WO1998046712A1 - Gelled cleaning agent for flush toilets - Google Patents
Gelled cleaning agent for flush toilets Download PDFInfo
- Publication number
- WO1998046712A1 WO1998046712A1 PCT/EP1998/002123 EP9802123W WO9846712A1 WO 1998046712 A1 WO1998046712 A1 WO 1998046712A1 EP 9802123 W EP9802123 W EP 9802123W WO 9846712 A1 WO9846712 A1 WO 9846712A1
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- WO
- WIPO (PCT)
- Prior art keywords
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- amounts
- particularly preferably
- agents
- composition according
- Prior art date
Links
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- -1 scale preventives Substances 0.000 claims abstract description 26
- 239000000975 dye Substances 0.000 claims abstract description 25
- 150000004676 glycans Chemical class 0.000 claims abstract description 21
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 21
- 239000005017 polysaccharide Substances 0.000 claims abstract description 21
- 238000004140 cleaning Methods 0.000 claims abstract description 16
- 239000004615 ingredient Substances 0.000 claims abstract description 5
- 239000006096 absorbing agent Substances 0.000 claims abstract description 3
- 239000003381 stabilizer Substances 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 52
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 35
- 239000002304 perfume Substances 0.000 claims description 35
- 125000000217 alkyl group Chemical group 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 25
- 229920001285 xanthan gum Polymers 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 10
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 10
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 9
- 239000000230 xanthan gum Substances 0.000 claims description 9
- 235000010493 xanthan gum Nutrition 0.000 claims description 9
- 229940082509 xanthan gum Drugs 0.000 claims description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000008139 complexing agent Substances 0.000 claims description 5
- 230000002401 inhibitory effect Effects 0.000 claims description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003599 detergent Substances 0.000 claims description 3
- 230000002829 reductive effect Effects 0.000 claims description 3
- 150000003873 salicylate salts Chemical class 0.000 claims description 3
- 150000001558 benzoic acid derivatives Chemical class 0.000 claims description 2
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 2
- 239000003623 enhancer Substances 0.000 claims description 2
- 239000004310 lactic acid Substances 0.000 claims description 2
- 235000014655 lactic acid Nutrition 0.000 claims description 2
- 150000007522 mineralic acids Chemical class 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- 235000005985 organic acids Nutrition 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000000645 desinfectant Substances 0.000 abstract description 7
- 239000003205 fragrance Substances 0.000 abstract description 4
- 230000003449 preventive effect Effects 0.000 abstract 1
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 239000000499 gel Substances 0.000 description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 28
- 238000004519 manufacturing process Methods 0.000 description 18
- 239000003921 oil Substances 0.000 description 14
- 238000005191 phase separation Methods 0.000 description 14
- 238000003860 storage Methods 0.000 description 14
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
- 239000000194 fatty acid Substances 0.000 description 11
- 229930195729 fatty acid Natural products 0.000 description 11
- 150000002191 fatty alcohols Chemical class 0.000 description 11
- 150000004665 fatty acids Chemical class 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 8
- 238000011049 filling Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 235000002639 sodium chloride Nutrition 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 229920002125 Sokalan® Polymers 0.000 description 6
- 150000002170 ethers Chemical class 0.000 description 6
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229920000151 polyglycol Polymers 0.000 description 5
- 239000010695 polyglycol Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 241000207199 Citrus Species 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 239000004584 polyacrylic acid Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000000346 sugar Nutrition 0.000 description 3
- 150000008163 sugars Chemical class 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical group C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000004064 cosurfactant Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 2
- 229940038773 trisodium citrate Drugs 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- LCTONWCANYUPML-UHFFFAOYSA-M Pyruvate Chemical compound CC(=O)C([O-])=O LCTONWCANYUPML-UHFFFAOYSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 241000589636 Xanthomonas campestris Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- IAJILQKETJEXLJ-QTBDOELSSA-N aldehydo-D-glucuronic acid Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)C(O)=O IAJILQKETJEXLJ-QTBDOELSSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229940097043 glucuronic acid Drugs 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 235000011147 magnesium chloride Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- FFQQCJGNKKIRMD-UHFFFAOYSA-N methyl n-(3-hydroxyphenyl)carbamate Chemical compound COC(=O)NC1=CC=CC(O)=C1 FFQQCJGNKKIRMD-UHFFFAOYSA-N 0.000 description 1
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920001522 polyglycol ester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000009489 vacuum treatment Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
Definitions
- the present invention relates to a gel-type cleaning agent which can preferably be used in flush toilets.
- solid cleaning agents are used in piece form for automatically keeping toilets clean. These are either installed in the toilet bowl or in the water tank.
- the moldings are overflowed with water during each rinsing process, whereby they gradually dissolve and release their active cleaning ingredients during this time.
- These cleaning moldings usually contain additional perfume for room scenting or disinfectant agents for hygiene optimization.
- the piece-shaped detergent tablets described are partially applied in suitable containers with special refill options.
- the moldings described are generally produced by casting, pressing, extruding or granulating processes, which require a high level of technical outlay and frequently suffer undesirable perfume losses due to the temperature load (casting / extruding process) that occurs.
- the object of the invention was to develop a system which does not have the disadvantages described. Surprisingly, it was found that special gel-like preparations with pseudoplastic properties significantly reduce the outlay for production and, because of the simple technique, are more cost-effective are to be produced. The problem of the individual refill possibility can also be solved by such pseudoplastic active substance preparations.
- a special container which is particularly suitable for the gel-form cleaning agents according to the invention is described in DE-A-195 201 45.
- the invention relates to a stable, gel-like and shear-thinning cleaning agent which, in addition to a polysaccharide, contains a C 8 to C 22 alkyl polyglycoside as a surfactant system and perfume components, the agent containing a polysaccharide in amounts of between 1 and 5% by weight as a component of the A C 8 to C 22 alkyl polyglucoside in amounts of between 3 and 25% by weight, the perfume component (s) in amounts of 2 to 15% by weight and possibly further ingredients such as cosurfactants, descaling agents, dyes, germ-inhibiting agents Contains agents, pearlescent agents, stabilizers, cleaning enhancers and odor absorbers and has a viscosity of 30,000 to 150,000 mPas; the viscosity was measured using a Brookfield rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
- Another advantage is that the viscosity decreases with increasing shear rate, resulting in filling in the production process and easy handling by the consumer during metering / refilling.
- the size of the air bubbles that z. B. on the stirring speed in the production process and the viscosity of the agent can be neither too large nor too small; in addition, the amount of air bubbles should also only be selected in a preferred range. If the presence of air bubbles is desired, it should not contain more than 30% by volume of air, preferably between 2 and 25% by volume of air and very particularly preferably between 5 and 20% by volume of air.
- the most preferred embodiments contain air bubbles between 0.1 mm and 20 mm in diameter, most preferably between 1 mm and 15 mm in diameter.
- the viscosity of the agents according to the invention also allows the air bubbles already entered in the production process by briefly applying a negative pressure which can be in a range just below room pressure to close to a vacuum.
- the duration of the vacuum treatment depends on the strength of the vacuum. With a stronger negative pressure, the treatment does not have to be carried out as long.
- the person skilled in the art also knows that if the negative pressure is too strong, undesirable side effects can occur, such as, for. B. the increased evaporation of volatile perfume components and u. U. Problems with the stirrability of the system. Degassing of the agents according to the invention by treatment in a centrifuge or by ultrafast stirring is possible, but less preferred.
- the person skilled in the art according to the present invention avoids excessive action of shear forces on the agents according to the invention during and after the production process, since otherwise the properties according to the invention are often lost in the short to medium term and can only be recovered after longer waiting times.
- water is in a commercial mixer, such as. B. a Beco mix system, submitted and the dye stirred.
- a commercial mixer such as. B. a Beco mix system
- the xanthan gum which is preferably used as the polysaccharide is preferred with solvent
- Suspension is added to the initial charge and stirred at low speeds, for example 30 rpm.
- the mixture is generally to be placed in a suitable container, depending on the viscosity, for a short time, for example 15 minutes, under reduced pressure or under a vacuum.
- the disinfectant is then added, preferably selected from the group of isothiazolines, benzoates or salicylic acid or salicylates.
- the filling can in this case, for. B. done in a commercial dosing bottle via a rotary bottle.
- Brookfield viscometers were used, which are a spindle intended for gels have ready.
- the viscosities according to the invention were measured with this Helipath spindle.
- formulations according to the invention can contain the following components in a frame formulation:
- complexing agent 2 0 to 5.0% by weight of complexing agent 2 to 15% by weight, preferably 2 to 12% by weight and in particular 3 to 8% by weight of perfume to 5.0% by weight, preferably 0.01 to 4 wt .-% solvent, such as Ethanol
- Xanthan is formed from a chain with ß-1, 4-bound glucose (cellulose) with side chains. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate.
- Xanthomonas campestris produces xanthan under aerobic conditions with a molecular weight of 2-15 X 10 6 .
- Xanthan is produced in batch cultures and dried and ground with propanol after killing the culture and cases. Other suitable methods are also described in the literature.
- the polysaccharide in particular xanthan gum, is preferably present in the compositions in amounts of between 1 and 4% by weight, in particular between 1.5 and 3.5% by weight and most preferably between 1, 8 and 3% by weight .
- Alkyl polyglycosides are surfactants which can be obtained by the reaction of sugars and alcohols using the relevant methods of preparative organic chemistry, with a mixture of monoalkylated, oligomeric or polymeric sugars depending on the type of preparation.
- Preferred alkyl polyglycosides can be alkyl polyglucosides, the alcohol being particularly preferably a long-chain fatty alcohol with alkyl chain lengths between C 8 and C 22 , preferably between C 8 and C ⁇ and particularly preferably between C 8 and C 12 or a mixture of long-chain fatty alcohols.
- the degree of oligomerization of the sugars which is a calculated and therefore generally not an integer size, is between 1 and 10, preferably between 1, 1 and 5 and very particularly preferably between 1, 2 and 3 and extremely preferably between 1, 3 and 2 , 5th
- the agents contain C 8 to C 22 alkyl polyglycosides, preferably in amounts of 4 to 20% by weight, in particular 5 to 17% by weight and extremely preferably 5 to 15% by weight, with amounts of up to 12% by weight also .-% can be advantageous.
- Anionic co-surfactants according to the present invention can be aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkane sulfonates, olefin sulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates, and lignin sulfonates.
- aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkane sulfonates, olefin sulfonates, ether sulfonates, n-alkyl ether
- Fatty acid cyanamides, sulfosuccinic acid esters, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates are also usable within the scope of the present invention, but are not preferred.
- Fatty alcohol sulfates and fatty alcohol ether sulfates are preferably used. So far, less good results have been achieved with alkylbenzenesulfonates.
- the weight ratio of alkyl polyglycoside to cosurfactants is at least 1, ratios between 50: 1 and 1: 1, particularly preferably between 10: 1 and 1.5: 1 and very particularly preferably between 5: 1 and 1.8: 1, are particularly advantageous.
- Nonionic co-surfactants can also be used.
- Nonionic surfactants in the context of the present invention can be alkoxylated alcohols, such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
- alkoxylated alcohols such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters.
- Ethylene oxide, propylene oxide, block polymers and fatty acid alkanolamides can also be used
- alkoxylated alcohols to mean the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably the longer-chain alcohols in the sense of the present invention.
- n moles of ethylene oxide and one mole of alcohol form a complex mixture of addition products of different degrees of ethoxylation, depending on the reaction conditions.
- a further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
- final etherification with short-chain alkyl groups such as preferably the butyl group, can also give the substance class of the “closed” alcohol ethoxylates, which can also be used for the purposes of the invention.
- Highly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or their mixtures with end-capped fatty alcohol ethoxylates.
- the formulations described can preferably contain inorganic or organic acids such as citric acid, acetic acid, lactic acid or their water-soluble salts in an amount of 1-12% by weight as descaling agents. Contents of 2-5% by weight are particularly preferred.
- the agents according to the invention preferably contain dye, either for the coloring of the product or for the coloring of the liquid surrounding the container.
- the content of water-soluble dyes is preferably ⁇ 1% by weight and serves to improve the appearance of the product. If an additional color signal is required during the flushing process, the content of water-soluble dyes can be up to 5% by weight.
- the content is preferably in amounts of up to 3% by weight, in particular up to 2% by weight and very preferably up to 1% by weight.
- the gels according to the invention already have an excellent cleaning action without this component, the hygienic action can be enhanced by the addition of germ-inhibiting agents.
- the amount of these agents depends strongly on the effectiveness of the particular compound and can be up to 5% by weight. At least 0.01% by weight is preferably incorporated into the gels. The range between 0.01% by weight and 3% by weight is particularly preferred. Isothiazoline mixtures, sodium benzoate or salicylic acid or salicylates are particularly suitable. Further preferred amounts are from 0.01 to 2% by weight, in particular from 0.01 to 1% by weight.
- Solubilizers for example for dyes and perfume oils, can be used, for example, as alkanolamines, polyols such as ethylene glycol, representatives of the lower alcohols such as propylene glycol, glycerol and other mono- and polyhydric alcohols, and also alkylbenzenesulfonates with 1 to 3 carbon atoms in the alkyl radical.
- Preferred amounts are up to 5% by weight, in particular 0.01 to 4% by weight, advantageously 0.1 to 4% by weight and very particularly preferably 0.5 to 3% by weight.
- the usual thickeners which could also be used if required, include urea, sodium chloride, sodium sulfate, magnesium sulfate, ammonium chloride and magnesium chloride and the combination of these thickeners. However, the use of these additional thickeners is not preferred.
- Water-soluble and water-insoluble builders may be present in the cleaning agents according to the invention. Then there are water-soluble builders preferred because they tend to have less tendency to form insoluble residues on hard surfaces.
- Customary builders or complexing agents which can be present in the context of the invention are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the citric acid and their salts, the carbonates, phosphates and silicates.
- Water-insoluble builders include the zeolites, which can also be used, as well as mixtures of the abovementioned builder substances. The group of citrates is particularly preferred.
- the agents according to the invention preferably contain builders or complexing agents in amounts of up to 10% by weight, in particular 0.1 to 8% by weight, particularly preferably 1 to 6% by weight and very particularly preferably 2 to 5% by weight.
- the viscosity in the examples listed was measured using a Brookfield Roto viscometer, rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
- 0.1 g of gel are foamed in 500 ml of tap water at 17 ° d in a 1000 ml measuring cylinder with 40 strokes at a rotation speed of 100 rpm.
- the structure of the foam volume is read after 1, 3 and 10 min.
- the measurement is carried out on an automatically controlled toilet system, which dispenses the contents of the water tank every 1 hour and refills the tank with 9 liters of tap water at 17 ° d and a water temperature of 15 - 16 ° C.
- an automatically controlled toilet system which dispenses the contents of the water tank every 1 hour and refills the tank with 9 liters of tap water at 17 ° d and a water temperature of 15 - 16 ° C.
- 1 filling of a vessel according to DE 195 201 45 is hung in the toilets and it is determined how many flushes are possible until it is completely used up.
- the average results are determined from 5 parallel tests.
- Pre-weighed white Carrara marble slabs measuring 75 x 150 x 5 mm are completely immersed in the gel in a plexiglass cell. This is done for a time of 10 seconds.
- the plate is then removed and placed vertically in a stand provided for this purpose. This has to be done in such a way that adhering product can run off.
- the exposure time of the adhesive Product is another 10 min.
- the plate is then rinsed with water and the weight loss is determined after drying at 105 ° C.
- the measurement was carried out electrochemically in the concentrate.
- the storage took place in electrically controlled heat chambers.
- the storage time at 40 ° C is 3 and 4 weeks, at 23 ° C 12 weeks. This was followed by a visual inspection of the stored goods.
- Xanthan gum granulated e.g. Keltrol® RD 2.3
- Rinsing behavior 220 rinses at 21 rinses / day
- the production can be in a wide variety of batch sizes up to
- Tone scale can be carried out.
- water is in a commercial mixer, such as. B. submitted to a Beco mix system, and the dye stirred.
- the xanthan gum used is slurried separately with solvent, preferably ethanol and the desired perfume oil.
- Suspension is added to the aqueous template and with small
- the mixture should, as a rule, be placed in a suitable container depending on the viscosity for a short time, for example 15 minutes under reduced pressure or under a vacuum.
- the filling in the appropriate storage container can then, for. B. via a suitable commercially available tube filler.
- Rinsing behavior 250 rinses at 21 rinses / day
- Tone scale can be carried out.
- the suspension is added to the template and with low
- the filling can in this case, for. B. done in a commercial dosing bottle via a rotary bottle.
- Rinsing behavior 230 rinses at 21 rinses / day
- TTF Perfume oil apple note
- TTF Perfume oil apple note
- Rinsing behavior 300 rinses at 21 rinses / day
- Foaming behavior 100 ml 1 min; 80 ml 3 min; 50 ml 10 min.
- TTF Perfume oil apple note
- Rinsing behavior 500 rinses at 21 rinses / day
- Rinsing behavior 280 rinses at 21 rinses / day
- TTF Perfume oil Cool water
Abstract
The object of the invention is to improve the stability, fragrance, cleaning power and rechargeability of gelled cleaning agents, preferably for flush toilets. This object is attained by preparing a gelled, shear-reducing cleaning agent which contains 1 to 5 % by weight of a polysaccharide, 3 to 25 % by weight of a C8-C22 alkylpolyglycoside as a component of the surfactant system, up to 15 % by weight fragrance and if required other ingredients such as scale preventives, dyes, disinfectants, nacreous brighteners, stabilisers, cleaning power reinforcing agents and odour absorbers. The cleaning agent has a viscosity from 30,000 to 150,000 mPas.
Description
"Gelförmiges Reinigungsmittel für Spültoiletten" "Gel-shaped detergent for flush toilets"
Die vorliegende Erfindung betrifft ein gelförmiges Reinigungsmittel, das bevorzugt in Spültoiletten eingesetzt werden kann.The present invention relates to a gel-type cleaning agent which can preferably be used in flush toilets.
Bekanntermaßen werden feste Reinigungsmittel in Stückform zur automatischen Reinhaltung von Toiletten eingesetzt. Diese werden entweder in der WC- Schüssel oder im Wasserkasten angebracht. Die Formkörper werden bei jedem Spülvorgang von Wasser überströmt, wobei sie sich allmählich auflösen und während dieser Zeit ihre reinigungsaktiven Wirkstoffe freisetzen. Üblicherweise enthalten diese Reinigungsformkörper zusätzlich Parfüm zur Raumbeduftung oder desinfizierende Wirkstoffe zur Hygieneoptimierung. Die beschriebenen stückförmigen Reinigungsmittelformkörper werden in dafür geeigneten Behältnissen teilweise mit speziellen Nachfüllmöglichkeiten appliziert.It is known that solid cleaning agents are used in piece form for automatically keeping toilets clean. These are either installed in the toilet bowl or in the water tank. The moldings are overflowed with water during each rinsing process, whereby they gradually dissolve and release their active cleaning ingredients during this time. These cleaning moldings usually contain additional perfume for room scenting or disinfectant agents for hygiene optimization. The piece-shaped detergent tablets described are partially applied in suitable containers with special refill options.
Die beschriebenen Formkörper werden in der Regel nach Gieß-, Preß-, Extrudier- oder Granulierverfahren gefertigt, die einen hohen technischen Aufwand erfordern und häufig durch die auftretende Temperaturbelastung (Gieß- /Extrudierverfahren) unerwüschte Parfümverluste erleiden.The moldings described are generally produced by casting, pressing, extruding or granulating processes, which require a high level of technical outlay and frequently suffer undesirable perfume losses due to the temperature load (casting / extruding process) that occurs.
Als nachteilig erweist es sich auch, daß die aus ökologischen Gründen verbreiteten Nachfülleinheiten nur nach vollständigem Verbrauch des stückförmigen Körpers eingesetzt werden können. Eine wünschenswerte beliebige Nachfüllung, z.B. zur stärkeren Wirkstoffreisetzung oder insbesondere der intensiveren Duftentfaltung, ist nicht möglich.It also proves to be disadvantageous that the refill units, which are widespread for ecological reasons, can only be used after the piece-like body has been completely used up. Any desirable refill, e.g. for more active ingredient release or in particular the more intense fragrance development is not possible.
Aufgabe der Erfindung war es, ein System zu entwickeln, das die beschriebenen Nachteile nicht aufweist. Überraschenderweise wurde gefunden, daß spezielle gelförmige Zubereitungen mit strukturviskosen Eigenschaften den Aufwand der Herstellung erheblich verringern und aufgrund einfacher Technik kostengünstiger
zu produzieren sind. Auch das Problem der individuellen Nachfüllmöglichkeit kann durch derartige strukturviskose Wirkstoffzubereitungen gelöst werden. Ein spezielles Behältnis, das für die erfindungsgemäßen gelförmigen Reinigungsmittel besonders geeignet ist, wird in der DE-A- 195 201 45 beschrieben.The object of the invention was to develop a system which does not have the disadvantages described. Surprisingly, it was found that special gel-like preparations with pseudoplastic properties significantly reduce the outlay for production and, because of the simple technique, are more cost-effective are to be produced. The problem of the individual refill possibility can also be solved by such pseudoplastic active substance preparations. A special container which is particularly suitable for the gel-form cleaning agents according to the invention is described in DE-A-195 201 45.
Gegenstand der Erfindung ist ein stabiles gelförmiges und scherverdünnendes Reinigungsmittel, welches außer einem Polysaccharid ein C8- bis C22- Alkylpolyglycosid als Tensidsystem und Parfümkomponenten enthält, wobei das Mittel ein Polysaccharid in Mengen zwischen 1 und 5 Gew.-%, als eine Komponente des Tensidsystems ein C8- bis C22-Alkylpolyglucosid in Mengen zwischen 3 und 25 Gew.-%, die Parfümkomponente(n) in Mengen von 2 bis 15 Gew.-% sowie ggf. weitere Inhaltsstoffe wie Cotenside, kalklösende Mittel, Farbstoffe, keimhemmende Mittel, Perlglanzmittel, Stabilisatoren, Reinigungsverstärker und Geruchsabsorber enthält und eine Viskosität von 30 000 bis 150 000 mPas aufweist; die Viskosität wurde dabei mit einem Brookfield Rotationsviskosimeter, Typ RVT mit Helipath-Einrichtung und der Spindel TA bei 1 Upm und 23°C gemessen.The invention relates to a stable, gel-like and shear-thinning cleaning agent which, in addition to a polysaccharide, contains a C 8 to C 22 alkyl polyglycoside as a surfactant system and perfume components, the agent containing a polysaccharide in amounts of between 1 and 5% by weight as a component of the A C 8 to C 22 alkyl polyglucoside in amounts of between 3 and 25% by weight, the perfume component (s) in amounts of 2 to 15% by weight and possibly further ingredients such as cosurfactants, descaling agents, dyes, germ-inhibiting agents Contains agents, pearlescent agents, stabilizers, cleaning enhancers and odor absorbers and has a viscosity of 30,000 to 150,000 mPas; the viscosity was measured using a Brookfield rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
Es hat sich gezeigt, daß nur mit Polysacchariden in den beschriebenen Kombinationen je nach Wahl der Type mit hohen Parfüm- und APG- Konzentrationen optisch ansprechende transluzente oder klare strukturviskose Gelstrukturen erzielt werden können, die in den dafür geeigneten Behältnissen vergleichbare Haltbarkeiten von festen WC-Blöcken erreichen.It has been shown that only with polysaccharides in the combinations described, depending on the choice of type with high perfume and APG concentrations, visually appealing translucent or clear structurally viscous gel structures can be achieved which have comparable shelf lives of solid toilet blocks in the appropriate containers to reach.
Andere übliche Gelbildner wie z.B. Polyacrylsäure (Carbopol), tensidverdickte Systeme, MHPC (Natrosol) oder kochsalz- bzw. elektrolytverdickte Tensidsysteme zeigen bei Einsatz der notwendigen hohen Tensid- und Parfümanteile keine ausreichende Gelstabilität. Diese Formulierungen sind häufig nicht ausreichend strukturviskos, verdünnen sich beim Überströmen mit Wasser und tropfen wegen ihres ungenügenden Viskositätsverhalten trotz geeigneter Behältnisse undosiert in die WC-Schüssel. Dagegen sind die erfindungsgemäßen
Formulierungen ausgesprochen strukturviskos und widerstehen dabei dem überströmenden Wasser in der Form, daß nur geringe Teilmengen abgegeben werden und die gewünschte Haltbarkeit erzielt wird. Die erhaltenen Mittel dürfen sich nämlich in dem in die dafür vorgesehenen Behältnisse eindringenden Wasser auch nicht zu gut lösen, damit sie nicht nach einer geringen Anzahl von verwendungsgemäßen wässrigen Überströmungen bereits aufgelöst und damit verbraucht sind.Other customary gel formers such as polyacrylic acid (Carbopol), surfactant thickened systems, MHPC (Natrosol) or sodium chloride or electrolyte thickened surfactant systems do not show sufficient gel stability when the necessary high surfactant and perfume levels are used. These formulations are often not sufficiently viscous, dilute with water when poured over and, due to their inadequate viscosity behavior, drop undosed into the toilet bowl despite suitable containers. In contrast, the invention Formulations are extremely viscous and withstand the overflowing water in such a way that only small quantities are released and the desired durability is achieved. The agents obtained must not dissolve too well in the water penetrating into the containers provided, so that they are not already dissolved and thus consumed after a small number of aqueous overflows according to the use.
Dabei muß außerdem gewährleistet sein, daß trotz der hohen Parfüm- und Emulgatormenge eine ausreichende Langzeitstabilität der Gele gewährleistet ist, und sich z. B. keine Phasenseparation einstellt, die nicht nur ein für den Verbraucher optisch minder ansprechendes Produkt bedeuten würde, sondern auch Lösekinetik und Dosierfähigkeit beeinträchtigen würde.It must also be ensured that despite the high amount of perfume and emulsifier, sufficient long-term stability of the gels is guaranteed, and z. B. does not set phase separation, which would not only mean an optically less appealing product for the consumer, but would also impair the kinetics of dissolution and the ability to dose.
Als Vorteil ist zusätzlich gegeben, daß mit zunehmender Schergeschwindigkeit die Viskosität abnimmt und ein Abfüllen im Produktionsprozeß sowie ein leichtes Handling beim Verbraucher während des Dosierens/Nachfüllung resultiert.Another advantage is that the viscosity decreases with increasing shear rate, resulting in filling in the production process and easy handling by the consumer during metering / refilling.
Überraschenderweise wurde auch gefunden, daß unter bestimmten Bedingungen beim Produktionsprozeß Luftblasen in die Mittel erfindungsgemäßer Zusammensetzung eingebracht werden können, die über einen Zeitraum von mehreren Wochen in Größe und Form stabil sind und damit ein für den Verbraucher optisch noch ansprechenderes Produkt bedeuten.Surprisingly, it was also found that under certain conditions in the production process, air bubbles can be introduced into the compositions according to the invention which are stable in size and shape over a period of several weeks and thus mean a product which is even more visually appealing to the consumer.
Dabei darf die Größe der Luftblasen, die sich z. B. über die Rührgeschwindigkeit im Produktionsprozeß und die Viskosität der Mittel steuern läßt, weder zu groß noch zu klein sein; außerdem sollte die Menge der Luftblasen ebenfalls nur in einem bevorzugten Bereich ausgewählt sein. Sollte also die Anwesenheit von Luftblasen erwünscht sein, so sollte nicht mehr als 30 Vol-% Luft enthalten sein, bevorzugt wischen 2 und 25 Vol-% Luft und ganz besonders bevorzugt zwischen 5 und 20 Vol.-% Luft. Die ganz besonders bevorzugten Ausführungsformen
enthalten Luftblasen zwischen 0,1 mm und 20 mm Durchmesser, äußerst bevorzugt zwischen 1 mm und 15 mm Durchmesser.The size of the air bubbles that z. B. on the stirring speed in the production process and the viscosity of the agent can be neither too large nor too small; in addition, the amount of air bubbles should also only be selected in a preferred range. If the presence of air bubbles is desired, it should not contain more than 30% by volume of air, preferably between 2 and 25% by volume of air and very particularly preferably between 5 and 20% by volume of air. The most preferred embodiments contain air bubbles between 0.1 mm and 20 mm in diameter, most preferably between 1 mm and 15 mm in diameter.
Die Viskosität der erfindungsgemäßen Mittel erlaubt aber auch, die im Produktionsprozeß bereits eingetragenen Luftblasen durch kurzzeitiges Anlegen eines Unterdrucks, der in einem Bereich knapp unterhalb Raumdruck bis nahe einem Vakuum liegen kann. Dabei ist die Dauer der Unterdruckbehandlung abhängig von der Stärke des Unterdrucks. Bei stärkerem Unterdruck muß die Behandlung nicht so lange durchgeführt werden. Der Fachmann weiß aber auch, daß bei zu starkem Unterdruck unerwünschte Nebeneffekte auftreten können, wie z. B. das verstärkte Abdampfen von leichterflüchtigen Parfümkomponenten und u. U. Probleme bei der Rührbarkeit des Systems. Ein Entgasen der erfindungsgemäßen Mittel durch die Behandlung in einer Zentrifuge oder durch ultraschnelles Rühren ist zwar möglich, aber weniger bevorzugt.However, the viscosity of the agents according to the invention also allows the air bubbles already entered in the production process by briefly applying a negative pressure which can be in a range just below room pressure to close to a vacuum. The duration of the vacuum treatment depends on the strength of the vacuum. With a stronger negative pressure, the treatment does not have to be carried out as long. However, the person skilled in the art also knows that if the negative pressure is too strong, undesirable side effects can occur, such as, for. B. the increased evaporation of volatile perfume components and u. U. Problems with the stirrability of the system. Degassing of the agents according to the invention by treatment in a centrifuge or by ultrafast stirring is possible, but less preferred.
Wenn möglich, vermeidet nämlich der Fachmann gemäß der vorliegenden Erfindung übermäßiges Einwirken von Scherkräften auf die erfindungsgemäßen Mittel während und nach dem Produktionsprozeß, da sonst die erfindungsgemäßen Eigenschaften oft kurz- bis mittelfristig verlorengehen und nur nach längeren Wartezeiten wiedergewonnen werden.If possible, the person skilled in the art according to the present invention avoids excessive action of shear forces on the agents according to the invention during and after the production process, since otherwise the properties according to the invention are often lost in the short to medium term and can only be recovered after longer waiting times.
Bei der Herstellung der erfindungsgemäßen Rezepturen, die in den unterschiedlichsten Ansatzgrößen bis zum Tonnenmaßstab durchführbar ist, kann der Fachmann auf unterschiedliche Weise vorgehen.The person skilled in the art can proceed in different ways in the preparation of the recipes according to the invention, which can be carried out in a wide variety of batch sizes up to the ton scale.
Üblicherweise wird Wasser in einer handelsüblichen Mischeranlage, wie z. B. einer Beco-Mix-Anlage, vorgelegt und der Farbstoff eingerührt. Der vorzugsweise als Polysaccharid verwendete Xanthan-Gum wird mit Lösungsmittel, bevorzugtUsually, water is in a commercial mixer, such as. B. a Beco mix system, submitted and the dye stirred. The xanthan gum which is preferably used as the polysaccharide is preferred with solvent
Ethanol, und dem gewünschten Parfumöl separat aufgeschlämmt. DieEthanol, and the desired perfume oil slurried separately. The
Suspension wird der Vorlage zugegeben und mit geringen Geschwindigkeiten, beispielsweise 30 Upm gerührt.Suspension is added to the initial charge and stirred at low speeds, for example 30 rpm.
Es zeigt sich bei den Untersuchungen, daß nach Zugabe aller Komponenten eineThe investigations show that after all components have been added, a
Zeit zwischen wenigen Minuten und einigen Stunden zur Erreichung der
erfindungsgemäßen Konsistenz wünschenswert ist. Im vorliegenden Fall wurde nach 30 min das Tensid (Alkylpolyglycosid) langsam zudosiert. Anschließend werden die weiteren Komponenten zugesetzt.Time between a few minutes and a few hours to achieve the consistency according to the invention is desirable. In the present case, the surfactant (alkyl polyglycoside) was slowly added after 30 minutes. The other components are then added.
Soll ein blasenfreies Gel gewährleistet werden, ist die Mischung, wie oben bereits beschrieben, in einem geeigneten Behälter in Abhängigkeit von der Viskosität in der Regel aber für eine kurze Zeit, beispielsweise 15 min, unter reduzierten Druck oder ein Vakuum zu setzen.If a bubble-free gel is to be ensured, the mixture, as already described above, is generally to be placed in a suitable container, depending on the viscosity, for a short time, for example 15 minutes, under reduced pressure or under a vacuum.
Der Fachmann kann aber auch anders vorgehen. Dies empfiehlt sich z. B. bei der Einarbeitung von Desinfektionsmitteln. Üblicherweise wird hier Wasser in einer handelsüblichen Mischeranlage, wie z. B. einer Beco-Mix-Anlage, vorgelegt und der verwendete Xanthan-Gum eingerührt . Die Suspension wird der Vorlage zugegeben und mit geringen Geschwindigkeiten, beispielsweise 30 Upm gerührt, bevor nach 30 min das Tensidgemisch (Alkylpolyglycosid/Fettalkoholethersulfat) langsam zudosiert wird. Anschließend wird der Farbstoff zugegeben, bevor eine ethanolische Lösung des Parfüms nachdosiert wurde.The person skilled in the art can also proceed differently. This is recommended e.g. B. when incorporating disinfectants. Usually water is here in a commercial mixer, such as. B. a Beco mix system, submitted and the xanthan gum used stirred. The suspension is added to the initial charge and stirred at low speeds, for example 30 rpm, before the surfactant mixture (alkyl polyglycoside / fatty alcohol ether sulfate) is slowly metered in after 30 minutes. The dye is then added before an ethanolic solution of the perfume has been added.
Danach erfolgt die Zugabe des Desinfektionsmittels, bevorzugt ausgewählt aus der Gruppe der Isothiazoline, der Benzoate oder der Salicylsäure oder Salicylate. Die Abfüllung kann in diesem Fall z. B. über einen Flaschenrundläufer in eine handelsübliche Dosierflasche erfolgen.The disinfectant is then added, preferably selected from the group of isothiazolines, benzoates or salicylic acid or salicylates. The filling can in this case, for. B. done in a commercial dosing bottle via a rotary bottle.
Besondere Vorsicht muß man walten lassen, wenn man Substanzen in das vorbereitete und gequollene wässerige Xanthan-Gel zugibt, damit sich die erfindungsgemäße Struktur bilden kann. Bei einer zu schnellen Zugabe kann es zu Phasentrennungsproblemen kommen. Ebenfalls darf bei der Herstellung der Xanthan-Gel-Komponente kein Tensid zugegen sein, da es die Gel-Bildung verhindern könnte. Daher ist es äußerst bevorzugt, die tensidischen Komponenten erst nach der Bildung des Gels zuzugeben.Special care must be taken when adding substances to the prepared and swollen aqueous xanthan gel so that the structure according to the invention can form. If the addition is too fast, phase separation problems can arise. Likewise, no surfactant may be present in the manufacture of the xanthan gel component, since this could prevent gel formation. It is therefore extremely preferred to add the surfactant components only after the gel has formed.
Zur Messung der Viskosität können die gängigen Methoden der Viskositätsbestimmung verwendet werden. Im vorliegenden Fall wurde mit Brookfield-Viskosimetern gearbeitet, welche eine für Gele vorgesehene Spindel
bereithalten. Mit dieser Helipath-Spindel wurden die erfindungsgemäßen Viskositäten gemessen.The usual methods of viscosity determination can be used to measure the viscosity. In the present case, Brookfield viscometers were used, which are a spindle intended for gels have ready. The viscosities according to the invention were measured with this Helipath spindle.
Die erfindungsgemäßen Formulierungen können in einer Rahmenrezeptur folgende Komponenten enthalten:The formulations according to the invention can contain the following components in a frame formulation:
1 ,0 - 5,0 Gew.-% Polysaccharid1.0-5.0% by weight polysaccharide
3,0 - 25,0 Gew.-% C8-C22 Alkylpolyglycosid3.0-25.0 wt% C 8 -C 22 alkyl polyglycoside
0 - 15,0 Gew.-% Co-Tenside (FAS, FAEOS)0 - 15.0% by weight of co-surfactants (FAS, FAEOS)
0 - 5,0 Gew.-% Zitronensäure0 - 5.0 wt% citric acid
0 - 5,0 Gew.-% Komplexbildner 2 bis 15 Gew.-%, bevorzugt 2 - 12 Gew.-% und insbesondere 3 bis 8 Gew.-% Parfüm bis 5,0 Gew.-%, bevorzugt 0,01 bis 4 Gew.-% Lösungsmittel, wie z.B. Ethanol0 to 5.0% by weight of complexing agent 2 to 15% by weight, preferably 2 to 12% by weight and in particular 3 to 8% by weight of perfume to 5.0% by weight, preferably 0.01 to 4 wt .-% solvent, such as Ethanol
0 - 1 ,0 Gew.-% Konservierungsmittel0-1.0% by weight preservative
0 - 10,0 Gew.-% Farbstoff0-10.0% by weight of dye
0 - 5,0 Gew.-%, bevorzugt 0,01 bis 3 Gew.-% keimhemmende Mittel0 to 5.0% by weight, preferably 0.01 to 3% by weight of germ-inhibiting agents
Dabei versteht man beispielsweise erfindungsgemäß unter einem Polysaccarid z. B. ein Xanthan-Gum oder ein Guar-Gum oder Gemische aus Polysaccariden. Xanthan wird aus einer Kette mit ß-1 ,4-gebundener Glucose (Cellulose) mit Seitenketten gebildet. Die Struktur der Untergruppen besteht aus Glucose, Mannose, Glucuronsäure, Acetat und Pyruvat. Xanthan wird von Xanthomonas campestris unter aeroben Bedingungen mit einem Molekulargewicht von 2-15 X 106 produziert. Xanthan wird u.a. in Batch-Kulturen hergestellt und nach Abtöten der Kultur und Fällen mit Propanol getrocknet und gemahlen. Andere geeignete Verfahren werden in der Literatur ebenfalls beschrieben. Vorzugsweise ist das Polysaccharid, insbesondere Xanthan-Gum, in Mengen zwischen 1 und 4 Gew.- %, insbesondere zwischen1 ,5 und 3,5 Gew.-% und äußert bevorzugt zwischen 1 ,8 und 3 Gew.-% in den Mitteln enthalten.
Alkylpolyglycoside sind Tenside, die durch die Reaktion von Zuckern und Alkoholen nach den einschlägigen Verfahren der präparativen organischen Chemie erhalten werden können, wobei es je nach Art der Herstellung zu einem Gemisch monoalkylierter, oligomerer oder polymerer Zucker kommt. Bevorzugte Alkylpolyglycoside können Alkylpolyglucoside sein, wobei besonders bevorzugt der Alkohol ein langkettiger Fettalkohol ist mit Alkylkettenlängen zwischen C8 und C22, bevorzugt zwischen C8 und Cιβ und besonders bevorzugt zwischen C8 und C12 liegt oder ein Gemisch langkettiger Fettalkohole ist. Der Oligomerisierungsgrad der Zucker, der eine berechnete und damit in der Regel nicht ganzzahlige Größe ist, liegt zwischen 1 und 10, bevorzugt zwischen 1 ,1 und 5 und ganz besonders bevorzugt zwischen 1 ,2 und 3 und äußerst bevorzugt zwischen 1 ,3 und 2,5. Die Mittel enthalten C8- bis C22-Alkylpolyglycoside vorzugsweise in Mengen von 4 bis 20 Gew.-%, insbesondere von 5 bis 17 Gew.- % und äußerst bevorzugt von 5 bis 15 Gew.-%, wobei auch Mengen bis 12 Gew.- % von Vorteil sein können.According to the invention, this means, for example, a polysaccharide such. B. a xanthan gum or a guar gum or mixtures of polysaccharides. Xanthan is formed from a chain with ß-1, 4-bound glucose (cellulose) with side chains. The structure of the subgroups consists of glucose, mannose, glucuronic acid, acetate and pyruvate. Xanthomonas campestris produces xanthan under aerobic conditions with a molecular weight of 2-15 X 10 6 . Xanthan is produced in batch cultures and dried and ground with propanol after killing the culture and cases. Other suitable methods are also described in the literature. The polysaccharide, in particular xanthan gum, is preferably present in the compositions in amounts of between 1 and 4% by weight, in particular between 1.5 and 3.5% by weight and most preferably between 1, 8 and 3% by weight . Alkyl polyglycosides are surfactants which can be obtained by the reaction of sugars and alcohols using the relevant methods of preparative organic chemistry, with a mixture of monoalkylated, oligomeric or polymeric sugars depending on the type of preparation. Preferred alkyl polyglycosides can be alkyl polyglucosides, the alcohol being particularly preferably a long-chain fatty alcohol with alkyl chain lengths between C 8 and C 22 , preferably between C 8 and Cιβ and particularly preferably between C 8 and C 12 or a mixture of long-chain fatty alcohols. The degree of oligomerization of the sugars, which is a calculated and therefore generally not an integer size, is between 1 and 10, preferably between 1, 1 and 5 and very particularly preferably between 1, 2 and 3 and extremely preferably between 1, 3 and 2 , 5th The agents contain C 8 to C 22 alkyl polyglycosides, preferably in amounts of 4 to 20% by weight, in particular 5 to 17% by weight and extremely preferably 5 to 15% by weight, with amounts of up to 12% by weight also .-% can be advantageous.
Anionische Co-Tenside gemäß der vorliegenden Erfindung können aliphatische Sulfate wie Fettalkoholsulfate, Fettalkoholethersulfate, Dialkylethersulfate, Mono- glyceridsulfate und aliphatische Sulfonate wie Alkansulfonate, Olefinsulfonate, Ethersulfonate, n-Alkylethersulfonate, Estersulfonate, und Ligninsulfonate sein. Ebenfalls im Rahmen der vorliegenden Erfindung verwendbar, aber nicht bevorzugt sind Fettsäurecyanamide, Sulfobernsteinsäureester, Fettsäure- isethionate, Acylaminoalkansulfonate (Fettsäuretauride), Fettsäuresarcosinate, Ethercarbonsäuren und Alkyl(ether)phosphate. Bevorzugt werden Fettalkoholsulfate und Fettalkoholethersulfate verwendet. Weniger gute Ergebnisse wurden bisher mit Alkylbenzolsulfonaten erzielt.Anionic co-surfactants according to the present invention can be aliphatic sulfates such as fatty alcohol sulfates, fatty alcohol ether sulfates, dialkyl ether sulfates, monoglyceride sulfates and aliphatic sulfonates such as alkane sulfonates, olefin sulfonates, ether sulfonates, n-alkyl ether sulfonates, ester sulfonates, and lignin sulfonates. Fatty acid cyanamides, sulfosuccinic acid esters, fatty acid isethionates, acylaminoalkanesulfonates (fatty acid taurides), fatty acid sarcosinates, ether carboxylic acids and alkyl (ether) phosphates are also usable within the scope of the present invention, but are not preferred. Fatty alcohol sulfates and fatty alcohol ether sulfates are preferably used. So far, less good results have been achieved with alkylbenzenesulfonates.
In einer bevorzugten Ausführungsform der Erfindung liegt das Gewichtsverhältnis Alkylpolyglycosid zu Co-Tensiden, insbesondere zu Fettalkoholethersulfat und/oder Fettalkoholsulfat, bei mindestens 1 , wobei Verhältnisse zwischen 50:1 und 1 :1 , besonders bevorzugt zwischen 10:1 und 1 ,5:1 und ganz besonders bevorzugt zwischen 5:1 und 1 ,8:1 , besonders vorteilhaft sind.
Aber auch nichtionische Co-Tenside können Verwendung finden. Nichtionische Tenside im Rahmen der vorliegenden Erfindung können alkoxylierte Alkohole sein, wie Polyglycolether, Fettalkoholpolygycolether, Alkylphenolpolyglycolether, endgruppenverschlossene Polyglycolether, Mischether und Hydroxymischether und Fettsäurepolyglycolester sein. Ebenfalls verwendbar sind Ethylenoxid, Propylenoxid, Blockpolymere und Fettsäurealkanolamide undIn a preferred embodiment of the invention, the weight ratio of alkyl polyglycoside to cosurfactants, in particular to fatty alcohol ether sulfate and / or fatty alcohol sulfate, is at least 1, ratios between 50: 1 and 1: 1, particularly preferably between 10: 1 and 1.5: 1 and very particularly preferably between 5: 1 and 1.8: 1, are particularly advantageous. Nonionic co-surfactants can also be used. Nonionic surfactants in the context of the present invention can be alkoxylated alcohols, such as polyglycol ethers, fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, end-capped polyglycol ethers, mixed ethers and hydroxy mixed ethers and fatty acid polyglycol esters. Ethylene oxide, propylene oxide, block polymers and fatty acid alkanolamides and can also be used
Fettsäurepolyglycolether.Fatty acid polyglycol ether.
Dabei versteht der Fachmann allgemein unter alkoxylierten Alkoholen die Reaktionsprodukte von Alkylenoxid, bevorzugt Ethylenoxid, mit Alkoholen, bevorzugt im Sinne der vorliegenden Erfindung die längerkettigen Alkohole. In der Regel entsteht aus n Molen Ethylenoxid und einem Mol Alkohol, abhängig von den Reaktionsbedingungen ein komplexes Gemisch von Additionsprodukten unterschiedlichen Ethoxylierungsgrades. Eine weitere Ausführungsform besteht im Einsatz von Gemischen der Alkylenoxide, bevorzugt des Gemisches von Ethylenoxid und Propylenoxid. Auch kann man gewünschtenfalls durch eine abschließende Veretherung mit kurzkettigen Alkylgruppen, wie bevorzugt der Butylgruppe, zur Substanzklasse der "verschlossenen" Alkoholethoxylate gelangen, die ebenfalls im Sinne der Erfindung eingesetzt werden kann. Ganz besonders bevorzugt im Sinne der vorliegenden Erfindung sind dabei hochethoxylierte Fettalkohole oder deren Gemische mit endgruppenverschlossenen Fettalkoholethoxylaten.The person skilled in the art generally understands alkoxylated alcohols to mean the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably the longer-chain alcohols in the sense of the present invention. As a rule, n moles of ethylene oxide and one mole of alcohol form a complex mixture of addition products of different degrees of ethoxylation, depending on the reaction conditions. A further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. If desired, final etherification with short-chain alkyl groups, such as preferably the butyl group, can also give the substance class of the “closed” alcohol ethoxylates, which can also be used for the purposes of the invention. Highly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or their mixtures with end-capped fatty alcohol ethoxylates.
Die beschriebenen Formulierungen können vorzugsweise als kalklösende Mittel anorganische oder organische Säuren wie die Zitronensäure, Essigsäure, Milchsäure oder deren wasserlöslichen Salze in einer Menge von 1 - 12 Gew.-% enthalten. Besonders bevorzugt sind Gehalte von 2 - 5 Gew.-%.The formulations described can preferably contain inorganic or organic acids such as citric acid, acetic acid, lactic acid or their water-soluble salts in an amount of 1-12% by weight as descaling agents. Contents of 2-5% by weight are particularly preferred.
Die erfindungsgemäßen Mittel enthalten vorzugsweise Farbstoff, entweder für die Farbgebung des Produktes oder für die Farbgebung der den Behälter umspielenden Flüssigkeit. Bevorzugt liegt der Gehalt an wasserlöslichen Farbstoffen < 1 Gew.-% und dient zur Verbesserung der Optik des Produktes.
Wenn ein zusätzliches Farbsignal beim Einspülvorgang gewünscht ist, kann der Gehalt an wasserlöslichen Farbstoffen bis 5 Gew.-% betragen. Vorzugsweise liegt der Gehalt bei Mengen bis zu 3 Gew.-%, insbesondere bis zu 2 Gew.-% und äußerst bevorzugt bis zu 1 Gew.-%.The agents according to the invention preferably contain dye, either for the coloring of the product or for the coloring of the liquid surrounding the container. The content of water-soluble dyes is preferably <1% by weight and serves to improve the appearance of the product. If an additional color signal is required during the flushing process, the content of water-soluble dyes can be up to 5% by weight. The content is preferably in amounts of up to 3% by weight, in particular up to 2% by weight and very preferably up to 1% by weight.
Obwohl die erfindungsgemäßen Gele bereits ohne diese Komponente bereits eine ausgezeichnete Reinigungswirkung besitzen, kann die hygienische Wirkung durch den Zusatz keimhemmender Mittel verstärkt werden. Die Menge dieser Mittel hängt stark von der Wirksamkeit der jeweiligen Verbindung ab und kann bis zu 5 Gew.-% betragen. Vorzugsweise werden mindestens 0,01 Gew.-% in die Gele eingearbeitet. Besonders bevorzugt ist der Bereich zwischen 0,01 Gew.-% und 3 Gew.-%. Geeignet sind insbesondere Isothiazolingemische, Natriumbenzoat oder Salicylsäure bzw. Salicylate. Weitere bevorzugte Einsatzmengen liegen bei 0,01 bis 2 Gew.-%, insbesondere bei 0,01 bis 1 Gew.- %.Although the gels according to the invention already have an excellent cleaning action without this component, the hygienic action can be enhanced by the addition of germ-inhibiting agents. The amount of these agents depends strongly on the effectiveness of the particular compound and can be up to 5% by weight. At least 0.01% by weight is preferably incorporated into the gels. The range between 0.01% by weight and 3% by weight is particularly preferred. Isothiazoline mixtures, sodium benzoate or salicylic acid or salicylates are particularly suitable. Further preferred amounts are from 0.01 to 2% by weight, in particular from 0.01 to 1% by weight.
Als Lösungsvermittler, etwa für Farbstoffe und Parfümöle, können beispielsweise Alkanolamine, Polyole wie Ethylenglycol, Vertreter der niederen Alkohole wie Propylenglycol, Glycerin und andere ein- und mehrwertige Alkohole, sowie Alkyl- benzolsulfonate mit 1 bis 3 Kohlenstoffatomen im Alkylrest dienen. Besonders bevorzugt ist dabei die Gruppe der niederen Alkohole, ganz besonders Ethanol. Bevorzugte Einsatzmengen liegen bis zu 5 Gew.-%, insbesondere bei 0,01 bis 4 Gew.-%, vorteilhafterweise bei 0,1 bis 4 Gew.-% und ganz besonders bevorzugt bei 0,5 bis 3 Gew.-%.Solubilizers, for example for dyes and perfume oils, can be used, for example, as alkanolamines, polyols such as ethylene glycol, representatives of the lower alcohols such as propylene glycol, glycerol and other mono- and polyhydric alcohols, and also alkylbenzenesulfonates with 1 to 3 carbon atoms in the alkyl radical. The group of lower alcohols, particularly ethanol, is particularly preferred. Preferred amounts are up to 5% by weight, in particular 0.01 to 4% by weight, advantageously 0.1 to 4% by weight and very particularly preferably 0.5 to 3% by weight.
Zu den üblichen Verdickungsmitteln, die bei Bedarf zusätzlich ebenfalls einsetzbar wären, zählen Harnstoff, Natriumchlorid, Natriumsulfat, Magnesiumsulfat, Ammoniumchlorid und Magnesiumchlorid sowie die Kombination dieser Verdickungsmittel. Der Einsatz dieser zusätzlichen Verdickungsmittel ist jedoch nicht bevorzugt.The usual thickeners, which could also be used if required, include urea, sodium chloride, sodium sulfate, magnesium sulfate, ammonium chloride and magnesium chloride and the combination of these thickeners. However, the use of these additional thickeners is not preferred.
In den erfindungsgemäßen Reinigungsmitteln können ggf. wasserlösliche und wasserunlösliche Builder enthalten sein. Dabei sind dann wasserlösliche Builder
bevorzugt, da sie auf harten Oberflächen in der Regel weniger dazu tendieren, unlösliche Rückstände zu bilden. Übliche Builder oder Komplexbildner, die im Rahmen der Erfindung zugegen sein können, sind die niedermolekularen Polycarbonsäuren und ihre Salze, die homopolymeren und copolymeren Polycarbonsäuren und ihre Salze, die Citronensäure und ihre Salze, die Carbonate, Phosphate und Silikate. Zu wasserunlöslichen Buildern zählen die Zeolithe, die ebenfalls verwendet werden können, ebenso wie Mischungen der vorgenannten Buildersubstanzen. Besonders bevorzugt ist die Gruppe der Citrate. Vorzugsweise enthalten die erfindungsgemäßen Mittel Builder oder Komplexbildner in Mengen bis zu 10 Gew.-% insbesondere 0,1 bis 8 Gew.-%, besonders bevorzugt 1 bis 6 Gew.-% und ganz besonders bevorzugt 2 bis 5 Gew.-%.
Water-soluble and water-insoluble builders may be present in the cleaning agents according to the invention. Then there are water-soluble builders preferred because they tend to have less tendency to form insoluble residues on hard surfaces. Customary builders or complexing agents which can be present in the context of the invention are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the citric acid and their salts, the carbonates, phosphates and silicates. Water-insoluble builders include the zeolites, which can also be used, as well as mixtures of the abovementioned builder substances. The group of citrates is particularly preferred. The agents according to the invention preferably contain builders or complexing agents in amounts of up to 10% by weight, in particular 0.1 to 8% by weight, particularly preferably 1 to 6% by weight and very particularly preferably 2 to 5% by weight.
BeispieleExamples
Die nachfolgenden Beispiele sollen einige der bevorzugten erfindungsgemäßen Zusammensetzungen beschreiben. Dabei wurde die Leistungsfähigkeit mit folgenden Methoden bestimmt.The following examples are intended to describe some of the preferred compositions of the invention. The performance was determined using the following methods.
Viskositätviscosity
Die Messung der Viskosität in den aufgeführten Beispielen erfolgte mit einem Brookfield Roto Viskosimeter, Rotationsviskosimeter, Typ RVT mit Helipath- Einrichtung und der Spindel TA bei 1 Upm und 23 °C.The viscosity in the examples listed was measured using a Brookfield Roto viscometer, rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
Schaumverhaltentest nach WagnerFoam behavior test according to Wagner
0,1 g Gel werden in 500 ml Leitungswasser 17 °d in einem 1000 ml Meßzylinder mit 40 Hüben bei einer Drehgeschwindigkeit von 100 Upm aufgeschäumt. Das Gebilde des Schaumvolumens wird nach 1 , 3 und 10 min abgelesen.0.1 g of gel are foamed in 500 ml of tap water at 17 ° d in a 1000 ml measuring cylinder with 40 strokes at a rotation speed of 100 rpm. The structure of the foam volume is read after 1, 3 and 10 min.
AbspülverhaltenRinsing behavior
Die Messung erfolgt auf einer automatisch gesteuerten WC-Anlage, die in Abständen von 1 Stunde den Inhalt des Wasserkastens abgibt und den Kasten neu mit 9 I Leitungswasser mit 17 °d und einer Wassertemperatur von 15 - 16 °C füllt. Es wird jeweils 1 Füllung eines Gefäßes gemäß der DE 195 201 45 in die Toiletten eingehängt und festgestellt, wieviel Spülungen bis zum vollständigen Verbrauch möglich sind. Die Durchschnittsergebnisse werden aus 5 Parallelversuchen ermittelt.The measurement is carried out on an automatically controlled toilet system, which dispenses the contents of the water tank every 1 hour and refills the tank with 9 liters of tap water at 17 ° d and a water temperature of 15 - 16 ° C. In each case 1 filling of a vessel according to DE 195 201 45 is hung in the toilets and it is determined how many flushes are possible until it is completely used up. The average results are determined from 5 parallel tests.
Bestimmung des KalklösevermögensDetermination of descaling ability
Vorgewogene weiße Carrara-Marmorplatten mit der Abmessung 75 x 150 x 5 mm werden in einer Plexiglasküvette vollständig in das Gel eingetaucht. Dies geschieht für eine Zeit von 10 sec. Danach wird die Platte entnommen und senkrecht in ein dafür vorgesehenes Stativ gestellt. Das hat so zu geschehen, daß anhaftendes Produkt ablaufen kann. Die Einwirkzeit des anhaftenden
Produktes beträgt weitere 10 min. Danach wird die Platte mit Wasser abgespült und nach Trocknung bei 105 °C der Gewichtsverlust ermittelt.Pre-weighed white Carrara marble slabs measuring 75 x 150 x 5 mm are completely immersed in the gel in a plexiglass cell. This is done for a time of 10 seconds. The plate is then removed and placed vertically in a stand provided for this purpose. This has to be done in such a way that adhering product can run off. The exposure time of the adhesive Product is another 10 min. The plate is then rinsed with water and the weight loss is determined after drying at 105 ° C.
pH-WertPH value
Die Messung erfolgte elektrochemisch im Konzentrat.The measurement was carried out electrochemically in the concentrate.
LagerstabilitätStorage stability
Die Lagerung erfolgte in elektrisch gesteuerten Wärmekammem. Die Lagerzeit bei 40 °C beträgt 3 und 4 Wochen, bei 23 °C 12 Wochen. Danach erfolgte eine visuelle Abmusterung der gelagerten Ware.The storage took place in electrically controlled heat chambers. The storage time at 40 ° C is 3 and 4 weeks, at 23 ° C 12 weeks. This was followed by a visual inspection of the stored goods.
Beispiel 1example 1
Reinigungs-Gel mit Kalklösung auf Basis eines nichtionischenCleaning gel with lime solution based on a non-ionic
TensidsystemsSurfactant systems
Mengenangaben in Gew.-%Quantities in% by weight
Xanthan Gum granuliert, z.B. Keltrol® RD 2,3Xanthan gum granulated, e.g. Keltrol® RD 2.3
C8 - 10 Alkylpolyglycosid 16,0C 8-10 alkyl polyglycoside 16.0
Parfümöle Zitronennote 5,0Perfume oils lemon note 5.0
Citronensäure 3,0Citric acid 3.0
Ethanol 3,0Ethanol 3.0
Farbstoff, wasserlöslich < 0,01Dye, water soluble <0.01
Wasser add 100Water add 100
Viskosität 70.000 - 75.000 mPas pH-Wert 2,6Viscosity 70,000 - 75,000 mPas pH 2.6
Gel-Struktur/Aussehen transparentes GelGel structure / appearance transparent gel
Füllmenge 40 g40 g capacity
Abspülverhalten 220 Spülungen bei 21 Spülungen/TagRinsing behavior 220 rinses at 21 rinses / day
Schaumverhalten 300 ml nach 1 min; 300 ml nach 3 min; 250 ml nach 10 min Kalklösevermögen 193 mg CalciumcarbonatFoam behavior 300 ml after 1 min; 300 ml after 3 min; 250 ml after 10 min descaling capacity 193 mg calcium carbonate
Lagerstabilität 4 Wochen bei 40 °C keine Phasentrennung
12 Wochen bei 23 °C keine PhasentrennungStorage stability 4 weeks at 40 ° C no phase separation No phase separation for 12 weeks at 23 ° C
Herstellungsvariante 1 :Production variant 1:
Die Herstellung kann in den unterschiedlichsten Ansatzgrößen bis zumThe production can be in a wide variety of batch sizes up to
Tonnenmaßstab durchgeführt werden. Üblicherweise wird Wasser in einer handelsüblichen Mischeranlage, wie z. B. einer Beco-Mix-Anlage vorgelegt, und der Farbstoff eingerührt. Der verwendete Xanthan Gum wird mit Lösungsmittel, bevorzugt Ethanol und dem gewünschten Parfumöl separat aufgeschlämmt. DieTone scale can be carried out. Usually, water is in a commercial mixer, such as. B. submitted to a Beco mix system, and the dye stirred. The xanthan gum used is slurried separately with solvent, preferably ethanol and the desired perfume oil. The
Suspension wird der wässerigen Vorlage zugegeben und mit geringenSuspension is added to the aqueous template and with small
Geschwindigkeiten, beispielsweise 30 Upm gerührt.Speeds, for example 30 rpm, are stirred.
Es zeigt sich bei den Untersuchungen, daß nach Zugabe aller Komponenten eineThe investigations show that after all components have been added, a
Zeit zwischen wenigen Minuten und einigen Stunden zur Erreichung der erfindungsgemäßen Konsistenz wünschenswert ist. Im vorliegenden Fall wurde nach 30 min das Tensid (Alkylpolyglycosid) langsam zudosiert. Anschließend wurde die Zitronensäure zugesetzt.Time between a few minutes and a few hours is desirable to achieve the consistency according to the invention. In the present case, the surfactant (alkyl polyglycoside) was slowly added after 30 minutes. The citric acid was then added.
Soll ein blasenfreies Gel gewährleistet werden, ist die Mischung in einem geeigneten Behälter in Abhängigkeit von der Viskosität in der Regel aber für eine kurze Zeit, beispielsweise 15 min unter reduzierten Druck oder ein Vakuum zu setzen.If a bubble-free gel is to be ensured, the mixture should, as a rule, be placed in a suitable container depending on the viscosity for a short time, for example 15 minutes under reduced pressure or under a vacuum.
Die Abfüllung in die geeigneten Vorratsbehälter kann dann z. B. über einen geeigneten handelsüblichen Tubenfüller erfolgen.The filling in the appropriate storage container can then, for. B. via a suitable commercially available tube filler.
Beispiel 2Example 2
Reinigungs-Gel mit Kalklösung und DesinfektionsmittelCleaning gel with lime solution and disinfectant
Gew.-%% By weight
Xanthan Gum 2,70Xanthan gum 2.70
C8 - 10 Alkylpolyglucosid 5,44C 8-10 alkyl polyglucoside 5.44
Parfüm Apfelnote 6,00Perfume apple note 6.00
Citronensäure 1 H2O 3,30Citric acid 1 H2O 3.30
Ethanol 3,00Ethanol 3.00
Halbacetale-Isothiazoline-Kombination 0, 15
Farbstoff Blau / Farbstoff Gelb < 0,01Semi-acetal isothiazoline combination 0, 15 Blue dye / yellow dye <0.01
Wasser add 100Water add 100
Viskosität 65. 000- 70.000 mPas pH-Wert , 2,6Viscosity 65,000-70,000 mPas pH , 2.6
Gel-Struktur/Aussehen transparentes GelGel structure / appearance transparent gel
Füllmenge 50 gFilling quantity 50 g
Abspülverhalten 250 Spülungen bei 21 Spülungen/TagRinsing behavior 250 rinses at 21 rinses / day
Schaumverhalten 310 ml nach 1 min; 300 ml nach 3 min; 270 ml nach 10 min Kalklösevermögen 190 mg CalciumcarbonatFoaming behavior 310 ml after 1 min; 300 ml after 3 min; 270 ml after 10 min descaling capacity 190 mg calcium carbonate
Lagerstabilität 4 Wochen bei 40 °C Luftblasen im Gel stabilStorage stability 4 weeks at 40 ° C air bubbles in the gel stable
12 Wochen bei 23 °C keine PhasentrennungNo phase separation for 12 weeks at 23 ° C
Herstellungsvariante 2:Production variant 2:
Die Herstellung kann auch hier in den unterschiedlichsten Ansatzgrößen bis zumHere, too, production can be carried out in a wide variety of batch sizes up to
Tonnenmaßstab durchgeführt werden.Tone scale can be carried out.
Üblicherweise wird hier Wasser in einer handelsüblichen Mischeranlage, wie z. B. einer Beco-Mix-Anlage vorgelegt und der verwendete Xanthan Gum eingerührt .Usually water is here in a commercial mixer, such as. B. submitted to a Beco mix system and stirred in the xanthan gum used.
Die Suspension wird der Vorlage zugegeben und mit geringenThe suspension is added to the template and with low
Geschwindigkeiten, beispielsweise 30 Upm gerührt, bevor nach 30 min dasSpeeds, for example 30 rpm, before the after 30 min
Tensid (bzw. das Tensidgemisch; siehe nachfolgende Beispiele) langsam zudosiert wurde. Anschließend wurde der Farbstoff zugegeben, bevor eine ethanolische Lösung des Parfüms nachdosiert wurde. Danach wurde dasSurfactant (or the surfactant mixture; see examples below) was slowly added. The dye was then added before an ethanolic solution of the perfume was replenished. After that it was
Desinfektionsmittel zugegeben.Disinfectant added.
Die Abfüllung kann in diesem Fall z. B. über einen Flaschenrundläufer in eine handelsübliche Dosierflasche erfolgen.The filling can in this case, for. B. done in a commercial dosing bottle via a rotary bottle.
Beispiel 3Example 3
Reinigungs-Gel mit Komplexbildner und DesinfektionsmittelCleaning gel with complexing agent and disinfectant
Gew.-% Polysaccharid (Keltrol RD) 2,9
C8 - 10 Alkylpolyglucosid 5,4% By weight of polysaccharide (Keltrol RD) 2.9 C 8-10 alkyl polyglucoside 5.4
C-12-14 Fettalkylethersulfat mit 2 EO 8,1C-12-14 fatty alkyl ether sulfate with 2 EO 8.1
Trinatriumcitrat 5,0Trisodium citrate 5.0
Parfümöl Missouri (Lucta) 91025 P 6,0Perfume oil Missouri (Lucta) 91025 P 6.0
Ethanol 3,0Ethanol 3.0
Salicylsäure 0,3Salicylic acid 0.3
Farbstoff, wasserl. Blau / Gelb < 0,01Dye, waterl. Blue / yellow <0.01
Wasser ad 100Water ad 100
Viskosität 70.000 mPas pH-Wert 10,0Viscosity 70,000 mPas pH 10.0
Gel-Struktur/Aussehen transparentes GelGel structure / appearance transparent gel
Füllmenge 40 g40 g capacity
Abspülverhalten 230 Spülu ngen bei 21 Spülungen/ TagRinsing behavior 230 rinses at 21 rinses / day
Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keineStorage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C none
PhasentrennungPhase separation
Herstellung wie Beispiel 1Preparation as in example 1
Beispiel 4Example 4
Duftverstärktes Reinigungs-GelFragrance-enhanced cleaning gel
Gew.-%% By weight
Polysaccharid (Keltrol RD) 2,5Polysaccharide (Keltrol RD) 2.5
C8 - 10 Alkylpolyglucosid 12,0C 8-10 alkyl polyglucoside 12.0
C12-14 Alkylpolyglucosid 2,5C12-14 alkyl polyglucoside 2.5
C12-14 Fettalkylethersulfat mit 2 EO 2,8C12-14 fatty alkyl ether sulfate with 2 EO 2.8
Citronensäure 3,0Citric acid 3.0
Parfümöl Apfelnote (TTF) 88-3813 10,0Perfume oil apple note (TTF) 88-3813 10.0
Ethanol 3,0Ethanol 3.0
Farbstoff, wasserl. Blau < 0,01 %Dye, waterl. Blue <0.01%
Wasser ad 100
Viskosität 87.000 mPas pH-Wert 3,5Water ad 100 Viscosity 87,000 mPas pH 3.5
Gel-Struktur/Aussehen trübes Gel mit LuftblasenGel structure / appearance cloudy gel with air bubbles
Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keineStorage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C none
PhasentrennungPhase separation
Herstellung: wie Beispiele 1, 2Production: as examples 1, 2
Beispiel 5Example 5
Hochduftaktives Reinigungs-Gel mit maximalem ParfümgehaltHighly fragrant cleansing gel with maximum perfume content
Gew.-% Polysaccharid (Keltrol T) 2,6% By weight polysaccharide (Keltrol T) 2.6
C8 - 10 Alkylpolyglucosid 16,0C 8-10 alkyl polyglucoside 16.0
C-12-14 Ethersulfat mit 2 EO 2,8 Citronensäure 3,0C-12-14 ether sulfate with 2 EO 2.8 citric acid 3.0
Parfümöl Apfelnote (TTF) 88-3813 15,0Perfume oil apple note (TTF) 88-3813 15.0
Ethanol 6,0Ethanol 6.0
Halbacetale-Isothiazolin-Kombination 0, 15Semi-acetal isothiazoline combination 0, 15
Farbstoff, wasserl. Blau / Gelb < 0,01 %Dye, waterl. Blue / yellow <0.01%
Wasser ad 100Water ad 100
Viskosität 95.000 mPas pH-Wert 3,6Viscosity 95,000 mPas pH 3.6
Gel-Struktur/Aussehen trübes Gel mit cremigem CharakterGel structure / appearance cloudy gel with a creamy character
Füllmenge 35 gCapacity 35 g
Abspülverhalten 300 Spülungen bei 21 Spülungen/TagRinsing behavior 300 rinses at 21 rinses / day
Schaumverhalten 100 ml 1 min; 80 ml 3 min; 50 ml 10 min.Foaming behavior 100 ml 1 min; 80 ml 3 min; 50 ml 10 min.
Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keineStorage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C none
PhasentrennungPhase separation
Herstellung: wie Beispiel 1Production: as example 1
Die Einarbeitung von hohen Parfumgehalten bedarf u. U. kleinerer Dosierschritte, um die Phasenstabilität noch zu gewährlwisten.
Beispiel 6The incorporation of high perfume contents may require U. smaller dosing steps to ensure the phase stability. Example 6
Hochviskoses Reinigungs-Gei mit erhöhter HaltbarkeitHighly viscous cleaning gel with increased durability
Gew.-%% By weight
Polysaccharid (Keltrol RD) 4,5Polysaccharide (Keltrol RD) 4.5
C8 - 10 Alkylpolyglucosid 16,0C 8-10 alkyl polyglucoside 16.0
C12-14 Ethersulfat mit 2 EO 2,9C12-14 ether sulfate with 2 EO 2.9
Citronensäure 3,5Citric acid 3.5
Parfümöl Apfelnote (TTF) 88-3813 6,0Perfume oil apple note (TTF) 88-3813 6.0
Ethanol 3,5Ethanol 3.5
Salicylsäure 0,2Salicylic acid 0.2
Farbstoff, wasserl. Blau / Gelb < 0,01Dye, waterl. Blue / yellow <0.01
Wasser ad 100Water ad 100
Viskosität 148.000 mPas pH-Wert 3,6Viscosity 148,000 mPas pH 3.6
Gel-Struktur/Aussehen frisches, leicht trübes Gel mit LuftblasenGel structure / appearance fresh, slightly cloudy gel with air bubbles
Füllmenge 50 gFilling quantity 50 g
Abspülverhalten 500 Spülungen bei 21 Spülungen/TagRinsing behavior 500 rinses at 21 rinses / day
Schaumverhalten 290 ml nach 1 min, 290 ml nach 3 min, 250 ml nach 10 min Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keine Phasentrennung Herstellung: wie Beispiel 1Foaming behavior 290 ml after 1 min, 290 ml after 3 min, 250 ml after 10 min Storage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C no phase separation Production: as in Example 1
Beispiel 7Example 7
Viskoses Reinigungs-Gel mit AmphotensidViscous cleaning gel with amphoteric surfactant
Gew.-% Polysaccharid (Keltrol T) 2,7% By weight polysaccharide (Keltrol T) 2.7
C8 - 10 Alkylpolyglucosid 12,8
Fettsäureamidderivat m. Betainstruktur (DehytonK) 10,0C 8-1 0 alkyl polyglucoside 12.8 Fatty acid amide derivative m. Betaine structure (DehytonK) 10.0
Citronensäure 3,0Citric acid 3.0
Parfümöl Citrusnote (TTF) 15-0596-A 5,0Perfume oil Citrus Note (TTF) 15-0596-A 5.0
Ethanol 2,5Ethanol 2.5
Halbacetale-Isothiazolin-Kombination 0, 15Semi-acetal isothiazoline combination 0, 15
Farbstoff, wasserl. Gelb < 0,01Dye, waterl. Yellow <0.01
Wasser ad 100Water ad 100
Viskosität 90.000 mPas pH-Wert 3,5Viscosity 90,000 mPas pH 3.5
Gel-Struktur/Aussehen transparentes GelGel structure / appearance transparent gel
Füllmenge 40 g40 g capacity
Abspülverhalten 280 Spülungen bei 21 Spülungen/TagRinsing behavior 280 rinses at 21 rinses / day
Schaumverhalten 250 ml 1 min; 200 ml 3 min; 150 ml 10 minFoaming behavior 250 ml 1 min; 200 ml 3 min; 150 ml 10 min
Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keineStorage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C none
PhasentrennungPhase separation
Herstellung: wie Beispiel 1Production: as example 1
Beispiel 8Example 8
Reinigungs-Gel mit SchaumboosterCleaning gel with foam booster
Gew.-%% By weight
Polysaccharid (Keltrol RD) 2,0Polysaccharide (Keltrol RD) 2.0
C8 - 10 Alkylpolyglucosid 5,4C 8-10 alkyl polyglucoside 5.4
C12-14 FAS (Texapon LS 35) 5,7C12-14 FAS (Texapon LS 35) 5.7
Kokosfettsäurediethanolamid 2,0Coconut fatty acid diethanolamide 2.0
Citronensäure 3,5Citric acid 3.5
Parfümöl Citrusnote (TTF) 92-4536 6,0Perfume oil Citrus Note (TTF) 92-4536 6.0
Ethanol 3,0Ethanol 3.0
Halbacetale-Isothiazolin-Kombination 0, 15Semi-acetal isothiazoline combination 0, 15
Farbstoff, wasserl. Blau < 0,01Dye, waterl. Blue <0.01
Wasser ad 100
Viskosität 53.000 mPas pH-Wert 3,5Water ad 100 Viscosity 53,000 mPas pH 3.5
Gel-Struktur/Aussehen trübes GelGel structure / appearance cloudy gel
Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keineStorage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C none
PhasentrennungPhase separation
Herstellung: wie Beispiel 1 + Zusatz von Fettsäurediethanolamid.Production: as example 1 + addition of fatty acid diethanolamide.
Beispiel 9Example 9
Reinigungs-Gel mit erhöhtem KalklösevermögenCleaning gel with increased descaling power
Gew.-%% By weight
Polysaccharid (Keltrol T) 2,8Polysaccharide (Keltrol T) 2.8
C8 - 10 Alkylpolyglucosid 5,4C 8-10 alkyl polyglucoside 5.4
Cι2-ι Ethersulfat mit 2 EO 8,1Cι 2 -ι ether sulfate with 2 EO 8.1
Citronensäure 10,0Citric acid 10.0
Parfümöl Cool water (TTF) 96-5239 4,5Perfume oil Cool water (TTF) 96-5239 4.5
Ethanol 3,0Ethanol 3.0
Halbacetale-Isothiazolin-Kombination 0,15Semi-acetal isothiazoline combination 0.15
Farbstoff, wasserl. Blau / Gelb < 0,01Dye, waterl. Blue / yellow <0.01
Wasser ad 100Water ad 100
Viskosität 72.000 mPas pH-Wert 2,3Viscosity 72,000 mPas pH 2.3
Gel-Struktur/Aussehen opakes GelGel structure / appearance of opaque gel
Lagerstabilität:4 Wochen bei 40 °C und nach 12 Wochen bei 23 °C keineStorage stability: 4 weeks at 40 ° C and after 12 weeks at 23 ° C none
PhasentrennungPhase separation
Herstellung: wie Beispiel 1
Beispiel 11Production: as example 1 Example 11
Reinigungsgel auf Nio-TensidbasisCleaning gel based on nio-surfactants
Gew.-%% By weight
Polysaccharid (Keltrol T) 2,5Polysaccharide (Keltrol T) 2.5
C8 - C10 Alkylpolyglucosid 5,4C 8 -C 10 alkyl polyglucoside 5.4
Fettalkohol Cι2-Cι8 + 7 EO (Dehydol LT 7) 10,0Fatty alcohol Cι 2 -Cι 8 + 7 EO (Dehydol LT 7) 10.0
Citronensäure 3,0Citric acid 3.0
Parfümöl Citrusnote 5,1Perfume oil citrus note 5.1
Ethanol 3,0Ethanol 3.0
Halbacetale-Isothiazolin-Kombination 0,05Semi-acetal isothiazoline combination 0.05
Farbstoff wasserlösl. Blau + Gelb < 0,01Dye water-soluble Blue + yellow <0.01
Wasser ad 100Water ad 100
Viskosität 100.000 mPas pH-Wert 2,8Viscosity 100,000 mPas pH 2.8
Gel-Struktur/Aussehen klar, transparentes GelGel structure / appearance clear, transparent gel
Lagerstabilität 3 Wochen 40 °C keine PhasentrennungStorage stability 3 weeks 40 ° C no phase separation
12 Wochen 23 °C keine Phasentrennung Herstellung: wie Beispiel 212 weeks at 23 ° C. no phase separation. Production: as in example 2
Vergleichs-Beispiele mit anderen Gelbildenden SystemenComparative examples with other gel-forming systems
A1 , A2 Kochsalzverdicktes TensidsystemA1, A2 Saline-thickened surfactant system
B1 , B2, B3 Gel auf PolyacrylsäurebasisB1, B2, B3 gel based on polyacrylic acid
C1 Gel auf Hydroxyethylcellulose-BasisC1 Hydroxyethyl cellulose-based gel
Kochsaizverdicktes TensidsystemKochsaiz thickened surfactant system
Gew.-% Gew.-%% By weight% by weight
Natriumchlorid 1 ,0 5,0Sodium chloride 1.0 5.0
C12-M Fettalkoholethersulfat + 2 EO 5,6 6,0
Fettsäureamid mit Betainstruktur Dehyto )nn KK 33,,33 3,5C12-M fatty alcohol ether sulfate + 2 EO 5.6 6.0 Fatty acid amide with betaine structure dehyto) nn KK 33,, 33 3.5
Parfüm Citrus 1 ,0 6,0Perfume Citrus 1.0, 6.0
Wasser ad 100 100Water ad 100 100
Viskosität 60,000 mPas 18.000 mPas pH-Wert 9,0 9,0Viscosity 60,000 mPas 18,000 mPas pH 9.0 9.0
Gel-Struktur/Aussehen klar, leicht trübeGel structure / appearance clear, slightly cloudy
Haltbarkeit verdünnt sich beim Abspülen stark mit Wasser.Shelf life dilutes heavily with water when rinsed off.
Keine stabile Viskosität. Fließt nach dem Einfüllen aus dem Behältnis.Not a stable viscosity. Flows out of the container after filling.
Vergleichs-Beispiele B1, B2, B3 Gel auf PolyacrylsäurebasisComparative examples B1, B2, B3 gel based on polyacrylic acid
Gew.- •% Gew.-% Gew.-0/% By weight% by weight% by weight 0 /
Polyacrylsäure (Carbopol® ETD 2690) 1 ,0 - -Polyacrylic acid (Carbopol® ETD 2690) 1, 0 - -
ETD 2691 - 1 ,0 -ETD 2691 - 1, 0 -
EZ 2 - - 1 ,0EZ 2 - - 1, 0
C8-ιo Alkylpolyglucosid 5,4 5,4 5,4C 8 -IO alkyl polyglucoside 5.4 5.4 5.4
Ci2-ι4 Fettalkoholethersulfat + 2 EO 8,12 8,12 8,12Ci2-ι 4 fatty alcohol ether sulfate + 2 EO 8.12 8.12 8.12
Parfümöl Apfelnote 6,0 6,0 6,0Perfume oil apple note 6.0 6.0 6.0
Ethanol 3,0 3,0 3,0Ethanol 3.0 3.0 3.0
Triethanolamin 1 ,8 2,0 2,2Triethanolamine 1, 8 2.0 2.2
Farbstoff < 0,1 < 0,1 < 0,1Dye <0.1 <0.1 <0.1
Wasser ad 100 ad 100 ad 100Water ad 100 ad 100 ad 100
Viskosität 200 mPas pH-Wert 7,5 8,0 8,5Viscosity 200 mPas pH 7.5 8.0 8.5
Gel-Struktur/Aussehen trübe, , gerinc ) viskose Flüssigkeit ohne Gel-Gel structure / appearance cloudy,, gerinc) viscous liquid without gel
Bildungeducation
Haltbarkeit fließt undosierbar aus dem Behältnis
Vergleichs-Beispiel C1Shelf life flows undosably from the container Comparative example C1
Gel auf Hydroxyethylcellulose-BasisHydroxyethyl cellulose-based gel
Gew.-%% By weight
Natrosol 250 HHBR 2,5Natrosol 250 HHBR 2.5
C8-ιo Alkylpolyglucosid 5,4C 8 -ιo alkyl polyglucoside 5.4
C12-14 Fettalkoholethersulfat + 2 EO 8,12C12-14 fatty alcohol ether sulfate + 2 EO 8.12
Ethanol 3,0Ethanol 3.0
Parfümöl Apfelnote 6,0Perfume oil apple note 6.0
Trinatriumcitrat 3,0Trisodium citrate 3.0
Farbstoff, Konservierungsmittel < 1 ,0Dye, preservative <1, 0
Wasser ad 100Water ad 100
Viskosität nicht zu ermitteln, da das entstehende Gel sofort nach derViscosity not to be determined, since the resulting gel immediately after the
Parfümzugabe phasensepariert. pH-Wert 7,5
Perfume addition phase separated. pH 7.5
Claims
1. Stabiles gelförmiges scherverdünnendes Reinigungsmittel enthaltend Polysaccarid, als Tensidsystem ein C8- bis C22-Alkylpolyglycosid und Parfümkomponenten, dadurch gekennzeichnet, daß1. Stable gel-form shear thinning detergent containing polysaccharide, as a surfactant system a C 8 - to C22 alkyl polyglycoside and perfume components, characterized in that
• ein Polysaccharid in Mengen zwischen 1 und 5 Gew.-%,A polysaccharide in amounts between 1 and 5% by weight,
• als eine Komponente des Tensidsystems ein C8 bis C22 Alkylpolyglycosid in Mengen zwischen 3 und 25 Gew.-% und• As a component of the surfactant system, a C 8 to C 2 2 alkyl polyglycoside in amounts between 3 and 25% by weight and
• die Parfümkomponente oder die Parfümkomponenten in Mengen von 2 bis 15 Gew.-%The perfume component or the perfume components in amounts of 2 to 15% by weight
• sowie ggf. weitere Inhaltsstoffe wie Co-Tenside, kalklösende Mittel, Farbstoffe, keimhemmende Mittel, Perlglanzmittel, Stabilisatoren, Reinigungsverstärker und Geruchsabsorber enthalten sind, wobei• and possibly other ingredients such as co-surfactants, lime-dissolving agents, dyes, germ-inhibiting agents, pearlescent agents, stabilizers, cleaning enhancers and odor absorbers are included
• die Mittel eine Viskosität von 30 000 bis 150 000 mPas aufweisen, gemessen mit einem Brookfield Rotationsviskosimeter, Typ RVT mit Helipath-Einrichtung und der Spindel TA bei 1 Upm und 23 °C.• The agents have a viscosity of 30,000 to 150,000 mPas, measured with a Brookfield rotary viscometer, type RVT with Helipath device and the spindle TA at 1 rpm and 23 ° C.
2. Mittel nach Anspruch 1 , dadurch gekennzeichnet, daß es ein Polysaccharid, vorzugsweise ein Xanthan-Gum, in Mengen zwischen 1 und 4 Gew.-%, vorzugsweise zwischen 1 ,5 und 3,5 Gew.-% und insbesondere zwischen 1 ,8 und 3 Gew.-% enthält.2. Composition according to claim 1, characterized in that it is a polysaccharide, preferably a xanthan gum, in amounts between 1 and 4 wt .-%, preferably between 1, 5 and 3.5 wt .-% and in particular between 1, Contains 8 and 3 wt .-%.
3. Mittel nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß es C8- bis C22- Alkylpolyglycoside in Mengen von 4 bis 20 Gew.-%, vorzugsweise von 5 bis 17 Gew.-% und insbesondere von 5 bis 15 Gew.-% enthält.3. Composition according to claim 1 or 2, characterized in that there are C 8 - to C 22 - alkyl polyglycosides in amounts of 4 to 20 wt .-%, preferably from 5 to 17 wt .-% and in particular from 5 to 15 wt. -% contains.
4. Mittel nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß es die Parfümkomponente(n) in Mengen von 2 bis 12 Gew.-% und vorzugsweise von 3 bis 8 Gew.-% enthält.
4. Composition according to one of claims 1 to 3, characterized in that it contains the perfume component (s) in amounts of 2 to 12 wt .-% and preferably from 3 to 8 wt .-%.
5. Mittel nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß es Luftblasen, vorzugsweise solche mit 0,1 bis 20 mm Durchmesser enthält, wobei vorteilhafterweise nicht mehr als 30 Vol.-% Luft enthalten sind.5. Composition according to one of claims 1 to 4, characterized in that it contains air bubbles, preferably those with 0.1 to 20 mm in diameter, advantageously not containing more than 30 vol .-% air.
6. Mittel nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß als kalklösende Mittel anorganische oder organische Säuren oder deren Salze oder deren Gemische, bevorzugt Zitronensäure, Essigsäure, Milchsäure in Mengen von 1 bis 12 Gew.-%, bevorzugt in 2 bis 5 Gew.-% enthalten sind.6. Composition according to one of claims 1 to 5, characterized in that inorganic or organic acids or their salts or mixtures thereof, preferably citric acid, acetic acid, lactic acid in amounts of 1 to 12% by weight, preferably in 2 to, as descaling agents 5 wt .-% are included.
7. Mittel nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß ein Farbstoff, bevorzugt in wasserlöslicher Form, in Mengen bis zu 5 Gew.-% bevorzugt bis 3 Gew.-%, besonders bevorzugt bis 2 Gew.-% und ganz besonders bevorzugt bis zu 1 Gew.-% enthalten ist.7. Composition according to one of claims 1 to 6, characterized in that a dye, preferably in water-soluble form, in amounts up to 5 wt .-%, preferably up to 3 wt .-%, particularly preferably up to 2 wt .-% and entirely up to 1% by weight is particularly preferably contained.
8. Mittel nach einem der Ansprüche 1 bis 7, dadurch gekennzeichnet, daß ein keimhemmendes Mittel, bevorzugt ausgewählt aus der Gruppe der Isothiazoline, der Benzoate oder der Salicylsäure oder Salicylate, in Mengen bis zu 5 Gew.-%, bevorzugt 0,01 bis 3 Gew.-%, besonders bevorzugt 0,01 bis 2 Gew.-% und ganz besonders bevorzugt 0,01 bis 1 Gew.-% enthalten ist.8. Agent according to one of claims 1 to 7, characterized in that a germ-inhibiting agent, preferably selected from the group of isothiazolines, benzoates or salicylic acid or salicylates, in amounts up to 5 wt .-%, preferably 0.01 to 3 wt .-%, particularly preferably 0.01 to 2 wt .-% and very particularly preferably 0.01 to 1 wt .-% is included.
9. Mittel nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, daß ein Builder oder Komplexbildner, bevorzugt ausgewählt aus der Gruppe der Citrate, in Mengen bis zu 10 Gew.-%, bevorzugt 0,1 bis 8 Gew.-%, besonders bevorzugt 1 bis 6 Gew.-% und ganz besonders bevorzugt 2 bis 5 Gew.-% enthalten ist.9. Composition according to one of claims 1 to 8, characterized in that a builder or complexing agent, preferably selected from the group of citrates, in amounts up to 10 wt .-%, preferably 0.1 to 8 wt .-%, particularly preferably 1 to 6% by weight and very particularly preferably 2 to 5% by weight.
10. Mittel nach einem der Ansprüche 1 bis 9, dadurch gekennzeichnet, daß ein Lösungsmittel, bevorzugt ausgewählt aus der Gruppe der niederen Alkohole in Mengen bis zu 5 Gew.-%, bevorzugt 0,01 bis 4 Gew.-%, besonders bevorzugt 0,1 bis 4 Gew.-% und ganz besonders bevorzugt 0,5 bis 3 Gew.- % enthalten ist.
10. Agent according to one of claims 1 to 9, characterized in that a solvent, preferably selected from the group of lower alcohols in amounts up to 5 wt .-%, preferably 0.01 to 4 wt .-%, particularly preferably 0 , 1 to 4 wt .-% and very particularly preferably 0.5 to 3 wt .-% is included.
11. Mittel nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, daß als zusätzliche Co-Tenside Fettalkoholethersulfate (FAEOS) und/oder Fettalkoholsulfate (FAS) enthalten sind, wobei das Gewichtsverhältnis Alkylpolyglycosid zu Co-Tensid bevorzugt mindestens 1 , vorzugsweise zwischen 50:1 und 1 :1 , besonders bevorzugt zwischen 10:1 und 1 ,5 zu 1 und ganz besonders bevorzugt zwischen 5:1 und 1 ,8:1 liegt.11. Composition according to one of claims 1 to 10, characterized in that fatty alcohol ether sulfates (FAEOS) and / or fatty alcohol sulfates (FAS) are contained as additional co-surfactants, the weight ratio of alkyl polyglycoside to co-surfactant preferably being at least 1, preferably between 50: 1 and 1: 1, particularly preferably between 10: 1 and 1.5 to 1 and very particularly preferably between 5: 1 and 1.8: 1.
12. Verfahren zur Herstellung der Reinigungsmittel nach einem der Ansprüche 1 bis 11 , dadurch gekennzeichnet, daß das Polysaccarid in einem Lösungsmittel aus der Gruppe der niederen einwertigen Alkohole, bevorzugt Ethanol, mit dem gewünschten Parfümöl separat aufgeschlämmt, zu einer wässerigen Lösung gegeben wird, die einen Farbstoff enthalten kann, und dann, gegebenenfalls nach einer Wartezeit zwischen wenigen Minuten und mehreren Stunden, das Tensid oder das Tensidgemisch langsam zudosiert wird und anschließend mit weiteren Inhaltsstoffen versetzt wird, bevor gewünschtenfalls für einen Zeitraum zwischen wenigen Minuten und mehreren Stunden ein reduzierter Druck angelegt wird.12. A process for the preparation of the cleaning agents according to any one of claims 1 to 11, characterized in that the polysaccharide, suspended separately in a solvent from the group of the lower monohydric alcohols, preferably ethanol, with the desired perfume oil, is added to an aqueous solution which can contain a dye, and then, if necessary after a waiting time of between a few minutes and several hours, the surfactant or the surfactant mixture is slowly metered in and then further ingredients are added before, if desired, a reduced pressure is applied for a period of between a few minutes and several hours becomes.
13. Verwendung der Reinigungsmittel nach einem der Ansprüche 1 bis 11 als Reinigungsmittel für Spültoiletten.
13. Use of the cleaning agent according to one of claims 1 to 11 as a cleaning agent for flush toilets.
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DK98921455T DK0975721T3 (en) | 1997-04-16 | 1998-04-11 | Gel-shaped detergent for flushing toilets |
| BR9811461-1A BR9811461A (en) | 1997-04-16 | 1998-04-11 | Gel cleaner for toilets |
| DE59811584T DE59811584D1 (en) | 1997-04-16 | 1998-04-11 | GEL-SHAPED DETERGENT FOR RINSING TOILETS |
| US09/403,150 US6336977B1 (en) | 1998-04-11 | 1998-04-11 | Gelled cleaning agent for flush toilets |
| AT98921455T ATE269389T1 (en) | 1997-04-16 | 1998-04-11 | GEL CLEANING AGENT FOR FLUSH TOILETS |
| CA002287449A CA2287449A1 (en) | 1997-04-16 | 1998-04-11 | Gelled cleaning agent for flush toilets |
| EP98921455A EP0975721B1 (en) | 1997-04-16 | 1998-04-11 | Gelled cleaning agent for flush toilets |
| JP54347498A JP2001518969A (en) | 1997-04-16 | 1998-04-11 | Gel detergent for flush toilet |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19715872A DE19715872C2 (en) | 1997-04-16 | 1997-04-16 | Gel-shaped detergent for flush toilets |
| DE19715872.2 | 1997-04-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1998046712A1 true WO1998046712A1 (en) | 1998-10-22 |
Family
ID=7826682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP1998/002123 WO1998046712A1 (en) | 1997-04-16 | 1998-04-11 | Gelled cleaning agent for flush toilets |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP0975721B1 (en) |
| JP (1) | JP2001518969A (en) |
| AT (1) | ATE269389T1 (en) |
| BR (1) | BR9811461A (en) |
| CA (1) | CA2287449A1 (en) |
| DE (2) | DE19715872C2 (en) |
| DK (1) | DK0975721T3 (en) |
| ES (1) | ES2224390T3 (en) |
| WO (1) | WO1998046712A1 (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999066017A1 (en) * | 1998-06-12 | 1999-12-23 | Buck-Chemie Gmbh & Co. | Adhesive sanitary agent |
| GB2360293A (en) * | 2000-03-14 | 2001-09-19 | Procter & Gamble | Detergent compositions |
| GB2364709A (en) * | 2000-07-12 | 2002-02-06 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system |
| GB2364710A (en) * | 2000-07-12 | 2002-02-06 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system |
| US7048205B2 (en) | 2000-07-12 | 2006-05-23 | S.C. Johnson & Son, Inc. | Lavatory freshening and/or cleaning system and method |
| US7541325B2 (en) * | 2001-01-11 | 2009-06-02 | Joker Ag | Agent for removing solid particles |
| EP2212408A1 (en) * | 2007-11-01 | 2010-08-04 | The Clorox Company | Acidic cleaning compositions |
| WO2011014241A1 (en) * | 2009-07-31 | 2011-02-03 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| EP2662435A1 (en) | 2012-05-11 | 2013-11-13 | Eurvest | Sanitary composition |
| WO2014180579A1 (en) | 2013-05-10 | 2014-11-13 | Eurvest Sa | New sanitary composition |
| US9169456B2 (en) | 2008-02-21 | 2015-10-27 | S.C. Johnson & Son, Inc. | Cleaning composition comprising an ethoxylated alcohol blend, having high self-adhesion and providing residual benefits |
| US9175248B2 (en) | 2008-02-21 | 2015-11-03 | S.C. Johnson & Son, Inc. | Non-ionic surfactant-based cleaning composition having high self-adhesion and providing residual benefits |
| US9410111B2 (en) | 2008-02-21 | 2016-08-09 | S.C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US9481854B2 (en) | 2008-02-21 | 2016-11-01 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
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| DE19853110A1 (en) * | 1998-11-18 | 2000-05-25 | Cognis Deutschland Gmbh | Gel-shaped detergent for flush toilets |
| DE19906481A1 (en) * | 1999-02-17 | 2000-08-24 | Cognis Deutschland Gmbh | Gel-shaped detergent for flush toilets |
| DE19910788A1 (en) * | 1999-03-11 | 2000-09-14 | Cognis Deutschland Gmbh | Gel-shaped detergent for flush toilets |
| DE19918191A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent for hard surfaces, especially flush toilet pans, comprising a mixture of alk(en)yl oligoglycoside, alk(en)yl (ether)sulfate and/or betaine, and ethoxylated glucoside ester |
| DE19918185A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Hard surface detergent, typically in form of high foaming viscous gel, includes oligoglycoside derivative, glycerin fatty acid ester and sulfate or betaine component |
| DE19918182A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent for hard surfaces, especially flush toilet pans, comprising a mixture of alk(en)yl oligoglycoside, alk(en)yl (ether)sulfate and/or betaine, and cellulosepolyglycolester |
| DE19918192A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent for hard surfaces, especially flush toilet pans, comprising a mixture of alk(en)yl oligoglycoside, alk(en)yl (ether)sulfate and/or betaine, and terpene alcohol |
| DE19918184A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent for hard surfaces, especially flush toilet pans, comprising a mixture of alk(en)yl oligoglycoside, alk(en)yl (ether)sulfate and/or betaine, and fatty alcoholpolyglycolether with narrow homologue distribution |
| DE19918186A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent, typically in form of viscous gel, includes oligoglycoside derivative, poly(meth)acrylamidoalkyl alkanesulfonic acid and sulfate or betaine component |
| DE19918188A1 (en) | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent, especially for cleaning toilet bowls, is typically in form of high foaming viscous gel and includes ethoxylated fatty amine as a thickener |
| DE19918189A1 (en) * | 1999-04-22 | 2000-10-26 | Cognis Deutschland Gmbh | Cleaning agent for hard surfaces, especially flush toilet pans, comprising a mixture of alk(en)yl oligoglycoside, alk(en)yl (ether)sulfate and/or betaine, and alkanediol |
| DE19924368A1 (en) * | 1999-05-27 | 2000-11-30 | Henkel Ecolab Gmbh & Co Ohg | Cleaning tablets containing surfactants |
| DE10012949A1 (en) | 2000-03-16 | 2001-09-27 | Henkel Kgaa | Mixtures of cyclic and linear silicic esters of lower alcohols and fragrance and/or biocide alcohols are used as fragrance and/or biocide in liquid or solid laundry and other detergents and in skin and hair cosmetics |
| DE10048887A1 (en) * | 2000-09-29 | 2002-04-18 | Buck Chemie Gmbh | Adhesive sanitary cleaner and fragrance |
| JP4541076B2 (en) * | 2004-09-07 | 2010-09-08 | 京都リフレ新薬株式会社 | Urine stone adhesion inhibitor |
| DE102004056554A1 (en) * | 2004-11-23 | 2006-05-24 | Buck-Chemie Gmbh | Adhesive sanitary cleaning and scenting agent |
| JP2005330498A (en) * | 2005-05-09 | 2005-12-02 | Sara Lee De Nv | Freshener-/cleaner-system for lavatory |
| EP1894989A1 (en) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Pasty Composition for Sanitary Ware |
| EP1894990A1 (en) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Unit dose of pasty composition for sanitary ware |
| EP1894578A1 (en) * | 2006-09-01 | 2008-03-05 | The Procter and Gamble Company | Method of applying a pasty composition for sanitary ware |
| ES2422261T5 (en) | 2008-02-21 | 2017-05-12 | S.C. Johnson & Son, Inc. | Cleaning composition that has high self-adhesion and provides residual benefits |
| DE102009001841A1 (en) * | 2009-03-25 | 2010-09-30 | Henkel Ag & Co. Kgaa | System of detergent and dispenser |
| JP5579593B2 (en) * | 2010-12-22 | 2014-08-27 | ニュートリー株式会社 | Jelly cleaning composition |
| JP2016526057A (en) * | 2013-04-25 | 2016-09-01 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Cleaning composition with improved distribution and suspendability |
| DE102013226098A1 (en) | 2013-12-16 | 2015-06-18 | Henkel Kgaa | Silyl enol ethers of fragrance ketones or aldehydes |
| DE102013226216A1 (en) | 2013-12-17 | 2015-06-18 | Henkel Ag & Co. Kgaa | Michael systems for perfume stabilization |
| DE102013226602A1 (en) | 2013-12-19 | 2015-06-25 | Henkel Ag & Co. Kgaa | Use of CNGA2 agonists to enhance the olfactory effect of a fragrance |
| EP2963103A1 (en) | 2014-07-04 | 2016-01-06 | Henkel AG & Co. KGaA | pH-sensitive nanocapsules |
| DE102017123282A1 (en) | 2017-10-06 | 2019-04-11 | Henkel Ag & Co. Kgaa | Hydrolysis-labile silyl enol ethers of fragrance ketones or aldehydes |
| DE102017124612A1 (en) | 2017-10-20 | 2019-04-25 | Henkel Ag & Co. Kgaa | Hydrolysis-labile dienol silyl ethers of fragrance ketones or aldehydes |
| DE102017124611A1 (en) | 2017-10-20 | 2019-04-25 | Henkel Ag & Co. Kgaa | Thermolabile fragrance storage substances of fragrance ketones |
| DE102017127776A1 (en) | 2017-11-24 | 2019-05-29 | Henkel Ag & Co. Kgaa | Hydrolysis-labile heterocycles of perfume ketones or aldehydes |
| DE102018210801A1 (en) * | 2018-06-29 | 2020-01-02 | Henkel Ag & Co. Kgaa | Self-adhesive foaming sanitary products |
| EP3722401B1 (en) * | 2019-04-10 | 2024-01-17 | Henkel AG & Co. KGaA | Gel sanitary agent for biofilm inhibition |
| EP4098734A1 (en) | 2021-06-02 | 2022-12-07 | Henkel AG & Co. KGaA | Wc system with multiphase gel composition |
| DE102022121759A1 (en) | 2022-08-29 | 2024-02-29 | Henkel Ag & Co. Kgaa | TEMPERATURE STABLE GEL COMPOSITIONS |
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| EP0323209A2 (en) * | 1987-12-30 | 1989-07-05 | Unilever Plc | Detergent compositions |
| WO1990012082A1 (en) * | 1989-04-11 | 1990-10-18 | Unilever Plc | Cleaning composition |
| US5047167A (en) * | 1987-12-30 | 1991-09-10 | Lever Brothers Company, Division Of Conopco, Inc. | Clear viscoelastic detergent gel compositions containing alkyl polyglycosides |
| WO1992006161A1 (en) * | 1990-09-28 | 1992-04-16 | The Procter & Gamble Company | Detergent compositions containing polyhydroxy fatty acid amides and suds enhancing agent |
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| US4668422A (en) * | 1985-05-31 | 1987-05-26 | A. E. Staley Manufacturing Company | Liquid hand-soap or bubble bath composition |
| GB9103090D0 (en) * | 1991-02-14 | 1991-04-03 | Unilever Plc | Hair care compositions |
-
1997
- 1997-04-16 DE DE19715872A patent/DE19715872C2/en not_active Expired - Lifetime
-
1998
- 1998-04-11 DK DK98921455T patent/DK0975721T3/en active
- 1998-04-11 WO PCT/EP1998/002123 patent/WO1998046712A1/en active IP Right Grant
- 1998-04-11 CA CA002287449A patent/CA2287449A1/en not_active Abandoned
- 1998-04-11 DE DE59811584T patent/DE59811584D1/en not_active Expired - Lifetime
- 1998-04-11 BR BR9811461-1A patent/BR9811461A/en not_active Application Discontinuation
- 1998-04-11 ES ES98921455T patent/ES2224390T3/en not_active Expired - Lifetime
- 1998-04-11 AT AT98921455T patent/ATE269389T1/en active
- 1998-04-11 JP JP54347498A patent/JP2001518969A/en active Pending
- 1998-04-11 EP EP98921455A patent/EP0975721B1/en not_active Expired - Lifetime
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| EP0323209A2 (en) * | 1987-12-30 | 1989-07-05 | Unilever Plc | Detergent compositions |
| US5047167A (en) * | 1987-12-30 | 1991-09-10 | Lever Brothers Company, Division Of Conopco, Inc. | Clear viscoelastic detergent gel compositions containing alkyl polyglycosides |
| WO1990012082A1 (en) * | 1989-04-11 | 1990-10-18 | Unilever Plc | Cleaning composition |
| WO1992006161A1 (en) * | 1990-09-28 | 1992-04-16 | The Procter & Gamble Company | Detergent compositions containing polyhydroxy fatty acid amides and suds enhancing agent |
| GB2288186A (en) * | 1994-02-17 | 1995-10-11 | Kelco Int Ltd | Toilet cleansing gel block |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999066017A1 (en) * | 1998-06-12 | 1999-12-23 | Buck-Chemie Gmbh & Co. | Adhesive sanitary agent |
| US6667286B1 (en) | 1998-06-12 | 2003-12-23 | Buck-Chemie Gmbh | Adhesive sanitary agent |
| GB2360293A (en) * | 2000-03-14 | 2001-09-19 | Procter & Gamble | Detergent compositions |
| GB2364709A (en) * | 2000-07-12 | 2002-02-06 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system |
| GB2364710A (en) * | 2000-07-12 | 2002-02-06 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system |
| GB2364710B (en) * | 2000-07-12 | 2003-01-15 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system and method |
| GB2364709B (en) * | 2000-07-12 | 2004-12-22 | Johnson & Son Inc S C | Lavatory freshening and/or cleaning system and method |
| AU2001273339B2 (en) * | 2000-07-12 | 2005-07-14 | S.C. Johnson & Son, Inc. | Lavatory freshening and/or cleaning system and method |
| US7048205B2 (en) | 2000-07-12 | 2006-05-23 | S.C. Johnson & Son, Inc. | Lavatory freshening and/or cleaning system and method |
| US7541325B2 (en) * | 2001-01-11 | 2009-06-02 | Joker Ag | Agent for removing solid particles |
| AU2008319172B2 (en) * | 2007-11-01 | 2014-02-13 | The Clorox Company | Acidic cleaning compositions |
| EP2212408A1 (en) * | 2007-11-01 | 2010-08-04 | The Clorox Company | Acidic cleaning compositions |
| EP2212408A4 (en) * | 2007-11-01 | 2011-04-20 | Clorox Co | Acidic cleaning compositions |
| US9243214B1 (en) | 2008-02-21 | 2016-01-26 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US9296980B2 (en) | 2008-02-21 | 2016-03-29 | S.C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US10597617B2 (en) | 2008-02-21 | 2020-03-24 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US8143206B2 (en) | 2008-02-21 | 2012-03-27 | S.C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US10435656B2 (en) | 2008-02-21 | 2019-10-08 | S. C. Johnson & Son, Inc. | Cleaning composition comprising a fatty alcohol mixture having high self-adhesion and providing residual benefits |
| US9169456B2 (en) | 2008-02-21 | 2015-10-27 | S.C. Johnson & Son, Inc. | Cleaning composition comprising an ethoxylated alcohol blend, having high self-adhesion and providing residual benefits |
| US9175248B2 (en) | 2008-02-21 | 2015-11-03 | S.C. Johnson & Son, Inc. | Non-ionic surfactant-based cleaning composition having high self-adhesion and providing residual benefits |
| US9181515B2 (en) | 2008-02-21 | 2015-11-10 | S.C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US10392583B2 (en) | 2008-02-21 | 2019-08-27 | S. C. Johnson & Son, Inc. | Cleaning composition with a hydrophilic polymer having high self-adhesion and providing residual benefits |
| US10266798B2 (en) | 2008-02-21 | 2019-04-23 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US9399752B2 (en) | 2008-02-21 | 2016-07-26 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US9410111B2 (en) | 2008-02-21 | 2016-08-09 | S.C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US9481854B2 (en) | 2008-02-21 | 2016-11-01 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US9771544B2 (en) | 2008-02-21 | 2017-09-26 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US9982224B2 (en) | 2008-02-21 | 2018-05-29 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits comprising a cationic/nonionic surfactant system |
| AU2010276734B2 (en) * | 2009-07-31 | 2012-12-06 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| WO2011014241A1 (en) * | 2009-07-31 | 2011-02-03 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| EP2662435A1 (en) | 2012-05-11 | 2013-11-13 | Eurvest | Sanitary composition |
| WO2014180579A1 (en) | 2013-05-10 | 2014-11-13 | Eurvest Sa | New sanitary composition |
Also Published As
| Publication number | Publication date |
|---|---|
| DE19715872C2 (en) | 1999-04-29 |
| EP0975721A1 (en) | 2000-02-02 |
| BR9811461A (en) | 2000-09-12 |
| DK0975721T3 (en) | 2004-10-25 |
| DE19715872A1 (en) | 1998-10-22 |
| DE59811584D1 (en) | 2004-07-22 |
| CA2287449A1 (en) | 1998-10-22 |
| JP2001518969A (en) | 2001-10-16 |
| EP0975721B1 (en) | 2004-06-16 |
| ES2224390T3 (en) | 2005-03-01 |
| ATE269389T1 (en) | 2004-07-15 |
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