WO1999026996A3 - Verfahren zur kontinuierlichen extraktion von polyamid - Google Patents

Verfahren zur kontinuierlichen extraktion von polyamid Download PDF

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Publication number
WO1999026996A3
WO1999026996A3 PCT/EP1998/007575 EP9807575W WO9926996A3 WO 1999026996 A3 WO1999026996 A3 WO 1999026996A3 EP 9807575 W EP9807575 W EP 9807575W WO 9926996 A3 WO9926996 A3 WO 9926996A3
Authority
WO
WIPO (PCT)
Prior art keywords
caprolactam
polyamide
extraction process
zone
solution
Prior art date
Application number
PCT/EP1998/007575
Other languages
English (en)
French (fr)
Other versions
WO1999026996A2 (de
Inventor
Joerg Erbes
Alfons Ludwig
Gunter Pipper
Original Assignee
Basf Ag
Joerg Erbes
Alfons Ludwig
Gunter Pipper
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to PL98341685A priority Critical patent/PL341685A1/xx
Priority to KR1020007005644A priority patent/KR20010032404A/ko
Priority to AU17571/99A priority patent/AU1757199A/en
Priority to IL13605898A priority patent/IL136058A0/xx
Priority to EP98962391A priority patent/EP1034208B1/de
Priority to DE59805550T priority patent/DE59805550D1/de
Priority to HU0100525A priority patent/HUP0100525A3/hu
Priority to US09/554,214 priority patent/US6326457B1/en
Application filed by Basf Ag, Joerg Erbes, Alfons Ludwig, Gunter Pipper filed Critical Basf Ag
Priority to SI9830167T priority patent/SI1034208T1/xx
Priority to CA002310849A priority patent/CA2310849A1/en
Priority to BR9815036-7A priority patent/BR9815036A/pt
Priority to JP2000522148A priority patent/JP2001524560A/ja
Priority to SK698-2000A priority patent/SK6982000A3/sk
Priority to IDW20000977D priority patent/ID24575A/id
Publication of WO1999026996A2 publication Critical patent/WO1999026996A2/de
Publication of WO1999026996A3 publication Critical patent/WO1999026996A3/de
Priority to BG104458A priority patent/BG104458A/bg

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/46—Post-polymerisation treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/02—Solvent extraction of solids
    • B01D11/0215—Solid material in other stationary receptacles
    • B01D11/0223—Moving bed of solid material
    • B01D11/0242—Moving bed of solid material in towers, e.g. comprising contacting elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/04—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14—Lactams
    • C08G69/16—Preparatory processes

Abstract

Die Erfindung betrifft ein Verfahren zur kontinuierlichen Extraktion von Polyamidteilchen mit im Kreislauf geführter Extraktionslösung in einer senkrechten, in zwei Zonen unterteilten Extraktionskolonne, wobei man das Polyamid in der ersten Zone mit einer wässrigen ε-Caprolactamlösung mit 40 bis 95 Gew.-% ε-Caprolactam als Extraktionsmittel bei 100 bis 140 °C behandelt und dann in der zweiten Zone mit Wasser nachbehandelt. Anschliessend kann das Caprolactam in an sich bekannter Weise extrahiert werden. Das Verfahren erlaubt eine wirtschaftliche Herstellung von Polyamid mit geringem Dimergehalt.
PCT/EP1998/007575 1997-11-25 1998-11-24 Verfahren zur kontinuierlichen extraktion von polyamid WO1999026996A2 (de)

Priority Applications (15)

Application Number Priority Date Filing Date Title
SI9830167T SI1034208T1 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
KR1020007005644A KR20010032404A (ko) 1997-11-25 1998-11-24 연속식 폴리아미드 추출 방법
CA002310849A CA2310849A1 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
EP98962391A EP1034208B1 (de) 1997-11-25 1998-11-24 Verfahren zur kontinuierlichen extraktion von polyamid
DE59805550T DE59805550D1 (de) 1997-11-25 1998-11-24 Verfahren zur kontinuierlichen extraktion von polyamid
HU0100525A HUP0100525A3 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
US09/554,214 US6326457B1 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
PL98341685A PL341685A1 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
AU17571/99A AU1757199A (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
IL13605898A IL136058A0 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
BR9815036-7A BR9815036A (pt) 1997-11-25 1998-11-24 Processo para extração contìnua de partìculas de poliamida em uma coluna de extração essencialmente vertical usando um agente de extração aquoso, e, coluna de extração para realizar o mesmo
JP2000522148A JP2001524560A (ja) 1997-11-25 1998-11-24 ポリアミドの連続抽出法
SK698-2000A SK6982000A3 (en) 1997-11-25 1998-11-24 Continuous polyamide extraction process
IDW20000977D ID24575A (id) 1997-11-25 1998-11-24 Ekstraksi kontinyu dari poliamida
BG104458A BG104458A (bg) 1997-11-25 2000-05-18 Метод за непрекъсната екстракция на полиамид

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19752183A DE19752183A1 (de) 1997-11-25 1997-11-25 Verfahren zur kontinuierlichen Extraktion von Polyamid
DE19752183.5 1997-11-25

Publications (2)

Publication Number Publication Date
WO1999026996A2 WO1999026996A2 (de) 1999-06-03
WO1999026996A3 true WO1999026996A3 (de) 1999-09-02

Family

ID=7849759

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/007575 WO1999026996A2 (de) 1997-11-25 1998-11-24 Verfahren zur kontinuierlichen extraktion von polyamid

Country Status (20)

Country Link
US (1) US6326457B1 (de)
EP (1) EP1034208B1 (de)
JP (1) JP2001524560A (de)
KR (1) KR20010032404A (de)
CN (1) CN1284095A (de)
AU (1) AU1757199A (de)
BG (1) BG104458A (de)
BR (1) BR9815036A (de)
CA (1) CA2310849A1 (de)
CO (1) CO5040123A1 (de)
DE (2) DE19752183A1 (de)
HU (1) HUP0100525A3 (de)
ID (1) ID24575A (de)
IL (1) IL136058A0 (de)
PL (1) PL341685A1 (de)
SA (1) SA98190809B1 (de)
SK (1) SK6982000A3 (de)
TR (1) TR200001512T2 (de)
TW (1) TW492987B (de)
WO (1) WO1999026996A2 (de)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19957663A1 (de) * 1999-11-30 2001-05-31 Basf Ag Verfahren zur kontinuierlichen Herstellung von Copolyamiden, die auf einem Lactam (I), einem Diamin (II) und einer Dicarbonsäure (III) basieren
US6476181B1 (en) * 2001-06-01 2002-11-05 E. I. Du Pont De Nemours And Company Increased volatile removal during solid phase processing of nylon 6 by temperature programming
US7554121B2 (en) * 2003-12-26 2009-06-30 Semiconductor Energy Laboratory Co., Ltd. Organic semiconductor device
BRPI0707534A2 (pt) * 2006-02-08 2011-05-03 Dsm Ip Assests Bv processo para aumentar o peso molecular de uma poliamida
WO2008075461A1 (ja) * 2006-12-18 2008-06-26 Unitika Ltd. 二軸延伸ポリアミド樹脂フィルムおよびその製造方法
DE102008044452A1 (de) * 2008-08-19 2010-02-25 Lurgi Zimmer Gmbh Kontinuierliches Verfahren zur Extraktion von Polyamid-6
EP2532698B1 (de) 2011-06-08 2016-04-20 Uhde Inventa-Fischer GmbH Verfahren und Vorrichtung zur direkten, kontinuierlichen Modifizierung von Polymerschmelzen
AR088912A1 (es) 2011-11-21 2014-07-16 Basf Se Procedimiento para preparar poliamidas a partir de los correspondientes monomeros y/o prepolimeros
US8629237B2 (en) 2011-11-21 2014-01-14 Basf Se Simplified production of nylon-6
EP2682417A1 (de) 2012-07-06 2014-01-08 Basf Se Verfahren zur Reinigung von Polyamidteilchen
EP2727637B1 (de) * 2012-11-06 2019-08-28 Uhde Inventa-Fischer GmbH Extraktionsreaktor sowie verfahren zur extraktion von granulärem material
US9708271B2 (en) * 2012-11-06 2017-07-18 Uhde Inventa-Fischer Gmbh Extraction reactor and also method for extraction from granular material
PL2784102T3 (pl) * 2013-03-26 2016-06-30 Uhde Inventa Fischer Gmbh Sposób i urządzenie do ciągłej recyrkulacji wód ekstrakcyjnych w procesie produkcji poliamidu
CN105377945B (zh) 2013-05-02 2018-07-06 巴斯夫欧洲公司 制备高粘度聚酰胺的方法
US20170029566A1 (en) * 2014-04-15 2017-02-02 Basf Se Method of Producing a Polyamide
CN107030925A (zh) * 2017-05-27 2017-08-11 江苏华洋尼龙有限公司 一种尼龙切片生产线及其生产方法
BR112022023709A2 (pt) * 2021-02-15 2022-12-20 T En Zimmer Gmbh Método e dispositivo para a produção de pelotas de poliamida 6

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE425503C (de) * 1924-07-01 1926-02-19 J G Farbenindustrie Ag Verfahren und Vorrichtung zur ununterbrochenen Reinigung von mit loeslichen, unloeslichen oder beiderlei fremden Bestandteilen behafteten Salzen
CH363639A (de) * 1958-12-11 1962-08-15 Inventa Ag Vorrichtung zur kontinuierlichen Gegenstrombehandlung von schüttbaren Feststoffen mit Flüssigkeiten
DE1770097A1 (de) * 1968-03-30 1971-09-30 Basf Ag Verfahren zum kontinuierlichen Extrahieren von koernigen Polyamiden
US3751362A (en) * 1971-07-08 1973-08-07 Avco Corp Continuous fluid-solid contact process
JPS51149397A (en) * 1975-02-12 1976-12-22 Unitika Ltd Scouring of polycaprolamide chip
DD206999A1 (de) * 1981-09-04 1984-02-15 Peter Kramer Kontinuierliches extraktionsverfahren fuer kunststoff-granulat
JPS60166324A (ja) * 1984-02-09 1985-08-29 Teijin Ltd ポリアミドチツプの連続式洗浄装置
EP0308774A2 (de) * 1987-09-24 1989-03-29 Bayer Ag Verfahren zur kontinuierlichen Extraktion von Polyamiden
DD289471A5 (de) * 1988-08-03 1991-05-02 Veb Chemieanlagenbau Erfurt-Rudisleben,De Verfahren zur intensivierung der gegenstromextraktion von polyamid-6-granulat
DE4324616A1 (de) * 1993-07-22 1995-01-26 Bayer Ag Extraktion von Polyamid 6
DE19505150A1 (de) * 1995-02-16 1996-08-22 Bayer Ag Verfahren zur Extraktion von Polyamid-6 oder Copolyamiden mit epsilon-Caprolactam

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DE289471C (de)
DE1519936B2 (de) 1966-04-06 1973-09-27 Davy-Ashmore Ag, 6000 Frankfurt Extraktionsrohr zum kontinuierlichen Entfernen niedermolekularer Bestandteile aus granulierten Polyamiden
GB1279606A (en) 1968-09-27 1972-06-28 English Clays Lovering Pochin Improvements in or relating to filter thickeners
DE2501348B2 (de) 1975-01-15 1981-04-09 Basf Ag, 6700 Ludwigshafen Kontinuierliches Verfahren zur Herstellung von Polyamiden aus epsilon-Caprolactam
JPS5371196A (en) 1976-12-06 1978-06-24 Mitsubishi Chem Ind Ltd Preparation of purified polyamide
DE2732328A1 (de) 1977-07-16 1979-02-01 Basf Ag Verfahren zur herstellung von polycaprolactam
IT1100787B (it) 1978-12-06 1985-09-28 Snia Viscosa Processo e apparecchiatura per demonomerizzazione di policaproammide
DE3710803A1 (de) 1987-03-31 1988-10-20 Basf Ag Verfahren zur entfernung von caprolactam und dessen oligomeren aus solches enthaltendem polyamidgranulat
US7384921B2 (en) 2004-02-20 2008-06-10 Enanta Pharmaceuticals, Inc. Polymorphic forms of 6-11 bicyclic ketolide derivatives

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE425503C (de) * 1924-07-01 1926-02-19 J G Farbenindustrie Ag Verfahren und Vorrichtung zur ununterbrochenen Reinigung von mit loeslichen, unloeslichen oder beiderlei fremden Bestandteilen behafteten Salzen
CH363639A (de) * 1958-12-11 1962-08-15 Inventa Ag Vorrichtung zur kontinuierlichen Gegenstrombehandlung von schüttbaren Feststoffen mit Flüssigkeiten
DE1770097A1 (de) * 1968-03-30 1971-09-30 Basf Ag Verfahren zum kontinuierlichen Extrahieren von koernigen Polyamiden
US3751362A (en) * 1971-07-08 1973-08-07 Avco Corp Continuous fluid-solid contact process
JPS51149397A (en) * 1975-02-12 1976-12-22 Unitika Ltd Scouring of polycaprolamide chip
DD206999A1 (de) * 1981-09-04 1984-02-15 Peter Kramer Kontinuierliches extraktionsverfahren fuer kunststoff-granulat
JPS60166324A (ja) * 1984-02-09 1985-08-29 Teijin Ltd ポリアミドチツプの連続式洗浄装置
EP0308774A2 (de) * 1987-09-24 1989-03-29 Bayer Ag Verfahren zur kontinuierlichen Extraktion von Polyamiden
DD289471A5 (de) * 1988-08-03 1991-05-02 Veb Chemieanlagenbau Erfurt-Rudisleben,De Verfahren zur intensivierung der gegenstromextraktion von polyamid-6-granulat
DE4324616A1 (de) * 1993-07-22 1995-01-26 Bayer Ag Extraktion von Polyamid 6
DE19505150A1 (de) * 1995-02-16 1996-08-22 Bayer Ag Verfahren zur Extraktion von Polyamid-6 oder Copolyamiden mit epsilon-Caprolactam

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PATENT ABSTRACTS OF JAPAN vol. 010, no. 013 (C - 323) 18 January 1986 (1986-01-18) *

Also Published As

Publication number Publication date
CO5040123A1 (es) 2001-05-29
HUP0100525A2 (hu) 2001-06-28
ID24575A (id) 2000-07-27
HUP0100525A3 (en) 2002-03-28
EP1034208A2 (de) 2000-09-13
KR20010032404A (ko) 2001-04-16
JP2001524560A (ja) 2001-12-04
BG104458A (bg) 2001-01-31
SA98190809B1 (ar) 2006-04-18
AU1757199A (en) 1999-06-15
DE59805550D1 (de) 2002-10-17
TW492987B (en) 2002-07-01
WO1999026996A2 (de) 1999-06-03
SK6982000A3 (en) 2000-11-07
CA2310849A1 (en) 1999-06-03
PL341685A1 (en) 2001-04-23
BR9815036A (pt) 2000-10-03
CN1284095A (zh) 2001-02-14
IL136058A0 (en) 2001-05-20
EP1034208B1 (de) 2002-09-11
DE19752183A1 (de) 1999-05-27
TR200001512T2 (tr) 2002-08-21
US6326457B1 (en) 2001-12-04

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