WO2000059612A1 - Seawater pressure-driven desalinization apparatus and method with gravity-driven brine return - Google Patents

Seawater pressure-driven desalinization apparatus and method with gravity-driven brine return Download PDF

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Publication number
WO2000059612A1
WO2000059612A1 PCT/US1999/026025 US9926025W WO0059612A1 WO 2000059612 A1 WO2000059612 A1 WO 2000059612A1 US 9926025 W US9926025 W US 9926025W WO 0059612 A1 WO0059612 A1 WO 0059612A1
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WIPO (PCT)
Prior art keywords
brine
water
enclosure
pressure
channel
Prior art date
Application number
PCT/US1999/026025
Other languages
French (fr)
Inventor
Kenneth R. Bosley
Original Assignee
Bosley Kenneth R
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bosley Kenneth R filed Critical Bosley Kenneth R
Priority to AU18128/00A priority Critical patent/AU1812800A/en
Priority to AT99961580T priority patent/ATE291482T1/en
Priority to DE69924411T priority patent/DE69924411T2/en
Priority to EP99961580A priority patent/EP1214137B1/en
Publication of WO2000059612A1 publication Critical patent/WO2000059612A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/10Accessories; Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08Prevention of membrane fouling or of concentration polarisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/02Forward flushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/20By influencing the flow
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • Y02A20/131Reverse-osmosis

Definitions

  • the present invention relates to a reverse osmosis
  • the present invention is distinguishable from the
  • the present invention is an apparatus and method
  • each pressure hull is maintained at about one
  • ROD reverse osmosis devices
  • the brine can be turned off, as gravity will cause it
  • It is a fourth object of the invention is to
  • pressure hulls can be removed and taken to a central facility for maintenance, rather than the on-site
  • present invention allows an offshore desalinization
  • Fig. 1 is a schematic environmental front
  • Fig. 2 is a schematic environmental front
  • FIG. 3 is a schematic environmental front
  • Fig. 4 is a schematic cross-sectional view of one
  • Fig. 5 is a schematic cross-sectional view of one
  • the present invention is an apparatus and method
  • FIG. 1 is a schematic environmental front
  • a large metal cylinder 10 with an open
  • top openings and/or a plurality of bottom openings may
  • the apparatus can be used. Also, the apparatus can be supported by
  • hulls 15 are removably attached to the side of the
  • Fig. 2 is a schematic environmental front
  • FIG. 3 is a schematic environmental front
  • brine pipe 35 projects over a cliff E in the sea floor.
  • Fig. 4 is a schematic cross-sectional view of one
  • each pressure hull is maintained at a
  • RODs each having a selectively permeable membrane 22 surrounding a brine enclosure 24.
  • seawater to pass from outside the hulls into the RODs.
  • the check valves enhance the efficiency of the process
  • conduit should be external to the cylinder, as concentrated brine is highly corrosive.
  • Fig. 5 is a schematic cross-sectional view of one
  • freshwater pipes 48 which are connected to the fresh
  • At least one of the brine pumps is preferably
  • the brine can be turned off, as gravity will cause it
  • desalinating seawater it can also be used to remove a
  • h b Height of a brine column (in meters)
  • the brine density may be calculated from the
  • the brine's density will equal the
  • TDS Total Dissolved Solids
  • the concentration of TDS in seawater is given by:
  • concentration factor E.g., an 80% efficient process
  • the process depth may be determined by the desired process depth

Abstract

An apparatus and method of removing salt from seawater to produce potable freshwater. A large metal cylinder (12), with open top and bottom ends, is anchored to the sea floor offshore. Several pressure hulls (15, 16) are attached to the side of the cylinder. The interior of each pressure hull is maintained at about one atmosphere, but the hulls are submerged at a depth at which the ambient water pressure is several atmospheres. Within each pressure hull there are several reverse osmosis devices ('RODs') (20). Check valves (30) allow seawater to pass from outside the hulls into the RODs. Due to the pressure differential, freshwater passes through the membranes (22) of the RODs by reverse osmosis, and is pumped out of the pressure hulls to a storage facility (36) onshore.

Description

SEAWATER PRESSURE-DRIVEN DESALINIZATION APPARATUS AND METHOD WITH GRAVITY-DRIVEN BRINE RETURN
BACKGROUND OF THE INVENTION
1. FIELD OF THE INVENTION
The present invention relates to a reverse osmosis
method of removing the salt from water in the ocean or
inland bodies of salt water, using the pressure of the
seawater itself, and the force of gravity.
2. DESCRIPTION OF THE PRIOR ART
Due to the shortage of freshwater in the
southwestern United States and other arid parts of the
world, there have been numerous inventions for
desalinating sea water, by reverse osmosis,
distillation, and other means. However, desalinization
remains an expensive process . The concentrated brine
produced as a by-product of desalinization can itself
contribute to pollution of the environment in onshore facilities. The production of electricity or other
forms of energy consumed in desalinization can also
contribute to pollution of the air, water and land.
U.S. Patent No. 4,335,576, issued on June 22,
1982, to Harold H. Hopfe, discloses a device for
producing freshwater from seawater which floats on the
surface of the sea. It derives the energy for
desalinization from the motion of the waves on the
surface of the water. Movement of the water on the
surface causes reaction plates to move, and the
movement is ultimately transmitted to pistons that move
in cylinders to exert pressure on seawater to force
reverse osmosis.
U.S. Patent No. 4,452,969, issued on June 5, 1984,
to Fernand Lopez, discloses a reverse osmosis apparatus
for producing freshwater from seawater, which is
designed to be temporarily submerged, as on a fishing
line. U.S. Patent No. 4,770,775, issued on September
13, 1988, to Fernand Lopez, discloses another apparatus
for the production of freshwater from seawater, which
is also designed to be temporarily submerged, and has a chamber that expands as freshwater is produced. Both of
these apparatuses use the pressure of the seawater
itself to force reverse osmosis .
U.S. Patent No. 5,167,786, issued on December 1,
1992, to William J. Eberle, discloses a wave power
collection apparatus, which is anchored in the sea
floor, and in one embodiment desalinates seawater by
reverse osmosis. The movement of floats is used in
that embodiment to turn a generator which produces
electricity to power pumps that force seawater through
a membrane in a reverse osmosis unit.
U.S. Patent No. 5,229,005, issued on July 20,
1993, to Yu-Si Fok and Sushil K. Gupta, discloses a
process for the desalinization of seawater, by lowering
reverse osmosis devices into the ocean by means of
lines attached to pulleys, and raising them again by
the same means to remove the freshwater produced. The
pressure of the seawater itself is used to force
reverse osmosis of the seawater across a membrane to
produce freshwater. U.S. Patent No. 5,366,635, issued on November 22,
1994, to Larry 0. Watkins, discloses a desalinization
apparatus and means in which a separator is placed on
the sea floor, and the pressure at the sea floor is
used to force seawater through a membrane to form
freshwater by reverse osmosis, which is then pumped
out .
British Patent No. 2,068,774, published on August
19, 1981, to Jose Luis Ramo Mesple, discloses an
apparatus for desalinating water by reverse osmosis in
cells located deep underground, utilizing the pressure
resulting from the water being deep underground.
The present invention is distinguishable from the
prior art cited, in that only it takes advantage of the
fact that the concentrated brine produced as a by¬
product of reverse osmosis desalinization is heavier
than seawater to reduce the energy consumed in
desalinization. None of the above inventions and
patents, taken either singly or in combination, will be
seen to describe the present invention as claimed. SUMMARY OF THE INVENTION
The present invention is an apparatus and method
of removing salt from seawater to produce potable
freshwater. A large metal cylinder, with open top and
bottom ends, is anchored to the floor of the ocean (or
inland sea) offshore. Several pressure hulls are
attached to the side of the cylinder. The interior of
each pressure hull is maintained at about one
atmosphere of pressure, but the hulls are submerged at
a depth at which the ambient water pressure is several
atmospheres. Within each pressure hull there are
several reverse osmosis devices ("RODs"), each
containing a membrane that will allow water molecules,
but not sodium and chlorine ions, to pass through.
Check valves allow sea water to pass from outside the
hulls into the RODs. Due to the pressure differential,
water molecules pass through the membranes by reverse
osmosis, while salt is left behind, and freshwater is
pumped out of the pressure hulls to a storage facility
on shore (or where ever else it is needed) . Initially, the seawater remaining on the other side of the
membrane, which has a greatly increased concentration
of salt due to water passing through the membrane, is
pumped into the cylinder. (The water with an increased
concentration of salt is hereinafter referred to as
"brine".) After an initial surge, the level of the
brine in the cylinder will eventually reach
equilibrium, at a height below the height of the
seawater outside the cylinder, due to the greater
weight of the brine compared to unconcentrated
seawater. After equilibrium is reached, the pumps for
the brine can be turned off, as gravity will cause it
to flow down from the pressure hulls to the surface of
the brine in the cylinder. This will reduce the energy
needed to desalinate seawater. (It will still be
necessary to pump out the freshwater.)
Accordingly, it is a principal object of the
invention to provide a means for reducing the energy
required to desalinate seawater. Conventional
desalinization plants, located on or near the seashore,
require four pumping processes: first, pumping the seawater to the plant; second, pumping to raise the
pressure high enough for the RODs to operate; third,
pumping the brine back out to sea; and fourth, pumping
the freshwater to a reservoir or a treatment facility
for further purification, and ultimately to the
consumer. The present invention eliminates all but the
fourth pumping process. While prior inventions of
offshore desalinization apparatus, as in U.S. Patent
No. 5,366,635 to Watkins, will also eliminate the first
and second processes, only the instant invention will
also eliminate the third process of pumping out the
brine, without requiring that energy be expended in
raising the RODs, as in U.S. Patent No. 4,452,969 to
Lopez and U.S. Patent No. 5,229,005 to Fok et al .
It is second object of the invention to provide a
means for reducing the need for using expensive real
estate on or near the oceanfront for desalinization
facilities. As no oceanfront or near-oceanfront
property is used exclusively for the process, most real
estate costs associated with desalinization plants can
be avoided. Some offshore site leasing may be required, but this cost should be much lower than for
offshore sites involved in petroleum or mineral
extraction.
It is a third object of the invention to provide a
means for making the expansion of desalinization
facilities easier and less expensive. As no dry land
is used, and each platform must have a clear navigation
zone around it (as most jurisdictions require by law) ,
sufficient space for attaching additional pressure
hulls to the cylinder will be available and facility
expansion considerably eased. The expansion of a
facility is limited only by the number of pressure
hulls that can be fitted onto the cylinder at
appropriate depths, rather than allowances made by a
zoning commission with many other constituents to
satisfy, as may the case with a land-based
desalinization facility.
It is a fourth object of the invention is to
provide a means for reducing the cost of desalinizing
seawater by centralizing maintenance facilities, as the
pressure hulls can be removed and taken to a central facility for maintenance, rather than the on-site
maintenance required by conventional shore-based
desalinization plants.
It is a fifth object of the invention to reduce
pollution of the shoreline from the release of
concentrated brine by desalinization plants.
Conventional onshore desalinization facilities pump
their brine out to sea through a bottom-laid pipeline,
which releases the brine on or near the ocean floor.
Releasing the brine near the ocean floor increases the
area affected by the brine's toxicity. Existing
methods to reduce the toxic effects add to the cost of
desalinization through greater plant infrastructural
requirements or reduced process efficiency. The
present invention allows an offshore desalinization
facility to release its brine into mid-water, where
mixing with the ocean current is more efficient, with
fewer effects upon bottom-dwelling flora and fauna.
Because the facility can be located offshore, ocean
currents and tidal action will thoroughly mix the brine
back into the surrounding seawater, and the overall impact of increased salinity from the brine release
could be infinitesimal as little as two or three
kilometers down-current.
It is an object of the invention to provide
improved elements and arrangements thereof in an
apparatus for the purposes described which is
inexpensive, dependable and fully effective in
accomplishing its intended purposes.
These and other objects of the present invention
will become readily apparent upon further review of the
following specification and drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a schematic environmental front
elevational view of the first preferred embodiment of
the invention.
Fig. 2 is a schematic environmental front
elevational view of the second preferred embodiment of
the invention. Fig. 3 is a schematic environmental front
elevational view of the third preferred embodiment of
the invention.
Fig. 4 is a schematic cross-sectional view of one
of the pressure hulls of the first type that may be
used in any of the preferred embodiments of the
invention.
Fig. 5 is a schematic cross-sectional view of one
of the pressure hulls of the second type that may be
used in any of the preferred embodiments of the
invention.
Similar reference characters denote corresponding
features consistently throughout the attached drawings.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
The present invention is an apparatus and method
of removing salt from seawater to produce potable fresh
water. It may be used in either the oceans or in
inland bodies of salt water. Fig. 1 is a schematic environmental front
elevational view of the first preferred embodiment of
the invention. A large metal cylinder 10, with an open
top end 12 and an bottom opening 14, rests on platform
13 which is anchored to the floor A of the ocean B (or
inland sea) offshore. (Alternatively, a tube or
channel of a different shape and/or with a plurality of
top openings and/or a plurality of bottom openings may
be used. Also, the apparatus can be supported by
flotation devices, or by cables attached to ships,
rather than resting on the sea floor.) Bottom pressure
hulls 15 are removably attached to the side of the
cylinder, just above the equilibrium level C of brine
in the cylinder. When greater production capacity is
needed, upper pressure hulls 16 are added.
Fig. 2 is a schematic environmental front
elevational view of the second preferred embodiment of
the invention, which is the same as the first preferred
embodiment, except that the bottom of the cylinder
rests directly on the sea floor. Fig. 3 is a schematic environmental front
elevational view of the third preferred embodiment of
the invention, which is the
same as the second preferred embodiment, except that
brine pipe 35 projects over a cliff E in the sea floor.
This embodiment may be used in areas such as the Red
Sea where the submarine topography makes it possible.
Sending the brine over a submarine cliff will make
possible more efficient mixing of the brine with the
sea water.
Fig. 4 is a schematic cross-sectional view of one
of the pressure hulls of the first type that may be
used in any of the preferred embodiments of the
invention. The fresh water enclosure 18 in the
interior of each pressure hull is maintained at a
pressure below that of the ambient seawater, preferably
at one atmosphere of pressure, but the hulls are
preferably submerged at a depth at which the ambient
water pressure is several atmospheres. Within each
pressure hull there are several reverse osmosis devices
20 ("RODs"), each having a selectively permeable membrane 22 surrounding a brine enclosure 24. The
membrane allows water molecules, but not sodium and
chlorine ions, to pass through. (Other substances may
also be filtered out of the seawater, depending on the
characteristics of the membrane.) The pressure hulls
have an external skin 26 which is impermeable to water.
Seawater conduits 28, having check valves 30, pass
through the external skin and the membranes, to allow
seawater to pass from outside the hulls into the RODs.
The check valves enhance the efficiency of the process,
by preventing brine from returning directly to the
surrounding seawater by the same route . The space
between the external skin and the other contents of the
pressure hulls forms the fresh water enclosure 18. Due
to the pressure difference, water molecules pass
through the membranes by reverse osmosis, and
desalinated water is pumped out of the pressure hulls
through the freshwater conduit 32 and (referring back
to Fig. 1) pipeline 34 to an onshore storage facility
36 (or where ever else it is needed) . The freshwater
conduit should be external to the cylinder, as concentrated brine is highly corrosive. Freshwater
pumps (not shown in the drawings) may be located in the
storage facility, the pipeline, the cylinder, and/or
elsewhere. The pumping out of the freshwater maintains
the pressure difference across the membrane, so that
reverse osmosis can continue. The desalinated water
may undergo further purification at a local water
treatment plant .
Fig. 5 is a schematic cross-sectional view of one
of the pressure hulls of the second type that may be
used in any of the preferred embodiments of the
invention. It differs from the first type in having a
dry interior 42, which is kept dry by an air vent 44 to
the atmosphere above the surface D through which any
moisture evaporates . The RODs are enclosed by water
proof surfaces 46. Freshwater is drained from the RODs
by freshwater pipes 48 which are connected to the fresh
water conduit 32.
Initially, the seawater remaining on the other
side of the membranes ("brine"), which has a greatly
increased concentration of salt due to water passing through the membranes, is pumped into the cylinder by
the brine pumps 38 through the brine conduits 40 (see
Fig. 4) . At least one of the brine pumps is preferably
located in each pressure hull, as shown, but other
locations are possible. The pumping out of the brine
maintains a pressure difference across the seawater
conduits, causing seawater to continue to flow into the
reverse osmosis devices. After an initial surge, the
level of the brine C in the cylinder will eventually
reach equilibrium at an elevation below the sea level D
outside the cylinder (see Fig. 1) , due to the greater
weight of the brine compared to unconcentrated
seawater. After equilibrium is reached the pumps for
the brine can be turned off, as gravity will cause it
to flow down from the hulls to the surface of the brine
in the cylinder. This will reduce the energy needed to
desalinate seawater. (It will still be necessary to
pump out the freshwater.) The lower pressure hulls 15
should be attached to the cylinder first, as the
pressure difference will be greatest just above the
brine level C. (While the pressure difference would be greater at lower depths, gravity will not cause brine
to flow out of the pressure hulls if they are below the
brine's surface.) When greater capacity is needed, the
upper hulls 16 should be added, desalinization will not
be as efficient in them, as the pressure difference
will be lower.
The earth's gravity will cause the brine in the
tube to flow out of the bottom opening until the weight
of the brine in the tube equals the weight of an
equivalent column of water in the sea outside the tube.
As brine continually flows into the tube when the
invention is in operation, the weight of the brine in
the tube will continue to be heavier than that an
equivalent column of seawater outside, and brine will
continue to flow out. If there were no currents in the
sea, the salinity of the sea in the immediate area
around the tube could eventually rise to almost the
degree of salinity in the tube (though not to complete
equality, due to diffusion of salt through the
seawater) . This would cause the level of brine in the
tube to rise to almost the level of the sea outside the tube, and it would be necessary to reactivate the brine
pumps for desalinization to continue. (This might
actually happen in inland bodies of salt water, which
lack drainage to the oceans, if desalinization were
carried out on a massive scale over a long period of
time.) Thus, the present invention derives its energy
savings, not out of nothing, as would a perpetual
motion machine, but from the force of the earth's
gravity, from ocean currents and interlayer mixing that
are driven by electromagnetic radiation produced by
nuclear reactions in the sun, and from diffusion made
possible by random movements of molecules and ions in
the seawater that are also driven by heat from the sun.
It is to be understood that the present invention
is not limited to the embodiments described above, but
encompasses any and all embodiments within the scope of
the following claims. Although the method of the
invention is primarily intended as a means for
desalinating seawater, it can also be used to remove a
purified solvent from any solution, where a solution
with a higher concentration of solute is denser than a solution with a lower concentration of solute. An
apparatus similar to the preferred embodiment, but
smaller in size, may be useful in chemistry
laboratories and chemical processing plants.
MATHEMATICAL APPENDIX
In the following discussion, let:
Pd = Process depth
Pe = Process efficiency (1.0 = 100% efficiency)
df = Density of fresh water (999.97 kilograms per cubic
meter at four degrees Celcius)
ds = Density of sea water (1,025 kilograms per cubic
meter at four degrees Celcius)
db = Density of brine (variable dependant upon process
efficiency)
hs = Height of a seawater column (in meters)
hb = Height of a brine column (in meters)
For brine to flow out of the cylinder by the force
of gravity, the pressure of the brine column must exceed the pressure of the seawater at the same depth
as the cylinder's bottom opening:
(1) dbhb > dshs
The brine density may be calculated from the
process efficiency and the densities of freshwater and
seawater as follows:
(2) db = df + [(d8 - df)/(l - Pe)]
Alternatively, the brine's density will equal the
density of the freshwater plus the concentration of
Total Dissolved Solids ("TDS") in the remaining fluid.
The concentration of TDS in seawater is given by:
( 3 ) TDSseawater = ( ds - df )
Dividing equation (3) by 1 - Pe gives the
concentration factor. E.g., an 80% efficient process
(Pe = 0.80) will concentrate the TDS of 100 cubic
meters of seawater into 20 cubic meters of brine and
produce 80 cubic meters of freshwater:
(4) 1.00 - 0.80 = 0.20
with the TDS concentration of the brine being five
times that of seawater, as dividing by 0.20 is
equivalent to multiplying by five. Thus, the TDS load in the brine is given by:
(5) [(ds - df)/(l - Pe)]
Adding the TDS load for the brine to the density
of freshwater gives the total density of the brine:
(6) db = df + [(ds - df)/(l - P ]
which is identical to equation (2) .
The process depth may be determined by the desired
operating pressure for the desalinization process. If
a pressure of four atmospheres (4.05 bars or 58.8
pounds per square inch) is desired, then the process
must operate at a depth of forty meters below mean low
tide. For every increase or decrease of one atmosphere
(1.013 bars or 14.7 pounds per square inch) in the
process operating pressure the process depth must
change by approximately ten meters.
For any process depth and any process efficiency,
the range of allowable depths for the bottom opening of
the cylinder is given by the following inequality:
(7) hb > Pd(ds/db)/(l - ds/db)
This inequality is derived as follows: We seek
the depth at which the pressure of the brine column exceeds that of the seawater column, i.e., when the
following inequality is satisfied:
(8) dbhb > dshs
We know that the height of the seawater column is
the same or greater than the height of the brine column
plus the process depth:
(9) hs > hb + Pd
An inequality is preferred to an equation to allow
a safety factor for brine density fluctuations.
Substituting inequality (9) into inequality (8), we
get:
(10) dbhb > ds(hb + Pd)
Isolating the height of the brine column, we get:
hb > ds(hb + Pd) /db = hb(ds/db) + Pd(ds/db)
Subtracting hb(ds/db) from both sides of the inequality
gives :
hb(l - ds/db) > Pd(ds/db)
Dividing both sides of the inequality by (1 - ds/db)
gives :
(11) hb > Pd(ds/db)/(l - ds/db)
which is the same as inequality (7) . E.g., for a process which is 80% efficient,
operating at a depth of 40 meters, we first use
equation (2) to determine the brine's density:
db = df + [(ds - df)/(l - Pe)]
= 999.97 + (1,025.00 - 999.97)/(l - 0.80)
= 999.97 + (25.03/0.20)
= 999.97 + 125.15
= 1,125.12 kg/m3
Substituting the value of 1,125.12 kg/m3 into
inequality (7) gives:
hb > Pd(da/db)/(l - ds/db)
> 40 (1,025.00/1,125.12) / (1 - 1,025.00/1,125.12)
> 409.51 meters
Thus, the depth of the bottom opening in the
cylinder must be at least 409.51 + 40.00 = 449.51
meters below the surface of the surrounding seawater
(at mean low tide) . Adding a ten percent safety factor
(about 40.1 meters) increases this difference to
approximately 490 meters. We can check this result by
comparing the difference between the pressures of the
seawater column at 490 meters and the brine column at 450 meters (with the 10% safety factor) with the
difference between the pressures of the seawater column
at 450 meters and the brine column at 410 meters
(without the 10% safety factor) :
With the safety factor:
dbhb - dshs = (l,125kg/m3) (450m) -
(l,025.00kg/m3) (490m)
= (506,304.0 - 502,250.0) kg/m2
= 4,054.0 kg/m2
Without the safety factor:
dbhb - dshs = (l,125kg/m3) (410m) -
(1, 025.00kg/m3) (450m)
= (461,299.2 - 461,250.0) kg/m2
= 49.2 kg/m2
The fact that the difference is positive in both
cases ensures an outward flow of brine. These depths
and pressures are well within the state of the art in
off-shore platform construction and operation. The
desalinated water will need to be pumped out of the
pressure hulls with sufficient pressure to overcome the difference in hydraulic head, its own viscosity, and the friction in the pipeline through which it is
carried to shore. This is a proven engineering task
that is well with our current capabilities.

Claims

CLAIMSI claim:
1. An apparatus for desalinating seawater,
comprising :
at least one membrane through which water
molecules can flow, but through which sodium and
chlorine ions cannot flow;
at least one fresh water enclosure, within which
water that has been desalinated by passing through at
least one membrane, can be collected and separated from
salt water;
at least one brine enclosure, within which water
that has not passed through at least one membrane, and
has an increased concentration of salt, can be
collected and separated from water with a lower
concentration of salt;
a channel having at least one top opening and at
least one bottom opening; and
at least one brine conduit between at least one brine enclosure and the channel.
2. The apparatus for desalinating seawater
according to claim 1, wherein:
at least one membrane and at least one freshwater
enclosure are positioned far enough below the surface
of a body of salt water, that there is a sufficient
pressure difference across the membrane for water to be
desalinated by reverse osmosis and to collect in the
freshwater enclosure;
the top openings of the channel are positioned
above the surface of a body of water;
the bottom openings of the channel are positioned
below the surface of the body of water and below at
least one brine enclosure and at least one brine
conduit; and
at least one brine enclosure and at least one
brine conduit are positioned above a level at which
water having an increased concentration of salt will
reach equilibrium in the channel.
3. The apparatus for desalinating seawater
according to claim 2, further comprising:
at least one freshwater pump for removing
desalinated water from at least one freshwater
enclosure; and
at least one brine pump for removing water having
an increased concentration of salt from at least one
brine enclosure, until the level of water having an
increased concentration of salt has reached equilibrium
in the channel.
4. The apparatus for desalinating seawater
according to claim 3, further comprising:
at least one pressure hull, retained on the
channel, and containing at least one membrane, at least
one brine enclosure, and at least one freshwater
enclosure;
at least one seawater conduit, through which water
exterior to the pressure hull can flow into at least
one brine enclosure; and
at least one check valve in at least one seawater
conduit, that prevents water from flowing from the
brine enclosure back through the seawater conduit .
5. The apparatus for desalinating seawater
according to claim 4, wherein there are a plurality of
pressure hulls.
6. The apparatus for desalinating seawater
according to claim 5, wherein the channel has only one
top opening and only one bottom opening, and the
channel is impermeable to water except at the top
opening and the bottom opening .
7. The apparatus for desalinating seawater
according to claim 6, wherein each pressure hull has an
external skin that is impermeable to water.
8. The apparatus for desalinating seawater
according to claim 7, wherein each pressure hull has
a plurality of reverse osmosis devices, with each
of the reverse osmosis devices comprising one of the
brine enclosures surrounded by one of the membranes,
with a seawater conduit for each reverse osmosis device
passing through the external skin of the pressure hull
and the membrane .
9. The apparatus for desalinating seawater
according to claim 8, wherein each pressure hull has
one of the brine pumps, and internal brine conduits
through which water can flow from the brine enclosures
to the brine pump .
10. The apparatus for desalinating seawater
according to claim 9, wherein each pressure hull has
only one fresh water enclosure, which is formed by the
external skin, and occupies space between the external
skin and the reverse osmosis devices, the internal
brine conduits, and the brine pump, with a freshwater
conduit passing through the external skin through which
desalinated water can be pumped out.
11. The apparatus for desalinating seawater
according to claim 10, wherein the freshwater pump
maintains water pressure within the pressure hulls
lower than water pressure outside the pressure hulls.
12. The apparatus for desalinating seawater
according to claim 11, wherein the water pressure
within the pressure hulls is equivalent to pressure at
the surface of the sea.
13. The apparatus for desalinating seawater
according to claim 9, wherein each reverse osmosis
device is surrounded by a water proof surface connected
by a freshwater pipe to a freshwater conduit passing
through the external skin through which desalinated
water can be pumped out.
14. The apparatus for desalinating seawater
according to claim 13, wherein each pressure hull has
an interior between the external skin and the water
proof surfaces of the reverse osmosis devices, with the
interior connected to an air vent.
15. The apparatus for desalinating seawater
according to claim 9, wherein the pressure hulls are
removably retained on the channel, whereby they can be
temporarily removed for maintenance.
16. The apparatus for desalinating seawater
according to claim 15, wherein the channel is
cylindrical .
17. The apparatus for desalinating seawater
according to claim 16, wherein the desalinated water is
pumped out to a water treatment facility for further
purification .
18. The apparatus for desalinating seawater
according claim 1, wherein the apparatus is positioned
in a current so as to minimize environmental effects of
discharge of brine.
19. The apparatus for desalinating seawater
according to claim 1, wherein the channel has a bottom
end resting on the floor of the sea.
20. The apparatus for desalinating seawater
according to claim 1, wherein the apparatus is
supported by means of flotation.
21. The apparatus for desalinating seawater
according to claim 1, wherein the apparatus is
supported on an offshore platform.
22. The apparatus for desalinating seawater
according to claim 1, wherein the apparatus is adjacent
to a sudden drop in elevation of a sea floor, and
includes a means for conveying brine over the sudden
drop in elevation.
23. A method for desalinating seawater,
comprising the steps of:
allowing sea water to flow through a check valve
into a brine enclosure which is separated from a
freshwater enclosure by a membrane through which water
molecules, but not sodium and chlorine ions, can flow;
reverse osmosis of the seawater, by maintaining a
pressure differential across the membrane, by pumping
out desalinated water from the freshwater enclosure;
causing seawater to continue to flow into the
brine enclosure, by maintaining a pressure differential
across the check valve, by pumping out water having an
increased concentration of salt from the brine
enclosure into a channel with an open top above the
surface of the sea, and an open bottom below the
surface of the sea and below the brine enclosure; and
allowing the surface level of the water having an
increasing concentration of salt to reach equilibrium
in the channel below the surface of the sea and below
the brine enclosure, and then discontinuing the pumping
of water out of the brine enclosure, and allowing water to flow out of the brine enclosure into the channel by
the force of gravity.
24. A method for separating a lighter solvent
from a heavier solution, comprising the steps of:
allowing a solution to flow through a check valve
into a first enclosure which is separated from a second
enclosure by a membrane through which a solvent, but
not a solute, can flow;
reverse osmosis of the solution, by maintaining a
pressure differential across the membrane, by pumping
out purified solvent from the second enclosure;
causing the solution to continue to flow into the
first enclosure, by maintaining a pressure differential
across the check valve, by pumping out the solution
having an increased concentration of solute from the
first enclosure into a channel with an open top above a
surface of the solution, and an open bottom below the
surface of the solution and below the first enclosure;
and
allowing the surface level of the solution having
an increased concentration of solute to reach
equilibrium in the channel below the surface of the
solution and below the first enclosure, and then discontinuing the pumping of the solution out of the
first enclosure, and allowing the solution to flow out
of the first enclosure into the channel by the force of
gravity.
PCT/US1999/026025 1999-04-07 1999-11-30 Seawater pressure-driven desalinization apparatus and method with gravity-driven brine return WO2000059612A1 (en)

Priority Applications (4)

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AU18128/00A AU1812800A (en) 1999-04-07 1999-11-30 Seawater pressure-driven desalinization apparatus and method with gravity-drivenbrine return
AT99961580T ATE291482T1 (en) 1999-04-07 1999-11-30 PRESSURE-OPERATED SEAWATER DESALINATION DEVICE AND METHOD WITH GRAVITATION-OPERATED CAUSE RECYCLING
DE69924411T DE69924411T2 (en) 1999-04-07 1999-11-30 PRESSURE-BASED SEA-WATER DISCHARGE DEVICE AND METHOD WITH GRAVITY-DRIVEN LAUGHTER RETURN
EP99961580A EP1214137B1 (en) 1999-04-07 1999-11-30 Seawater pressure-driven desalinization apparatus and method with gravity-driven brine return

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US28765899A 1999-04-07 1999-04-07
US09/287,658 1999-04-07

Publications (1)

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EP (1) EP1214137B1 (en)
AT (1) ATE291482T1 (en)
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AU1812800A (en) 2000-10-23
US20020125190A1 (en) 2002-09-12
US6656352B2 (en) 2003-12-02
EP1214137B1 (en) 2005-03-23
US20040108272A1 (en) 2004-06-10
US6800201B2 (en) 2004-10-05
US6348148B1 (en) 2002-02-19
DE69924411D1 (en) 2005-04-28
EP1214137A4 (en) 2003-06-18
ATE291482T1 (en) 2005-04-15
DE69924411T2 (en) 2006-03-09
EP1214137A1 (en) 2002-06-19

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