WO1998003265A1 - Cap-shape reagent container for analysis reagents - Google Patents

Cap-shape reagent container for analysis reagents Download PDF

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Publication number
WO1998003265A1
WO1998003265A1 PCT/JP1997/002472 JP9702472W WO9803265A1 WO 1998003265 A1 WO1998003265 A1 WO 1998003265A1 JP 9702472 W JP9702472 W JP 9702472W WO 9803265 A1 WO9803265 A1 WO 9803265A1
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WO
WIPO (PCT)
Prior art keywords
reagent
container
lid
shaped
analysis
Prior art date
Application number
PCT/JP1997/002472
Other languages
French (fr)
Japanese (ja)
Inventor
Kanji Okauchi
Original Assignee
Kyoritsu Chemical-Check Lab., Corp.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyoritsu Chemical-Check Lab., Corp. filed Critical Kyoritsu Chemical-Check Lab., Corp.
Publication of WO1998003265A1 publication Critical patent/WO1998003265A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/24Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes
    • B65D51/28Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials
    • B65D51/2807Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials the closure presenting means for placing the additional articles or materials in contact with the main contents by acting on a part of the closure without removing the closure, e.g. by pushing down, pulling up, rotating or turning a part of the closure, or upon initial opening of the container
    • B65D51/2814Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials the closure presenting means for placing the additional articles or materials in contact with the main contents by acting on a part of the closure without removing the closure, e.g. by pushing down, pulling up, rotating or turning a part of the closure, or upon initial opening of the container the additional article or materials being released by piercing, cutting or tearing an element enclosing it
    • B65D51/2821Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes with auxiliary containers for additional articles or materials the closure presenting means for placing the additional articles or materials in contact with the main contents by acting on a part of the closure without removing the closure, e.g. by pushing down, pulling up, rotating or turning a part of the closure, or upon initial opening of the container the additional article or materials being released by piercing, cutting or tearing an element enclosing it said element being a blister, a capsule or like sealed container
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01LCHEMICAL OR PHYSICAL LABORATORY APPARATUS FOR GENERAL USE
    • B01L3/00Containers or dishes for laboratory use, e.g. laboratory glassware; Droppers
    • B01L3/50Containers for the purpose of retaining a material to be analysed, e.g. test tubes
    • B01L3/508Containers for the purpose of retaining a material to be analysed, e.g. test tubes rigid containers not provided for above
    • B01L3/5082Test tubes per se
    • B01L3/50825Closing or opening means, corks, bungs

Definitions

  • the present invention relates to a lid-like reagent container for an analysis reagent which can easily perform water quality analysis.
  • the colorimetric analysis method is widely used in the industry because the instrument used is small, lightweight, inexpensive, and the results are visible as colors and the measurement results are fast. .
  • colorimetric analysis requires chemical knowledge, technology, and experience because chemicals are used.
  • Reagents for water analysis include liquid and powdered reagents.
  • the reagents stored in glass or plastic bottles can be collected with the attached spots or built into glass or plastic bottles. There are methods such as dispensing with a spotted drop or dropping with an eye drop bottle.
  • powdered reagents are obtained by dispensing the reagent contained in a glass or plastic container with the attached lightweight spoon, or in some cases, once in a laminating bag, or at both ends.
  • a reagent packed in a soft plastic tube to which is welded is cut into a packaging material and added to the sample.
  • the automatic measurement is performed by automatically inputting the reagents by using a machine or the like.
  • the structure becomes complicated, and the storage method of the reagents is complicated as described above.
  • a first technical problem of the present invention is to provide a lid-like reagent container for an analysis reagent that can perform safe and accurate water quality analysis with a simple operation without chemical knowledge.
  • a second technical problem of the invention of the present application is to simplify the manufacturing process.
  • a solution of the first technical problem of the present invention is that a predetermined amount is set from an opening as described in claim 1.
  • a transparent container main body capable of injecting a test sample, a lid main body mounted from the opening side of the container main body, and a reagent storage container mounted on the lid main body and storing a predetermined reagent.
  • a cutter which is pushed into the inside of the lid main body according to an amount of the lid main body attached to the container main body, pierces the reagent storage container loaded in the lid main body, and discharges the reagent into the inside of the container main body.
  • the reagent when analyzing water samples, the reagent can be mixed with the water sample by attaching the lid body to the container body into which the water sample has been injected. Water quality analysis can be performed safely and accurately with simple operations.
  • the lid body is mounted by tightening the container body from the opening side,
  • One of the features is that the lid body is pushed into the inside of the lid body in accordance with the amount of tightening of the lid body to the container body.
  • the cutter is pushed into the inside of the lid main body according to the amount of tightening of the lid main body with respect to the container main body.
  • the lid main body is mounted by pushing from the opening side of the container main body, One is that the lid body is pushed into the inside of the lid body in accordance with the pushing amount of the lid body into the container body.
  • a plurality of reagent containers accommodating different reagents in the lid main body are provided in the lid main body.
  • the plurality of reagent storage containers are stored along the moving direction, and are sequentially pierced by the cutter according to mounting, tightening, or pushing of the lid body.
  • each reagent is mixed with the sample in turn by attaching, tightening or pushing in the lid to the container body into which the sample was injected.
  • packing is mounted on a lower surface side of the cutout, and the lid main body with respect to the container main body is provided. By mounting, tightening or pushing in, the opening ⁇ of the container body comes into contact with the packing, and the inside of the container body and the lid body is sealed.
  • the packing attached to the lower surface side of the lid comes into contact with the opening edge of the container body by tightening the lid body, so that the container body and the inside of the lid body are sealed. Even when the sample and the reagent are stirred, the sample and the reagent do not leak out.
  • Another solution of the first technical problem of the present invention is as described in claim 6, wherein a protector made of a soft material is interposed between the reagent storage container and the cutter, The reagent container is protected from being inadvertently damaged by a force.
  • a soft material protector held between the reagent storage container and Katsu Yuichi cuts off the contact between the reagent storage container and Katsu Yuichi, so the analysis of the water sample
  • the reagent storage container is not accidentally pierced by a cut, and the storage of the reagent storage container is reliably performed.
  • Another solution of the first technical problem of the present invention is that, as described in claim 7, the cuts between the reagent containers are attached, tightened or pushed in with the lid body. A stirrer for interrupting the movement during the evening is interposed, so that the reagent storage container is moderately pierced by the force.
  • a spacer is interposed between the reagent storage containers, and a cutter is provided.
  • Moderation is provided when the reagent storage container is pierced by the pressure sensor, so if a time lag is required for reagent introduction, the tightness of the moderation can be used to adjust the tightening of the lid body. Becomes
  • the cutlet has a disk-shaped cutter bottom having a plurality of reagent passage holes, and It has a plurality of slits protruding from the center of the bottom of the cutter and communicating with the reagent passage hole on the side surface, and has a crescent-shaped cutter blade at the tip.
  • the reagent in the reagent container pierced by the blade is leaked to the outside of the reagent container along a plurality of slits formed on the side surface of the cylinder portion.
  • the water sample and the reagent inside the container body are mixed via the plurality of reagent passage holes at the bottom of the force hopper.
  • the cutlet is formed by cutting and raising a disc-shaped cutter bottom and a center of the cutter bottom. It is composed of a crown-shaped cutting edge and a reagent passage hole formed at the center thereof.
  • the cutting edge is formed by cutting and raising the center of the bottom of the power cutter, and at the same time, a reagent passage hole is also formed, thereby simplifying the manufacturing process.
  • the cutting edge of the cutting tool has a plurality of cut and raised portions at the bottom of the cutting tool. Consists of a blade.
  • the cutting edge of the cutter is formed by cutting and raising at the center of the bottom of the blade, and at the same time, a reagent passage hole is also formed.
  • a bent flange portion is provided on an outer peripheral portion of the bottom of the cutlet. It is being done.
  • the rigidity of the bottom of the cutter is increased by providing a bent flange at the outer peripheral edge of the cutter bottom, so the thickness of the cutter bottom can be reduced. This makes it possible to reduce costs while simplifying the manufacturing process.
  • FIG. 1 is a sectional view showing one embodiment of a lid-like reagent container for an analysis reagent of the present invention.
  • FIG. 2 is a perspective view showing the protector of FIG.
  • FIG. 3 is a perspective view showing the cutter of FIG.
  • FIG. 4 is a sectional view showing another embodiment in which the configuration of the cutter in FIG. 1 is changed.
  • FIG. 5 is a perspective view showing the cutout of FIG.
  • FIG. 6 is a cross-sectional view showing the cutting tool in FIG. 4.
  • FIG. 7 is a perspective view showing another embodiment in which the configuration of the lid reagent container for the analysis reagent in FIG. 1 is changed.
  • FIG. 1 to FIG. 3 show an embodiment of a lid-like reagent container for an analysis reagent of the present invention.
  • the reagent container is configured such that the female screw part 2 of the lid body 3 is screwed into the thread part 19 of the transparent container body 15 which becomes a colorimetric cell, so that the lid body 3 becomes It is designed to be freely fit to.
  • chemical resistant film containers 4 and 5 containing different types of reagents are stored.
  • the film containers 4 and 5 are housed, they are in a state along the moving direction of the cutter 8A.
  • each of the film containers 4 and 5 only needs to have high barrier resistance (moisture and oxygen) and high chemical resistance, and is composed of a laminated material having a multilayered Z composite structure.
  • polypropylene, PET or the like can be used.
  • a protector 7 made of a soft material such as paper and a hard plastic cutter 8A are provided.
  • the protector 7 is for preventing the film containers 4 and 5 from being inadvertently torn by the cutout 8A. As shown in Fig. 2, the protector 7 is located at the center of the disk-shaped protector 7a. A protector hole 13 is formed, and a bent piece 18 is provided on the outer peripheral edge of the protector body 7a. Then, as described later, when the cutter 8A pushes up the protector main body 7a, the protector main body 7a bends from the fold 18a of the bent piece 18.
  • the cutter 8A has a disk-shaped cutter bottom 8a, as shown in FIG.
  • the cutter bottom 8a is provided with a plurality of reagent passage holes 10 through which the reagents in the film containers 4 and 5 and the water sample in the container body 15 pass through the reagent passage holes 10 respectively. Are mixed while moving.
  • a plurality of protrusions 12 are provided on the lower surface side of the bottom 8a of the cutlet.
  • a donut-shaped packing 11 whose diameter is slightly larger than that of the cutter bottom 8a is provided.
  • a scale 16 is formed on the transparent container body 15, which is a reference position for the amount of water to be taken into the container body 15.
  • the opening edge of the screw portion 19 of the container body 15 serves as the pedestal 17 of the packing 11, and the pedestal 17 is tightened by the lid body 3 so that the pedestal 17 becomes the lower surface of the packing 11.
  • the space between the pedestal 17 and the packing 11 is sealed, so that leakage of liquid to the outside of the container body 15 is prevented.
  • water is injected up to the position of the scale 16 of the container body 15 which becomes a colorimetric cell.
  • the water volume is about 25 m 1.
  • the container main body 15 is put into a cell box of a photoelectric photometer (not shown) that detects the concentration of the test water using light of a predetermined wavelength, and zeroing of the photoelectric photometer is performed.
  • the container body 15 is taken out of the photoelectric photometer, and the lid body 3 is attached to the screw portion 19 of the container body 15.
  • the film containers 4 and 5 of the lid body 3 respectively contain a powder reagent containing ascorbic acid and a 10% diluted sulfuric acid containing ammonium molybdate.
  • the female thread 2 of the lid body 3 is engaged with the thread 19 of the container body 15.
  • the pedestal 17 at the opening ⁇ of the screw part 19 of the container body 15 comes into contact with the lower surface side of the packing 11, and the force 8 A is applied. Push inside.
  • the bent piece 18 of the protector main body 7a bends from the fold 18a with the movement of the power meter 8A.
  • the film container 4 in which the predetermined reagent is stored inside from the opening of the container body 15, the cutter 8A is moved according to the tightening amount, the film containers 4 and 5 are pierced, and the reagents inside the film containers 4 and 5 are removed. Is released into the container body 15. Therefore, when analyzing the test water, the reagent can be mixed with the test water by tightening the lid main body 3 into the container main body 15 into which the test water has been injected. However, water quality analysis can be performed safely and accurately with simple operations.
  • the container body 15 serving as a colorimetric cell can be shared for all water samples, it can be used any number of times after washing, which is very economical.
  • the base 17 comes into contact with the lower surface of the packing 11 to prevent leakage of the liquid to the outside of the container body 15, after the water quality analysis is completed, Even when it is not possible to dispose or wash the container body 15 and the lid body 3, it is possible to take it home with the lid closed and sealed.
  • the container when using such a lid-shaped reagent container for an analytical reagent in an automatic measurement device, the container itself has the same shape, so that the mechanism can be simplified and the container can be stored in the automatic measurement device itself. Since there is no need to provide functions, the size of the device can be reduced.
  • the lid body 3 is loaded with the two film containers 4 and 5 has been described.
  • the present invention is not limited to this example, and the case where one film container 4 or 5 is loaded is used. Inspection of water samples is possible. That is, in the case of nickel measurement as an example, as in the above, water is sampled up to the graduation 16 position of the container body 15 serving as a colorimetric cell. In this state, the container body 15 is placed in the cell box of the photoelectric photometer set to a predetermined wavelength, and zeroing of the photoelectric photometer is performed as described above.
  • the nickel coloring reagent (powder reagent mainly comprising dimethylglycoxime) contained in the film container 4 or 5 is supplied to a plurality of slits formed on the side surface of the cut-off cylinder portion 8 of the cutter 8A. 1 Leaks out of film container 4 or 5 along 4.
  • the crescent-shaped cutter blade 9 of 8 A cut-off is fitted into the groove 1 so that the tightening of the lid body 3 is stopped.
  • the pedestal 17 at the opening ⁇ of the screw portion 19 of the container body 15 comes into contact with the lower surface of the packing 11, and the space between the pedestal 17 and the packing 11 is sealed, Liquid leakage to the outside of the container body 15 is prevented.
  • the container main body 15 is inverted and stirred, and the reagent is sufficiently mixed with the test sample, and then left for 10 minutes.
  • the encapsulated reagent is a powder, it may remain in the film container 4 or 5, so that the container body 15 is sufficiently inverted.
  • the density can be read in mg / 1 unit.
  • Container 4 A spacer may be interposed between steps 5 and 5 so that the movement of the cutter 8A is moderated.
  • the reaction time of the previously charged reagents may be required, and in this case, the cut-off by the spacer-8 A It is possible to know the degree of tightening of the lid body 3 as a touch, and there is no need to break through the film containers 4 and Z or 5 containing the next reagent during the reaction of the previous reagent.
  • FIGS. 4 to 6 show another embodiment in which the configuration of the cutter 8A is changed.
  • the same parts as those in FIGS. 1 to 3 are denoted by the same reference numerals, and redundant description will be omitted.
  • the cutter 20 shown in these figures is made of, for example, 0.15 mm hard stainless steel.
  • a crown-shaped power cutter blade 22 is provided at the center of the bottom 21 of the cutlet 20 of the cutlet 20.
  • This cutter blade tip 22 is composed of four blade pieces 23 with the center of the power cutter bottom 21 raised upward, and the inside of the four blade pieces 23 is raised and raised.
  • a reagent passage hole 24 formed at the same time is provided.
  • a flange portion 25 bent downward is provided on the outer periphery of the cutter bottom portion 21.
  • the flange 25 enhances the rigidity of the cutter bottom 21.
  • the packing 11 attached to the lower surface side of the cutout 20 is slightly larger in diameter than the cutter bottom 21, and the center corresponds to the reagent passage hole 24 described above.
  • a communication hole 13 is formed, and a projection 12 is provided on an outer peripheral portion thereof.
  • the lid-shaped reagent container for the analysis reagent having such a configuration is used as follows.
  • the cutter blade 22 of the cutter 20 first breaks through the film container 5. At this time, since the cutting edge 22 consists of four blade pieces 23, the film container 5 can be easily and reliably pierced.
  • the 10% diluted sulfuric acid containing ammonium molybdate stored in the film container 5 described above passes through the reagent passage hole 24 formed in the center of the container 20 through the reagent passage hole 24. 1 Move to the 5 side.
  • the cutting edge 22 of the cutter 20 breaks through the film container 4. Also at this time, since the cutter blade tip 22 consists of four blade pieces 23, the film container 5 can be easily and reliably pierced.
  • the powder reagent containing ascorbic acid leaks out of the film container 4 described above.
  • the cutter body 22 of the cutter 20 fits into the groove 1 and the tightening of the lid body 3 stops.
  • the container body 1 5 by inverting stir and mix thoroughly reagent test water, P 0 4 3 included in the test water - coloration reacts with the molybdenum Bull one Ru so-called To color. Then, mix the reagent with the test water sufficiently. After standing for 5 minutes, set the container body 15 on the photometer again, and the test water concentration will be displayed in mg Z 1.
  • the cutting edge 22 is formed of a plurality of cutting pieces 23 formed by cutting and raising the center of the cutter bottom 21. Since the number of blades of the blade pieces 23 is plural, the film containers 4 and 5 can be easily and reliably pierced.
  • the rigidity of the cutter bottom 21 is increased by providing the bent flange 25 on the outer periphery of the cutter bottom 21, thereby increasing the rigidity of the cutter bottom 21. This makes it possible to reduce the thickness of the plate, which can simplify manufacturing processes and reduce costs.
  • the cutter 8A, 20 is connected to the cover body 3 by tightening the cover body 3 in a state where the female thread 2 of the cover body 3 is engaged with the screw portion 19 of the container body 15.
  • a guide protrusion 31 having elasticity is provided on the outer periphery of the upper portion of the mouth portion 30 of the container body 15.
  • locking grooves 32, 33 formed around the circumference and guide grooves 34, 35 formed along the axial direction of the lid main body 3 are formed. ing.
  • each of the locking grooves 32, 33 and each of the guide grooves 34, 35 and each of the guide projections 31 is such that each of the guide projections 31 having elasticity has its own. It is maintained by contacting the groove.
  • the analytical reagent lid reagent container of the present invention after injecting a predetermined amount of test water into the transparent container main body, the predetermined reagent is stored inside from the opening of the container main body.
  • the cutter is moved according to the amount of tightening, the reagent storage container is pierced, and the reagent inside the reagent storage container is inserted into the container main body. Released.
  • the reagent when analyzing the test water, the reagent can be mixed with the test water by tightening the lid body into the container main body into which the test water has been injected. Water quality analysis can be performed safely and accurately with simple operations.

Abstract

A cap-shape reagent container for analysis reagents, which makes a water quality analysis simple. A technical issue of the invention is to provide a cap-shape reagent container for analysis reagents, which enables a water quality analysis safely and precisely in a simple operation even in the absence of a chemical knowledge. A solution to a first technical issue of the invention is to provide a transparent container body enabling injection of a predetermined amount of test water from an opening thereof, a cap body capable of being mounted by tightening from a side of the opening of the container body, a reagent storage container loaded into the cap body for storing a predetermined reagent, and a cutter adapted to be pushed into the interior of the cap body depending upon an amount, with which the cap body is tightened onto the container body, to break through the reagent storage container loaded into the cap body to allow the reagent to be discharged into the container body, as described in claim 1. With the solution, when the cap body holding the reagent storage container, in which a predetermined reagent is received, is mounted from the opening of the container body in a tightening manner after a predetermined amount of the test water is injected into the transparent container body, the cutter is moved in accordance with an amount of tightening, so that the reagent storage container is broken through to allow the reagent in the reagent storage container to be discharged into the container body. Accordingly, in the event of carrying out an analysis of the test water, tightening of the cap body onto the container body, into which the test water has been injected, enables mixing the reagent with the test water, so that a water quality analysis can be performed safely and precisely in a simple operation even in the absence of a chemical knowledge.

Description

明 細 書 分析試薬の蓋状試薬容器 「技術分野」  Description Lid-shaped reagent container for analytical reagents `` Technical field ''
本発明は、 水質分析を簡単に行うようにした分析試薬の蓋状試薬容器 に関する。  TECHNICAL FIELD The present invention relates to a lid-like reagent container for an analysis reagent which can easily perform water quality analysis.
「背景技術」 "Background technology"
簡易水質分析の分析手法の多くは比色分析を採用している。  Many of the simple water analysis methods employ colorimetry.
比色分析法は、 使用器具が小形軽量であり、 且つ安価であり、 結果が 色として目で見えたり、 測定結果が早かったりする等の特長があること から、 産業界で広く使用されている。 但し、 このような比色分析では、 化学薬品を使用するため、 化学的な知識、 技術や経験等が必要となって いる。  The colorimetric analysis method is widely used in the industry because the instrument used is small, lightweight, inexpensive, and the results are visible as colors and the measurement results are fast. . However, such colorimetric analysis requires chemical knowledge, technology, and experience because chemicals are used.
また、 化学薬品を多種類使用するため、 数種類以上の試薬を用意する 必要があるばかり力 その保管も必要である。 さらにまた、 試薬類を使 用するためには必要量を分取するための天秤、 メスシリンダー等の重量 計や容積測定器具等が必要であったり、 これらを撹拌したり保管したり するための沢山のビーカーやフラスコ類を必要とする。  In addition, since many kinds of chemicals are used, it is necessary to prepare more than a few kinds of reagents and also to store them. Furthermore, in order to use the reagents, a balance for collecting required amounts, a weighing scale such as a measuring cylinder, a volume measuring instrument, and the like are required, and these are used for stirring and storing. Requires a lot of beakers and flasks.
このため、 現地で水質分析を行おうとした場合には、 試薬の分取等の 作業が極めて困難であるばかりか、 場合によっては水質分析が不可能と なることもある。  For this reason, if water quality analysis is to be performed on-site, not only is it extremely difficult to perform operations such as fractionation of reagents, but in some cases water quality analysis becomes impossible.
水質分析を行うための試薬は、 液状のものと粉末のものとがある。 液 状の試薬にあっては、 ガラス又はプラスチックのビンに収納された試薬 を付属のスポィ 卜で分取したり、 ガラス又はプラスチックのビンに内蔵 されたスポイ トで分取したり、 目薬ビンで滴下させたりする方法等があ る。 Reagents for water analysis include liquid and powdered reagents. For liquid reagents, the reagents stored in glass or plastic bottles can be collected with the attached spots or built into glass or plastic bottles. There are methods such as dispensing with a spotted drop or dropping with an eye drop bottle.
一方、 粉末の試薬は、 ガラス又はプラスチックの容器に収納された試 薬を付属の軽量スプーンで分取するか、 場合によっては 1回づっラミネ 一卜包材の袋に詰められていたり、 或いは両端を溶着した軟質プラスチ ックチューブの中に詰められたり している試薬を、 包材をカツ 卜して検 水に加える方法等がある。  On the other hand, powdered reagents are obtained by dispensing the reagent contained in a glass or plastic container with the attached lightweight spoon, or in some cases, once in a laminating bag, or at both ends. For example, there is a method in which a reagent packed in a soft plastic tube to which is welded is cut into a packaging material and added to the sample.
さらには、 透明ガラスや透明プラスチック製の比色セルそのものに、 予め 1 回分づつの液状又は粉末の試薬が封入されているものもある。  In addition, there is a case in which a liquid or powdered reagent for one dose is previously enclosed in the colorimetric cell itself made of transparent glass or transparent plastic.
ところで、 混在保存が不可能な液状又は粉末の試薬を 2種類以上使用 する場合、 それぞれを別包装にして保存する必要があり、 検水の分析を 行う場合には、 それぞれの試薬を使用方法に従って別々に検水に投入し なければならない。 したがって、 試薬の数が多ければ多いほど、 分析作 業は煩雑になり、 それぞれの試薬毎に操作法が異なれば使用者は混乱す ることになる。  By the way, when using two or more types of liquid or powder reagents that cannot be mixed and stored, it is necessary to store each in a separate package.When analyzing the sample, use each reagent according to the usage method. They must be separately injected into the water sample. Therefore, as the number of reagents increases, the analysis work becomes more complicated, and the user becomes confused if the operation method is different for each reagent.
一方、 機械等で試薬を自動的に投入して自動測定を行わせことも考え られる力 投入試薬が多いと構造が複雑になってしまうとともに、 上記 同様に、 試薬の保管方法が複雑である。  On the other hand, it is conceivable that the automatic measurement is performed by automatically inputting the reagents by using a machine or the like. When there are many input reagents, the structure becomes complicated, and the storage method of the reagents is complicated as described above.
ちなみに、 混在保存ができない試薬を別々に保管し、 使用時に簡便に 混ぜ合わせる工夫をしたものがある。 すなわち、 分析用の試薬操作目的 ではないが、 たとえば液体試薬を密封したガラスアンプルを軟質プラス チックチューブの中に他の試薬と共に入れ、 使用時には軟質ブラスチッ クに衝撃を与えて中のガラスアンプルを破損させ試薬を混合させるよう にしたものがある。 また、 混在しては保存のきかない物質を二重の袋に 別々に入れ、 使用時に外部から圧力を加え、 中の袋だけを破損させる方 法等がある。 ところが、 このような操作方法では、 慎重な操作が必要となるばかり 力 使用目的毎に操作方法が異なる可能性があるため、 使用者は作業手 順や方法に戸惑うことになる。 By the way, there is a method in which reagents that cannot be mixed and stored are stored separately and mixed easily when used. In other words, it is not the purpose of operating the reagent for analysis, but, for example, a glass ampule sealed with a liquid reagent is placed in a soft plastic tube together with other reagents, and when used, the glass ampule is broken by impacting the soft plastic. Some reagents are mixed together. There is also a method in which substances that cannot be stored if mixed together are separately placed in a double bag, and external pressure is applied during use to damage only the inner bag. However, such an operation method requires careful operation, and the operation method may be different depending on the purpose of use. Therefore, the user is confused by the operation procedure and method.
このように、 簡易水質分析を行うに当たり、 上述した比色分析を用い ることは使用器具が小形軽量であり、 且つ安価であり、 結果が色として 目で見えたり、 測定結果が早かったりする等の特長があるが、 使用する 試薬の準備や保存、 さ らには試薬の操作が煩雑である等の理由から、 水 質分析には十分な化学的知識と経験等が必要とされるという不具合があ つた。  As described above, when performing the simple water quality analysis, the above-mentioned colorimetric analysis is used because the equipment used is small and lightweight, and it is inexpensive, and the results can be seen visually as colors, and the measurement results can be quickly obtained. However, due to the complexity of preparation and storage of reagents to be used and the operation of reagents, water quality analysis requires sufficient chemical knowledge and experience. There was.
「発明の開示」 "Disclosure of the invention"
本発明の第 1 の技術的課題は、 化学的知識がなくても、 簡単な操作で 安全且つ正確に水質分析を行うことができる分析試薬の蓋状試薬容器を 提供することにある。  A first technical problem of the present invention is to provide a lid-like reagent container for an analysis reagent that can perform safe and accurate water quality analysis with a simple operation without chemical knowledge.
本願発明の第 2の技術的課題は、 製造工程の簡素化を図ることにある 本発明の第 1 の技術的課題の解決方法は、 請求の範囲 1 に記載のよう に、 開口部から所定量の検水の注入が可能とされる透明な容器本体と、 この容器本体の前記開口部側から装着される蓋本体と、 この蓋本体に装 填され、 所定の試薬を収納する試薬収納容器と、 前記蓋本体の前記容器 本体に対する装着量に応じて前記蓋本体内部に押し込まれ、 前記蓋本体 に装填される前記試薬収納容器を突き破って前記試薬を前記容器本体内 部に放出させるカッターとを具備することにある。  A second technical problem of the invention of the present application is to simplify the manufacturing process. A solution of the first technical problem of the present invention is that a predetermined amount is set from an opening as described in claim 1. A transparent container main body capable of injecting a test sample, a lid main body mounted from the opening side of the container main body, and a reagent storage container mounted on the lid main body and storing a predetermined reagent. A cutter which is pushed into the inside of the lid main body according to an amount of the lid main body attached to the container main body, pierces the reagent storage container loaded in the lid main body, and discharges the reagent into the inside of the container main body. To have.
この解決方法では、 透明な容器本体に所定量の検水を注入した後、 容 器本体の開口部から内部に所定の試薬が収納されている試薬収納容器を 保持した蓋本体を装着する際、 その装着量に応じてカッターが移動され、 試薬収納容器が突き破られて試薬収納容器内部の試薬が容器本体内部に 放出される。 In this solution, after injecting a predetermined amount of water into a transparent container main body, when attaching a lid main body holding a reagent storage container containing a predetermined reagent therein through an opening of the container main body, The cutter is moved according to the installed amount, the reagent container is pierced, and the reagent inside the reagent container is Released.
したがって、 検水の分析を行う場合には、 検水を注入した容器本体に 蓋本体を装着することで、 試薬を検水に混ぜ合わせることが可能となる ため、 化学的知識がなくても、 簡単な操作で安全且つ正確に水質分析が 行える。  Therefore, when analyzing water samples, the reagent can be mixed with the water sample by attaching the lid body to the container body into which the water sample has been injected. Water quality analysis can be performed safely and accurately with simple operations.
また、 本発明の第 1 の技術的課題の他の解決方法は、 請求の範囲 2に 記載のように、 前記蓋本体は前記容器本体の前記開口部側から締め込み によって装着され、 前記力ッタ一は前記蓋本体の前記容器本体に対する 締め込み量に応じて前記蓋本体内部に押し込まれることにある。  In another solution of the first technical problem of the present invention, as described in claim 2, the lid body is mounted by tightening the container body from the opening side, One of the features is that the lid body is pushed into the inside of the lid body in accordance with the amount of tightening of the lid body to the container body.
この解決方法では、 カッターが蓋本体の容器本体に対する締め込み量 に応じて蓋本体内部に押し込まれるため、 請求の範囲 1 と同じ作用効果 を有する。  In this solution, the cutter is pushed into the inside of the lid main body according to the amount of tightening of the lid main body with respect to the container main body.
また、 本発明の第 1 の技術的課題の他の解決方法は、 請求の範囲 3に 記載のように、 前記蓋本体は前記容器本体の前記開口部側から押し込み によって装着され、 前記力ッ夕一は前記蓋本体の前記容器本体に対する 押し込み量に応じて前記蓋本体内部に押し込まれることにある。  Further, as another solution of the first technical problem of the present invention, as described in claim 3, the lid main body is mounted by pushing from the opening side of the container main body, One is that the lid body is pushed into the inside of the lid body in accordance with the pushing amount of the lid body into the container body.
この解決方法では、 力ッ夕一が蓋本体の容器本体に対する押し込み量 に応じて蓋本体内部に押し込まれるため、 請求の範囲 1 と同じ作用効果 を有する。  In this solution, since the force is pushed into the inside of the lid body in accordance with the pushing amount of the lid body into the container body, the same operation and effect as in claim 1 are obtained.
また、 本発明の第 1の技術的課題の他の解決方法は、 請求の範囲 4に 記載のように、 前記蓋本体内部には互いに異なる試薬を収納した複数の 試薬収納容器が前記力ッターの移動方向に沿って収納され、 前記蓋本体 の装着、 締め込み又は押し込みに応じて、 前記複数の試薬収納容器が前 記カッターにより、 順次突き破られることにある。  Further, as another solution of the first technical problem of the present invention, as described in claim 4, a plurality of reagent containers accommodating different reagents in the lid main body are provided in the lid main body. The plurality of reagent storage containers are stored along the moving direction, and are sequentially pierced by the cutter according to mounting, tightening, or pushing of the lid body.
この解決方法では、 蓋本体に複数の試薬収納容器が力ッ夕一の移動方 向に沿って収納されており、 検水の分析試薬の蓋状試薬容器を行う場合 には、 検水を注入した容器本体に蓋本体を装着、 締め込み又は押し込む ことで、 それぞれの試薬が順次検水に混ぜ合わされる。 In this solution, when a plurality of reagent storage containers are stored in the lid body along the moving direction at the same time, and a lid-shaped At this time, each reagent is mixed with the sample in turn by attaching, tightening or pushing in the lid to the container body into which the sample was injected.
また、 本発明の第 1 の技術的課題の他の解決方法は、 請求の範囲 5に 記載のように、 前記カツ夕一の下面側にはパッキンが装着され、 前記容 器本体に対する前記蓋本体の装着、 締め込み又は押し込みにより、 前記 容器本体の開口緣部が前記パッキンに当接し、 前記容器本体及び前記蓋 本体内部が密閉されることにある。  Further, as another solution of the first technical problem of the present invention, as set forth in claim 5, packing is mounted on a lower surface side of the cutout, and the lid main body with respect to the container main body is provided. By mounting, tightening or pushing in, the opening 緣 of the container body comes into contact with the packing, and the inside of the container body and the lid body is sealed.
この解決方法では、 力ッ夕一の下面側に装着されたパッキンが蓋本体 の締め込みにより、 容器本体の開口縁部に当接することで、 容器本体及 び蓋本体内部が密閉されるため、 検水と試薬との撹拌を行う場合であつ ても、 これら検水及び試薬が外部に洩れ出すことがなくなる。  In this solution, the packing attached to the lower surface side of the lid comes into contact with the opening edge of the container body by tightening the lid body, so that the container body and the inside of the lid body are sealed. Even when the sample and the reagent are stirred, the sample and the reagent do not leak out.
また、 本発明の第 1 の技術的課題の他の解決方法は、 請求の範囲 6に 記載のように、 前記試薬収納容器と前記カッターとの間には、 軟質素材 のプロテクターが介在され、 前記力ッ夕一によつて前記試薬収納容器が 不用意に傷付けられないよう保護されていることにある。  Another solution of the first technical problem of the present invention is as described in claim 6, wherein a protector made of a soft material is interposed between the reagent storage container and the cutter, The reagent container is protected from being inadvertently damaged by a force.
この解決方法では、 試薬収納容器とカツ夕一との間に開催された軟質 素材のプロテクターにより、 試薬収納容器とカツ夕一との接触が断たれ るようになっているため、 検水の分析を行わないときに、 誤ってカツ夕 一により試薬収納容器を突き破ることがなくなり、 試薬収納容器の保存 が確実に行われる。  In this solution, a soft material protector held between the reagent storage container and Katsu Yuichi cuts off the contact between the reagent storage container and Katsu Yuichi, so the analysis of the water sample When the reagent storage is not performed, the reagent storage container is not accidentally pierced by a cut, and the storage of the reagent storage container is reliably performed.
また、 本発明の第 1 の技術的課題の他の解決方法は、 請求の範囲 7に 記載のように、 前記試薬収納容器間には、 前記蓋本体の装着、 締め込み 又は押し込みに伴う前記カツ夕一の移動中断を促すスぺ一ザが介在され、 前記力ッ夕一による前記試薬収納容器の突き破りに節度がもたされてい る し とにの 。  Another solution of the first technical problem of the present invention is that, as described in claim 7, the cuts between the reagent containers are attached, tightened or pushed in with the lid body. A stirrer for interrupting the movement during the evening is interposed, so that the reagent storage container is moderately pierced by the force.
この解決方法では、 試薬収納容器間にスぺ一ザが介在され、 カッター による試薬収納容器の突き破りに節度がもたされるようになっているた め、 試薬投入に時間差等を必要とする場合には、 その節度感により蓋本 体の締め込みを加減することが可能となる。 In this solution, a spacer is interposed between the reagent storage containers, and a cutter is provided. Moderation is provided when the reagent storage container is pierced by the pressure sensor, so if a time lag is required for reagent introduction, the tightness of the moderation can be used to adjust the tightening of the lid body. Becomes
また、 本発明の第 1 の技術的課題の他の解決方法は、 請求の範囲 8に 記載のように、 前記カツ夕一は、 複数の試薬通過穴を有した円盤形状の カッター底部と、 このカッター底部の中心部に突設され、 側面に前記試 薬通過穴に連通させた複数のスリ ッ トを有するとともに、 先端に三日月 状のカッター刃先を有することにある。  Another solution of the first technical problem of the present invention is that, as described in claim 8, the cutlet has a disk-shaped cutter bottom having a plurality of reagent passage holes, and It has a plurality of slits protruding from the center of the bottom of the cutter and communicating with the reagent passage hole on the side surface, and has a crescent-shaped cutter blade at the tip.
この解決方法では、 力ッ夕ー刃先によって突き破られた試薬収納容器 内の試薬が力ッ夕一筒部の側面に形成されている複数のスリ ッ 卜に沿つ て試薬収納容器外部に洩れ出し、 この状態で容器本体を転倒撹拌させる ことで、 容器本体内部の検水と試薬とが力ッター底部の複数の試薬通過 穴を介して混ざり合う。  According to this solution, the reagent in the reagent container pierced by the blade is leaked to the outside of the reagent container along a plurality of slits formed on the side surface of the cylinder portion. By taking out and stirring the container body in this state, the water sample and the reagent inside the container body are mixed via the plurality of reagent passage holes at the bottom of the force hopper.
本発明の第 2の技術的課題の他の解決方法は, 請求の範囲 9に記載の 通り、 前記カツ夕一は、 円盤形状のカッター底部と、 このカッター底部 の中心部に切り起しによって形成される王冠状のカツ夕一刃先と、 その 中心部に形成される試薬通過穴とで構成されていることにある。  Another solution of the second technical problem of the present invention is that, as set forth in claim 9, the cutlet is formed by cutting and raising a disc-shaped cutter bottom and a center of the cutter bottom. It is composed of a crown-shaped cutting edge and a reagent passage hole formed at the center thereof.
この解決方法では、 力ッ夕ー刃先が力ッター底部の中心部に切り起し によって形成され、 これと同時に試薬通過穴も形成されるため、 製造ェ 程が簡素化される。  In this solution, the cutting edge is formed by cutting and raising the center of the bottom of the power cutter, and at the same time, a reagent passage hole is also formed, thereby simplifying the manufacturing process.
また、 本発明の第 2の技術的課題の他の解決方法は、 請求の範囲 1 0 に記載の通り、 前記カツ夕一刃先は、 カツ夕一底部の中心部が切り起さ れた複数の刃片からなることにある。  Further, as another solution of the second technical problem of the present invention, as set forth in Claim 10, the cutting edge of the cutting tool has a plurality of cut and raised portions at the bottom of the cutting tool. Consists of a blade.
この解決方法では、 カッター刃先が力ッ夕ー底部の中心部に切り起し によって形成され、 これと同時に試薬通過穴も形成されるため、 請求の 範囲 9 と同じ作用効果を有する。 また、 本発明の第 2の技術的課題の他の解決方法は、 請求の範囲 1 1 に記載の通り、 前記カツ夕一底部の外周緣部には、 折曲げ加工されたフ ランジ部が設けられていることにある。 In this solution, the cutting edge of the cutter is formed by cutting and raising at the center of the bottom of the blade, and at the same time, a reagent passage hole is also formed. Further, as another solution of the second technical problem of the present invention, as described in Claim 11, a bent flange portion is provided on an outer peripheral portion of the bottom of the cutlet. It is being done.
この解決方法では、 カッター底部の外周縁部に、 折曲げ加工されたフ ランジ部が設けられることにより、 力ッ夕ー底部の剛性が高められるた め、 カッター底部の板厚を薄くすることが可能となり、 製造工程の簡素 化に併せて低コス 卜化が図れる。  In this solution, the rigidity of the bottom of the cutter is increased by providing a bent flange at the outer peripheral edge of the cutter bottom, so the thickness of the cutter bottom can be reduced. This makes it possible to reduce costs while simplifying the manufacturing process.
「図面の簡単な説明」 "Brief description of the drawings"
図 1 は、 本発明の分析試薬の蓋状試薬容器の一実施の形態を示す断面 図である。 図 2は、 図 1のプロテクターを示す斜視図である。 図 3は、 図 1 のカッターを示す斜視図である。 図 4は、 図 1 のカッターの構成を 変えた場合の他の実施の形態を示す断面図である。 図 5は、 図 4のカツ 夕一を示す斜視図である。 図 6は、 図 4のカツ夕一を示す断面図である c 図 7は、 図 1 の分析試薬の蓋状試薬容器の構成を変えた場合の他の実施 の形態を示す斜視図である。 FIG. 1 is a sectional view showing one embodiment of a lid-like reagent container for an analysis reagent of the present invention. FIG. 2 is a perspective view showing the protector of FIG. FIG. 3 is a perspective view showing the cutter of FIG. FIG. 4 is a sectional view showing another embodiment in which the configuration of the cutter in FIG. 1 is changed. FIG. 5 is a perspective view showing the cutout of FIG. FIG. 6 is a cross-sectional view showing the cutting tool in FIG. 4. c FIG. 7 is a perspective view showing another embodiment in which the configuration of the lid reagent container for the analysis reagent in FIG. 1 is changed.
「発明を実施するための最良の形態」 "Best mode for carrying out the invention"
以下、 本発明の実施の形態の詳細を図面に基づいて説明する。  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.
図 1乃至図 3は、 本発明の分析試薬の蓋状試薬容器の一実施の形態を 示すものである。  FIG. 1 to FIG. 3 show an embodiment of a lid-like reagent container for an analysis reagent of the present invention.
これらの図に示すように、 試薬容器は、 蓋本体 3の雌ねじ部 2が比色 セルとなる透明な容器本体 1 5のねじ部 1 9にねじ込まれることにより、 蓋本体 3が容器本体 1 5に対して嵌着自在とされている。  As shown in these figures, the reagent container is configured such that the female screw part 2 of the lid body 3 is screwed into the thread part 19 of the transparent container body 15 which becomes a colorimetric cell, so that the lid body 3 becomes It is designed to be freely fit to.
蓋本体 3の内部中央には、 蓋本体 3の締め込みに伴って押し上げられ る後述のカッター 8 Aの三日月状のカッター刃先 9が嵌り込むための溝 1が形成されている。 蓋本体 3内部には、 種類の異なる試薬を収納した 耐薬品性のフィルム容器 4, 5が収容されている。 また、 これらフィル ム容器 4, 5の収容状態にあっては、 カッター 8 Aの移動方向に沿った 状態とされている。 In the center of the inside of the lid body 3, a groove for fitting a crescent-shaped cutter blade 9 of a cutter 8A, which will be described later, which is pushed up when the lid body 3 is tightened, is fitted. 1 is formed. Inside the lid body 3, chemical resistant film containers 4 and 5 containing different types of reagents are stored. In addition, when the film containers 4 and 5 are housed, they are in a state along the moving direction of the cutter 8A.
ここで、 それぞれのフィルム容器 4, 5は、 耐バリヤ一性 (湿気、 酸 素) 、 耐薬品性の高いものであればよく、 多層 Z複合構造ラミネー ト包 材で構成されている。  Here, each of the film containers 4 and 5 only needs to have high barrier resistance (moisture and oxygen) and high chemical resistance, and is composed of a laminated material having a multilayered Z composite structure.
具体的には、 外側から順にポリエステル ( 1 2 ) —ポリエチレン ( 1 5 w ) —アルミ ( 7 ) 一ボリエチレン ( 2 5 α ) の 4層構造とな つている。  Specifically, it has a four-layer structure of polyester (12) -polyethylene (15w) -aluminum (7) -polyethylene (25α) in order from the outside.
さらには、 ポリプロピレンや P E T等の使用も可能である。  Furthermore, polypropylene, PET or the like can be used.
フィルム容器 5の下部には、 紙等の軟質素材からなるプロテクター 7 及び硬質プラスチック製のカツ夕一 8 Aが配設されている。  At the lower part of the film container 5, a protector 7 made of a soft material such as paper and a hard plastic cutter 8A are provided.
プロテクター 7は、 カツ夕一 8 Aによるフィルム容器 4, 5の不用意 な破れを防止するためのものであって、 図 2に示すように、 円盤形状の プロテク夕一本体 7 aの中心部にプロテク夕一穴 1 3が形成されている とともに、 プロテクター本体 7 aの外周縁部に折れ片 1 8が設けられた 構成とされている。 そして、 後述するように、 カッター 8 Aがプロテク 夕一本体 7 aを押し上げると、 プロテクター本体 7 aは折れ片 1 8の折 れ目 1 8 a部分から折れ曲がるようになつている。  The protector 7 is for preventing the film containers 4 and 5 from being inadvertently torn by the cutout 8A. As shown in Fig. 2, the protector 7 is located at the center of the disk-shaped protector 7a. A protector hole 13 is formed, and a bent piece 18 is provided on the outer peripheral edge of the protector body 7a. Then, as described later, when the cutter 8A pushes up the protector main body 7a, the protector main body 7a bends from the fold 18a of the bent piece 18.
カッター 8 Aは、 図 3に示すように、 円盤形状のカッター底部 8 aを 有している。 カッター底部 8 aには、 複数の試薬通過穴 1 0が設けられ ており、 フィルム容器 4, 5内の試薬と容器本体 1 5内部の検水とがそ れらの試薬通過穴 1 0を通って移動しつつ混ぜ合わされるようになって いる。  The cutter 8A has a disk-shaped cutter bottom 8a, as shown in FIG. The cutter bottom 8a is provided with a plurality of reagent passage holes 10 through which the reagents in the film containers 4 and 5 and the water sample in the container body 15 pass through the reagent passage holes 10 respectively. Are mixed while moving.
また、 カツ夕一底部 8 aの下面側には、 複数の突起 1 2を有するとと もに、 カッター底部 8 aより も径が若千大きめとされた ドーナツ形状の パッキン 1 1が設けられている。 そして、 カッター 8 Aが蓋本体 3内部 に収納されたとき、 パッキン 1 1 の突起 1 2が蓋本体 3の内面に突っ張 ることで、 カツ夕一 8 Aの抜け落ちが防止されるようになっている。 さ らに、 カッター底部 8 aの中心部分には、 先端に三日月状のカツ夕一刃 先 9を有するとともに、 側面に複数のスリ ツ ト 1 4を有したカッター筒 部 8が設けられている。 In addition, it is assumed that a plurality of protrusions 12 are provided on the lower surface side of the bottom 8a of the cutlet. In addition, a donut-shaped packing 11 whose diameter is slightly larger than that of the cutter bottom 8a is provided. When the cutter 8A is stored inside the lid body 3, the protrusions 12 of the packing 11 protrude against the inner surface of the lid body 3 so that the cutout 8A can be prevented from falling off. ing. Further, at the center of the cutter bottom portion 8a, a cutter tube portion 8 having a crescent-shaped cutting edge 9 at its tip and a plurality of slits 14 on its side surface is provided. .
一方、 透明な容器本体 1 5には目盛り 1 6が形成されており、 容器本 体 1 5に取り込むべき検水の量の基準位置とされている。 また、 容器本 体 1 5のねじ部 1 9の開口縁部は、 上記のパッキン 1 1 の台座 1 7 とな つており、 蓋本体 3の締め込みによってその台座 1 7がパッキン 1 1 の 下面部に当接すると、 台座 1 7 とパッキン 1 1 との間が密閉され、 容器 本体 1 5外部への液洩れが防止されるようになっている。  On the other hand, a scale 16 is formed on the transparent container body 15, which is a reference position for the amount of water to be taken into the container body 15. The opening edge of the screw portion 19 of the container body 15 serves as the pedestal 17 of the packing 11, and the pedestal 17 is tightened by the lid body 3 so that the pedestal 17 becomes the lower surface of the packing 11. When it comes into contact with, the space between the pedestal 17 and the packing 11 is sealed, so that leakage of liquid to the outside of the container body 15 is prevented.
続いて、 このような構成の分析試薬の蓋状試薬容器による分析方法に ついて説明する。 なお、 以下の分析方法においては、 検水のリン酸 ( P 〇4 :iつ 濃度の検出を行う場合について説明する。 Next, a method of analyzing an analysis reagent having such a configuration using a lid-shaped reagent container will be described. In the following analysis method, the case of detecting the concentration of phosphoric acid (P〇4 : i ) in the sample will be described.
すなわち、 比色セルとなる容器本体 1 5の目盛り 1 6の位置まで検水 を注入する。 この場合の検水量は約 2 5 m 1 である。  That is, water is injected up to the position of the scale 16 of the container body 15 which becomes a colorimetric cell. In this case, the water volume is about 25 m 1.
この状態で、 容器本体 1 5を、 所定の波長光によって検水の濃度を検 出する図示しない光電光度計のセルボックスに入れ、 光電光度計の零合 わせを行う。  In this state, the container main body 15 is put into a cell box of a photoelectric photometer (not shown) that detects the concentration of the test water using light of a predetermined wavelength, and zeroing of the photoelectric photometer is performed.
次に、 容器本体 1 5を光電光度計より取り出し、 蓋本体 3を容器本体 1 5のねじ部 1 9に装着する。 このとき、 蓋本体 3のフィルム容器 4, 5には、 それぞれァスコルビン酸を含む粉末試薬及びモリブデン酸アン モニゥムを含む 1 0 %希硫酸が収納されている。  Next, the container body 15 is taken out of the photoelectric photometer, and the lid body 3 is attached to the screw portion 19 of the container body 15. At this time, the film containers 4 and 5 of the lid body 3 respectively contain a powder reagent containing ascorbic acid and a 10% diluted sulfuric acid containing ammonium molybdate.
そして、 容器本体 1 5のねじ部 1 9に蓋本体 3の雌ねじ部 2を嚙み合 わせた状態で蓋本体 3を締め付けると、 まず容器本体 1 5のねじ部 1 9 の開口緣部の台座 1 7がパッキン 1 1 の下面側に当接しつつ力ッ夕ー 8 Aを蓋本体 3内部に押し込む。 これに伴い、 プロテク夕一本体 7 aの折 れ片 1 8が力ッター 8 Aの移動に伴いその折れ目 1 8 a部分から折れ曲 がる。 Then, the female thread 2 of the lid body 3 is engaged with the thread 19 of the container body 15. When the lid body 3 is tightened in this state, the pedestal 17 at the opening の of the screw part 19 of the container body 15 comes into contact with the lower surface side of the packing 11, and the force 8 A is applied. Push inside. Along with this, the bent piece 18 of the protector main body 7a bends from the fold 18a with the movement of the power meter 8A.
この状態から蓋本体 3をさらに締め込むと、 カッター 8 Aの三日月状 のカツ夕一刃先 9がまずフィルム容器 5を突き破る。 これにより、 フィ ルム容器 5内部に収納されているモリブデン酸アンモニゥムを含む 1 0 %希硫酸が力ッター 8 Aのカッター筒部 8の側面に形成されている複数 のスリ ツ ト 1 4に沿ってフィルム容器 5外部に洩れ出す。  When the lid body 3 is further tightened in this state, the crescent-shaped cutting edge 9 of the cutter 8 A first breaks through the film container 5. As a result, 10% dilute sulfuric acid containing ammonium molybdate stored in the film container 5 is passed along the plurality of slits 14 formed on the side surface of the cutter cylinder 8 of the power meter 8A. Film container 5 leaks out.
この状態から蓋本体 3をさらに締め込むと、 カツ夕一 8 Aのカッター 刃先 9がフィルム容器 4を突き破る。 これにより、 フィルム容器 4から ァスコルビン酸を含む粉末試薬が洩れ出する。 この状態から蓋本体 3を さらに締め込むと、 カッター 8 Aの三日月状のカッター刃先 9が溝 1 に 嵌り込むことで、 蓋本体 3の締め込みが止まる。  When the lid body 3 is further tightened in this state, the cutter edge 9 of the cut-off 8 A breaks through the film container 4. As a result, the powder reagent containing ascorbic acid leaks from the film container 4. When the lid body 3 is further tightened from this state, the crescent-shaped cutter blade 9 of the cutter 8A fits into the groove 1, and the tightening of the lid body 3 stops.
この状態で、 容器本体 1 5を転倒撹拌させて、 試薬を検水に十分混ぜ 合わせると、 検水に含まれる P O — と反応し、 いわゆるモリブデンブ ルーを呈色する。 試薬を検水に十分混ぜ合わせ、 5分間放置した後に 光電光度計に再び容器本体 1 5をセッ トする。 これにより、 検水の濃度 が m g Z 1 で表示される。  In this state, when the container body 15 is overturned and agitated, and the reagent is sufficiently mixed with the test water, it reacts with P O — contained in the test water to give a so-called molybdenum blue color. Mix the reagent thoroughly with the sample, allow it to stand for 5 minutes, and then set the container body 15 on the photometer again. As a result, the test sample concentration is displayed in mg z 1.
このように、 この実施の形態では、 透明な容器本体 1 5に所定量の検 水を注入した後、 容器本体 1 5の開口部から内部に所定の試薬が収納さ れているフィルム容器 4 , 5を保持した篕本体 3を締め込みによって装 着する際、 その締め込み量に応じてカツ夕一 8 Aが移動され、 フィルム 容器 4 , 5が突き破られてフィルム容器 4 , 5内部の試薬が容器本体 1 5内部に放出される。 したがって、 検水の分析を行う場合には、 検水を注入した容器本体 1 5に蓋本体 3を締め込むことで、 試薬を検水に混ぜ合わせることが可能 となるため、 化学的知識がなくても、 簡単な操作で安全且つ正確に水質 分析が行える。 As described above, in this embodiment, after injecting a predetermined amount of water into the transparent container body 15, the film container 4, in which the predetermined reagent is stored inside from the opening of the container body 15, When the main body 3 holding 5 is mounted by tightening, the cutter 8A is moved according to the tightening amount, the film containers 4 and 5 are pierced, and the reagents inside the film containers 4 and 5 are removed. Is released into the container body 15. Therefore, when analyzing the test water, the reagent can be mixed with the test water by tightening the lid main body 3 into the container main body 15 into which the test water has been injected. However, water quality analysis can be performed safely and accurately with simple operations.
また、 1回の検水の分析には 1個の蓋本体 3があればよく、 液体試薬 等を収容する別の容器を用意する必要がない。  In addition, only one lid body 3 is required for one analysis of the water sample, and there is no need to prepare a separate container for accommodating the liquid reagent and the like.
さらに、 比色セルとなる容器本体 1 5は全ての検水に対して共用する ことができるため、 洗浄後何度でもその使用が可能となり、 非常に経済 的である。  Furthermore, since the container body 15 serving as a colorimetric cell can be shared for all water samples, it can be used any number of times after washing, which is very economical.
さらにまた、 台座 1 7がパッキン 1 1 の下面部に当接することによつ て、 容器本体 1 5外部への液洩れが防止されるようになっているため、 水質分析終了後、 その溶液の廃棄や容器本体 1 5や蓋本体 3の洗浄が不 可能な場合であっても、 そのまま蓋をして密閉したまま持ち帰ることが 可能となる。  Furthermore, since the base 17 comes into contact with the lower surface of the packing 11 to prevent leakage of the liquid to the outside of the container body 15, after the water quality analysis is completed, Even when it is not possible to dispose or wash the container body 15 and the lid body 3, it is possible to take it home with the lid closed and sealed.
しかも、 このような分析試薬の蓋状試薬容器を自動測定装置に利用し ようとした場合、 容器自体が同じ形状であるため、 機構の簡素化が図れ るとともに、 自動測定装置自体に容器の保管機能をもたせる必要がない ため、 装置の小型化も図れる。  Moreover, when using such a lid-shaped reagent container for an analytical reagent in an automatic measurement device, the container itself has the same shape, so that the mechanism can be simplified and the container can be stored in the automatic measurement device itself. Since there is no need to provide functions, the size of the device can be reduced.
なお、 以上の実施の形態では、 蓋本体 3に 2個のフィルム容器 4, 5 を装填させた場合について説明したが、 この例に限らず、 フィルム容器 4又は 5を 1個装填させた場合であっても、 検水の検査が可能である。 すなわち、 ニッケル測定を例にとれば、 上記同様に、 比色セルとなる 容器本体 1 5の目盛り 1 6位置まで検水を入れる。 この状態で、 容器本 体 1 5を、 所定の波長にセッ 卜された光電光度計のセルボックスに入れ、 上記同様に、 光電光度計の零合わせを行う。  In the above embodiment, the case where the lid body 3 is loaded with the two film containers 4 and 5 has been described. However, the present invention is not limited to this example, and the case where one film container 4 or 5 is loaded is used. Inspection of water samples is possible. That is, in the case of nickel measurement as an example, as in the above, water is sampled up to the graduation 16 position of the container body 15 serving as a colorimetric cell. In this state, the container body 15 is placed in the cell box of the photoelectric photometer set to a predetermined wavelength, and zeroing of the photoelectric photometer is performed as described above.
次に、 容器本体 1 5を光電光度計から取り出し、 N i表示された試薬 を内蔵している蓋本体 3を上記同様に容器本体 1 5に装着して蓋本体 3 を締め付ける。 このとき、 上記同様に、 容器本体 1 5のねじ部 1 9の開 口縁部の台座 1 7がパッキン 1 1 の下面側に当接しつつ力ッ夕ー 8 Aを 蓋本体 3内部に押し込む。 これに伴い、 プロテクター本体 7 aの折れ片 1 8がカッター 8 Aの移動に伴いその折れ目 1 8 a部分から折れ曲がる, この状態から蓋本体 3をさらに締め込むと、 カッター 8 Aの三日月状 のカッター刃先 9がまずフィルム容器 4又は 5を突き破る。 これにより フィルム容器 4又は 5内部に収納されているニッケル発色用試薬 (ジメ チルグリォキシムを主体とする粉末試薬) がカッター 8 Aのカツ夕一筒 部 8の側面に形成されている複数のスリ ッ ト 1 4に沿ってフィルム容器 4又は 5外部に洩れ出す。 この状態から蓋本体 3をさらに締め込むと、 カツ夕一 8 Aの三日月状のカッター刃先 9が溝 1 に嵌り込むことで、 蓋 本体 3の締め込みが止められる。 Next, remove the container body 15 from the photoelectric meter and display the reagent indicated by Ni. Is attached to the container body 15 in the same manner as above, and the lid body 3 is tightened. At this time, similarly to the above, the pedestal 17 at the opening edge of the threaded portion 19 of the container body 15 is pressed into the lid body 3 while the pedestal 17 is in contact with the lower surface of the packing 11. Along with this, the bent piece 18 of the protector body 7a bends from the fold 18a with the movement of the cutter 8A, and when the lid body 3 is further tightened from this state, the crescent shape of the cutter 8A The cutter blade 9 first breaks through the film container 4 or 5. As a result, the nickel coloring reagent (powder reagent mainly comprising dimethylglycoxime) contained in the film container 4 or 5 is supplied to a plurality of slits formed on the side surface of the cut-off cylinder portion 8 of the cutter 8A. 1 Leaks out of film container 4 or 5 along 4. When the lid body 3 is further tightened in this state, the crescent-shaped cutter blade 9 of 8 A cut-off is fitted into the groove 1 so that the tightening of the lid body 3 is stopped.
このとき、 上述したように、 容器本体 1 5のねじ部 1 9の開口緣部の 台座 1 7がパッキン 1 1の下面部に当接し、 台座 1 7 とパッキン 1 1 と の間が密閉され、 容器本体 1 5外部への液洩れが防止される。 この状態 で、 容器本体 1 5 を転倒撹拌させて、 試薬を検水に十分混ぜ合わせた後 1 0分間放置する。  At this time, as described above, the pedestal 17 at the opening の of the screw portion 19 of the container body 15 comes into contact with the lower surface of the packing 11, and the space between the pedestal 17 and the packing 11 is sealed, Liquid leakage to the outside of the container body 15 is prevented. In this state, the container main body 15 is inverted and stirred, and the reagent is sufficiently mixed with the test sample, and then left for 10 minutes.
このとき、 封入されていた試薬が粉末である場合、 フィルム容器 4又 は 5の中に残留する可能性があるので、 容器本体 1 5の転倒撹拌を十分 に行う。  At this time, if the encapsulated reagent is a powder, it may remain in the film container 4 or 5, so that the container body 15 is sufficiently inverted.
そして、 1 0分後に、 光電光度計に再びセッ トすれば濃度を m g / 1 単位で読み取ることができる。  Then, 10 minutes later, if the photometer is set again, the density can be read in mg / 1 unit.
なお、 この実施の形態では、 蓋本体 3の締め込みに伴うカッター 8 A の移動によってフィルム容器 4及び/又は 5を単純に突き破るようにし た場合について説明したが、 この例に限らず、 たとえばフィルム容器 4 と 5 との間にスぺーサを介在させてカッター 8 Aの移動に節度をもたせ るようにしてもよい。 In this embodiment, the case where the film container 4 and / or 5 is simply pierced by the movement of the cutter 8A accompanying the tightening of the lid body 3 has been described. However, the present invention is not limited to this example. Container 4 A spacer may be interposed between steps 5 and 5 so that the movement of the cutter 8A is moderated.
すなわち、 2種類以上の試薬が投入される場合、 先に投入された試薬 の反応時間を必要とする場合があり、 この場合、 スぺーサによるカツ夕 - 8 Aの移動の節度感によつて蓋本体 3の締め込みの加減を感触として 知ることが可能となり、 先の試薬の反応中に次の試薬を収納しているフ ィルム容器 4及び Z又は 5を突き破る心配がなくなる。  In other words, when two or more types of reagents are charged, the reaction time of the previously charged reagents may be required, and in this case, the cut-off by the spacer-8 A It is possible to know the degree of tightening of the lid body 3 as a touch, and there is no need to break through the film containers 4 and Z or 5 containing the next reagent during the reaction of the previous reagent.
図 4乃至図 6は、 上記のカッター 8 Aの構成を変えた場合の他の実施 の形態を示すものである。 なお、 以下に説明する図において、 図 1乃至 図 3と共通する部分には同一符号を付し重複する説明を省略する。  4 to 6 show another embodiment in which the configuration of the cutter 8A is changed. In the drawings described below, the same parts as those in FIGS. 1 to 3 are denoted by the same reference numerals, and redundant description will be omitted.
これらの図に示すカッター 2 0は、 たとえば 0 . 1 5 m mの硬質ステ ンレス製とされている。 カツ夕一 2 0のカツ夕一底部 2 1 の中心部には、 王冠状の力ッター刃先 2 2が設けられている。 このカッター刃先 2 2は、 力ッター底部 2 1の中心部が上方に切り起された 4つの刃片 2 3からな るものであり、 これら 4つの刃片 2 3の内側には切り起しと同時に形成 される試薬通過穴 2 4が設けられている。  The cutter 20 shown in these figures is made of, for example, 0.15 mm hard stainless steel. At the center of the bottom 21 of the cutlet 20 of the cutlet 20, a crown-shaped power cutter blade 22 is provided. This cutter blade tip 22 is composed of four blade pieces 23 with the center of the power cutter bottom 21 raised upward, and the inside of the four blade pieces 23 is raised and raised. A reagent passage hole 24 formed at the same time is provided.
さらに、 カッター底部 2 1 の外周緣部には、 下方に向けて折曲げられ たフランジ部 2 5が設けられている。 このフランジ部 2 5によってカツ ター底部 2 1の剛性が高められるようになつている。  Further, a flange portion 25 bent downward is provided on the outer periphery of the cutter bottom portion 21. The flange 25 enhances the rigidity of the cutter bottom 21.
また、 カツ夕一 2 0の下面側に配接されるパッキン 1 1は、 カッター 底部 2 1 よりも径が若干大きめとされており、 その中心部には上記の試 薬通過穴 2 4に対応させた連通穴 1 3が形成されているとともに、 その 外周部には突起 1 2が設けられている。  In addition, the packing 11 attached to the lower surface side of the cutout 20 is slightly larger in diameter than the cutter bottom 21, and the center corresponds to the reagent passage hole 24 described above. A communication hole 13 is formed, and a projection 12 is provided on an outer peripheral portion thereof.
このような構成の分析試薬の蓋状試薬容器は、 次のようにして使用さ れる。  The lid-shaped reagent container for the analysis reagent having such a configuration is used as follows.
すなわち、 容器本体 1 5のねじ部 1 9に蓋本体 3の雌ねじ部 2を嚙み 合わせた状態で蓋本体 3を締め付けると、 上記同様に、 容器本体 1 5の 台座 1 7がパッキン 1 1 の下面側に当接しつつカツ夕一 2 0を蓋本体 3 内部に押し込む。 これに伴い、 プロテク夕一本体 7 aの折れ片 1 8が力 ッ夕ー 8 Aの移動に伴ってその折れ目 1 8 a部分から折れ曲がる。 That is, insert the female screw 2 of the lid 3 into the screw 19 of the container 15. When the lid body 3 is tightened in the fitted state, the pedestal 17 of the container body 15 is pushed into the lid body 3 while the pedestal 17 of the container body 15 is in contact with the lower surface side of the packing 11 as described above. Along with this, the bent piece 18 of the protector main body 7a bends from the fold 18a with the movement of the power 8A.
この状態から蓋本体 3をさらに締め込むと、 カッター 2 0のカッター 刃先 2 2がまずフィルム容器 5を突き破る。 このとき、 カツ夕一刃先 2 2が 4つの刃片 2 3からなるため、 フィルム容器 5の突き破りが容易且 つ確実に行われる。  When the lid body 3 is further tightened from this state, the cutter blade 22 of the cutter 20 first breaks through the film container 5. At this time, since the cutting edge 22 consists of four blade pieces 23, the film container 5 can be easily and reliably pierced.
これにより、 上述したフィルム容器 5内部に収納されているモリブデ ン酸アンモニゥムを含む 1 0 %希硫酸が力ッ夕一 2 0の中心部分に形成 されている試薬通過穴 2 4を通って容器本体 1 5側に移動する。  As a result, the 10% diluted sulfuric acid containing ammonium molybdate stored in the film container 5 described above passes through the reagent passage hole 24 formed in the center of the container 20 through the reagent passage hole 24. 1 Move to the 5 side.
この状態から蓋本体 3をさらに締め込むと、 カッター 2 0のカツ夕一 刃先 2 2がフィルム容器 4を突き破る。 このときも、 カッター刃先 2 2 が 4つの刃片 2 3からなるため、 フィルム容器 5の突き破りが容易且つ 確実に行われる。  When the lid body 3 is further tightened in this state, the cutting edge 22 of the cutter 20 breaks through the film container 4. Also at this time, since the cutter blade tip 22 consists of four blade pieces 23, the film container 5 can be easily and reliably pierced.
これにより、 上述したフィルム容器 4からァスコルビン酸を含む粉末 試薬が洩れ出る。 この状態から蓋本体 3 をさらに締め込むと、 カツ夕一 2 0のカッター刃先 2 2が溝 1 に嵌り込むことで、 蓋本体 3の締め込み が止まる。  As a result, the powder reagent containing ascorbic acid leaks out of the film container 4 described above. When the lid body 3 is further tightened in this state, the cutter body 22 of the cutter 20 fits into the groove 1 and the tightening of the lid body 3 stops.
この状態で、 上述したように、 容器本体 1 5を転倒撹拌させ、 試薬を 検水に十分混ぜ合わせると、 検水に含まれる P 0 4 3— と反応し、 いわゆ るモリブデンブル一を呈色する。 そして、 試薬を検水に十分混ぜ合わせ. 5分間放置した後に光電光度計に再び容器本体 1 5をセッ トすることで 検水の濃度が m g Z 1 で表示される。 In this state, as described above, the container body 1 5 by inverting stir and mix thoroughly reagent test water, P 0 4 3 included in the test water - coloration reacts with the molybdenum Bull one Ru so-called To color. Then, mix the reagent with the test water sufficiently. After standing for 5 minutes, set the container body 15 on the photometer again, and the test water concentration will be displayed in mg Z 1.
このように、 この実施の形態では、 カツ夕一刃先 2 2がカッター底部 2 1の中心部を切り起して形成される複数の刃片 2 3からなるため、 製 造が容易であるばかり力 刃片 2 3の刃先が複数とされることから、 フ イルム容器 4 , 5の突き破りを容易且つ確実に行うことができる。 As described above, in this embodiment, the cutting edge 22 is formed of a plurality of cutting pieces 23 formed by cutting and raising the center of the cutter bottom 21. Since the number of blades of the blade pieces 23 is plural, the film containers 4 and 5 can be easily and reliably pierced.
また、 この実施の形態では、 カッター底部 2 1 の外周緣部に、 折曲げ 加工されたフランジ部 2 5が設けられることにより、 カツター底部 2 1 の剛性が高められるため、 力ッター底部 2 1 の板厚を薄くすることが可 能となり、 製造工程の簡素化に併せて低コス ト化も図れる。  In addition, in this embodiment, the rigidity of the cutter bottom 21 is increased by providing the bent flange 25 on the outer periphery of the cutter bottom 21, thereby increasing the rigidity of the cutter bottom 21. This makes it possible to reduce the thickness of the plate, which can simplify manufacturing processes and reduce costs.
なお、 以上の各実施の形態では、 容器本体 1 5のねじ部 1 9に蓋本体 3の雌ねじ部 2を嚙み合わせた状態で蓋本体 3を締め付けることにより カッター 8 A , 2 0を蓋本体 3内部に押し込むようにした場合について 説明したが、 この例に限らず、 たとえば図 7 に示すように、 蓋本体 3を 容器本体 1 5側に押込むことで、 カッター 8 A , 2 0 を蓋本体 3内部に 押し込むようにすることもできる。  In each of the above embodiments, the cutter 8A, 20 is connected to the cover body 3 by tightening the cover body 3 in a state where the female thread 2 of the cover body 3 is engaged with the screw portion 19 of the container body 15. (3) Although the description has been given of the case where the cutters are pushed into the inside, the present invention is not limited to this example. For example, as shown in Fig. 7, the cutters 8A and 20 It can also be pushed into the body 3.
すなわち、 容器本体 1 5の口部 3 0の上部外周には、 弾性力を有した ガイ ド突起 3 1が設けられている。 一方、 蓋本体 3の内面側には、 周回 りに形成された係止溝 3 2, 3 3 と蓋本体 3の軸方向に沿って形成され たガイ ド溝 3 4 , 3 5 とが形成されている。 各ガイ ド突起 3 1が係止溝 3 2に嵌り込んでいる状態では、 容器本体 1 5側への蓋本体 3の押込み が阻止され、 蓋本体 3を回し各ガイ ド突起 3 1 を係止溝 3 2から外すこ とで、 蓋本体 3の押込みが可能となり、 上述したカッター 8 A , 2 0の 移動が可能とされる。  That is, a guide protrusion 31 having elasticity is provided on the outer periphery of the upper portion of the mouth portion 30 of the container body 15. On the other hand, on the inner surface side of the lid main body 3, locking grooves 32, 33 formed around the circumference and guide grooves 34, 35 formed along the axial direction of the lid main body 3 are formed. ing. When the guide projections 3 1 are fitted in the locking grooves 3 2, the lid body 3 is prevented from being pushed into the container body 15 side, and the lid body 3 is turned to lock each guide projection 3 1 By removing from the groove 32, the lid body 3 can be pushed in, and the above-mentioned cutters 8A and 20 can be moved.
そして、 各ガイ ド突起 3 1がガイ ド溝 3 4によってガイ ドされて係止 溝 3 3に嵌り込んだ位置では、 上述したカツ夕一 8 A , 2 0によってフ イルム容器 5が突き破られる。 このとき、 係止溝 3 3によって蓋本体 3 の押込みが阻止されるため、 再度蓋本体 3を回し各ガイ ド突起 3 1 を係 止溝 3 3から外すことで、 各ガイ ド突起 3 1がガイ ド溝 3 5に沿ってガ イ ドされ、 上述したカッター 8 A, 2 0によってフィルム容器 4が突き 破られる。 Then, at the position where each guide projection 31 is guided by the guide groove 34 and fitted into the locking groove 33, the film container 5 is pierced by the above-mentioned cutouts 8A and 20. . At this time, the pushing of the lid body 3 is prevented by the locking groove 3 3, so that the lid body 3 is turned again to remove each guide projection 31 from the locking groove 33 so that each guide projection 31 is formed. The film container 4 is guided along the guide groove 35, and the film container 4 is pushed by the cutters 8A and 20 described above. Torn.
これにより、 上述したように、 2種類以上の試薬が投入される場合、 先に投入された試薬の反応時間を必要とする場合があっても、 係止溝 3 3による蓋本体 3の押込み規制により、 先の試薬の反応中に次の試薬を 収納しているフィルム容器 4及び/又は 5を突き破る心配がなくなる。  As a result, as described above, when two or more types of reagents are supplied, even if the reaction time of the previously supplied reagents may be required, the pushing of the lid body 3 by the locking grooves 3 3 is restricted. This eliminates the risk of breaking through the film containers 4 and / or 5 containing the next reagent during the reaction of the previous reagent.
このとき、 各係止溝 3 2 , 3 3及び各ガイ ド溝 3 4, 3 5 と各ガイ ド 突起 3 1 との間の機密性は、 弾性力を有したガイ ド突起 3 1がそれぞれ の溝に弹接することで維持される。  At this time, the confidentiality between each of the locking grooves 32, 33 and each of the guide grooves 34, 35 and each of the guide projections 31 is such that each of the guide projections 31 having elasticity has its own. It is maintained by contacting the groove.
「産業上の利用可能性」 "Industrial applicability"
以上説明したように、 本発明の分析試薬の蓋状試薬容器によれば、 透 明な容器本体に所定量の検水を注入した後、 容器本体の開口部から内部 に所定の試薬が収納されている試薬収納容器を保持した蓋本体を締め込 みによって装着する際、 その締め込み量に応じてカッターが移動され、 試薬収納容器が突き破られて試薬収納容器内部の試薬が容器本体内部に 放出される。  As described above, according to the analytical reagent lid reagent container of the present invention, after injecting a predetermined amount of test water into the transparent container main body, the predetermined reagent is stored inside from the opening of the container main body. When the lid that holds the reagent storage container is attached by tightening, the cutter is moved according to the amount of tightening, the reagent storage container is pierced, and the reagent inside the reagent storage container is inserted into the container main body. Released.
したがって、 検水の分析を行う場合には、 検水を注入した容器本体に 蓋本体を締め込むことで、 試薬を検水に混ぜ合わせることが可能となる ため、 化学的知識がなくても、 簡単な操作で安全且つ正確に水質分析が 行える。  Therefore, when analyzing the test water, the reagent can be mixed with the test water by tightening the lid body into the container main body into which the test water has been injected. Water quality analysis can be performed safely and accurately with simple operations.

Claims

請 求 の 範 囲 The scope of the claims
1 . 開口部から所定量の検水の注入が可能とされる透明な容器本体と、 この容器本体の前記開口部側から装着される蓋本体と、 この蓋本体に装 填され、 所定の試薬を収納する試薬収納容器と、 前記蓋本体の前記容器 本体に対する装着量に応じて前記蓋本体内部に押し込まれ、 前記蓋本体 に装填される前記試薬収納容器を突き破って前記試薬を前記容器本体内 部に放出させるカッターとを具備することを特徴とする分析試薬の蓋状1. A transparent container main body through which a predetermined amount of water can be injected from an opening, a lid main body mounted from the opening side of the container main body, and a predetermined reagent loaded into the lid main body, And a reagent storage container for storing the reagent in the container main body according to the amount of attachment of the lid main body to the container main body. A lid for the analysis reagent, comprising:
B式 容^ 5。 Expression B ^ 5.
2 . 請求の範囲 1 の分析試薬の蓋状試薬容器において、 前記蓋本体は前 記容器本体の前記開口部側から締め込みによって装着され、 前記力ッ夕 一は前記蓋本体の前記容器本体に対する締め込み量に応じて前記蓋本体 内部に押し込まれることを特徴とする分析試薬の蓋状試薬容器。  2. The lid-shaped reagent container for an analytical reagent according to claim 1, wherein the lid body is mounted by being tightened from the opening side of the container body, and the force is applied to the container body of the lid body. A lid-like reagent container for an analysis reagent, which is pushed into the inside of the lid body in accordance with a tightening amount.
3 . 請求の範囲 1 の分析試薬の蓋状試薬容器において、 前記蓋本体は前 記容器本体の前記開口部側から押し込みによって装着され、 前記力ッ夕 一は前記蓋本体の前記容器本体に対する押し込み量に応じて前記蓋本体 内部に押し込まれることを特徴とする分析試薬の蓋状試薬容器。  3. The lid-shaped reagent container for an analytical reagent according to claim 1, wherein the lid body is mounted by being pushed in from the opening side of the container body, and the force is applied by pushing the lid body into the container body. A lid-like reagent container for an analysis reagent, which is pushed into the lid body according to the amount.
4 . 請求の範囲 1 〜 3のいずれかの分析試薬の蓋状試薬容器において、 前記蓋本体内部には互いに異なる試薬を収納した複数の試薬収納容器が 前記カッターの移動方向に沿って収納され、 前記蓋本体の装着、 締め込 み又は押し込みに応じて、 前記複数の試薬収納容器が前記力ッ夕一によ り、 順次突き破られることを特徴とする分析試薬の蓋状試薬容器。  4. The lid-shaped reagent container for an analysis reagent according to any one of claims 1 to 3, wherein a plurality of reagent storage containers storing different reagents are stored inside the lid body along a moving direction of the cutter, A lid-shaped reagent container for an analysis reagent, wherein the plurality of reagent storage containers are sequentially pierced by the force when the lid body is attached, tightened, or pressed.
5 . 請求項 1 ~ 4のいずれかの分析試薬の蓋状試薬容器において、 前記 力ッ夕一の下面側にはパッキンが装着され、 前記容器本体に対する前記 蓋本体の装着、 締め込み又は押し込みにより、 前記容器本体の開口縁部 が前記パッキンに当接し、 前記容器本体及び前記蓋本体内部が密閉され ることを特徵とする分析試薬の蓋状試薬容器。 5. The lid-shaped reagent container for an analytical reagent according to any one of claims 1 to 4, wherein a packing is mounted on a lower surface side of the pressure plate, and the lid body is mounted, tightened, or pushed into the container body. The opening edge of the container body abuts the packing, and the inside of the container body and the lid body is sealed. A lid-shaped reagent container for an analysis reagent, which is characterized in that:
6 . 請求の範囲 1 〜 5のいずれかの分析試薬の蓋状試薬容器において、 前記試薬収納容器と前記力ッ夕一との間には、 軟質素材のプロテクター が介在され、 前記力ッ夕一によつて前記試薬収納容器が不用意に傷付け られないよう保護されていることを特徴とする分析試薬の蓋状試薬容器, 6. The lid-shaped reagent container for an analytical reagent according to any one of claims 1 to 5, wherein a protector made of a soft material is interposed between the reagent storage container and the power container, Wherein the reagent storage container is protected from being inadvertently damaged by the lid,
7 . 請求項 4〜 6のいずれかの分析試薬の蓋状試薬容器において、 前記 試薬収納容器間には、 前記蓋本体の装着、 締め込み又は押し込みに伴う 前記力ッターの移動中断を促すスぺーサが介在され、 前記カッターによ る前記試薬収納容器の突き破りに節度がもたされていることを特徴とす る分析試薬の蓋状試薬容器。 7. The lid-shaped reagent container for analysis reagents according to any one of claims 4 to 6, wherein a space between the reagent storage containers is provided to prompt the interruption of the movement of the power meter due to the mounting, tightening, or pushing of the lid body. A lid-like reagent container for an analysis reagent, characterized in that a moderator is interposed and moderation is provided for the cutter to pierce the reagent storage container.
8 . 請求の範囲 1 〜 3の分析試薬の蓋状試薬容器において、 前記カツ夕 一は、 複数の試薬通過穴を有した円盤形状のカッター底部と、 このカツ 夕一底部の中心部に突設され、 側面に前記試薬通過穴に連通させた複数 のスリ ツ 卜を有するとともに、 先端に三日月状のカツ夕一刃先を有する カツ夕一筒部とで構成されていることを特徴とする。  8. The lid-shaped reagent container for an analytical reagent according to any one of claims 1 to 3, wherein the cut has a disc-shaped cutter bottom having a plurality of reagent passage holes, and protrudes from the center of the cut bottom. It has a plurality of slits connected to the reagent passage hole on the side surface, and a cut-and-cut cylindrical portion having a crescent-shaped cut and cut edge at the tip.
9 . 請求の範囲 8の分析試薬の蓋状試薬容器において、 前記カツ夕一は 円盤形状のカツ夕一底部と、 このカツ夕一底部の中心部に切り起しによ つて形成される王冠状の力ッ夕ー刃先と、 その中心部に形成される試薬 通過穴とで構成されていることを特徴とする分析試薬の蓋状試薬容器。 9. The lid-shaped reagent container for an analytical reagent according to claim 8, wherein the cut is a disk-shaped cut bottom and a crown formed by cutting and raising at the center of the cut bottom. A lid-shaped reagent container for an analysis reagent, comprising: a blade tip; and a reagent passage hole formed in the center of the blade tip.
1 0 . 請求の範囲 9の分析試薬の蓋状試薬容器において、 前記カッター 刃先は、 力ッ夕ー底部の中心部が切り起された複数の刃片からなること を特徴とする。 10. The lid-shaped reagent container for an analytical reagent according to claim 9, wherein the cutter blade edge is composed of a plurality of blade pieces whose central portion at the bottom of the blade is cut and raised.
1 1 . 請求の範囲 9又は 1 0の分析試薬の蓋状試薬容器において、 前記 カツ夕一底部の外周緣部には、 折曲げ加工されたフランジ部が設けられ ていることを特徴とする。 補正書の請求の範囲 11. The lid-shaped reagent container for an analysis reagent according to claim 9 or 10, wherein a bent flange portion is provided on an outer peripheral portion of the bottom of the cutout. Claims of amendment
[ 1 9 9 7年 1 2月 2 9日 (2 9 . [1992 1 February 29 (29.
1 2 . 9 7 ) 国際事務局受理:出願当初の請求の範囲 1及び 4 は補正された;他の請求の範囲は変更なし。 (2頁) ] 12) 9) Accepted by the International Bureau: Claims 1 and 4 as originally filed have been amended; other claims remain unchanged. (2 pages)]
1 . (補正後) 開口部から所定量の検水の注入が可能とされる透明な容 器本体と、 この容器本体の前記開口部側から装着される蓋本体と、 試薬 が収納される気密性の収納容器が複数有り, それぞれの試薬収納容器に は異なる試薬が収容されるとともに、 前記蓋本体に 1 乃至複数着脱自在 に装填される試薬収納容器と、 前記蓋本体の前記容器本体に対する装着 量に応じて前記蓋本体内部に押し込まれ、 前記蓋本体に装填される前記 試薬収納容器を突き破って前記試薬を前記容器本体内部に放出させる力 ッ夕一とを具備することを特徴とする分析試薬の蓋状試薬容器。  1. (After correction) A transparent container main body through which a predetermined amount of water can be injected from the opening, a lid main body mounted from the opening side of the container main body, and an airtight housing for storing reagents. There are a plurality of storage containers having different properties. Each reagent storage container stores a different reagent, and one or more reagent storage containers are detachably mounted on the lid body, and mounting of the lid body on the container body. An analysis unit that is pressed into the inside of the lid main body in accordance with the amount, and pierces the reagent storage container loaded in the lid main body to discharge the reagent into the inside of the container main body. Lid-shaped reagent container for reagent.
2 . 請求の範囲 1 の分析試薬の蓋状試薬容器において、 前記蓋本体は前 記容器本体の前記開口部側から締め込みによって装着され、 前記力ッ夕 一は前記蓋本体の前記容器本体に対する締め込み量に応じて前記篕本体 内部に押し込まれることを特徴とする分析試薬の蓋状試薬容器。  2. The lid-shaped reagent container for an analytical reagent according to claim 1, wherein the lid body is mounted by being tightened from the opening side of the container body, and the force is applied to the container body of the lid body. A lid-shaped reagent container for an analysis reagent, which is pushed into the main body according to the amount of tightening.
3 - 請求の範囲 1 の分析試薬の蓋状試薬容器において、 前記蓋本体は前 記容器本体の前記開口部側から押し込みによって装着され、 前記カツ夕 一は前記蓋本体の前記容器本体に対する押し込み量に応じて前記蓋本体 内部に押し込まれることを特徴とする分析試薬の蓋状試薬容器。  3-The lid-shaped reagent container for an analytical reagent according to claim 1, wherein the lid body is mounted by being pushed from the opening side of the container body, and the cut is a pushing amount of the lid body into the container body. A lid-shaped reagent container for an analytical reagent, which is pushed into the lid body in accordance with the above.
4 . (補正後) 請求の範囲 1 〜 3のいずれかの分析試薬の蓋状試薬容器 において、 前記蓋本体内部には前記複数の試薬収納容器が前記力ッ夕ー の移動方向に沿って収納され、 前記蓋本体の装着、 締め込み又は押し込 みに応じて、 前記複数の試薬収納容器が前記カツ夕一により、 順次突き 破られることを特徴とする分析試薬の蓋状試薬容器。  4. (After Correction) The lid-shaped reagent container for an analytical reagent according to any one of claims 1 to 3, wherein the plurality of reagent storage containers are accommodated in the lid main body along the moving direction of the power supply. A lid-shaped reagent container for an analysis reagent, wherein the plurality of reagent storage containers are sequentially pierced by the cutout in accordance with mounting, tightening, or pushing of the lid body.
5 . 請求項 1 〜 4のいずれかの分析試薬の蓋状試薬容器において、 前記 力ッターの下面側にはパッキンが装着され、 前記容器本体に対する前記 蓋本体の装着、 締め込み又は押し込みにより、 前記容器本体の開口縁部  5. The lid-shaped reagent container for an analysis reagent according to any one of claims 1 to 4, wherein a packing is mounted on a lower surface side of the force hopper, and the lid body is mounted on the container body, and tightened or pushed into the container body. Opening edge of container body
補正された用紙 (条約第 19条) が前記パッキンに当接し、 前記容器本体及び前記蓋本体内部が密閉され ることを特徴とする分析試薬の蓋状試薬容器。 Amended paper (Article 19 of the Convention) A lid reagent container for an analysis reagent, wherein the container body and the lid body are hermetically sealed in contact with the packing.
6 . 請求の範囲 1 〜 5のいずれかの分析試薬の蓋状試薬容器において、 前記試薬収納容器と前記力ッターとの間には、 軟質素材のプロテク夕一 が介在され、 前記力ッ夕一によって前記試薬収納容器が不用意に傷付け られないよう保護されていることを特徴とする分析試薬の蓋状試薬容器 t 6. The lid-shaped reagent container for an analysis reagent according to any one of claims 1 to 5, wherein a soft material protector is interposed between the reagent storage container and the power meter. the lid-shaped reagent containers t analytical reagent, wherein said reagent container is protected against damaged accidentally by
7 . 請求項 4〜 6のいずれかの分析試薬の蓋状試薬容器において、 前記 試薬収納容器間には、 前記蓋本体の装着、 締め込み又は押し込みに伴う 前記カッターの移動中断を促すスぺ一サが介在され, 前記カツ夕一によ る前記試薬収納容器の突き破りに節度がもたされていることを特徴とす る分析試薬の蓋状試薬容器。 7. The lid-shaped reagent container for an analysis reagent according to any one of claims 4 to 6, further comprising a step for urging the cutter to stop moving when the lid body is mounted, tightened, or pushed in between the reagent storage containers. A lid-shaped reagent container for an analysis reagent, wherein a cutout is provided to prevent the reagent storage container from being pierced by the cutout.
8 . 請求の範囲 1 〜 3の分析試薬の蓋状試薬容器において、 前記カツ夕 —は、 複数の試薬通過穴を有した円盤形状のカッター底部と、 このカツ 夕一底部の中心部に突設され、 側面に前記試薬通過穴に連通させた複数 のスリ ツ トを有するとともに、 先端に三日月状のカッター刃先を有する カッター筒部とで構成されていることを特徴とする。  8. The lid-shaped reagent container for an analytical reagent according to any one of claims 1 to 3, wherein the cut is provided with a disk-shaped cutter bottom having a plurality of reagent passage holes, and protruding from the center of the cut bottom. And a plurality of slits connected to the reagent passage hole on the side surface, and a cutter cylinder having a crescent-shaped cutter blade at the tip.
9 - 請求の範囲 8の分析試薬の蓋状試薬容器において、 前記カッターは, 円盤形状のカッター底部と、 このカツ夕一底部の中心部に切り起しによ つて形成される王冠状の力ッ夕一刃先と、 その中心部に形成される試薬 通過穴とで構成されていることを特徴とする分析試薬の蓋状試薬容器。 9-The lid-shaped reagent container for an analytical reagent according to claim 8, wherein the cutter has a disk-shaped cutter bottom and a crown-shaped force formed by cutting and raising the center of the cut bottom. A lid-shaped reagent container for an analysis reagent, comprising a cutting edge and a reagent passage hole formed in the center thereof.
1 0 . 請求の範囲 9の分析試薬の蓋状試薬容器において、 前記カッター 刃先は、 力ッ夕ー底部の中心部が切り起された複数の刃片からなること を特徴とする。 10. The lid-shaped reagent container for an analytical reagent according to claim 9, wherein the cutter blade edge is composed of a plurality of blade pieces whose central portion at the bottom of the blade is cut and raised.
1 1 . 請求の範囲 9又は 1 0の分析試薬の蓋状試薬容器において、 前記 力ッ夕一底部の外周縁部には、 折曲げ加工されたフランジ部が設けられ ていることを特徴とする。 補正された用紙 (条約第 19条) 条約第 1 9条 ( 1 ) に基づく説明書 請求の範囲第 1項は、 気密性の試薬収納容器が複数有ること、 それぞ れの試薬収納容器には異なる試薬が収容されること、 その試薬収納容器 が蓋本体に対して 1 乃至複数装填可能であること、 及びそれぞれの試薬 収納容器の交換が可能であることを明確にした。 11. The lid-shaped reagent container for an analytical reagent according to claim 9 or 10, wherein a bent flange portion is provided on an outer peripheral edge of the bottom portion of the wedge. . Amended paper (Article 19 of the Convention) Statements based on Article 19 (1) of the Convention Claim 1 states that there are multiple airtight reagent storage containers, that each reagent storage container holds a different reagent, Clarified that one or more storage containers can be loaded into the lid body, and that each reagent storage container can be replaced.
引用例 (特開昭 9 一 2 5 5 0 4 7号) は、 本願の蓋本体に対して着脱 自在に装填される気密性の試薬収納容器を具備するものではなく、 カー トリ ッジ自体に水和剤等の内容物を収容しているとともに、 容器本体内 部の水に混和させる内容物を一種類のみとしている。  The cited example (Japanese Unexamined Patent Publication No. 9-255507) does not include an airtight reagent storage container that is removably mounted to the lid body of the present application, but rather a cartridge itself. In addition to containing wettable powder and other contents, only one type of content is mixed with the water inside the container body.
引用例 (実開平 5— 6 8 8 6 5号) も、 上記の本願の構成を具備して おらず、 キャップ 体に容器内の液体に混和させる収容物を収容させて いるとともに、 収容物を一種類のみとしている。  The cited example (Japanese Utility Model Laid-Open No. 5-688865) also does not have the above-described configuration of the present application, and has a cap body containing a material to be mixed with the liquid in the container, and Only one type.
引用例 (実開平 1 一 1 3 2 5 7 1号) も、 上記本願の構成を具備して おらず、 第 2の容器自体に第 1 の容器内の第 1 の収容物に混和される第 2の収容物を収容しているいとともに、 その収容物を一種類のみとして いる。  The cited example (Japanese Utility Model Application No. 1 1 1 3 2 5 7 1) also does not have the configuration of the above-mentioned application, and the second container itself is mixed with the first container contained in the first container. It wants to contain 2 items and only one type.
引用例 (実公昭 6 2— 4 5 1 7 0号) も、 上記の本願の構成を具備し ておらず、 混和すべきものをブラズチック焼結多孔体としている。  The cited example (Japanese Utility Model Publication No. 62-450170) also does not have the configuration of the present application described above, and uses what is to be mixed as a porous sintered porous body.
引用例 (実開昭 5 7— 5 1 6 4 0号) も、 上記の本願の構成を具備し ておらず、 試薬を中栓自体に収容するとともに、 試薬を一種類のみとし ている。 請求の範囲第 4項は、 蓋本体内部に収納される試薬収納容器が複数で あることを明確とした。  The cited example (Japanese Utility Model Application Laid-Open No. 57-51640) also does not have the configuration of the above-mentioned application, and stores the reagent in the inner stopper itself and uses only one type of reagent. Claim 4 clarified that there are a plurality of reagent storage containers to be stored inside the lid main body.
PCT/JP1997/002472 1996-07-18 1997-07-16 Cap-shape reagent container for analysis reagents WO1998003265A1 (en)

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