WO2000019952A1 - Elastic laminate including nonwoven layer formed from highly oriented component fibers - Google Patents

Elastic laminate including nonwoven layer formed from highly oriented component fibers Download PDF

Info

Publication number
WO2000019952A1
WO2000019952A1 PCT/US1998/021013 US9821013W WO0019952A1 WO 2000019952 A1 WO2000019952 A1 WO 2000019952A1 US 9821013 W US9821013 W US 9821013W WO 0019952 A1 WO0019952 A1 WO 0019952A1
Authority
WO
WIPO (PCT)
Prior art keywords
nonwoven layer
elastic laminate
layer
elastomeric
nonwoven
Prior art date
Application number
PCT/US1998/021013
Other languages
French (fr)
Inventor
Ebrahim Rezai
Yoko Mizutani
Kazuyuki Ohnishi
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to AU96857/98A priority Critical patent/AU9685798A/en
Priority to PCT/US1998/021013 priority patent/WO2000019952A1/en
Priority to DE1999628420 priority patent/DE69928420T2/en
Priority to AT99951630T priority patent/ATE309904T1/en
Priority to EP99951630A priority patent/EP1117530B1/en
Priority to JP2000573543A priority patent/JP2003524533A/en
Priority to AU64031/99A priority patent/AU6403199A/en
Priority to PCT/US1999/022471 priority patent/WO2000020206A1/en
Priority to US09/806,047 priority patent/US6878647B1/en
Priority to CA002345756A priority patent/CA2345756A1/en
Priority to PE1999001001A priority patent/PE20001001A1/en
Priority to TW088121661A priority patent/TW434007B/en
Publication of WO2000019952A1 publication Critical patent/WO2000019952A1/en
Priority to JP2010146661A priority patent/JP5925412B2/en
Priority to JP2014119038A priority patent/JP2014221549A/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/45Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the shape
    • A61F13/49Absorbent articles specially adapted to be worn around the waist, e.g. diapers
    • A61F13/49007Form-fitting, self-adjusting disposable diapers
    • A61F13/49009Form-fitting, self-adjusting disposable diapers with elastic means
    • A61F13/4902Form-fitting, self-adjusting disposable diapers with elastic means characterised by the elastic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00Other non-woven fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/007Addition polymers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/005Synthetic yarns or filaments
    • D04H3/009Condensation or reaction polymers
    • D04H3/011Polyesters
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/14Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic yarns or filaments produced by welding
    • D04H3/147Composite yarns or filaments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F5/00Orthopaedic methods or devices for non-surgical treatment of bones or joints; Nursing devices; Anti-rape devices
    • A61F5/44Devices worn by the patient for reception of urine, faeces, catamenial or other discharge; Portable urination aids; Colostomy devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0253Polyolefin fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/02Cellular or porous
    • B32B2305/024Honeycomb
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/10Fibres of continuous length
    • B32B2305/20Fibres of continuous length in the form of a non-woven mat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514Oriented
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2555/00Personal care
    • B32B2555/02Diapers or napkins

Definitions

  • the present invention relates to elastic laminates. More specifically, the present invention relates to elastic laminates which includes a nonwoven layer formed from highly oriented component fibers.
  • Elastic laminates have previously been used in a variety of disposable products, including sweat bands, bandages, body wraps, and disposable garments including disposable diapers and incontinence devices.
  • elastic laminate refers to an elastically stretchable two or more layered materials including at least one elastically stretchable single layer material. It is generally expected that these products provide good fit to the body and/or skin of the user by using suitable elastic members during the entire use period of products.
  • a “zero strain” stretch laminate is one type of elastic laminate which is preferably used for such disposable products.
  • methods for making "zero strain” stretch laminate webs are disclosed in U.S. Patent No. 5,167,897 issued to Weber et al. on December 1 , 1992; U.S. Patent No. 5,156,793 issued to Buell et al. on October 20, 1990; and U.S. Patent No. 5,143,679 issued to Weber et al. on September 1, 1992.
  • the elastomeric material is operatively joined to at least one component material in a substantially untensioned (zero strain) condition.
  • At least a portion of the resultant composite stretch laminate is then subjected to mechanical stretching sufficient to permanently elongate the non-elastic components.
  • the composite stretch laminate is then allowed to return to its substantially untensioned condition.
  • the elastic laminate is formed into a "zero strain" stretch laminate.
  • zero strain stretch laminate refers to a laminate comprised of at least two plies of material which are secured to one another along at least a portion of their coextensive surfaces while in a substantially untensioned (“zero strain") condition; one of the plies comprising a material which is stretchable and elastomeric (i.e., will return substantially to its untensioned dimensions after an applied tensile force has been released) and a second ply which is elongatable (but not necessarily elastomeric) so that upon stretching the second ply will be, at least to a degree, permanently elongated so that upon release of the applied tensile forces, it will not fully return to its original undeformed configuration.
  • the manufacturing process of such "zero strain" stretch laminate includes the step of subjecting the non-elastic composite stretch laminate to mechanical stretching sufficient to permanently elongate the non-elastic components. This step is additional to normal elastic lamination processes and gives limitations to materials to be used in the elastic laminate. For example, the elastomeric material and other composite material(s) used in the elastic laminate need to have enough physical strength or toughness since those materials tend to be mechanically damaged by the process.
  • the elastomeric material for example, does not have enough strength or toughness, the elastomeric material tends to be easily shred or torn by the stress which is applied to the elastomeric material during the mechanical stretching in the manufacturing process and during the use of products.
  • the present invention is directed to an elastic laminate which is elastically extensible in at least one direction.
  • the elastic laminate includes an elastomeric material having a first surface and a second surface opposing the first surface; and a first nonwoven layer joined to the first surface of the elastomeric material.
  • the first nonwoven layer is formed from component fibers having a primary fiber direction.
  • the first nonwoven layer has a Fiber Orientation Ratio within about ⁇ 20 degrees from the primary fiber direction of at least about 65%.
  • Fig. 1 is a fragmentary enlarged perspective view of an elastic laminate of one preferred embodiment of the present invention, prior to being formed into the elastic laminate;
  • Fig. 2 is a simplified cross-sectional view of an elastic laminate of another preferred embodiment
  • Fig. 3 is a enlarged perspective view of an elastic laminate of yet another embodiment of the present invention, wherein a portion of the nonwoven layer has been removed to show the bonded structure;
  • Fig. 4 is a fragmentary enlarged perspective view of an alternative embodiment of the elastomeric material.
  • Fig. 5 is a schematic representation of a lamination device for forming the elastic laminate shown in Fig. 3.
  • joind or “joining” encompasses configurations whereby an element is directly secured to another by affixing the element directly to the other element, and configurations whereby the element is indirectly secured to the other element by affixing the element to intermediate member(s) which in turn are affixed to the other element.
  • layer does not necessarily limit the element to a single stratum of material in that a layer may actually comprise laminates or combinations of sheets or webs of materials.
  • nonwoven may include any material which has been formed without the use of textile weaving processes which produce a structure of individual fibers which are interwoven in an identifiable manner.
  • Methods of making suitable nonwovens includes a spunbonded nonwoven process, a meltblown nonwoven process, a carded nonwoven process, or the like.
  • the present invention relates to an elastic laminate which does not have a limitation(s) to an elastomeric material to be used therein. This and other advantages of the invention are described in more detail herein.
  • Fig. 1 is a fragmentary enlarged perspective view of an elastic laminate 70 of one preferred embodiment, prior to being formed into the elastic laminate. (Preferred embodiments of the elastic laminate 70 after the formation are shown in Figs. 2 and 3.)
  • the elastic laminate 70 of the present invention includes an elastomeric layer 124 having a first surface 150 and a second surface 152 opposing the first surface 150; and a first nonwoven layer 122 which is joined to the first surface 150 of the elastomeric layer 124.
  • the first surface 150 and second surface 152 of the elastomeric layer 124 are substantially parallel with the plane of the first nonwoven layer 122.
  • the first nonwoven layer 122 has an inner surface (or a first surface) 142 and an outer surface (or a second surface) 144.
  • the inner surface 142 of the first nonwoven layer 122 is the surface that is positioned facing the elastomeric layer 124.
  • the elastic laminate 70 further comprises a second nonwoven layer 126 joined to the second surface 152 of the elastic material 70.
  • the second nonwoven layer 126 also has an inner surface 146 and an outer surface 148.
  • the inner surface 146 of the second nonwoven layer 126 is the surface that is positioned facing the elastomeric layer 124.
  • the second surface 152 of the elastomeric layer 124 is substantially parallel with the plane of the second nonwoven layer 126.
  • the nonwoven layer 126 is formed by an identical nonwoven material with that is employed in the first nonwoven layer 122.
  • the nonwoven layer 126 may be formed by a different material from that is employed in the first nonwoven layer 122.
  • the elastic laminate 70 of the present invention is elastically extensible in at least one direction (first direction).
  • first direction the elastic laminate 70 shown in Fig. 1 is elastically extensible in the structural direction D.
  • structural direction e.g., D and B
  • structural direction B is intended to mean a direction which extends substantially along and parallel to the plane of the first nonwoven layer 122.
  • the elastic laminate 70 is also elastically extensible in the second direction which is perpendicular to the first direction.
  • the elastic laminate 70 shown in Fig. 1 is also elastically extensible in the structural direction B.
  • the first nonwoven layer 122 of the present invention is formed from component fibers which are joined together.
  • the component fibers have a primary fiber direction.
  • the first nonwoven layer 122 has a Fiber Orientation Ratio within about ⁇ 20 degrees from the primary fiber direction (FOR20) of at least about 65%; more oreferably at least about 75%; more preferably still at least about 85%.
  • the first nonwoven layer 122 additionally has a Fiber Orientation Ratio within about ⁇ 10 degrees from the primary fiber direction (FOR10) of at least about 45%; more preferably at least about 60%; more preferably still at least about 70%.
  • Fiber Orientation Ratio indicates the ratio of the number of the component fibers whose directions are within about ⁇ # degrees, (e.g., ⁇ 10 degrees) from the primary fiber direction to the total number of component fibers.
  • primary fiber direction refers to an average direction of component fibers in the nonwoven layer.
  • the first nonwoven layer 122 has a Tensile Strength Ratio (TSR) of at least about 15, more preferably at least about 60.
  • TSR Tensile Strength Ratio
  • TS1 a tensile strength (TS) at the breaking point in the primary fiber direction
  • TS2 a tensile strength (TS) at the breaking point in the perpendicular direction which is perpendicular to the primary fiber direction.
  • Tensile Strength (ST) is measured as the maximum tensile strength value recorded while the first nonwoven layer 122 is stretched at a rate of about 20 inches/min (about 50 cm/min) to its breaking point. The tensile strength of the first nonwoven layer 122 is measured before the first nonwoven layer 122 is joined to the elastomeric layer 124.
  • the first nonwoven layer 122 has a tensile strength of less than about 200 gf/inch (about 80 gf/cm) at 30% elongation to the direction which is perpendicular to the primary fiber direction; more preferably less than about 100 gf/inch (about 40 gf/cm), more preferably still less than about 50 gf/inch (about 20 gf/cm).
  • the first nonwoven layer 122 may be manufactured from a wide range of component fibers including, e.g., natural fibers (e.g., wool and cotton fibers), synthetic fibers (e.g., polyolefin, polyester, nylon, and rayon fibers), or a mixture of natural fibers and/or synthetic fibers.
  • the first nonwoven layer 122 is preferably formed from synthetic continuous fibers. More preferably, such synthetic continuous fibers are formed from a polyolefin (e.g., polyethylene and polypropylene) or a polyester.
  • Preferred polyester material includes a polyethylene terephthalate, a polybutylene terephthalate and a polypropylene terephthalate, or mixtures thereof.
  • the first nonwoven layer 122 additionally includes component fibers formed from the other materials (i.e., non-polyester materials) such as polyolefin and nylon.
  • the individual component fibers are formed from a single type of material which is selected from the above materials (i.e., the individual fiber is not made from polyolefin and nylon).
  • the component fibers are formed from a polyester, more preferably a polyethylene terepthalate, or one of its relatives which has an average molecular weight from about 5,000 to about 60,000, preferably from about 10,000 to about 40,000, more preferably from about 14,000 to about 23,000.
  • the component fibers may be formed from a mixture of two (or more) materials which are selected from the above materials.
  • the component fiber has a bi-component fiber structure formed from two distinct materials of a polyester and a polyolefin.
  • the component fiber has a bi-component fiber structure formed from two distinct molecular weight materials of one identical material, for example, a polyester.
  • Preferred bi-component fiber structures may include a side-by-side bi- component fiber structure and a sheath-core bi-component fiber structure known in the art.
  • the component fiber has a bi-component fiber structure having a core of polyolefin and a sheath of a polyester.
  • the first nonwoven layer 122 has a basis weight of less than about 60 g/r ⁇ r, and comprises fibers having a fiber diameter of less than about 50 ⁇ m. More preferably, for products such as disposable garment and the like, the first nonwoven layer 122 has a basis weight of from about 3 g/m ⁇ to about 50 g/m ⁇ , more preferably from about 10 g/m ⁇ to about 25 g/m ⁇ , and a fiber diameter of from about 1 ⁇ m to about 30 ⁇ m, more preferably from about 3 ⁇ m to about 20 ⁇ m.
  • the component fibers may be joined together by adhesives, thermal bonding, water-jetting, needling/felting, or other methods known in the art to form nonwoven fabrics.
  • the first nonwoven layer 122 is formed from a nonwoven manufacturing process handling continuous component fibers or filaments known in the art. Preferred manufacturing process are described in, for example, EP 0843036A1 (Kurihara et al.) published on May 20, 1998; U.S. Patent No. 5,312,500, entitled “Non-Woven Fabric and Method and Apparatus for Making The Same", issued to Kurihara et al. on May 17, 1994; Japanese Laid-Open Patent Publication (Kokai) No. H2-269859 published on November 5, 1990; and Japanese Patent Publication (Kokoku) No. S60-25541 published on June 19, 1985.
  • Preferred nonwoven fabrics which are suitably applicable to the first nonwoven layer 122 are available from Nippon Petrochemicals Co., Ltd., Tokyo, Japan, under Code Nos. MBE8202-3-2; MBE8202-3-1 ; MBE7711-2; MBE6515-10; and MBE7922-1 which have the following properties.
  • the elastomeric layer 124 may be formed in a wide variety of sizes, forms and shapes.
  • the elastomeric layer 124 is in the form of a continuous plane layer such as shown in, for example, Fig. 1.
  • Preferred forms of a continuous plane layer include a scrim, a perforated (or apertures formed) film, an elastomeric woven or nonwoven, and the like.
  • the elastomeric layer 124 has a thickness of from about 0.05 mm to about 1 mm (about 0.002 inch - about 0.039 inch).
  • the continuous plane layer may take any shape which can be suitably provided in products.
  • Preferred shapes of a continuous plane layer include a quadrilateral including a rectangle and a square, a trapezoid, and the other polygons.
  • the elastomeric layer 124 is in the form of discrete strands (or strings) which are not connected each other.
  • the elastomeric material of the present invention may include all suitable elastic materials known in the art.
  • Elastomeric materials suitable for use herein include synthetic or natural rubber materials known in the art.
  • Preferred elastomeric materials include the diblock and triblock copolymers based on polystyrene and unsaturated or fully hydrogenerated rubber bolcks, and their blends with other polymers such as polyolefin polymers.
  • the elastomeric material is made from a polystyrene thermoplastic elastomer including styrene block copolymer based materials.
  • a preferred styrenic block copolymer based material contains from about 1 wt% to about 70 wt% of polystyrene, more preferably from about 10 wt% to about 50 wt% of polystyrene.
  • the polystyrene thermoplastic elastomer is selected from the group consisting of a styrene-butadiene-styrene thermoplastic elastomer, a styrene-isopren-styrene thermoplastic elastomer, a styrene-ethylene/butylene- styrene thermoplastic elastomer, a styrene-ethylene/propylene-styrene thermoplastic elastomer, a styrene-ethylene/propylene thermoplastic elastomer, a hydrogenated styrene butadiene rubber, and a mixture thereof.
  • a preferred styrenic block copolymer based material contains from about 1 wt% to about 70 wt% of polystyrene, more preferably from about 10 wt% to about 50 wt% of polystyrene.
  • the elastomeric material 124 is a porous, macroscopically-expanded, three-dimensional elastomeric web 172 as shown in Fig. 4.
  • the web 172 has a continuous first surface 174 and a discontinuous second surface 176 opposing to the first surface 174.
  • the elastomeric web 172 preferably comprises a formed film interconnecting member 186 including at least two polymeric layers 178 and 182.
  • the first layer 178 is substantially elastic and the second layer 182 is substantially less elastic than the first layer 178.
  • At least one of the two polymeric layers 178 and 182 is formed from a polystyrene thermoplastic elastomer.
  • the elastomeric web 172 exhibits a multiplicity of primary apertures 184 in the first surface 174 of the web 172.
  • the primary apertures 184 are defined in the plane of the first surface 174 by a continuous network of the interconnecting member 186.
  • the interconnecting member 186 exhibits an upwardly concave-shaped cross-section along its length.
  • the interconnecting member 186 also forms secondary apertures 188 in the plane of the second surface 176 of the web 172.
  • the apertures 184 and 188 may take any shape.
  • a preferred elastomeric web is disclosed in U.S. Patent application serial number 08/816,106, filed on March 14, 1997.
  • a preferred porous elastomeric material for the elastomeric layer 124 is available from Tredegar Film Products under the designation X-25007.
  • the elastomeric layer 124 is in the form of a scrim 130 as shown in Fig. 1.
  • the elastomeric scrim 130 comprises a plurality of first strands 125 which intersect or cross (with or without bonding to) a plurality of second strands 127 at nodes 128 at a predetermined angle ⁇ , thereby forming a net-like open structure having a plurality of apertures 132.
  • Each aperture 132 is defined by at least two adjacent first strands 125 and at least two adjacent second strands 127 such that apertures 132 are substantially rectangular (preferably square) in shape.
  • Other aperture configurations, such as parallelograms or circular arc segments, can also be provided. Such configurations could be useful for providing non-linear elastic structural directions.
  • first strands 125 are substantially straight and substantially parallel to one another; and, more preferably, the second strands 127 are also substantially straight and substantially parallel to one another. More preferably, first strands 125 intersect second strands 127 at nodes 128 at a predetermined angle ⁇ of about 90 degrees.
  • Each node 128 is an overlaid node, wherein first strands 125 and second strands 127 are preferably joined or bonded (although it is contemplated that joining or bonding may not be required) at the point of intersection with the strands still individually distinguishable at the nodes 128.
  • other node configurations such as merged or a combination of merged and overlaid would be equally suitable.
  • first and second strands 125 and 127 be substantially straight, parallel, and intersect at an angle ⁇ of about 90 degrees, it is noted that first and second strands 125 and 127 can intersect at other angles ⁇ , and that first strands 125 and/or second strands 127 can be aligned in circular, elliptical or otherwise nonlinear patterns relative to one another.
  • first strands 125 and second strands 127 have a substantially circular cross-sectional shape prior to incorporation into elastic laminate 70 (as shown in Fig. 1), the first and second strands 125 and 127 can also have other cross-sectional shapes such as elliptical, square, triangular or combinations thereof.
  • the material for the first strands 125 is chosen so that the first strands 125 can maintain the second strands 127 in relative alignment prior to forming elastic laminate 70. It is also desirable that the materials for the first and second strands 125 and 127 are capable of being deformed (or initially formed) into predetermined shapes upon application of a predetermined pressure or a pressure in combination with a heat flux prior to forming elastic laminate 70. These deformed shapes (e.g., elliptical second strands, substantially flat first strands and the like) can provide an elastic laminate 70 which can be comfortably worn about the body without irritation or other discomfort.
  • the first and second strands 125 and 127 are formed from an identical elastomeric material.
  • the first and second strands 125 and 127 are formed from an identical polystyrene thermoplastic elastomer which is selected from the group consisting of a styrene-butadiene- styrene thermoplastic elastomer, a styrene-isopren-styrene thermoplastic elastomer, a styrene-ethylene/butylene-styrene thermoplastic elastomer, a styrene- ethylene/propylene-styrene thermoplastic elastomer, a styrene-ethylene/propylene thermoplastic elastomer, a hydrogenated styrene butadiene rubber or an unsaturated styrene butadiene rubber, and a mixture thereof.
  • a preferred elastomeric scrim 124 which containes a styrene-butadiene-styrene thermoplastic elastomer is manufactured by the Conwed Plastics Company (Minneapolis, Minn., U.S.A.) under the designation X02514. This material has about 12 elastic strands per inch (about 5 strands/cm) in the structural direction B (i.e., the first strands 125) and about 7 elastic strands per inch (about 3 strands/cm) in the structural direction D (i.e., the second strands 127) before lamination.
  • first and second strands 125 and 127 are formed from two different material.
  • one of the first and second strands 125 and 127 is formed from one of the above described polystyrene thermoplastic elastomer, while the other of the first and second strands 125 and 127 is formed from material(s) other than the above described polystyrene thermoplastic elastomer.
  • Such other material(s) may be either elastic or non-elastic, and selected from suitable materials known in the art.
  • the first nonwoven layer 122 of the present invention can be joined to the elastomeric layer 124 by any means known in the art.
  • the first nonwoven layer 122 is joined to the first surface 150 of the elastomeric layer 124 by an adhesive means such as those well known in the art.
  • the first nonwoven layer 122 may be secured to the first surface 150 of the elastomeric layer 124 by a uniform continuous layer of adhesive, a patterned layer of adhesive, or an array of separate lines or spots of adhesive.
  • Fig. 2 shows a simplified fragmentary enlarged side view looking into the structural direction B of the elastic laminate 70.
  • the elastic laminate 70 includes the second nonwoven layer 126.
  • a first adhesive 170 is applied to the inner surface 142 of the first nonwoven layer 122 in positions that correspond to each of the outer edges 180 of the laminate structure 120.
  • the first adhesive 170 may alternatively or additionally be applied to the inner surface 146 of the second nonwoven layer 126.
  • the description and Figs, refer to application to the first nonwoven layer 122 only.
  • the first adhesive 170 is applied as a plurality of beads 168, as shown in Fig. 2.
  • the first adhesive 170 is a flexible adhesive with an amorphous and crystallizing component. Such a preferred adhesive is made by Ato Findley Inc., Wl, U.S.A., under the designation H9224.
  • the side anchoring is preferably performed by side gluing with adhesive beads to anchor the elastomeric layer 124 between the nonwoven layers 122 and 126 as a part of the lamination process.
  • side anchoring may be performed by sewing, heat sealing, ultrasonic bonding, needle punching, alternative gluing processes, or by any other means known to those skilled in the art.
  • the elastic laminate 70 includes a second adhesive 164.
  • the second adhesive 164 is an elastomeric adhesive.
  • the second adhesive 164 is preferably applied to the first surface 150 of the elastomeric layer 130.
  • the second adhesive 164 is preferably applied in a spiral spray pattern 166, thereby forming bond points 167b that are more discrete than would be formed by a linear spray application. Without being bound by theory, it is believed that most of the second adhesive 164 is sprayed in the structural direction D (Fig. 1).
  • the layer of second adhesive 164 is directly applied onto the first surface 150 of the elastomeric layer 124 in the lamination process.
  • a third adhesive 160 may also preferably be applied to the inner surface 146 of the second nonwoven layer 126.
  • the third adhesive 160 is an elastomeric adhesive.
  • the third adhesive 160 is preferably applied in a spiral spray pattern 162, thereby forming bond points 167a that are more discrete than would be formed by a linear spray application.
  • the layer of third adhesive 160 is directly applied onto the second surface 152 of the elastomeric layer 124 in the lamination process.
  • second and third adhesives 160 and 164 are the same elastomeric adhesive.
  • a preferred adhesive for use in the second and third adhesive spiral sprays 162 and 166 is made by Ato Findley Inc., Wl, U.S.A., under the designation H2120.
  • the add-on level for each of the second and third spiral sprays 162 and 166 is about 4 mg/inch (about 1.6 mg/cm) to about 12 mg/inch (about 4.8 mg/cm), more preferably about 8 mg/inch (about 3.2 mg/cm).
  • the first nonwoven layer 122 is bonded to the first surface 150 of the elastomeric layer 124 by forming a heat/pressure bond between the first nonwoven layer 122 and the elastomeric layer 124.
  • heat/pressure bond is either a physical or chemical bond formed by an application of appropriate heat and pressure to two different members so that the two members can have a portion which has an increased peel strength by the formation of the bond.
  • peel strength refers to the amount of force required to separate the two members from each other. Higher peel strengths typically equate to less chance of de-lamination of the elastic laminates in use of products.
  • any pressure can be applied to the first nonwoven layer 122 and the elastomeric layer 124 at a certain temperature as long as it does not substantially damage the physical and/or chemical properties of the resulting elastic laminate.
  • Fig. 3 is a partial perspective view of an elastic laminate 70 of yet another embodiment, wherein a portion of the first nonwoven layer 122 has been removed to show the heat/pressure bond structure.
  • the elastomeric scrim 130 which is formed by the first and second strands 125 and 127 is used as an example for the elastomeric layer 124.
  • the first nonwoven layer 122 is bonded to the first surface 150 of the elastomeric layer 124 by forming a heat/pressure bond between the first nonwoven layer 122 and the elastomeric layer 124.
  • the elastic laminate further includes a second nonwoven layer (not shown in Fig. 3) which is bonded to the second surface 152 of the elastomeric layer 124 by forming another heat/pressure bond therebetween.
  • the heat/pressure bond is formed by softening only the material of the elastomeric layer 124 (i.e., without melting the component fibers of the first nonwoven layer 122).
  • This heat/pressure bond is preferably formed by application of a bonding temperature which is lower than the melting point of the material of the first nonwoven layer 122. This generally results in a decrease in the viscosity of the material which may or may not involve a "melting" of the material. As a result, the component materials of the elastomeric layer 124 are softened to form the heat/pressure bond.
  • the elastomeric layer 124 is formed from a polystyrene thermoplastic elastomer including a polystyrene segment, a bonding temperature which is higher than the glass transition temperature of the polystyrene segment is applied for forming the heat/pressure bond.
  • Fig. 5 shows one preferred example of a lamination device for forming the elastic laminate 70 shown in Fig. 3.
  • the lamination device 800 includes a first pressure plate 801 having a first surface 803, and a second plate 802 having a second surface 804.
  • the second pressure plate 802 is fixed, while the first pressure plate 801 is movable to apply a pressure P to the first nonwoven layer 122 and the elastomeric layer 124 in cooperation with the second pressure plate 802.
  • the first and second surfaces 803 and 804 are substantially plane and are substantially parallel each other.
  • the first nonwoven layer 122 is juxtaposed with the elastomeric layer 124 such that the first nonwoven layer 122 is immediately adjacent the elastomeric layer 124.
  • the juxtaposed two layers 122 and 124 are manually supplied to the lamination device 800.
  • a preferred lamination device 800 is available from Toyo Tester Industry Co., Ltd., Osaka, Japan, under a trade name "Heat Sealer".
  • the first surface 803 is heated to a temperature T1 , while the second surface 804 is heated to a temperature T2.
  • the temperature T1 is from about 80°C to about 160°C, more preferably from about 100°C to about 130°C.
  • the temperature T2 is preferably from about 30°C to about 60°C, more preferably from about 45°C to about 55°C.
  • the pressure P is preferably from about 6 kg/cm 2 to about 15 kg/cm 2 , more preferably from about 9 kg/cm' 1 to about 11 kg/cm .
  • the time period of the application of the pressure P is preferably from about 1 second to about 20 seconds, more preferably from about 5 seconds to about 15 seconds.
  • the application of pressure P can be performed two (or more) times to increase the peel strength of the resulting laminate 70.
  • the elastomeric layer 124 is bonded to the first nonwoven layer 122 through a heat/pressure bond which is formed by softening the material of the elastomeric layer 124 (e.g., the polystyrene thermoplastic elastomer).
  • the elastic laminate 70 of the present invention can be incorporated into a variety of products wherein it is desired to provide an elastic stretchability in at least one structural direction either partially or entirely.
  • Examples of such products include disposable products, including sweat bands, bandages, body wraps, and disposable garments including disposable diapers and incontinence products.
  • the following method is preferably used to determine the Fiber Orientation Ratio (FOR) of nonwoven material.
  • a sample nonwoven fabric (or layer) is placed on a specimen stub.
  • the sample nonwoven fabric is fixed on the specimen stub at a flat condition so that the primary fiber direction (to be defined hereinafter) of the sample nonwoven fabric can be roughly aligned with the longitudinal direction of the photograph to be taken.
  • a scanning electron microscope (SEM) is used to take a photograph at 50X magnification.
  • a preferred SEM is available from Japan Electron Optics Laboratory (JEOL) Ltd., Tokyo, Japan, under Code No. JSM-5310
  • a preferred digitizer is available from Graphtec Co., Ltd., Tokyo, Japan, under Code No. KD9600.
  • a photograph is placed on the digitizer.
  • a square area 500 ⁇ m x 500 ⁇ m is chosen at will in the photograph on the digitizer.
  • the both ends of every component fiber which can be seen in the square area are manually identified by an operator and the coordinates thereof are detected and recorded by the digitizer.
  • This work is conducted on three different square areas (each having 500 ⁇ m x 500 ⁇ m) which are chosen at will in the photograph to obtain coordinate data on the all fibers in the three different square areas.
  • the orientation angle of each fiber is calculated based on the coordinate data.
  • the primary fiber direction of the sample nonwoven fabric is determined by the average orientation angle, which is an average value of the all orientation angle data obtained from the three different square areas.
  • the Fiber Orientation Ratio within about ⁇ 10 degrees is determined by the following calculation:
  • FOR10 NF10 / TNF x 100 (2) wherein, NF10: the number of fibers which have orientation angles within about ⁇ 10 degrees from the primary fiber direction; and TNF: the total number of fibers measured within the three different square areas.
  • Fiber Orientation Ratio within about ⁇ 20 degrees is determined by the following calculation:
  • NF20 the number of fibers which have orientation angles within about ⁇ 20 degrees from the primary fiber direction. 2. Test Method for Tensile Strength
  • the following method is preferably used to measure the tensile strength of materials.
  • a tensile tester is prepared.
  • the tensile tester has an upper jaw and a lower jaw which is located below the upper jaw.
  • the upper jaw is movable and is connected to an extension force measuring means.
  • the lower jaw is fixed in the tester.
  • a test specimen i.e., a nonwoven fabric to be measured
  • a test specimen which has about 2.5 cm (about 1 inch) in width and about 10.2 cm (about 4 inches) in length is prepared and clamped with the upper jaw and the lower jaw so that the effective specimen length (L) (i.e., gauge length) is about 5.1 cm (about 2 inch).
  • An extension force is continuously applied to the test specimen through the upper jaw at a cross-head speed of about 50 cm (about 20 inches) per minute, until the test specimen is physically broken.
  • the applied extension force is recorded by a recorder (e.g., a computer system).
  • the tensile strength at the breaking point is determined at the maximum tensile strength value.
  • a tensile tester suitable for use is available from Instron Corporation (100 Royall Street, Canton, MA02021 , U.S.A.) as Code No. Instron 5564.

Abstract

The present invention is directed to an elastic laminate which is elastically extensible in at least one direction. The elastic laminate includes an elastomeric material having a first surface and a second surface opposing the first surface; and a first nonwoven layer joined to the first surface of the elastomeric material. The first nonwoven layer is formed from component fibers having a primary fiber direction. The first nonwoven layer has a Fiber Orientation Ratio within about ±20 degrees from a primary fiber drection of at least about 65 %.

Description

ELASTIC LAMINATE INCLUDING NONWOVEN LAYER FORMED FROM HIGHLY ORIENTED COMPONENT FIBERS
FIELD The present invention relates to elastic laminates. More specifically, the present invention relates to elastic laminates which includes a nonwoven layer formed from highly oriented component fibers.
BACKGROUND Elastic laminates have previously been used in a variety of disposable products, including sweat bands, bandages, body wraps, and disposable garments including disposable diapers and incontinence devices. Herein, "elastic laminate" refers to an elastically stretchable two or more layered materials including at least one elastically stretchable single layer material. It is generally expected that these products provide good fit to the body and/or skin of the user by using suitable elastic members during the entire use period of products.
A "zero strain" stretch laminate is one type of elastic laminate which is preferably used for such disposable products. For example, methods for making "zero strain" stretch laminate webs are disclosed in U.S. Patent No. 5,167,897 issued to Weber et al. on December 1 , 1992; U.S. Patent No. 5,156,793 issued to Buell et al. on October 20, 1990; and U.S. Patent No. 5,143,679 issued to Weber et al. on September 1, 1992. In a manufacturing process for such "zero strain" stretch laminate, the elastomeric material is operatively joined to at least one component material in a substantially untensioned (zero strain) condition. At least a portion of the resultant composite stretch laminate is then subjected to mechanical stretching sufficient to permanently elongate the non-elastic components. The composite stretch laminate is then allowed to return to its substantially untensioned condition. Thus, the elastic laminate is formed into a "zero strain" stretch laminate. Herein, "zero strain" stretch laminate refers to a laminate comprised of at least two plies of material which are secured to one another along at least a portion of their coextensive surfaces while in a substantially untensioned ("zero strain") condition; one of the plies comprising a material which is stretchable and elastomeric (i.e., will return substantially to its untensioned dimensions after an applied tensile force has been released) and a second ply which is elongatable (but not necessarily elastomeric) so that upon stretching the second ply will be, at least to a degree, permanently elongated so that upon release of the applied tensile forces, it will not fully return to its original undeformed configuration. The resulting stretch laminate is thereby rendered elastically extensible, at least up to the point of initial stretching, in the direction of initial stretching. As is noted in the above, the manufacturing process of such "zero strain" stretch laminate includes the step of subjecting the non-elastic composite stretch laminate to mechanical stretching sufficient to permanently elongate the non-elastic components. This step is additional to normal elastic lamination processes and gives limitations to materials to be used in the elastic laminate. For example, the elastomeric material and other composite material(s) used in the elastic laminate need to have enough physical strength or toughness since those materials tend to be mechanically damaged by the process. If the elastomeric material, for example, does not have enough strength or toughness, the elastomeric material tends to be easily shred or torn by the stress which is applied to the elastomeric material during the mechanical stretching in the manufacturing process and during the use of products.
Based on the foregoing, there is a need for an elastic laminate that does not have such limitations to the elastomeric material to be used therein.
SUMMARY
The present invention is directed to an elastic laminate which is elastically extensible in at least one direction. The elastic laminate includes an elastomeric material having a first surface and a second surface opposing the first surface; and a first nonwoven layer joined to the first surface of the elastomeric material. The first nonwoven layer is formed from component fibers having a primary fiber direction. The first nonwoven layer has a Fiber Orientation Ratio within about ±20 degrees from the primary fiber direction of at least about 65%.
These and other features, aspects, and advantages of the present invention will become evident to those skilled in the art from reading of the present disclosure. BRIEF DESCRIPTION OF THE DRAWINGS
While the specification concludes with claims particularly pointing out and distinctly claiming the invention, it is believed that the invention will be better understood from the following description of preferred embodiments which is taken in conjunction with the accompanying drawings and which like designations are used to designate substantially identical elements, and in which:
Fig. 1 is a fragmentary enlarged perspective view of an elastic laminate of one preferred embodiment of the present invention, prior to being formed into the elastic laminate;
Fig. 2 is a simplified cross-sectional view of an elastic laminate of another preferred embodiment;
Fig. 3 is a enlarged perspective view of an elastic laminate of yet another embodiment of the present invention, wherein a portion of the nonwoven layer has been removed to show the bonded structure;
Fig. 4 is a fragmentary enlarged perspective view of an alternative embodiment of the elastomeric material; and
Fig. 5 is a schematic representation of a lamination device for forming the elastic laminate shown in Fig. 3.
DETAILED DESCRIPTION All cited references are incorporated herein by reference in their entireties. Citation of any reference is not an admission regarding any determination as to its availability as prior art to the claimed invention. Herein, "comprise", "include" and "have" mean that other element(s) and step(s) which do not affect the end result can be added. These terms encompass the terms "consisting of and "consisting essentially of. Herein, "gf stands for gram force.
Herein, "joined" or "joining" encompasses configurations whereby an element is directly secured to another by affixing the element directly to the other element, and configurations whereby the element is indirectly secured to the other element by affixing the element to intermediate member(s) which in turn are affixed to the other element. Herein, "layer" does not necessarily limit the element to a single stratum of material in that a layer may actually comprise laminates or combinations of sheets or webs of materials.
Herein, "nonwoven" may include any material which has been formed without the use of textile weaving processes which produce a structure of individual fibers which are interwoven in an identifiable manner. Methods of making suitable nonwovens includes a spunbonded nonwoven process, a meltblown nonwoven process, a carded nonwoven process, or the like.
A. Laminate Structure
The present invention relates to an elastic laminate which does not have a limitation(s) to an elastomeric material to be used therein. This and other advantages of the invention are described in more detail herein.
Fig. 1 is a fragmentary enlarged perspective view of an elastic laminate 70 of one preferred embodiment, prior to being formed into the elastic laminate. (Preferred embodiments of the elastic laminate 70 after the formation are shown in Figs. 2 and 3.) Referring to Fig. 1 , the elastic laminate 70 of the present invention includes an elastomeric layer 124 having a first surface 150 and a second surface 152 opposing the first surface 150; and a first nonwoven layer 122 which is joined to the first surface 150 of the elastomeric layer 124. In a preferred embodiment, the first surface 150 and second surface 152 of the elastomeric layer 124 are substantially parallel with the plane of the first nonwoven layer 122. The first nonwoven layer 122 has an inner surface (or a first surface) 142 and an outer surface (or a second surface) 144. The inner surface 142 of the first nonwoven layer 122 is the surface that is positioned facing the elastomeric layer 124.
In a preferred embodiment, the elastic laminate 70 further comprises a second nonwoven layer 126 joined to the second surface 152 of the elastic material 70. The second nonwoven layer 126 also has an inner surface 146 and an outer surface 148. The inner surface 146 of the second nonwoven layer 126 is the surface that is positioned facing the elastomeric layer 124. The second surface 152 of the elastomeric layer 124 is substantially parallel with the plane of the second nonwoven layer 126. In a preferred embodiment, the nonwoven layer 126 is formed by an identical nonwoven material with that is employed in the first nonwoven layer 122. Alternatively, the nonwoven layer 126 may be formed by a different material from that is employed in the first nonwoven layer 122. The elastic laminate 70 of the present invention is elastically extensible in at least one direction (first direction). For example, the elastic laminate 70 shown in Fig. 1 is elastically extensible in the structural direction D. Herein, "structural direction" (e.g., D and B) is intended to mean a direction which extends substantially along and parallel to the plane of the first nonwoven layer 122. In a preferred embodiment, the elastic laminate 70 is also elastically extensible in the second direction which is perpendicular to the first direction. For example, the elastic laminate 70 shown in Fig. 1 is also elastically extensible in the structural direction B.
B. Nonwoven Layers
The first nonwoven layer 122 of the present invention is formed from component fibers which are joined together. The component fibers have a primary fiber direction. The first nonwoven layer 122 has a Fiber Orientation Ratio within about ±20 degrees from the primary fiber direction (FOR20) of at least about 65%; more oreferably at least about 75%; more preferably still at least about 85%. In a more preferred embodiment, the first nonwoven layer 122 additionally has a Fiber Orientation Ratio within about ±10 degrees from the primary fiber direction (FOR10) of at least about 45%; more preferably at least about 60%; more preferably still at least about 70%.
"FOR#" (e.g., FOR10) indicates the ratio of the number of the component fibers whose directions are within about ±# degrees, (e.g., ±10 degrees) from the primary fiber direction to the total number of component fibers. Herein, "primary fiber direction" refers to an average direction of component fibers in the nonwoven layer. One preferred method for measuring the Fiber Orientation Ratio of nonwoven layers is explained in more detail below.
In a preferred embodiment, the first nonwoven layer 122 has a Tensile Strength Ratio (TSR) of at least about 15, more preferably at least about 60. The TSR is defined by the following calculation: TSR = TS1 / TS2 (1) wherein,
TS1 (gf/inch): a tensile strength (TS) at the breaking point in the primary fiber direction; and
TS2 (gf/inch): a tensile strength (TS) at the breaking point in the perpendicular direction which is perpendicular to the primary fiber direction. Tensile Strength (ST) is measured as the maximum tensile strength value recorded while the first nonwoven layer 122 is stretched at a rate of about 20 inches/min (about 50 cm/min) to its breaking point. The tensile strength of the first nonwoven layer 122 is measured before the first nonwoven layer 122 is joined to the elastomeric layer 124.
In a preferred embodiment, the first nonwoven layer 122 has a tensile strength of less than about 200 gf/inch (about 80 gf/cm) at 30% elongation to the direction which is perpendicular to the primary fiber direction; more preferably less than about 100 gf/inch (about 40 gf/cm), more preferably still less than about 50 gf/inch (about 20 gf/cm).
The first nonwoven layer 122 may be manufactured from a wide range of component fibers including, e.g., natural fibers (e.g., wool and cotton fibers), synthetic fibers (e.g., polyolefin, polyester, nylon, and rayon fibers), or a mixture of natural fibers and/or synthetic fibers. For ease of manufacture and cost efficiency, the first nonwoven layer 122 is preferably formed from synthetic continuous fibers. More preferably, such synthetic continuous fibers are formed from a polyolefin (e.g., polyethylene and polypropylene) or a polyester. Preferred polyester material includes a polyethylene terephthalate, a polybutylene terephthalate and a polypropylene terephthalate, or mixtures thereof. In a preferred embodiment, the first nonwoven layer 122 additionally includes component fibers formed from the other materials (i.e., non-polyester materials) such as polyolefin and nylon.
In a preferred embodiment, the individual component fibers are formed from a single type of material which is selected from the above materials (i.e., the individual fiber is not made from polyolefin and nylon). Preferably, the component fibers are formed from a polyester, more preferably a polyethylene terepthalate, or one of its relatives which has an average molecular weight from about 5,000 to about 60,000, preferably from about 10,000 to about 40,000, more preferably from about 14,000 to about 23,000. Alternatively, the component fibers may be formed from a mixture of two (or more) materials which are selected from the above materials.
In one embodiment, the component fiber has a bi-component fiber structure formed from two distinct materials of a polyester and a polyolefin. In an alternative embodiment, the component fiber has a bi-component fiber structure formed from two distinct molecular weight materials of one identical material, for example, a polyester. Preferred bi-component fiber structures may include a side-by-side bi- component fiber structure and a sheath-core bi-component fiber structure known in the art. In one embodiment, the component fiber has a bi-component fiber structure having a core of polyolefin and a sheath of a polyester.
In a preferred embodiment, the first nonwoven layer 122 has a basis weight of less than about 60 g/rτr, and comprises fibers having a fiber diameter of less than about 50 μm. More preferably, for products such as disposable garment and the like, the first nonwoven layer 122 has a basis weight of from about 3 g/m^ to about 50 g/m^, more preferably from about 10 g/m^ to about 25 g/m^, and a fiber diameter of from about 1 μm to about 30 μm, more preferably from about 3 μm to about 20 μm.
The component fibers may be joined together by adhesives, thermal bonding, water-jetting, needling/felting, or other methods known in the art to form nonwoven fabrics. In a preferred embodiment, the first nonwoven layer 122 is formed from a nonwoven manufacturing process handling continuous component fibers or filaments known in the art. Preferred manufacturing process are described in, for example, EP 0843036A1 (Kurihara et al.) published on May 20, 1998; U.S. Patent No. 5,312,500, entitled "Non-Woven Fabric and Method and Apparatus for Making The Same", issued to Kurihara et al. on May 17, 1994; Japanese Laid-Open Patent Publication (Kokai) No. H2-269859 published on November 5, 1990; and Japanese Patent Publication (Kokoku) No. S60-25541 published on June 19, 1985.
Preferred nonwoven fabrics which are suitably applicable to the first nonwoven layer 122 are available from Nippon Petrochemicals Co., Ltd., Tokyo, Japan, under Code Nos. MBE8202-3-2; MBE8202-3-1 ; MBE7711-2; MBE6515-10; and MBE7922-1 which have the following properties.
Table
Figure imgf000009_0001
C. Elastomeric Material
The elastomeric layer 124 may be formed in a wide variety of sizes, forms and shapes. In a preferred embodiment, the elastomeric layer 124 is in the form of a continuous plane layer such as shown in, for example, Fig. 1. Preferred forms of a continuous plane layer include a scrim, a perforated (or apertures formed) film, an elastomeric woven or nonwoven, and the like. Preferably, the elastomeric layer 124 has a thickness of from about 0.05 mm to about 1 mm (about 0.002 inch - about 0.039 inch). The continuous plane layer may take any shape which can be suitably provided in products. Preferred shapes of a continuous plane layer include a quadrilateral including a rectangle and a square, a trapezoid, and the other polygons. In an alternative embodiment, the elastomeric layer 124 is in the form of discrete strands (or strings) which are not connected each other.
The elastomeric material of the present invention may include all suitable elastic materials known in the art. Elastomeric materials suitable for use herein include synthetic or natural rubber materials known in the art. Preferred elastomeric materials include the diblock and triblock copolymers based on polystyrene and unsaturated or fully hydrogenerated rubber bolcks, and their blends with other polymers such as polyolefin polymers. In a preferred embodiment, the elastomeric material is made from a polystyrene thermoplastic elastomer including styrene block copolymer based materials. A preferred styrenic block copolymer based material contains from about 1 wt% to about 70 wt% of polystyrene, more preferably from about 10 wt% to about 50 wt% of polystyrene. Preferably, the polystyrene thermoplastic elastomer is selected from the group consisting of a styrene-butadiene-styrene thermoplastic elastomer, a styrene-isopren-styrene thermoplastic elastomer, a styrene-ethylene/butylene- styrene thermoplastic elastomer, a styrene-ethylene/propylene-styrene thermoplastic elastomer, a styrene-ethylene/propylene thermoplastic elastomer, a hydrogenated styrene butadiene rubber, and a mixture thereof.
A preferred styrenic block copolymer based material contains from about 1 wt% to about 70 wt% of polystyrene, more preferably from about 10 wt% to about 50 wt% of polystyrene.
In an alternative preferred embodiment, the elastomeric material 124 is a porous, macroscopically-expanded, three-dimensional elastomeric web 172 as shown in Fig. 4. The web 172 has a continuous first surface 174 and a discontinuous second surface 176 opposing to the first surface 174. The elastomeric web 172 preferably comprises a formed film interconnecting member 186 including at least two polymeric layers 178 and 182. The first layer 178 is substantially elastic and the second layer 182 is substantially less elastic than the first layer 178. At least one of the two polymeric layers 178 and 182 is formed from a polystyrene thermoplastic elastomer. The elastomeric web 172 exhibits a multiplicity of primary apertures 184 in the first surface 174 of the web 172. The primary apertures 184 are defined in the plane of the first surface 174 by a continuous network of the interconnecting member 186. The interconnecting member 186 exhibits an upwardly concave-shaped cross-section along its length. The interconnecting member 186 also forms secondary apertures 188 in the plane of the second surface 176 of the web 172. The apertures 184 and 188 may take any shape. A preferred elastomeric web is disclosed in U.S. Patent application serial number 08/816,106, filed on March 14, 1997. A preferred porous elastomeric material for the elastomeric layer 124 is available from Tredegar Film Products under the designation X-25007.
In one preferred embodiment, the elastomeric layer 124 is in the form of a scrim 130 as shown in Fig. 1. The elastomeric scrim 130 comprises a plurality of first strands 125 which intersect or cross (with or without bonding to) a plurality of second strands 127 at nodes 128 at a predetermined angle α, thereby forming a net-like open structure having a plurality of apertures 132. Each aperture 132 is defined by at least two adjacent first strands 125 and at least two adjacent second strands 127 such that apertures 132 are substantially rectangular (preferably square) in shape. Other aperture configurations, such as parallelograms or circular arc segments, can also be provided. Such configurations could be useful for providing non-linear elastic structural directions. Preferably, the first strands 125 are substantially straight and substantially parallel to one another; and, more preferably, the second strands 127 are also substantially straight and substantially parallel to one another. More preferably, first strands 125 intersect second strands 127 at nodes 128 at a predetermined angle α of about 90 degrees. Each node 128 is an overlaid node, wherein first strands 125 and second strands 127 are preferably joined or bonded (although it is contemplated that joining or bonding may not be required) at the point of intersection with the strands still individually distinguishable at the nodes 128. However, it is believed that other node configurations such as merged or a combination of merged and overlaid would be equally suitable.
Although it is preferred that first and second strands 125 and 127 be substantially straight, parallel, and intersect at an angle α of about 90 degrees, it is noted that first and second strands 125 and 127 can intersect at other angles α, and that first strands 125 and/or second strands 127 can be aligned in circular, elliptical or otherwise nonlinear patterns relative to one another. Although for ease of manufacture it is contemplated that first strands 125 and second strands 127 have a substantially circular cross-sectional shape prior to incorporation into elastic laminate 70 (as shown in Fig. 1), the first and second strands 125 and 127 can also have other cross-sectional shapes such as elliptical, square, triangular or combinations thereof.
Preferably, the material for the first strands 125 is chosen so that the first strands 125 can maintain the second strands 127 in relative alignment prior to forming elastic laminate 70. It is also desirable that the materials for the first and second strands 125 and 127 are capable of being deformed (or initially formed) into predetermined shapes upon application of a predetermined pressure or a pressure in combination with a heat flux prior to forming elastic laminate 70. These deformed shapes (e.g., elliptical second strands, substantially flat first strands and the like) can provide an elastic laminate 70 which can be comfortably worn about the body without irritation or other discomfort.
In a preferred embodiment, the first and second strands 125 and 127 are formed from an identical elastomeric material. For example, the first and second strands 125 and 127 are formed from an identical polystyrene thermoplastic elastomer which is selected from the group consisting of a styrene-butadiene- styrene thermoplastic elastomer, a styrene-isopren-styrene thermoplastic elastomer, a styrene-ethylene/butylene-styrene thermoplastic elastomer, a styrene- ethylene/propylene-styrene thermoplastic elastomer, a styrene-ethylene/propylene thermoplastic elastomer, a hydrogenated styrene butadiene rubber or an unsaturated styrene butadiene rubber, and a mixture thereof. A preferred elastomeric scrim 124 which containes a styrene-butadiene-styrene thermoplastic elastomer is manufactured by the Conwed Plastics Company (Minneapolis, Minn., U.S.A.) under the designation X02514. This material has about 12 elastic strands per inch (about 5 strands/cm) in the structural direction B (i.e., the first strands 125) and about 7 elastic strands per inch (about 3 strands/cm) in the structural direction D (i.e., the second strands 127) before lamination.
Alternatively, the first and second strands 125 and 127 are formed from two different material. For example, one of the first and second strands 125 and 127 is formed from one of the above described polystyrene thermoplastic elastomer, while the other of the first and second strands 125 and 127 is formed from material(s) other than the above described polystyrene thermoplastic elastomer. Such other material(s) may be either elastic or non-elastic, and selected from suitable materials known in the art.
D. Joining Nonwoven to Elastomeric Material
The first nonwoven layer 122 of the present invention can be joined to the elastomeric layer 124 by any means known in the art. In a preferred embodiment, the first nonwoven layer 122 is joined to the first surface 150 of the elastomeric layer 124 by an adhesive means such as those well known in the art. For example, the first nonwoven layer 122 may be secured to the first surface 150 of the elastomeric layer 124 by a uniform continuous layer of adhesive, a patterned layer of adhesive, or an array of separate lines or spots of adhesive. One preferred laminate structure formed by an adhesive means is shown in Fig. 2. Fig. 2 shows a simplified fragmentary enlarged side view looking into the structural direction B of the elastic laminate 70. In this embodiment, the elastic laminate 70 includes the second nonwoven layer 126. Referring to Fig. 2, a first adhesive 170 is applied to the inner surface 142 of the first nonwoven layer 122 in positions that correspond to each of the outer edges 180 of the laminate structure 120. The first adhesive 170 may alternatively or additionally be applied to the inner surface 146 of the second nonwoven layer 126. For ease of illustration, the description and Figs, refer to application to the first nonwoven layer 122 only.
This pattern creates side anchor zones A, which substantially eliminate the delamination and creep associated with previously known laminates and which allows the elastic laminate 70 to experience higher strains without creeping or delaminating. It has also been found that confining the first adhesive 170 to the edge areas 180 of the laminate structure 120 avoids impeding the extensibility of the elastic laminate 70 and also avoids tears in the nonwoven layers 122 and 126. Preferably, the first adhesive 170 is applied as a plurality of beads 168, as shown in Fig. 2. Preferably, the first adhesive 170 is a flexible adhesive with an amorphous and crystallizing component. Such a preferred adhesive is made by Ato Findley Inc., Wl, U.S.A., under the designation H9224.
The side anchoring is preferably performed by side gluing with adhesive beads to anchor the elastomeric layer 124 between the nonwoven layers 122 and 126 as a part of the lamination process. Alternatively, side anchoring may be performed by sewing, heat sealing, ultrasonic bonding, needle punching, alternative gluing processes, or by any other means known to those skilled in the art.
More preferably, the elastic laminate 70 includes a second adhesive 164. Preferably, the second adhesive 164 is an elastomeric adhesive. The second adhesive 164 is preferably applied to the first surface 150 of the elastomeric layer 130. The second adhesive 164 is preferably applied in a spiral spray pattern 166, thereby forming bond points 167b that are more discrete than would be formed by a linear spray application. Without being bound by theory, it is believed that most of the second adhesive 164 is sprayed in the structural direction D (Fig. 1). Preferably, the layer of second adhesive 164 is directly applied onto the first surface 150 of the elastomeric layer 124 in the lamination process.
A third adhesive 160 may also preferably be applied to the inner surface 146 of the second nonwoven layer 126. Preferably, the third adhesive 160 is an elastomeric adhesive. In a manner similar to that described with reference to the second spiral adhesive application 166, the third adhesive 160 is preferably applied in a spiral spray pattern 162, thereby forming bond points 167a that are more discrete than would be formed by a linear spray application. Preferably, the layer of third adhesive 160 is directly applied onto the second surface 152 of the elastomeric layer 124 in the lamination process.
Preferably, second and third adhesives 160 and 164 are the same elastomeric adhesive. A preferred adhesive for use in the second and third adhesive spiral sprays 162 and 166 is made by Ato Findley Inc., Wl, U.S.A., under the designation H2120. Preferably, the add-on level for each of the second and third spiral sprays 162 and 166 is about 4 mg/inch (about 1.6 mg/cm) to about 12 mg/inch (about 4.8 mg/cm), more preferably about 8 mg/inch (about 3.2 mg/cm).
In an alternative preferred embodiment, the first nonwoven layer 122 is bonded to the first surface 150 of the elastomeric layer 124 by forming a heat/pressure bond between the first nonwoven layer 122 and the elastomeric layer 124. Herein, "heat/pressure bond" is either a physical or chemical bond formed by an application of appropriate heat and pressure to two different members so that the two members can have a portion which has an increased peel strength by the formation of the bond. Herein, "peel strength" refers to the amount of force required to separate the two members from each other. Higher peel strengths typically equate to less chance of de-lamination of the elastic laminates in use of products. To form such heat/pressure bond(s) between the first nonwoven layer 122 and the elastomeric layer 124, any pressure can be applied to the first nonwoven layer 122 and the elastomeric layer 124 at a certain temperature as long as it does not substantially damage the physical and/or chemical properties of the resulting elastic laminate.
Fig. 3 is a partial perspective view of an elastic laminate 70 of yet another embodiment, wherein a portion of the first nonwoven layer 122 has been removed to show the heat/pressure bond structure. In Fig. 3, the elastomeric scrim 130 which is formed by the first and second strands 125 and 127 is used as an example for the elastomeric layer 124. Referring to Fig. 3, the first nonwoven layer 122 is bonded to the first surface 150 of the elastomeric layer 124 by forming a heat/pressure bond between the first nonwoven layer 122 and the elastomeric layer 124. In a preferred embodiment, the elastic laminate further includes a second nonwoven layer (not shown in Fig. 3) which is bonded to the second surface 152 of the elastomeric layer 124 by forming another heat/pressure bond therebetween.
The heat/pressure bond is formed by softening only the material of the elastomeric layer 124 (i.e., without melting the component fibers of the first nonwoven layer 122). This heat/pressure bond is preferably formed by application of a bonding temperature which is lower than the melting point of the material of the first nonwoven layer 122. This generally results in a decrease in the viscosity of the material which may or may not involve a "melting" of the material. As a result, the component materials of the elastomeric layer 124 are softened to form the heat/pressure bond. In a more preferred embodiment wherein the elastomeric layer 124 is formed from a polystyrene thermoplastic elastomer including a polystyrene segment, a bonding temperature which is higher than the glass transition temperature of the polystyrene segment is applied for forming the heat/pressure bond.
Fig. 5 shows one preferred example of a lamination device for forming the elastic laminate 70 shown in Fig. 3. Referring to Fig. 5, the lamination device 800 includes a first pressure plate 801 having a first surface 803, and a second plate 802 having a second surface 804. The second pressure plate 802 is fixed, while the first pressure plate 801 is movable to apply a pressure P to the first nonwoven layer 122 and the elastomeric layer 124 in cooperation with the second pressure plate 802. Preferably, the first and second surfaces 803 and 804 are substantially plane and are substantially parallel each other. The first nonwoven layer 122 is juxtaposed with the elastomeric layer 124 such that the first nonwoven layer 122 is immediately adjacent the elastomeric layer 124. The juxtaposed two layers 122 and 124 are manually supplied to the lamination device 800. A preferred lamination device 800 is available from Toyo Tester Industry Co., Ltd., Osaka, Japan, under a trade name "Heat Sealer".
In the lamination process, the first surface 803 is heated to a temperature T1 , while the second surface 804 is heated to a temperature T2. Preferably, the temperature T1 is from about 80°C to about 160°C, more preferably from about 100°C to about 130°C. The temperature T2 is preferably from about 30°C to about 60°C, more preferably from about 45°C to about 55°C. The pressure P is preferably from about 6 kg/cm2 to about 15 kg/cm2, more preferably from about 9 kg/cm'1 to about 11 kg/cm . The time period of the application of the pressure P is preferably from about 1 second to about 20 seconds, more preferably from about 5 seconds to about 15 seconds. Preferably, the application of pressure P can be performed two (or more) times to increase the peel strength of the resulting laminate 70. By the application of the temperatures T1 and T2 at the pressure P, the elastomeric layer 124 is bonded to the first nonwoven layer 122 through a heat/pressure bond which is formed by softening the material of the elastomeric layer 124 (e.g., the polystyrene thermoplastic elastomer).
The elastic laminate 70 of the present invention can be incorporated into a variety of products wherein it is desired to provide an elastic stretchability in at least one structural direction either partially or entirely. Examples of such products include disposable products, including sweat bands, bandages, body wraps, and disposable garments including disposable diapers and incontinence products.
E. Test Methods
1. Test Method for Fiber Orientation
The following method is preferably used to determine the Fiber Orientation Ratio (FOR) of nonwoven material. A sample nonwoven fabric (or layer) is placed on a specimen stub. The sample nonwoven fabric is fixed on the specimen stub at a flat condition so that the primary fiber direction (to be defined hereinafter) of the sample nonwoven fabric can be roughly aligned with the longitudinal direction of the photograph to be taken. A scanning electron microscope (SEM) is used to take a photograph at 50X magnification. A preferred SEM is available from Japan Electron Optics Laboratory (JEOL) Ltd., Tokyo, Japan, under Code No. JSM-5310
The following analysis is conducted on the photograph by using a digitizer.
A preferred digitizer is available from Graphtec Co., Ltd., Tokyo, Japan, under Code No. KD9600. A photograph is placed on the digitizer. A square area (500 μm x 500 μm) is chosen at will in the photograph on the digitizer. The both ends of every component fiber which can be seen in the square area are manually identified by an operator and the coordinates thereof are detected and recorded by the digitizer. This work is conducted on three different square areas (each having 500 μm x 500 μm) which are chosen at will in the photograph to obtain coordinate data on the all fibers in the three different square areas. The orientation angle of each fiber is calculated based on the coordinate data. The primary fiber direction of the sample nonwoven fabric is determined by the average orientation angle, which is an average value of the all orientation angle data obtained from the three different square areas.
The Fiber Orientation Ratio within about ±10 degrees (FOR10) is determined by the following calculation:
FOR10 = NF10 / TNF x 100 (2) wherein, NF10: the number of fibers which have orientation angles within about ±10 degrees from the primary fiber direction; and TNF: the total number of fibers measured within the three different square areas.
Similarly, the Fiber Orientation Ratio within about ±20 degrees (FOR20) is determined by the following calculation:
FOR20 = NF20 / TNF x 100 (3) wherein,
NF20: the number of fibers which have orientation angles within about ±20 degrees from the primary fiber direction. 2. Test Method for Tensile Strength
The following method is preferably used to measure the tensile strength of materials.
A tensile tester is prepared. The tensile tester has an upper jaw and a lower jaw which is located below the upper jaw. The upper jaw is movable and is connected to an extension force measuring means. The lower jaw is fixed in the tester. A test specimen (i.e., a nonwoven fabric to be measured) which has about 2.5 cm (about 1 inch) in width and about 10.2 cm (about 4 inches) in length is prepared and clamped with the upper jaw and the lower jaw so that the effective specimen length (L) (i.e., gauge length) is about 5.1 cm (about 2 inch). An extension force is continuously applied to the test specimen through the upper jaw at a cross-head speed of about 50 cm (about 20 inches) per minute, until the test specimen is physically broken. The applied extension force is recorded by a recorder (e.g., a computer system). The tensile strength at the breaking point is determined at the maximum tensile strength value. A tensile tester suitable for use is available from Instron Corporation (100 Royall Street, Canton, MA02021 , U.S.A.) as Code No. Instron 5564.
It is understood that the examples and embodiments described herein are for illustrative purpose only and that various modifications or changes will be suggested to one skilled in the art without departing from the scope of the present invention.

Claims

WHAT IS CLAIMED IS:
1. An elastic laminate elastically extensible in at least one direction, comprising: an elastomeric material having a first surface and a second surface opposing the first surface; and a first nonwoven layer joined to the first surface of the elastomeric material, the first nonwoven layer being formed from component fibers having a primary fiber direction; wherein the first nonwoven layer has a Fiber Orientation Ratio within about +20 degrees from a primary fiber direction of at least about 65%.
2. The elastic laminate according to Claim 1 , wherein the first nonwoven layer has a Tensile Strength Ratio of at least about 15.
3. The elastic laminate of Claim 1 , wherein the first nonwoven layer has a stress of less than about 200 gf/inch (about 80 gf/cm) at 30% elongation.
4. The elastic laminate of Claim 1 , wherein the first nonwoven layer has a Fiber Orientation Ratio within about ±10 degrees from the primary fiber direction of at least about 45%.
5. The elastic laminate of Claim 1 , wherein the first nonwoven layer has a basis weight of less than about 60 g/m .
6. The elastic laminate of Claim 1 , further comprising a second nonwoven layer joined to the second surface of the elastomeric material.
7. The elastic laminate of Claim 1 , wherein the elastomeric material is in the form of a continuous plane layer or a strand.
8. The elastic laminate of Claim 1 , wherein the first nonwoven layer is made from synthetic continuous fibers.
9. The elastic laminate of Claim 8, wherein the synthetic continuous fibers are made from a polyolefin or a polyester.
10. The elastic laminate of Claim 8, wherein the synthetic continuous fibers are bicomponent fibers.
PCT/US1998/021013 1998-10-02 1998-10-02 Elastic laminate including nonwoven layer formed from highly oriented component fibers WO2000019952A1 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
AU96857/98A AU9685798A (en) 1998-10-02 1998-10-02 Elastic laminate including nonwoven layer formed from highly oriented component fibers
PCT/US1998/021013 WO2000019952A1 (en) 1998-10-02 1998-10-02 Elastic laminate including nonwoven layer formed from highly oriented component fibers
PCT/US1999/022471 WO2000020206A1 (en) 1998-10-02 1999-09-28 Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
AT99951630T ATE309904T1 (en) 1998-10-02 1999-09-28 NON-WOVEN FABRIC CONTAINING ELASTIC LAMINATE MADE OF HIGHLY ORIENTED FIBERS AND DISPOSABLE GARMENT USING IT
EP99951630A EP1117530B1 (en) 1998-10-02 1999-09-28 Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
JP2000573543A JP2003524533A (en) 1998-10-02 1999-09-28 Elastic laminate comprising a nonwoven layer formed from strongly oriented component fibers and disposable clothing using the same
AU64031/99A AU6403199A (en) 1998-10-02 1999-09-28 Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
DE1999628420 DE69928420T2 (en) 1998-10-02 1999-09-28 LUBRICANT CONTAINING ELASTIC LAMINATE MADE OF HIGH-ORIENTED FIBERS AND ONE-WAY FASHION PIECE THAT USES THIS
US09/806,047 US6878647B1 (en) 1998-10-02 1999-09-28 Elastic laminate including nonwoven layer formed from highly-oriented-component fibers and disposable garment employing the same
CA002345756A CA2345756A1 (en) 1998-10-02 1999-09-28 Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
PE1999001001A PE20001001A1 (en) 1998-10-02 1999-10-01 ELASTIC SHEET INCLUDING A NON-WOVEN LAYER FORMED OF HIGHLY ORIENTED COMPONENT FIBERS AND DISPOSABLE GARMENT USING SUCH SHEET
TW088121661A TW434007B (en) 1998-10-02 1999-12-10 Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
JP2010146661A JP5925412B2 (en) 1998-10-02 2010-06-28 Elastic laminate comprising a nonwoven layer formed from strongly oriented component fibers and disposable clothing using the same
JP2014119038A JP2014221549A (en) 1998-10-02 2014-06-09 Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1998/021013 WO2000019952A1 (en) 1998-10-02 1998-10-02 Elastic laminate including nonwoven layer formed from highly oriented component fibers

Publications (1)

Publication Number Publication Date
WO2000019952A1 true WO2000019952A1 (en) 2000-04-13

Family

ID=22268025

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/021013 WO2000019952A1 (en) 1998-10-02 1998-10-02 Elastic laminate including nonwoven layer formed from highly oriented component fibers

Country Status (2)

Country Link
AU (1) AU9685798A (en)
WO (1) WO2000019952A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005110731A2 (en) * 2004-05-10 2005-11-24 3M Innovative Properties Company Composite webs with elastic composite structures
US7195729B2 (en) 2003-03-13 2007-03-27 3M Innovative Properties Company Composite webs and closure systems
US7390451B2 (en) 2003-03-13 2008-06-24 3M Innovative Properties Company Composite webs and closure systems

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0688665A2 (en) * 1994-06-20 1995-12-27 Nippon Petrochemicals Company, Limited Composite material with controlled elasticity
WO1996034741A1 (en) * 1995-05-02 1996-11-07 Kimberly-Clark Worldwide, Inc. Nonwoven-film laminates
DE19647459A1 (en) * 1996-11-16 1998-05-20 Mildenberger & Willing Verpack Elastic absorbent material for sanitary wear
EP0843036A1 (en) * 1996-11-19 1998-05-20 Nippon Petrochemicals Co., Ltd. Longitudinally stretched nonwoven fabric and method for producing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0688665A2 (en) * 1994-06-20 1995-12-27 Nippon Petrochemicals Company, Limited Composite material with controlled elasticity
WO1996034741A1 (en) * 1995-05-02 1996-11-07 Kimberly-Clark Worldwide, Inc. Nonwoven-film laminates
DE19647459A1 (en) * 1996-11-16 1998-05-20 Mildenberger & Willing Verpack Elastic absorbent material for sanitary wear
EP0843036A1 (en) * 1996-11-19 1998-05-20 Nippon Petrochemicals Co., Ltd. Longitudinally stretched nonwoven fabric and method for producing the same

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7195729B2 (en) 2003-03-13 2007-03-27 3M Innovative Properties Company Composite webs and closure systems
US7238314B2 (en) 2003-03-13 2007-07-03 3M Innovative Properties Company Polymer transfer apparatus, methods, and composite webs
US7390451B2 (en) 2003-03-13 2008-06-24 3M Innovative Properties Company Composite webs and closure systems
WO2005110731A2 (en) * 2004-05-10 2005-11-24 3M Innovative Properties Company Composite webs with elastic composite structures
WO2005110731A3 (en) * 2004-05-10 2006-08-10 3M Innovative Properties Co Composite webs with elastic composite structures
US7799162B2 (en) 2004-05-10 2010-09-21 3M Innovative Properties Company Composite webs with elastic composite structures
US8227071B2 (en) 2004-05-10 2012-07-24 3M Innovative Properties Company Composite webs with elastic composite structures

Also Published As

Publication number Publication date
AU9685798A (en) 2000-04-26

Similar Documents

Publication Publication Date Title
JP2919980B2 (en) Composite stretchable material and method for producing the same
AU694214B2 (en) Slit elastic fibrous nonwoven laminates
CN101925459B (en) Elastic laminate and method of making
CA2347135C (en) Laminated elastic composites
EP0915751B1 (en) Laminate composite structure and manufacturing method
JP3926850B2 (en) LAMINATE STRUCTURE STRUCTURE AND METHOD OF FORMING
KR20160147939A (en) Method of making breathable, elastic film laminates and articles derived therefrom
CA1339061C (en) Composite elastic necked-bonded material
US6863959B2 (en) Laminate and web characteristic control by varying bonding patterns
JP3865534B2 (en) Method for producing elastic stretchable composite sheet
TW200422461A (en) Elastic composite fabric, method for manufacturing the same, applications thereof
WO2000020206A1 (en) Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
WO1996010481A1 (en) Slit elastic fibrous nonwoven laminates
CN1429149A (en) Three dimensional highly elastic film/non-woven composite
JP2007500615A (en) Tearable elastic composite article and manufacturing method
JP2014525324A (en) Fastening member with bonded reinforcing layer
JP2003053894A (en) Laminated body
JP4651573B2 (en) Elastic nonwoven fabric
KR20180098317A (en) Single-fiber non-woven fabric, loop member for surface fastener, and sanitary article
WO2000019952A1 (en) Elastic laminate including nonwoven layer formed from highly oriented component fibers
CA2345756A1 (en) Elastic laminate including nonwoven layer formed from highly oriented component fibers and disposable garment employing the same
WO2000020205A1 (en) Elastic laminates and method for making the same
WO2000030581A1 (en) Disposable diaper having elastic side panels
JPH0770902A (en) Stretchable nonwoven cloth
TW201714593A (en) Loop member for surface fastener and adult diaper

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AL AM AT AT AU AZ BA BB BG BR BY CA CH CN CU CZ CZ DE DE DK DK EE EE ES FI FI GB GE GH GM HR HU ID IL IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SK SL TJ TM TR TT UA UG US UZ VN YU ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

NENP Non-entry into the national phase

Ref country code: CA

122 Ep: pct application non-entry in european phase