WO2000037512A3 - Olefin polymerization catalysts, their production and use - Google Patents

Olefin polymerization catalysts, their production and use Download PDF

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Publication number
WO2000037512A3
WO2000037512A3 PCT/US1999/029755 US9929755W WO0037512A3 WO 2000037512 A3 WO2000037512 A3 WO 2000037512A3 US 9929755 W US9929755 W US 9929755W WO 0037512 A3 WO0037512 A3 WO 0037512A3
Authority
WO
WIPO (PCT)
Prior art keywords
group
containing group
phenoxide
bound
carbon
Prior art date
Application number
PCT/US1999/029755
Other languages
French (fr)
Other versions
WO2000037512A2 (en
Inventor
Gregory T Whiteker
Jack A Smith
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Priority to AU21846/00A priority Critical patent/AU2184600A/en
Publication of WO2000037512A2 publication Critical patent/WO2000037512A2/en
Publication of WO2000037512A3 publication Critical patent/WO2000037512A3/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Abstract

This invention relates to a catalyst system comprising an activator and one or more heteroatom substituted phenoxide group 3 to 10 transition metal or lanthanide metal compounds wherein the metal is bound to the oxygen of the phenoxide group and provided that: a) if more than one heteroatom substituted phenoxide is present it is not bridged to the other heteroatom substituted phenoxide; b) if the metal is a group 4 metal then the carbon adjacent to the carbon bound to the oxygen of the phenoxide may not be bound to an aldehyde or an ester c) the carbon ortho to the carbon bound to the oxygen of the phenoxide may not be bound to C1 carbon in group represented by formula: (I), wherein R?6 and R7¿ are independently hydrogen, halogen, a hydrocarbon group, a heterocyclic compound residue, an oxygen containing group, a nitrogen containing group, a boron containing group, a sulfur containing group, a phosphorus containing group, a silicon containing group, a germanium containing group, or a tin containing group, and R?1 and R2¿ may be bonded to each other to form a ring. The activator may be an aluminum alkyl, an alumoxane, a modified alumoxane, a non-coordinating anion, a borane, a borate or a mixture thereof.
PCT/US1999/029755 1998-12-18 1999-12-14 Olefin polymerization catalysts, their production and use WO2000037512A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU21846/00A AU2184600A (en) 1998-12-18 1999-12-14 Olefin polymerization catalysts, their production and use

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US21659498A 1998-12-18 1998-12-18
US09/216,594 1998-12-18
US09/248,147 US6333389B2 (en) 1998-12-18 1999-02-10 Olefin polymerization catalysts, their production and use
US09/248,147 1999-02-10

Publications (2)

Publication Number Publication Date
WO2000037512A2 WO2000037512A2 (en) 2000-06-29
WO2000037512A3 true WO2000037512A3 (en) 2000-10-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/029755 WO2000037512A2 (en) 1998-12-18 1999-12-14 Olefin polymerization catalysts, their production and use

Country Status (3)

Country Link
US (2) US6333389B2 (en)
AU (1) AU2184600A (en)
WO (1) WO2000037512A2 (en)

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US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same

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US6596827B2 (en) * 1999-09-10 2003-07-22 Ramot At Tel Aviv University Ltd. Method for catalytic polymerization of alpha-olefin monomers using an ultra-high activity non-metallocene pre-catalyst
US6274684B1 (en) * 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
EP1303543A1 (en) * 2000-07-17 2003-04-23 Univation Technologies LLC A catalyst system and its use in a polymerization process
US6531555B2 (en) * 2000-12-19 2003-03-11 Univation Technologies, Llp Olefin oligomerization catalysts, their production and use
US6930070B2 (en) * 2002-01-28 2005-08-16 Univation Technologies, Llc Heterocyclic nitrogen-containing activators and catalyst systems for olefin polymerization
US6794514B2 (en) 2002-04-12 2004-09-21 Symyx Technologies, Inc. Ethylene-styrene copolymers and phenol-triazole type complexes, catalysts, and processes for polymerizing
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
AU2003302033A1 (en) 2002-10-15 2004-06-15 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7094848B2 (en) * 2003-05-13 2006-08-22 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
US7705157B2 (en) * 2004-12-16 2010-04-27 Symyx Solutions, Inc. Phenol-heterocyclic ligands, metal complexes, and their uses as catalysts
US6987152B1 (en) 2005-01-11 2006-01-17 Univation Technologies, Llc Feed purification at ambient temperature
US7312279B2 (en) * 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
US7947797B2 (en) 2005-09-14 2011-05-24 Univation Technologies, Llc Method for operating a gas-phase reactor at or near maximum production rates while controlling polymer stickiness
US20070109911A1 (en) * 2005-11-16 2007-05-17 Neubauer Anthony C High speed and direct driven rotating equipment for polyolefin manufacturing
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BRPI0717152B1 (en) 2006-10-03 2018-07-03 Univation Technologies, Llc. OLEFINE POLYMERIZATION METHOD AND OLEFINE POLYMERIZATION REACTION SYSTEM
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EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
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TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
KR101071399B1 (en) * 2007-12-05 2011-10-07 주식회사 엘지화학 Non-metallocene catalysts having tetrazol group for olefin polymerization and polymerizing method of olefin using the same
US20090286944A1 (en) * 2008-05-15 2009-11-19 Symyx Technologies, Inc. Select phenol-heterocycle ligands, metal complexes formed therefrom, and their uses as catalysts
CN102257017B (en) 2008-12-18 2014-02-12 尤尼威蒂恩技术有限责任公司 Method for seed bed treatment for polymerization reaction
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WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
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WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
CN103228682B (en) 2010-11-30 2015-07-22 尤尼威蒂恩技术有限责任公司 Processes for the polymerization of olefins with extracted metal carboxylate salts
SG190429A1 (en) 2010-11-30 2013-06-28 Univation Tech Llc Catalyst composition having improved flow characteristics and methods of making and using the same
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CN103534279B (en) 2011-05-13 2016-08-17 尤尼威蒂恩技术有限责任公司 The carbon monoxide-olefin polymeric being spray-dried and the polymerization using it
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KR102022132B1 (en) 2011-11-08 2019-09-17 유니베이션 테크놀로지즈, 엘엘씨 Methods of preparing a catalyst system
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US8937139B2 (en) * 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US10280283B2 (en) 2012-12-28 2019-05-07 Univation Technologies, Llc Supported catalyst with improved flowability
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Also Published As

Publication number Publication date
US20010031843A1 (en) 2001-10-18
WO2000037512A2 (en) 2000-06-29
AU2184600A (en) 2000-07-12
US6333389B2 (en) 2001-12-25
US20020016254A1 (en) 2002-02-07

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