WO1999043744A1 - Membrane filtration of polymer containing solutions - Google Patents

Membrane filtration of polymer containing solutions Download PDF

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Publication number
WO1999043744A1
WO1999043744A1 PCT/GB1999/000299 GB9900299W WO9943744A1 WO 1999043744 A1 WO1999043744 A1 WO 1999043744A1 GB 9900299 W GB9900299 W GB 9900299W WO 9943744 A1 WO9943744 A1 WO 9943744A1
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WO
WIPO (PCT)
Prior art keywords
acid
solution
polymers
polymer
reactant
Prior art date
Application number
PCT/GB1999/000299
Other languages
French (fr)
Inventor
Mohsen Zakikhani
Original Assignee
Albright & Wilson Uk Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albright & Wilson Uk Limited filed Critical Albright & Wilson Uk Limited
Priority to JP2000533490A priority Critical patent/JP2002504610A/en
Priority to AU22908/99A priority patent/AU737961B2/en
Priority to IL13714099A priority patent/IL137140A0/en
Priority to KR1020007007564A priority patent/KR20010033976A/en
Priority to BR9907840A priority patent/BR9907840A/en
Priority to CA 2321727 priority patent/CA2321727C/en
Priority to NZ50553399A priority patent/NZ505533A/en
Publication of WO1999043744A1 publication Critical patent/WO1999043744A1/en
Priority to NO20004166A priority patent/NO20004166D0/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/06—Recovery or working-up of waste materials of polymers without chemical reactions
    • C08J11/08—Recovery or working-up of waste materials of polymers without chemical reactions using selective solvents for polymer components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
    • C08J2343/02—Homopolymers or copolymers of monomers containing phosphorus
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Definitions

  • the present invention relates to the recovery of substantially pure polymers from aqueous solutions.
  • Phosphonic acid - containing polymers are used in the treatment of metal (particularly aluminium) surfaces.
  • Such treatment may, for example, comprise dipping a metal plate into a bath containing a solution of the polymer or spraying a metal plate with a solution of the polymer.
  • the bath prior to application to the metal surface, may consist essentially of a solution of a polymer such as poly-vinylphosphonic acid, poly (vinylphosphonic acid-co-acrylic acid), poly (vinylphosphonic acid-co-methacrylic acid) or poly (vinylphosphonic acid-co-acrylic acid-co-vinylsulphonic acid).
  • a polymer such as poly-vinylphosphonic acid, poly (vinylphosphonic acid-co-acrylic acid), poly (vinylphosphonic acid-co-methacrylic acid) or poly (vinylphosphonic acid-co-acrylic acid-co-vinylsulphonic acid).
  • the bath may contain polymers including vinylidene-l, 1-di ⁇ hosphonic acid (VDPA) , such as poly(VDPA), copolymers or terpolymers of VDPA with other water-soluble monomers
  • VDPA vinylidene-l, 1-di ⁇ hosphonic acid
  • the bath may contain polymers including vinylidene-l, 1-di ⁇ hosphonic acid (VDPA) , such as poly(VDPA), copolymers or terpolymers of VDPA with other water-soluble monomers
  • VDPA functionalised polymers or polymers containing phosphono-succinic acid.
  • the spent bath contains polymer residues in the form of metal/polymer complexes, e.g. aluminium/polymer complex or iron/polymer complex.
  • metal/polymer complexes e.g. aluminium/polymer complex or iron/polymer complex.
  • the presence of such complexes in the spent bath can be indicated by an increase in the apparent molecular weight of the polymer (as shown by gel-permeation chromatography) as well as a general broadening of J P nmr signals.
  • the presence of such complexes in the spent bath can also be indicated by the formation of a white precipitate where the metal ion content of the bath exceeds about 200 p. p.m.
  • the spent bath has been disposed of by neutralising the waste and filtering off the resulting polymer-containing solids (which have been used for landfill purposes).
  • the present invention provides a method for recovering polymers in a substantially pure form from a solution containing said polymers, in which the method comprises the steps of (a) treating the solution with a reactant so as to form the free polymers and one or more salts of said reactant; (b) treating the solution to remove the salts therefrom and (c) concentrating the polymer solution to recover the polymer therefrom.
  • the reactant used in the treatment step (a) may be, for example, an acid (such as sulphuric acid, hydrochloric acid or phosphoric acid) .
  • the reactant may be a sequestrant (such as 1-hydroxyethane- 1 , 1-diphosphonic acid) or a mixture of said acid and said sequestrant.
  • the treatment step (b) comprises membrane-filtration of the solution.
  • the treatment step (b) comprises contacting the solution with an ion-exchange resin.
  • the treatment step (b) comprises electrodialysis of the solution.
  • the polymers may be copolymers of vinylphosphonic acid and acrylic acid, copolymers of vinylphosphonic acid and methacrylic acid, homopolymers or oligomers of vinylphosphonic acid, or terpolymers of vinylphosphonic acid, acrylic acid and vinylsulphonic acid.
  • the polymers may be homo-, co- or terpolymers of VDPA, VDPA-functionalised polymers or polymers containing phosphono-succinic acid.
  • the polymers may be present in pure or impure forms in the solution.
  • the solution from which the polymer is to be recovered includes one or more aluminium/polymer complexes.
  • Acidification of the solution with an acid e.g. sulphuric acid, hydrochloric acid or phosphoric acid
  • the salt of said acid e.g. aluminium sulphate or aluminium chloride
  • Treatment by membrane-filtration separates the aluminium salts and other low molecular weight impurities and/or by-products from the polymer solution.
  • the polymer solution is then concentrated and the free polymer recovered.
  • Treatment by ion-exchange can likewise be employed to reverse the metal/polymer complex and return the polymer to its original form.
  • Treatment by electrodialysis can be applied either to the spent bath or to the acidified spent bath.
  • the membrane may be made from a ceramic material or from one or more polymeric materials.
  • the membrane may comprise a layer of a polymeric material supported on a paper substrate.
  • the cut-off size of the membrane is determined by reference to the molecular weight of the polymer to be recovered from solution.
  • the membrane prevents substances having a molecular weight higher than the upper limit of the molecular weight range of the membrane from passing therethrough.
  • the solution from which the polymer is recovered may be a reaction solution.
  • the solution may be a waste process solution containing polymers, for example a spent bath from lithographic plate covering.
  • the solution from which the polymer is recovered is an aqueous solution.
  • the present invention will be illustrated, merely by way of example, as follows:
  • the pH of 10 ⁇ of a 20% solution of spent bath (made by concentrating a lg/1 solution of spent bath) was adjusted to about 0.5 by adding about 740ml of 98% sulphuric acid.
  • the solution was diafiltered using an ES404 membrane (available from PCI Membrane Systems Limited, England) until 3 to 4 volume equivalents of water had passed through the system at a module inlet pressure of 10 bar.
  • the volume of the solution was then reduced to achieve a 20% solution of the polymer.
  • the solution was spray-dried (using apparatus available from Croda Colloids Limited, England) and the polymer was isolated.
  • Example 1 The process of Example 1 (above) was repeated, using a bath containing poly(vinylphosphonic acid).
  • a first portion of the acidified polymer solution was diafiltered by means of a set of 5 GR90PP membranes.
  • a second portion was diafiltered by means of a set of 5 GR95PP membranes (both sets available from Danish Separation Systems A/S, Denmark) .
  • the initial concentration of the polymer in each portion was adjusted to about 6.7% and 2.7 volume equivalents of water were passed through the system at a pressure of 2 bar, until the conductivity of each portion of the polymer solution reached 82.6 m.S.
  • the treated solution was subjected to 12 dia-filtrations using an ES 404 membrane (available from PCI Membrane Systems Ltd).
  • the solution was concentrated to achieve a 2% solution of the polymer. Analysis at this stage showed the presence of 2 p. p.m. or less of each of the aluminium, chromium and magnesium ions and 6 p. p.m. or less of the iron ions. Also, analysis showed that 2 p. p.m. or less of each of the ions of calcium, nickel, sodium and potassium was present in the solution.
  • the solution was further concentrated to 20% and subjected to 6 further dia-filtrations using an ES 404 membrane.
  • Example 1 The process of Example 1 was repeated, using a NF 45 membrane (available from Danish Separation Systems A/S) and a 20% solution of the polymer was isolated.
  • NF 45 membrane available from Danish Separation Systems A/S
  • Example 2 The process of Example 2 was repeated, using a NF 45 membrane (available from Danish Separation Systems A/S) and a 20% solution of the polymer was isolated.
  • NF 45 membrane available from Danish Separation Systems A/S

Abstract

In a method for recovering polymers in a substantially pure form from a solution containing the polymers, the solution is first treated with a reactant (e.g. an acid, a sequestrant or a mixture of both) to form the free polymers and salts of the reactant. Second, the solution is treated to remove the salts therefrom and in a final stage the polymer solution is concentrated and the polymers recovered. The second treatment step may consist of membrane-filtration, ion-exchange or electrodialysis.

Description

MEMBRANE FILTRATION OF POLYMER CONTAINING SOLUTIONS
The present invention relates to the recovery of substantially pure polymers from aqueous solutions.
Phosphonic acid - containing polymers are used in the treatment of metal (particularly aluminium) surfaces. Such treatment may, for example, comprise dipping a metal plate into a bath containing a solution of the polymer or spraying a metal plate with a solution of the polymer.
For example, the bath, prior to application to the metal surface, may consist essentially of a solution of a polymer such as poly-vinylphosphonic acid, poly (vinylphosphonic acid-co-acrylic acid), poly (vinylphosphonic acid-co-methacrylic acid) or poly (vinylphosphonic acid-co-acrylic acid-co-vinylsulphonic acid).
Alternatively, the bath may contain polymers including vinylidene-l, 1-diρhosphonic acid (VDPA) , such as poly(VDPA), copolymers or terpolymers of VDPA with other water-soluble monomers
(e.g. acrylic acid or vinylsulphonic acid) , VDPA - functionalised polymers or polymers containing phosphono-succinic acid.
Although the polymer content is depleted during application, a considerable amount of unreacted polymer remains in the spent bath. Moreover, the spent bath contains polymer residues in the form of metal/polymer complexes, e.g. aluminium/polymer complex or iron/polymer complex. The presence of such complexes in the spent bath can be indicated by an increase in the apparent molecular weight of the polymer (as shown by gel-permeation chromatography) as well as a general broadening of J P nmr signals. The presence of such complexes in the spent bath can also be indicated by the formation of a white precipitate where the metal ion content of the bath exceeds about 200 p. p.m.
Hitherto, the spent bath has been disposed of by neutralising the waste and filtering off the resulting polymer-containing solids (which have been used for landfill purposes).
We have now found a simple and economic method of recovering polymers in substantially pure form from solutions such as reaction solutions or waste process solutions.
Accordingly the present invention provides a method for recovering polymers in a substantially pure form from a solution containing said polymers, in which the method comprises the steps of (a) treating the solution with a reactant so as to form the free polymers and one or more salts of said reactant; (b) treating the solution to remove the salts therefrom and (c) concentrating the polymer solution to recover the polymer therefrom.
The reactant used in the treatment step (a) may be, for example, an acid (such as sulphuric acid, hydrochloric acid or phosphoric acid) . Alternatively, the reactant may be a sequestrant (such as 1-hydroxyethane- 1 , 1-diphosphonic acid) or a mixture of said acid and said sequestrant. In a first preferred embodiment of the present invention, the treatment step (b) comprises membrane-filtration of the solution.
In a second preferred embodiment of the present invention, the treatment step (b) comprises contacting the solution with an ion-exchange resin.
In a third preferred embodiment of the present invention, the treatment step (b) comprises electrodialysis of the solution.
The polymers may be copolymers of vinylphosphonic acid and acrylic acid, copolymers of vinylphosphonic acid and methacrylic acid, homopolymers or oligomers of vinylphosphonic acid, or terpolymers of vinylphosphonic acid, acrylic acid and vinylsulphonic acid.
Alternatively, the polymers may be homo-, co- or terpolymers of VDPA, VDPA-functionalised polymers or polymers containing phosphono-succinic acid.
The polymers may be present in pure or impure forms in the solution.
Typically, the solution from which the polymer is to be recovered includes one or more aluminium/polymer complexes. Acidification of the solution with an acid (e.g. sulphuric acid, hydrochloric acid or phosphoric acid) reverses the complex to form the free polymer and the salt of said acid (e.g. aluminium sulphate or aluminium chloride) . Treatment by membrane-filtration separates the aluminium salts and other low molecular weight impurities and/or by-products from the polymer solution. The polymer solution is then concentrated and the free polymer recovered.
Treatment by ion-exchange can likewise be employed to reverse the metal/polymer complex and return the polymer to its original form.
Treatment by electrodialysis can be applied either to the spent bath or to the acidified spent bath.
Preferably, the membrane may be made from a ceramic material or from one or more polymeric materials.
Alternatively, the membrane may comprise a layer of a polymeric material supported on a paper substrate.
The cut-off size of the membrane is determined by reference to the molecular weight of the polymer to be recovered from solution. The membrane prevents substances having a molecular weight higher than the upper limit of the molecular weight range of the membrane from passing therethrough.
The solution from which the polymer is recovered may be a reaction solution. Alternatively, the solution may be a waste process solution containing polymers, for example a spent bath from lithographic plate covering.
Preferably, the solution from which the polymer is recovered is an aqueous solution. The present invention will be illustrated, merely by way of example, as follows:
EXAMPLE 1
Isolation of poly(vinyIphosphonic acid-co-acrylic acid)
The pH of 10 ^ of a 20% solution of spent bath (made by concentrating a lg/1 solution of spent bath) was adjusted to about 0.5 by adding about 740ml of 98% sulphuric acid.
The solution was diafiltered using an ES404 membrane (available from PCI Membrane Systems Limited, England) until 3 to 4 volume equivalents of water had passed through the system at a module inlet pressure of 10 bar.
The volume of the solution was then reduced to achieve a 20% solution of the polymer.
The solution was spray-dried (using apparatus available from Croda Colloids Limited, England) and the polymer was isolated.
Further analysis by P nmr showed that an essentially pure polymer had been isolated. EXAMPLE 2
Isolation of poIy(vinylphosphoπic acid)
The process of Example 1 (above) was repeated, using a bath containing poly(vinylphosphonic acid).
A first portion of the acidified polymer solution was diafiltered by means of a set of 5 GR90PP membranes. A second portion was diafiltered by means of a set of 5 GR95PP membranes (both sets available from Danish Separation Systems A/S, Denmark) .
The initial concentration of the polymer in each portion was adjusted to about 6.7% and 2.7 volume equivalents of water were passed through the system at a pressure of 2 bar, until the conductivity of each portion of the polymer solution reached 82.6 m.S.
Each portion of the polymer solution was spray-dried (using apparatus available from Niro Limited, England) and the polymer was isolated.
Further analysis by P nmr showed that an essentially pure polymer had been isolated from each portion of the polymer solution.
EXAMPLE 3
To 200 Kg of a spent bath with white precipitate containing 0.2% poly (vinylphosphonic acid-co-acrylic acid) , 600 p. p.m. aluminium, 190 p. p.m. iron, 30 p. p.m. chromium and 10 p. p.m. magnesium ions, was added 0.5 Kg of 50% sulphuric acid, 0.5 Kg of hydrochloric acid, 0.5 Kg of phosphoric acid and 0.5 Kg of a 60% aqueous solution of 1 - hydroxyelhane-1 , 1-diphosphonic acid (available from Albright & Wilson UK Limited as BRIQUEST* ADPA- 60-A) .
The treated solution was subjected to 12 dia-filtrations using an ES 404 membrane (available from PCI Membrane Systems Ltd).
After the 2nd, 4th and 6th dia-filtrations, lKg of sulphuric acid and lKg of BRIQUEST* ADPA 60-A was added to the bath.
After the 8th and 10th dia-filtrations, lKg of sulphuric acid was added to the bath.
After the 12th dia-filtration, the solution was concentrated to achieve a 2% solution of the polymer. Analysis at this stage showed the presence of 2 p. p.m. or less of each of the aluminium, chromium and magnesium ions and 6 p. p.m. or less of the iron ions. Also, analysis showed that 2 p. p.m. or less of each of the ions of calcium, nickel, sodium and potassium was present in the solution.
The solution was further concentrated to 20% and subjected to 6 further dia-filtrations using an ES 404 membrane.
After the 6th dia-filtration a sample of the solution was filtered through a 0.45 micron filter paper. The filtrate was pale yellow in colour (colour value 0.04; turbidity 1.98 NUT) and was found to contain less than 2 p. p.m. in all of metal ions. EXAMPLE 4
The process of Example 1 was repeated, using a NF 45 membrane (available from Danish Separation Systems A/S) and a 20% solution of the polymer was isolated.
EXAMPLE 5
The process of Example 2 was repeated, using a NF 45 membrane (available from Danish Separation Systems A/S) and a 20% solution of the polymer was isolated.
*BRIQUEST is a Registered Trade Mark.

Claims

CLAIMS (EP)
1 . A method for recovering polymers in a substantially pure form from a solution containing said polymers4 characterised in that the method comprises the steps of (a) treating the solution with a reactant so as to form the free polymers and one or more salts of said reactant, followed by (b) treating the solution (a) to remove the salts therefrom and (c) concentrating the polymer solution (b) to recover the polymer therefrom.
2. A method according to Claim 1 , characterised in that the reactant used in step (a) comprises one or more acids.
3. A method according to Claim 1 , characterised in that the reactant used in step (a) comprises one or more sequestrants.
4. ' A method according to Claim 1 , characterised in that the reactant used in step (a) comprises a mixture of one or more acids and one or more sequestrants.
5. A method according to any one of Claims 1 to 4, characterised in that the treatment step (b) comprises membrane-filtration of the solution (a).
6. A method according to any one of Claims 1 to 4, characterised in that the treatment step (b) comprises the use of an ion-exchange resin in contact with the solution (a) .
7. A method according to any one of Claims 1 to 4, characterised in that the treatment step (b) comprises electrodialysis of the solution (a) .
8. A method according to any one of Claims 1* to 7, characterised in that the polymers are copolymers of vinylphosphonic acid and acrylic acid, copolymers of vinylphosphonic acid and methacrylic acid, homopolymers or oligomers of vinylphosphonic acid, or terpolymers of vinylphosphonic acid, acrylic acid and vinylsulphonic acid.
9. A method according to any one of Claims 1 to 7, characterised in that the polymers are homo-, co- or terpolymers of vinylidene-1 , 1-diphosphonic acid (VDPA) with other water-soluble monomers (e.g. acrylic acid or vinylsulphonic acid) VDPA-functionalised polymers or polymers containing phosphono-succinic acid.
10. A method according to any one of Claims 1 to 9, characterised in that the solution from which the polymer is to be recovered further includes one or more metal/polymer complexes.
11. A method according to Claim 11 , characterised in that the metal is aluminium or iron.
12. A method according to Claim 2 and to any one of Claims 4 to 11 dependent upon Claim 2, characterised in that the acid is sulphuric acid, hydrochloric acid or phosphoric acid.
13. A method according to Claim 3 and to any one of claims 4 to 11 dependent upon Claim 3, characterised in that the sequestrant is 1- hydroxyethane -1 , 1-diphosphonic acid.
14. A method according to any one of Claims 4 to 11 , characterised in that the mixture comprises sulphuric acid and 1-hydroxyethane -1 , 1- disphosphonic acid.
15. A method according to Claim 5 , and to any one of Claims 8 to 14 dependent upon Claim 5, characterised in that the membrane is made from a ceramic metal, from one or more polymeric materials or from a layer of a polymeric material supported on a paper substrate.
PCT/GB1999/000299 1998-02-25 1999-01-28 Membrane filtration of polymer containing solutions WO1999043744A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
JP2000533490A JP2002504610A (en) 1998-02-25 1999-01-28 Membrane filtration of polymer-containing solutions
AU22908/99A AU737961B2 (en) 1998-02-25 1999-01-28 Membrane filtration of polymer containing solutions and a method for recovering polymers
IL13714099A IL137140A0 (en) 1998-02-25 1999-01-28 Membrane filtration of polymer containing solutions
KR1020007007564A KR20010033976A (en) 1998-02-25 1999-01-28 Membrane filtration of polymer containing solutions
BR9907840A BR9907840A (en) 1998-02-25 1999-01-28 Solutions containing polymers
CA 2321727 CA2321727C (en) 1998-02-25 1999-01-28 Membrane filtration of polymer containing solutions
NZ50553399A NZ505533A (en) 1998-02-25 1999-01-28 Membrane filtration of polymer containing solutions
NO20004166A NO20004166D0 (en) 1998-02-25 2000-08-21 Membrane filtration of polymer-containing solutions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9803812.8 1998-02-25
GB9803812A GB9803812D0 (en) 1998-02-25 1998-02-25 Membrane filtration of polymer containing solutions

Publications (1)

Publication Number Publication Date
WO1999043744A1 true WO1999043744A1 (en) 1999-09-02

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Country Status (16)

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US (1) US6162340A (en)
EP (1) EP0939100B1 (en)
JP (1) JP2002504610A (en)
KR (1) KR20010033976A (en)
AT (1) ATE287921T1 (en)
AU (1) AU737961B2 (en)
BR (1) BR9907840A (en)
CA (1) CA2321727C (en)
DE (1) DE69828767T2 (en)
DK (1) DK0939100T3 (en)
GB (1) GB9803812D0 (en)
ID (1) ID25879A (en)
IL (1) IL137140A0 (en)
NO (1) NO20004166D0 (en)
NZ (1) NZ505533A (en)
WO (1) WO1999043744A1 (en)

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US9598802B2 (en) 2013-12-17 2017-03-21 Eastman Chemical Company Ultrafiltration process for producing a sulfopolyester concentrate
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EP3950796A1 (en) 2020-08-07 2022-02-09 Apk Ag Method for solvent removal from a polymer solution by integrated size classification and extrusion in a plastic extruder
EP3950797A1 (en) 2020-08-07 2022-02-09 Apk Ag Method for solvent removal from a polymer solution by integrated drum-drying and extrusion
WO2022029324A1 (en) 2020-08-07 2022-02-10 Apk Ag Method for solvent removal from a polymer solution by integrated drum-drying and extrusion
WO2022029326A1 (en) 2020-08-07 2022-02-10 Apk Ag Method for solvent removal from a polymer solution by integrated size classification and extrusion in a plastic extruder

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DE69828767T2 (en) 2006-05-18
ATE287921T1 (en) 2005-02-15
DE69828767D1 (en) 2005-03-03
GB9803812D0 (en) 1998-04-22
NO20004166L (en) 2000-08-21
IL137140A0 (en) 2001-07-24
DK0939100T3 (en) 2005-06-06
AU2290899A (en) 1999-09-15
KR20010033976A (en) 2001-04-25
EP0939100B1 (en) 2005-01-26
ID25879A (en) 2000-11-09
BR9907840A (en) 2000-10-24
US6162340A (en) 2000-12-19
CA2321727C (en) 2008-05-06
EP0939100A1 (en) 1999-09-01
NO20004166D0 (en) 2000-08-21
JP2002504610A (en) 2002-02-12
CA2321727A1 (en) 1999-09-02
NZ505533A (en) 2002-12-20

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