WO2000079051A1 - Preservation of paper and textile materials - Google Patents

Preservation of paper and textile materials Download PDF

Info

Publication number
WO2000079051A1
WO2000079051A1 PCT/US2000/016234 US0016234W WO0079051A1 WO 2000079051 A1 WO2000079051 A1 WO 2000079051A1 US 0016234 W US0016234 W US 0016234W WO 0079051 A1 WO0079051 A1 WO 0079051A1
Authority
WO
WIPO (PCT)
Prior art keywords
paper
solutions
fluoropolymer
teflon
inches
Prior art date
Application number
PCT/US2000/016234
Other languages
French (fr)
Inventor
Andrew Kelsey Birchenall
Original Assignee
E.I. Du Pont De Nemours And Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by E.I. Du Pont De Nemours And Company filed Critical E.I. Du Pont De Nemours And Company
Priority to JP2001505390A priority Critical patent/JP2003502531A/en
Priority to IL14618900A priority patent/IL146189A0/en
Priority to US10/031,998 priority patent/US6800176B1/en
Priority to AU54859/00A priority patent/AU5485900A/en
Priority to EP00939840A priority patent/EP1190140A1/en
Priority to KR1020017016148A priority patent/KR20020047051A/en
Priority to CA002372697A priority patent/CA2372697A1/en
Publication of WO2000079051A1 publication Critical patent/WO2000079051A1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/08—After-treatment with organic compounds macromolecular
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
    • B44D7/00—Preserving paintings, e.g. by varnishing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/08—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with halogenated hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D06M15/3335—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol fluorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D06M15/353—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/18—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00 of old paper as in books, documents, e.g. restoring

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)

Abstract

A method is disclosed for strengthening a paper or textile article. The method involves (a) applying to the article a solution of an amorphous fluoropolymer in a perfluoroalkane solvent; and (b) drying the article. Also disclosed are strengthened paper and textile articles which include a fibrous paper or textile substrate, and amorphous fluoropolymer interconnecting fibers of the substrate.

Claims

Minneapolis, MN). In general, the perfluoroalkane solvents used in these solutions are not considered aggressive to many paper and textile articles. Most inks will not dissolve in perfluorinated solvents. Similarly, many substrates are unaffected by exposure to these solvents. The fluoropolymer solutions may be applied to the fibrous articles by common coating methods, including but not limited to spray application, dipping and brushing. After application of the solutions, the articles can be dried by conventional methods (e.g., air or vacuum drying).
EXAMPLES Fluoropolymer Solution Preparation:
Teflon® AF solutions were used in the examples below, and were used as received from E. I. du Pont de Nemours and Company, Wilmington, DE, unless otherwise noted. To dilute the Teflon® AF2130, solvent (FC-75, 3M, Minneapolis, MN) was weighed and was placed into a container, with the calculated amount of Teflon® AF2130 added to the solvent. The samples were mixed before use.
EXAMPLE 1 Paper Treatment Several types of paper, including newsprint and copier paper were dipped for about 30 seconds into several Teflon® AF solutions, having concentrations between 1 and 6% solids by weight, such that about half the sheet was impregnated with the solution. The papers were removed from the solution and dried for about 30 minutes. The entire sheets of paper were immersed in water at room temperature. The treated portion emerged in undamaged condition while the untreated paper fell apart. No dissolution or blurring of ink was observed in the treated portion of the newsprint.
EXAMPLE 2 Strength Testing of Paper The strength of treated paper was compared to that of an untreated paper. Strips of paper (20 pound White Wove, Gilbert, Inc., Menasha, WI) about 1 inch wide, 8 inches long, and 0.004 inches thick, were immersed for 10 minutes in solutions with varying concentrations of fluoropolymer. The strips were removed and dried, leaving a fluoropolymer deposit in the paper. The tensile strengths of the strips were measured using a model 1122 Instron test machine (Instron Corp., Canton, MA) and ASTM Method D 828 procedures (the test bars were held in grips with a separation of 5 inches, and the cross head speed was 2 inches/minute). The fluoropolymer treatment increased the strength of the paper. The results are shown in Table 1 below, as well as in Figure 1.
PCT/US2000/016234 1999-06-17 2000-06-13 Preservation of paper and textile materials WO2000079051A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2001505390A JP2003502531A (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials
IL14618900A IL146189A0 (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials
US10/031,998 US6800176B1 (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials
AU54859/00A AU5485900A (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials
EP00939840A EP1190140A1 (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials
KR1020017016148A KR20020047051A (en) 1999-06-17 2000-06-13 Preservation of Paper and Textile Materials
CA002372697A CA2372697A1 (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13965199P 1999-06-17 1999-06-17
US60/139,651 1999-06-17

Publications (1)

Publication Number Publication Date
WO2000079051A1 true WO2000079051A1 (en) 2000-12-28

Family

ID=22487669

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/016234 WO2000079051A1 (en) 1999-06-17 2000-06-13 Preservation of paper and textile materials

Country Status (7)

Country Link
EP (1) EP1190140A1 (en)
JP (1) JP2003502531A (en)
KR (1) KR20020047051A (en)
AU (1) AU5485900A (en)
CA (1) CA2372697A1 (en)
IL (1) IL146189A0 (en)
WO (1) WO2000079051A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100453205B1 (en) * 2001-07-11 2004-10-15 주식회사 흥인화학 A Long Term Preservative For Cellulose Materials Using A Mixture Of Fluorine Compounds Having Low Molecular Weight As A Carrier

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100970953B1 (en) * 2009-07-06 2010-07-20 (주)노바텍인코퍼레이션 Writable decoration wallpaper

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1007981A (en) * 1961-04-17 1965-10-22 William Herbert Langwell Improvements in or relating to the preservation of documents for storage
WO1992010532A1 (en) * 1990-12-07 1992-06-25 Vascutek Limited Fluorinating polymer surfaces
US5409736A (en) * 1993-08-31 1995-04-25 Preservation Technologies, Inc. Deacidification of cellulose based materials using perfluorinated carriers
WO1997019224A1 (en) * 1995-11-23 1997-05-29 Institut für Neue Materialien Gemeinnützige GmbH Process for preserving paper

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1007981A (en) * 1961-04-17 1965-10-22 William Herbert Langwell Improvements in or relating to the preservation of documents for storage
WO1992010532A1 (en) * 1990-12-07 1992-06-25 Vascutek Limited Fluorinating polymer surfaces
US5409736A (en) * 1993-08-31 1995-04-25 Preservation Technologies, Inc. Deacidification of cellulose based materials using perfluorinated carriers
WO1997019224A1 (en) * 1995-11-23 1997-05-29 Institut für Neue Materialien Gemeinnützige GmbH Process for preserving paper

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100453205B1 (en) * 2001-07-11 2004-10-15 주식회사 흥인화학 A Long Term Preservative For Cellulose Materials Using A Mixture Of Fluorine Compounds Having Low Molecular Weight As A Carrier

Also Published As

Publication number Publication date
JP2003502531A (en) 2003-01-21
KR20020047051A (en) 2002-06-21
CA2372697A1 (en) 2000-12-28
EP1190140A1 (en) 2002-03-27
AU5485900A (en) 2001-01-09
IL146189A0 (en) 2002-07-25

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