WO2000003856A1 - Rotational molding process - Google Patents

Rotational molding process Download PDF

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Publication number
WO2000003856A1
WO2000003856A1 PCT/US1999/015889 US9915889W WO0003856A1 WO 2000003856 A1 WO2000003856 A1 WO 2000003856A1 US 9915889 W US9915889 W US 9915889W WO 0003856 A1 WO0003856 A1 WO 0003856A1
Authority
WO
WIPO (PCT)
Prior art keywords
mold
resin
rotational molding
molding method
melt
Prior art date
Application number
PCT/US1999/015889
Other languages
French (fr)
Other versions
WO2000003856A9 (en
Inventor
Stephen Crane
Dave Gruenwald
Original Assignee
Brunswick Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brunswick Corporation filed Critical Brunswick Corporation
Priority to AU52123/99A priority Critical patent/AU5212399A/en
Priority to CA002337454A priority patent/CA2337454C/en
Priority to EP99937248A priority patent/EP1109658A1/en
Publication of WO2000003856A1 publication Critical patent/WO2000003856A1/en
Publication of WO2000003856A9 publication Critical patent/WO2000003856A9/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/04Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/22Making multilayered or multicoloured articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/34Component parts, details or accessories; Auxiliary operations
    • B29C41/36Feeding the material on to the mould, core or other substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/08Coating a former, core or other substrate by spraying or fluidisation, e.g. spraying powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0063Density
    • B29K2995/0064Non-uniform density

Definitions

  • the present invention relates generally to rotational molding methods and particularly to a rotational molding which create a shiny and hard surface layer for a molded part.
  • Rotational molding which is often referred to as "rotomolding”
  • Rotomolding is a process where a powdered thermoplastic is poured into a mold and the mold is suspended in an oven.
  • the material utilized for the powdered thermoplastic is often polyethylene, while the mold is ordinarily constructed from metal. Once suspended in the oven, the metal mold is heated beyond the melting point of the powder and rotated to evenly coat the inner surface of the mold with the melted plastic. Once properly heated, the mold is then cooled and the part is demolded.
  • the mold serves two purposes: (1) to transfer heat to the resin to establish the shape to be formed and (2) to provide a cavity in which to cool the material.
  • a pre- measured resin is loaded into the mold and the mold is disposed within an oven and rotated on both its vertical and horizontal axis. As the resin melts it sticks to the inner surface of the mold, coating such surface evenly. Usually, the rotation of the mold continues during the cooling cycle to allow the intended part to maintain an even wall thickness. Once the part is cooled, it is removed from the mold. Rotomolding has been utilized, amongst other items, for the manufacture of boats.
  • Rotomolding provides for consistent wall thickness and sharp outside corners which are essentially stress free.
  • Rotomolding has also been traditionally limited to use with a single material.
  • one specific problem with rotomolded products is that the surface of the product is soft.
  • the present invention discloses a process for creating an improved rotomolded products.
  • a material such as an acrylic polyethylene alloy
  • the inner mold area is sprayed with a material, such as an acrylic polyethylene alloy, prior to loading the resin into the mold.
  • the mold is then heated, rotated and cooled to form the molded part. Once cooled the part is then removed from the mold.
  • the acrylic polyethylene alloy is loaded into the mold with the resin. Once loaded, the mold is then heated, rotated and cooled. Once cooled the part is then removed from the mold.
  • a mold is opened and a first resin which is to become the outer surface of the part is added. Gte the first resin is added the mold is closed, heated and rotated. Once first resin is sufficiently melted, a "drop" box is opened within the mold to introduce a second resin into the mold. The second resin will become the body or structure of the molded part. After the second resin is introduced by the drop box, the mold is again heated and rotated as described above. As heating begins, the second resin material begins to melt and sticks to the inner surface of the mold over the first resin. Thus, when the mold is cooled, the first resin will form the surface layer of the part. Once cooled the mold is opened and the part is removed.
  • a mold is opened and a first resin which is to become the outer surface of the part is added.
  • the first resin is not an alloy but rather preferably consist of a separate material such as acrylic, polycarbonate, styrenic or other hardened plastic which will create a hardened outer shell.
  • a first drop box is opened within the mold to introduce a second resin which acts as a tie coat or bond layer.
  • the tie coat bonds to the first resin.
  • the mold is heated and rotated to evenly bond to the first resin which is provided over the inner surface of the mold.
  • a second drop box is opened within the mold and a third resin is released.
  • the third resin will become the body or structure of the molded part.
  • the mold is once again heated and rotated, allowing the third resin to become melted and evenly distributed over the inside of the mold.
  • This third resin bonds to the tie coat layer.
  • the previously released tie coat acts as a bridge or intermediary allowing the main body resin to bond to the first layer, thereby bonding two materials which might not normally bond.
  • the first resin will form the surface layer of the part, the second layer the tie coat and the third layer the main body or substrate of the par .
  • a rotomolded product can be constructed having an outer surface with different characteristics and properties as compared to its inner surface or substrate .
  • the methods provided for stronger bonds between the materials as compared to conventional methods, such as lamination.
  • the molded part can be provided with a shinier and harder surface layer as compared to previous rotational molding methods.
  • the present invention allows for a softer surface layer with a harder substrate layer.
  • Figure 1 is a block diagram of a first method for the rotational molding process of the present invention
  • Figure 2 is a block diagram of a second method for the rotational molding process of the present invention.
  • Figure 3 is a block diagram of a third method for the rotational molding process of the present invention.
  • Figure 4 is a block diagram of a fourth method for the rotational molding process of the present invention.
  • a first method is illustrated for the rotational molding process of the present invention.
  • a mold is provided which is shaped to correspond to the shape of the intended part.
  • a metal mold is utilized, however such is not limiting.
  • an inner area of the mold can be sprayed with an alloy consisting of acrylic and polyethylene in the preferred embodiment.
  • the invention is not limited to the specific acrylic polyethylene alloy for the outer surface.
  • other materials or alloys that will provide for a relatively hard outer surface can be substituted for the acrylic polyethylene alloy and are considered within the scope of the invention.
  • a conventional aerosol is utilized to spray the acrylic polyethylene alloy.
  • a conventional solvent material such as alcohol
  • the alcohol eventually evaporates off, after transporting the alloy, once the mold is heated.
  • the mold is preferably preheated prior to spraying the acrylic polyethylene alloy. Where preheated, upon being sprayed by the aerosol sprayer, the acrylic polyethylene alloy melts and sticks to the inner surface of the mold and ultimately will become the outer surface of the molded part . Having an outer surface consisting of the acrylic polyethylene alloy provides the molded part with a relatively harder appearance as compared to conventional rotational methods. The acrylic polyethylene alloy also provides a harder outer surface, less likely to crack.
  • the mold After spraying, the mold is loaded with a resin charge.
  • the preferred material for the resin is at least one form of polyethylene.
  • the resin can consist of polyethylene and can include two sizes of polyethylene to create a "sandwich" type structure having solid skins and a foamed polyethylene core.
  • the resin is also provided in powder form.
  • the mold is preferably disposed within a conventional rotomolding oven where it is heated and rotated. Any conventional method can be used for the heating and rotating of the mold.
  • the mold can be suspended or disposed within an oven and rotated on both its vertical and horizontal axis. The mold is heated to a temperature beyond the melting point of the resin which causes the resin to melt and stick to the inner surface of the mold which is already coated with the acrylic polyethylene alloy.
  • Rotating the mold allows for an even coat of the inner surface of the mold with the resin and the acrylic polyethylene alloy.
  • the mold is heated to a temperature ranging between 350° to 500°, however such range should not be considered limiting.
  • the resin and acrylic polyethylene alloy form the shape of the intended part, with the composite acting as a thin surface layer and bonding alloy, and the resin forming the substrate of the part.
  • the shape of the part corresponds to the shape of the mold.
  • the mold After the mold has been sufficiently heated and rotated, the mold remains closed and is allowed to cool. While cooling the mold can continue to be rotated to allow the part inside the mold to maintain an even wall thickness. Once properly cooled, the mold is opened or separated and the molded part is removed.
  • Figure 2 illustrates the second method for the rotational molding process of the present invention.
  • a mold similar to the mold described above is provided.
  • the acrylic polyethylene alloy is not sprayed prior to loading the resin. Rather, the acrylic polyethylene alloy is preferably provided in powder form and loaded into the mold at the same time the resin is loaded.
  • the resin is also preferably provided in powder form and can consist of one or more polyethylene materials. When loading, the alloy powder and the resin powder can be mixed together.
  • the particles consisting of the alloy powder are preferably smaller in size as compared to the particles constituting the resin powder.
  • the forces of gravity will caused the smaller size particles to move outward within the mold.
  • the smaller size alloy particles will also melt quicker than the larger size resin particles.
  • the force of gravity and quicker melting characteristics assure that the particles constituting the acrylic polyethylene alloy form the outer surface layer of the molded part .
  • the alloy material can be cryogenically ground to ensure that the size of the alloy material is smaller than the size of the resin material .
  • the mold is heated and rotated as described above. As heating begins, the smaller alloy material will melt first, as compared to the resin material. By melting first, the alloy material will stick to the inner surface of the mold. Once the resin material begins to melt it will also stick to the inner surface of the mold over the alloy material. Thus, when the mold is cooled, the alloy material will form the surface layer of the part, with the polyethylene portion of the composite acting as an alloy to bond the surface layer to the substrate formed by the resin material.
  • the substrate in one embodiment can consist of "sandwich" type structure with solid skins and a foamed polyethylene core.
  • the solid skins can also constructed from a polyethylene material.
  • the polyethylene material which makes up the solid skins will be sized smaller then the polyethylene material comprising the foamed core. As such, the polyethylene skin material will melt quicker then the core material causing it to travel outward from the foam material inside the mold.
  • the polyethylene material which comprises the substrate's core can be provided with a blowing agent to create a foam substrate.
  • the mold can also be preheated prior to loading the resin and alloy.
  • the preheating of the mold may cause the smaller alloy material to begin to melt, prior to the mold being fully heated during the heating and rotating steps.
  • the mold is also allowed to cool as described above, and thus, the mold can continue to be rotated during cooling to allow the part inside the mold to maintain an even wall thickness. Once cooled the mold is opened and the part is removed.
  • Figure 3 illustrates the third method for the rotational molding process of the present invention.
  • a mold similar to the mold described above is provided. Initially, the mold is opened and a first resin which is to become the outer surface of the part is added.
  • the first resin consist of any acrylic polyethylene alloy, though such is not limiting.
  • the resin is also preferably provided in powder form.
  • the mold is closed, heated and rotated.
  • the mold is heated to a temperature which causes the first resin to melt.
  • the melted first resin evenly sticks to the entire inner surface of the mold and ultimately will become the outer surface of the molded part.
  • a box commonly referred to as a "drop box" is opened within the mold to introduce a second resin into the mold.
  • the second resin will become the body or structure of the molded part.
  • the resin consist of a polyethylene material, though other materials can be used and are considered within the scope of the invention.
  • the need to grind the resins as described in the second method is eliminated, as the resins are introduced at separate times.
  • the mold is again heated and rotated as described above. As heating begins, the second resin material begins to melt and sticks to the inner surface of the mold over the first resin.
  • the first resin will form the surface layer of the part.
  • the polyethylene portion of the first resin composite acts as an alloy to bond the surface layer to the substrate formed by the second resin material.
  • the substrate in one embodiment can consist of "sandwich" type structure with solid skins and a foamed polyethylene core.
  • the solid skins can also constructed from a polyethylene material.
  • the polyethylene material which comprises the substrate's core can be provided with a blowing agent to create a foam substrate.
  • the mold can also be preheated prior to loading the first resin. The preheating of the mold, may cause the first resin to begin to melt, prior to the mold being fully heated during the heating and rotating steps.
  • the mold is also allowed to cool as described above, and thus, the mold can continue to be rotated during cooling to allow the part inside the mold to maintain an even wall thickness. Once cooled the mold is opened and the part is removed.
  • Figure 4 illustrates the fourth method for the rotational molding process of the present invention.
  • a mold similar to the mold described above is provided. Initially, the mold is opened and a first resin which is to become the outer surface of the part is added.
  • the first resin is not an alloy but rather consist of a separate material such as acrylic, polycarbonate, styrenic or other hardened plastic which will create a hardened outer shell.
  • the resin is also preferably provided in powder form.
  • the mold is closed, heated and rotated. The mold is heated to a temperature which causes the first resin to melt. By rotating, the melted first resin evenly sticks to the entire inner surface of the mold and ultimately will become the outer surface of the molded part.
  • a first drop box is opened within the mold to introduce a second resin which acts as a tie coat or bond layer, preferably consisting of a modified polyethylene or alloy material, though other materials can be used and are considered within the scope of the invention.
  • the tie coat bonds to the first resin.
  • the mold is heated and rotated to evenly bond to the first resin which is provided over the inner surface of the mold.
  • a second drop box is opened within the mold and a third resin is released.
  • the third resin will become the body or structure of the molded part .
  • the resin consist of a polyethylene material, though other materials can be used and are considered within the scope of the invention.
  • the mold is once again heated and rotated, allowing the third resin to become melted and evenly distributed over the inside of the mold.
  • This third resin bonds to the tie coat layer.
  • the previously released tie coat acts as a bridge or intermediary allowing the main body resin to bond to the first layer, thereby bonding two materials which might not normally bond.
  • the first resin will form the surface layer of the part, the second layer the tie coat and the third layer the main body or substrate of the part.
  • the substrate in one embodiment can consist of "sandwich" type structure with solid skins and a foamed polyethylene core.
  • the solid skins can also constructed from a polyethylene material .
  • the polyethylene material which comprises the substrate's core can be provided with a blowing agent to create a foam substrate .
  • the mold can also be preheated prior to loading the first resin. The preheating of the mold, may cause the first resin to begin to melt, prior to the mold being fully heated during the heating and rotating steps.
  • the mold is also allowed to cool as described above, and thus, the mold can continue to be rotated during cooling to allow the part inside the mold to maintain an even wall thickness . Once cooled the mold is opened and the part is removed.
  • the molded part can be provided with a harder, shinier and stronger surface layer as compared to parts molded by conventional rotational molding techniques.
  • the surface layer is also relatively thin as compared to the remaining portion of the molded part.
  • the outer surface layer can be the softer layer, with the substrate acting as the harder layer.
  • the present invention allows for an outer surface layer having different characteristics and properties than those of the inner surface layer.
  • the above-described methods also provide for a relatively stronger bond between the materials, as compared to traditional lamination.
  • a polyethylene material is used for the resin which the part is molded from.
  • a polyethylene material is included in the composite to act, amongst other things, as an alloy with the polyethylene resin.
  • the present invention should not be considered limited to polyethylene materials. Accordingly, it is within the scope of the invention to use other materials for the resin. In such event, it is preferred that a similar material, as the material selected for the resin, be selected as at least a part of the alloy material which forms the surface layer of the molded part .
  • the alloy material is not limited to being only the material used for the surface layer. It is within the scope of the invention to use a alloy material, such as the acrylic polyethylene combination, as the resin for the mold. In such cases, it is not necessary to provide a alloy material prior to adding the resin.
  • the above described methods can be utilized with various conventional molds.
  • the heating, rotating and cooling steps of the methods are performed utilizing conventional devices, i.e. ovens, molds, etc.

Abstract

A rotational molding method is provided consisting in a first method of spraying the inner mold area with an acrylic polyethylene alloy prior to loading the resin into the mold. The mold is then heated, rotated and cooled to form the molded part. The part is provided with a shinier and harder surface layer as compared to previous rotational molding methods. In a second method, in lieu of spraying, the acrylic polyethylene alloy is loaded into the mold with the resin. In the third and fourth methods, a drop box is provided for releasing resins into the mold. Other materials, in addition to acrylic polyethylene, can also be used with the various methods.

Description

ROTATIONAL MOLDING PROCESS
CROSS-REFERENCE TO RELATED APPLICATIONS Not applicable.
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT Not applicable.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates generally to rotational molding methods and particularly to a rotational molding which create a shiny and hard surface layer for a molded part.
2. Description of Related Art
Rotational molding, which is often referred to as "rotomolding" , is a process where a powdered thermoplastic is poured into a mold and the mold is suspended in an oven. The material utilized for the powdered thermoplastic is often polyethylene, while the mold is ordinarily constructed from metal. Once suspended in the oven, the metal mold is heated beyond the melting point of the powder and rotated to evenly coat the inner surface of the mold with the melted plastic. Once properly heated, the mold is then cooled and the part is demolded.
The mold serves two purposes: (1) to transfer heat to the resin to establish the shape to be formed and (2) to provide a cavity in which to cool the material. Typically, a pre- measured resin is loaded into the mold and the mold is disposed within an oven and rotated on both its vertical and horizontal axis. As the resin melts it sticks to the inner surface of the mold, coating such surface evenly. Usually, the rotation of the mold continues during the cooling cycle to allow the intended part to maintain an even wall thickness. Once the part is cooled, it is removed from the mold. Rotomolding has been utilized, amongst other items, for the manufacture of boats. Some advantages to rotomolding, as compared to other molding techniques is the relatively low cost for molds, ease in adaptation for short production runs, the elimination of secondary tooling and the minimal amount of scrap which is produced from the process. Rotomolding also provides for consistent wall thickness and sharp outside corners which are essentially stress free.
Rotomolding has also been traditionally limited to use with a single material. Thus, one specific problem with rotomolded products is that the surface of the product is soft.
When creating a structure comprise of at least two different materials, bonding of the materials is typically an issue, particularly with materials having disparate properties. In the past, rotomolding processes have not been used for marrying materials having separate properties.
It is therefore to the effective resolution of the aforementioned problem that the present invention is directed.
BRIEF SUMMARY OF THE INVENTION The present invention discloses a process for creating an improved rotomolded products. In a first method the inner mold area is sprayed with a material, such as an acrylic polyethylene alloy, prior to loading the resin into the mold. Once the resin is loaded, the mold is then heated, rotated and cooled to form the molded part. Once cooled the part is then removed from the mold. In a second method, in lieu of spraying, the acrylic polyethylene alloy is loaded into the mold with the resin. Once loaded, the mold is then heated, rotated and cooled. Once cooled the part is then removed from the mold.
In a third method, a mold is opened and a first resin which is to become the outer surface of the part is added. Gte the first resin is added the mold is closed, heated and rotated. Once first resin is sufficiently melted, a "drop" box is opened within the mold to introduce a second resin into the mold. The second resin will become the body or structure of the molded part. After the second resin is introduced by the drop box, the mold is again heated and rotated as described above. As heating begins, the second resin material begins to melt and sticks to the inner surface of the mold over the first resin. Thus, when the mold is cooled, the first resin will form the surface layer of the part. Once cooled the mold is opened and the part is removed.
In a fourth method, a mold is opened and a first resin which is to become the outer surface of the part is added. In this embodiment, the first resin is not an alloy but rather preferably consist of a separate material such as acrylic, polycarbonate, styrenic or other hardened plastic which will create a hardened outer shell. Once the first resin is added the mold is closed, heated and rotated. The mold is heated to a temperature which causes the first resin to melt.
Once the first resin is sufficiently melted, a first drop box is opened within the mold to introduce a second resin which acts as a tie coat or bond layer. The tie coat bonds to the first resin. After the second tie coat resin is released into the mold, the mold is heated and rotated to evenly bond to the first resin which is provided over the inner surface of the mold.
Once the tie coat is properly melted, a second drop box is opened within the mold and a third resin is released. The third resin will become the body or structure of the molded part. After the third resin is released into the mold, the mold is once again heated and rotated, allowing the third resin to become melted and evenly distributed over the inside of the mold. This third resin bonds to the tie coat layer. The previously released tie coat acts as a bridge or intermediary allowing the main body resin to bond to the first layer, thereby bonding two materials which might not normally bond. Thus, when the mold is cooled, the first resin will form the surface layer of the part, the second layer the tie coat and the third layer the main body or substrate of the par . Once cooled the mold is opened and the part is removed.
With all of the methods, a rotomolded product can be constructed having an outer surface with different characteristics and properties as compared to its inner surface or substrate . The methods provided for stronger bonds between the materials as compared to conventional methods, such as lamination. Thus, in one embodiment the molded part can be provided with a shinier and harder surface layer as compared to previous rotational molding methods. Alternatively, the present invention allows for a softer surface layer with a harder substrate layer.
Accordingly, it is an object of the present invention to provide a rotational molding process which yields a harder outer surface of a molded part as compared to conventional rotational molding processes.
It is another object of the present invention to provide a rotational molding process which yields a stronger bond between the surface layer and the substrate of a molded part as compared to conventional rotational molding processes.
In accordance with these and other objects which will become apparent hereinafter, the instant invention will now be described with particular reference to the accompanying drawings.
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
The invention may be better understood by reference to the drawings in which:
Figure 1 is a block diagram of a first method for the rotational molding process of the present invention;
Figure 2 is a block diagram of a second method for the rotational molding process of the present invention;
Figure 3 is a block diagram of a third method for the rotational molding process of the present invention; and Figure 4 is a block diagram of a fourth method for the rotational molding process of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
As seen in Figure 1 a first method is illustrated for the rotational molding process of the present invention. In the first method a mold is provided which is shaped to correspond to the shape of the intended part. Preferably, a metal mold is utilized, however such is not limiting. After the mold is opened, an inner area of the mold can be sprayed with an alloy consisting of acrylic and polyethylene in the preferred embodiment. However, it should be understood that the invention is not limited to the specific acrylic polyethylene alloy for the outer surface. Thus, other materials or alloys that will provide for a relatively hard outer surface can be substituted for the acrylic polyethylene alloy and are considered within the scope of the invention.
Preferably, a conventional aerosol is utilized to spray the acrylic polyethylene alloy. As the alloy is preferably in a powder form, a conventional solvent material, such as alcohol, can be provided to act as carrier of the alloy from the aerosol sprayer to the mold. The alcohol eventually evaporates off, after transporting the alloy, once the mold is heated.
The mold is preferably preheated prior to spraying the acrylic polyethylene alloy. Where preheated, upon being sprayed by the aerosol sprayer, the acrylic polyethylene alloy melts and sticks to the inner surface of the mold and ultimately will become the outer surface of the molded part . Having an outer surface consisting of the acrylic polyethylene alloy provides the molded part with a relatively harder appearance as compared to conventional rotational methods. The acrylic polyethylene alloy also provides a harder outer surface, less likely to crack.
After spraying, the mold is loaded with a resin charge. Though the present invention is intended to be used with various materials used for the resin, the preferred material for the resin is at least one form of polyethylene. However, other materials for the resin are considered within the scope of the invention. The resin can consist of polyethylene and can include two sizes of polyethylene to create a "sandwich" type structure having solid skins and a foamed polyethylene core. Preferably, the resin is also provided in powder form.
Once the resin is loaded into the mold, the mold is preferably disposed within a conventional rotomolding oven where it is heated and rotated. Any conventional method can be used for the heating and rotating of the mold. Thus, the mold can be suspended or disposed within an oven and rotated on both its vertical and horizontal axis. The mold is heated to a temperature beyond the melting point of the resin which causes the resin to melt and stick to the inner surface of the mold which is already coated with the acrylic polyethylene alloy.
Rotating the mold allows for an even coat of the inner surface of the mold with the resin and the acrylic polyethylene alloy. Where polyethylene is used as the resin, preferably the mold is heated to a temperature ranging between 350° to 500°, however such range should not be considered limiting.
Once sufficiently melted, the resin and acrylic polyethylene alloy form the shape of the intended part, with the composite acting as a thin surface layer and bonding alloy, and the resin forming the substrate of the part. The shape of the part corresponds to the shape of the mold.
After the mold has been sufficiently heated and rotated, the mold remains closed and is allowed to cool. While cooling the mold can continue to be rotated to allow the part inside the mold to maintain an even wall thickness. Once properly cooled, the mold is opened or separated and the molded part is removed.
Figure 2 illustrates the second method for the rotational molding process of the present invention. In this method, a mold, similar to the mold described above is provided. However, the acrylic polyethylene alloy is not sprayed prior to loading the resin. Rather, the acrylic polyethylene alloy is preferably provided in powder form and loaded into the mold at the same time the resin is loaded. The resin is also preferably provided in powder form and can consist of one or more polyethylene materials. When loading, the alloy powder and the resin powder can be mixed together.
The particles consisting of the alloy powder are preferably smaller in size as compared to the particles constituting the resin powder. When the alloy and resin are loaded the forces of gravity will caused the smaller size particles to move outward within the mold. The smaller size alloy particles will also melt quicker than the larger size resin particles. Thus, the force of gravity and quicker melting characteristics assure that the particles constituting the acrylic polyethylene alloy form the outer surface layer of the molded part .
As with the first method, other materials can be used for the outer surface and/or resin and are considered within the scope of the invention.
Where a powder is used for the resin, the alloy material can be cryogenically ground to ensure that the size of the alloy material is smaller than the size of the resin material . The mold is heated and rotated as described above. As heating begins, the smaller alloy material will melt first, as compared to the resin material. By melting first, the alloy material will stick to the inner surface of the mold. Once the resin material begins to melt it will also stick to the inner surface of the mold over the alloy material. Thus, when the mold is cooled, the alloy material will form the surface layer of the part, with the polyethylene portion of the composite acting as an alloy to bond the surface layer to the substrate formed by the resin material. As discussed above, the substrate in one embodiment can consist of "sandwich" type structure with solid skins and a foamed polyethylene core. In this embodiment, the solid skins can also constructed from a polyethylene material. To achieve the "sandwich" structure, in either method of the invention, the polyethylene material which makes up the solid skins will be sized smaller then the polyethylene material comprising the foamed core. As such, the polyethylene skin material will melt quicker then the core material causing it to travel outward from the foam material inside the mold. The polyethylene material which comprises the substrate's core can be provided with a blowing agent to create a foam substrate.
The mold can also be preheated prior to loading the resin and alloy. The preheating of the mold, may cause the smaller alloy material to begin to melt, prior to the mold being fully heated during the heating and rotating steps. The mold is also allowed to cool as described above, and thus, the mold can continue to be rotated during cooling to allow the part inside the mold to maintain an even wall thickness. Once cooled the mold is opened and the part is removed.
Figure 3 illustrates the third method for the rotational molding process of the present invention. In this method, a mold, similar to the mold described above is provided. Initially, the mold is opened and a first resin which is to become the outer surface of the part is added. In the preferred embodiment the first resin consist of any acrylic polyethylene alloy, though such is not limiting. The resin is also preferably provided in powder form.
Once the first resin is added the mold is closed, heated and rotated. The mold is heated to a temperature which causes the first resin to melt. By rotating, the melted first resin evenly sticks to the entire inner surface of the mold and ultimately will become the outer surface of the molded part.
Once the first resin is sufficiently melted, a box, commonly referred to as a "drop box", is opened within the mold to introduce a second resin into the mold. The second resin will become the body or structure of the molded part. In the preferred embodiment the resin consist of a polyethylene material, though other materials can be used and are considered within the scope of the invention. With the use of a drop box, the need to grind the resins as described in the second method is eliminated, as the resins are introduced at separate times. After the second resin is introduced by the drop box, the mold is again heated and rotated as described above. As heating begins, the second resin material begins to melt and sticks to the inner surface of the mold over the first resin. Thus, when the mold is cooled, the first resin will form the surface layer of the part. In the preferred embodiment, the polyethylene portion of the first resin composite acts as an alloy to bond the surface layer to the substrate formed by the second resin material.
As discussed above, the substrate in one embodiment can consist of "sandwich" type structure with solid skins and a foamed polyethylene core. In this embodiment, the solid skins can also constructed from a polyethylene material. The polyethylene material which comprises the substrate's core can be provided with a blowing agent to create a foam substrate. In the third method, the mold can also be preheated prior to loading the first resin. The preheating of the mold, may cause the first resin to begin to melt, prior to the mold being fully heated during the heating and rotating steps. The mold is also allowed to cool as described above, and thus, the mold can continue to be rotated during cooling to allow the part inside the mold to maintain an even wall thickness. Once cooled the mold is opened and the part is removed.
Figure 4 illustrates the fourth method for the rotational molding process of the present invention. In this method, a mold, similar to the mold described above is provided. Initially, the mold is opened and a first resin which is to become the outer surface of the part is added. In this embodiment, the first resin is not an alloy but rather consist of a separate material such as acrylic, polycarbonate, styrenic or other hardened plastic which will create a hardened outer shell. The resin is also preferably provided in powder form. Once the first resin is added the mold is closed, heated and rotated. The mold is heated to a temperature which causes the first resin to melt. By rotating, the melted first resin evenly sticks to the entire inner surface of the mold and ultimately will become the outer surface of the molded part.
Once the first resin is sufficiently melted, a first drop box is opened within the mold to introduce a second resin which acts as a tie coat or bond layer, preferably consisting of a modified polyethylene or alloy material, though other materials can be used and are considered within the scope of the invention. The tie coat bonds to the first resin. After the second tie coat resin is released into the mold, the mold is heated and rotated to evenly bond to the first resin which is provided over the inner surface of the mold. Once the tie coat is properly melted, a second drop box is opened within the mold and a third resin is released. The third resin will become the body or structure of the molded part . In the preferred embodiment the resin consist of a polyethylene material, though other materials can be used and are considered within the scope of the invention.
After the third resin is released into the mold, the mold is once again heated and rotated, allowing the third resin to become melted and evenly distributed over the inside of the mold. This third resin bonds to the tie coat layer. The previously released tie coat acts as a bridge or intermediary allowing the main body resin to bond to the first layer, thereby bonding two materials which might not normally bond. Thus, when the mold is cooled, the first resin will form the surface layer of the part, the second layer the tie coat and the third layer the main body or substrate of the part.
As discussed above, the substrate in one embodiment can consist of "sandwich" type structure with solid skins and a foamed polyethylene core. In this embodiment, the solid skins can also constructed from a polyethylene material . The polyethylene material which comprises the substrate's core can be provided with a blowing agent to create a foam substrate . In the fourth method, the mold can also be preheated prior to loading the first resin. The preheating of the mold, may cause the first resin to begin to melt, prior to the mold being fully heated during the heating and rotating steps. The mold is also allowed to cool as described above, and thus, the mold can continue to be rotated during cooling to allow the part inside the mold to maintain an even wall thickness . Once cooled the mold is opened and the part is removed.
In all of the above-described methods, the molded part can be provided with a harder, shinier and stronger surface layer as compared to parts molded by conventional rotational molding techniques. The surface layer is also relatively thin as compared to the remaining portion of the molded part. Alternatively, the outer surface layer can be the softer layer, with the substrate acting as the harder layer. Thus, the present invention allows for an outer surface layer having different characteristics and properties than those of the inner surface layer. The above-described methods also provide for a relatively stronger bond between the materials, as compared to traditional lamination.
The invention is described above where a polyethylene material is used for the resin which the part is molded from. Thus, a polyethylene material is included in the composite to act, amongst other things, as an alloy with the polyethylene resin. However, as stated above, the present invention should not be considered limited to polyethylene materials. Accordingly, it is within the scope of the invention to use other materials for the resin. In such event, it is preferred that a similar material, as the material selected for the resin, be selected as at least a part of the alloy material which forms the surface layer of the molded part .
Furthermore, the alloy material is not limited to being only the material used for the surface layer. It is within the scope of the invention to use a alloy material, such as the acrylic polyethylene combination, as the resin for the mold. In such cases, it is not necessary to provide a alloy material prior to adding the resin.
The above described methods can be utilized with various conventional molds. The heating, rotating and cooling steps of the methods are performed utilizing conventional devices, i.e. ovens, molds, etc.
The instant invention has been shown and described herein in what is considered to be the most practical and preferred embodiment. It is recognized, however, that departures may be made therefrom within the scope of the invention and that obvious modifications will occur to a person skilled in the art.

Claims

CLAIMSWhat Is Claimed Is:
1. A rotational molding method comprising the steps of:
(a) spraying an inner surface of a mold with a first resin;
(b) adding a second resin to said mold; (c) heating and rotating said mold to form a part having a shape resembling the shape of the mold;
(d) cooling said mold; and
(e) removing said part.
2. The rotational molding method of claim 1 wherein step (c) includes heating the mold to a temperature beyond the melting point of the first and second resins.
3. The rotational molding method of claim 1 wherein step (c) includes rotating the mold to evenly coat the inner surface of the mold with the first and second resins.
4. The rotational molding method of claim 1 further including the step of preheating the mold prior to spraying the inner surface of the mold with the first resin which causes the first resin to melt and stick to an inner surface of the mold.
5. The rotational molding method of claim 4 wherein heating the mold to a temperature beyond the melting point of the second resin causes the second resin to melt and stick to the inner surface of the mold which is already coated with the first resin.
6. The rotational molding method of claim 1 wherein said mold continues to rotate while the mold is cooled during step (d) to allow the part to maintain an even wall thickness.
7. The rotational molding method of claim 1 wherein said first resin is an acrylic polyethylene alloy.
8. A rotational molding method for forming a part, said part have an outer surface, said method comprising the steps of:
(a) preheating a mold having an inner surface and a specific shape;
(b) opening said mold;
(c) spraying an inner area of said mold with an acrylic polyethylene alloy which will form an outer surface of a molded part, said preheating of the mold causing said acrylic polyethylene alloy to begin to melt and coat the inner surface of the mold;
(d) adding a resin to said mold which will form a body of the molded part;
(e) closing said mold;
(f) heating the mold to a temperature beyond the melting point of the resin and rotating said mold to form a part having a shape resembling the shape of the mold, said heating causing said resin to melt and stick to the inner surface of said mold over the acrylic polyethylene alloy, said rotating causing the inner surface of said mold to be evenly coated with said resin and acrylic polyethylene alloy;
(g) cooling said mold; and (h) opening said mold and removing said part.
9. The rotational molding method of claim 8 wherein said mold continues to rotate while the mold is cooled during step
(g) to allow the part to maintain an even wall thickness.
10. A rotational molding method comprising the steps of: (a) adding a first resin and a second resin to a mold;
(b) heating and rotating said mold to form a part having an outer surface and a shape resembling the shape of the mold;
(c) cooling said mold; and (d) removing said part.
11. The rotational molding method of claim 10 wherein said first resin consisting of particles sized smaller than particles which comprise said second resin, causing said first resin to melt quicker than said second resin and form the outer surface of said part.
12. The rotational molding method of claim 10 further including the step of preheating the mold prior to adding the first and second resins.
13. The rotational molding method of claim 10 wherein step (b) includes heating the mold to a temperature beyond the melting point of the first and second resins.
14. The rotational molding method of claim 10 wherein step
(b) includes rotating the mold to evenly coat the inner surface of the mold with the first and second resins.
15. The rotational molding method of claim 13 wherein heating the mold to a temperature beyond the melting point of the second resin causes the second resin to melt and stick to and evenly coat the inner surface of the mold which is already coated with the first resin.
16. The rotational molding method of claim 10 wherein said mold continues to rotate while the mold is cooled during step
(c) to allow the part to maintain an even wall thickness.
17. The rotational molding method of claim 10 wherein said first resin consist of an acrylic polyethylene alloy.
18. A rotational molding method for forming a part, said part have an outer surface, said method comprising the steps of: (a) opening a mold having an inner surface and specific shape;
(b) adding a resin and an acrylic polyethylene alloy 90 to said mold;
(c) closing said mold;
(d) heating the mold to a temperature beyond the melting point of the resin and rotating said mold to form a part having an outer surface and a shape resembling the shape of the
95 mold, said acrylic polyethylene alloy consisting of particles sized smaller than particles comprising said resin, causing said acrylic polyethylene alloy to melt quicker than said resin to allow the acrylic polyethylene alloy to form an outer surface of a molded part and the resin to form a body portion of the molded 100 part, said rotating causing the inner surface of said mold to be evenly coated with said resin and acrylic polyethylene alloy;
(e) cooling said mold; and
(f) opening said mold and removing said part.
19. The rotational molding method of claim 18 further 105 including the step of preheating the mold prior to adding the resin and acrylic polyethylene alloy.
20. The rotational molding method of claim 18 wherein said mold continues to rotate while the mold is cooled during step
(e) to allow the part to maintain an even wall thickness.
110 21. A rotational molding method comprising the steps of:
(a) adding a first resin to a mold;
(b) heating and rotating said mold to allow said first resin to melt and form an outer surface of a molded part;
(c) releasing a second resin into the mold through a 115 drop box;
(d) heating and rotating said mold to allow said second resin to melt over the first resin and to form a body portion of the molded part;
(e) cooling said mold; and 120 (f) removing said part.
22. The rotational molding method of claim 21 further including the step of preheating the mold prior to adding the first resin which causes the first resin to begin melt and stick to an inner surface of the mold.
125 23. The rotational molding method of claim 21 wherein said mold continues to rotate while the mold is cooled during step (e) to allow the molded part to maintain an even wall thickness .
24. The rotational molding method of claim 21 wherein said 130 first resin is an acrylic polyethylene alloy.
25. A rotational molding method comprising the steps of:
(a) adding a first resin to a mold;
(b) heating and rotating said mold to allow said first resin to melt and form an outer surface of a molded part;
135 (c) releasing a tie coat or bonding layer into the mold through a first drop box;
(d) heating and rotating said mold to allow said tie coat to melt over and bond to the first resin;
(e) releasing a third resin into the mold through a 140 second drop box;
(f) heating and rotating said mold to allow said second resin to melt over and bond to the tie coat and to form a body portion of the molded part;
(g) cooling said mold; and 145 (h) removing said molded part.
26. The rotational molding method of claim 25 further including the step of preheating the mold prior to adding the first resin which causes the first resin to begin melt and stick to an inner surface of the mold.
27. The rotational molding method of claim 25 wherein said mold continues to rotate while the mold is cooled during step (g) to allow the molded part to maintain an even wall thickness .
PCT/US1999/015889 1998-07-14 1999-07-13 Rotational molding process WO2000003856A1 (en)

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AU52123/99A AU5212399A (en) 1998-07-14 1999-07-13 Rotational molding process
CA002337454A CA2337454C (en) 1998-07-14 1999-07-13 Rotational molding process
EP99937248A EP1109658A1 (en) 1998-07-14 1999-07-13 Rotational molding process

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US09/115,132 US6214272B1 (en) 1998-07-14 1998-07-14 Rotational molding process

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AU5212399A (en) 2000-02-07
WO2000003856A9 (en) 2000-07-20
US6214272B1 (en) 2001-04-10
CA2337454A1 (en) 2000-01-27
CA2337454C (en) 2009-01-27

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