WO2001053379A8 - Macrocyclic polyester oligomers and processes for polymerizing the same - Google Patents

Macrocyclic polyester oligomers and processes for polymerizing the same

Info

Publication number
WO2001053379A8
WO2001053379A8 PCT/US2001/002064 US0102064W WO0153379A8 WO 2001053379 A8 WO2001053379 A8 WO 2001053379A8 US 0102064 W US0102064 W US 0102064W WO 0153379 A8 WO0153379 A8 WO 0153379A8
Authority
WO
WIPO (PCT)
Prior art keywords
macrocyclic polyester
processes
polymerizing
polyester oligomers
same
Prior art date
Application number
PCT/US2001/002064
Other languages
French (fr)
Other versions
WO2001053379A1 (en
Inventor
Steven J Winckler
Tohru Takekoshi
Original Assignee
Cyclics Corp
Steven J Winckler
Tohru Takekoshi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/535,132 external-priority patent/US6369157B1/en
Application filed by Cyclics Corp, Steven J Winckler, Tohru Takekoshi filed Critical Cyclics Corp
Priority to JP2001553844A priority Critical patent/JP2003520875A/en
Priority to EP01942649A priority patent/EP1250374B1/en
Priority to AU2001229689A priority patent/AU2001229689A1/en
Priority to DE2001609575 priority patent/DE60109575T2/en
Priority to AT01942649T priority patent/ATE291602T1/en
Publication of WO2001053379A1 publication Critical patent/WO2001053379A1/en
Publication of WO2001053379A8 publication Critical patent/WO2001053379A8/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/246—Moulding high reactive monomers or prepolymers, e.g. by reaction injection moulding [RIM], liquid injection moulding [LIM]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B15/00—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00
    • B29B15/08—Pretreatment of the material to be shaped, not covered by groups B29B7/00 - B29B13/00 of reinforcements or fillers
    • B29B15/10—Coating or impregnating independently of the moulding or shaping step
    • B29B15/12—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length
    • B29B15/122—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex
    • B29B15/125—Coating or impregnating independently of the moulding or shaping step of reinforcements of indefinite length with a matrix in liquid form, e.g. as melt, solution or latex by dipping
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
    • B29C41/06—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould about two or more axes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Abstract

The invention features macrocyclic polyester oligomers and processes for polymerizing the same. In one aspect, the invention relates to a blend material including a macrocyclic polyester oligomer and a polymerisation catalyst. In another aspect, the invention relates to various processes for using macrocyclic polyester oligomers including rotational molding, resin film infusion, making and using various prepregs, pultrusion, resin transfer molding, filament winding, compression molding, roll wrapping, and water slurry.
PCT/US2001/002064 2000-01-21 2001-01-19 Macrocyclic polyester oligomers and processes for polymerizing the same WO2001053379A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2001553844A JP2003520875A (en) 2000-01-21 2001-01-19 Macrocyclic polyester oligomer and process for polymerizing the same
EP01942649A EP1250374B1 (en) 2000-01-21 2001-01-19 Macrocyclic polyester oligomers and processes for polymerizing the same
AU2001229689A AU2001229689A1 (en) 2000-01-21 2001-01-19 Macrocyclic polyester oligomers and processes for polymerizing the same
DE2001609575 DE60109575T2 (en) 2000-01-21 2001-01-19 MACROCYCLIC POLYESTER OLIGOMERS AND THEIR POLYMERIZATION PROCESS
AT01942649T ATE291602T1 (en) 2000-01-21 2001-01-19 MACROCYCLIC POLYESTER OLIGOMERS AND THEIR POLYMERIZATION PROCESSES

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US17772700P 2000-01-21 2000-01-21
US60/177,727 2000-01-21
US09/535,132 2000-03-24
US09/535,132 US6369157B1 (en) 2000-01-21 2000-03-24 Blend material including macrocyclic polyester oligomers and processes for polymerizing the same
US09/754,943 2001-01-04
US09/754,943 US6420047B2 (en) 2000-01-21 2001-01-04 Macrocyclic polyester oligomers and processes for polymerizing the same

Publications (2)

Publication Number Publication Date
WO2001053379A1 WO2001053379A1 (en) 2001-07-26
WO2001053379A8 true WO2001053379A8 (en) 2002-01-03

Family

ID=27390858

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/002064 WO2001053379A1 (en) 2000-01-21 2001-01-19 Macrocyclic polyester oligomers and processes for polymerizing the same

Country Status (6)

Country Link
US (4) US6420047B2 (en)
EP (1) EP1250374B1 (en)
JP (1) JP2003520875A (en)
AT (1) ATE291602T1 (en)
DE (1) DE60109575T2 (en)
WO (1) WO2001053379A1 (en)

Families Citing this family (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US6960626B2 (en) * 2000-01-21 2005-11-01 Cyclics Corporation Intimate physical mixtures containing macrocyclic polyester oligomer and filler
US6420047B2 (en) * 2000-01-21 2002-07-16 Cyclics Corporation Macrocyclic polyester oligomers and processes for polymerizing the same
US20050282952A1 (en) * 2000-01-21 2005-12-22 Cyclics Corporation Graphite-polyester composites made from macrocyclic polyester oligomers
US7151143B2 (en) * 2000-01-21 2006-12-19 Cyclics Corporation Blends containing macrocyclic polyester oligomer and high molecular weight polymer
US7256241B2 (en) * 2000-01-21 2007-08-14 Cyclics Corporation Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters
US7223359B2 (en) * 2002-11-05 2007-05-29 Northwestern University Method of producing an exfoliated polymer-clay nanocomposite through solid-state shear pulverization
US20040010066A1 (en) * 2000-06-30 2004-01-15 Devine Stephen J Flame retardant dispersible powders on a wax, polymer, or organic carrier
US7767781B2 (en) * 2000-09-01 2010-08-03 Cyclics Corporation Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom
US7750109B2 (en) 2000-09-01 2010-07-06 Cyclics Corporation Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer
CN1217974C (en) * 2000-09-01 2005-09-07 赛克利克斯公司 Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
US6436548B1 (en) 2000-09-12 2002-08-20 Cyclics Corporation Species modification in macrocyclic polyester oligomers, and compositions prepared thereby
US6420048B1 (en) * 2001-06-05 2002-07-16 Cyclics Corporation High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters
JP3952706B2 (en) * 2001-06-14 2007-08-01 富士ゼロックス株式会社 POLYMER COMPOUND AND PROCESS FOR PRODUCING THE SAME, MOLDED ARTICLE AND METHOD FOR PRODUCING THE SAME
US7304123B2 (en) * 2001-06-27 2007-12-04 Cyclics Corporation Processes for shaping macrocyclic oligoesters
ATE305931T1 (en) * 2001-06-27 2005-10-15 Cyclics Corp ISOLATION, FORMULATION AND FORMULATION OF MACROCYCLIC OLIGOESTERS
US6436549B1 (en) * 2001-07-16 2002-08-20 Cyclics Corporation Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers
US6787632B2 (en) * 2001-10-09 2004-09-07 Cyclics Corporation Organo-titanate catalysts for preparing pure macrocyclic oligoesters
US6831138B2 (en) * 2002-01-07 2004-12-14 Cyclics Corporation Polymer-containing organo-metal catalysts
US6806346B2 (en) * 2002-07-12 2004-10-19 E. I. Du Pont De Nemours And Company Copolymerization of cyclic ester oligomers
EP1415793A1 (en) * 2002-11-04 2004-05-06 Alcan Technology & Management Ltd. Method of manufacturing fibre reinforced composite structural elements
US20040106713A1 (en) * 2002-12-03 2004-06-03 Avakian Roger W. Use of additives in compounds containing macrocyclic poly(alkylene dicarboxylate) oligomers
US7078451B2 (en) * 2002-12-19 2006-07-18 Owens Corning Fiberglas Technology, Inc. Formulation and process for compression molded component parts
US6962968B2 (en) * 2002-12-20 2005-11-08 Cyclics Corporation Purification of macrocyclic oligoesters
CN100392006C (en) * 2002-12-20 2008-06-04 陶氏环球技术公司 Polymerized macrocyclic oligomer nanocomposite compositions
AU2003301178A1 (en) * 2002-12-23 2004-07-22 Dow Global Technologies Inc. Electrically conductive polymerized macrocyclic oligomer carbon nanofiber compositions
JP2007521341A (en) * 2002-12-23 2007-08-02 ダウ グローバル テクノロジーズ インコーポレイティド SMC molding method
NZ544769A (en) * 2003-06-25 2007-11-30 Joseph Steven Egan Method of construction of moulded leg prosthesis
US20050095415A1 (en) * 2003-10-30 2005-05-05 Raghavendran Venkat K. Glass mat thermoplastic composite
DE602004025971D1 (en) * 2003-12-19 2010-04-22 Cyclics Corp METHOD OF DISPERSING A PUNCHING MODULE IN A MACROCYCLIC POLYESTEROLIGOMER
US7351769B2 (en) * 2004-01-26 2008-04-01 Freudenberg-Nok General Partnership Dynamic vulcanization of elastomers with in-situ polymerization
EP1570976A1 (en) * 2004-03-04 2005-09-07 Alcan Technology & Management Ltd. Processes for converting cyclic oligomers into thermoplastic PBT products
EP1570977A1 (en) * 2004-03-05 2005-09-07 Alcan Technology & Management Ltd. Process for continuous manufacturing of fibre reinforced plastic sheets
EP1580246A1 (en) * 2004-03-24 2005-09-28 The Dow Chemical Company Reactive hot melt adhesive
USRE44893E1 (en) 2004-03-26 2014-05-13 Hanwha Azdel, Inc. Fiber reinforced thermoplastic sheets with surface coverings
US7196160B2 (en) * 2004-04-22 2007-03-27 Dow Global Technologies Inc Catalysts and methods for polymerizing macrocyclic oligomers
EP1773927A1 (en) * 2004-06-18 2007-04-18 Dow Gloval Technologies Inc. Polymerizable macrocyclic oligomer masterbatches containing dispersed fillers
US20060003887A1 (en) * 2004-06-18 2006-01-05 Paquette Michael S Catalyst-containing clay materials for composites in polymer of macrocyclic oligomers
EP1761583A1 (en) * 2004-06-18 2007-03-14 Dow Gloval Technologies Inc. Delayed action catalysts and methods for polymerizing macrocyclic oligomers
US20060067055A1 (en) * 2004-09-30 2006-03-30 Heffner Kenneth H Thermally conductive composite and uses for microelectronic packaging
WO2006039291A1 (en) * 2004-09-30 2006-04-13 Honeywell International Inc. Thermally conductive composite and uses for microelectronic packaging
EP1824897A2 (en) * 2004-11-09 2007-08-29 E.I. Dupont De Nemours And Company Polymerization of macrocyclic polyester oligomers using n-heterocyclic carbene and metal amide or metal alkoxide catalyst
US7622543B2 (en) * 2004-11-09 2009-11-24 E.I. Du Pont De Nemours And Company Polymerization of macrocyclic polyester oligomers using N-heterocyclic carbene catalysts
US7557157B2 (en) * 2004-11-09 2009-07-07 E. I. Du Pont De Nemours And Company Polymerization of macrocyclic polyester oligomers at elevated temperature using rare earth element catalysts
WO2006053070A1 (en) * 2004-11-09 2006-05-18 E.I. Dupont De Nemours And Company Polymerization of macrocyclic polyester oligomers using metal amide and metal alkoxide catalysts
US7642028B2 (en) * 2005-03-17 2010-01-05 Xerox Corporation Imaging members
DE102005018450B3 (en) * 2005-04-20 2006-10-12 Heraeus Kulzer Gmbh Use of butylene terephthalate for the production of thermoplastic dentures
US20070173630A1 (en) * 2005-12-02 2007-07-26 Cyclics Corporation Macrocyclic polyester oligomers as flow modifier additives for thermoplastics
US7745561B2 (en) 2006-01-31 2010-06-29 Cyclics Corporation Processes for making copolymers using macrocyclic oligoesters, and copolymers therefrom
US7934580B2 (en) * 2006-04-12 2011-05-03 Ocv Intellectual Capital, Llc Long fiber thermoplastic composite muffler system
US7942237B2 (en) * 2006-04-12 2011-05-17 Ocv Intellectual Capital, Llc Long fiber thermoplastic composite muffler system with integrated reflective chamber
US7730996B2 (en) * 2006-04-12 2010-06-08 Ocv Intellectual Capital, Llc Long fiber thermoplastic composite muffler system with integrated crash management
WO2008021035A1 (en) * 2006-08-10 2008-02-21 Dow Global Technologies, Inc. Polymers of macrocyclic oligomers containing highly expanded graphite
WO2008057113A1 (en) 2006-11-06 2008-05-15 Johnson & Johnson Consumer Companies, Inc. Cosmetic device comprising discrete elements
FR2918081B1 (en) * 2007-06-27 2009-09-18 Cabinet Hecke Sa METHOD FOR IMPREGNATING FIBERS CONTINUOUS BY A COMPOSITE POLYMERIC MATRIX COMPRISING A THERMOPLASTIC POLYMER
WO2009055598A1 (en) * 2007-10-23 2009-04-30 Cyclics Corporation Processes for reducing acid content of a polyalkylene terephthalate product and using such in the production of macrocyclic polyester oligomer
US7686862B1 (en) * 2008-09-22 2010-03-30 Peerless Mfg. Co. Composite vane and method of manufacture
WO2010050202A1 (en) * 2008-10-30 2010-05-06 株式会社カネカ High thermal conductivity thermoplastic resin composition and thermoplastic resin
BR112012000563A2 (en) 2009-06-19 2016-11-16 Polyone Corp oxygen scavenging terpolymer.
CN102498149B (en) 2009-09-16 2013-11-27 株式会社钟化 Thermally-conductive organic additive, resin composition, and cured product
WO2011132389A1 (en) 2010-04-19 2011-10-27 株式会社カネカ Thermoplastic resin with high thermal conductivity
CN102844351B (en) 2010-04-19 2014-11-19 株式会社钟化 Thermoplastic resin with high thermal conductivity
ES2378129B1 (en) * 2010-04-30 2013-03-25 Airbus Operations, S.L. RESIN APPLICATION PROCESS ON A SURFACE TREATED WITH DEMOLDING SUBSTANCES OF A USEFUL MOLDING BASE TO OBTAIN BODIES OF COMPOSITE MATERIAL.
US20130221555A1 (en) * 2011-08-26 2013-08-29 Basf Se Process for producing moldings
CN104334605B (en) 2012-05-25 2016-05-04 普立万公司 The oxygen scavenging copolymers of being made by annular aliphatic monomer
RU2648995C2 (en) * 2013-03-15 2018-03-29 Зульцер Хемтех Аг Method for producing cyclic oligomer and cyclic oligomer obtained thereof
US20160102182A1 (en) * 2013-06-11 2016-04-14 Johns Manville Fiber-reinforced composite articles and methods of making them
US9855680B2 (en) 2013-06-11 2018-01-02 Johns Manville Fiber-reinforced composite articles and methods of making them
US9115266B2 (en) 2013-07-31 2015-08-25 E I Du Pont De Nemours And Company Carbon nanotube-polymer composite and process for making same
JP6121978B2 (en) * 2014-12-10 2017-04-26 株式会社 サン・テクトロ Prepreg manufacturing equipment
US20160230412A1 (en) * 2015-02-09 2016-08-11 Keenan & Associates Fence And Deck Post Cap
WO2016178400A1 (en) * 2015-05-01 2016-11-10 日立化成株式会社 Method for producing frp precursor and device for producing same
CN110023295B (en) * 2016-09-29 2024-03-22 苏尔寿管理有限公司 Method for producing polyester polymers and polyester polymers obtainable therefrom
EP3632643B1 (en) * 2017-06-02 2022-08-10 Jamco Corporation Method for producing composite material component and device for producing composite material component
US10717245B2 (en) 2018-04-03 2020-07-21 Johns Manville System for producing a fully impregnated thermoplastic prepreg
EP3643736A1 (en) * 2018-10-26 2020-04-29 Johns Manville System for producing a fully impregnated thermoplastic prepreg
WO2020226660A1 (en) * 2019-05-09 2020-11-12 Dustin Eplee Fluidized bed rotational molding
US11117292B2 (en) 2019-05-09 2021-09-14 Dustin Eplee Fluidized bed rotational molding

Family Cites Families (131)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2628171A (en) 1950-02-23 1953-02-10 Du Pont Solvent-soluble water-repellency compositions
US3018272A (en) 1955-06-30 1962-01-23 Du Pont Sulfonate containing polyesters dyeable with basic dyes
US3875275A (en) * 1958-05-05 1975-04-01 Jerome H Lemelson Method for molding composite bodies
US3090753A (en) 1960-08-02 1963-05-21 Exxon Research Engineering Co Ester oil compositions containing acid anhydride
GB991020A (en) 1960-11-29 1965-05-05 Martin Marietta Corp Esterification of iso- and terephthalic acids
GB957841A (en) 1961-04-10 1964-05-13 Ici Ltd The preparation of organo-tin compounds and their use as catalysts in the productionof polymethanes
DE1518103C3 (en) 1964-04-10 1975-05-22 E.I. Du Pont De Nemours And Co., Wilmington, Del. (V.St.A.) Macrocyclic polyethers and their use as cation complexing agents
AT265646B (en) 1965-02-25 1968-10-25 Metallgesellschaft Ag Process for increasing the molecular weight of a fiber and film-forming polyester
US3528935A (en) * 1967-11-30 1970-09-15 Sinclair Research Inc Package stable,low viscosity,high solids,thermosetting coating compositions with latent curing catalyst
US3786067A (en) 1972-02-18 1974-01-15 Ashland Oil Inc Cyclic organometallic compounds
US4111899A (en) 1977-07-20 1978-09-05 The Dow Chemical Company Heat stabilized thermoplastic resins containing compounds with phosphorus to phosphorus bonds
US4559262A (en) * 1981-01-21 1985-12-17 Imperial Chemical Industries, Plc Fibre reinforced compositions and methods for producing such compositions
SU1077893A1 (en) 1981-11-27 1984-03-07 Всесоюзный научно-исследовательский институт синтетических и натуральных душистых веществ Process for preparing macrocyclic diesters
US4644053A (en) 1984-05-11 1987-02-17 General Electric Company Cyclic polycarbonate oligomers and methods for their preparation and use
US4740583A (en) 1984-05-11 1988-04-26 General Electric Company Method for converting cyclic polycarbonate oligomer mixtures to linear polycarbonate, and composition resulting therefrom
US4568703A (en) 1984-07-27 1986-02-04 Bp Chemicals Limited Process for the production of polymers containing isocyanurate and or oxazolidone linkages
US4638077A (en) 1984-11-29 1987-01-20 General Electric Company Method for the preparation of chloroformate compositions
US4590259A (en) 1984-11-30 1986-05-20 General Electric Company High molecular weight linear polyesters and method for their preparation
US4727134A (en) 1985-02-22 1988-02-23 General Electric Company Method for preparing cyclic polycarbonate oligomer mixtures
US4605731A (en) 1985-04-16 1986-08-12 General Electric Company Method for preparing linear polycarbonate from cyclic oligomer with aryl carbanion generating catalyst
US4680345A (en) 1985-06-05 1987-07-14 Toyo Boseki Kabushiki Kaisha Continuous production of elastic polyesters
US5039717A (en) 1985-07-25 1991-08-13 Amoco Corporation Copolyesters
JPS6275547A (en) 1985-09-30 1987-04-07 Canon Inc Charge applying material for electrostatic charge image development
US4616077A (en) 1985-11-22 1986-10-07 General Electric Company Method for preparing cyclic polycarbonate oligomer from bischloroformate composition
US4888411A (en) 1985-11-25 1989-12-19 General Electric Company Crosslinkable polycyclic polycarbonate oligomer and methods for their preparation and use
DE3607627A1 (en) 1986-03-07 1987-09-10 Bayer Ag THERMOPLASTIC BLOCK COPOLYMERS BASED ON CYCLIC CARBONATES OR ESTERS
US4803288A (en) 1986-03-20 1989-02-07 Nisso Petrochemical Industries Co., Ltd. Process for producing macrocyclic ester compounds
US4980453A (en) 1986-07-21 1990-12-25 General Electric Company Macrocyclic oligomers containing spiro(bis)indane moietes
USRE34431E (en) 1986-07-21 1993-11-02 General Electric Company Macrocyclic oligomers containing spiro(bis)indane moieties
US4757132A (en) 1986-10-20 1988-07-12 General Electric Company Cyclic polyester oligomer polymerization
US4785060A (en) 1986-08-28 1988-11-15 Colgate-Palmolive Company Soil release promoting pet-poet copolymer, method of producing same and use thereof in detergent composition having soil release promoting property
JPS6372513A (en) * 1986-09-16 1988-04-02 Nippon Carbide Ind Co Ltd Method of molding fiber reinforced resin composition and unsaturated polyester resin used therefor
US4829144A (en) 1986-10-20 1989-05-09 General Electric Company Cyclic polyester oligomer and method for their preparation
US4816548A (en) 1986-10-30 1989-03-28 General Electric Company Cyclic polycarbonate oligomers: inhibition and control of polymerization to linear polycarbonates
US4831001A (en) 1986-10-30 1989-05-16 General Electric Company Cyclic polycarbonate oligomers: inhibition and control of polymerization to linear polycarbonates
US4904810A (en) 1987-01-16 1990-02-27 General Electric Company Bischoloroformate preparation method with phosgene removal and monochloroformate conversion
US4900706A (en) 1987-03-17 1990-02-13 Sumitomo Chemical Company, Limited Process for producing olefin polymers and catalyst used therein
DE3737047A1 (en) 1987-10-31 1989-05-11 Huels Troisdorf PREPARATION BASED ON TITANIUM CHELATES OF DIOLES AND TITANIACYLATES
US5202386A (en) 1987-12-14 1993-04-13 Akzo Nv Modification of (co)polymers employing organic peroxides
EP0338115A3 (en) * 1988-02-05 1991-02-27 Basf Aktiengesellschaft Process for preparing a void-free pre-impregnated material comprising a thermoplastic polymer
DE3831886A1 (en) 1988-09-20 1990-03-29 Bayer Ag PROCESS FOR PREPARING AROMATIC POLYCARBONATES
DE3838752A1 (en) 1988-11-16 1990-05-17 Bayer Ag METHOD FOR PRODUCING CYCLIC CARBONIC ESTERS
US5191038A (en) 1989-06-01 1993-03-02 General Electric Company Preparation of branched polycarbonate composition from cyclic aromatic polycarbonate oligomer, polyhydric phenol and polycarbonate
US5097008A (en) 1989-06-01 1992-03-17 General Electric Company Preparation of branched polycarbonate from oligomeric cyclic polycarbonate and polyhydric phenol
US5006637A (en) 1989-06-12 1991-04-09 General Electric Company Method for preparing copolyestercarbonates from cyclic oligomers
US4970288A (en) 1989-09-22 1990-11-13 Atochem North America, Inc. Non-toxic polyester compositions made with organotin esterification catalysts
US5071711A (en) 1989-09-28 1991-12-10 The Dow Chemical Company Preforms for molding processes
US4992228A (en) 1989-09-28 1991-02-12 The Dow Chemical Company Method for preparing preforms for molding processes
DE4000173A1 (en) 1990-01-05 1991-07-11 Bayer Ag THERMO-RESISTANT, EASILY PROCESSABLE AND THERMOSTABLE POLYCARBONATE MOLDS
US5241880A (en) 1990-02-07 1993-09-07 Nippon Cable System, Inc. Control cable
US5116900A (en) 1990-02-13 1992-05-26 Owens-Corning Fiberglas Corporation Coating composition for fibers
US5207850A (en) 1990-07-17 1993-05-04 General Electric Company Process for making thermoplastic composites with cyclics oligomers and composites made thereby
NL9001641A (en) 1990-07-19 1992-02-17 Stamicarbon METHOD FOR MAKING POLYMERIC PRODUCTS FROM CYCLIC ESTERS.
US6353030B1 (en) 1990-08-01 2002-03-05 Novartis Ag Relating to organic compounds
US5095088A (en) 1990-08-13 1992-03-10 Shell Oil Company Cyclic polycarbonate oligomer containing spiro diLactam moieties
US5264548A (en) 1990-09-20 1993-11-23 General Electric Company Low melting cyclic polycarbonate composition
DE4034574A1 (en) 1990-10-31 1992-05-07 Bayer Ag Thermoplasts modified with cyclic arylene sulphide oligomers - having lower melt viscosity and improved UV resistance, used for prepn. of shaped articles, films and fibres
US5466744A (en) 1990-11-05 1995-11-14 General Electric Company Polymerization of macrocyclic poly(alkylene dicarboxylate) oligomers
US5039783A (en) 1990-11-05 1991-08-13 General Electric Company Method for preparing and polymerizing macrocyclic poly(alkylene discarboxylate) oligomers
US5136018A (en) 1990-11-19 1992-08-04 General Electric Company Macrocyclic polyarylate compositions of decreased crystallinity
WO1992015573A1 (en) 1991-03-11 1992-09-17 Henkel Corporation Process for controlled depolymerization of feed material to produce a product with lower molecular weight
US5654395A (en) 1991-05-03 1997-08-05 Eastman Chemical Company Reinforced polyester compositions and method of making same
US5191013A (en) 1991-05-16 1993-03-02 General Electric Company Macrocyclic filled compositions convertible to polyester composites
US5214158A (en) 1991-06-03 1993-05-25 General Electric Company Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers
KR940010346B1 (en) 1991-06-12 1994-10-22 한국과학기술연구원 Process for preparation of polybuthylene therephtalate polymer
US5200496A (en) 1991-07-02 1993-04-06 The Dow Chemical Company Process for preparing polycarbonate having reduced carbonate byproduct content
US5128439A (en) 1991-10-11 1992-07-07 Exxon Research And Engineering Company Saturated polyesters and crosslinked membranes therefrom for aromatics/saturates separation
US5340909A (en) 1991-12-18 1994-08-23 Hoechst Celanese Corporation Poly(1,3-propylene terephthalate)
US5281669A (en) 1992-04-13 1994-01-25 General Electric Company Blends of linear polymers with macrocyclic oligomers
US5300392A (en) 1992-06-29 1994-04-05 Xerox Corporation Imaging member with polycarbonate obtained from cyclic oligomers
US5300393A (en) 1992-08-14 1994-04-05 Xerox Corporation Imaging members and processes for the preparation thereof
US5302484A (en) 1992-08-24 1994-04-12 Xerox Corporation Imaging members and processes for the preparation thereof
US5314779A (en) 1992-08-24 1994-05-24 Xerox Corporation Imaging members and processes for the preparation thereof
EP0589640A1 (en) 1992-09-24 1994-03-30 General Electric Company Macrocyclic molding compositions
US5830541A (en) 1992-09-30 1998-11-03 The Dow Chemical Company Process for electrostatically painting polymers containing a non-volatile metal salt conductivity inducing material
US5231161A (en) 1992-10-22 1993-07-27 General Electric Company Method for preparation of macrocyclic poly(alkylene dicarboxylate) oligomers from bis(hydroxyalkyl) dicarboxylates
US5321117A (en) 1992-11-19 1994-06-14 General Electric Company Macrocyclic polyester oligomer preparation with Lewis acid as catalyst
US5300590A (en) 1992-11-30 1994-04-05 General Electric Company Macrocyclic polyester compositions convertible to linear polyesters of improved integrity
DE4244008C2 (en) 1992-12-24 1997-04-24 Bayer Ag Process for the production of aliphatic-aromatic polycarbonates
ES2142379T3 (en) 1993-07-22 2000-04-16 Gen Electric CYCLIC PHOSPHITES AS STABILIZERS OF POLYMERS.
US5420226A (en) 1993-08-11 1995-05-30 Xerox Corporation Method of making photoreceptor charge transport layers
EP0655476A1 (en) 1993-11-29 1995-05-31 General Electric Company Fibrous preforms containing cyclic polyester oligomers
US5968642A (en) 1993-12-22 1999-10-19 Dupont-Mitsui Fluorochemicals Co., Ltd. Article having a water-repellent fluororesin surface, and method for manufacturing the same
US5348985A (en) 1994-01-18 1994-09-20 General Electric Company Process for making thermoplastic polyester foams
US5356984A (en) 1994-02-14 1994-10-18 General Electric Company Method for molding magnets and compositions for use therein
GB9409293D0 (en) 1994-05-10 1994-06-29 Ici Plc Polyesters
US5389719A (en) 1994-06-20 1995-02-14 General Electric Company Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers
US5387666A (en) 1994-06-20 1995-02-07 General Electric Company Branched polyesters prepared from macrocyclic poly(Alkylene Dicarboxylate) oligomers
US5386037A (en) 1994-06-20 1995-01-31 General Electric Company Trisstannoxanes useful for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers
US5407984A (en) 1994-08-31 1995-04-18 General Electric Company Process for preparing macrocyclic polyester oligomers
US5646454A (en) * 1994-09-24 1997-07-08 Robert Bosch Gmbh Electronic safety device for vehicle occupants including a memory device for storing fault conditions and associated control commands
US5446122A (en) 1994-11-30 1995-08-29 General Electric Company Process for preparing macrocyclic polyesters
US5434244A (en) 1994-12-09 1995-07-18 General Electric Company Process for isolating macrocyclic polyester oligomers
US5527976A (en) 1995-01-12 1996-06-18 General Electric Company Method for polymerizing macrocyclic poly(alkylene dicarboxylate) oligomers
US5530052A (en) 1995-04-03 1996-06-25 General Electric Company Layered minerals and compositions comprising the same
US5605979A (en) 1995-05-22 1997-02-25 Bayer Corporation Method for modifying the backbone of polymeric resins
US5693722A (en) 1995-05-22 1997-12-02 Bayer Corporation Method for modifying the backbone of polymeric resins
JPH08323748A (en) * 1995-05-29 1996-12-10 Toho Rayon Co Ltd Molding material and manufacture thereof
US5519108A (en) 1995-06-07 1996-05-21 Industrial Technology Research Institute Catalytic compositions containing tetrabutyl titanate and a mixture of cocatalysts for the preparation of poly(butylene terephthalate)
US5498651A (en) 1995-06-19 1996-03-12 General Electric Company Method for polymerizing macrocyclic polyester oligomers
US5663282A (en) 1995-11-13 1997-09-02 General Electric Company Method for producing polyesters
DE19546500A1 (en) * 1995-12-13 1997-06-19 Hoechst Ag Production of cyclo-olefin copolymers e.g. for pipes
US5648454A (en) 1996-02-14 1997-07-15 General Electric Company Process for producing high ductile polyesters
US5710086A (en) 1996-03-20 1998-01-20 General Electric Company Titanate catalysts
US5668186A (en) 1996-03-20 1997-09-16 General Electric Company Process for depolymerizing polyesters
US5661214A (en) 1996-08-05 1997-08-26 General Electric Company Titanate esters useful as polymerization initiators for macrocylic polyester oligomers
US5700888A (en) 1996-11-07 1997-12-23 Bridgestone Corporation Synthesis of macrocyclic polymers having low hysteresis compounded properties
US5795423A (en) 1996-12-05 1998-08-18 Ford Global Technologies, Inc. Method for manufacturing a fiber reinforced article
US6395865B2 (en) * 1997-12-05 2002-05-28 Continental Pet Technologies Inc Process for making pen/pet blends and transparent articles therefrom
DE19651445A1 (en) 1996-12-11 1998-06-18 Bayer Ag Mixtures of amide group-containing polycarbonate polycycles and their preparation
US5760161A (en) 1997-02-10 1998-06-02 Albemarle Corporation Process for making unsaturated, thermosetting, brominated phthalic anhydride/polyol polyester resins
DE19727271A1 (en) 1997-06-26 1999-01-07 Basf Ag Functionalized carbon monoxide copolymers
CA2309995A1 (en) * 1997-11-17 1999-05-27 Delta Airlines, Inc. Surface treatments for articles and vehicles
JP3373164B2 (en) * 1997-12-26 2003-02-04 住友ベークライト株式会社 Method for producing prepreg and laminate
US6124412A (en) 1997-12-29 2000-09-26 Saudi Basic Industries Corporation Alumoxane-enhanced, supported ziegler-natta polymerization catalysts, methods of making same, processes of using same and polymers produced therefrom
DE19808843C2 (en) 1998-03-03 2003-10-02 Degussa Process for the preparation of macrocyclic esters
US6297330B1 (en) 1998-08-28 2001-10-02 E. I. Du Pont De Nemours And Company Polymerizations based on cyclic oligomer
US6080834A (en) 1999-04-16 2000-06-27 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith
JP2001031846A (en) 1999-07-19 2001-02-06 Unitika Ltd Polyester composition and its production
US6376026B1 (en) 1999-12-20 2002-04-23 Rohm And Haas Company Method of coating with powders comprising macrocyclic oligomers
US6369157B1 (en) * 2000-01-21 2002-04-09 Cyclics Corporation Blend material including macrocyclic polyester oligomers and processes for polymerizing the same
US6420047B2 (en) * 2000-01-21 2002-07-16 Cyclics Corporation Macrocyclic polyester oligomers and processes for polymerizing the same
DE10041198B4 (en) * 2000-08-23 2004-01-15 Symrise Gmbh & Co. Kg Process for the preparation of macrocyclic esters
CN1217974C (en) * 2000-09-01 2005-09-07 赛克利克斯公司 Methods for converting linear polyesters to macrocyclic oligoester compositions and macrocyclic oligoesters
US6436548B1 (en) * 2000-09-12 2002-08-20 Cyclics Corporation Species modification in macrocyclic polyester oligomers, and compositions prepared thereby
US6376025B1 (en) * 2000-09-14 2002-04-23 Phillip Mark Method and system for applying minute bristles to a flow through applicator
US6420048B1 (en) * 2001-06-05 2002-07-16 Cyclics Corporation High molecular weight copolyesters from macrocyclic oligoesters and cyclic esters
US6436549B1 (en) * 2001-07-16 2002-08-20 Cyclics Corporation Block copolymers from macrocyclic oligoesters and dihydroxyl-functionalized polymers
US20040018883A1 (en) * 2002-07-17 2004-01-29 Robert Toth Bowling tournament method
CN100392006C (en) * 2002-12-20 2008-06-04 陶氏环球技术公司 Polymerized macrocyclic oligomer nanocomposite compositions
JP2007521341A (en) * 2002-12-23 2007-08-02 ダウ グローバル テクノロジーズ インコーポレイティド SMC molding method

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WO2001053379A1 (en) 2001-07-26
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DE60109575T2 (en) 2006-02-09
US20050245676A1 (en) 2005-11-03
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US6420047B2 (en) 2002-07-16
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