WO1999067347A3 - Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants - Google Patents

Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants Download PDF

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Publication number
WO1999067347A3
WO1999067347A3 PCT/EP1999/003809 EP9903809W WO9967347A3 WO 1999067347 A3 WO1999067347 A3 WO 1999067347A3 EP 9903809 W EP9903809 W EP 9903809W WO 9967347 A3 WO9967347 A3 WO 9967347A3
Authority
WO
WIPO (PCT)
Prior art keywords
oligodecenes
lubricants
linear
metallocene
catalyzed
Prior art date
Application number
PCT/EP1999/003809
Other languages
German (de)
French (fr)
Other versions
WO1999067347A2 (en
Inventor
Hans Peter Rath
Helmut Mach
Original Assignee
Basf Ag
Hans Peter Rath
Helmut Mach
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Hans Peter Rath, Helmut Mach filed Critical Basf Ag
Priority to JP2000555993A priority Critical patent/JP2002518582A/en
Priority to AU45046/99A priority patent/AU4504699A/en
Priority to KR1020007014401A priority patent/KR20010053003A/en
Priority to EP99927838A priority patent/EP1088049A2/en
Publication of WO1999067347A2 publication Critical patent/WO1999067347A2/en
Publication of WO1999067347A3 publication Critical patent/WO1999067347A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/08—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/10—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

Abstract

The invention relates to oligodecenes which are obtained by oligomerisation of linear 1-decene, whereby up to 40 mol %, in relation to the quantity of linear 1-decene, of other linear C8-C12-1-alkenes can be included by polymerization, in the presence of a titanium, zirconium or hafnium metallocene catalyst and an activator on a basis of aluminium-organic, boron-organic or carbo-cationic compounds, and which have possibly been hydrogenated following oligomerisation. Said oligodecenes have a number average molecular weight of between 500 and 200,000. The invention further relates to their use as components in lubricants, especially motor oils and transmission oils.
PCT/EP1999/003809 1998-06-19 1999-06-02 Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants WO1999067347A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2000555993A JP2002518582A (en) 1998-06-19 1999-06-02 Oligodecenes prepared using metallocene catalysts, their preparation and their use as components in lubricants
AU45046/99A AU4504699A (en) 1998-06-19 1999-06-02 Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants
KR1020007014401A KR20010053003A (en) 1998-06-19 1999-06-02 Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants
EP99927838A EP1088049A2 (en) 1998-06-19 1999-06-02 Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19827323.1 1998-06-19
DE19827323A DE19827323A1 (en) 1998-06-19 1998-06-19 Oligodecenes used as components of lubricants

Publications (2)

Publication Number Publication Date
WO1999067347A2 WO1999067347A2 (en) 1999-12-29
WO1999067347A3 true WO1999067347A3 (en) 2000-02-17

Family

ID=7871379

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1999/003809 WO1999067347A2 (en) 1998-06-19 1999-06-02 Metallocene-catalyzed oligodecenes, their production and their use as component in lubricants

Country Status (6)

Country Link
EP (1) EP1088049A2 (en)
JP (1) JP2002518582A (en)
KR (1) KR20010053003A (en)
AU (1) AU4504699A (en)
DE (1) DE19827323A1 (en)
WO (1) WO1999067347A2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8865959B2 (en) 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production
US8921291B2 (en) 2005-07-19 2014-12-30 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US9409834B2 (en) 2005-07-19 2016-08-09 Exxonmobil Chemical Patents Inc. Low viscosity poly-alpha-olefins
US9469704B2 (en) 2008-01-31 2016-10-18 Exxonmobil Chemical Patents Inc. Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins

Families Citing this family (34)

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DE10041345A1 (en) * 2000-08-23 2002-03-07 Basf Ag Process for the synthesis of terminal olefins with a narrow molecular weight distribution
MY139205A (en) * 2001-08-31 2009-08-28 Pennzoil Quaker State Co Synthesis of poly-alpha olefin and use thereof
US6713582B2 (en) 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
US6680417B2 (en) 2002-01-03 2004-01-20 Bp Corporation North America Inc. Oligomerization using a solid, unsupported metallocene catalyst system
ATE472566T1 (en) 2002-02-21 2010-07-15 Idemitsu Kosan Co HIGHER ALPHA-OLEFIN CRYSTALLINE POLYMER AND PROCESS FOR PRODUCTION THEREOF
US6706828B2 (en) * 2002-06-04 2004-03-16 Crompton Corporation Process for the oligomerization of α-olefins having low unsaturation
JP2005200453A (en) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc METHOD FOR PRODUCING alpha-OLEFIN (CO)POLYMER
JP2005200452A (en) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc METHOD FOR PRODUCING alpha-OLEFIN (CO)POLYMER
CN100390256C (en) * 2004-11-26 2008-05-28 三井化学株式会社 Synthetic lubricating oil and lubricating oil composition
JP4933089B2 (en) 2005-05-12 2012-05-16 出光興産株式会社 Method for producing lubricating oil composition
CN101233217B (en) 2005-08-31 2012-08-08 出光兴产株式会社 Refrigerating machine oil composition
JP5390738B2 (en) * 2005-11-15 2014-01-15 出光興産株式会社 Lubricating oil composition for internal combustion engines
JP5431672B2 (en) 2005-11-15 2014-03-05 出光興産株式会社 Transmission oil composition
JP5330824B2 (en) * 2006-03-10 2013-10-30 出光興産株式会社 Refrigerator oil composition
US8535514B2 (en) * 2006-06-06 2013-09-17 Exxonmobil Research And Engineering Company High viscosity metallocene catalyst PAO novel base stock lubricant blends
US8501675B2 (en) 2006-06-06 2013-08-06 Exxonmobil Research And Engineering Company High viscosity novel base stock lubricant viscosity blends
US8834705B2 (en) 2006-06-06 2014-09-16 Exxonmobil Research And Engineering Company Gear oil compositions
US8299007B2 (en) 2006-06-06 2012-10-30 Exxonmobil Research And Engineering Company Base stock lubricant blends
US8921290B2 (en) 2006-06-06 2014-12-30 Exxonmobil Research And Engineering Company Gear oil compositions
CN101501083B (en) * 2006-07-19 2012-12-05 埃克森美孚化学专利公司 Process to produce high viscosity fluids
JP5285218B2 (en) * 2006-12-28 2013-09-11 出光興産株式会社 Lubricating oil composition for metal working
US8227392B2 (en) 2008-01-25 2012-07-24 Exxonmobil Research And Engineering Company Base stocks and lubricant blends containing poly-alpha olefins
WO2009135876A1 (en) 2008-05-07 2009-11-12 Basf Se α-OLEFIN/ISOBUTENE DIBLOCK COPOLYMERS
JP2011121990A (en) * 2008-11-17 2011-06-23 Idemitsu Kosan Co Ltd Lubricant composition
JP5555478B2 (en) * 2008-11-17 2014-07-23 出光興産株式会社 Lubricating oil composition for transmission
US8389625B2 (en) 2008-12-23 2013-03-05 Exxonmobil Research And Engineering Company Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks
JP5357605B2 (en) * 2009-04-02 2013-12-04 出光興産株式会社 Method for producing α-olefin polymer and lubricating oil
CA2782873C (en) 2009-12-24 2016-06-28 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
WO2012027139A2 (en) 2010-08-25 2012-03-01 Exxonmobil Chemical Patents Inc. Functionalizable synthetic hydrocarbon fluids and integrated method of for production thereof
US9815915B2 (en) 2010-09-03 2017-11-14 Exxonmobil Chemical Patents Inc. Production of liquid polyolefins
EP2669301A4 (en) * 2010-11-26 2014-07-09 Idemitsu Kosan Co a-OLEFIN POLYMER AND METHOD FOR PRODUCING SAME
WO2012134688A1 (en) 2011-03-30 2012-10-04 Exxonmobil Chemical Patents Inc. Polyalphaolefins by oligomerization and isomerization
KR101449474B1 (en) * 2012-11-23 2014-10-13 아주대학교산학협력단 Catalyst for trimerization of alpha-olefin, method for trimerization of alpha-olefin comprising using the same and method for preparing lubricating oil comprising using the same
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins

Citations (3)

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US4282392A (en) * 1976-10-28 1981-08-04 Gulf Research & Development Company Alpha-olefin oligomer synthetic lubricant
EP0613873A2 (en) * 1993-02-23 1994-09-07 Shell Internationale Researchmaatschappij B.V. Oligomerisation process
WO1996023751A1 (en) * 1995-02-01 1996-08-08 Basf Aktiengesellschaft Process for preparing olefin oligomers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4282392A (en) * 1976-10-28 1981-08-04 Gulf Research & Development Company Alpha-olefin oligomer synthetic lubricant
EP0613873A2 (en) * 1993-02-23 1994-09-07 Shell Internationale Researchmaatschappij B.V. Oligomerisation process
WO1996023751A1 (en) * 1995-02-01 1996-08-08 Basf Aktiengesellschaft Process for preparing olefin oligomers

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8921291B2 (en) 2005-07-19 2014-12-30 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US9409834B2 (en) 2005-07-19 2016-08-09 Exxonmobil Chemical Patents Inc. Low viscosity poly-alpha-olefins
US9593288B2 (en) 2005-07-19 2017-03-14 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US9469704B2 (en) 2008-01-31 2016-10-18 Exxonmobil Chemical Patents Inc. Utilization of linear alpha olefins in the production of metallocene catalyzed poly-alpha olefins
US8865959B2 (en) 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production

Also Published As

Publication number Publication date
JP2002518582A (en) 2002-06-25
WO1999067347A2 (en) 1999-12-29
DE19827323A1 (en) 1999-12-23
EP1088049A2 (en) 2001-04-04
KR20010053003A (en) 2001-06-25
AU4504699A (en) 2000-01-10

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