WO2000066506A9 - Highly tetrahedral amorphous carbon coating on glass - Google Patents
Highly tetrahedral amorphous carbon coating on glassInfo
- Publication number
- WO2000066506A9 WO2000066506A9 PCT/US2000/011711 US0011711W WO0066506A9 WO 2000066506 A9 WO2000066506 A9 WO 2000066506A9 US 0011711 W US0011711 W US 0011711W WO 0066506 A9 WO0066506 A9 WO 0066506A9
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon
- glass
- layer
- substrate
- coating
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 137
- 239000011248 coating agent Substances 0.000 title claims abstract description 132
- 239000011521 glass Substances 0.000 title claims abstract description 126
- 229910003481 amorphous carbon Inorganic materials 0.000 title claims abstract description 50
- 239000000758 substrate Substances 0.000 claims abstract description 127
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims abstract description 57
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 44
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 21
- 238000005260 corrosion Methods 0.000 claims abstract description 13
- 230000007797 corrosion Effects 0.000 claims abstract description 13
- 150000002500 ions Chemical class 0.000 claims description 31
- 238000000151 deposition Methods 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 230000008021 deposition Effects 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 14
- 238000002834 transmittance Methods 0.000 claims description 14
- 239000005361 soda-lime glass Substances 0.000 claims description 9
- 238000010884 ion-beam technique Methods 0.000 claims description 7
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 239000005388 borosilicate glass Substances 0.000 claims description 3
- 230000007774 longterm Effects 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 99
- 239000000463 material Substances 0.000 description 13
- 150000001721 carbon Chemical group 0.000 description 10
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical group C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 10
- 229910003460 diamond Inorganic materials 0.000 description 10
- 239000010432 diamond Substances 0.000 description 10
- 125000004429 atom Chemical group 0.000 description 8
- 238000005137 deposition process Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 5
- -1 carbon ions Chemical class 0.000 description 5
- 229910003472 fullerene Inorganic materials 0.000 description 5
- 238000009396 hybridization Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000011253 protective coating Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000005328 architectural glass Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002180 anti-stress Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000002153 concerted effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 238000010849 ion bombardment Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229960003753 nitric oxide Drugs 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3634—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing carbon, a carbide or oxycarbide
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
- B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
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- B08B17/06—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement
- B08B17/065—Preventing deposition of fouling or of dust by giving articles subject to fouling a special shape or arrangement the surface having a microscopic surface pattern to achieve the same effect as a lotus flower
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- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
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- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
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- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
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- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
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- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
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- B32B17/1033—Laminated safety glass or glazing containing temporary protective coatings or layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
- B60S1/00—Cleaning of vehicles
- B60S1/02—Cleaning windscreens, windows or optical devices
- B60S1/54—Cleaning windscreens, windows or optical devices using gas, e.g. hot air
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
- B60S1/00—Cleaning of vehicles
- B60S1/02—Cleaning windscreens, windows or optical devices
- B60S1/56—Cleaning windscreens, windows or optical devices specially adapted for cleaning other parts or devices than front windows or windscreens
- B60S1/58—Cleaning windscreens, windows or optical devices specially adapted for cleaning other parts or devices than front windows or windscreens for rear windows
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3441—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising carbon, a carbide or oxycarbide
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/3411—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
- C03C17/3429—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
- C03C17/3464—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a chalcogenide
- C03C17/347—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising a chalcogenide comprising a sulfide or oxysulfide
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/0075—Cleaning of glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/26—Deposition of carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/28—Other inorganic materials
- C03C2217/282—Carbides, silicides
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/76—Hydrophobic and oleophobic coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/151—Deposition methods from the vapour phase by vacuum evaporation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/31—Pre-treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/268—Monolayer with structurally defined element
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Definitions
- This invention relates to a diamond-like carbon (DLC)
- this invention relates to a highly tetrahedral
- Soda inclusive glasses are known in the art .
- Soda lime silica glass for example, is used for
- silica glass known in the art .
- conventional soda inclusive glasses are susceptible to environmental corrosion which occurs when
- Na sodium diffuses from or leaves the glass interior.
- DLC diamond like carbon
- the DLC of the ⁇ 353 patent is deposited in a less than efficient manner for certain embodiments of this invention.
- Strength of glass is in part controlled by the growth of cracks that penetrate the glass. Water, in these cracks, reacts with glass and causes it to
- An object of this invention is to provide a coated
- article that can shed water e.g. automotive windshield,
- Another object of this invention is to provide a system
- Another object of this invention is to provide a coated
- Another object of this invention is to provide a coated
- Another object is to provide a barrier layer with no
- Another object of this invention is to provide a coated
- Another object of this invention is to provide a glass
- Another object of this invention is to provide a DLC coating on a substrate, wherein the coating includes
- a DLC coating may have therein
- this invention fulfills certain of
- coated glass comprising:
- a glass substrate including at least about 5% by weight soda/Na 2 0; an amorphous carbon layer provided on the glass
- said amorphous carbon layer includes
- amorphous carbon layer has more sp 3 carbon- carbon bonds than sp 2 carbon-carbon bonds .
- this invention fulfills certain of the above described needs in the art by providing a
- coated glass comprising: a soda inclusive glass substrate comprising, on a weight basis, from about 60-80% ⁇ i0 2 , from about 10-20% Na 2 0, from about 0-16% CaO, from about 0-10% K 2 0, from about 0-10% MgO, and from about 0-5% Al 2 0 3 ; and
- the glass substrate is a soda lime silica float glass substrate.
- a layer within the DLC coating has a density of from about 2.4 to 3.4 gm/cm 3 , most preferably from about 2.7 to 3.0 gm/cm 3 .
- the tetrahedral amorphous carbon layer has the aforesaid density range and includes at least about 70% sp 3 carbon-carbon bonds, and most preferably
- the DLC coating includes a top layer (e.g. from about 2 to 8 atomic layers, or less than about 20 A) that is less dense than other portions of the DLC coating, thereby providing a solid lubricant portion at
- Another advantage of this invention is that the temperature of the glass substrate is less than about 200°
- This invention further fulfills the above described
- a window having a substrate and a highly tetrahedral amorphous carbon layer thereon
- the substrate is or includes at least one of
- Figure 1 is a side cross sectional view of a coated article according to an embodiment of this invention, wherein a substrate is provided with a DLC coating including
- Figure 2 is a side cross sectional view of a coated
- a highly tetrahedral amorphous carbon DLC coating is provided on and in contact with a substrate .
- Figure 3 is a side cross sectional view of a coated article according to yet another embodiment of this
- Figure 4 illustrates an exemplar sp 3 carbon atom hybridization bond.
- Figure 5 illustrates an exemplar sp 2 carbon atom hybridization bond.
- Figure 6 illustrates exemplar sp hybridizations of a
- Figure 7 is a side cross sectional view of carbon ions penetrating the substrate or DLC surface so as to strongly bond a DLC layer according to any embodiment herein.
- Figure 8 is a side cross sectional view of a coated glass substrate according to an embodiment of this
- Figure 1 is a side cross sectional view of a coated
- DLC coating 3 in the Fig. 1 embodiment
- ta-C highly tetrahedral amorphous carbon
- Coating 3 further includes at least one
- interfacing layer 8 directly adjacent substrate 1, where layer 8 has a lesser density and a lesser percentage of sp 3 carbon-carbon bonds than ta-C layer 7. Even though layer 8
- interfacing layer 8 differs from layer 7 in these manner (s), interfacing layer 8
- coating 3 may or may not qualify as ta-C with a density of at least about 2.4 gm/cm 3 , as described below. It is noted that in certain embodiments, coating 3 may include multiple ta-C
- Layers 7 and 8 of the coating may be formed in a continuous or non-continuous
- Figure 2 is a side cross sectional view of a coated
- substantially the entire DLC coating 3 is made up of highly tetrahedral amorphous carbon (ta-C), similar to layer 7, -having -a—density-of at least about 2.4 grams per cubic
- centimeter and a high percentage e.g. at least about 35%
- ta-C layer 7 from the Fig. 1 embodiment forms the entirety of DLC coating 3 in the Fig. 2 embodiment.
- DLC coating 3 in the Fig. 2 embodiment may or may not have equal
- a low-E or other coating 5 is
- DLC coating 3 i.e. the DLC coating of either the Fig. 1 or Fig. 2 embodiment
- DLC coating 3 is still on substrate 1 in the Fig. 3 embodiment, along with a ta-C portion 7 of coating 3.
- substrate 1 supports DLC coating 3 or any layer (e.g. 7, 8) thereof, regardless of
- protective coating 3 may be provided directly on
- coating 3 so that coating 3 (of either the Fig. 1 or Fig. 2
- embodiments is located between coating (s) 5 and substrate 1.
- a DLC coating 3 may be provided
- coatings that may be used as low-E or other coating (s) 5,
- coating (s) may also be used as coating (s) 5.
- tetrahedral amorphous carbon (ta-C) layer (s) 7 is a special
- DLC diamond-like carbon
- C layer (s) 7 has at least about 35% sp 3 carbon-carbon bonds
- the amounts of sp 3 bonds may be
- Ta-C layer 7 forms the entirety of DLC coating 3 in the
- ta-C layer 7 forms only a portion of
- embodiment sometimes has a density less than about 2.4 grams
- DLC coating 3 has
- embodiment has a density of at least about 2.4 grams per
- layer 7 herein refers to both layer-7 -as ⁇ :il-lustrated in the -Fig-. 1 -embodiment as well as
- some sp 2 and/or sp 3 carbon-carbon bonds are provided in fissures or cracks in a surface (e.g. top surface) of the glass substrate, or may penetrate the glass surface of
- Figure 4 illustrates an exemplar sp 3 carbon-carbon or C-C bond (i.e. carbon to carbon diamond like bond) in coating 3
- Figure 4 an exemplar
- ta-C limits sodium diffusion from the substrate
- Coating (s) 3, and layer (s) 7, 8, also strengthen the glass article, reduce stress at the bonding surfaces between coating 3 and substrate 1, and provide a solid lubricant
- Coating (s) 3 and/or layer 7 may includes a top layer portion (e.g. the top 3 to 15 A) that
- Ta-C layer 7 also provides resistance to water/moisture entering or coming into substrate 1. Coating 3, and thus ta-C layer 7, are preferably formed/deposited continuously across glass substrate 1, absent any pinholes
- glass substrate is deposited at an ion energy that allows
- Advantages associated with certain embodiments of this invention include: (i) coated window articles that can shed water in different environments (e.g. automotive windows
- the inner surface of automotive window substrates 1 may be coated with coating 3 in accordance with any of the Fig. 1-3
- coating 3 is at least about 70% transparent to or transmissive of visible light rays, preferably at least about 80%, and most preferably at least about 90% transparent to visible light rays.
- DLC coating 3 (and thus layer 7 in the Fig. 2 embodiment) may be from about 30 to 3,000 A
- glass substrate 1 may be from about 1.5 to 5.0 mm thick, preferably from about 2.3 to 4.8 mm thick, and most
- Ta-C layer 7 in certain embodiments, has a density of at least about 2.4 grams per cubic centimeter, more preferably from about 2.4 to 3.4 gm/cm 3 , and most preferably from about 2.7 to 3.0
- Substrate 1 includes soda or Na 2 0 in certain embodiments of this invention.
- ta-C layer (s) 7 minimize the amount of soda that can reach the surface of
- substrate 1 includes, on a weight basis, from about 60-80% Si0 2 , from about 10-20% Na 2 0, from about 0-16%
- CaO from about 0-10% K 2 0, from about 0-10% MgO, and from
- substrate 1 is about 0-5% A1 2 0 3 . In certain other embodiments, substrate 1
- soda lime silica glass including, on a weight basis
- substrate 1 is soda lime silica glass including, by weight, from about 70-74%
- Si0 2 from about 12-16% Na 2 0, from about 7-12% CaO, from about 3.5 to 4.5% MgO, from about 0 to 2.0% A1 2 0 3 , from
- embodiments may have a density of from about 150 to 160
- pounds per cubic foot preferably about 156
- an average short term bending strength of from about 6,500 to 7,500 psi
- any combination thereof (room temperature to 350 degrees C) of from about 4.7 to 5.0 x 10" 6 degrees F. In certain embodiments, any combination thereof.
- any such aforesaid glass substrate 1 may be, for
- colorant (s) are provided in the glass.
- substrate 1 may be of borosilicate glass, or of
- the substrate 1 may include from about 75-85%
- Si0 2 from about 0-5% Na 2 0, from about 0 to 4% Al 2 0 3 , from
- an automotive window is provided.
- substrate 1 may include first and second glass sheets of any
- window e.g. automotive windshield, residential window, commercial window, automotive side window, automotive backlite or back window, etc.
- window e.g. automotive windshield, residential window, commercial window, automotive side window, automotive backlite or back window, etc.
- window e.g. automotive windshield, residential window, commercial window, automotive side window, automotive backlite or back window, etc.
- coating 3 and/or ta-C layer 7 may have an average hardness of from about 30-80 GPa (most
- coating 3 and/or layers 7, 8 thereof may be any hardness and density of coating 3 and/or layers 7, 8 thereof. It is noted that the hardness and density of coating 3 and/or layers 7, 8 thereof may be any hardness and density of coating 3 and/or layers 7, 8 thereof.
- substrate 1 of any of the aforesaid materials is coated with at least DLC coating 3 according to any of the
- the resulting coated article has the following characteristics in certain embodiments: visible transmittance (111. A) greater than about 60% (preferably
- amorphous carbon (ta-C) form 7 of DLC utilized in certain
- Ta-C 7 is
- bonds preferably at least about 70% and most preferably at
- ta-C also includes sp 2 C-C
- layer depends for example on the carbon ion energy used during deposition of coating 3 and/or layers 7 and 8.
- sp 3 bonds discussed herein are sp 3 carbon-carbon bonds which result in a high density coating 3 and/or 7 and are not sp 3 carbon-hydrogen bonds which do not
- ta-C layers 7 herein contain amounts of H (up to about 4%) which
- Ta-C films also have some fraction of sp 2 or graphic bonding.
- the spatial distribution of trigonal (sp 2 ) and tetrahedral carbon atoms may determine the bonding
- This diamond-like bonding confers upon ta-C 7 properties which are unrivaled by other forms of so called DLC which have lower densities and/or greater proportion of
- Ta-C 7 has high density (at least about 2.4 grams per
- the top surface of substrate 1 is preferably cleaned by way
- Oxygen gas physically cleans the surface due to its atomic weight of from about 28 - 40 amu, most preferably about 32.
- Substrate 1 may also be cleaned by,
- This cleaning may utilize oxygen and/or carbon atoms, and can be at an ion energy of from about 800 to 1200 eV, most preferably about 1,000 eV.
- carbon ions may be energized to form a stream from plasma toward substrate 1 so that carbon from the ions is deposited on substrate 1.
- acetylene feedstock gas (C 2 H 2 ) is used to prevent or minimize polymerization and to obtain an appropriate energy to allow the ions to penetrate the substrate 1 surface and subimplant therein, thereby causing coating 3 atoms to intermix with
- Impact energy of ions for the bulk of coating 3 may be from about 100 to
- the energetic carbon ions may be- within_a range to promote formation of the desired lattice structure, such bonds in an
- interfacing portion (e.g. layer 8 in the Fig. 1 embodiment) of coating 3 apparently being formed at least in part by subimplantation into the substrate as shown in Figure 7.
- the stream may be optionally composed of ions having
- Coating 3, and especially layer 7, are preferably free of pinholes, to achieve satisfactory water repulsion and suppression of soda diffusion.
- the C-C sp 3 bonding is preferably formed by having a predetermined range of ion energy prior to reaching substrate 1, or prior to reaching ta-C growing on the
- the optimal ion energy window for ta-C layer 7 formation in the Fig. 1 and 2 embodiments is from about 100-
- 200 eV (preferably from about 100-150 eV, and most
- films 7 i.e. layer 3 in the Fig. 2 embodiment
- Such stress can reach as high as 10 Gpa and can potentially cause delamination from
- the plasma ion beam source enables ion energy to be controlled within different ranges in an industrial process
- the first 1-40% thickness (preferably the first 1-20% and most preferably the first 5-10% thickness) 8 of coating 3 is deposited on substrate 1 using high anti-stress energy levels of from
- DLC coating 3 is 100 A thick.
- the first 10 A layer 8 of coating 3 i.e. interfacing portion
- interfacing layer 8 only C ions are used in the deposition of interfacing layer 8, with the graded
- composition interface being mainly ⁇ iC.
- This interface 8 between substrate 1 and coating 3 improves adhesion of coating 3 to substrate 1 and the gradual composition change
- Layer 8 of DLC coating 3 may or may not have a density of at least about 2.4 grams per cubic
- centimeter in different embodiments, and may or may not have
- the ion energy is gradually or quickly decreased to ⁇ luu to 15u eV for the remainder [may be either ta-C or ta-C:H] 7 of coating 3 so
- layer 7 has a higher density and a higher percentage of sp 3 C-C bonds than layer 8.
- ta-C coating 3 in Figs. 1-3 has different densities and different
- coating 3 is a highly reflective material.
- tetrahedral ta-C layer 7 having a density of at least about 2.4 grams per cubic centimeter and at least about 35% sp 3 .
- the highly tetrahedral ta-C portion is the portion furthest
- CH 4 may be used as a feedstock
- a glass substrate has tiny cracks or microcracks defined therein. These cracks may weaken glass by orders of magnitude, especially when water seeps therein and ruptures
- amorphous carbon atoms and/or networks of layer 7 or 8 fill in or collect in these small cracks because of the small size of carbon atoms (e.g. less
- the nano cracks in the glass surface shown in Figure 8 may sometimes be from about 0.4 nm to 1 nm in width. The inert nature and size of the carbon atoms in these nonocracks will prevent water from attacking bonds at
- Tips 14 of these cracks are, typically, from about 0.5 to 50 nm below the
- the top surface of layers 7 and/or 8 remains smooth and/or approximately flat within about less
- Carbon has the ability to form structures based on
- carbon atom is tetrahedrally bonded to four other carbon
- diamond is a macromolecule (with entirely covalent bonds) give diamond unique physical properties: high atomic density, transparency, extreme hardness, exceptionally high thermal conductivity and extremely high electrical
- fullerenes formed entirely of carbon in the sp 2 hybridised state.
- Each fullerenes C n consists of 12
- amorphous carbon there exists a class of carbon in the metastable state without any long range order. Material properties change when using different deposition
- a-C amorphous carbon
- Amorphous materials such as layer (s) 3, 7 and 8, are metastable solids. In an amorphous solid there exists a set of equilibrium positions about which atoms oscillate. The atoms in an amorphous material are often extended into a
- the sp 3 /sp 2 C-C bonded fraction or percentage (%) e.g. in a vacuum arc deposition technique or techniques used in the * 477 patent or
- tetrahedral amorphous carbon (ta-C)
- automotive windshields automotive back windows, automotive side windows, architectural glass, IG glass units, residential or commercial windows, and the like.
- a layer of non- porous tungsten disuifide (WS 2 ) 12 may be provided on top of
- Layer 12 (e.g. see Figure 8) may be applied by plasma spraying to a thickness of from about 300 to 10,000 A.
- WS 2 layer 12 is removeable in certain embodiments.
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000615344A JP5097317B2 (en) | 1999-05-03 | 2000-05-01 | Tetrahedral amorphous carbon coating on glass |
CA002368471A CA2368471C (en) | 1999-05-03 | 2000-05-01 | Highly tetrahedral amorphous carbon coating on glass |
AU48113/00A AU4811300A (en) | 1999-05-03 | 2000-05-01 | Highly tetrahedral amorphous carbon coating on glass |
DE60002060T DE60002060T2 (en) | 1999-05-03 | 2000-05-01 | HIGH TEDRAEDRIC AMORPHOUS CARBON FILMS ON GLASS |
BRPI0008391-7A BR0008391B1 (en) | 1999-05-03 | 2000-05-01 | coated glass, process for producing a coated glass article and automotive window. |
PL00356132A PL195615B1 (en) | 1999-05-03 | 2000-05-01 | Highly tetrahedral amorphous carbon coating on glass |
AT00930259T ATE236860T1 (en) | 1999-05-03 | 2000-05-01 | HIGH TETRAHEDRAL AMORPHOUS CARBON FILM ON GLASS |
EP00930259A EP1177156B1 (en) | 1999-05-03 | 2000-05-01 | Highly tetrahedral amorphous carbon coating on glass |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/303,548 | 1999-05-03 | ||
US09/303,548 US6261693B1 (en) | 1999-05-03 | 1999-05-03 | Highly tetrahedral amorphous carbon coating on glass |
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WO2000066506A1 WO2000066506A1 (en) | 2000-11-09 |
WO2000066506B1 WO2000066506B1 (en) | 2001-01-25 |
WO2000066506A9 true WO2000066506A9 (en) | 2002-02-21 |
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Application Number | Title | Priority Date | Filing Date |
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PCT/US2000/011711 WO2000066506A1 (en) | 1999-05-03 | 2000-05-01 | Highly tetrahedral amorphous carbon coating on glass |
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US (6) | US6261693B1 (en) |
EP (2) | EP1177156B1 (en) |
JP (1) | JP5097317B2 (en) |
AT (2) | ATE300506T1 (en) |
AU (1) | AU4811300A (en) |
BR (1) | BR0008391B1 (en) |
CA (1) | CA2368471C (en) |
CZ (1) | CZ20013760A3 (en) |
DE (2) | DE60021627T2 (en) |
ES (2) | ES2243829T3 (en) |
HU (1) | HUP0200949A2 (en) |
PL (1) | PL195615B1 (en) |
WO (1) | WO2000066506A1 (en) |
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FR2776540B1 (en) * | 1998-03-27 | 2000-06-02 | Sidel Sa | BARRIER-EFFECT CONTAINER AND METHOD AND APPARATUS FOR ITS MANUFACTURING |
US6964731B1 (en) * | 1998-12-21 | 2005-11-15 | Cardinal Cg Company | Soil-resistant coating for glass surfaces |
US6660365B1 (en) * | 1998-12-21 | 2003-12-09 | Cardinal Cg Company | Soil-resistant coating for glass surfaces |
US6974629B1 (en) * | 1999-08-06 | 2005-12-13 | Cardinal Cg Company | Low-emissivity, soil-resistant coating for glass surfaces |
US6475573B1 (en) * | 1999-05-03 | 2002-11-05 | Guardian Industries Corp. | Method of depositing DLC inclusive coating on substrate |
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US6461731B1 (en) * | 1999-05-03 | 2002-10-08 | Guardian Industries Corp. | Solar management coating system including protective DLC |
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US6303225B1 (en) * | 2000-05-24 | 2001-10-16 | Guardian Industries Corporation | Hydrophilic coating including DLC on substrate |
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US6740211B2 (en) | 2001-12-18 | 2004-05-25 | Guardian Industries Corp. | Method of manufacturing windshield using ion beam milling of glass substrate(s) |
US6660340B1 (en) * | 2000-02-08 | 2003-12-09 | Epion Corporation | Diamond-like carbon film with enhanced adhesion |
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