WO1997039203A2 - Fiber-reinforced concrete building material - Google Patents

Fiber-reinforced concrete building material Download PDF

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Publication number
WO1997039203A2
WO1997039203A2 PCT/US1997/006363 US9706363W WO9739203A2 WO 1997039203 A2 WO1997039203 A2 WO 1997039203A2 US 9706363 W US9706363 W US 9706363W WO 9739203 A2 WO9739203 A2 WO 9739203A2
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WO
WIPO (PCT)
Prior art keywords
concrete
structural
weight units
structural concrete
fiber
Prior art date
Application number
PCT/US1997/006363
Other languages
French (fr)
Other versions
WO1997039203A3 (en
Inventor
George C. Bobo
Original Assignee
Concrete Technology 1, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Concrete Technology 1, Ltd. filed Critical Concrete Technology 1, Ltd.
Priority to AU28031/97A priority Critical patent/AU2803197A/en
Publication of WO1997039203A2 publication Critical patent/WO1997039203A2/en
Publication of WO1997039203A3 publication Critical patent/WO1997039203A3/en
Priority to MXPA/A/1997/009803A priority patent/MXPA97009803A/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/52Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/12Roofing elements shaped as plain tiles or shingles, i.e. with flat outer surface
    • E04D1/16Roofing elements shaped as plain tiles or shingles, i.e. with flat outer surface of ceramics, glass or concrete, with or without reinforcement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/29Producing shaped prefabricated articles from the material by profiling or strickling the material in open moulds or on moulding surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B17/00Details of, or accessories for, apparatus for shaping the material; Auxiliary measures taken in connection with such shaping
    • B28B17/02Conditioning the material prior to shaping
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/288Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and concrete, stone or stone-like material
    • E04C2/2885Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and concrete, stone or stone-like material with the insulating material being completely surrounded by, or embedded in, a stone-like material, e.g. the insulating material being discontinuous
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/29Means for connecting or fastening adjacent roofing elements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00129Extrudable mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00586Roofing materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00637Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials

Definitions

  • steel fibers may be mixed with polypropylene fibers. It has been found that when such mixture is used. approximately 0 1 weight units of steel fiber and about 0.0075 weight units of polypropylene fibers will provide satisfactory results When mixed properly, the fibers within the structural concrete ofthe present invention will be found to be oriented in random directions and distributed substantially uniformly within the fiber-reinforced structural concrete after the structural fiber-reinforced concrete has cured
  • the structural concrete of the present invention may be made by mixing one 94 lb bag of Po ⁇ land Type I or Type II cement with one 94 lb. bag of salt-free clean masonry sand
  • the water required for such an amount of sand and cement is about 31 lbs
  • approximately 16 ounces of liquid sodium silicate are used with about 8 ounces of plasticizer
  • a polypropylene fiber is used. 1 lb of polypropylene fiber is added to the mixture. If a steel fiber is used, approximate!) 13 lbs ol steel fiber are added to the mixture
  • the resulting hardened concrete 10 is shown in Figure 3 Note that the fibers 10 are substantialh uniformh distributed and randomh oriented
  • the mold 30 should be covered with a moisture resistant material (not shown) to retain moisture w ithin
  • the strength and flexibility of the fiber-reinforced structural concrete of the present invention 10 lends itself to the manufacturer of a wide variety of products as shown, for example, in Figures 5, 6, 10, 1 1 which may be used to erect buildings or residences as shown in Figures 15 and 21.
  • the female end of a threaded fastener 46 is molded into the building panel 100 and the male end of a threaded fastener 48 extends therefrom.
  • lifting plate 52 having a lifting plate 52 is attached to the end of the panel 100 so that a hook 54 may be used. If desired, plate 50 and lifting plate 52 may be eliminated by placing eye bolts into
  • the molding into a building panel 100 a wooden or metal frame.
  • the wooden or metal frame may later be used as a support or an outer frame of a window or a door assembly.
  • tunnels or passageways 140 ( Figure 15) may be formed in the building panels 100.
  • Figure 14A of simulated stucco and wood surface 132 is shown.
  • Figure 14B illustrates a
  • any desired surface may be placed in the outer surface of the concrete shingles or shakes 200, 204.
  • concrete shingles or shakes 200, 204 are made
  • roof trusses may be molded using the structural concrete ofthe present invention.
  • FIG. 15A Such mcthoc' of construction involves embedding metal plates 56 in a poured
  • Additional threaded fasteners may be used at other locations on the molded wall panel to tie the wall panels 100 one to
  • the panels 100 are formed so that a corner column void 90 is formed as shown in Figure 19B. It is also recommended that a horizontal metal reinforcing bar 88 in the
  • FIG. 21 A typical floor plan for a low cost dwelling 450 is shown in Figure 21 . Therein it
  • This area opens into a living area 402. Behind the living area 402 is a dining area 404 which opens into a kitchen 406. Adjacent to the kitchen 406 is a bath 408 which is adjacent to a bedroom 410. This entire structure 450 may be erected pursuant to the method illustrated

Abstract

A fiber-reinforced concrete (10) used for molding or extruding a variety of building materials (100, 126, 200, 204, 300, 450, 500) includes a mixture of cement, sand, water, liquid sodium silicate, plasticizer and hydrophobic fiber. The water, liquid sodium silicate and plasticizer are mixed together before adding the sand and cement to the mixture. The last component to be added to the mixture is the hydrophobic fiber.

Description

FIBER-REINFORCED CONCRETE BUILDING MATERIAL
This application claims the benefit of U.S. Pi owsional Patent Application Seπal
Number 60/015598 filed April 1 8. 1996
Field The present invention pertains to fiber-reinforced concrete, more particularly, the
present invention peπains to fiber-reinforced concrete used in the construction of buildings
or residences
Background The search for low-cost housing has been a problem that has plagued builders and
governments for many years The beneficial effects associated with home ownership are
well recognized. Early in the 20th centun . Thomas Edison indicated that "I am going to live
to see the day when a working man's home can be built of concrete in a week if I
succeed, it will take from the city's slums everybody who is worth taking " Unfortunateh .
Thomas Edison's dream was never realized and the dreams of others to erect low-cost
housing are often not realized because of strict building code requirements and the
complexity of construction techniques
While fiber-reinforced concrete has been in use for many years, it has been difficult
to obtain a fiber-reinforced concrete where the fibers ai e uniformly distributed throughout
the concrete mixture This is because a relativeh liquid or wateπ mixture is needed to
assure distribution of the reinforcing fibers throughout the concrete Unfortunateh . such
liquid or water.' concrete mixture allows the fibers to migrate through the concrete mixture and settle on one side, thus creating a non-unirorm distribution of fibers One attempt to solve this problem has been to spray concrete and reinforcing fibers together This spraying
causes the concrete and the fibers to mix during the spraving process Unfortunately, the spray-mixing system produces un-predictable results, non-uniform strength propemes in the
sprayed concrete and massive clean-up problems for the operator
Another attempt to strengthen fiber-reinforced concrete has been to add a variety of
different additives to the mixture of water, cement and sand For example, either sodium silicate or plasticizers. sometimes called water-reducers, have been used Examples of such
fiber-reinforced concrete mixtures ma\ be found in U S Patent 2.623.828
U.S Patent 4.406.703
U S Patent 4.482.385
U S Patent 5.082.181
U.S Patent 5.167.710
A mixture of sodium silicate and a plasticizer appears in the non-fiber reinforced
concrete descπbed in U S Patent 5.482.549
Despite the man> attempts to make a low cost concrete usable concrete to build
homes there remains a need in the art to provide a fiber-remforced concrete which can be
used to manufacture and erect low-cost homes Such low-cost, fiber-reinforced concrete
homes should be durable, easy to construct and environmentally fπendh
Summary of the Invention
The fiber-remforced concrete of the present invention provides tor the manufacture
ol residences and buildings which are durable. eas\ to construct and environmental h
fπendh The fiber-reinforced concrete of the present invention includes a unique mixture of components which provides strong, durable, impact resistant and water-proof, fiber-reinforced concrete which can be used to build a vaπet\ of products from which low- cost buildings and residences may be built. The low -cost fiber-reinforced concrete of the present invention includes Poπland Type i or 1 ype II cement, sand and water. Added to the mixture of cement, sand and water is liquid sodium silicate and plasticizer. This mixture is fuπher strengthened by the addition of hydrophobic fibers. Because the concrete provides for the uniform distπbution and the random orientation of the hydrophobic fibers, the hydrophobic fibers serve to control the growth of cracks in the concrete and to act as energ\ absorbers should the concrete become cracked
Brief Description of the Figures
A better understanding of the fiber-reinforced concrete building mateπal of the present invention may be had by reference to the drawing figures wherein:
Figure 1 is a flow chaπ of the mixing process for the fiber-reinforced concrete building material of the present invention:
Figure 2 is a perspective view of the fiber-reinforced concrete of the present invention being formed into a wall panel in a mold.
Figure 3 is a perspective view in paπial section of a poπion of a wall panel. Figure 4 is a perspective view of a section of a wall panel showing the positioning of a metal weld plate:
Figure 4A is a perspective view of a panel w ith a lifting fixture attached. Figure 5 is a perspective view in paπial section showing the installation of a wall board:
SUBSTTTUTE SHEET (RULE 26) Figure 6 is a perspective view in paπial section of the installation of a roof panel.
Figure 7 is a perspective view of the installation of a wall panel havmg an outer skin utilizing the fiber-reinforced concrete of the present invention and 5 backing beams.
Figure 8 is a front elevational view of a fust alternate embodiment of a wall panel:
Figure 8 A is a left side elevational view of the wall panel shown in Figure 8: ] o Figure 9 is a front elevational view ol a first alternate embodiment ot a root panel:
Figure 9A is a top plan view of the rool panel illustrated in Figure 9. Figure 10 is a perspective view of siding shingles or shakes installed on a building or residence: 15 Figure 1 1 is a perspective view of roof shingles or shakes.
Figure 1 1 A is a perspective view of a roof having shingles or shakes formed of the concrete of the present invention installed thereon.
Figure 12 is a perspective view of a roof covered with roofing panels using the fiber-reinforced concrete of the present invention: 20 Figure 12A is a perspective view of the roof tiles shown in Figure 12.
Figure 12B is a perspective view of the installation of the roof tiles shown
in Figure 12A:
Figure 13 is a front elevational view of a wall panel including a door cutout and a brick outer surface. Figures 14A-F are front elevauonai views ot wall panels having a variety ot different outer surfaces and configurations.
Figure 15 is a perspective view illustrating the assembh of a dwelling using the wall and roof panels shown in Figures 5 and 6. Figure 15A is a perspective view of the installation of the bottom of a wall panel onto a foundation.
Figure 16 is a perspective view of an alternate method of installing wall panels to a foundation.
Figure 16A is a perspective view ot a fixture used in a foundation for () mounting wall panels thereto.
Figure 16B is an alternate embodiment ot the fixture illustrated in Figure 16A. but usable at the corner of a foundation.
Figure 17 is a perspective view of an alignment tool. Figure 17A is a top plan view of the alignment tool shown in Figure 17. 5 Figure 18 is a perspective view of a corner alignment tool.
Figure 18A is a top plan view of the corner alignment tool shown in Figure 18.
Figure 19 is a side elevational view of a wall panel mounted on a foundation according to the pour-in-place method. 0 Figure 19A is a top plan view of the pour-in-place method of mounting of a wall panel on a foundation as shown in Figure 19.
Figure 19B is a top plan view of the poui-in-place method of construction onlv at a corner.
SUBSTTTUTE SHEET (RULE 26) Figure 20 is a top plan view of the installation of a roof panel bv the pour-in-place method.
Figure 21 is a top plan view ol a typical floor plan for a dwelling using the construction panels made of the fiber-reinforced concrete of the present invention Figure 22 is a perspective view oi a modular house made of the fiber-reinforced concrete of the present invention.
Figure 22A is a left side module of the house shown in Figure 22. Figure 22B is a center module of the house shown in Figure 22. and Figure 22C is a side module of the house shown in Figure 22 Description of the Embodiments
This section is divided into tour subsections. Components. Method of Manufacture. Products and Construction Methods While the drawing figures are referenced throughout all four sections, the drawing figures are organized to generally track with the descπptions m the Products and Construction Methods subsections
Components
The structural concrete of the present invention is a fiber-reinforced concrete In addition to the fiber component, the concrete also includes a dn component and a wet component The dry component includes sand and cement While equal quantities of sand and cement are used in the preferred embodiment, it has been found that the ratio ol sand to cement is not paπicularly cπtical For example, cement to sand ratios from about 3 1 to about 1 3 have proven satisfacton As the amount of sand with respect to cement is increased, the compressn e strength ot the fiber-reinforced concrete decreases while its tensile strength increases The preferred type oi cement is Type I oi I ype II Portland
6
SUBSTTTUTE SHEET (RULE 26) cement. The preferred type of sand is fine silica masonry grade sand. Such sand should be clean and essentially salt-free.
The wet component of the invention includes approximately 0.33 weight units of water when compared to the weight units of cement. In actual practice it has been found
5 that about 0.28 to about 0.40 weight units of water w ill also work. The water should be clean and salt-free. In the preferred embodiment, it has been found that de-mineralized or distilled water provides the best results. The wet component also includes approximately
0.01 weight units of liquid sodium silicate: however, the liquid sodium silicate may be reduced or increased by about 25% without a significant change in the propeπies of the
] () fiber-reinforced concrete. Liquid sodium silicate is often referred to as "liquid glass" or
"water glass." In the preferred embodiments, the liquid sodium silicate is marketed under the trademark "Crystal Lok" sold by Corroseal. Inc. Fuπher. the wet component includes preferably about 0.005 weight units of a plasticizer or a high range water reducer: however. the plasticizer may be reduced by as much as about 50% or increased by as much as about
] 5 300% without a significant change in the propeπies ofthe fiber-reinforced concrete. In the preferred embodiment, the plasticizer used is marketed under the trademark "Supercizer 7" sold by Fritz Industries. Inc. This plasticizer is funher described in U.S. Patent 4.961.790 and 5.120.367.
The third component of the structural concrete of the present invention is a fiber
20 component. The fibers in the fiber component may be selected from any number of commonly available fibers. The essential quality of the fibers is that they be resistant to absorbing water or hydrophobic. Specifically, fiberglass fibers may be used. If fiberglass fibers are used, approximately 0.10 weight units of fiberglass fibers are used with respect
7
SUBSTTTUTE SHEET (RULE 26) to 1 weight unit of cement. Nylon fibers may also be used If nylon fibers are used, it has been found that approximately 0.03 weight units of nvlon to 1 weight unit of cement will provide satisfactory results If the selected fiber is polypropylene, it has been found that approximately 0.01 weight units of polypropylene fibers to 1 weight unit of cement will provide satisfactory results Fuπher. the fiber component may be steel fibers. Such steel fibers are sold under the brand name "DRAMIX" by the Bekaeπ Corporation While mam lengths and diameters of steel fibers may be used, it has been found that in the preferred embodiment a steel fiber having a length of 30 millimeters and a diameter of 0.5 millimeters provides satisfactory results
If desired, different types of fibers mav be mixed For example, steel fibers may be mixed with polypropylene fibers. It has been found that when such mixture is used. approximately 0 1 weight units of steel fiber and about 0.0075 weight units of polypropylene fibers will provide satisfactory results When mixed properly, the fibers within the structural concrete ofthe present invention will be found to be oriented in random directions and distributed substantially uniformly within the fiber-reinforced structural concrete after the structural fiber-reinforced concrete has cured
As cement and sand are normally available in 94 lb bags, it has been found that the structural concrete of the present invention may be made by mixing one 94 lb bag of Poπland Type I or Type II cement with one 94 lb. bag of salt-free clean masonry sand The water required for such an amount of sand and cement is about 31 lbs To this mixture, approximately 16 ounces of liquid sodium silicate are used with about 8 ounces of plasticizer If a polypropylene fiber is used. 1 lb of polypropylene fiber is added to the mixture. If a steel fiber is used, approximate!) 13 lbs ol steel fiber are added to the mixture
SUBSTTTUTE SHEET (RULE 26) and if a combination of steel fiber and polypropylene fiber is used, approximate!} 10 lbs of steel fiber and approximately 0.75 lbs of polypropylene fiber are added to the mixture. As there is almost no waste, and none of the materials are toxic, the fiber- reinforced concrete of the present invention is environmentally fπendh Test Results
A test of the fiber-reinforced structural concrete of the present invention produced the followme results:
Figure imgf000011_0001
Method of Manufacture
The fiber-reinforced structural concrete of the present invention is made accordmg to the steps illustrated in the flow chaπ at Figure 1 First, water, preferabh clean, salt-free water, is mixed together with the liquid sodium silicate and the plasticizer for about 30 seconds in the following propomons.
SUBSTTTUTE SHEET (RULE 26) about 0 33 weight units of water about 0 01 weight units of liquid sodium silicate about 0 005 weight units of plasticizer
Once the water, the liquid sodium silicate and the plasticizer have been mixed together for about 30 seconds, about one weight unit of Portland Type 1 or Type II cement and about one weight unit of clean, masonry grade, preferabh salt-free sand is added to the mixture of water, liquid sodium silicate and plasticizer while it is still being mixed The cement, sand and the mixture of water, liquid sodium silicate and plasticizer is then mixed for about seven minutes Once the cement, the sand and the mixture ot watei liquid sodium silicate and plasticizer have been mixed together for about seven minutes, a hydrophobic fiber is added This hvdrophobic fiber is then stirred into the mixture for about one minute
As previously indicated, the hydrophobic fiber may be about 0 10 weight unit of a fiberglass fiber, about 0 03 weight units of a nylon fiber, about 0 01 weight units of a polypropylene fiber or about 0 20 weight units of a steel fiber If desired, about 0 10 weight units of a steel fiber may be mixed together with about 0 0075 weight units of a poh propylene fiber in the structural concrete
Once the fiber-remforced structural concrete 10 has been mixed together, it may be formed into a wide vaπety of shapes and products by pouring it into a mold 30 as shown in Figure 2 Preferably the structural concrete 10 is allowed to cure in the mold 30 m an atmosphere of about 90° Fahrenheit having a 50% relative humiditv
The resulting hardened concrete 10 is shown in Figure 3 Note that the fibers 10 are substantialh uniformh distributed and randomh oriented
10
SUBSTTTUTE SHEET (RULE 26) The wide flexibility of the fiber-reinforced structural concrete of the present invention 10 may be illustrated by indicating that the mold 30 may have a textured surface on its bottom 32 Thus, after the fiber-reinforced structural concrete 10 is poured on the textured surface, the molded fiber-remforced structural concrete 10 w ill have a similarh textured outer surface 104 The top side 106 of the poured fiber-reinforced structural concrete 10 may be smoothed with a vibrating screed to assure that the exposed back surface 102 of the poured fiber-remforced structural concrete 10 is smooth
It will be well understood by those of ordinal v skill in the an that numerous additions may be made to the mold 30 to produce a wide vaπetv of different products For example, flanged beams 126 as shown in Figure 7 mav be placed on the exposed surface 10" of a laver ofthe poured fiber-remforced structural concrete 10 and then attached thereto
Figure imgf000013_0001
pouring additional fiber-reinforced structural concrete 128 over the flange 127 of the flanged beam 126 and onto the exposed back surface 103 of the poured fiber-reinforced structural concrete 10 Another example of a product is a wall board 100 as shown in the mold 30 in
Figure 2. Such wall boards 100 may have a foam core 1 10 made of styrofoam or urethane foam If desired, the foam core 1 10 may be entireh encapsulated with a top 106. a bottom 108 and side walls 1 12 The core material may be another type of non- fiber-reinforced concrete or cement In addition to forming wall boards 100. or alternative!} roofing boards 100 as shown in Figure 6. the fiber-remforced structural concrete 10 mav be molded into the shape of a structural beam, such as an I-beam, a box beam or a double bo\ beam If desired, the fiber-reinforced structural concrete mav also be molded into more complex structures, such as a roofing suppoπ truss
SUBSTTTUTE SHEET (RULE 26) It has also been found that the fiber-reinforced structural concrete of the present invention 10 may be formed in relatively thin sections as shown in Figures 10 and 1 1 and that such thm sections may be used as a siding shake or a shingle 200 on the wall W of a building or a roofing shake or shingle 204 over the ratters R of a building. By inseπing various different structures into the mold 30 shown in Figure 2. it is possible to increase the utility of the molded items. For example, an outer window frame or an outer door frame may be placed into the mold so that a wall panel may be formed with an opening and a frame already molded therein. A panel 100D with a door opening D is shown in Figure 13 and a panel 100E with a window poπal P is shown in Figure 14F When such wall panel 100 is erected, it remains for the builder to only inseπ a framed door or a framed window within the opening created in the wall panel 100.
Devices may also be added to the mold which will be exposed when the molded fiber-reinforced structural concrete is removed from the mold. For example, such devices may include a metal plate 42 which is exposed when the poured fiber-reinforced structural concrete 10 is removed from the mold 30 as shown in Figure 4 The exposed metal plate 42 may be used at a later time for welding the poured fiber-reinforced structural concrete wall panels 100 together or attaching the fiber-reinforced structural concrete wail panels 100 to a foundation F as shown in Figure 15.
In another embodiment, a threaded fastener, either a female threaded fastener 48 or
a combination of a male 48 and female threaded fastener 46. may be placed near the edge ofthe poured fiber-reinforced structural concrete wall panel 100 as shown in Figure 4 so that the male fastener 48 extends through any one of the surfaces of the wall panel 100 after it is removed from the mold 30 Optional!) , a threaded male fastener 48 may extend
SUBSTTTUTE SHEET (RULE 26) downwardly from female threaded fastener 46 into the fiber-reinforced structural concrete to provide for greater lifting capacity such as shown in Figure 5
To fuπher increase the utilization of the formed fiber-reinforced structural concrete panels, a tunnel or passage 140 may be formed in a wall panel 100 as shown in Figure 15 for a later utilization as a passageway for utilities such as plumbing, electπcal wires or ventilation
In situations where the poured fiber-reinforced structural concrete 10 is to be used in high load situations, or where large panels are required it is possible to add one or more steel reinforcing bars 120 to the poured fiber- reinforced concrete 10 before it cures as shown in Figures 9. 19. 19A. 19B and 20
It has also been found that because ofthe nature of the mixture of ingredients in the poured fiber-reinforced structural concrete of the present invention, the outer surface of the poured structural fiber-reinforced concrete may be polished
If it is desired to use slabs of molded fiber-reinforced structural concrete 10 on a roof, it is found that the slabs 300 of poured fiber-reinforced structural concrete 10. once cured, may be coated with a ceramic layer 302 as shown in Figure 12
In the preferred embodiment, it has been found that the following detailed steps mav be used to mold a sandwich panel 100. 100B. 100C as shown in Figures 5. 6. 8. 8A. 9 and 9A having an outer surface of structural concrete 10 and an inner foam core 1 10 Step ! The mold is coated lightly with oil or a smooth material
Step 2 Randomlv placed pourings of the fiber-reinforced structural concrete mixture to are placed on the bottom 32 of the mold 30 and spread out bv hand or bv a
SUBSTTTUTE SHEET (RULE 26) mechanical method so that all areas of the mold bottom 32 are covered This step is continued until the desired thickness of fiber-iemtorced concrete 10 is obtained
Step 3 A v ibrating screed 40 is calibrated to the required thickness of the fiber-reinforced structural concrete 10 Step 4 The vibrating screed 40 is placed on the open top 38 of the mold 40 at one
end 34
Step 5 The vibrating screed 40 is then slow h moved from one end 34 of the mold 30 to the other end 34 of the mold 30 across the open top 38 of the mold 30 and anv excess fiber-reinforced concrete 10 is removed or added as required Step 6 The vibrating screed 40 is then returned to the opposite end of the mold 34 to achieve a uniform thickness of fiber-remforced concrete 10
Step 7 A pre-cut foam core 1 10 is laid ov er the smoothed fiber- reinforced concrete 10. taking care not to press the core material 1 10 into the bottom layer 108 of the just poured and smoothed fiber-reinforced concrete 10 Step 8 Fiber-reinforced concrete mix 10 is also poured into any surfaces ties 1 14 as shown in Figure 8 and formed in the rigid foam core 1 10 Optionalh concrete ribs 1 18 as shown in Figure 8. may be used in large panels
Step 9 Randomlv placed patties of fiber-reinforced concrete 10 are then poured over the top of the foam core 1 10 and spread by hand so that all areas are covered Step 10 The vibrating screed 40 is again calibrated to the necessary thickness
Step 1 1 The vibrating screed 40 is placed at one end 34 of the mold 30
14 SUBSTTTUTE SHEET (RULE 26) Step 12 The vibrating screed 40 is moved from one end 34 of the mold 30 to the
other end 34 of the mold 30 and fiber-reinforced concrete 10 is removed or added as
required
Step 13 The vibrating screed 40 is returned to the opposite end 34 of the mold 30
to achieve a uniform thickness of fiber-remforced concrete 10
If desired, the top surface 104 of the fiber-reinforced concrete may be either textured
or troweled to a smooth finish It is recommended that the curing fiber-reinforced
concrete 10 not be exposed to direct sunlight To achieve maximum strength, the mold 30 should be covered with a moisture resistant material ( not shown) to retain moisture w ithin
the fiber-reinforced concrete 10
To de-mold the fiber-reinforced concrete, the following steps are followed
Step 1 Check the outer surface 104 of the fiber-reinforced concrete 10 after 72 hours If the outer surface 104 of the fiber-reinforced concrete 10 has hardened after 72
hours, proceed with the following steps'
Step 2 Carefully remove the mold edges Great care should be exercised as if the
fiber-reinforced concrete is still green or soft, it may break if excess force is used In some situations, the layer of fiber-remforced concrete 10 at the bottom of the mold 30 may be paπicularly soft.
Step 3 The molded fiber-remforced concrete form 100 is then lifted off the mold
bottoms 32 The molded fiber-reinforced concrete forms 100 may be then stacked with a
sheet therebetween or stood on their long edges w ith approximate!} 1 inch separation
between each molded fiber-reinforced concrete form 100 to allow proper hvdration If required, a shade cover (not shown) should be placed over the molded pieces 100 to prevent their exposure to direct sunlight.
Step 4: After the pieces 100 have cured for a full seven days, they may be used in construction.
Testing of building panels having a foam core as previously described have resulted
in compression strengths of greater than 5,800 PSI and moisture resistance of about 45 PSI.
Additionally, such structural panels will have an impact resistance of 55 x 10 inch lbs. per square inch.
Products
The strength and flexibility of the fiber-reinforced structural concrete of the present invention 10 lends itself to the manufacturer of a wide variety of products as shown, for example, in Figures 5, 6, 10, 1 1 which may be used to erect buildings or residences as shown in Figures 15 and 21.
The most basic of these products is a structural wall or roof panel 100 as shown in Figures 5 and 6 which includes an outer layer formed of the fiber-reinforced structural concrete 10 ofthe present invention. Such outer layer may include a back surface 102, front
surface 104, a top 106, a bottom 108, and one or more side walls 1 12. Within the outer
layer ofthe fiber-reinforced structural concrete is an inner foam core 1 10. It has been found
that such inner foam cores 1 10 may be formed using a styrofoam core or a urethane foam core. Those of ordinary skill in the art will understand that additional types of foam or cores 1 10 may be used without departing from the scope ofthe present invention. As shown in Figure 3, the fiber-reinforced structural concrete of the present invention 10 is
16 SUBSTTTUTE SHEET (RULE 26), characterized by having a plurality of fibers 10F dispersed substantially uniformly and at
random angles. There is no bonding between the concrete and the fibers.
To facilitate the construction of a building or residence using the wall panel 100 previously described, it has been found that it is possible to mold in a metallic piece 42 on
one ofthe surfaces as shown in Figure 4, preferably at a corner, of the structural panel 100.
When this metallic piece 42 comes in contact with a metallic piece 42 on another wall
panel 100 or on the foundation F, the metallic pieces 42 may be welded together, thus facilitating the construction of a welded together building or residence.
If welding is difficult, it is also possible to erect a building or a residence using threaded fasteners which are molded into the building panel 100 as shown in Figure 4.
Specifically, the female end of a threaded fastener 46 is molded into the building panel 100 and the male end of a threaded fastener 48 extends therefrom. When it is desired to mount
the building panels 100 to a foundation F or connect the building panels 100 one to another, the threaded fasteners may be used to connect and align the building panels 100 as shown
in Figure 16. The basic construction of a wall panel 100 with connectors molded therein is
shown in Figure 4 where a metal plate 42 is connected to a female threaded fastener 46 by
a connector rod 44. Those of ordinary skill in the art will understand that the plate 42 or
threaded connectors 46, 48 may be used alone. Alternatively, the threaded connectors 46, 48 may be used to lift the panels 100 into place as shown in Figure 5. Therein a plate 50
having a lifting plate 52 is attached to the end of the panel 100 so that a hook 54 may be used. If desired, plate 50 and lifting plate 52 may be eliminated by placing eye bolts into
the female threaded connectors 46. Alternatively, the panel 100 may be lifted with a fork lift truck.
17
SUBSTTTUTE SHEET (RULE 26) As shown in Figure 5. the wall panel 100 ofthe present invention 100. once having
been lifted into place, is placed on a foundation F. If the wall panels 100 are properly
molded so that the mounting surfaces arc true, one with respect to another, there will be a close fit between the wall panels 100 when they are placed on a foundation F. To assure a
solid wall, filler material 124 may be placed in the space between two adjacent wall panels
100.
If desired, structural steel or wooden studs may be placed inside the wall panel 100 to serve as a mounting surface for interior wall board.
In Figure 6, the panel 100 ofthe present invention is used as a roof panel instead of as a wall panel. Therein, it may be seen that the panel 100 rests on and is attached by conventional methods to rafters R.
In Figure 7, a different type of wall panel 100Λ is shown. Specifically, the wall
panel 100A docs not include a foam core. Rather, it consists only of a bottom 108 which is poured on the bottom 32 of the mold 30 shown in Figure 2. Placed on the back surface 103 of the bottom 108 are a plurality of wall studs or beams 126. Such beams may be
formed of wood, steel or fiber-reinforced concrete 10. Once the beams 126 have been
placed on the back surface 103 ofthe bottom 108, additional deposits of cement 128 may
be poured onto the back surface 103 ofthe back skin 102 such that they overlap a flange or a surface 127 on the beam 126 which allows the beam 126 to be affixed to the skin 102
when the fiber-reinforced concrete dries. The beams 126 may then be used for the
attachment of commonly available interior wall board on the inside ofthe panel 100A. As
the fiber-reinforced concrete 10 does not adhere to the flanged portion 127 of the beams
126. there is no danger of the panel 100A cracking in response to temperature changes.
18
SUBSTTTUTE SHEET (RULE 26) In Figure 8, a first alternate embodiment of a wall panel 100B is shown. Note that
it has open sides but a solid foot 1 16. Also shown are surface ties 1 14 through the foam core 1 10 which may be used to connect the bottom 108 to the top 106. If the wall panel 100B is of a large size, it may be desired to add an optional rib 1 18 formed of the
fiber-reinforced concrete ofthe present invention. Such panels 100B are particularly useful
with the pour-in-place method of construction as described in Figures 19, 19A and 19B.
A first alternate embodiment of a roof panel 100C is shown in Figures 9 and 9A.
Note that the bottom 108 is smaller than the top 106 and that reinforcing bars 1 14 pass
through the foam core 1 10 at the surface ties 1 14. If desired, a solid panel end 122 may be formed at the lower end of the panel 100C. The installation of such panels 100C to form
a poured-in-place roof is illustrated in Figure 20.
The flexibility ofthe staictural concrete 10 of the present invention also allows for
the molding into a building panel 100 a wooden or metal frame. The wooden or metal frame may later be used as a support or an outer frame of a window or a door assembly. If desired, tunnels or passageways 140 (Figure 15) may be formed in the building panels 100. Such
tunnels or passageways 140 are extremely helpful for tieing together utility services, such
as plumbing, electricity or ventilation.
As previously indicated, the building panels may have any width x and height y and may have any type of outer surface desired as shown in Figures 14A through F. In
Figure 14A of simulated stucco and wood surface 132 is shown. Figure 14B illustrates a
simulated plane stucco surface 134. A simulated wood surface 136 appears in Figure 14C. Figure 14D shows a simulated limestone shingle surface 138. A simulated brick surface 130 appears in Figures 14E and 14F. The desired outer surface is placed in the bottom 32 ofthe mold 30 and once the fiber-reinforced structural concrete of the present invention is poured thereon, the outer surface of the building panel will pick up the features found on the
bottom 32 of the mold 30. If desired a colorizer may be added to the fiber-reinforced structural concrete 10 to accent its surface appearance.
In larger panels, it may be necessary to assure that the structural concrete top 106 and bottom 108 of the building panel 100 are properly supported. This is accomplished by
assuring that surface ties 1 14 are formed through the foam core 1 10 and that structural fiber-reinforced concrete 10 connects the top 106 and the bottom 108 of the building panel,
one to another, by forming a passageway 1 14 which is filled with fiber-reinforced concrete through the foam core 1 10. In extremely large panels, it may be necessary to include
reinforcing bar 120 in the structural panel or possibly form concrete ribs 1 18 between sections of the foam core 1 10.
Further, it has been shown that if the fiber-reinforced structural concrete 10 of the
present invention is extruded, it may be formed into concrete shingles or shakes. Such
shingles or shakes may be used as siding 200 on a wall W as shown in Figure 10 or as roofing 204 as shown in Figure 1 1. The concrete shingles or shakes may have any desired
color by adding a colorizer to the mixture of the structural concrete of the present
invention 10 and any desired surface may be placed in the outer surface of the concrete shingles or shakes 200, 204. Typically, such concrete shingles or shakes 200, 204 are made
not by molding the fiber-reinforced concrete 10 of the present invention, but rather by extruding it. To facilitate the attachment of such concrete shingles or shakes 200, 204 to a residence or building, the fiber-reinforced concrete shingles or shakes 200, 204 are typically provided with one or more holes 202 formed therein through which a fastener 206 may be
20
SUBSTTTUTE SHEET (RULE 26) passed. Alternately, thin fiber-reinforced concrete panels may be molded or extruded which are larger than a single shake but may be used to give a wall a decorative appearance such
as a brick veneer 130.
The fiber-reinforced structural concrete ofthe present invention 10 may also be used without a foam core 1 10 for roofing panels as shown in Figures 12, 12A and 12B.
Specifically, if a slab of fiber-reinforced structural concrete according to the present
invention is molded into a convenient size as shown by the dimensions x and y in
Figure 12A, it may later be coated with a ceramic 302. One example of a ceramic elastomeric coating is marketed under the trademark "Uniflex" by Kool Seal Inc. As roof panels do not need the amount of structural strength that is required of load-
bearing wall panels, it is possible to form roof panels by a combination of a cement backing
with an outer skin of the fiber-reinforced structural concrete of the present invention. Attachment of roof panels 300 may be over sheeting S placed over rafters R as shown in Figure 12 and 12B. If desired, the roof panels 300 may then have a covering C as shown
in Figure 12 or left exposed.
It has also been found that the fiber-reinforced structural concrete of the present
invention 10 may be used to mold structural members. Such structural members may
include box beams, double box beams, I-beams, channel beams or combinations thereof. In applications where wood or steel beams may not be available, roof trusses may be molded using the structural concrete ofthe present invention.
Construction Methods
21
SUBSTTTUTE SHEET (RULE 26) Residences or buildings utilizing wall panels or structural members 100 employing
the fiber- reinforced concrete of the present invention 10 may be put together in several ways.
The first method of construction is to weld the wall panels 100 in place as shown in
Figure 15A. Such mcthoc' of construction involves embedding metal plates 56 in a poured
concrete foundation F as shown in Figure 15. Compatible weld plates 42 are set into the surface ofthe molded wall panel 100. When the molded wall panels are put in place on a poured concrete foundation F. the metal plates 42 in the wall panels 100 are positioned to
abut the metal plates 56 in the poured concrete foundation F. Such plates 56 may be positioned by times 64 which extend downwardly from the plate 56 into the foundation F
as shown in Figures 16A and 16B. With the metal plates abutting, it is then possible weld the metal plates together. Alternatively an angle iron 58 may be used to tie the metal
surfaces together. Similarly, at the top ofthe molded wall panels, it is also possible to use metal plates 42 at the corners as shown in Figure 15. When wall panels 100 are in position,
the metal plates 42 are put together so as to abut one another or be connected by a small
metal tie plate. Once again, the metal plates 42 are welded together and the wall panels are held securely in place, one with respect to another. Utility services, generally K, may be molded into the wall panels 100 to facilitate construction.
An alternate method of construction involves utilizing threaded fasteners as shown
in Figure 16. Typically, a female threaded fastener 46 is molded into the wall panel 100 so
that its opening is coplanar with a surface of the wall panel 100. When the surface of the wall panel 100 is placed against a plate or an angle iron 58 which is positioned in the foundation, it is possible to pass a male threaded fastener 48 through a hole 60 in the plate 58 and into the female threaded fastener 46 located in the wall panel 100. A corner plate 62 is shown in Figure 16B. It will be well understand by those of ordinary skill in the
art that is possible to juxtapose the position of the male and female threaded fasteners
without departing from the scope ofthe present invention. Additional threaded fasteners may be used at other locations on the molded wall panel to tie the wall panels 100 one to
another. If a female threaded fastener 46 is placed coplanar with the bottom edge of the molded wall panel 100 and a male fastener 48 is inserted therein, it is possible to adjust the
position of the male fastener with respect to the female threaded fastener 46 to adjust or align the bottom ofthe wall panel so that it fits properly with respect to the adjacent wall panel 100 and to the foundation F.
Alignment ofthe top ofthe wall panels 100 is facilitated by utilization of a straight
alignment tool 66 as shown in Figures 17 and 17A or a 90° corner alignment tool 76 as
shown in Figures 18 and 18A.
The straight alignment tool 66 includes a flat bar 68. Attached to the flat bar 68 are
a plurality of C-clamps 70. Once the flat bar 68 is placed on the outside ofthe wall panel
100, the knobs 74 are turned such that the foot 72 on a C-clamp 70 contacts the opposite
surface ofthe wall panel 100. Once the tops of adjacent wall panels 100 have been properly aligned, the bottoms ofthe adjacent wall panels 100 may be welded in place, bolted in place or poured-in-place as previously discussed. A similar operation exists at the corner of a structure. Specifically as shown in
Figure 18 a 90° corner bai" 78 is placed on the outside surface of adjacent wall panels 100. C-clamps 70 are placed such that the foot 72 ofthe C-clamps 70 contacts the inner wall of
the wall panel 100 when knobs 74 are turned. Similarly, once the tops of adjacent panels
SUBSTTTUTE SHEET (RULE 26) 100 have been aligned, the bottoms of the adjacent panels 100 may be affixed in place by
welding, bolting or pouring-in-place as previously discussed.
Still another method of erecting a building or a residence using wall panels formulated from the fiber-reinforced concrete of the present invention involves placing the molded wall panels 100B (Figures 8 and 8A) on a foundation F with a space therebetween
as shown in Figures 19, 19A, and 19B. In this method of construction, each molded panel 100B has metal reinforcing bars 120 extending from its edges so that when the panels
are placed on a foundation F a void 90 exists therebetween. The metal reinforcing bar 120 extends into the void 90 between the panels 100B. With the panels 100B held in position, it is possible to fill up the void 90 between the panels with concrete so that the metal reinforcing bars 120 extending outwardly from the panels 100B are in the void 90 which is
filled with concrete. If desired, a substantially vertical metal reinforcing bar 84 may be placed in the void 90 between the adjacent panels 100B. This metal reinforcing bar 84 may be tied to a wall anchor 80 extending upwardly out of the foundation F by using a wire
tie 82.
It is recommended that in this method of erecting a house by pouring concrete
between the adjacent wall panels 100, the construction begin at one corner of the building. The panels 100 are formed so that a corner column void 90 is formed as shown in Figure 19B. It is also recommended that a horizontal metal reinforcing bar 88 in the
lintels 86 poured on top of the wall panels 100 be attached to the substantially vertical reinforcing bar 84. Additional wall panels 100 are then put in place along the foundation F
so that they are level and secure.
24
SUBSTTTUTE SHEET (RULE 26) A poured-in-place roof is shown in Figure 20. An opening or void 90 between the panels 100C is shown on the right side of the figure. On the left side of the figure the void 90 has been filled with a poured beam 94 strengthened by two reinforcing rods 92.
A typical floor plan for a low cost dwelling 450 is shown in Figure 21 . Therein it
may be seen that an entrance or porch area 400 is formed at the front of the dwelling 450.
This area opens into a living area 402. Behind the living area 402 is a dining area 404 which opens into a kitchen 406. Adjacent to the kitchen 406 is a bath 408 which is adjacent to a bedroom 410. This entire structure 450 may be erected pursuant to the method illustrated
in Figure 15. It has also been found that a modular house 500 such as shown in Figure 22 may also be constructed in a factory using the fiber-reinforced concrete of the present invention 10
and erected on site. Such a modular house 500 may include a left side module 502 as shown
in Figure 22A, a center module 504 as shown in Figure 22B and a right side module 504 as shown in Figure 22C. To facilitate the construction a utilities pod 508 may be placed on one
of the modules.
There has now been disclosed by the foregoing specification a low cost, durable, environmentally friendly, fiber-reinforced concrete formulation which may be utilized to formulate a variety of different products to erect residences or buildings. While the
invention has been disclosed by reference to its preferred and alternate embodiments, those
of ordinary skill will understand that numerous other embodiments are possible by reference to the foregoing disclosure. Such other embodiments shall be included within the scope and meaning of the appended claims.
FΛA I 1229\CON046\58000\FIB-PA I APP

Claims

I claim:
1 . A structural concrete comprising:
a dry component, said dry component including about one weight unit of cement and about one weight unit of sand; a wet component, said wet component including: about 0.33 weight units of water. about 0.01 weight units of liquid sodium silicate, and about 0.005 weight units of plasticizer; a fiber component, said fiber component including one or more hydrophobic materials.
2. The structural concrete as defined in Claim 1 wherein said fiber component is fiberglass.
3. The structural concrete as defined in Claim 2 including about 0.10 weight units of
fiberglass.
4. The structural concrete as defined in Claim 1 wherein said fiber component is nylon.
5. The structural concrete as defined in Claim 4 including about 0.03 weight units of nylon.
6. The structural concrete as defined in Claim I wherein said fiber component is polypropylene.
7. The structural concrete as defined in Claim 6 including about 0.01 weight units of
polypropylene.
8. The structural concrete as defined in Claim 1 wherein said fiber component is steel.
9. The structural concrete as defined in Claim 8 including about 0.20 weight units of steel.
26
SUBSTTTUTE SHEET (RULE 26)
10. The structural concrete as defined in Claim 1 wherein said fiber component includes steel and polypropylene.
1 1. The structural concrete as defined in Claim 10 including about 0.10 weight units of steel and about 0.0075 weight units of polypropylene.
12. The structural concrete as defined in Claim 1 wherein the range of water is from about 0.28 weight units to about 0.40 weight units.
13. The structural concrete as defined in Claim 1 wherein said cement is Type 1 or Type II Portland cement.
14. The structural concrete as defined in Claim 1 wherein said sand is fine, masonry sand.
15. The stmctural concrete as defined in Claim 1 w herein the ratio, by weight, of sand to cement is from about 3: 1 to about 1 :3.
16. The structural concrete as defmed in Claim 1 wherein said fibers are oriented in random directions and distributed substantially uniformly within said structural concrete once said structural concrete has cured.
17. The structural concrete as defined in Claim 1 having a compression strength of at least 8000 psi after curing for about 89 days.
18. A structural concrete comprising: about 94 pounds of Portland Type I or Portland Type II cement; about 94 pounds of salt- free, clean, masonry sand:
about 31 pounds of clean, salt-free, water: about 1 pound of liquid sodium silicate. about 0.5 pounds of plasticizer; about 1 pound of polypropylene fiber.
19. The structural concrete as defined in Claim 18 where about 13 pounds of steel fiber may be used in place of said about 1 pound of polypropylene fiber.
27
SUBSTTTUTE SHEET (RULE 26)
20. The structural concrete as defined in Claim 18 wherein about 10 pounds of steel fiber and about 0.75 pounds of polypropylene fiber may be used in place of said about 1 pound of polypropylene liber.
21. A method of making structural concrete comprising the steps of:
(a) mixing about 0.33 weight units of water with about 0.01 weight units of liquid sodium silicate and about 0.005 weight units of plasticizer together for about 30 seconds;
(b) adding about one weight unit of cement and about one weight unit of sand to said mixture of water, liquid sodium silicate, and plasticizer while said water, liquid sodium silicate, plasticizer are being mixed;
(c) mixing said cement, said sand, and said mixture of water, liquid sodium silicate, and plasticizer together for about 7 minutes;
(d) adding hydrophobic fiber to said mixture of cement, sand, water, liquid sodium silicate, and plasticizer while said mixture of cement sand, water, liquid sodium silicate, and plasticizer is still being mixed;
(e) mixing said hydrophobic fiber into said mixture of cement, sand, water, liquid sodium silicate, and plasticizer for about 1 minute.
22. The method as defined in Claim 21 wherein said hydrophobic fiber includes about 0.10 weight units of fiberglass fiber.
23. The method as defined in Claim 21 wherein said hydrophobic fiber includes about 0.03 weight units of nylon.
24. The method as defined in Claim 21 wherein said hydrophobic fiber includes about 0.01 weight units of polypropylene.
25. The method as defined in Claim 21 wherein said hydrophobic fiber includes about 0.20 weight units of steel.
26. The method as defined in Claim 21 wherein said hydrophobic fiber includes about 0.10 weight units of steel and about 0.0075 weight units of polypropylene.
27. The method as defined in Claim 21 further including the step of pouring the structural
concrete mixture into a mold having an open side.
28. The method as defined in Claim 27 further including the step of allowing said poured structural concrete to cure at a temperature of about 90° F in an atmosphere having about 50% relative humidity.
29. The method as defined in Claim 27 wherein the bottom surface of said mold has a textured surface.
30. The method as defined in Claim 27 further including the step of smoothing the exposed surface of said poured mixture of stmctural concrete on the open side of said
mold with a vibrating screed.
31 . The method as defined in Claim 21 further including the step of adding a colorizer fluid to the mixture of structural concrete.
32. The method as defined in Claim 27 further including the step of placing the flange portion of one or more flanged beams on the exposed surface of said poured stmctural concrete and securing said flanged beams to said exposed surface of poured stmctural concrete by pouring additional stmctural concrete over said flange portion of said flanged beam and the said exposed surface of said poured stmctural concrete.
33. The method as defined in Claim 27 further including the step of placing a core material on the exposed surface of said poured structural concrete and then pouring additional structural concrete over said core material.
34. The method as defined in Claim 33 wherein said core material is styrofoam.
35. The method as defined in Claim 33 wherein said core material is urethane foam.
29
SUBSTTTUTE SHEET (RULE 26)
36. The method as defmed in Claim 33 wherein said core material is another type of concrete or cement.
37. The method as defined in Claim 27 wherein said mold enables said structural concrete to be formed in the shape of a structural beam.
38. The method as defined in Claim 27 wherein said mold enables said structural concrete to be formed in the shape of a roofing support truss.
39. The method as defined in Claim 21 wherein said structural concrete is extruded into the shape of a shake or a shingle.
40. The method as defined in Claim 27 further in including the step of placing a window frame or a door frame in said mold so that said window frame or said door frame is attached to said poured stmctural concrete.
41. The method as defined in Claim 27 fuπher including the step of placing a metal plate within said mold such that said metal plate will be exposed when said poured structural concrete is removed from said mold.
42. The method as defined in Claim 27 fuπher including the step of placing a threaded fastener within said mold so that said threaded fastener is exposed when said poured structural concrete is removed from said mold.
43. The method as defined in Claim 27 further including the step of forming a tunnel or passageway within said poured structural concrete.
44. The method as defined in Claim 27 further including the step of placing at least one metal reinforcing bar within said poured structural concrete.
45. The method as defined in Claim 27 further including the step of removing said poured structural concrete from said mold after it has cured and polishing the surface of said poured structural concrete.
30 SUBSTTTUTE SHEET (RULE 26)
46. The method as defined in Claim 27 further including the step of removing said poured structural concrete from said mold and coating it with a ceramic layer.
47. A structural wall or roof panel comprising: an outer layer of structural concrete: said outer layer of structural concrete including: about one weight unit of Portland Type I or Type II cement; about one weight unit of clean masonry sand: about 0.33 weight units of clean water; about 0.01 weight units of liquid sodium silicate; about 0.005 weight units of plasticizer: hydrophobic fiber;
an inner foam core.
48. The stmctural wall or roof panel as defined in Claim 47 wherein said inner foam core is styrofoam.
49. The stmctural wall or roof panel as defined in Claim 47 wherein said inner foam core is urethane.
50. The stmctural wall or roof panel as defined in Claim 47 further including at least one metallic weld plate on its outer surface.
51. The stmctural wall or roof panel as defined in Claim 47 further including at least one threaded fastener extending from its outer surface.
52. The structural wall or roof panel as defined in Claim 47 fuπher including a frame formed therein into which a window assembly or a door assembly may be inserted and attached.
53. The stmctural wall or roof panel as defined in Claim 47 further including a tunnel or a passageway formed therein.
3 1
SUBSTTTUTE SHEET (RULE 26)
54. The structural wall or roof panel as defined in C laim 47 further including a textured outer surface.
55. The structural wall or roof panel as defined in Claim 47 wherein said outer layer of structural concrete encapsulates said foam core.
56. The structural wall or roof panel as defined in Claim 55 wherein surface tics pass through said foam core.
57. The stmctural wall or roof panel as defined in Claim 47 further including structural concrete ribs passing through said foam core.
58. The stmctural wall or roof panel as defined in Claim 56 further including at least one
metal reinforcing bar passing through said foam core and said surface ties.
59. The stmctural wall or roof panel as defined in Claim 47 further having a compression strength of greater than 5800 psi.
60. The stmctural wall or roof panel as defined Claim 47 having a moisture resistance of about 45 psi.
61. The stmctural wall or roof panel as defined in Claim 47 having an impact resistance
of about 55 x 106 in-lbs/square inch.
62. A roof panel comprising: a molded slab of structural concrete; said molded slab of structural concrete including: about one weight unit of Portland Type I or II cement: about one weight unit of clean, masonry Type sand; about 0.33 weight units of clean water: about 0.01 units of liquid sodium silicate; about 0.05 units of plasticizer: hydrophobic fiber:
32
SUBSTTTUTE SHEET (RULE 26) a ceramic coating.
63. The roof panel as defined in Claim 62 further including as least one metallic weld plate at fastening points.
64. The roof panel as defined in Claim 62 wlierein said molded slab of structural concrete has a cement backing.
65. A roofing shake or shingle comprising:
a slab of extruded structural concrete, said slab of extruded stmctural concrete including: about one weight unit of Portland Type I or Type II cement; about one weight unit of clean, masonry sand; about 0.33 weight units of clean water; about 0.01 weight units of liquid sodium silicate; about 0.005 weight units of plasticizer;
hydrophobic fiber; at least one hole formed through said slab of molded structural concrete.
66. The roofing shake or shingle as defined in Claim 65 further including a colorizer.
67. The roofing shake or shingle as defined in Claim 66 wherein the outer surface of the
slab of molded structural concrete is textured.
68. A wall or siding panel comprising: a molded or extruded structural concrete slab, said molded or extruded structural concrete slab including:
about one weight unit of Portland Type I or Type II cement: about one weight unit of clean masonry sand; about 0.33 weight units of clean water; about 0.01 weight units of liquid sodium silicate: about 0.005 weight units of plasticizer:
hydrophobic fiber:
at least one hole formed through said molded or extruded structural concrete slab.
69. The wall or siding panel as defined in Claim 68 wherein said wall or siding panel has
a textured outer surface.
70. The wall or siding panel as defined in Claim 68 wherein said wall or siding panel has
at least one layer of molded or extruded structural concrete and at least one layer of cement.
71 . A building panel comprising:
a structural concrete skin, said structural concrete skin including:
about one weight unit of Portland Type I or Type II cement: about one weight unit of clean masonry sand;
about 0.33 weight units of clean water;
about 0.01 weight units of liquid sodium silicate:
about 0.005 weight units of plasticizer;
hydrophobic fiber;
at least one flanged structural member:
said at least one flanged stmctural member being attached to said structural concrete
skin with structural concrete.
72. The building panel as defined in Claim 71 wherein the outer surface of said structural
concrete skin has a textured surface.
73. The building panel as defined in Claim 71 wherein said at least one Hanged structural
member is a channel.
34
SUBSTTTUTE SHEET (RULE 26)
74. A structural load bearing member for use in supporting a building, said structural load bearing member comprising:
a molded concrete form, said molded concrete form including: at least one weight unit of Portland Type I or Type II cement: at least one weight unit of clean, masonry sand; at least 0.33 weight units of clean water;
at least 0.01 weight units of liquid sodium silicate; at least 0.005 weight units of plasticizer; hydrophobic fiber.
75. A method of erecting a residence or a building comprising the steps of: pouring a concrete foundation: embedding within said poured concrete foundation at least one exposed metal weld plate in close proximity to the location of the walls ofthe building or residence;
placing molded wall panels on said poured concrete foundation, said molded wall panels including: about one weight unit of Portland Type I or Type II cement; about one weight unit of clean masonry sand: about 0.33 weight units of clean water; about 0.01 weight units of liquid sodium silicate; about 0.005 weight units of plasticizer; hydrophobic fiber: at least one exposed metal plate: welding said at least one exposed metal plate in said molded wall panel to said at least one exposed metal plate in said poured concrete foundation after said molded wall panel has been placed in the desired location in said poured concrete foundation.
76. A building or residence constructed according to the method of Claim 75.
77. A method of erecting a building or a residence comprising the steps of: pouring a concrete foundation; embedding a plate within said concrete foundation, said plate having at least one hole formed therein, said plate being in close proximity to the location of the walls of the building or residence; placing molded wall panels on said concrete foundation, said molded wall panels including: about one weight unit of Portland Type I or Type II cement; about one weight unit of clean, masonry sand; about 0.33 weight units of clean water; about 0.01 weight units of liquid sodium silicate; about 0.005 weight units of plasticizer; hydrophobic fiber; at least one first threaded fastener: securing said molded wall panel to said poured foundation by passing at least one second compatible threaded fastener through said hole in said plate and
threadably engaging said first and said second threaded fasteners.
78. A building or residence erected according to the method described in Claim 77.
79. A method of erecting a building or residence comprising the steps of: pouring a concrete foundation;
36
SUBSTTTUTE SHEET (RULE 26) embedding within said concrete foundation a metal bar. said metal bar protruding out of said concrete foundation in close proximity to the location ofthe
walls in the building or residence: placing at least a first and second molded wall panel on said concrete foundation with a space therebetween, said at least first and second molded wall
panel including: about one weight unit of Portland Type I or Type II cement; about one weight unit of clean masonry sand; about 0.33 weight units of clean water;
about 0.01 weight units of liquid sodium silicate; about 0.005 weight units of plasticizer; hydrophobic fiber; metal bars constructed and arranged to extend outwardly from said at least
first and second molded wall panels into the space therebetween; filling said space between said first and second molded wall panels with concrete.
80. The method as defined in Claim 79 wherein a substantially vertical metal bar is placed in the space between said first and second molded wall panels and said concrete is poured around said substantially vertical metal bar.
81. A building or residence erected according to the method defined in Claim 79.
82. A building or residence comprising: a foundation; at least one wall emanating upwardly from said foundation, said at least one wall including molded wall panels: said molded wall panels including: about one weight unit of Portland Type I or Type II cement:
about one weight unit of clean masonry sand;
about 0.33 weight units of water:
about 0.01 weight units of liquid sodium silicate: about 0.005 weight units of plasticizer:
hydrophobic fiber;
a roof support structure;
a roof. A building or a residence comprising:
a first module, said first module being formed from one or more concrete
panels;
at least one second module, said at least one second module being compatible
with said first module and being formed from one or more concrete panels:
said one or more concrete panels including:
about one weight unit of Portland Type I or Type II cement:
about one weight unit of clean masonry sand;
about 0.33 weight units of clean water;
about 0.01 weight units of liquid sodium silicate:
about 0.005 weight units of plasticizer:
hydrophobic fiber.
38
SUBSTTTUTE SHEET (RULE 26)
PCT/US1997/006363 1996-04-18 1997-04-17 Fiber-reinforced concrete building material WO1997039203A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU28031/97A AU2803197A (en) 1996-04-18 1997-04-17 Fiber-reinforced concrete building material
MXPA/A/1997/009803A MXPA97009803A (en) 1996-04-18 1997-12-08 Construction material of reinforced concrete with fi

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1559896P 1996-04-18 1996-04-18
US60/015,598 1996-04-18

Publications (2)

Publication Number Publication Date
WO1997039203A2 true WO1997039203A2 (en) 1997-10-23
WO1997039203A3 WO1997039203A3 (en) 1997-11-27

Family

ID=21772366

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AU (1) AU2803197A (en)
TR (1) TR199802083T2 (en)
WO (1) WO1997039203A2 (en)
ZA (1) ZA973308B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008140821A2 (en) * 2007-05-11 2008-11-20 Carbon Sciences, Inc. Fine particle carbon dioxide transformation and sequestration
EP2218563A3 (en) * 2009-02-16 2011-06-29 Nikolaos Kefalogiannis Prefabricated stamped walls
WO2016064324A1 (en) * 2014-10-22 2016-04-28 Smart Development Sweden Ab Concrete mixture and applications of the concrete mixture
CN112265106A (en) * 2020-09-10 2021-01-26 南京永顺机械有限公司 V-shaped pyramid device for automatic pipe piece concrete troweling machine and using method
SE2130040A1 (en) * 2021-02-07 2022-08-08 Rz Solutions Ab Composite laminate

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3765919A (en) * 1970-10-15 1973-10-16 L Gelbman Synthetic light-weight material and process and system for manufacturing same
US3853571A (en) * 1972-10-05 1974-12-10 L Gelbman Fire resistant composition containing gypsum and silicate-based material and processs for making same
US4406703A (en) * 1980-02-04 1983-09-27 Permawood International Corporation Composite materials made from plant fibers bonded with portland cement and method of producing same
US4482385A (en) * 1983-06-30 1984-11-13 Research One Limited Partnership Cementitious composite material with stainless steel particulate filler
US4725632A (en) * 1985-12-12 1988-02-16 Vess-Tech Industries, Inc. Cementitious composition
US4765113A (en) * 1987-03-10 1988-08-23 Jong Slosson B Roofing structure
US5167710A (en) * 1989-06-09 1992-12-01 Saint-Gobain Recherche Process for manufacturing a cement mixture containing reinforcing fibers and products obtained therefrom
US5352288A (en) * 1993-06-07 1994-10-04 Dynastone Lc Low-cost, high early strength, acid-resistant pozzolanic cement
US5378278A (en) * 1993-07-23 1995-01-03 Colburn; Howard E. Cement compositions for temporary structures
US5482549A (en) * 1993-04-05 1996-01-09 Enci Nederland B.V. Cement, method of preparing such cement and method of making products using such cement

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3765919A (en) * 1970-10-15 1973-10-16 L Gelbman Synthetic light-weight material and process and system for manufacturing same
US3853571A (en) * 1972-10-05 1974-12-10 L Gelbman Fire resistant composition containing gypsum and silicate-based material and processs for making same
US4406703A (en) * 1980-02-04 1983-09-27 Permawood International Corporation Composite materials made from plant fibers bonded with portland cement and method of producing same
US4482385A (en) * 1983-06-30 1984-11-13 Research One Limited Partnership Cementitious composite material with stainless steel particulate filler
US4725632A (en) * 1985-12-12 1988-02-16 Vess-Tech Industries, Inc. Cementitious composition
US4765113A (en) * 1987-03-10 1988-08-23 Jong Slosson B Roofing structure
US5167710A (en) * 1989-06-09 1992-12-01 Saint-Gobain Recherche Process for manufacturing a cement mixture containing reinforcing fibers and products obtained therefrom
US5482549A (en) * 1993-04-05 1996-01-09 Enci Nederland B.V. Cement, method of preparing such cement and method of making products using such cement
US5352288A (en) * 1993-06-07 1994-10-04 Dynastone Lc Low-cost, high early strength, acid-resistant pozzolanic cement
US5378278A (en) * 1993-07-23 1995-01-03 Colburn; Howard E. Cement compositions for temporary structures

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008140821A2 (en) * 2007-05-11 2008-11-20 Carbon Sciences, Inc. Fine particle carbon dioxide transformation and sequestration
WO2008140821A3 (en) * 2007-05-11 2009-03-19 Carbon Sciences Inc Fine particle carbon dioxide transformation and sequestration
EP2218563A3 (en) * 2009-02-16 2011-06-29 Nikolaos Kefalogiannis Prefabricated stamped walls
WO2016064324A1 (en) * 2014-10-22 2016-04-28 Smart Development Sweden Ab Concrete mixture and applications of the concrete mixture
CN112265106A (en) * 2020-09-10 2021-01-26 南京永顺机械有限公司 V-shaped pyramid device for automatic pipe piece concrete troweling machine and using method
CN112265106B (en) * 2020-09-10 2022-03-08 南京永顺机械有限公司 V-shaped pyramid device for automatic pipe piece concrete troweling machine and using method
SE2130040A1 (en) * 2021-02-07 2022-08-08 Rz Solutions Ab Composite laminate

Also Published As

Publication number Publication date
AU2803197A (en) 1997-11-07
WO1997039203A3 (en) 1997-11-27
TR199802083T2 (en) 1998-12-21
ZA973308B (en) 1997-11-14
MX9709803A (en) 1998-08-30

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