WO1998048991A1 - Wound product cores and processes for making them - Google Patents
Wound product cores and processes for making them Download PDFInfo
- Publication number
- WO1998048991A1 WO1998048991A1 PCT/US1998/008691 US9808691W WO9848991A1 WO 1998048991 A1 WO1998048991 A1 WO 1998048991A1 US 9808691 W US9808691 W US 9808691W WO 9848991 A1 WO9848991 A1 WO 9848991A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sludge
- core
- paper
- making
- binder material
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21J—FIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
- D21J3/00—Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds
- D21J3/04—Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds of tubes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S162/00—Paper making and fiber liberation
- Y10S162/09—Uses for paper making sludge
Definitions
- the present invention is directed to the field of making useful products, such as cores for tissue and other rolled or wound products, from papermaking fiber sludge.
- Paper is conventionally made by draining a low consistency dispersion of cellulose fiber pulp, fillers, and additives through a paper machine "wire" (essentially an endless mesh or sieve). A certain amount of solid material passes through the wire with the suspending water and is, thus, not retained in the wet paper web formed on the wire.
- the drained liquid suspension known generally in the industry as “white water,” carries entrained solid material. White water from which the suspended particles have been removed is re-used in the papermaking process to the extent possible.
- wastepaper if it can be recycled, is a much cheaper and environmentally friendly source of wood pulp for making paper.
- wastepaper Before wastepaper can be reused as recycle material, however, the wastepaper must be de-inked. De-inking processes remove inks and coating materials from the wood fibers. Thus, when recycled fibers, as opposed to virgin pulps, are used in the papermaking process, the drained liquid suspension will contain additional types of waste materials such as inks and hot melt adhesives.
- Unused white water and de-inking effluents must be treated before being discharged from the paper mill. Treatment normally involves passing the effluent through a clarifier, prior to which flocculants are added to promote sedimentation of solid material suspended in the water. A biological treatment with microorganisms is also commonly performed to reduce the biological oxygen demand (BOD) of the liquid effluent before it is discharged. As can be expected, disposal of the unused white water and de-inked effluents results in costs to the papermaking facility.
- BOD biological oxygen demand
- the sediment accumulated in the clarifier is a sludge composed of pulp fibers, fiber particles or fines, fillers, pigments, and other miscellaneous debris such as grit, sand, plastic particles, general dirt.
- Many of the sludge components are fillers, pigments and the like that were added to the pulp during the sheet-forming process for the purpose of producing desired properties in the finished paper.
- Such properties include proper surface, opacity, strength and brightness.
- finely ground inorganic fillers such as talc, certain clays, calcium carbonate, blanc fixe, and titanium dioxide may be added to papers to improve surface smoothness, whiteness, printability and opacity.
- Sizing agents such as soaps, gelatins, and rosins (with alum), wax emulsions and starches, may be added to papers for improving resistance to penetration by liquids.
- coloring agents such as acid, basic, direct and sulfur dyes and natural and synthetic pigments may be added for coloring purposes. Any of such products may ultimately end up in the clarifier as part of the sludge.
- the clarifier is usually a large open- air tank, other debris such as leaves, branches, insects, etc. can also become part of paper sludge.
- the major constituents of the sludge are generally fiber/fines and the inorganic fillers calcium carbonate and clay.
- de-inking processes involve the use of flotation and washing.
- wastepaper is first washed and then pulped with dilute sodium hydroxide or surfactants in a pulper tank to cause the fibers to swell and loosen the ink and coating material particles contained thereon.
- these coating materials include the previously mentioned clays, talc, etc.
- the pulp stocks go through screening, cleaning, washing, floatation, and bleaching to further remove trash, stickies, inks, ash, and short fiber fines. During the washing and floatation stages, most ash, stickies, and short fiber fines are separated from the pulp stock.
- this sludge may also have accumulations of adhesives (otherwise known as “stickies”), foreign bodies (such as pieces of plastic material or metal, otherwise known as “contraries”) in very small quantities, and other additives, such as those described above, that are used in the papermaking process.
- adhesives otherwise known as “stickies”
- foreign bodies such as pieces of plastic material or metal, otherwise known as “contraries”
- additives such as those described above, that are used in the papermaking process.
- the sludge is drawn off from the clarifier at about 2.5 percent consistency (or "percent dry solids content") and is then dewatered to a consistency of around 20 to 55 percent, for example, by means of rotary vacuum filters, screw presses, or belt presses.
- Dewatering reduces the weight of material going to the landfill and reduces the charges for landfill disposal because these are typically based on weight. Since the majority of the weight in the sludge comes from water, it behooves the sludge processor to remove as much water as possible.
- the dewatered sludge is in a semi-solid state and usually contains about 40 percent to about 80 percent by dry weight relatively fine wood fibers and from about 20 percent to about 60 percent inorganics (also referred to as "ash") and the additives mentioned above.
- the material typically is a crumbly, not very cohesive material that appears to be dry. At thirty percent consistency, most sludges are more like dry solids as opposed to a suspension or dispersion. Because of the non-cohesive character of sludge, the materials handling equipment for moving, storing and transporting are generally the same as for dry materials. Once in this state, the sludge is then capable of being collected and transported for disposal in landfills.
- This sludge is produced by both papermaking from virgin pulp and papermaking from recycled fibers.
- a typical de-inking plant employing recycled fibers processes about 100 dry tons of waste paper into about 65 to about 80 dry tons of recycled (reusable) fiber. The remaining 20 to 35 tons of waste paper is unusable, and becomes part of the sludge produced by the deinking plant.
- recycled fiber sludge is dewatered with various suitable dewatering devices, including, for example, a belt press or screw press, 100 dry tons of waste paper still produce from about 70 to about 120 wet tons of sludge which must be disposed.
- the sludge produced during the making of tissue from an integrated mill with a recycled fiber plant produces 10 times the amount of sludge produced during the making of tissue from virgin pulp.
- the typical virgin pulp tissue making process produces 10 tons of sludge per day at the typical commercial plant while the typical tissue making with recycled fiber plant produces 100 tons of sludge per day.
- Conventional methods for disposing of sludges include landfill, land spreading, composting and incineration. Landfill and land spreading sites are being depleted at an alarming rate, and the establishment of new sites is difficult due to environmental concerns.
- the cost associated with using landfills to dispose of sludge is constantly increasing. For example, paper manufacturers typically spend about $30/wet ton to send sludge to the landfill.
- sludge disposal techniques include processing the sludge into pellets for fuel or into lightweight aggregates for construction, pyrolysis, gasification, and incorporation into cements.
- these techniques generally require the use of complex methods and expensive equipment.
- attempts to recycle sludge to make paper have been unsuccessful because the process is inefficient due to drainage problems resulting from the presence of slow drying fines which tend to clog the wires and other equipment.
- pellets can be used as absorbents or chemical carriers, e.g., fertilizer. Alternatively, large diameter pellets or cylinders are used as fuel.
- U.S. Patent No. 4,303,019 to Haataia discloses the making of pallets by molding paper mill sludge blended with a fibrous reinforcing material.
- U.S. Patent No. 5,215,625 to Burton discloses the making of products such as stepping stones, acoustic paneling, flower pots and planters, sculptures, shipping containers and packing materials, and the like, from waste products such as ink and waste slurry from pulp manufacturing.
- the incorporation of de-inking byproducts from wastepaper recycling operations and pulp mill clarifier sludge into drywall and other gypsum-based building products is disclosed in U.S. Patent No. 5,496,441 to Iran.
- U.S. Patent No. 5,478,441 to Hamilton discloses a process for recovering such raw materials.
- U.S. Patent No. 5,332,474 to Maxham discloses a process for producing a papermaking filler product from the fiber fines/clay fraction of a pulp, paper, paperboard, or deinking mill waste solids. While considerable prior art exists with regard to methods for handling, utilizing or recycling of sludge as outlined above, in actual fact there has been little commercial implementation. The majority of the materials classified as sludge from both deinking operations as well as conventional pulp and paper mills ends up in landfills or is discarded or disposed of in some other way. The major reason is that few of the many procedures available to convert sludges can produce products that have significant value.
- the purpose for the added inorganic material is to provide superior opacity.
- incorporation of clay as a coating or filler and calcium carbonate as a filler also provide improvements to the surface of the paper such that the quality of the printing is improved.
- wood pulp even though it is a renewable resource, is becoming more expensive. The cost of wood pulp currently exceeds the cost of calcium carbonate or clay, and it, therefore, makes economic sense to include considerable amounts of these fillers in paper.
- Rolled, or wound, paper products such as toilet tissue and kitchen towels are generally marketed on paperboard cores in the shape of a tube. These cores are commonly made by winding two narrow webs of paperboard core stock into a tube on a special mandrel while gluing the webs. Typically, the paperboard web will pass through an adhesive and then will be wound in spring-like fashion around a mandrel by a winding machine. Processes for making cores are disclosed in U.S. Patent Nos. 5,573,638 and 5,586,963, both to Lennon et al.
- the winding of papers onto the cores usually occurs in a continuous manner with the cores being fed to a turret tissue winder after making.
- the cores are rotated into position to have tissue wound onto them until they are of the proper diameter.
- the finished rolls are then rotated to another position and ejected from the machine while a new core is inserted.
- the cores are usually made in lengths equal to the width of the parent tissue reel exiting the paper machine producing the tissue or paper product to be wound on the core. After the tissue or paper is wound onto the long cores, the cores (with paper rolled thereon) are cut into smaller, consumer-width rolls by sharp metal discs or saws. As soon as the consumer-sized rolls are cut, they are grouped into singles, pairs, or other configurations and then wrapped or inserted into plastic bags for shipping.
- Cores are typically made of unbleached Kraft paper. Generally, the pulp for such paper is obtained by recycling corrugated fibers from paper bags or corrugated boxes. If white cores are desired, then the pulp will be bleached. It would be beneficial if a waste product, such as sludge, could be used to replace all or some of the paper necessary for making such cores.
- Another object of the present invention is to provide a winding core made from waste materials.
- papermaking processes include the making of paper from virgin pulp and/or recycled fiber, the making of virgin pulp from wood or other cellulosic materials, and the making of recycled fiber from waste paper.
- the process involves providing the waste sludge, drying it, mixing it with binders such as adhesives, including resins, starches, or the like, and then compressing the mixture into cores.
- the compression can be carried out by extrusion or by molding. Extrusion can be by continuous extruders such as heated single- screw extruders. Zoned heating may be utilized.
- a volume reduction extruder may be employed if the sludge is not first dried.
- a molding process may be used as the compression step to obtain the desired cores.
- the mixture is provided, for example, to a mold with a dual cylinder arrangement wherein an inner cylinder made of heat or pressure expandable materials is housed within an outer rigid cylinder or wherein the inner cylinder is rigid and the outer cylinder is radially contractible. After holding the temperature for a certain time, compression is released and the desired molded core is obtained.
- Fig. 1 is a schematic block diagram illustrating one embodiment of the present process for making wound product cores
- Fig. 2 is a schematic block diagram illustrating another embodiment of the present process for making wound product cores
- Fig. 3 is a plan view of a core of the present invention
- Fig. 4 is a plan view of a core of the present invention having a paper product wound there around in accordance with the present invention.
- the present invention is directed to a core around which a product, usually a paper product such as tissue, paper towels, wrapping paper, or the like, is wrapped, or rolled.
- a product usually a paper product such as tissue, paper towels, wrapping paper, or the like
- the core could be the parent roll for use on the winding machines.
- Such cores are much longer and thicker than the cores upon which the final product, such as tissue, paper towels, -or wrapping paper, is wound.
- the core of the present invention is made from sludge produced during the process of making paper from virgin wood pulp, the making of virgin pulp from cellulosic materials, the making of paper from recycled fiber, or the making of recycled fiber from waste paper (all referred to herein as papermaking processes).
- the sludge is mixed with a binder material and is then compressed by various methods into the inventive cores.
- the present invention involves obtaining sludge produced during a papermaking process.
- the sludge is typically subjected to a pressing process which increases the solids content of the sludge to somewhere in the range of about 30 percent to about 50 percent by weight solids.
- Such presses are common to paper mills and are typically used to dry the produced sludges to acceptable solids contents. With typical belt presses, a solids content of about 30 percent to about 40 percent will be obtained. With typical screw presses, a solids content of about 40 percent to about 50 percent will be obtained. It is to be understood, however, that the stated solids content of sludge is not meant to be limiting, but is merely an example of typical contents found in waste sludge from paper plants.
- the pressed sludge may then be treated with an optional drying process to result in a dried sludge with about 90 percent to about 100 percent by weight solids.
- the prepared sludge is mixed with binder materials such as adhesives like starches or resins.
- the compression mechanism is either an extruder which can extrude the mixture into roll tubes or a mold which can allow the tubes to be molded.
- the cores made from the present process may then be used as winder cores upon which products such as paper towels and tissues may be rolled or wound.
- the first step in the process is obtaining the necessary virgin pulp sludge or recycled fiber sludge.
- sludges are housed in a sludge tank 20 at the mill or, in some plants, may come directly from a press 30 after being subjected to the herein described dewatering process.
- Press 30 may comprise any type of press, all of which would be recognized as applicable by one having ordinary skill in the art.
- the sludge may then be further dried by using the optional dryer 40 shown in the Figures.
- the mixture is then provided to a mixer 50 where a relatively homogenous mixture is obtained.
- Suitable binder materials 70 such as adhesives, including resins, are added to mixer 50. At this point, other materials, such as pulp, may also be added to increase the strength characteristics of the ultimate product.
- the mixture is then provided to a suitable compression means, typically either an extruder 60 ( Figure 1 ) or a mold 80 ( Figure 2), for forming the cores.
- dryers which may be used in the optional drying step include conveyor or belt dryers, flash dryers, fluidized bed dryers, paddle dryers, rotary dryers, spiral screw dryers, tumble dryers, and vibrating dryers. If the drying step is not used, the moisture within the sludge will be removed from the sludge during a heated compression step.
- Suitable binder materials that may be mixed with the sludge during the mixing step include any materials that will bind the sludge sufficiently to allow it to be molded or extruded under pressure into a relatively rigid article of manufacture.
- the binder agents will cure at temperatures above the boiling point of water and less than about 240° F.
- the preferred binders will cure at a temperature of between about 212°F and about 240°F.
- the temperatures used herein are given as pressure equivalent temperatures which means that the stated temperatures are those achieved at ambient pressure. If greater pressure is applied, a lower temperature will be equivalent. Likewise, if less pressure is applied, a higher temperature will be equivalent.
- Suitable binders include both dry strength agents and wet strength agents. Some binders may require the presence of water to achieve mixability with certain types of sludge. However, if water is added, it should be kept to a minimum, since the water will ultimately affect the mechanical strength of any article ultimately formed during the inventive process. If the finished cores are to be used for items which are normally not in contact with water, i.e., regular tissue or jumbo tissue cores, a dry strength agent can be used. Suitable dry strength agents include natural starch, ionic starch, polyvinyl alcohol, polyacrylamide, lignosulphate, and carboxymethyl cellulose. Other agents providing characteristics similar to those listed may also be used.
- wet strength agents include polyamide-epichlorohydrin resins, polyacrylamide resins, insolubilized polyvinyl alcohol, polyethylenimine resins, and urea and melamine formaldehyde resins.
- Suitable wet strength agents include polyamide-epichlorohydrin resins, polyacrylamide resins, insolubilized polyvinyl alcohol, polyethylenimine resins, and urea and melamine formaldehyde resins.
- Kymene® sold by Hercules, Inc.
- Other agents providing characteristics similar to those listed may also be used.
- High-intensity mixers are the most suitable ones for use in the present process. High-intensity mixing ensures dispersion of the binders into the dried sludge. Mixer such as ribbon mixers, spiral mixers, kneaders, high-shear mixers, rotary blade mixers and screw mixers may be utilized. Generally, the sludge/binder mixture should be mixed until substantially homogenous. The less homogenous the mixture, the less strength the ultimate product will have. Compression of the mixed sludge/adhesive to achieve curing of the binder material and ensure sufficient evaporation of the liquid components may be carried out by various processes. The most common processes for use in the present invention are extrusion and molding.
- Extrusion can be carried out by continuous extruders such as heated single-screw or twin-screw extruders, typical of the type of extruders used to make PVC piping. If heated twin-screw extruders are used, then the mixing of the binders and the sludge may be carried out in the extruder.
- water vapor is evaporated to obtain the desired solids contents, which may vary depending on the mechanical strength desired. Heating can also be accomplished in zones to provide better control of moisture release. The heat and pressure assists in releasing the small amount of moisture remaining as the core exits the extrusion die.
- the heat applied will generally be somewhere within the range of from about
- a volume reduction extruder device may be employed.
- the volume within the extruder is constantly reduced between the point the mixture enters the device until the point the mixture enters the die. In this manner, formation pressure on the mixture is gradually increased as volume is gradually decreased. This allows for excess moisture to be evaporated as the mixture moves through the extrusion.
- the length of the die, the relative sizes of the inner and outer compression cylinders, the heat applied, and the speed of extrusion will affect the final product produced by this, as with any, extrusion device.
- the dryness of the mixture entering into the extruder will depend on the flow characteristics of the mixture. In a normal extruder, the process temperature may be lower. Excess moisture will be further removed after the extruded product exits the die. This would also broaden the range of suitable binding agents for the present invention.
- Compression may also be carried out in a mold.
- the sludge/binder mixture is poured into a mold that is in the form of the core.
- the mold will consist of two different diameter coaxial hollow cylinders. The smaller diameter cylinder is inside the larger one.
- the structure of the outer cylinder is solid and rigid while the inner cylinder is made of heat or pressure-expandable materials, such as thermoplastic polymers or rubber.
- the structure of the inner cylinder is rigid and the outer cylinder is made of radially contractible materials.
- the inner expandable cylinder is expanded radially by high pressure hydraulic fluid or heat in one arrangement, or the outer contractible cylinder is contracted radially.
- the mixture is compressed toward the inner wall of the outside cylinder and the outer wall of the inside cylinder in either arrangement. Simultaneously with the compression or contraction, an external press compresses the mixture tangentially. After a certain compression ratio is achieved, the compressing is held constant for a certain time to ensure that the mixture is molded into the final core form. After the release of the compression, the molded core is removed.
- the desired strength of the cores will determine the variations in the amount of binder materials, the extrusion or molding pressure, the curing times, and the curing methods (vacuum or heat).
- core 100 is a hollow cylindrical tube having an outer surface 110 and inner surface 120.
- This core is the product made according to the presently described processes.
- the length of the core tube will depend on the width of the product to be wound onto the core. As indicated above, longer rolls may be cut into smaller width sections for commercial use.
- a typical core with a paper product wound thereon is shown in Figure 4.
- Tissue 130 is wrapped concentrically around the outer surface 110 of core 100.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU71705/98A AU7170598A (en) | 1997-04-30 | 1998-04-30 | Wound product cores and processes for making them |
CA002288229A CA2288229A1 (en) | 1997-04-30 | 1998-04-30 | Wound product cores and processes for making them |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/846,697 | 1997-04-30 | ||
US08/846,697 US6146498A (en) | 1997-04-30 | 1997-04-30 | Wound product cores and processes for making them |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998048991A1 true WO1998048991A1 (en) | 1998-11-05 |
Family
ID=25298685
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/008691 WO1998048991A1 (en) | 1997-04-30 | 1998-04-30 | Wound product cores and processes for making them |
Country Status (9)
Country | Link |
---|---|
US (1) | US6146498A (en) |
AR (1) | AR012646A1 (en) |
AU (1) | AU7170598A (en) |
CA (1) | CA2288229A1 (en) |
CO (1) | CO5021236A1 (en) |
CR (1) | CR5769A (en) |
MY (1) | MY132804A (en) |
TW (1) | TW407175B (en) |
WO (1) | WO1998048991A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015097346A1 (en) * | 2013-12-23 | 2015-07-02 | Upm-Kymmene Corporation | A method for manufacturing a material composition, a material composition and a use and a composite product |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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US6699426B1 (en) * | 1999-06-15 | 2004-03-02 | National Gypsum Properties, Llc. | Gypsum wallboard core, and method and apparatus for making the same |
SE0102801D0 (en) * | 2001-08-23 | 2001-08-23 | Kmi Kemimaeklarna Internat Ab | Recycle product |
US20040065419A1 (en) * | 2002-10-04 | 2004-04-08 | Vicente Lasmarias | Removal of contaminants from recycled paper fibers |
NZ582254A (en) * | 2007-06-28 | 2012-07-27 | Buckman Labor Inc | Use of cyclodextrins for odor control in papermaking sludges, and deodorized sludge and products |
EP2658686A1 (en) * | 2010-12-27 | 2013-11-06 | Amanda Patent & Licensing SIA | Sanding device |
EP2658687A1 (en) * | 2010-12-27 | 2013-11-06 | Amanda Patent & Licensing SIA | Sanding device |
CN102825646B (en) * | 2011-06-17 | 2016-06-15 | 太仓市鑫海纸业有限公司 | The making method of a kind of cellulosic bobbin |
CN103603222A (en) * | 2013-11-05 | 2014-02-26 | 湖南广信科技股份有限公司 | Process for producing shaping plates by using waste paper, plates and waste plastics |
US9777129B2 (en) * | 2014-04-11 | 2017-10-03 | Georgia-Pacific Consumer Products Lp | Fibers with filler |
US9777143B2 (en) | 2014-04-11 | 2017-10-03 | Georgia-Pacific Consumer Products Lp | Polyvinyl alcohol fibers and films with mineral fillers and small cellulose particles |
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US5215625A (en) * | 1992-03-02 | 1993-06-01 | Burton R Edward | Method for producing articles from waste fiber, waste/surplus paint, and waste/surplus ink |
US5478441A (en) * | 1992-06-17 | 1995-12-26 | The Wiggins Teape Group Limited | Recovery and re-use of raw materials from paper mill waste sludge |
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-
1997
- 1997-04-30 US US08/846,697 patent/US6146498A/en not_active Expired - Fee Related
-
1998
- 1998-04-29 CO CO98023612A patent/CO5021236A1/en unknown
- 1998-04-30 CR CR5769A patent/CR5769A/en unknown
- 1998-04-30 AU AU71705/98A patent/AU7170598A/en not_active Abandoned
- 1998-04-30 CA CA002288229A patent/CA2288229A1/en not_active Abandoned
- 1998-04-30 WO PCT/US1998/008691 patent/WO1998048991A1/en active Application Filing
- 1998-04-30 MY MYPI98001941A patent/MY132804A/en unknown
- 1998-04-30 AR ARP980102051A patent/AR012646A1/en unknown
- 1998-10-26 TW TW087106702A patent/TW407175B/en not_active IP Right Cessation
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US1827203A (en) * | 1928-02-11 | 1931-10-13 | Western Electric Co | Cellulose-containing articles and method of producing such articles |
FR660811A (en) * | 1928-09-21 | 1929-07-17 | Reel refinements | |
US5215625A (en) * | 1992-03-02 | 1993-06-01 | Burton R Edward | Method for producing articles from waste fiber, waste/surplus paint, and waste/surplus ink |
US5478441A (en) * | 1992-06-17 | 1995-12-26 | The Wiggins Teape Group Limited | Recovery and re-use of raw materials from paper mill waste sludge |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015097346A1 (en) * | 2013-12-23 | 2015-07-02 | Upm-Kymmene Corporation | A method for manufacturing a material composition, a material composition and a use and a composite product |
Also Published As
Publication number | Publication date |
---|---|
AU7170598A (en) | 1998-11-24 |
CO5021236A1 (en) | 2001-03-27 |
CA2288229A1 (en) | 1998-11-05 |
MY132804A (en) | 2007-10-31 |
AR012646A1 (en) | 2000-11-08 |
TW407175B (en) | 2000-10-01 |
CR5769A (en) | 1998-07-27 |
US6146498A (en) | 2000-11-14 |
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