not bonded across its entire surface and the anvil is usually flat.
  • various patterns for calender rolls have been developed for functional as well as aesthetic reasons.
  • One example of a pattern is the Hansen Pennings or "H&P" pattern with between about a 5 and 50% bond area with between about 50-3200 bonds/square inch as taught in U.S. Patent 3,855,046 to Hansen and Pennings.
  • H&P pattern has square point or pin bonding areas wherein each pin has a side dimension of 0.038 inches (0.965 mm), a spacing of 0.070 inches (1.778 mm) between pins, and a depth of bonding of 0.023 inches (0.584 mm).
  • Another typical point bonding pattern is the expanded Hansen Pennings or "EHP" bond pattern which produces about a 15% bond area with a square pin having a side dimension of 0.037 inches (0.94 mm), a pin spacing of 0.097 inches (2.464 mm) and a depth of 0.039 inches (0.991 mm).
  • Another typical point bonding pattern designated “714" has square pin bonding areas wherein each pin has a side dimension of 0.023 inches, a spacing of 0.062 inches (1.575 mm) between pins, and a depth of bonding of 0.033 inches (0.838 mm). The resulting pattern has a bonded area of about 15%.
  • Yet another common pattern is the C-Star pattern which has a bond area of about 16.9%.
  • the C-Star pattem has a cross-directional bar or "corduroy" design interrupted by shooting stars.
  • Other common patterns include a diamond pattem with repeating and slightly offset diamonds and a wire weave pattem looking as the name suggests, e.g. like a window screen.
  • the percent bonding area varies from around 10% to around 30% of the area of the fabric laminate web.
  • the spot bonding holds the laminate layers together as well as imparts integrity to each individual layer by bonding filaments and/or fibers within each layer.
  • ultrasonic bonding means a process performed, for example, by passing the fabric between a sonic horn and anvil roll as illustrated in U.S. Patent 4,374,888 to Bomslaeger.
  • Frazier Permeability A measure of the permeability of a fabric or web to air is the Frazier Permeability which is performed according to Federal Test Standard No. 191 A, Method 5450 dated July 20, 1978, and is reported as an average of 3 sample readings. Frazier Permeability measures the air flow rate through a web in cubic feet of air per minute per square foot of web or CFM/SF. Convert CFM/SF to liters per square meter per minute (LSM) by multiplying CFM/SF by 304.8.
  • LSM liters per square meter per minute
  • NaCl Efficiency is a measure of the ability of a fabric or web to stop the passage of small particles through it. A higher efficiency is generally more desirable and indicates a greater ability to remove particles. NaCl efficiency is measured in percent according to the TSI Inc., Model 8110 Automated Filter Tester Operation Manual of February 1993, P/N 1980053, revision D, at a flow rate of 32 liters per minute using 0.1 micron sized NaCl particles and is reported as an average of 3 sample readings. The manual is available from TSI Inc. at PO Box 64394, 500 Cardigan Rd, St. Paul, MN 55164. This test also can yield a pressure differential across a fabric using the same particle size and airflow rate.
  • the melt flow rate is a measure of the viscosity of a polymer.
  • the MFR is expressed as the weight of material which flows from a capillary of known dimensions under a specified load or shear rate for a measured period of time and is measured in grams/10 minutes at a set temperature and load according to, for example, ASTM test 1238-90b.
  • the spunbond process generally uses a hopper which supplies polymer to a heated extruder.
  • the extruder supplies melted polymer to a spinneret where the polymer is fiberized as it passes through fine openings arranged in one or more rows in the spinneret, forming a curtain of filaments.
  • the filaments are usually quenched with air at a low pressure, drawn, usually pneumatically and deposited on a moving foraminous mat, belt or "forming wire” to form the nonwoven web.
  • Polymers useful in the spunbond process generally have a process melt temperature of between about 400°F to about 610°F (200°C to 320 ⁇ C).
  • the fibers produced in the spunbond process are usually in the range of from about 10 to about 50 microns in average diameter, depending on process conditions and the desired end use for the webs to be produced from such fibers. For example, increasing the polymer molecular weight or decreasing the processing temperature results in larger diameter fibers. Changes in the quench fluid temperature and pneumatic draw pressure can also affect fiber diameter.
  • the fibers used in the practice of this invention usually have average diameters in the range of from about 7 to about 35 microns, more particularly from about 15 to about 25 microns.
  • the fabric of this invention may be a multilayer laminate and may be formed by a number of different techniques including but not limited to using adhesive, needle punching, ultrasonic bonding, thermal calendering and any other method known in the art.
  • a multilayer laminate may be an embodiment wherein some of the layers are spunbond and some meltblown such as a spunbond/meltblown/spunbond (SMS) laminate as disclosed in U.S. Patent no. 4,041,203 to Brock et al. and U.S. Patent no. 5,169,706 to Collier, et al. or as a spunbond/spunbond laminate.
  • SMS spunbond/meltblown/spunbond
  • An SMS laminate may be made by sequentially depositing onto a moving conveyor belt or forming wire first a spunbond web layer, then a meltblown web layer and last another spunbond layer and then bonding the laminate in a manner described above. Altematively, the three web layers may be made individually, collected in rolls, and combined in a separate bonding step.
  • the fabric may also be a laminate of spunbond fabric and scrim materials. Scrim materials provide little mass and essentially no filtration ability but do provide an additional degree of intregrity or strength to the fabric. Scrims usually are fibers bonded together to produce a square pattem which is quite large, e.g. as much as 5 inches (127mm) by 5 inches, though the pattem need not be exactly square. Scrims may be, for example, 3 inches (76mm) by 2 inches (51mm), 4 inches (101 mm) by 4 inches, and 3 inches (76 mm) by 3 inches. When a scrim is used it should be place between two other layers so that its ability to provide integrity to the fabric is maximized.
  • Scrims may be made from any polymer known conventionally as being used for that purpose, examples include, polypropylene, ethyl vinyl acetate (EVA), polyamides, polyurethane, polybutylene, polystyrene, polyvinyl chloride, polyethylene, polyethylene terephathalate, and polytetrafluoroethylene.
  • EVA ethyl vinyl acetate
  • the area in which the web of this invention finds utility is as a dust sock for industrial applications.
  • fans are used to move air away from a work area.
  • the air moved by the fan contains particulates which must be removed from the air for safety or environmental reasons.
  • the fans used to move the air are generally a few feet in diameter and are fitted on the discharge side with a long cylindrical fabric "sock" to catch the particles.
  • the Figure shows a dust sock (1) attached to a fan (2) and such a sock may be, for example, about 1 to 2 feet (25 to 61 cm) in diameter and about 8 to 15 feet (244 to 915 cm) in length.
  • a dust sock (1) attached to a fan (2) and such a sock may be, for example, about 1 to 2 feet (25 to 61 cm) in diameter and about 8 to 15 feet (244 to 915 cm) in length.
  • materials such as cotton and canvas have been used but such materials are quite heavy and do not have the filtration efficiency of the nonwoven fabrics of this invention.
  • the more permeable, higher efficiency fabrics of this invention will allow smaller socks to be used than, for example, a canvas sock, for the same particulate load.
  • Filter fabrics for use in this invention may have basis weights ranging from about 0.25 osy (8.5 gsm) to about 10 osy (340 gsm).
  • the fibers used to produce the web of this invention maybe conjugate fibers, such as side-by-side (S/S) fibers.
  • the polymers used to produce the fibers are may be polyamides, polyurethane, polybutylene, polyvinylchloride, polytetrafluoroethylene, polystyrene, polyethylene terephathalate, polycarbonates,
  • 4-methyl-1-pentene and polyolefins particulariy polypropylene and polyethylene.
  • polyethylenes such as Dow Chemical's ASPUN® 6811
  • a linear low density polyethylene, 2553 LLDPE and 25355 and 12350 high density polyethylene are such suitable polymers.
  • the polymers mentioned above for scrim production may be used.
  • the polyethylenes have melt flow rates in g/10 min. at 190°F and a load of 2.16 kg, of about 26, 40, 25 and 12, respectively.
  • Fiber forming polypropylenes include Exxon
  • polyamides are nylon-6, nylon 6,6, nylon- 11 and nylon-12. These polyamides are available from a number of sources such as Nyltech North America of Manchester, NH, Emser
  • a compatible tackifying resin may be added to the extrudable compositions described above to provide tackified materials that autogenously bond.
  • Any tackifier resin can be used which is compatible with the polymers and can withstand the high processing (e.g., extrusion) temperatures. If the polymer is blended with processing aids such as, for example, polyolefins or extending oils, the tackifier resin should also be compatible with those processing aids.
  • hydrogenated hydrocarbon resins are preferred tackifying resins, because of their better temperature stability.
  • REGALREZ® and ARKON® P series tackifiers are examples of hydrogenated hydrocarbon resins.
  • ZONATAC®501 lite is an example of a terpene hydrocarbon.
  • REGALREZ® hydrocarbon resins are available from Hercules Inco ⁇ orated.
  • ARKON® P series resins are available from Arakawa Chemical (USA) Inco ⁇ orated.
  • the tackifying resins such as disclosed in U.S. patent No. 4,787,699, hereby inco ⁇ orated by reference, are suitable.
  • Other tackifying resins which are compatible with the other components of the composition and can withstand the high processing temperatures, can also be used. It is also possible to have other materials blended in minor amounts with the polymers used to produce the nonwoven and/or film layer according to this invention like fluorocarbon chemicals to enhance chemical repellency which may be, for example, any of those taught in U.S.
  • Fire retardants and pigments for spunbond and meltblown thermoplastic polymers are known in the art and are internal additives.
  • a pigment, e.g. TiO 2 if used, is generally present in an amount less than 5 weight percentage of the layer while other materials may be present in a cumulative amount less than 25 weight percent.
  • Ultraviolet radiation resistance improving chemical may be, for example, hindered amines and other commerciallly available compounds. Hindered amines are discussed in U.S.
  • Patent 5,200,443 to Hudson and examples of such amines are Hostavin TMN 20 from American Hoescht Co ⁇ oration of Somerville, New Jersey, Chimassorb® 944 FL from the Ciba-Geigy Co ⁇ oration of Hawthorne, New York, Cyasorb UV-3668 from American Cyanamid Company of Wayne, New Jersey and Uvasil-299 from Enichem Americas, Inc. of New York. Dust sock laminates of this invention may also have topical treatments applied to them for more specialized functions. Such topical treatments and their methods of application are known in the art and include, for example, alcohol repellency treatments, anti-static treatments and the like, applied by spraying, dipping, etc. An example of such a topical treatment is the application of Zelec® antistat (available from E.I. duPont, Wilmington, Delaware).
  • sample data numbered 1-6 include a Comparative Example (1), and examples of webs of the invention (2-5, 7 and 8).
  • the testing was done according to the test methods cited above with the differential pressure being measured as described in the NaCl efficiency test manual.
  • Sample 1 is a canvas fabric used commercially in the production of dust socks. It has a relatively poor filtration efficiency, high differential pressure and low airflow yet is quite heavy.
  • Sample 2 is a laminate of two spunbond fabrics, each of which weighed 2.5 osy (85 gsm) with two meltblown layers having a basis weight of 0.5 osy (17 gsm) each, between them .
  • the spunbond was produced from Himont's PF-305 polypropylene and the meltblown from Himont's PF-015.
  • the spunbond layers each included about 1.25 weight percent of Chimassorb® 944 FL and the meltblown layers each included about 1 weight percent of the same chemical.
  • These layers also had a pigment from the Standridge Chemical Co ⁇ . of Social Circle, GA, present in an amount less than 3 weight percent.
  • the particular pigment was SCC- 5181 (tan) though SCC-4876 (blue) and SCC-8992 (gray) are also used.
  • Sample 3 is a laminate of two spunbond layers, each of which weighed 1.3 osy (44 gsm). The spunbond layers were produced using Himont's PF-305 polypropylene polymer.
  • Sample 4 is a laminate of two spunbond layers, each of which weighed 1.3 osy (44 gsm), between which there is a 2 osy (68 gsm) spunbond layer of side by side polyethylene/polyproplyene.
  • the outer spunbond layers were produced using Himont's PF-305.
  • the inner spunbond layer was a side-by-side conjugate fabric produced using Himont's PF-305 polypropylene and Dow Chemical's ASPUN® 6811 A in a 50/50 ratio.
  • Sample 5 is a laminate of two spunbond fabrics, each of which weighed 2.5 osy (85 gsm). The spunbond was produced from a Himont's PF-305 polymer.
  • Sample 6 is an example of a single layer, non-laminated 2.7 osy (92 gsm) fabric.
  • the spunbond was a sheath/core conjugate fiber of Dow Chemical's ASPUN® 6811 A polyethylene (sheath) and nylon 6 from Nyltech North America (core).
  • Sample 7 is a laminate of two 3 osy (102 gsm) layers of conjugate spunbond fabric using the polymers of the inner spunbond layer of sample 4.
  • Sample 8 is a laminate identical to sample 7 except that it included a 5 inch by 5 inch (127 by 127 mm) scrim fabric between the conjugate spunbond layers.
  • the scrim was an EVA coated polypropylene available from Conwed Plastics Inc., of Minneapolis, MN.
  • the dust sock laminate fabrics of this invention have higher Frazier permeability and higher efficiency than canvas while weighing at least one third less than canvas, i.e., compared to a given canvas fabric, the fabric of this invention will have a higher Frazier permeability and higher NaCl efficiency while weighing about two thirds as much as the canvas. More particularly, it is desired that such dust sock fabrics have an NaCl efficiency above about 60 percent with a basis weight between about 85 and 205 gsm, or still more particularly between about 85 and 170 gsm. It is preferred that the Frazier permeability be above about 100 CFM/SF.

Abstract

A dust sock filter medium laminate is provided which has at least two nonwoven webs of microfibers which have an average diameter (using a sample size of at least 10) between about 10 and 25 microns and which webs have been joined by a method comprising the steps of (a) directing the component layers to a separation zone, (b) applying water in the amount of from about 5 % to 25 % based on the weight of the combined layers, (c) combining the component layers, (d) passing the combination through a sonic bonder operating within the range of up to about 40,000 cps against a patterned anvil to produce a corresponding pattern of thermal bond areas over about 3 % to 25 % of the surface area of the combination, and, (e) drying the sonically bonded combination.

Description

HIGH EFFICIENCY DUST SOCK
BACKGROUND OF THE INVENTION
This invention relates generally to a nonwoven fabric or web which is formed from spunbond fibers of a thermoplastic resin, and laminates using such a web as a component. The fabric is used as a filter, particularly for industrial applications where the fabric is in the form of a sock.
Thermoplastic resins have been extruded to form fibers, fabrics and webs for a number of years. The most common thermoplastics for this application are polyolefins, particularly polypropylene. Other materials such as polyesters, polyetheresters, polyamides and polyurethanes are also used to form nonwoven spunbond fabrics.
Nonwoven fabrics or webs are useful for a wide variety of applications such as diapers, feminine hygiene products, towels, recreational or protective fabrics and as geotextiles and filter media. The nonwoven webs used in these applications may be simply spunbond fabrics but are often in the form of nonwoven fabric laminates like spunbond/spunbond (SS) laminates or spunbond/meltblown/spunbond (SMS) laminates.
As filter media, some of the desired characteristics of nonwoven fabrics are that they be permeable to the fluid being filtered yet have a high filtration efficiency. Permeability to the fluid being filtered is quite important as low permeability could result in a high pressure drop across the filter requiring a higher, and hence more costly, energy input into the filtered fluid and shortening filter life. In a dust sock application, a fan is generally used to force air through the sock. A sock having low permeability increases the back pressure on the fan and so increases the energy input required to move the same amount of fluid and shortens the fan's life.
High filtration efficiency is, of course, the main purpose for a filter and great efficiency and ability to maintain the efficiency at an acceptable level are key to filter performance.
It is an object of this invention to provide a spunbond polyolefin nonwoven fabric or web for use as a filter medium which has a high permeability and high filtration efficiency. It is a further object of this invention to provide a dust sock filter made from the filter medium.
SUMMARY OF THE INVENTION
The objects of this invention are achieved by a dust sock filter medium laminate which has at least two nonwoven webs of microfibers which have an average diameter (using a sample size of at least 10) between about 10 and 25 microns and which webs have been joined by a method comprising the steps of (a) directing the component layers to a separation zone, (b) applying water in the amount of from about 5% to 25% based on the weight of the combined layers, (c) combining the component layers, (d) passing the combination through a sonic bonder operating within the range of up to about 40,000 cps against a patterned anvil to produce a corresponding pattern of thermal bond areas over about 3% to 25% of the surface area of the combination, and, (e) drying the sonically bonded combination. While this invention is directed mainly to air filtration, other gasses may be filtered as well. The dust socks of this invention desirably have a basis weight between about 85 and 205 gsm, a Frazier permeability of above 100
CFM/SF and an NaCl efficiency above about 60 percent.
BRIEF DESCRIPTION OF THE DRAWING
The Figure is a schematic drawing of a dust sock attached to a fan.
DEFINITIONS
As used herein the term "nonwoven fabric or web" means a web having a structure of individual fibers or threads which are interlaid, but not in an identifiable manner as in a knitted fabric. Nonwoven fabrics or webs have been formed from many processes such as, for example, meltblowing processes, spunbonding processes, and bonded carded web processes. The basis weight of nonwoven fabrics is usually expressed in ounces of material per square yard (osy) or grams per square meter (gsm) and the fiber diameters useful are usually expressed in microns. (Note that to convert from osy to gsm, multiply osy by 33.91).
As used herein the term "microfibers" means small diameter fibers having an average diameter not greater than about 75 microns, for example, having an average diameter of from about 0.5 microns to about 50 microns, or more particularly, microfibers may have an average diameter of from about 2 microns to about 40 microns. Another frequently used expression of fiber diameter is denier, which is defined as grams per 9000 meters of a fiber and may be calculated as fiber diameter in microns squared, multiplied by the density in grams/cc, multiplied by 0.00707. A lower denier indicates a finer fiber and a higher denier indicates a thicker or heavier fiber. For example, the diameter of a polypropylene fiber given as 15 microns may be converted to denier by squaring, multiplying the result by .89 g/cc and multiplying by .00707. Thus, a 15 micron polypropylene fiber has a denier of about 1.42 (152 x 0.89 x .00707 = 1.415). Outside the United States the unit of measurement is more commonly the "tex", which is defined as the grams per kilometer of fiber. Tex may be calculated as denier/9.
As used herein the term "spunbonded fibers" refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced as by, for example, in U.S. Patent no. 4,340,563 to Appel et al., and U.S. Patent no. 3,692,618 to Dorschner et al., U.S. Patent no. 3,802,817 to Matsuki et al., U.S. Patent nos. 3,338,992 and 3,341,394 to Kinney, U.S. Patent no. 3,502,763 to Hartman, and U.S. Patent no. 3,542,615 to Dobo et al. Spunbond fibers are generally not tacky when they are deposited onto a collecting surface. Spunbond fibers are generally continuous and have average diameters (using a sample size of at least 10) larger than 7 microns, more particularly, between about 10 and 25 microns.
As used herein the term "meltblown fibers" means fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity, usually hot, gas (e.g. air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly disbursed meltblown fibers. Such a process is disclosed, for example, in U.S. Patent no. 3,849,241 to Butin. Meltblown fibers are microfibers which may be continuous or discontinuous, are generally smaller than 10 microns in average diameter (using a sample size of at least 10), and are generally tacky when deposited onto a collecting surface.
As used herein the term "conjugate fibers" refers to fibers which have been formed from at least two polymers extruded from separate extruders but spun together to form one fiber. Conjugate fibers are also sometimes referred to as multicomponent or bicomponent fibers. The polymers are usually different from each other though conjugate fibers may be monocomponent fibers. The polymers are arranged in substantially constantly positioned distinct zones across the cross- section of the conjugate fibers and extend continuously along the length of the conjugate fibers. The configuration of such a conjugate fiber may be, for example, a sheath/core arrangement wherein one polymer is surrounded by another or may be a side by side arrangement, a segmented configuration or an "islands-in-the-sea" arrangement. Conjugate fibers are taught in U.S. Patent 5,108,820 to Kaneko et al., U.S. Patent 5,336,552 to Strack et al., and U.S. Patent 5,382,400 to Pike et al. For two component fibers, the polymers may be present in ratios of 75/25, 50/50, 25/75 or any other desired ratios.
As used herein "thermal point bonding" involves passing a fabric or web of fibers to be bonded between a heated calender roll and an anvil roll. The calender roll is usually, though not always, patterned in some way so that the entire fabric is not bonded across its entire surface and the anvil is usually flat. As a result, various patterns for calender rolls have been developed for functional as well as aesthetic reasons. One example of a pattern is the Hansen Pennings or "H&P" pattern with between about a 5 and 50% bond area with between about 50-3200 bonds/square inch as taught in U.S. Patent 3,855,046 to Hansen and Pennings. One example of the H&P pattern has square point or pin bonding areas wherein each pin has a side dimension of 0.038 inches (0.965 mm), a spacing of 0.070 inches (1.778 mm) between pins, and a depth of bonding of 0.023 inches (0.584 mm). Another typical point bonding pattern is the expanded Hansen Pennings or "EHP" bond pattern which produces about a 15% bond area with a square pin having a side dimension of 0.037 inches (0.94 mm), a pin spacing of 0.097 inches (2.464 mm) and a depth of 0.039 inches (0.991 mm). Another typical point bonding pattern designated "714" has square pin bonding areas wherein each pin has a side dimension of 0.023 inches, a spacing of 0.062 inches (1.575 mm) between pins, and a depth of bonding of 0.033 inches (0.838 mm). The resulting pattern has a bonded area of about 15%. Yet another common pattern is the C-Star pattern which has a bond area of about 16.9%. The C-Star pattem has a cross-directional bar or "corduroy" design interrupted by shooting stars. Other common patterns include a diamond pattem with repeating and slightly offset diamonds and a wire weave pattem looking as the name suggests, e.g. like a window screen. Typically, the percent bonding area varies from around 10% to around 30% of the area of the fabric laminate web. As in well known in the art, the spot bonding holds the laminate layers together as well as imparts integrity to each individual layer by bonding filaments and/or fibers within each layer.
As used herein, "ultrasonic bonding" means a process performed, for example, by passing the fabric between a sonic horn and anvil roll as illustrated in U.S. Patent 4,374,888 to Bomslaeger.
TEST METHODS
Frazier Permeability: A measure of the permeability of a fabric or web to air is the Frazier Permeability which is performed according to Federal Test Standard No. 191 A, Method 5450 dated July 20, 1978, and is reported as an average of 3 sample readings. Frazier Permeability measures the air flow rate through a web in cubic feet of air per minute per square foot of web or CFM/SF. Convert CFM/SF to liters per square meter per minute (LSM) by multiplying CFM/SF by 304.8.
NaCl Efficiency: The NaCl Efficiency is a measure of the ability of a fabric or web to stop the passage of small particles through it. A higher efficiency is generally more desirable and indicates a greater ability to remove particles. NaCl efficiency is measured in percent according to the TSI Inc., Model 8110 Automated Filter Tester Operation Manual of February 1993, P/N 1980053, revision D, at a flow rate of 32 liters per minute using 0.1 micron sized NaCl particles and is reported as an average of 3 sample readings. The manual is available from TSI Inc. at PO Box 64394, 500 Cardigan Rd, St. Paul, MN 55164. This test also can yield a pressure differential across a fabric using the same particle size and airflow rate.
Melt Flow Rate: The melt flow rate (MFR) is a measure of the viscosity of a polymer. The MFR is expressed as the weight of material which flows from a capillary of known dimensions under a specified load or shear rate for a measured period of time and is measured in grams/10 minutes at a set temperature and load according to, for example, ASTM test 1238-90b.
DETAILED DESCRIPTION
The spunbond process generally uses a hopper which supplies polymer to a heated extruder. The extruder supplies melted polymer to a spinneret where the polymer is fiberized as it passes through fine openings arranged in one or more rows in the spinneret, forming a curtain of filaments. The filaments are usually quenched with air at a low pressure, drawn, usually pneumatically and deposited on a moving foraminous mat, belt or "forming wire" to form the nonwoven web. Polymers useful in the spunbond process generally have a process melt temperature of between about 400°F to about 610°F (200°C to 320βC).
The fibers produced in the spunbond process are usually in the range of from about 10 to about 50 microns in average diameter, depending on process conditions and the desired end use for the webs to be produced from such fibers. For example, increasing the polymer molecular weight or decreasing the processing temperature results in larger diameter fibers. Changes in the quench fluid temperature and pneumatic draw pressure can also affect fiber diameter. The fibers used in the practice of this invention usually have average diameters in the range of from about 7 to about 35 microns, more particularly from about 15 to about 25 microns.
The fabric of this invention may be a multilayer laminate and may be formed by a number of different techniques including but not limited to using adhesive, needle punching, ultrasonic bonding, thermal calendering and any other method known in the art. Such a multilayer laminate may be an embodiment wherein some of the layers are spunbond and some meltblown such as a spunbond/meltblown/spunbond (SMS) laminate as disclosed in U.S. Patent no. 4,041,203 to Brock et al. and U.S. Patent no. 5,169,706 to Collier, et al. or as a spunbond/spunbond laminate. An SMS laminate may be made by sequentially depositing onto a moving conveyor belt or forming wire first a spunbond web layer, then a meltblown web layer and last another spunbond layer and then bonding the laminate in a manner described above. Altematively, the three web layers may be made individually, collected in rolls, and combined in a separate bonding step.
The fabric may also be a laminate of spunbond fabric and scrim materials. Scrim materials provide little mass and essentially no filtration ability but do provide an additional degree of intregrity or strength to the fabric. Scrims usually are fibers bonded together to produce a square pattem which is quite large, e.g. as much as 5 inches (127mm) by 5 inches, though the pattem need not be exactly square. Scrims may be, for example, 3 inches (76mm) by 2 inches (51mm), 4 inches (101 mm) by 4 inches, and 3 inches (76 mm) by 3 inches. When a scrim is used it should be place between two other layers so that its ability to provide integrity to the fabric is maximized. Scrims may be made from any polymer known conventionally as being used for that purpose, examples include, polypropylene, ethyl vinyl acetate (EVA), polyamides, polyurethane, polybutylene, polystyrene, polyvinyl chloride, polyethylene, polyethylene terephathalate, and polytetrafluoroethylene. The area in which the web of this invention finds utility is as a dust sock for industrial applications. In such applications, fans are used to move air away from a work area. The air moved by the fan contains particulates which must be removed from the air for safety or environmental reasons. The fans used to move the air are generally a few feet in diameter and are fitted on the discharge side with a long cylindrical fabric "sock" to catch the particles. The Figure shows a dust sock (1) attached to a fan (2) and such a sock may be, for example, about 1 to 2 feet (25 to 61 cm) in diameter and about 8 to 15 feet (244 to 915 cm) in length. In the past materials such as cotton and canvas have been used but such materials are quite heavy and do not have the filtration efficiency of the nonwoven fabrics of this invention. The more permeable, higher efficiency fabrics of this invention will allow smaller socks to be used than, for example, a canvas sock, for the same particulate load. Filter fabrics for use in this invention may have basis weights ranging from about 0.25 osy (8.5 gsm) to about 10 osy (340 gsm).
The fibers used to produce the web of this invention maybe conjugate fibers, such as side-by-side (S/S) fibers. The polymers used to produce the fibers are may be polyamides, polyurethane, polybutylene, polyvinylchloride, polytetrafluoroethylene, polystyrene, polyethylene terephathalate, polycarbonates,
4-methyl-1-pentene and polyolefins, particulariy polypropylene and polyethylene.
Many polyolefins are available for fiber production, for example polyethylenes such as Dow Chemical's ASPUN® 6811 A linear low density polyethylene, 2553 LLDPE and 25355 and 12350 high density polyethylene are such suitable polymers.
In addition, the polymers mentioned above for scrim production may be used. The polyethylenes have melt flow rates in g/10 min. at 190°F and a load of 2.16 kg, of about 26, 40, 25 and 12, respectively. Fiber forming polypropylenes include Exxon
Chemical Company's ESCORENE® PD 3445 polypropylene and Himont Chemical Co.'s PF-304 and PF-305. Many other fiber forming polyolefins are commercially available.
The polyamides which may be used in the practice of this invention may be any polyamide known to those skilled in the art including copolymers and mixtures thereof. Examples of polyamides and their methods of synthesis may be found in "Polymer Resins" by Don E. Floyd (Library of Congress Catalog number 66-20811 ,
Reinhold Publishing, NY, 1966). Particularly commercially useful polyamides are nylon-6, nylon 6,6, nylon- 11 and nylon-12. These polyamides are available from a number of sources such as Nyltech North America of Manchester, NH, Emser
Industries of Sumter, South Carolina (Grilon® & Grilamid® nylons) and Atochem Inc. Polymers Division, of Glen Rock, New Jersey (Rilsan® nylons), among others.
In addition, a compatible tackifying resin may be added to the extrudable compositions described above to provide tackified materials that autogenously bond. Any tackifier resin can be used which is compatible with the polymers and can withstand the high processing (e.g., extrusion) temperatures. If the polymer is blended with processing aids such as, for example, polyolefins or extending oils, the tackifier resin should also be compatible with those processing aids. Generally, hydrogenated hydrocarbon resins are preferred tackifying resins, because of their better temperature stability. REGALREZ® and ARKON® P series tackifiers are examples of hydrogenated hydrocarbon resins. ZONATAC®501 lite is an example of a terpene hydrocarbon. REGALREZ® hydrocarbon resins are available from Hercules Incoφorated. ARKON® P series resins are available from Arakawa Chemical (USA) Incoφorated. The tackifying resins such as disclosed in U.S. patent No. 4,787,699, hereby incoφorated by reference, are suitable. Other tackifying resins which are compatible with the other components of the composition and can withstand the high processing temperatures, can also be used. It is also possible to have other materials blended in minor amounts with the polymers used to produce the nonwoven and/or film layer according to this invention like fluorocarbon chemicals to enhance chemical repellency which may be, for example, any of those taught in U.S. patent 5,178,931, fire retardants, ultraviolet radiation resistance improving chemicals and pigments to give each layer the same or distinct colors. Fire retardants and pigments for spunbond and meltblown thermoplastic polymers are known in the art and are internal additives. A pigment, e.g. TiO2, if used, is generally present in an amount less than 5 weight percentage of the layer while other materials may be present in a cumulative amount less than 25 weight percent. Ultraviolet radiation resistance improving chemical may be, for example, hindered amines and other commerciallly available compounds. Hindered amines are discussed in U.S. Patent 5,200,443 to Hudson and examples of such amines are Hostavin TMN 20 from American Hoescht Coφoration of Somerville, New Jersey, Chimassorb® 944 FL from the Ciba-Geigy Coφoration of Hawthorne, New York, Cyasorb UV-3668 from American Cyanamid Company of Wayne, New Jersey and Uvasil-299 from Enichem Americas, Inc. of New York. Dust sock laminates of this invention may also have topical treatments applied to them for more specialized functions. Such topical treatments and their methods of application are known in the art and include, for example, alcohol repellency treatments, anti-static treatments and the like, applied by spraying, dipping, etc. An example of such a topical treatment is the application of Zelec® antistat (available from E.I. duPont, Wilmington, Delaware).
The following sample data numbered 1-6 include a Comparative Example (1), and examples of webs of the invention (2-5, 7 and 8). The testing was done according to the test methods cited above with the differential pressure being measured as described in the NaCl efficiency test manual.
Sample 1 is a canvas fabric used commercially in the production of dust socks. It has a relatively poor filtration efficiency, high differential pressure and low airflow yet is quite heavy.
Sample 2 is a laminate of two spunbond fabrics, each of which weighed 2.5 osy (85 gsm) with two meltblown layers having a basis weight of 0.5 osy (17 gsm) each, between them . The spunbond was produced from Himont's PF-305 polypropylene and the meltblown from Himont's PF-015. The spunbond layers each included about 1.25 weight percent of Chimassorb® 944 FL and the meltblown layers each included about 1 weight percent of the same chemical. These layers also had a pigment from the Standridge Chemical Coφ. of Social Circle, GA, present in an amount less than 3 weight percent. The particular pigment was SCC- 5181 (tan) though SCC-4876 (blue) and SCC-8992 (gray) are also used. A similar laminate of lower basis weight is available as a car cover under the trade name Evolution® 4 fabric from the Kimberly-Clark Coφoration of Dallas, TX. Sample 3 is a laminate of two spunbond layers, each of which weighed 1.3 osy (44 gsm). The spunbond layers were produced using Himont's PF-305 polypropylene polymer.
Sample 4 is a laminate of two spunbond layers, each of which weighed 1.3 osy (44 gsm), between which there is a 2 osy (68 gsm) spunbond layer of side by side polyethylene/polyproplyene. The outer spunbond layers were produced using Himont's PF-305. The inner spunbond layer was a side-by-side conjugate fabric produced using Himont's PF-305 polypropylene and Dow Chemical's ASPUN® 6811 A in a 50/50 ratio. Sample 5 is a laminate of two spunbond fabrics, each of which weighed 2.5 osy (85 gsm). The spunbond was produced from a Himont's PF-305 polymer. Sample 6 is an example of a single layer, non-laminated 2.7 osy (92 gsm) fabric. The spunbond was a sheath/core conjugate fiber of Dow Chemical's ASPUN® 6811 A polyethylene (sheath) and nylon 6 from Nyltech North America (core).
Sample 7 is a laminate of two 3 osy (102 gsm) layers of conjugate spunbond fabric using the polymers of the inner spunbond layer of sample 4.
Sample 8 is a laminate identical to sample 7 except that it included a 5 inch by 5 inch (127 by 127 mm) scrim fabric between the conjugate spunbond layers. The scrim was an EVA coated polypropylene available from Conwed Plastics Inc., of Minneapolis, MN.
It should be noted that all laminates were produced according to the procedure of US patent no. 4,605,454 to Sayovitz et al., commonly assigned, and incoφorated herein by reference in its entirety. This patent teaches a method of forming a composite nonwoven web material having a basis weight in the range of from about 1.5 osy (52 gsm) to 9 osy (306 gsm) from component layers containng thermoplastic fibers, each having a basis weight in the range of from about 0.5 osy (17 gsm) to 3 osy (102 gsm) comprising the steps of (a) directing the component layers to a separation zone, (b) applying water in the amount of from about 5% to 25% based on the weight of the combined layers, (c) combining the component layers, (d) passing the combination through a sonic bonder operating within the range of up to about 40,000 cps against a patterned anvil to produce a corresponding pattem of thermal bond areas over about 3% to 25% of the surface area of the combination, and (e) drying said sonically bonded combination.
TABLE 1
Sample Basis Weight Frazier Permeability % Efficiency Pressure (gm) (CFM/SF) (0.1 um NaCD Differential
1 319 16 25 10
2 203 18 98 10
3 88 129 62 1.2
4 159 83 87 1.9
5 166 49 95 3.4
6 92 NA 11 3
7 203 84 58 1.8
8 231 85 61 1.9
The results show that the filter medium laminates of this invention, samples 2-5, 7 and 8, have a good combination of permeability and efficiency and yet are signficanlty lighter than the commercial canvas fabric now in widespread use. Note that in sample 2, though the Frazier permeability is about the same as the canvas of sample 1 , the efficiency is much higher, indicating a lighter fabric could be made having a higher Frazier permeability than canvas yet also having a much higher efficiency than canvas. In particular, the dust sock laminate fabrics of this invention have higher Frazier permeability and higher efficiency than canvas while weighing at least one third less than canvas, i.e., compared to a given canvas fabric, the fabric of this invention will have a higher Frazier permeability and higher NaCl efficiency while weighing about two thirds as much as the canvas. More particularly, it is desired that such dust sock fabrics have an NaCl efficiency above about 60 percent with a basis weight between about 85 and 205 gsm, or still more particularly between about 85 and 170 gsm. It is preferred that the Frazier permeability be above about 100 CFM/SF.
Although only a few exemplary embodiments of this invention have been described in detail above, those skilled in the art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this invention as defined in the following claims. In the claims, means plus function claims are intended to cover the structures described herein as performing the recited function and not only structural equivalents but also equivalent structures. Thus although a nail and a screw may not be structural equivalents in that a nail employs a cylindrical surface to secure wooden parts together, whereas a screw employs a helical surface, in the environment of fastening wooden parts, a nail and a screw may be equivalent structures.

Claims

What is claimed is:
1. A dust sock filter medium laminate comprising at least two nonwoven webs of microfibers which have an average diameter (using a sample size of at least 10) between about 10 and 25 microns and which webs have been joined by a method comprising the steps of:
(a) directing the component layers to a separation zone,
(b) applying water in the amount of from about 5% to 25% based on the weight of the combined layers,
(c) combining the component layers, (d) passing the combination through a sonic bonder operating within the range of up to about 40,000 cps against a patterned anvil to produce a corresponding pattem of thermal bond areas over about 3% to 25% of the surface area of the combination, and;
(e) drying said sonically bonded combination.
2. The dust sock filter medium laminate of claim 1 wherein said microfibers are spunbond fibers.
3. The dust sock filter medium laminate of claim 2 wherein at least one of said microfiber webs of spunbond fibers is comprised of spunbond fibers having a conjugate configuration.
4. The dust sock filter medium laminate of claim 3 wherein said conjugate spunbond fibers are in a side-by-side configuration.
5. The dust sock filter medium laminate of claim 4 wherein said conjugate spunbond fibers are comprised of polypropylene and polyethylene.
6. The dust sock filter medium laminate of claim 3 wherein said conjugate spunbond fibers are in a sheath/core configuration.
7. The dust sock filter medium laminate of claim 3 wherein said conjugate spunbond fibers are comprised of polyolefin and polyamide.
8. The dust sock filter medium laminate of claim 7 wherein said polyolefin is selected from the group consisting of polyethylene and polypropylene.
9. The dust sock filter medium laminate of claim 1 wherein said laminate has an NaCl efficiency above about 60 percent.
10. The dust sock filter medium laminate of claim 1 wherein said laminate has a basis weight between about 85 and 205 gsm.
11. The dust sock filter medium laminate of claim 10 wherein said laminate has a basis weight between about 85 and 170 gsm.
12. The dust sock filter medium laminate of claim 1 further comprising a scrim layer between said webs.
13. A dust sock comprised of the fabric of claim 1.
14. A dust sock comprising at least two nonwoven webs of microfibers which have an average diameter (using a sample size of at least 10) between about 10 and 25 microns and which webs have been joined by a method comprising the steps of:
(a) directing the component layers to a separation zone,
(b) applying water in the amount of from about 5% to 25% based on the weight of the combined layers, (c) combining the component layers,
(d) passing the combination through a sonic bonder operating within the range of up to about 40,000 cps against a patterned anvil to produce a corresponding pattem of thermal bond areas over about 3% to 25% of the surface area of the combination, and; (e) drying said sonically bonded combination, wherein said dust sock has an NaCl filtration efficiency above about 60 percent, a basis weight between about 85 and 170 gsm and a Frazier permeability above about 100 CFM/SF.
15. The dust sock of claim 14 wherein said microfibers are spunbond polypropylene fibers.
PCT/US1996/019851 1995-12-22 1996-12-11 High efficiency dust sock WO1997023265A1 (en)

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US08/577,368 US5607735A (en) 1995-12-22 1995-12-22 High efficiency dust sock

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