WO2001042347A1 - Copolyester containing 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and an ultraviolet light absorbing compound and articles made therefrom - Google Patents
Copolyester containing 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and an ultraviolet light absorbing compound and articles made therefrom Download PDFInfo
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- WO2001042347A1 WO2001042347A1 PCT/US2000/030185 US0030185W WO0142347A1 WO 2001042347 A1 WO2001042347 A1 WO 2001042347A1 US 0030185 W US0030185 W US 0030185W WO 0142347 A1 WO0142347 A1 WO 0142347A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
- C08K5/357—Six-membered rings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Definitions
- the present invention relates to blends of certain copolyesters and an ultraviolet light (UV) absorbing compounds which can be used in connection with sheets, films and other articles as an overlying layer in order to improve the weatherability of an underlying substrate.
- UV ultraviolet light
- Polymer compositions and particularly polymer compositions suitable for thermoforming have found wide spread acceptance and utility in home, commercial and industrial applications. Many polymeric materials have desirable mechanical and/or optical properties to allow their use for applications such as sheeting and formed parts in particular. Such applications range from outdoor signs, vending machine faces, carport covers, skylights, recreational vehicle covers, such as golf cart tops, off-road vehicle windshields such as for so-called ATV's and snowmobiles and the like, etc. It is well known in the art that polyesters are generally not very stable to the effects of UV radiation. This instability is manifest in a number of ways. The color of the polyester turns yellow, the impact resistance of the material is dramatically decreased and the surface glossiness of the article is diminished or becomes hazed. These problems have long limited the use of polyesters and must be solved in order for polyesters to be fit for articles used in an outdoor environment.
- an UVabsorbing compound can be incorporated into the polyester article to retard the loss of impact resistance, yellowness development and haze.
- the UV absorbing compound has an extinction coefficient much higher than that of the polymer so that almost all of the incident UV radiation is absorbed by the UV absorbing compound rather than the polymer compound itself.
- Two strategies have evolved for protecting the polyester from the effects of UV radiation: 1) using an acrylic-based polymer layer containing an UV absorber to protect the underlying polyester material, and 2) using a high loading of an UV absorber incorporated directly into a polyester material, which would then be incorporated as a thin layer on the surface of the polyester sheeting material.
- both of these methods are not without their problems.
- a serious problem with incorporating a strong UV absorber added to the acrylic layer in order to screen harmful UV radiation from the underlying polymeric material is the differences in rheological characteristics of the polyester substrates and the acrylic material. Another problem is the difference in melt temperatures of the two materials. This usually limits how such constructions are made to the lamination of a film of the acrylic material onto the polymeric substrate during its extrusion which tends to be more costly than a coextrusion process.
- a serious problem with this methodology is one of eventual delamination, especially in the conditions of high humidity and heat. Delamination, of course, renders the construction useless.
- polyesters and copolyesters while very tough in general, also are known to be generally notch sensitive. That is, when a small notch or scratch is introduced into the surface, the energy required for impact failure is reduced by more than an order of magnitude and the sheeting effectively becomes brittle. As a result of this notch sensitivity, when a brittle acrylic layer is intimately bonded with the underlying polyester or copolyester, a crack initiated in the acrylic layer is quickly and efficiently propagated through the polyester or copolyester substrate. Thus, the entire structure is as brittle as the protective acrylic film even before exposure to weathering.
- That portion of the UV light not absorbed by the UV absorber is absorbed by the polymeric matrix and over long exposure times contributes to damage of the polymeric matrix material as described above, i.e., discoloration, surface damage such as a haze or loss of surface gloss, and property loss, such as resistance to impacts.
- U.S. Patent No. 4,446,262 discloses a phot-stabilized polymer composition having a cyclic imino ester as an ultraviolet absorber.
- U.S. Patent No. 5,108,835 discloses a coextruded thermoplastic sheet having a 5 to 100 micron thick surface layer.
- the surface layer includes from 0.1 weight % to 20 weight % of an UV absorber.
- the thermoplastic material includes thermoplastic aromatic polycarbonates, thermoplastic aromatic polyester carbonates, thermoplastic aromatic polyester, thermoplastic aliphatic-aromatic polyesters of iso- and/or terephthalic acid, polyvinyl chloride, polyvinylidene chloride, thermoplastic copolymers of styrene and/or methyl styrene with maleic anhydride and/or with acrylonitrile, thermoplastic graft polymers of styrene and acrylonitrile on polybutadiene rubbers, thermoplastic poly- ⁇ - olefins, such as polyethylene and polypropylene, thermoplastic polyacrylates and polymethacrylates.
- U.S. Patent Nos. 5,558,912 and 5,480,926 disclose a polyethylene terephthalate based copolyester containing 1 ,4-cyclohexanedimethanol and an ultraviolet absorber selected from cyclic imino esters.
- U.S. Patent No. 5,654,083 discloses a two layer plastic sheet having a core section that includes a copolyester containing at least 40-50 mole % monomer units derived from a first aliphatic diol, 45-50 mole % monomer units derived from a first aromatic dicarboxylic acid, and 0.5-5 mole % monomer units derived from at least one member selected from the group consisting of a second aliphatic diol and a second aromatic dicarboxylic acid, but does not contain a copolyester that contains 50 mole % monomer units derived from terephthalic acid, 49.5-45 mole % monomer units derived from ethylene glycol, and 0.5-5 mole % monomer units derived from cyclohexane dimethanol.
- the second layer overlies one surface of the core section.
- the second layer includes the copolyester of the core section and 1-15 wt. % of a UV light-absorbing additive.
- U.S. Patent No. 5,709,9 ⁇ 9 discloses a multi-layered plastic sheet having a core section that includes a copolyner prepared by the reaction of dimethyl terephthalate or terephthalic acid with a mixture comprising about 99-55 mole % ethylene glycol and about 1-45 mole % 1 ,4-cyclohexane dimethanol.
- the second layer which has a thickness of between about 2 microns and about 100 microns, overlies one surface of the core section and includes the copolyester of the core section and a UV light- absorbing additive, which preferably includes a benzotriazole or a benzophenone as the light absorbing additive.
- UV absorbing compounds have been developed over the years of research in this area. It is also well known that many of these compounds are very specific to the polymer systems they are used in.
- Certain benzoxazinone compounds are disclosed as ultraviolet absorbers in U.S. Pat. No. 4,446,262.
- the disclosed benzoxazinones are said to be capable of melt mixing with various polymers.
- thermoplastic polymer classes are polyesters, polyamides, polycarbonates, polyolefms, polyesters and polysulfones.
- polyesters are polyethylene terephthalate, polytetramethylene terephthalate and polyethylene 2,6-naphthalate. These are stated to be optionally copolymerized with trifunctional or higher functional comonomers but no mention of coglycols is made for these materials.
- benzoxazinone compounds disclosed in U.S. Pat. No. 4,446,262 are also disclosed in U.S. Pat. No. 5,251,064 as being useful in a reflecting structure consisting of a metalized polyester layer of the same polyesters as disclosed in U.S. Pat. No. 4,446,262.
- the preferred polyester in U.S. Pat. No. 5,251 ,064 is stated to be polyethylene terephthalate.
- UV absorbers that would result from the substitution of various functional groups onto the aromatic ring(s) of the benzoxazinone system are broadly mentioned in U.S. Pat. No. 4,446,262, and mere specifically, in U.S. Pat. No. 5,264,539.
- U.S. Pat. No. 5,264,539 for example, an oligomer containing benzoxazinone units is blended with a polyester. Accordingly, there is still a need for polyester and copolyester blends that are UV light-stabilized suitable for use in outdoor applications.
- weatherable polyester and copolyester sheet constructions can be manufactured when a protective layer containing an effective amount of an UV light absorbing compound is incorporated into the product.
- the protective layer is a polyethylene terephthalate based copolyester containing certain amounts of 1,4-cyclohexanedimethanol, 4,4'-biphenyldicarboxylic acid and an ultraviolet absorber selected from benzoxazinones, dimeric benzotriazoles and triazines.
- thermoplastic article Another aspect of the present invention is a method for protecting from UV radiation a thermoplastic article which includes the step of applying to the thermoplastic article a protective layer of a polyethylene terephthalate based copolyester containing certain amounts of 1 ,4-cyclohexanedimethanol, 4,4'-biphenyldicarboxylic acid and an ultraviolet absorber selected from benzoxazinones, dimeric benzotriazoles and triazines.
- This invention produces an unexpected benefit in retaining clarity and physical properties over that of the prior art.
- thermoplastic and preferably a polyester, article having improved clarity and physical properties over that of the prior art when exposed to prolonged UV radiation.
- an UV radiation stabilized polymer composition includes a polyethylene terephthalate based copolyester having 1 ,4- cyclohexanedimethanol, an effective amount of an UV radiation absorbing compound selected from benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof, and from 2 mol % to about 25 mol % of 4,4'-biphenyldicarboxylic acid present in the copolyester wherein the mole percent of the 4,4'-biphenyldicarboxylic acid is based on 100 mole percent of dicarboxylic acid or equivalents.
- the copolyesters of the present invention have residue repeat units from a diacid and a diol wherein at least 98 mole % to about 75 mol % of the diacid is terephthalic acid or suitable synthetic equivalents such as dimethyl terephthalate.
- Typical methods describing the preparation of polyethylene terephthalate based copolyester resins useful in the blend of this invention are well known and, for example, are disclosed in U.S. Pat. Nos. 2,465,319 and 3,047,539.
- the polyethylene terephthalate based copolyester contains residues of from 95 mole % to about 80 mol % terephthalic acid and more preferably from about 93 mol % to about 85 mol % terephthalic acid.
- the terephthalic acid component of the diacid may contain up to about 5 mole % of one or more different diacids other than terephthalic acid.
- additional diacids include aromatic dicarboxylic acids having 8 to 14 carbon atoms, aliphatic dicarboxylic acids having 4 to 12 carbon atoms, or cycloaliphatic dicarboxylic acids preferably having 8 to 12 carbon atoms.
- the aforementioned additional dicarboxylic acid is selected from phthalic acid, isophthalic acid, naphthalene-2,6- dicarboxylic acid, cyclohexanedicarboxylic acid, cyclohexanediacetic acid, succinic acid, glutaric acid, adipic acid, azelaic acid, sebacic acid, and mixtures thereof.
- the polyethylene terephthalate based copolyester resins useful in the blend of the present invention further includes from 2 to 25 mol % residues from 4,4'- biphenyldicarboxylic acid.
- the copolyester contains from about 5 mol % to about 20 mol %, and preferably from about 7 mol % to about 15 mol % residues from 4,4'-biphenyldicarboxylic acid. It is to be understood that the sum of the mole percents for the above diacids equal 100% of the diacid residues in the copolyester resins of the present invention. It should be understood that use of the corresponding acid anhydrides, esters, and acid chlorides of these acids is included in the term "dicarboxylic acid".
- the diol residue moiety of the polyethylene terephthalate based copolyester is from about 60 mol % to about 85 mol % ethylene glycol. Desirably, the diol residue moiety of the polyethylene terephthalate based copolyester is from about 65 mol % to about 80 mol % ethylene glycol and more preferably from about 65 mol% to about 75 mol % ethylene glycol.
- the ethylene glycol may further be modified with up to about 10 mol % and desirably less than about 5 mol % of one or more different diols.
- Such modifying diols include cycloaliphatic diols having 6 to 20 carbon atoms and aliphatic diols having 3 to 20 carbon atoms.
- the aforementioned modifying diols are selected from: propane- 1,3 -diol; butane- 1,4-diol; pentane- 1,5 -diol; hexane-l,6-diol; 3- methylpentanediol-(2,4); 2-methylpentanediol-(l,4); 2,2,4-trimethylpentane-diol-(l,3); 2- ethylhexanediol-(l,3); 2,2-diethylpropane-diol-(l,3); hexanediol-(l,3); 1,4-di- (hydroxyethoxy)-benzene; 2,2-bis-(4-hydroxycyclohexyl)-prop
- the polyethylene terephthalate based copolyester resins useful in the blend of the invention further includes from 15 mol % to about 40 mol % of 1,4- cyclohexanedimethanol, preferably from about 20 to 35 mol %, and more preferably from about 25 to about 35 mol % 1,4-cyclohexanedimethanol. It is to be understood that the sum of the mole percents for the above diols equal 100% of the diol residues in the copolyester resins of the present invention.
- the polyethylene terephthalate based copolyester resins have blended therein an ultraviolet absorbing compound selected from benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof.
- an ultraviolet absorbing compound selected from benzoxazinones, dimeric benzotriazoles, triazines and mixtures thereof.
- X represents a divaleit aromatic residue in which the two bonds from X are at the 1- and 2-positions; n is 1, 1 or 3; and R 1 represents a hydrocarbon residue having a valence of n which may further contain a hetero atom, or R 1 may be a direct bond when n is 2, in the unreacted state.
- X 1 is a divalent aromatic residue in which two bonds from X 1 are at the 1- and 2- positions; n is 2, and R 1 is a hydrocarbon residue having a valence of n which may further contain a hetero atom, or R 1 may be a direct bond.
- X 1 examples include 1,2-phenylene, 1 ,2-naphthylene, 2,3-naphthylene, and groups represented by formulas (a) and (b), wherein formula (a) is:
- R for formulas (a) and (b) is -O-, -CO-, -S-, -SO 2 -, -CH 2 -, -(CH 2 ) 2 or -C(CH 3 ) 2 -.
- 1,2-phenylene is preferred.
- the aromatic residue for X 1 exemplified above may be substituted by substituents, for example, alkyl groups having 1 to 10 carbon atoms, such as methyl, ethyl, propyl, hexyl and decyl; aryl groups 6 to 12 carbon atoms such as phenyl and naphthyl; cycloalkyl groups having 5 to 12 carbon atoms such as cyclopentyl and cyclohexyl; aralkyl groups having 8 to 20 carbon atoms such as phenethyl; alkoxy groups having 1 to 10 carbon atoms such as methoxy, ethoxy and decyloxy; nitro; halogens such as chlorine and bromine; and acyl groups having 2 to 10 carbon atoms such as acetyl, propionyl, benzoyl and decanoyl.
- substituents for example, alkyl groups having 1 to 10 carbon atoms, such as methyl, ethyl
- Examples of the unsubstituted aliphatic residues having 2 to 10 carbon atoms are ethylene, trimethylene, tetramethylene and decamethylene.
- Examples of the unsubstituted aromatic residues having 6 to 12 carbon atoms are phenylene, naphthylene and p,p'-biphenylene.
- Examples of the unsubstituted alicyclic residues having 5 to 12 carbon atoms include cyclopentene and cyclohexylene.
- examples of the divalent hydrocarbon residue include groups represented by the following formula (c)
- R 2 is any one of the groups of formulae (d)-(h) defined below:
- R 4 represents an alkylene of 2 to 10 carbon atoms, phenylene or naphthylene
- R 5 represents an alkyl having 1 to 10 carbon atoms, a phenyl or a naphthyl; / R6
- R 4 and R 5 are as defined above, and R 6 is hydrogen atom or any one of the groups defined for R 5 and a group represented by formula (g) below
- R 4 and R 6 are as defined above, and R is hydrogen or any one of the groups defined for R 5 and substituted aliphatic or aromatic residues of formula (h) below
- R 1 is preferably a direct bond or any one of the unsubstituted or substituted aromatic hydrocarbon residues in the first to third groups. Those unsubstituted or substituted aromatic hydrocarbon residues in the first or third group in which the two bonds extend from positions farthest from each other, above all p- phenylene, p,p'-biphenylene, and 2,6-naphthylene, are especially preferred.
- Representative compounds of Formula (I) where n is 2 are:
- R 10 represents a divalent aromatic hydrocarbon residue.
- Particularly preferred compounds of formula (I) include 2,2'-p-[phenylene-bis(3,l-benzoxazin-4-one), 2,2'-(4,4'- diphenylene)-bis(3,l-benzoxazin-4-one), and 2,2'-(2,6-naphthalene)bis(3,l-benzoxazin-4- one) are especially preferred.
- the compound, 2,2'-P-(phenylene)-bis(3,l-benzoxazin-4- one) is even more preferred.
- the benzotriazole compounds are represented by the structure of formula II below:
- X 2 is an alkyl or aryl substituent or a halogen atom such as chlorine and R i l 1 l 1 is independently selected from alkyl or aryl groups having 1 to 20 carbon atoms.
- the R 11 moiety may be located on the ring but is usually located para- to the hydroxyl grouping for greatest synthetic ease.
- a representative structure from the class of triazine compounds is formula III below:
- R 13 , R 14 , and R 15 are an alkyl or aryl group. Their position of substitution on the rings may be as desired but is generally ortho- and para- to the bond to the triazine ring for best synthetic ease.
- One or both of the two groups R 13 or R 14 may be hydrogen.
- the amount of UV absorbing compound in the blend is from about 0.1 weight % to about 10 weight %, preferably from about 0.5 weight % to about 5 weight % and more preferably from about 0.5 weight % to about 4 weight %, wherein the weight % are based on the total weight of the blend.
- the UV absorbing compound may be incorporated into the copolyester and at the desired concentrations by suitable blending and/or mixing technology such as by preparation of a concentrate of the UV absorbing compound in a base copolymer followed by pellet blending of the concentrate with further copolyester pellets containing no UV absorber, such that the final extruded product will be the copolyester with the desired overall level of UV absorber.
- the UV absorbing compound may be placed as the layer onto the plastic sheeting or film to be stabilized with the protective stabilized layer facing the light exposure shielding the sheeting from the effects of UV exposure.
- the protective layer can be on both sides of the sheet or film either for purposes of attenuating the effect of reflected radiation in a particular application environment or to render installation of the product foolproof.
- Suitable means for application of this protective layer include, but are not limited to, coextrusion, extrusion coating, extrusion lamination, calendaring, hot press lamination, solvent coating, and the like.
- copolyesters blends of the present invention are suitable for use in both the protective layer and the substrate layer of film or sheeting to which the protective layer is applied, however, it is preferred that the substrate layer be composed of a polymer composition different than the protective layer.
- Such copolymers have numerous advantages in fabrication over the homopolymers and exhibit a stabilization for color and impact retention of the exposed sheeting not present outside of this range to the same degree.
- the structure of a coextruded product can be a film, a solid sheet or can be a profiled article. Many other configurations of such structures are possible, such as, having two or more layers of the sheeting connected by ribbing.
- the essential element of such structures is that they provide a great deal of rigidity of the final structure compared to the weight of the polymer employed therein.
- the UV absorber containing layer is placed on either one side or both flat sides just the same as if it were a solid sheet.
- the protective layer of film or sheeting need not be of the same copolyester composition as the substrate which does not contain the UV absorbing compound.
- the thickness of the protective layer on the underlying film or sheeting can vary according to the desired technological ends of the coating.
- This protective layer thickness will be governed by the concentration of UV absorber present and must be sufficient to absorb at least 90% of the harmful UV light prior to it reaching the underlying, polyester or copolyester. More preferably the protective layer should absorb 99% of the harmful UV radiation and even more preferably 99.9% of the UV radiation prior to it reaching the underlying material. As a general rule, using the UV absorber levels necessary for the practice of this invention, this protective layer need only be 1 mil (0.025 cm) in thickness in order to screen 99% of the incoming UV light in solar radiation and render the structure weathering resistant. As used herein "weathering resistant" means that the structure is resistant to a color change (b*) of less than about 3 units over 1536 hours of exposure to UVCON testing.
- the present invention also relates to shaped articles wholly or partially produced from the UV radiation stabilized polymer.
- Representative applications are for example; signs for businesses, both stationary mounted and also portable ones, luggage carriers for the tops of the vehicles, sign boards, marquees on stores, solar roof panels, skylights, highway sound barriers, greenhouse panels, both in the sidewalls and the roofing thereof, separation walls in aquariums, aquariums themselves, recreational vehicle windows and vents, snowmobile, jet ski, golf cart, motorcycle and other such recreation vehicle windshields, bug screens or air deflection screens on cars and trucks or other such vehicles, transparent or translucent awnings, formed letters to be applied to the sides of buildings, letters to be used on signs, particularly those where the letters are changed at some frequency to change what the sign says, airport runway and taxiway marker signs, multiwall sheeting for use in signs, greenhouses, glazing applications and fluorescent or other light covers, etc., facia for soft drink and juice dispensing machines, etc.
- the product can be used either as a clear plastic part or it could be colored via producer added colors to give a clear, colored sheet or it could be printed on the back surface, in particular for sign and marquee applications to give the desired effects of highlighting letters, for example.
- This list is not intended to be all inclusive but merely representative of the vast number of applications available for a material having suitable properties.
- the UV radiation stabilized polymer of the present invention may further include the usual additives such as lubricants, antioxidants, optically active additives, colorants, pigments, fillers and fibers.
- Samples were cut from the sheeting produced into 7.6 cm by 11.4 cm (3 X 4.5 inch) panels and exposed in a UVCON test device (available from Atlas electric Devices, Inc.) using 313B bulbs with a black panel temperature of 70°C. and a condensation cycle temperature of 40°C. The device was run on a cycle of 8 hours of having the lamps on followed by 4 hours of condensation having the lamps off. Samples were tested at 384 hour continuous increments of exposure inclusive of the condensation time. Yellow color in the specimens were measured using a Hunter Lab Ultrascan color device, (available from Hunter Lab, Inc.), under CIE recommendations for obtaining L*, a* and b* values using a D65 light source with a 10° observation angel and a specular mode included on the instrument. The b* value was reported, a positive b* value being yellow, the more positive the more yellow.
- Impact strength was determined using ASTM-D6395-99 flatwise impact method. Impact strength was carried out with the exposed surface being struck by the hammer, which puts the front surface into tension.
- This example illustrates the preparation of a copolyester useful in making a blend in accordance with the present invention.
- a copolyester of poly(ethylene terephthalate) copolymerized with 31 mol% of 1 ,4-cyclohexanedimethanol and 5 mol% of 4,4'- biphenyldicarboxylic acid was prepared in a 1 liter glass reaction vessel by combining the following: 276.5 g (1.425 o ) dimethyl terephthalate, 20.27 g (0.075 mol) dimethyl 4,4'- biphenyldicarboxylate, 156.2 g (2.52 mol) ethylene glycol, 69.1 g (0.48 mol) 1,4- cyclohexanedimethanol and titanium tetraisoproxide solution in n-butanol, manganese acetate in ethylene glycol solution and cobalt acetate in ethylene glycol solution sufficient
- the polymer had a nominal residence time of about 70 minutes (109.2 g/hr extrusion rate).
- the input hopper was held under nitrogen purge and preheated nitrogen gas at a nominal 285°C was used as a purge at the vent port half way down the extruder barrel at a flow rate of 38 SCFH.
- the final product IV was measured as 0.75. Concentration of the 4,4 '-biphenyldicarboxylic acid in the copolymer was
- This example illustrates the use of a protective layer prepared from the copolyester 30 of Example 1.
- the copolyester of example 1 was blended with 2,2'-(l,4- phenylene)bis(4H-3,l-benzoxazin-4-one) to produce a final mixture that contains 98.2 percent by weight of the copolyester and 1.8 weight % of the 2,2'-(l,4-phenylene)bis[4H- 3,l-benzoxazin-4-one].
- This physical blend was coextruded as a 5 mil (125 micron) thick top layer on a 113 mil layer of a copolyester consisting of poly(ethylene terephthalate) modified with 31 mol% 1,4-cyclohexanedimethanol (trade name, SPECTAR , available from Eastman Chemical Company, Kingsport, TN). Barrel set temperatures on the main and satellite extruders were set at 240°C. The overall sheeting thickness was 3 mm (118 mil). The sheet was cut into 7.62 cm by 1 1.43 cm (3 X 4.5 inch) pieces and tested as described above.
- the comparison copolymer was one where the protective layer was only the SPECTAR copolyester containing 1.8 weight % of 2,2'-(l,4-phenylene)bis[4H- 3,l-benzoxazin-4-one].
- the color, expressed as the b* value for the materials, vs. exposure time results are shown in Table 1 below:
- Example 2 The copolyester protective layer was prepared having poly(ethylene terephthalate) modified with 31 mol% of 1 ,4-cyclohexanedimethanol and 5 mol% of 2,6- naphthalenedicarboxylic acid using the same procedure as the copolymer of Example 1, except for the substitution of the same number of moles of dimethyl 2,6- naphthalenedicarboxylate in the place of the dimethyl 4,4'-biphenyldicarboxylate.
- EXAMPLE 4 This example illustrates the increasing benefit in reduction of color development obtained by adding additional amounts of 4,4'-biphenyldicarboxylic acid to the copolymer of example 1.
- a batch reactor is used to prepare 10 kg of the subject copolyesters.
- Copolyester 1 is modified with 5 mol% of 4,4'-biphenyldicarboxylic acid and 30 mol% of 1 ,4-cyclohexanedimethanol to give a copolyester substantially identical to that prepared in example 1.
- Copolyester 2 is the same in to copolyester 1 except that the amount of 4,4'-biphenyldicarboxylic acid is increased to 20 mol%.
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Application Number | Priority Date | Filing Date | Title |
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EP00976806A EP1252225A1 (en) | 1999-12-13 | 2000-11-01 | Copolyester containing 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and an ultraviolet light absorbing compound and articles made therefrom |
JP2001543638A JP2003516449A (en) | 1999-12-13 | 2000-11-01 | Copolyester containing 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and an ultraviolet absorbing compound and articles made therefrom |
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US09/459,966 US6352783B1 (en) | 1999-12-13 | 1999-12-13 | Copolyester containing 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and an ultraviolet light absorbing compound and articles made therefrom |
US09/459,966 | 1999-12-13 |
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- 2000-11-01 JP JP2001543638A patent/JP2003516449A/en active Pending
- 2000-11-01 EP EP00976806A patent/EP1252225A1/en not_active Withdrawn
- 2000-11-01 WO PCT/US2000/030185 patent/WO2001042347A1/en not_active Application Discontinuation
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EP2270076A1 (en) * | 2008-03-30 | 2011-01-05 | FUJIFILM Corporation | Resin molded product and polymer film |
EP2270076A4 (en) * | 2008-03-30 | 2012-01-04 | Fujifilm Corp | Resin molded product and polymer film |
US8541488B2 (en) | 2008-03-30 | 2013-09-24 | Fujifilm Corporation | Formed resin article and polymer film |
KR101536797B1 (en) * | 2008-03-30 | 2015-07-14 | 후지필름 가부시키가이샤 | Resin molded product and polymer film |
Also Published As
Publication number | Publication date |
---|---|
US6352783B1 (en) | 2002-03-05 |
EP1252225A1 (en) | 2002-10-30 |
JP2003516449A (en) | 2003-05-13 |
CN1409738A (en) | 2003-04-09 |
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