WO1998037841A1 - An absorbent article incorporating liquid barriers with sealing coating - Google Patents

An absorbent article incorporating liquid barriers with sealing coating Download PDF

Info

Publication number
WO1998037841A1
WO1998037841A1 PCT/SE1998/000339 SE9800339W WO9837841A1 WO 1998037841 A1 WO1998037841 A1 WO 1998037841A1 SE 9800339 W SE9800339 W SE 9800339W WO 9837841 A1 WO9837841 A1 WO 9837841A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
wearer
sheet
sealing
edge
Prior art date
Application number
PCT/SE1998/000339
Other languages
French (fr)
Inventor
Peter Rönnberg
Eva Simmons
Anders Gustafsson
Bo Runeman
Original Assignee
Sca Hygiene Products Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=20405947&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1998037841(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Sca Hygiene Products Ab filed Critical Sca Hygiene Products Ab
Priority to AU63156/98A priority Critical patent/AU730098C/en
Priority to JP53757598A priority patent/JP4211949B2/en
Priority to PL335255A priority patent/PL193232B1/en
Priority to EP98907316A priority patent/EP1005309B1/en
Priority to DE69806940T priority patent/DE69806940T2/en
Priority to US09/380,211 priority patent/US6817993B1/en
Priority to DK98907316T priority patent/DK1005309T3/en
Priority to CA002282487A priority patent/CA2282487A1/en
Publication of WO1998037841A1 publication Critical patent/WO1998037841A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/494Absorbent articles specially adapted to be worn around the waist, e.g. diapers characterised by edge leakage prevention means
    • A61F13/49406Absorbent articles specially adapted to be worn around the waist, e.g. diapers characterised by edge leakage prevention means the edge leakage prevention means being at the crotch region
    • A61F13/49413Absorbent articles specially adapted to be worn around the waist, e.g. diapers characterised by edge leakage prevention means the edge leakage prevention means being at the crotch region the edge leakage prevention means being an upstanding barrier
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/495Absorbent articles specially adapted to be worn around the waist, e.g. diapers with faecal cavity

Definitions

  • the present invention relates to absorbent articles, such as diapers or incontinence guards, which seal more effectively against the wearer than earlier known articles of
  • An absorbent article of the kind to which the invention relates comp ⁇ ses a liquid- ltnpermeable sheet which is intended to lie distal from the wearer in use, an absorbent body, and an upper liquid-permeable sheet which is intended to lie proximal to the wearer in use
  • the absorbent article When the absorbent article is a diaper or an incontinence guard it will also include flexible side flaps or wings that extend laterally outside the absorbent body on both sides thereof, and elastic elements that extend longitudinally along the free side-edges of the side-flaps at least within that part which is intended to form the crotch part of the article in use, said side flaps and elastic elements functioning to enable the absorbent article to be fitted to the wearer
  • These elastic elements function as leg elastic when the article is worn Thus, when the article is donned, the elastic elements will be stretched and hold the side flaps tightly against the wearer
  • cu ⁇ ently available absorbent articles may include along the outer longitudinal edges of the article sealing edges that are intended to lie tightly around the wearer ' s thighs and to shape the article to the wearer ' s body, as well as a pair of inner cuffs or liquid barriers which lie inwardly of the outer longitudinal edges and which are intended to form an impervious barrier against rapidly discharged liquid that is not absorbed immediately by the absorbent body of said article.
  • inner cuffs shall thus be capable of withstanding a relatively high liquid pressure over a limited time period in the order of a minute or so. The liquid will have been absorbed by the absorbent body when this time period has passed.
  • Side cuffs may also be used on sanitary napkins, for instance.
  • articles which include transverse cuffs that seal-off the transverse edges of the absorbent body.
  • absorbent articles which include a liquid-impermeable sheet that is intended to lie proximal to the wearer in use and that incorporate elastic threads for shaping the article to the wearer's body.
  • This liquid-impermeable sheet includes at least one aperture which is intended to register with the wearer ' s anus and urethra o ⁇ fice when the article is donned.
  • Elastic is provided around at least a part of the perimeter of the aperture or apertures so as to shape the edges of the aperture against the wearer and to form a seal.
  • an absorbent body which is enclosed between a liquid-permeable sheet and a liquid- impermeable sheet, such that the absorbent body will hang down beneath the wearer with the liquid-impermeable sheet lying distal from the wearer.
  • the inner cuffs are comprised partly of a thin barrier sheet of essentially liquid- impervious and inelastic material, e.g. nonwoven material, and an elastic device which puckers or gathers together that edge of the liquid barrier which lies against the wearer.
  • the unresilient inelastic material is fastened along one longitudinal edge either to the top liquid-permeable sheet, so that no liquid can pass between these two sheets, or to the bottom liquid-impervious sheet along the side-edge of the article.
  • the elastic device is fastened along the other edge of the unresilient material so as to gather the liquid barrier together and therewith form a puckered edge, which will extend or stretch partially when the article is donned.
  • the puckered edge is normally comprised of an elastic thread which is placed in a channel in the inelastic material, said channel being formed by folding over and welding one edge of the material.
  • the puckered edge will stretch partially, the extent of this stretch being dependent on the size of the wearer and how the article is donned.
  • an elastic element consisting of an elastic film.
  • the elastic element will not be enclosed in a channel, but will be fastened, in a prestretched state, along a first longitudinal side-edge against the other side-edge of the unresilient material, the second side-edge of the element being free and abutting the wearer when the article is donned.
  • the first longitudinal side-edge of the elastic film may be fastened, in a prestretched state, directly against the top liquid-permeable sheet or the bottom liquid-impermeable sheet.
  • the barriers will consist of solely the elastic film.
  • Figs. 1 a, b illustrate the measuring equipment used to determine the leakage pressure or breakthrough pressure without any material applied and with material applied in a stretched state, respectively, and 1 c is a principle illustration of how the leakage pressure is determined;
  • Figs. 2a, b illustrate schematically a pore in a liquid barrier and the principle of determining the weighted mean value cos ⁇ m and determining the radius r;
  • Figs. 3a, b illustrate a conventional diaper or incontinence guard with upstanding liquid barriers
  • Figs. 4a,b illustrate the principle in which the available elongation or stretch is calculated
  • Fig. 5a is a graphic illustration showing the measured breakthrough pressures for three different liquid barriers
  • Fig. 5b is a comparison diagram illustrating calculated and measured breakthrough pressures, respectively, for the best liquid barrier in Fig. 5a at different available degrees of elongation or stretch;
  • Fig. 6 illustrates the measured breakthrough pressure of a conventional upstanding liquid barrier and of two inventive embodiments
  • Fig. 7 is a comparison diagram illustrating calculated and measured breakthrough pressures at different available elongations for one of the embodiments of the invention shown in Figure 6;
  • Figs. 8-13 are reproductions of photographs of different liquid barriers at different available elongations, taken with the aid of an electron microscope;
  • Figs. 8a-12a are views co ⁇ esponding to the photograph reproductions in Figs. 8-12.
  • An absorbent article such as a diaper, is manufactured so that it can be used by persons of different sizes. This is achieved by gathering together, or puckering, liquid barriers and side-edges with the aid of elastic. These liquid barriers and side-edges will stretch to different extents in accordance with the size of the wearer, and the tension around the barrier edge will thus vary in dependence on the size of the wearer.
  • Tension in the barrier elastic can be expected to have significance in studies on the sealing property of a liquid barrier, and consequently the extent to which the barrier is stretched will also be significant.
  • the term available elongation or stretch can be used when considering the extent to which a liquid barrier is stretched.
  • the elastic material which has a given degree of stretchability, is fastened and "locked" firmly to the other non- stretchable materials, normally nonwoven.
  • the extent to which the elastic material is stretched in the manufacture of the article cannot be exceeded when the article is in use, since the elastic material is firmly locked to a non-stretchable material. This is shown in Figure 4a.
  • the elastic material has the length L at this point.
  • a diaper is puckered somewhat when placed on the wearer ' s body.
  • the elastic material has then been contracted to the smaller length Lx.
  • Test equipment was constructed with the intention of studying the sealing effect achieved between a liquid barrier or some other puckered barrier and the wearer's skin.
  • This equipment is shown in Figs, l a, lb and lc and comprises a Plexiglas stand which includes a base plate a and an upstanding support plate b.
  • a first upwardly open, semi- cylindrical element 1 is fastened horizontally to the upstanding support plate b and has around its periphery a scale which denotes the available elongation or stretch.
  • One end of the semi-cylindrical element is attached to the support plate while the other end has an end- wall 1 '.
  • the equipment also includes a loose second semi-cylindrical element 5 whose diameter is somewhat larger than the diameter of the first semi-cylindrical element 1 and which has one side open and an end- wall 5' at its other end.
  • a measuring operation is carried out by securing a liquid barrier around the outer periphery of the first semi-cylindrical element and fastening said barrier around the upper edges.
  • the elastic part 7 is directed towards the attachment of the semi-cylindrical element to the support plate b, and the liquid barrier material is folded around the end- wall 1' of the first semi-cylindrical element 1 on the other side.
  • the elastic part is fastened along the scale on the semi-cylindrical element so as to enable the available elongation or stretch to be read-off
  • the end-wall 5' of the second semi -cylindrical element 5 is placed against the end-wall 1' of the first semi-cylindrical element with said upfolded part of said barrier material located therebetween and pressed thereagainst with the aid of a clamp 10, such as to obtain a small clearance 9 between the cylindrical walls.
  • Synthetic urine is introduced through the vertical tube 3.
  • the liquid barrier is first weighted down so as to fill the clearance between the semi- cylindrical elements.
  • a liquid pressure is thereafter built-up against the elastic edge 7 at the same time as a liquid column is formed in the tubes 3, 4, where the pressure can be read-off Liquid is introduced until leakage occurs at a ⁇ ow B (Fig. lc) at the breakthrough pressure.
  • the invention takes as its starting point an attempt to provide an improved sealing effect on the basis of factors other than the actual tension in the elastic.
  • the capillary pressure of the pores in porous structures can be calculated with the Laplace equation.
  • the capillary pressure ⁇ P 2 ⁇ cos ⁇ /r, where ⁇ is the surface tension of the liquid, ⁇ is the wetting angle of the liquid to the material in the capillary walls, and r is the radius of the capillary.
  • is the surface tension of the liquid
  • is the wetting angle of the liquid to the material in the capillary walls
  • r is the radius of the capillary.
  • the capillary wall is hydrophobic and the resultant pressure ⁇ P can be said to describe the breakthrough pressure, i.e. the maximum pressure a capillary or pore can withstand.
  • the capillary wall is hydrophilic and ⁇ P and cos ⁇ are positive. Liquid is then "sucked" into the pores.
  • the walls of the pores consist partly of an hydrophilic material, i.e. skin, which has a wetting angle of less than 90°, and partly of the hydrophobic material in the liquid barrier, which has a wetting angle above 90°.
  • Cos ⁇ m will there equal A-cos ⁇ f0b + B-cos ⁇ fil .
  • the wetting angle of the skin varies in accordance with the state of the skin, i.e. whether the skin is clean or dirty for instance.
  • Measuring equipment comprised of Plexiglas with a wetting angle of 77°, which lies close to the mean value of the wetting angle of the skin (about 74°), was used for comparison purposes. Measurement were carried out on the commercial liquid barrier that produced the best sealing result according to Fig. 5a, i.e. Huggies standing gather which has a wetting angle of 120°.
  • the liquid used was synthetic urine, ⁇ is the surface tension of synthetic urine, i.e. 0.06 N/m.
  • the through-penetrating pore has been drawn in Figs. 8a- 12a.
  • the following pore- radius values were obtained at different available elongations, as shown in the Figures.
  • Figs. 8a-12a show the lateral terminal points of the pore intended for calculating the hydrophobic and hydrophilic proportions of circumference of the pore.
  • the length ratio between hydrophobic and hydrophilic surfaces in the pore at different available elongations is shown in the following Table.
  • Fig. 5b shows a comparison between the breakthrough pressures measured with the test equipment and the breakthrough pressures calculated with the aforesaid formula.
  • the sealing effect of an article against the wearer ' s skin can, thus, be improved by influencing I ⁇ P
  • i.e. I 2 ⁇ cos ⁇ m/r
  • the tension in the elastic will be sufficiently high to prevent the liquid barrier from allowing liquid to escape at a lower pressure as a result of the elastic relaxing and allowing the barrier to "ease" away from the wearer by virtue of the liquid column weighing down the barrier so that it releases its contact with the abutment surface.
  • can be caused to increase by increasing the product I (2 ⁇ cos ⁇ m/r)
  • the object of the present invention is to provide an absorbent article with improved sealing against the wearer ' s skin.
  • an absorbent article such as a diaper or an incontinence guard that includes a liquid-impermeable sheet which is intended to lie distal from the wearer in use, an upper liquid-permeable sheet which is intended to lie proximal to the wearer in use, an absorbent body disposed between said sheets, and on each side of the longitudinally extending center line of the liquid-permeable sheet at least one longitudinal elastic liquid barrier comprised of an essentially liquid-impervious material, where one longitudinal edge is free and faces towards the wearer and the other longitudinal edge is fastened to the upper liquid-permeable sheet along the longitudinal edge of the article or to the liquid-impermeable sheet at the longitudinal edge of said article, wherein at least the free edge of at least one liquid barrier on each side of the center line of the absorbent body is treated with a non-adhesive sealing medium which, in use, at least partly fills any through-penetrating pore formed between the free edge of the liquid barrier and the user abutment surface and/or which, when
  • an absorbent article that includes an essentially liquid impermeable sheet which is intended to lie proximal to the wearer in use and which incorporates elastic for shaping the article to the wearer's body, said sheet including an aperture which is intended to lie in register with the anus and urethra o ⁇ fice of a wearer, wherein elastically gathered sealing edges are disposed around said apertures in the essentially liquid-impermeable sheet, wherein an absorbent body is disposed on that side of the essentially liquid-impermeable sheet that lies distal to the wearer in use, wherein the absorbent body is enclosed between a liquid-permeable sheet on the side proximal to the wearer and a liquid-impermeable sheet, wherein at least one sealing edge is treated with a non-adhesive sealing medium which, in use, at least partly fills out any through-penetrating pore formed between the free sealing edge and the abutment surface on a wearer, and/or which, when
  • the edge of the liquid barrier or the sealing edge will conveniently be coated with sealing medium in an amount sufficient to both partly fill out the pores, i.e. decrease the pore radius, and to smear the skin of a wearer.
  • the sealing medium may be applied in a very thin layer, intended to be transferred to the wearer ' s skin when donning the article.
  • the sealing medium will suitably be applied in an amount sufficient to reduce the pore radius and to smear the wearer's skin.
  • the sealing medium may be applied in an amount corresponding to 0.1-100 g m 2 , suitably 1-30 g/m 2 , particularly 2-20 g/m 2 and preferably 3-10 g/m 2 .
  • the sealing medium may be applied in an amount co ⁇ esponding to about 20 g/m 2 .
  • the skin is hydrophilic and has a mean wetting angle of about 74°, it is suitable for the sealing medium to at least increase this wetting angle to about 90°, so that the skin will be hydrophobic.
  • the sealing medium will preferably have a wetting angle above 95°, and then particularly of at least 100°.
  • the sealing medium will preferably have rheological properties such as to be essentially rigid or viscous at room temperature, and sufficiently fluid to smear the wearer ' s skin at body temperature.
  • the sealing medium may not be so fluid as to run from the wearer ' s skin at body temperature and dirty the wearer's clothes. Neither should the sealing medium be excessively rigid at room temperature, since it would then be able to loosen from the liquid barrier or the sealing edge in lumps or "crumbs". The person skilled in this art will be able to determine after laboratory testing which sealing media that have appropriate rheological properties.
  • the sealing medium needing to have the correct viscosity and flow properties required to fill-out cavities, have the co ⁇ ect surface energy for the liquid barrier function, it will also preferably be unable to penetrate the skin or to emit harmful substances or have any other negative effect on the normal function of the skin. Neither may the properties of the sealing medium change in the passage of time.
  • the sealing medium will also preferably contribute towards reducing friction against and/or wearing of the skin.
  • ointments that include fat/oil of animal, vegetable or petrochemical origin.
  • examples of such ointments are Silonsalva (Perstorp Pharma), petrolatum (Vaseline ®).
  • sealing media are, for instance, preparations which are se isolid or solid at 20°C and which comprise 10-95% of a polysiloxane plastiziser that has a plastic or flowing consistency at 20°C, and 5-90%, preferably 5-50% of an agent that can cause the plastiziser to solidify on the barrier, said agent suitably having a melting point of at least 35°C, preferably at least 40°C, and consisting of fatty acid esters or fatty acid amides having several hydroxyl groups, fatty alcohols having 14-22 carbon atoms, fatty acids having 12-22 carbon atoms, fatty alcohol ethoxylates having 12-22 carbon atoms, or a mixture thereof.
  • Suitable sealing media are described in WO 96/16681.
  • the sealing medium used must be dermatologically acceptable and may not cause irritation or allergical reactions.
  • One advantage of the inventive article is that it will slide more readily against the wearer's skin and therewith cause less irritation than conventional articles of this kind.
  • Fig. 3a shows a conventional diaper or incontinence guard 20 which includes a liquid- permeable top sheef 22, an absorbent sheet 23, and a liquid-impermeable bottom sheet 21 , said sheets being delimited by two transverse edges 24, 25 and two longitudinal edges 26, 27.
  • the illustrated article also includes longitudinally extending leg elastic 28 and an upstanding liquid barrier 29 on each side of the longitudinal center line.
  • Fig. 3b is a sectional view that illustrates the construction of the upstanding liquid barrier comprising a liquid-impermeable sheet 12 whose free edge is curved around two stretched elastic threads 13. The threads 13 function to pucker the sheet 12.
  • the wetting angle was changed in two tests.
  • a plastic film having a wetting angle of 97.5° was stretched over the first semi-cylindrical Plexiglas surface. This co ⁇ esponds to such a treatment of the barrier that the wearer's skin will obtain a higher wetting angle therefrom.
  • This is hydrophobic in distinction to the normal skin mean wetting angle of about 74°.
  • the result of this change in wetting angle (center curve) is compared in Fig. 6 with the sealing effect achieved with the upstanding liquid barrier Huggies standing gather (lowermost curve). As the measuring values show, an improved sealing effect is achieved in this way.
  • the uppermost curve in Fig. 6 shows measurements obtained with a liquid barrier that had been treated with Vaseline®.
  • Vaseline® has a wetting angle of 100°.
  • the Vaseline® partially blocks the pores, i.e. reduces the pore radius, and smears the wearer's skin, thereby increasing the wetting angle of the skin.
  • Fig. 6a there is obtained a significant improvement that exceeds the improvement achieved when only the wetting angle of the skin is changed, despite obtaining, at the same time, a reduction in the wetting angle of the barrier by virtue of the Vaseline® also smearing the liquid barrier and therewith lowering its wetting angle from 120° to 100°.
  • Fig. 7 is a diagram in which the calculated and measured sealing values obtained when changing the wetting angle are shown.
  • the measured values have been obtained by cove ⁇ ng the Plexiglas with the aforedescribed plastic film, and corresponds to the centre curve in the diagram shown in Fig. 6. Good agreement is obtained between the calculated and measured values.
  • Figure 13 is a reproduction of an electron microscope photograph of a liquid barrier that has an available elongation or stretch of 30%, where the barrier material is coated with Vaseline®.
  • This sealing medium has the sealing properties shown in the diagram of Fig. 6. It will be evident from the photograph that the fibers in the barrier material have a thick coating which increases the diameter of the fibers and thereby reduces the size of through-penetrating pores.
  • the outer barriers i.e. the leg elastic
  • Both the inner and the outer barriers can also be treated in accordance with the present invention. In certain instances it may be beneficial to treat solely the outer barriers, even when the article includes inner liquid barriers.
  • Transverse liquid barriers may also be treated with a sealing medium.

Abstract

An oblong absorbent article that includes a liquid-impermeable bottom sheet, and upper liquid-permeable sheet and an absorbent body disposed between these sheets, and on each side of the longitudinal center line of the upper sheet at least one longitudinal elastic liquid barrier having at least the free edge treated with a non-adhesive sealing medium which partly fills out the pores formed between the free edge and the abutment surface on the wearer, and/or which, when the article is donned, increases, around said abutment surface, the wetting angle of the liquid to the skin. An absorbent article that includes an essentially liquid-impermeable top sheet above an absorbent body enclosed between an upper liquid-permeable sheet and a liquid-impermeable sheet, the top sheet being provided with elastic for shaping the article to the wearer's body and incorporating apertures intended to register with the anus and the urethra orifice of a wearer in use, around which apertures elastically puckered sealing edges are disposed, at least one sealing edge being coated with a sealing medium.

Description

An absorbent article incorporating liquid barriers with sealing coating
The present invention relates to absorbent articles, such as diapers or incontinence guards, which seal more effectively against the wearer than earlier known articles of
An absorbent article of the kind to which the invention relates compπses a liquid- ltnpermeable sheet which is intended to lie distal from the wearer in use, an absorbent body, and an upper liquid-permeable sheet which is intended to lie proximal to the wearer in use When the absorbent article is a diaper or an incontinence guard it will also include flexible side flaps or wings that extend laterally outside the absorbent body on both sides thereof, and elastic elements that extend longitudinally along the free side-edges of the side-flaps at least within that part which is intended to form the crotch part of the article in use, said side flaps and elastic elements functioning to enable the absorbent article to be fitted to the wearer These elastic elements function as leg elastic when the article is worn Thus, when the article is donned, the elastic elements will be stretched and hold the side flaps tightly against the wearer
Currentlv available absorbent articles have very high absorbencies and can also retain liquid under pressure The most seπous problem occur in the event of rapid liquid discharges In such cases, it is necessary for a large volume of liquid to pass first through the top liquid-permeable sheet and then be absorbed by and dispersed in the absorbent body This does not take place instantaneously The time taken for the liquid to pass through the top sheet may be from about 1 to 2 minutes, during which time liquid will run out to the edges of the article and leak therefrom These problems are addressed with the aid of so-called liquid barriers or inner cuffs or side-flaps that are intended to resist liquid leakage in the event of rapid liquid discharges The originally used cuffs where intended pπmaπly to retain faeces and were formed by folding a part of the liquid-permeable top sheet around an elastic thread. In recent times, manufacturers have begun to produce the cuffs from a liquid-impervious material in order to also retain liquid.
When the leg elastic on the absorbent article is stretched and the article fastened on the wearer, the elastic element of the liquid barriers will also be stretched, thereby raising the barriers up. The elastic element of the barriers will hold the barrier edges under tension against the wearer. The upstanding liquid barriers then form beneath the wearer a "trough" in which a rapidly discharged large volume of urine can be accommodated during the time required for the liquid to pass through the top liquid-permeable sheet. Attempts to improve the effectiveness of such liquid barriers have hitherto been directed towards the use of denser materials and towards flaps of sufficiently large size.
One drawback, however, is that liquid will rise above the brim of the barriers and leak out when the volume of liquid discharged is excessive or when the wearer sits or lies down such as to press together the space between the upstanding liquid barriers.
Thus, cuπently available absorbent articles, such as diapers or incontinence guards, may include along the outer longitudinal edges of the article sealing edges that are intended to lie tightly around the wearer's thighs and to shape the article to the wearer's body, as well as a pair of inner cuffs or liquid barriers which lie inwardly of the outer longitudinal edges and which are intended to form an impervious barrier against rapidly discharged liquid that is not absorbed immediately by the absorbent body of said article. These inner cuffs shall thus be capable of withstanding a relatively high liquid pressure over a limited time period in the order of a minute or so. The liquid will have been absorbed by the absorbent body when this time period has passed. Side cuffs may also be used on sanitary napkins, for instance. Also available are articles which include transverse cuffs that seal-off the transverse edges of the absorbent body.
Absorbent articles which lack the aforedescribed inner liquid barriers are also available. In these cases, the outer longitudinal sealing edges form the sole liquid barriers of the absorbent body.
Also available are absorbent articles which include a liquid-impermeable sheet that is intended to lie proximal to the wearer in use and that incorporate elastic threads for shaping the article to the wearer's body. This liquid-impermeable sheet includes at least one aperture which is intended to register with the wearer's anus and urethra oπfice when the article is donned. Elastic is provided around at least a part of the perimeter of the aperture or apertures so as to shape the edges of the aperture against the wearer and to form a seal. Situated beneath the liquid-impermeable sheet is an absorbent body which is enclosed between a liquid-permeable sheet and a liquid- impermeable sheet, such that the absorbent body will hang down beneath the wearer with the liquid-impermeable sheet lying distal from the wearer.
The inner cuffs are comprised partly of a thin barrier sheet of essentially liquid- impervious and inelastic material, e.g. nonwoven material, and an elastic device which puckers or gathers together that edge of the liquid barrier which lies against the wearer. The unresilient inelastic material is fastened along one longitudinal edge either to the top liquid-permeable sheet, so that no liquid can pass between these two sheets, or to the bottom liquid-impervious sheet along the side-edge of the article. The elastic device is fastened along the other edge of the unresilient material so as to gather the liquid barrier together and therewith form a puckered edge, which will extend or stretch partially when the article is donned. The puckered edge is normally comprised of an elastic thread which is placed in a channel in the inelastic material, said channel being formed by folding over and welding one edge of the material. When the absorbent article is donned, the puckered edge will stretch partially, the extent of this stretch being dependent on the size of the wearer and how the article is donned. It is also possible to use an elastic element consisting of an elastic film. In this case the elastic element will not be enclosed in a channel, but will be fastened, in a prestretched state, along a first longitudinal side-edge against the other side-edge of the unresilient material, the second side-edge of the element being free and abutting the wearer when the article is donned. Further, the first longitudinal side-edge of the elastic film may be fastened, in a prestretched state, directly against the top liquid-permeable sheet or the bottom liquid-impermeable sheet. In this case, the barriers will consist of solely the elastic film.
The invention will now be described with reference to the accompanying drawings, in which
Figs. 1 a, b illustrate the measuring equipment used to determine the leakage pressure or breakthrough pressure without any material applied and with material applied in a stretched state, respectively, and 1 c is a principle illustration of how the leakage pressure is determined;
Figs. 2a, b illustrate schematically a pore in a liquid barrier and the principle of determining the weighted mean value cos θm and determining the radius r;
Figs. 3a, b illustrate a conventional diaper or incontinence guard with upstanding liquid barriers;
Figs. 4a,b illustrate the principle in which the available elongation or stretch is calculated; Fig. 5a is a graphic illustration showing the measured breakthrough pressures for three different liquid barriers;
Fig. 5b is a comparison diagram illustrating calculated and measured breakthrough pressures, respectively, for the best liquid barrier in Fig. 5a at different available degrees of elongation or stretch;
Fig. 6 illustrates the measured breakthrough pressure of a conventional upstanding liquid barrier and of two inventive embodiments;
Fig. 7 is a comparison diagram illustrating calculated and measured breakthrough pressures at different available elongations for one of the embodiments of the invention shown in Figure 6;
Figs. 8-13 are reproductions of photographs of different liquid barriers at different available elongations, taken with the aid of an electron microscope; and
Figs. 8a-12a are views coπesponding to the photograph reproductions in Figs. 8-12.
An absorbent article, such as a diaper, is manufactured so that it can be used by persons of different sizes. This is achieved by gathering together, or puckering, liquid barriers and side-edges with the aid of elastic. These liquid barriers and side-edges will stretch to different extents in accordance with the size of the wearer, and the tension around the barrier edge will thus vary in dependence on the size of the wearer.
Tension in the barrier elastic can be expected to have significance in studies on the sealing property of a liquid barrier, and consequently the extent to which the barrier is stretched will also be significant. The term available elongation or stretch can be used when considering the extent to which a liquid barrier is stretched.
In the manufacture of the absorbent article, e.g. a diaper, the elastic material, which has a given degree of stretchability, is fastened and "locked" firmly to the other non- stretchable materials, normally nonwoven. The extent to which the elastic material is stretched in the manufacture of the article cannot be exceeded when the article is in use, since the elastic material is firmly locked to a non-stretchable material. This is shown in Figure 4a. The elastic material has the length L at this point.
A diaper is puckered somewhat when placed on the wearer's body. The elastic material has then been contracted to the smaller length Lx.
The available stretch or elongation X is the extent to which the material can be stretched from the user state to the maximum stretched state of the product. This can be expressed by the formula: L =Lx ((X/100) + 1), where X is the available stretch or elongation in percent.
Test equipment was constructed with the intention of studying the sealing effect achieved between a liquid barrier or some other puckered barrier and the wearer's skin. This equipment is shown in Figs, l a, lb and lc and comprises a Plexiglas stand which includes a base plate a and an upstanding support plate b. A first upwardly open, semi- cylindrical element 1 is fastened horizontally to the upstanding support plate b and has around its periphery a scale which denotes the available elongation or stretch. One end of the semi-cylindrical element is attached to the support plate while the other end has an end- wall 1 '. Provided at the very bottom of the semi-cylindrical element 1 is a hole 2 to which a vertically upstanding filling tube 3 and an inclined measuring tube 4 lead, both of said tubes having a scale expressed in mm water. The equipment also includes a loose second semi-cylindrical element 5 whose diameter is somewhat larger than the diameter of the first semi-cylindrical element 1 and which has one side open and an end- wall 5' at its other end.
As shown in Fig. lb, a measuring operation is carried out by securing a liquid barrier around the outer periphery of the first semi-cylindrical element and fastening said barrier around the upper edges. The elastic part 7 is directed towards the attachment of the semi-cylindrical element to the support plate b, and the liquid barrier material is folded around the end- wall 1' of the first semi-cylindrical element 1 on the other side. The elastic part is fastened along the scale on the semi-cylindrical element so as to enable the available elongation or stretch to be read-off The end-wall 5' of the second semi -cylindrical element 5 is placed against the end-wall 1' of the first semi-cylindrical element with said upfolded part of said barrier material located therebetween and pressed thereagainst with the aid of a clamp 10, such as to obtain a small clearance 9 between the cylindrical walls. Synthetic urine is introduced through the vertical tube 3. The liquid barrier is first weighted down so as to fill the clearance between the semi- cylindrical elements. A liquid pressure is thereafter built-up against the elastic edge 7 at the same time as a liquid column is formed in the tubes 3, 4, where the pressure can be read-off Liquid is introduced until leakage occurs at aπow B (Fig. lc) at the breakthrough pressure.
Two available types of liquid barriers, Huggies standing gather and Pampers standing gather, and a liquid barrier still not in production, Peaudouce leg elastic, were studied with this equipment, the leakage tendency being measured with the elastic element stretched to and locked at different available elongations. The liquid pressure at which leakage will occur in respect of a barrier stretched to a given extent, i.e. a barrier that has a given available elongation or stretch, has been determined with the aid of the test equipment and was found to vary in dependence on the extent to which the puckered or gathered edge is stretched. The measured values are shown in the diagram in Fig. 5a. As will be evident from the Figure, however, different barriers give different breakthrough pressures at the same available stretch or elongation. It thus appears that the sealing effect is influenced by factors other than solely the tension in the elastic material.
The invention takes as its starting point an attempt to provide an improved sealing effect on the basis of factors other than the actual tension in the elastic.
On the basis of the theory that leakage does not occur merely because the elastic in the barrier material releases its contact with the wearer's skin, but occurs primarily through the through-penetrating pores or channels that are formed between the wearer's skin and the folds in the puckered or gathered edge of the barrier material, endeavors have been made to create a model from which the leakage pressure can be determined theoretically and thereby become aware of those parameters that shall be influenced in order to achieve an improved sealing effect.
The capillary pressure of the pores in porous structures can be calculated with the Laplace equation.
According to Laplace, the capillary pressure ΔP = 2γ cosθ/r, where γ is the surface tension of the liquid, θ is the wetting angle of the liquid to the material in the capillary walls, and r is the radius of the capillary. When θ is greater than 90°, cosθ is negative and ΔP is consequently also negative. The capillary wall is hydrophobic and the resultant pressure ΔP can be said to describe the breakthrough pressure, i.e. the maximum pressure a capillary or pore can withstand. When θ is less than 90°, the capillary wall is hydrophilic and ΔP and cosθ are positive. Liquid is then "sucked" into the pores.
When studying the -pressure in a capillary or pore where the wall consists of several materials, such as in a pore formed between skin and a fold in a liquid barrier, the proportion of circumference of each material must be weighed together so as to provide a mean value of cosθ, hereinafter designated cosθm. The breakthrough pressure will then be ΔP = 2γ cosθm/r.
In the present case, the walls of the pores consist partly of an hydrophilic material, i.e. skin, which has a wetting angle of less than 90°, and partly of the hydrophobic material in the liquid barrier, which has a wetting angle above 90°. Cosθm is the weighted mean value of the pore wall's cosθ-values and is calculated in the manner illustrated in Fig. 2a, where A designates the circumference proportion hydrophobic wall and B designates the circumference proportion hydrophilic wall, where A + B = 1. Cosθm will there equal A-cosθf0b + B-cosθfil.
As described below, trials have been carried out with the intention of checking whether or not the described model can be used as a basis on which the breakthrough pressure can be determined.
The wetting angle of the skin varies in accordance with the state of the skin, i.e. whether the skin is clean or dirty for instance. Measuring equipment comprised of Plexiglas with a wetting angle of 77°, which lies close to the mean value of the wetting angle of the skin (about 74°), was used for comparison purposes. Measurement were carried out on the commercial liquid barrier that produced the best sealing result according to Fig. 5a, i.e. Huggies standing gather which has a wetting angle of 120°. The liquid used was synthetic urine, γ is the surface tension of synthetic urine, i.e. 0.06 N/m.
Abutment of a liquid barrier against the measuring equipment was studied at different available elongations with an electron microscope, enlargement 130 times, as illustrated in Figs. 8-12 and Figs. 8a-12a. As will be evident from the Figures, a through-penetrating pore is formed between the threads or fibres of the barrier material and the Plexiglas wall of the test equipment. This pore is assumed to function as a capillary, where r = the radius of the largest possible circle that can be enclosed in the channel, as evident from Fig. 2b.
The through-penetrating pore has been drawn in Figs. 8a- 12a. The following pore- radius values were obtained at different available elongations, as shown in the Figures.
Figure imgf000012_0001
Comments: It was very difficult to measure the pore radius on the photograph at a 10% available elongation, and the value given is therefore perhaps unreliable.
The crosses shown in Figs. 8a-12a show the lateral terminal points of the pore intended for calculating the hydrophobic and hydrophilic proportions of circumference of the pore. The length ratio between hydrophobic and hydrophilic surfaces in the pore at different available elongations is shown in the following Table.
Figure imgf000013_0001
Fig. 5b shows a comparison between the breakthrough pressures mesured with the test equipment and the breakthrough pressures calculated with the aforesaid formula.
Since the calculated and measured breakthrough pressures are in good agreement, the sealing effect of an article against the wearer's skin can, thus, be improved by influencing I ΔP| , i.e. I 2γ cosθm/r)| so that this value increases. One provision in this respect is that the tension in the elastic will be sufficiently high to prevent the liquid barrier from allowing liquid to escape at a lower pressure as a result of the elastic relaxing and allowing the barrier to "ease" away from the wearer by virtue of the liquid column weighing down the barrier so that it releases its contact with the abutment surface.
I ΔP| can be caused to increase by increasing the product I (2γ cosθm/r)|
The object of the present invention is to provide an absorbent article with improved sealing against the wearer's skin.
This object is achieved with an absorbent article such as a diaper or an incontinence guard that includes a liquid-impermeable sheet which is intended to lie distal from the wearer in use, an upper liquid-permeable sheet which is intended to lie proximal to the wearer in use, an absorbent body disposed between said sheets, and on each side of the longitudinally extending center line of the liquid-permeable sheet at least one longitudinal elastic liquid barrier comprised of an essentially liquid-impervious material, where one longitudinal edge is free and faces towards the wearer and the other longitudinal edge is fastened to the upper liquid-permeable sheet along the longitudinal edge of the article or to the liquid-impermeable sheet at the longitudinal edge of said article, wherein at least the free edge of at least one liquid barrier on each side of the center line of the absorbent body is treated with a non-adhesive sealing medium which, in use, at least partly fills any through-penetrating pore formed between the free edge of the liquid barrier and the user abutment surface and/or which, when the article is donned, smears said abutment surface and thereby increases the wetting angle of the liquid to the skin.
The object of the invention is also achieved with an absorbent article that includes an essentially liquid impermeable sheet which is intended to lie proximal to the wearer in use and which incorporates elastic for shaping the article to the wearer's body, said sheet including an aperture which is intended to lie in register with the anus and urethra oπfice of a wearer, wherein elastically gathered sealing edges are disposed around said apertures in the essentially liquid-impermeable sheet, wherein an absorbent body is disposed on that side of the essentially liquid-impermeable sheet that lies distal to the wearer in use, wherein the absorbent body is enclosed between a liquid-permeable sheet on the side proximal to the wearer and a liquid-impermeable sheet, wherein at least one sealing edge is treated with a non-adhesive sealing medium which, in use, at least partly fills out any through-penetrating pore formed between the free sealing edge and the abutment surface on a wearer, and/or which, when the article is donned, smears said abutment surface and thereby increases the wetting angle of the liquid to the skin. When the non-adhesive sealing medium at least partly fills out a pore, the pore radius will decrease and the product |(2γ cosθm/r)| will increase. The same applies when an increased wetting angle is achieved.
The edge of the liquid barrier or the sealing edge will conveniently be coated with sealing medium in an amount sufficient to both partly fill out the pores, i.e. decrease the pore radius, and to smear the skin of a wearer.
The sealing medium may be applied in a very thin layer, intended to be transferred to the wearer's skin when donning the article. However, the sealing medium will suitably be applied in an amount sufficient to reduce the pore radius and to smear the wearer's skin. The sealing medium may be applied in an amount corresponding to 0.1-100 g m2, suitably 1-30 g/m2, particularly 2-20 g/m2 and preferably 3-10 g/m2. For instance, the sealing medium may be applied in an amount coπesponding to about 20 g/m2.
Since the skin is hydrophilic and has a mean wetting angle of about 74°, it is suitable for the sealing medium to at least increase this wetting angle to about 90°, so that the skin will be hydrophobic. The sealing medium will preferably have a wetting angle above 95°, and then particularly of at least 100°.
The sealing medium will preferably have rheological properties such as to be essentially rigid or viscous at room temperature, and sufficiently fluid to smear the wearer's skin at body temperature. The sealing medium may not be so fluid as to run from the wearer's skin at body temperature and dirty the wearer's clothes. Neither should the sealing medium be excessively rigid at room temperature, since it would then be able to loosen from the liquid barrier or the sealing edge in lumps or "crumbs". The person skilled in this art will be able to determine after laboratory testing which sealing media that have appropriate rheological properties. In addition to the sealing medium needing to have the correct viscosity and flow properties required to fill-out cavities, have the coπect surface energy for the liquid barrier function, it will also preferably be unable to penetrate the skin or to emit harmful substances or have any other negative effect on the normal function of the skin. Neither may the properties of the sealing medium change in the passage of time.
The sealing medium will also preferably contribute towards reducing friction against and/or wearing of the skin.
To this end there can be used ointments that include fat/oil of animal, vegetable or petrochemical origin. Examples of such ointments are Silonsalva (Perstorp Pharma), petrolatum (Vaseline ®).
It is also possible to use water/oil emulsions, which are hydrophobic.
Other possible sealing media are, for instance, preparations which are se isolid or solid at 20°C and which comprise 10-95% of a polysiloxane plastiziser that has a plastic or flowing consistency at 20°C, and 5-90%, preferably 5-50% of an agent that can cause the plastiziser to solidify on the barrier, said agent suitably having a melting point of at least 35°C, preferably at least 40°C, and consisting of fatty acid esters or fatty acid amides having several hydroxyl groups, fatty alcohols having 14-22 carbon atoms, fatty acids having 12-22 carbon atoms, fatty alcohol ethoxylates having 12-22 carbon atoms, or a mixture thereof. Suitable sealing media are described in WO 96/16681.
The sealing medium used must be dermatologically acceptable and may not cause irritation or allergical reactions. One advantage of the inventive article is that it will slide more readily against the wearer's skin and therewith cause less irritation than conventional articles of this kind.
The invention will now be described in more detail with reference to the particular embodiments thereof and also with reference to the accompanying drawings.
Example
Fig. 3a shows a conventional diaper or incontinence guard 20 which includes a liquid- permeable top sheef 22, an absorbent sheet 23, and a liquid-impermeable bottom sheet 21 , said sheets being delimited by two transverse edges 24, 25 and two longitudinal edges 26, 27. The illustrated article also includes longitudinally extending leg elastic 28 and an upstanding liquid barrier 29 on each side of the longitudinal center line. Fig. 3b is a sectional view that illustrates the construction of the upstanding liquid barrier comprising a liquid-impermeable sheet 12 whose free edge is curved around two stretched elastic threads 13. The threads 13 function to pucker the sheet 12.
The wetting angle was changed in two tests. In the first case, a plastic film having a wetting angle of 97.5° was stretched over the first semi-cylindrical Plexiglas surface. This coπesponds to such a treatment of the barrier that the wearer's skin will obtain a higher wetting angle therefrom. This is hydrophobic in distinction to the normal skin mean wetting angle of about 74°. The result of this change in wetting angle (center curve) is compared in Fig. 6 with the sealing effect achieved with the upstanding liquid barrier Huggies standing gather (lowermost curve). As the measuring values show, an improved sealing effect is achieved in this way.
The uppermost curve in Fig. 6 shows measurements obtained with a liquid barrier that had been treated with Vaseline®. Vaseline® has a wetting angle of 100°. The Vaseline® partially blocks the pores, i.e. reduces the pore radius, and smears the wearer's skin, thereby increasing the wetting angle of the skin. As will be evident from the diagram shown in Fig. 6a, there is obtained a significant improvement that exceeds the improvement achieved when only the wetting angle of the skin is changed, despite obtaining, at the same time, a reduction in the wetting angle of the barrier by virtue of the Vaseline® also smearing the liquid barrier and therewith lowering its wetting angle from 120° to 100°.
Fig. 7 is a diagram in which the calculated and measured sealing values obtained when changing the wetting angle are shown. The measured values have been obtained by coveπng the Plexiglas with the aforedescribed plastic film, and corresponds to the centre curve in the diagram shown in Fig. 6. Good agreement is obtained between the calculated and measured values.
Figure 13 is a reproduction of an electron microscope photograph of a liquid barrier that has an available elongation or stretch of 30%, where the barrier material is coated with Vaseline®. This sealing medium has the sealing properties shown in the diagram of Fig. 6. It will be evident from the photograph that the fibers in the barrier material have a thick coating which increases the diameter of the fibers and thereby reduces the size of through-penetrating pores.
Although the invention has been described above with reference to certain concrete, non-limiting embodiments, it will be understood that the invention can be modified within the scope of the following claims. Particularly the outer barriers, i.e. the leg elastic, of articles that have no inner liquid barriers can be treated with a sealing medium. Both the inner and the outer barriers can also be treated in accordance with the present invention. In certain instances it may be beneficial to treat solely the outer barriers, even when the article includes inner liquid barriers. Transverse liquid barriers may also be treated with a sealing medium.

Claims

Claims
1. An absorbent article that includes a liquid-impermeable sheet (21) which is intended to lie distal from the-wearer in use, an upper liquid-permeable sheet (22) which is intended to lie proximal to the wearer in use, an absorbent body (23) disposed between these sheets, which are delimited by two generally transverse edges (24,25) and two generally longitudinal edges (26,27), and on each side of the longitudinal center line of the liquid-permeable sheet at least one longitudinal elastic liquid barrier (29) which is comprised of an essentially liquid-impervious material (12), wherein one longitudinal edge is free and faces towards the wearer and the other longitudinal edge is fastened either to the upper liquid-permeable sheet (22) along the longitudinal edge (26,27) of the article or to the liquid-impermeable sheet (21) at the longitudinal edge (26,27) of said article, characterized in that at least the free edge of at least one liquid barrier (29) on each side of the longitudinal center line of the absorbent body is treated with a non-adhesive sealing medium which, in use, at least partly fills out any through- penetrating pore formed between the free edge of the liquid barrier and the abutment surface on the wearer, and/or which, when the article is donned, smears said abutment surface and thereby increases the wetting angle of the liquid to the skin.
2. An absorbent article that includes an essentially liquid-impermeable sheet which is intended to lie proximal to the wearer in use and which is provided with elastic for shaping the article to the wearer's body, wherein said sheet incorporates apertures which are intended to register with the anus and the urethra orifice of a wearer in use, wherein elastically puckered sealing edges are disposed in the essentially liquid- impermeable sheet around said apertures, wherein an absorbent body is disposed on that side of the essentially liquid-impermeable sheet that lies distal from the wearer in use, said absorbent body being enclosed between a liquid-permeable sheet on the side proximal to the wearer in use and a liquid-impermeable sheet, characterized in that at least one sealing edge is coated with a non-adhesive sealing medium which, in use, at least partly fills out any through-penetrating pore formed between the free sealing edge and the abutment surface on the wearer, and/or which, when the article is donned, smears said abutment surface and thereby increases the wetting angle of the liquid to the skin.
3. An absorbent article according to Claim 1 or 2, characterized in that the liquid barrier edge or the sealing edge is coated with the sealing medium in an amount sufficient to both partly fill out the pores and to smear the wearer's skin.
4. An absorbent article according to any one of Claims 1-3, characterized in that said sealing medium is applied in an amount corresponding to 0.1-100 g/m2, suitably
1 -30 g/m2, particularly 2-20 g/m2 and preferably 3-10 g/m2.
5. An absorbent article according to any one of Claims 1-4, characterized in that the sealing medium has a wetting angle above 90┬░, preferably above 95┬░, and then particularly of at least 100┬░.
6. An absorbent article according to any one of Claims 1 -5, characterized in that the rheological properties of the sealing medium are such that said medium will be essentially rigid and viscous at room temperature and sufficiently fluid to smear the skin of the wearer at body temperature.
7. An absorbent article according to any one of Claims 1 -6, characterized in that the sealing medium is an ointment that comprises fat or oil of animal, vegetable or petrochemical origin, or a water-in-oil emulsion.
PCT/SE1998/000339 1997-02-26 1998-02-25 An absorbent article incorporating liquid barriers with sealing coating WO1998037841A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AU63156/98A AU730098C (en) 1997-02-26 1998-02-25 An absorbent article incorporating liquid barriers with sealing coating
JP53757598A JP4211949B2 (en) 1997-02-26 1998-02-25 Absorbent article comprising a liquid barrier having a sealing coating
PL335255A PL193232B1 (en) 1997-02-26 1998-02-25 Absorptive article insorporating barier elements impermeable to liquids with a sealing coating
EP98907316A EP1005309B1 (en) 1997-02-26 1998-02-25 An absorbent article incorporating liquid barriers with sealing coating
DE69806940T DE69806940T2 (en) 1997-02-26 1998-02-25 AN ABSORBING ARTICLE PROVIDED WITH LIQUID BARRIERS WITH SEALING TOP LAYER
US09/380,211 US6817993B1 (en) 1997-02-26 1998-02-25 Absorbent article incorporating liquid barriers with sealing coating
DK98907316T DK1005309T3 (en) 1997-02-26 1998-02-25 An absorbent article having a liquid barrier with a sealing coating
CA002282487A CA2282487A1 (en) 1997-02-26 1998-02-25 An absorbent article incorporating liquid barriers with sealing coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9700696-9 1997-02-26
SE9700696A SE512826C2 (en) 1997-02-26 1997-02-26 Absorbent articles with liquid barrier with sealing coating

Publications (1)

Publication Number Publication Date
WO1998037841A1 true WO1998037841A1 (en) 1998-09-03

Family

ID=20405947

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1998/000339 WO1998037841A1 (en) 1997-02-26 1998-02-25 An absorbent article incorporating liquid barriers with sealing coating

Country Status (14)

Country Link
US (1) US6817993B1 (en)
EP (1) EP1005309B1 (en)
JP (1) JP4211949B2 (en)
KR (1) KR20000075551A (en)
AU (1) AU730098C (en)
CA (1) CA2282487A1 (en)
CO (1) CO5050360A1 (en)
DE (1) DE69806940T2 (en)
DK (1) DK1005309T3 (en)
ES (1) ES2182275T3 (en)
PL (1) PL193232B1 (en)
SE (1) SE512826C2 (en)
WO (1) WO1998037841A1 (en)
ZA (1) ZA981581B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5998695A (en) * 1998-06-29 1999-12-07 The Procter & Gamble Company Absorbent article including ionic complexing agent for feces
US6018093A (en) * 1998-06-29 2000-01-25 The Procter & Gamble Company Absorbent article including a calcium-based feces modification agent
WO2003045298A1 (en) * 2001-11-26 2003-06-05 The Procter & Gamble Company Wearable disposable article having a wetness sensation member
US6639119B2 (en) 1998-06-29 2003-10-28 The Procter & Gamble Company Absorbent article including a reducing agent for feces
US6817993B1 (en) 1997-02-26 2004-11-16 Sca Hygiene Products Ab Absorbent article incorporating liquid barriers with sealing coating
US7736350B2 (en) * 2002-12-30 2010-06-15 Kimberly-Clark Worldwide, Inc. Absorbent article with improved containment flaps

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7314967B2 (en) 2004-05-26 2008-01-01 The Procter & Gamble Company Moisture responsive sealing members in disposable absorbent articles
KR100779781B1 (en) * 2006-07-31 2007-11-27 대우조선해양 주식회사 Preparation of stl cone with coating layers and lng ship having the same
US20170246052A1 (en) 2016-02-25 2017-08-31 The Procter & Gamble Company Configurable absorbent articles
EP3423017A1 (en) 2016-03-01 2019-01-09 The Procter and Gamble Company Diaper adapted for collection of uncontaminated and intact stool sample from an infant
US11134925B2 (en) 2016-03-01 2021-10-05 The Procter & Gamble Company Diaper adapted for collection of urine sample from an infant
US11452646B2 (en) 2017-06-05 2022-09-27 The Procter & Gamble Company Configurable absorbent articles having improved bodily exudate visualization
US11135104B2 (en) 2017-06-27 2021-10-05 The Procter & Gamble Company Diaper product adapted for collection of exudate sample from an infant
US11246571B2 (en) 2017-06-27 2022-02-15 The Procter & Gamble Company Configurable absorbent articles having improved bodily exudate separation and sampling
US11399992B2 (en) 2017-08-24 2022-08-02 The Procter & Gamble Company Configurable absorbent articles having removable fastening members
US11730633B2 (en) 2019-02-21 2023-08-22 The Procter & Gamble Company Absorbent articles having fully removable fastening members

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995016424A1 (en) * 1993-12-14 1995-06-22 Kimberly-Clark Corporation Absorbent article having a body adhesive
US5445627A (en) * 1993-08-06 1995-08-29 Uni-Charm Corporation Sanitary napkin

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3906951A (en) 1974-08-05 1975-09-23 Squibb & Sons Inc Stomal device including means to prolong attachment of flange
MA21077A1 (en) * 1986-10-10 1988-07-01 Procter & Gamble ABSORBENT ARTICLE COMPRISING DOUBLE FLUID RESISTANT CUFFS.
JPH0231756A (en) 1988-07-22 1990-02-01 Kiyoko Iwasaki Article for preventing adhesion of stool to hip
CA1332860C (en) 1988-12-21 1994-11-08 Bret Alan Sims Absorbent article having inflected barrier cuffs
JPH084020Y2 (en) * 1991-04-10 1996-02-07 ユニ・チャーム株式会社 Disposable diapers
JP3084121B2 (en) * 1992-04-06 2000-09-04 ユニ・チャーム株式会社 Disposable diapers
JP3130367B2 (en) * 1992-04-17 2001-01-31 ユニ・チャーム株式会社 Method for forming an elastic opening in the topsheet of a disposable diaper
JP3130365B2 (en) 1992-04-30 2001-01-31 ユニ・チャーム株式会社 Disposable diaper having elastic opening in skin top sheet and method of forming the elastic opening
SE502549C2 (en) * 1994-03-18 1995-11-13 Moelnlycke Ab Absorbent article, such as a diaper, comprising an apertured top layer
US5635191A (en) 1994-11-28 1997-06-03 The Procter & Gamble Company Diaper having a lotioned topsheet containing a polysiloxane emollient
US6156024A (en) * 1996-12-03 2000-12-05 The Procter & Gamble Company Absorbent articles having lotioned leg cuffs
JPH08322877A (en) 1995-05-30 1996-12-10 Uni Charm Corp Throw-away body fluid absorbent wearing article
US5607760A (en) 1995-08-03 1997-03-04 The Procter & Gamble Company Disposable absorbent article having a lotioned topsheet containing an emollient and a polyol polyester immobilizing agent
US5669902A (en) * 1996-06-24 1997-09-23 Humanicare International, Inc. Incontinence garment in the form of boxer shorts
SE512826C2 (en) 1997-02-26 2000-05-22 Sca Hygiene Prod Ab Absorbent articles with liquid barrier with sealing coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5445627A (en) * 1993-08-06 1995-08-29 Uni-Charm Corporation Sanitary napkin
WO1995016424A1 (en) * 1993-12-14 1995-06-22 Kimberly-Clark Corporation Absorbent article having a body adhesive

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6817993B1 (en) 1997-02-26 2004-11-16 Sca Hygiene Products Ab Absorbent article incorporating liquid barriers with sealing coating
US5998695A (en) * 1998-06-29 1999-12-07 The Procter & Gamble Company Absorbent article including ionic complexing agent for feces
US6018093A (en) * 1998-06-29 2000-01-25 The Procter & Gamble Company Absorbent article including a calcium-based feces modification agent
US6639119B2 (en) 1998-06-29 2003-10-28 The Procter & Gamble Company Absorbent article including a reducing agent for feces
WO2003045298A1 (en) * 2001-11-26 2003-06-05 The Procter & Gamble Company Wearable disposable article having a wetness sensation member
US7736350B2 (en) * 2002-12-30 2010-06-15 Kimberly-Clark Worldwide, Inc. Absorbent article with improved containment flaps

Also Published As

Publication number Publication date
KR20000075551A (en) 2000-12-15
ZA981581B (en) 1998-09-01
JP2001513671A (en) 2001-09-04
SE512826C2 (en) 2000-05-22
AU730098B2 (en) 2001-02-22
JP4211949B2 (en) 2009-01-21
PL193232B1 (en) 2007-01-31
PL335255A1 (en) 2000-04-10
DE69806940D1 (en) 2002-09-05
ES2182275T3 (en) 2003-03-01
US6817993B1 (en) 2004-11-16
AU730098C (en) 2002-02-07
CO5050360A1 (en) 2001-06-27
EP1005309B1 (en) 2002-07-31
AU6315698A (en) 1998-09-18
EP1005309A1 (en) 2000-06-07
SE9700696L (en) 1998-08-27
DK1005309T3 (en) 2002-11-25
SE9700696D0 (en) 1997-02-26
CA2282487A1 (en) 1998-09-03
DE69806940T2 (en) 2003-02-06

Similar Documents

Publication Publication Date Title
AU730098C (en) An absorbent article incorporating liquid barriers with sealing coating
US4681579A (en) Absorbent article having reservoirs
CA1303794C (en) Absorbent article having floating inner cuffs
HUT72267A (en) Extensible absorbent article having less extensible barriers
PT101743B (en) ABSORBENT ARTICLE WITH ELASTIC LATERAL FINGERS
JP2004113783A (en) Absorptive article
BRPI0618832A2 (en) disposable absorbent article with barrier clamp strip
US5868725A (en) Absorbent article having a cushioning member and a barrier
US6103952A (en) Absorbent article
AU707067B2 (en) Absorbent article
KR100385269B1 (en) Absorbent Article Having an Integral Barrier
BRPI0618830A2 (en) disposable absorbent article with bottom layer strips
JP3205342B2 (en) Absorber with bolster waist
BR112019000600B1 (en) ABSORBENT ARTICLE
EP1005311B1 (en) An absorbent article that includes a liquid barrier with improved sealing
EP4159174A1 (en) Disposable diaper and method for producing same
TW391869B (en) An absorbent article incorporating liquid barriers with sealing coating
JPH0592023A (en) Absorptive article
MXPA97000328A (en) Absorbent article that has a member of coupling and a barr
MXPA99007459A (en) An absorbent article that includes a liquid barrier with improved sealing
NZ247474A (en) Disposable nappy with containment pocket
MXPA97000329A (en) Article absorb
MXPA99001393A (en) Absorbent article having a containment dam

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GE GH HU IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 1998907316

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 1019997007611

Country of ref document: KR

ENP Entry into the national phase

Ref document number: 2282487

Country of ref document: CA

Ref country code: CA

Ref document number: 2282487

Kind code of ref document: A

Format of ref document f/p: F

Ref country code: JP

Ref document number: 1998 537575

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 63156/98

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 09380211

Country of ref document: US

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 1998907316

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 1019997007611

Country of ref document: KR

WWG Wipo information: grant in national office

Ref document number: 63156/98

Country of ref document: AU

WWG Wipo information: grant in national office

Ref document number: 1998907316

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1019997007611

Country of ref document: KR