WO2001034730A1 - Multiple feed process for the production of propylene - Google Patents
Multiple feed process for the production of propylene Download PDFInfo
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- WO2001034730A1 WO2001034730A1 PCT/US2000/031138 US0031138W WO0134730A1 WO 2001034730 A1 WO2001034730 A1 WO 2001034730A1 US 0031138 W US0031138 W US 0031138W WO 0134730 A1 WO0134730 A1 WO 0134730A1
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G51/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more cracking processes only
Definitions
- This invention relates to a process to produce propyiene from a hydrocarbon feed stream containing Cs's and/or C ⁇ 's, preferably a naphtha feed stream, where multiple feeds are used to feed portions of the feed stream into different portions of the reactor, or into different reactors.
- Propyiene is an important chemical of commerce.
- propyiene is largely derived from selected petroleum feed materials by procedures such as steam cracking which also produces high quantities of other materials.
- procedures such as steam cracking which also produces high quantities of other materials.
- propyiene which result in uncertainties in feed supplies, rapidly escalating raw material costs and similar situations which are undesirable from a commercial standpoint.
- economics often favor using feedstocks or operating conditions in steam cracking which produce less propyiene provided an effective process for forming propyiene was available.
- Methods are known for the conversion of higher hydrocarbons to reaction mixtures comprised of the C2 and C3 lighter olefins.
- EP 0 109 059 A and EP 0 109060 A provide illustrative disclosures of conditions and catalysts which are effective for the conversion of higher hydrocarbons such as butenes to the lighter olefins.
- USSN 07/343,097 likewise is believed to provide a detailed disclosure of prior methods for the production of lower olefins from higher hydrocarbon feed materials. In certain instances, it would be very advantageous to provide means for still further improving yields of propyiene which result from the conversion of less expensive higher hydrocarbon feed materials.
- Prior methods to produce propyiene include:
- U.S. Patent No. 4,830,728 discloses a fluid catalytic cracking (FCC) unit that is operated to maximize olefin production.
- the FCC unit has two separate risers into which a different feed stream is introduced.
- the operation of the risers is designed so that a suitable catalyst will act to convert a heavy gas oil in one riser and another suitable catalyst will act to crack a lighter olefin/naphtha feed in the other riser.
- Conditions within the heavy gas oil riser can be modified to maximize either gasoline or olefin production.
- the primary means of maximizing production of the desired product is by using a specified catalyst.
- U.S. Patent No. 5,069,776 teaches a process for the conversion of a hydrocarbonaceous feedstock by contacting the feedstock with a moving bed of a zeolitic catalyst comprising a zeolite with a pore diameter of 0.3 to 0.7 n , at a temperature above about 500°C and at a residence time less than about 10 seconds. Olefins are produced with relatively little saturated gaseous hydrocarbons being formed. Also, U.S.Patent No. 3,928,172 teaches a process for converting hydrocarbonaceous feedstocks wherein olefins are produced by reacting said feedstock in the presence of a ZSM-5 catalyst. 6. Concurrently pending USSN 09/072,632 discloses a method to improve the yield of propyiene by selecting certain reaction conditions and certain catalysts.
- Thermal and catalytic conversion of hydrocarbons to olefins is an important industrial process producing millions of pounds of olefins each year.
- Catalysts play an important role in more selective conversion of hydrocarbons to olefins.
- SAPO silicoaluminophosphates
- Patent 4.440,871 also provide excellent catalysts for cracking to selectively produce light hydrocarbons and olefins.
- the SAPO molecular sieve has a network of AlO > SiO 4 , and PO 4 tetrahedra linked by oxygen atoms.
- the negative charge in the network is balanced by the inclusion of exchangeable protons or cations such as alkali or alkaline earth metal ions.
- the interstitial spaces or channels formed by the crystalline network enables SAPOs to be used as molecular sieves in separation processes and in catalysis.
- SAPO catalysts mixed with zeolites are known to be useful in cracking of gasoils (U. S. Patent 5,318,696).
- U. S. Patents 5,456,821 and 5,366,948 describe cracking catalysts with enhanced propyiene selectivity which are mixtures of phosphorus treated zeolites with a second catalyst which may be a SAPO or a rare earth exchanged zeolite.
- Rare earth treated zeolite catalysts useful in catalytic cracking are disclosed in U. S. Patents 5,380,690, 5,358,918, 5,326,465, 5232,675 and 4,980,053.
- This invention relates to a process to produce propyiene from a hydrocarbon feed stream comprising C5 and/or C ⁇ components comprising introducing the light portion of the hydrocarbon feed stream into a reactor containing one or more catalysts separately from the heavy portion of the hydrocarbon feed stream, wherein the light portion of the feedstream comprises that portion that boils at 120°C or less, and the heavy portion of the feed stream is that portion left over after the light portion is removed.
- Figures 1 and 2 depict possible configurations for the multiple feeds into one or more reactors.
- a and B are different catalysts.
- This invention particularly relates to a process to produce propyiene from a hydrocarbon feed stream containing Cj and /or C ⁇ components comprising introducing the light portion of the hydrocarbon feed stream into a reactor separately from the heavy portion of the hydrocarbon feed stream, where the light portion is that portion that has a boiling point range of 120 °C or less, more preferably 100 °C or less, even more preferably 80 °C or less.
- the heavy portion of the hydrocarbon feed stream is the portion left over after the light portion has been removed.
- the light portion comprises C5 and/or C ⁇ components.
- the light portion comprises at least 50 weight%, preferably at least 75 weight%, more preferably at least 90 weight%, more preferably at least 98 weight%, of the C5 and/ or C ⁇ components present in the hydrocarbon feed stream, preferably a light cataiytically cracked naphtha feed stream.
- the light portion comprises at least 50 weight%, preferably at least 75 weight%, more preferably at least 90 weight%, more preferably at least 98 weight%, of the C 5 component present in the hydrocarbon feed stream, preferably a light cataiytically cracked naphtha feed stream.
- C 5 and C ⁇ components is meant a hydrocarbon feed stream containing linear, branched or cyclic paraffins, olefins, or aromatics, having 5 or 6 carbon atoms, respectively.
- Examples include pentane, cyclopentene, cyclopentane, cyclohexane, pentene, pentadiene cyclopentadiene, hexene, hexadiene, and benzene.
- the heavy portion of the hydrocarbon feed stream typically includes hydrocarbons having one more carbon than those in the light portion.
- the heavy component comprises hydrocarbons having 7 or more carbon atoms, typically between 7 and 12 carbon atoms. Examples include heptane, heptene, octane, octene, toluene and the like.
- the process of the invention can be used on any hydrocarbon feed stream containing olefins, particularly Cj and / or C ⁇ components which can be separated into light and heavy fractions.
- a cataiytically or thermally cracked naphtha stream is the hydrocarbon feed stream, or fractions thereof.
- Such streams can be derived from any appropriate source, for example, they can be derived from the fluid catalytic cracking (FCC) of gas oils and resids, or from delayed or fluid coking of resids.
- FCC fluid catalytic cracking
- the hydrocarbon feed streams used in the practice of the present invention is derived from the fluid catalytic cracking of gas oils and resids, and are typically rich in olefins and/or diolefins and relatively lean in paraffins.
- Preferred cataiytically cracked naphtha streams which are suitable for the practice of this invention include those streams or fractions thereof boiling in the naphtha range and containing from about 5 weight % to about 70 weight %, preferably from about 10 weight % to about 60 weight %, and more preferably from about 10 to 50 weight % paraffins, and from about 10 weight %, preferably from about 20 weight % to about 70 weight % olefins.
- the feed may also contain naphthenes and aromatics.
- Naphtha boiling range streams are typically those boiling in the range from about 18°C to 22°C, and preferably from about 18°C to 149°C.
- the catalysts that may be used in the practice of the invention include those which comprise a crystalline zeolite having an average pore diameter less than about 0.7 nanometers (nm), said crystalline zeolite comprising from about 10 weight % to about 50 weight % of the total fluidized catalyst composition. It is preferred that the crystalline zeolite be selected from the family of medium pore size ( ⁇ 0.7 nm) crystalline alumino silicates, otherwise referred to as zeolites.
- the pore diameter also sometimes referred to as effective pore diameter can be measured using standard adsorption techniques and hydrocarbonaceous compounds of known minimum kinetic diameters. See Breck, Zeolite Molecular Sieves, 1974 and Anderson et al., J. Catalysis 58, 114 (1979).
- Medium pore size zeolites that can be used in the practice of the present invention are described in "Atlas of Zeolite Structure Types", eds. W. H. Meier and D.H. Olson, Butterworth-Heineman, Third Edition, 1992.
- the medium pore size zeolites generally have a pore size from about 5 A, to about 7A and include for example, MFI, MFS, MEL, MTW, EUO, MTT, HEU, FER, and TON structure type zeolites (IUPAC Commission of Zeolite Nomenclature).
- Non- limiting examples of such medium pore size zeolites include ZSM-5, ZSM-12, ZSM-22, ZSM-23, ZSM-34, ZSM-35, ZSM-38, ZSM-48, ZSM-50, and silicalite.
- ZSM-5 which is described in U.S. Patent Nos. 3,702,886 and 3,770,614.
- ZSM-11 is described in U.S. Patent No. 3,709,979; ZSM-12 in U.S. Patent No. 3,832,449; ZSM-21 and ZSM-38 in U.S. Patent No. 3,948,758; ZSM-23 in US. Patent No. 4,076,842; and ZSM-35 in U.S. Patent No. 4,016,245.
- the medium pore size zeolites can include "crystalline admixtures" which are thought to be the result of faults occurring within the crystal or crystalline area during the synthesis of the zeolites.
- Examples of crystalline admixtures of ZSM-5 and ZSM-11 are disclosed in U.S. Patent No. 4,229,424.
- the crytalline admixtures are themselves medium pore size zeolites and are not to be confused with physical admixtures of zeolites in which distinct crystals of crystallites of different zeolites are physically present in the same catalyst composite or hydrothermal reaction mixtures.
- the catalysts of the present invention may be held together with an inorganic oxide matrix component.
- the inorganic oxide matrix component binds the catalyst components together so that the catalyst product is hard enough to survive interparticle and reactor wall collisions.
- the inorganic oxide matrix can be made from an inorganic oxide sol or gel which is dried to "glue" the catalyst components together.
- the inorganic oxide matrix is not cataiytically active and will be comprised of oxides of silicon and aluminum. It is also preferred that separate alumina phases be incorporated into the inorganic oxide matrix.
- Species of aluminum oxyhydroxides-g-alumina, boehmite, diaspore, and transitional aluminas such as ⁇ -alumina, ⁇ -alumina, ⁇ -alumina, ⁇ -alumina, ⁇ -alumina, and r- alumina can be employed.
- the alumina species is an aluminum trihydroxide such as gibbsite, bayerite, nordstrandite, or doyelite.
- the matrix material may also contain phosphorous or aluminum phosphate.
- Preferred silicoaluminophosphate (SAPO) catalysts useful in the present invention have a three-dimensional microporous crystal framework structure of PO 2 + , AlO 2 " and Si ⁇ 2 tetrahedral units, and whose essential empirical chemical composition on an anhydrous basis is: m R:(Si[x]Al[y]P[z])O[2 ] wherein "R” represents at least one organic templating agent present in the intracrystalline pore system: "m” represents the moles of "R” present per mole of (Si[x]Al[y]P[z])O2 and has a value of from zero to 0.3, the maximum value in each case depending upon the molecular dimensions of the templating agent and the available void volume of the pore system of the particular silicoaluminophosphate species involved, "x", "y” and “z” represent the mole fractions of silicon, aluminum and phosphorus, respectively, present as tetrahedral oxides, representing the following
- SAPO catalysts include SAPO-11, SAPO-17, SAPO-31, SAPO-34, SAPO-35, SAPO-41, and SAPO-44.
- the catalysts suitable for use in the present invention include, in addition to the SAPO catalysts, the metal integrated aluminophosphates (MeAPO and ELAPO) and metal integrated silicoaluminophosphates (MeAPSO and E1APSO).
- the MeAPO, MeAPSO, E1APO, and EIAPSO families have additional elements included in their framework.
- Me represents the elements Co, Fe, Mg, Mn, or Zn
- El represents the elements Li, Be, Ga, Ge, As, or Ti.
- Preferred catalysts include MeAPO-11, MeAPO-31, MeAPO-41, MeAPSO- 11, MeAPSO-31, and MeAPSO-41, MeAPSO-46, ElAPO-11, E1APO-31, E1APO-41, ElAPSO-11, E1APSO-31, and ElAPSO-41.
- the non-zeolitic SAPO, MeAPO, MeAPSO, E1APO and E1APSO classes of microporus materials are further described in the "Atlas of Zeolite Structure Types" by W. M. Meier, D. H. Olson and C. Baerlocher (4th ed., Butterworths/Intl. Zeolite Assoc. (1996) and "Introduction to Zeolite Science and Practice", H. Van Bekkum, E.M. Flanigen and J.C. Jansen Eds., Elsevier, New York, (1991).).
- SAPO silicoaluminophospha.es
- SAPO-4 and SAPO- 11 which is described in U.S. Patent No. 4,440,871
- chromosilicates gallium silicates
- iron silicates aluminum phosphates (ALPO), such as ALPO-11 described in U.S. Patent No. 4,310,440
- titanium aluminosilicates such as TASO-45 described inEP-ANo. 229,295
- boron silicates described in U.S. Patent No. 4,254,297
- titanium aluminophosphates such as TAPO-11 described in U.S. Patent No. 4,500,651
- iron aluminosilicates include the silicoaluminophospha.es (SAPO), such as SAPO-4 and SAPO- 11 which is described in U.S. Patent No. 4,440,871; chromosilicates; gallium silicates; iron silicates; aluminum phosphates (ALPO),
- the selected catalysts may also include cations selected from the group consisting of cations of Group HA, Group IEIA, Groups IHB to VHBB and rare earth cations selected from the group consisting of cerium, lanthanum- praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof.
- the hydrocarbon feed stream is separated into a light portion and a heavy portion which may be accomplished by conventional separation techniques such as a single flash or multiple flashes or by distillation or fractionation, prior to untroduction to a reactor having the catalyst.
- the reactor may be a fixed bed, a moving bed, a transfer line, a riser or fiuidized bed reactor containing the catalyst.
- the reactions are performed under conditions generally known in the art. For example, preferred conditions include a catalyst contacting temperature in the range of about 400°C to 750°C, more preferably in the range of 450°C to 700°C, most preferably in the range of 500°C to 650°C.
- the catalyst contacting process is preferably carried out at a weight hourly space velocity (WHSV) in the range of about 0.1 Hr"* to about 300 Hr" , more preferably in the range of about 1.0 Hr “1 to about 250 Hr " , and most preferably in the range of about 10 Hr " * to about 100
- WHSV weight hourly space velocity
- Pressure in the contact zone may be from 10-3040 kPa, preferably 101-304 kPa, most preferably about 101 kPa.
- the catalyst to feed (wt/wt) ratio is from about 3 to 12, preferably from about 4 to 10, where catalyst weight is total weight of the catalyst composite.
- steam may be concurrently introduced with the feed stream into the reaction zone, with the steam comprising up to about 50 wt.% of the hydrocarbon feed or in the range of about 10 to 250 mol.%, preferably from about 25 to 150 mol.% steam to hydrocarbon.
- the feed residence time in the reaction zone is preferably less than about 10 seconds, for example from about 1 to 10 seconds.
- the light portion is introduced into the reactor at a point before the point where the heavy portion(s) of the feed stream is introduced into the reactor.
- the heavy portion of the feed stream is introduced into the reactor at a point that is at least 1/3 of the total length of the reaction chamber apart from the point where the light portion is introduced. More preferably, the heavy portion of the feed stream is introduced into the reactor at a point that is at least 1/2 of the total length of the reaction chamber apart from the point where the light portion is introduced. Even more preferably, the heavy portion of the feed stream is introduced into the reactor at a point that is 1/3 to 1/2 of the total length of the reactor chamber apart from the point where the light portion is introduced.
- the multiple portions of the feed stream may be reacted with the same or different catalysts In one embodiment they are reacted with the same catalyst(s). In a preferred embodiment the heavy and light portions of a naphtha feed are reacted over a medium pore silicoaluminophosphate catalyst such as SAPO-11, RE SAPO- 11, SAPO-41, and/or RE SAPO-41.
- a medium pore silicoaluminophosphate catalyst such as SAPO-11, RE SAPO- 11, SAPO-41, and/or RE SAPO-41.
- the light and heavy portions are reacted with different catalysts.
- the light portion of the hydrocarbon feed stream is reacted with silicoaluminophosphates, such as SAPO- 11, SAPO-41, rare earth ion exchanged SAPO-11, and/or rare earth ion exchanged SAPO-41 while the heavy portion is reacted over medium pore crystalline aluminosilicate zeolites such as ZSM-5, ZSM-11, ZSM-23, ZSM-48 and/or ZSM-22.
- the reactor is a staged bed reactor where the first staged bed comprises one or more medium pore crystalline aluminosilicate zeolite catalysts such as ZSM-5, ZSM-11, and/or ZSM-22, and the heavy portion of the feed stream is introduced into the reactor such that it will react with the zeolite catalyst, while the second staged bed comprises medium pore silicoaluminophosphate molecular sieve catalysts such as SAPO-11, SAPO-41, rare earth SAPO-11, and/or rare earth SAPO-41 and the lighter portion of the feed stream is introduced into the reactor such that it will react with the silicoaluminaphosphate catalyst.
- the first staged bed comprises one or more medium pore crystalline aluminosilicate zeolite catalysts such as ZSM-5, ZSM-11, and/or ZSM-22, and the heavy portion of the feed stream is introduced into the reactor such that it will react with the zeolite catalyst
- the second staged bed comprises medium pore silicoaluminophosphate mole
- the catalysts be precoked prior to introduction of feed in order to further improve the selectivity to propyiene. It is also within the scope of this invention that an effective amount of single ring aromatics be fed to the reaction zone to also improve the selectivity of propyiene vs. ethylene.
- the aromatics may be from an external source such as a reforming process unit or they may consist of heavy naphtha recycle product from the instant process.
- the propyiene produced herein preferably comprises at least 80 mole % propyiene, perferably at least 95 mole%, more preferably 97 mole% based upon the total C 3 product produced.
- the processes described herein produce product comprising at least 20 weight % propyiene, preferably at least 25 weight % propyiene, based upon the weight of the total product produced.
- the process described herein is operated in the absence of a superfractionator.
- this invention relates to a process of polymerizing propyiene comprising obtaining propyiene produced by the process described herein and thereafter contacting the propyiene and optionally other olefins, with an olefin polymerization catalyst.
- the olefin polymerization catalyst may comprise one or more Ziegler-Natta catalysts, conventional-type transition metal catalyst, metallocene catalysts, chromium catalysts, or vanadium catalysts.
- Example 1 (comparative In this example, a blend of model compounds consisting of 16.7wt% 1- pentene, 15.6wt% 1-hexene, 11.4wt% 1-heptene, 4.4 wt% 1-octene, 1.3wt% nonene, 1.0wt% 1-decene, 11.7wt% n-pentane, 11.5wt% n-hexane, 5.7wt% n- heptane, 5.0wt% n-octane, 2.5wt% n-nonane, 1.7wt% n-octane, 0.6wt% benzene, 2.8wt% toluene, and 8.1wt% mixed xylenes was prepared to simulate a refinery light cataiytically cracked naphtha.
- This simulated light cat naphtha was then cracked over a commercial ZSM-5 catalyst at 50 hr '1 WHSV and 590° C with 0.2 steam/hydrocarbon.
- the propyiene yield obtained in cracking the simulated light cat naphtha over the commercial ZSM-5 catalyst is 19.8wt% propyiene at 95% purity level in the C 3 stream.
- Ethylene yield was 4.7wt%.
- Example 2 the same blend of model compounds used in Example 1 was cracked over a rare earth SAPO-11 catalyst.
- the propyiene yield obtained in cracking of the simulated light cat naphtha over the rare earth ion exchanged SAPO-11 catalyst is 24.4wt% propyiene at 95% purity level in the C 3 stream.
- Ethylene yield was 5. lwt%.
- a blend consisting of 60.0wt% 1-pentene and 40.0wt% n- pentane was prepared to simulate the C 5 cut of a refinery light cat naphtha.
- This simulated C5 cut and C ⁇ + cuts were cracked separately over the same rare earth ion exchanged SAPO-11 of Example 2.
- the residence time in the second reaction was calculated to simulate the shortened residence time of a feed stream injected at a point further along the reactor than the injection point of the first fraction.
- propyiene yield was 26.0wt% at 95% purity level in the C3 cut. Ethylene yield was improved to 8.6wt%. This example illustrates the benefit of splitting the feed and cracking the feed fractions separately over the cracking catalyst.
- Example 4 (comparative ' )
- a blend of model compounds consisting of 19.0 wt% 1- pentene, 20.4wt% 1-hexene, 15.1wt% 1-heptene, 1.1 wt% 1-octene, 10.4wt% n- pentane, 14.7% n-hexane, 13.5wt% n-heptane, 1.4wt% n-octane, l. lwt% benzene, and 3.3wt% toluene was prepared to simulate another refinery light cat naphtha. This simulated light cat naphtha was then cracked over a commercial ZSM-5 catalyst at 7.2 hr '1 WHSV and 600° C with 1.5 steam/hydrocarbon.
- the propyiene yield obtained in cracking of the simulated light cat naphtha over the commercial ZSM-5 catalyst is 28.4wt% propyiene at 52.2wt% conversion.
- Ethylene yield was 7. lwt%.
- Butylene yield was 14.2wt%.
- Example 5 (comparative) In this example, the same blend of model compounds which was used in
- Example 4 was cracked over a SAPO-11 catalyst at a weight hourly space velocity of 3.1 hr "1 .
- the propyiene yield obtained in cracking of the simulated light cat naphtha over SAPO-11 catalyst is 30.8wt% at 52. lwt% conversion.
- Ethylene yield is 5.6wt%.
- Butylene yield was 12.9wt%.
- a blend consisting of 30%wt% 1-pentene, 32.0wt% % 1- hexene, 16 wt% n-pentane, 22wt% n-hexane was prepared to simulate the Cs/C ⁇ cut of the refinery light cat naphtha used in Example 4
- a blend consisting of 42.5wt % 1-heptene, 3.2wt% 1-octene, 38wt% n-heptane, 3.8wt% n-octane, 3.1wt% benzene, 9.2wt% toluene was prepared to simulate the C 7 + cut of the refinery light cat naphtha used in Example 4.
- This simulated Cs/C ⁇ cut was cracked over SAPO-11 and the and C-7+ cut was cracked over ZSM-5 catalyst.
- the residence time in the second reaction was calculated to simulate the shortened residence time of a feed stream injected at a point further along the reactor than the injection point of the first fraction.
- the combined yields were calculated and tabulated in Table 2.
Abstract
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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AU16033/01A AU1603301A (en) | 1999-11-09 | 2000-11-09 | Multiple feed process for the production of propylene |
MXPA02004641A MXPA02004641A (en) | 1999-11-09 | 2000-11-09 | Multiple feed process for the production of propylene. |
JP2001537429A JP2003513987A (en) | 1999-11-09 | 2000-11-09 | Multi-stage feeding method for propylene production |
CA002390103A CA2390103A1 (en) | 1999-11-09 | 2000-11-09 | Multiple feed process for the production of propylene |
EP00978581A EP1232229A1 (en) | 1999-11-09 | 2000-11-09 | Multiple feed process for the production of propylene |
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US09/436,561 US6339181B1 (en) | 1999-11-09 | 1999-11-09 | Multiple feed process for the production of propylene |
US09/436,561 | 1999-11-09 |
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EP (1) | EP1232229A1 (en) |
JP (1) | JP2003513987A (en) |
CN (1) | CN1387558A (en) |
AU (1) | AU1603301A (en) |
CA (1) | CA2390103A1 (en) |
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US20090112031A1 (en) * | 2007-10-30 | 2009-04-30 | Eng Curtis N | Method for olefin production from butanes using a catalyst |
US20090112032A1 (en) * | 2007-10-30 | 2009-04-30 | Eng Curtis N | Method for olefin production from butanes and cracking refinery hydrocarbons |
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US20090112030A1 (en) * | 2007-10-30 | 2009-04-30 | Eng Curtis N | Method for olefin production from butanes |
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WO2011121613A2 (en) * | 2010-03-31 | 2011-10-06 | Indian Oil Corporation Ltd | A process for simultaneous cracking of lighter and heavier hydrocarbon feed and system for the same |
US8889942B2 (en) | 2010-12-23 | 2014-11-18 | Kellogg Brown & Root Llc | Integrated light olefin separation/cracking process |
CN105163851A (en) | 2013-04-29 | 2015-12-16 | 沙特基础工业公司 | Catalytic methods for converting naphtha into olefins |
KR102564959B1 (en) * | 2018-08-23 | 2023-08-07 | 주식회사 엘지화학 | Method for preparing 1,3-butadiene |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4802971A (en) * | 1986-09-03 | 1989-02-07 | Mobil Oil Corporation | Single riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments |
FR2690922A1 (en) * | 1992-05-07 | 1993-11-12 | Inst Francais Du Petrole | Process and device for catalytic cracking in two successive reaction zones |
EP0921179A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
US6069287A (en) * | 1998-05-05 | 2000-05-30 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3928172A (en) | 1973-07-02 | 1975-12-23 | Mobil Oil Corp | Catalytic cracking of FCC gasoline and virgin naphtha |
EP0109059B1 (en) | 1982-11-10 | 1987-07-15 | MONTEDIPE S.p.A. | Process for converting olefins having 4 to 12 carbon atoms into propylene |
EP0109060B1 (en) | 1982-11-10 | 1987-03-11 | MONTEDIPE S.p.A. | Process for the conversion of linear butenes to propylene |
US4666875A (en) | 1984-11-27 | 1987-05-19 | Union Carbide Corporation | Catalytic cracking catalysts using silicoaluminophosphate molecular sieves |
US4842714A (en) | 1984-11-27 | 1989-06-27 | Uop | Catalytic cracking process using silicoaluminophosphate molecular sieves |
US4830728A (en) | 1986-09-03 | 1989-05-16 | Mobil Oil Corporation | Upgrading naphtha in a multiple riser fluid catalytic cracking operation employing a catalyst mixture |
CN1004878B (en) | 1987-08-08 | 1989-07-26 | 中国石油化工总公司 | Hydrocarbon catalytic conversion method for preparing low-carbon olefin |
GB8904409D0 (en) | 1989-02-27 | 1989-04-12 | Shell Int Research | Process for the conversion of a hydrocarbonaceous feedstock |
US5043522A (en) | 1989-04-25 | 1991-08-27 | Arco Chemical Technology, Inc. | Production of olefins from a mixture of Cu+ olefins and paraffins |
US5026935A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of ethylene from higher hydrocarbons |
US5026936A (en) | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of propylene from higher hydrocarbons |
GB9012725D0 (en) | 1990-06-07 | 1990-08-01 | Exxon Chemical Patents Inc | Process for catalytic conversion of olefins |
US5146028A (en) * | 1990-10-18 | 1992-09-08 | Shell Oil Company | Olefin polymerization catalyst and process of polymerization |
US5366948A (en) | 1991-03-12 | 1994-11-22 | Mobil Oil Corp. | Catalyst and catalytic conversion therewith |
US5456821A (en) | 1991-03-12 | 1995-10-10 | Mobil Oil Corp. | Catalytic conversion with improved catalyst |
US5171921A (en) | 1991-04-26 | 1992-12-15 | Arco Chemical Technology, L.P. | Production of olefins |
CN1030287C (en) | 1992-10-22 | 1995-11-22 | 中国石油化工总公司 | Hydrocarbon conversion catalyst for preparation of high-quality gasoline, propene and butene |
CN1031646C (en) | 1992-10-22 | 1996-04-24 | 中国石油化工总公司 | Method for catalytic conversion of hydrocarbons |
US5318696A (en) | 1992-12-11 | 1994-06-07 | Mobil Oil Corporation | Catalytic conversion with improved catalyst catalytic cracking with a catalyst comprising a large-pore molecular sieve component and a ZSM-5 component |
CN1034223C (en) | 1993-03-29 | 1997-03-12 | 中国石油化工总公司 | Cracking catalyst for processing low-carbon olefines |
FR2715648B1 (en) | 1994-01-31 | 1996-04-05 | Elf Aquitaine | Microporous crystalline solids consisting of aluminophosphates substituted by a metal and optionally by silicon and belonging to the structural type Fau, their syntheses and applications. |
US5846403A (en) * | 1996-12-17 | 1998-12-08 | Exxon Research And Engineering Company | Recracking of cat naphtha for maximizing light olefins yields |
US6093867A (en) * | 1998-05-05 | 2000-07-25 | Exxon Research And Engineering Company | Process for selectively producing C3 olefins in a fluid catalytic cracking process |
US6106697A (en) * | 1998-05-05 | 2000-08-22 | Exxon Research And Engineering Company | Two stage fluid catalytic cracking process for selectively producing b. C.su2 to C4 olefins |
US6118035A (en) * | 1998-05-05 | 2000-09-12 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process from a naphtha/steam feed |
-
1999
- 1999-11-09 US US09/436,561 patent/US6339181B1/en not_active Expired - Fee Related
-
2000
- 2000-11-09 CA CA002390103A patent/CA2390103A1/en not_active Abandoned
- 2000-11-09 AU AU16033/01A patent/AU1603301A/en not_active Abandoned
- 2000-11-09 JP JP2001537429A patent/JP2003513987A/en not_active Withdrawn
- 2000-11-09 WO PCT/US2000/031138 patent/WO2001034730A1/en not_active Application Discontinuation
- 2000-11-09 EP EP00978581A patent/EP1232229A1/en not_active Withdrawn
- 2000-11-09 CN CN00815332.9A patent/CN1387558A/en active Pending
- 2000-11-09 MX MXPA02004641A patent/MXPA02004641A/en unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4802971A (en) * | 1986-09-03 | 1989-02-07 | Mobil Oil Corporation | Single riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments |
FR2690922A1 (en) * | 1992-05-07 | 1993-11-12 | Inst Francais Du Petrole | Process and device for catalytic cracking in two successive reaction zones |
EP0921179A1 (en) * | 1997-12-05 | 1999-06-09 | Fina Research S.A. | Production of olefins |
US6069287A (en) * | 1998-05-05 | 2000-05-30 | Exxon Research And Engineering Co. | Process for selectively producing light olefins in a fluid catalytic cracking process |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101163235B1 (en) | 2003-02-28 | 2012-07-05 | 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 | Fractionating and further cracking a c6 fraction from a naphtha feed for propylene generation |
JP4747089B2 (en) * | 2003-02-28 | 2011-08-10 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | Fractionation and further cracking of C6 fraction from naphtha feedstock for propylene production |
US7270739B2 (en) | 2003-02-28 | 2007-09-18 | Exxonmobil Research And Engineering Company | Fractionating and further cracking a C6 fraction from a naphtha feed for propylene generation |
JP2006519256A (en) * | 2003-02-28 | 2006-08-24 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | Fractionation and further cracking of C6 fraction from naphtha feedstock for propylene production |
US7425258B2 (en) | 2003-02-28 | 2008-09-16 | Exxonmobil Research And Engineering Company | C6 recycle for propylene generation in a fluid catalytic cracking unit |
KR101182981B1 (en) | 2003-02-28 | 2012-09-18 | 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 | Fractionating and further cracking a c6 fraction from a naphtha feed for propylene generation |
US7267759B2 (en) | 2003-02-28 | 2007-09-11 | Exxonmobil Research And Engineering Company | Fractionating and further cracking a C6 fraction from a naphtha feed for propylene generation |
US8049054B2 (en) | 2006-05-19 | 2011-11-01 | Shell Oil Company | Process for the preparation of C5 and/or C6 olefin |
US7932427B2 (en) | 2006-05-19 | 2011-04-26 | Shell Oil Company | Process for the preparation of propylene and industrial plant thereof |
US8168842B2 (en) | 2006-05-19 | 2012-05-01 | Shell Oil Company | Process for the alkylation of a cycloalkene |
US8598398B2 (en) | 2006-05-19 | 2013-12-03 | Shell Oil Company | Process for the preparation of an olefin |
WO2008012218A1 (en) * | 2006-07-26 | 2008-01-31 | Total Petrochemicals Research Feluy | Production of olefins |
TWI401310B (en) * | 2006-07-26 | 2013-07-11 | Total Petrochemicals Res Feluy | Production of olefins |
US8822749B2 (en) | 2007-11-19 | 2014-09-02 | Shell Oil Company | Process for the preparation of an olefinic product |
Also Published As
Publication number | Publication date |
---|---|
CA2390103A1 (en) | 2001-05-17 |
MXPA02004641A (en) | 2002-09-02 |
JP2003513987A (en) | 2003-04-15 |
US6339181B1 (en) | 2002-01-15 |
CN1387558A (en) | 2002-12-25 |
EP1232229A1 (en) | 2002-08-21 |
AU1603301A (en) | 2001-06-06 |
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