WO2001098231A1 - Concrete material for greening - Google Patents

Concrete material for greening Download PDF

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Publication number
WO2001098231A1
WO2001098231A1 PCT/JP2001/005359 JP0105359W WO0198231A1 WO 2001098231 A1 WO2001098231 A1 WO 2001098231A1 JP 0105359 W JP0105359 W JP 0105359W WO 0198231 A1 WO0198231 A1 WO 0198231A1
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Prior art keywords
concrete
aggregate
silica
greening
concrete material
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PCT/JP2001/005359
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French (fr)
Japanese (ja)
Inventor
Reizo Hoshino
Original Assignee
Kabushiki Kaisha Toho Material
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Priority claimed from JP2000190186A external-priority patent/JP3623718B2/en
Priority claimed from JP2001158995A external-priority patent/JP2002345332A/en
Application filed by Kabushiki Kaisha Toho Material filed Critical Kabushiki Kaisha Toho Material
Publication of WO2001098231A1 publication Critical patent/WO2001098231A1/en

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00758Uses not provided for elsewhere in C04B2111/00 for agri-, sylvi- or piscicultural or cattle-breeding applications
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to a concrete material for greening used on a slope of a land, a surface of a building, a surface of a civil engineering structure, and a river bay. Background art
  • aggregate having a relatively large particle size for example, a porous material obtained by mixing at a ratio of about 4 to 6 with cement 1 is solidified, and its surface layer and aggregate are solidified. Soil was placed in the gap, and sown in the soil to germinate and survive lawns and other plants.
  • conventional porous concrete uses coarse aggregate with high specific gravity and large particle size, such as cement and crushed stones and gravel, so it is not only inconvenient to transport the material, but also to handle and to construct it.
  • cement is strong in alkali and used for greening, germination of plant seeds and root activity There was a drawback that wearing was hindered.
  • the present invention provides a concrete material with the addition of aggregates and additives made of siliceous minerals to cement to provide the concrete with water absorption and water retention, and to increase the seeds of the plant.
  • the purpose is to promote the adhesion and germination of roots, the roots to take root, etc., and to facilitate the greening of concrete construction surfaces such as buildings, civil engineering structures, building surfaces, and slopes of rivers and roads.
  • a second object of the present invention is to use a coarse aggregate of sili-force to maintain water retention while maintaining water permeability, thereby exhibiting an effect on rainwater absorption and spring water discharge. It is an object of the present invention to provide a concrete material that can smoothly exchange water when used as a revetment material for wetlands, such as a biotope, and can also prevent deterioration of water quality.
  • a third object of the present invention is to increase the water absorption and water retention by adding an organic additive such as wood chips to a concrete material as a water retention aid, and to function as a fertilizer component for a green plant.
  • an organic additive such as wood chips
  • the concrete should be made porous to further enhance plant survival, permeability and water retention.
  • the fourth object of the present invention is to enable the production of lightweight porous concrete that is easy to handle before and after construction and before and after molding, and to reduce the weight of aggregate when used for spraying.
  • the purpose is to make the concrete adhere without being repelled to the ground or the base net, and to further improve the adhesion by mixing plant fiber materials.
  • a fifth object of the present invention is to reduce or reduce the degree of arsenic by mixing or adding a non-alliable material such as natural organic fiber, and to be suitable for germination and growth of plants and
  • An object of the present invention is to obtain a porous concrete excellent in both water retention and water retention.
  • the purpose is to provide convenience such as making the material itself lighter by using lightweight aggregates, and allowing it to be handled by being packed in a bag in a state of being mixed in a predetermined mixing ratio in advance.
  • the concrete material for greening of the present invention comprises silica as a main component in a concrete material in which cement and aggregate are blended, in order to provide one or both of the functions of the aggregate and the concrete additive.
  • a silica-based mineral is added and blended.
  • the above-mentioned concrete additive is a silica-based mineral ground into a powder, and the aggregate may be mainly a silica-based mineral.
  • a silica-based mineral pulverized in a powder form may be used as the concrete additive.
  • the aggregate may be crushed stone, gravel or other common aggregate having a high specific gravity, or a lightweight silica-based aggregate. May contain minerals.
  • a powder-based powder-based mineral can be added as a concrete additive.
  • Aggregates include crushed stones, gravel and other ordinary aggregates, and silica-based minerals.
  • silica-based minerals that have been pulverized into a powder form are added as concrete additives. All silica-based minerals are composed of one or more of lightweight diatomaceous earth, perlite, and loess.
  • pumice, artificial aggregate, and other materials containing one or two or more mineral lightweight aggregates of low specific gravity can be added as aggregates.
  • Other bamboo, palm, wood, etc. as water retention aids that give water retention to concrete It is also possible to add a material obtained by mixing one or more of fibrous materials, peat moss and other vegetable fibrous materials obtained by pulverizing the above.
  • ordinary Portland cement is used as the cement
  • crushed stone or gravel having a generally used particle size, and fine-grained sand can be used as needed as the ordinary aggregate.
  • minerals containing other amounts of S i0 2 it is possible to use loess (S i0 2 content 5 0-7 0%).
  • the above silica-based minerals may be used in the form of an aggregate having a particle size of 0.1 to 30 mm as an appropriate aggregate or mixed state.
  • a powder-like additive was added by crushing diatomaceous earth or perlite containing a large amount of silica to the same particle size as cement (for example, 45 / m) for the purpose of capturing the silica component to provide the above functionality. May be.
  • the silica component desirably has a content of 60% or more and 70% or more as a whole silica-based mineral in order to provide water retention and root activation at a predetermined mixing ratio to cement or the like.
  • the additives are mainly used for this adjustment.
  • These silica components also neutralize the alkali of the cement and promote the germination and growth of plant seeds.
  • Diatomaceous earth and perlite used as silica-based minerals are porous and are generally used as filter materials, water-absorbent materials, and soil improvement materials. It may be used as a deodorant wall material or the like by making use of its adsorptivity.
  • the silica component itself which is hardly present in cement, is a neutral or weakly acidic component that is indispensable for germination and growth of plants.
  • adding this to concrete at a suitable amount In addition to the effect of premature hardening of the concrete, when organic materials such as wood chips are mixed in to increase the water retention of the concrete as described later, the decomposition in the concrete is accelerated and the concrete is made porous. There is an effect that encourages. This is presumed to be due to the adhesion of bacteria along with moisture and air to the voids in the diatomaceous earth. This is supported by the fact that concrete becomes porous. This means that, in addition to the effect of diatomaceous earth g on promoting germination and growth on vegetation, diatomaceous earth has another effect of accelerating the decomposition of organic matter in concrete and promoting plant growth. Also means.
  • the silica component is one of the causes of the aggregate-aggregate reaction in concrete, but greening concrete itself generally does not require high strength as a structure itself, and is mainly There is no particular problem as it is used for the purpose of preventing the surface layer from flowing out and maintaining the shape until the greening of the greening surface is completed.
  • sepiolite which has a fibrous shape and has a certain level of water absorption for imparting tackiness and preventing cracking, etc., by retaining the water retention of concrete
  • a small amount of bentonite may be added as needed to promote water stoppage.
  • organic materials that provide water retention to concrete and that can also be used as fertilizer components for vegetation as well as decomposing over time for example, fibrous materials made by grinding bamboo, palm, wood, etc., peat moss, and other vegetable fibrous materials) ) Can be added alone or in combination of two or more.
  • a concrete material obtained by adding and kneading diatomaceous earth grains, diatomaceous earth powder, pearlite grains, etc., as a silica-based mineral, and zeolite grains as other aggregates, as appropriate, is mixed with cement and ordinary aggregate.
  • Blocks of X180 X200 (mm) were formed as samples A to E, and the same amount of western turf seed was directly and uniformly sown directly on the upper surface, and germinated and grown in the outdoor environment in Tokyo. Examples of cases (with appropriate watering to prevent seeds from drying) are described in Tables 1 and 2.
  • Table 1 shows the materials used in Samples A to E and their ingredients
  • Table 2 shows the observation results of the germination rate, growth degree, and root vigor of each sample (concrete block). is there.
  • the observation items in Table 2 are observations from the point of germination at about i O mm after seeding to the growth of about 40 to 50 mm on average.
  • the germination rate indicates the germination status of the entire upper surface of the block. Performed by eye measurement.
  • the roots after germination are marked with an X mark when the germinated turf is pulled out with little finger when pulled out with a finger, and a ⁇ mark when more than half of the germinated turf feels a certain resistance to pulling out. Indicates that stems were cut due to pull-out resistance. ⁇ table 1 ⁇
  • coarse aggregates containing more than 10 to 20 mm of crushed stones are more likely to germinate with more voids than concrete with only small crushed stones (for example, 5 mm or less).
  • Silica-based mineral was used as an aggregate having a coarse particle size of, for example, 3 to 30 mm. It was found that good results were obtained in germination, growth, and root activation.
  • These lightweight aggregates had specific gravities in the range of 0.38 to 0.5, low specific gravity to cement or water, and particle sizes of about 1 to 20 mm. Each material can absorb and hold 1.4 to 1.5 times the moisture of its volume. Minerals of weak acidity, neutrality, and weak alkalinity (eg, pH 6.0 to 8.0) are feldspar powder and serpentine to neutralize the strength of the cement while compensating for or reducing the strength of the cement. An adjusting material composed of rock powder or the like can be added.
  • bamboo, palm, crushed wood and other natural organic fibers such as peat moss are also used as water retention aids. Mixed.
  • These natural organic fibers use bamboo, palm, etc., crushed fibers with a width of about 0.1 to 5 mm and a length of about 30 to 10 O mm. Most of peat moss and the like are threadlike and 4 to 5 mm. It has a length of Further, the natural organic fiber is dried to a moisture content of about 30 to 50% and is weakly acidic, for example, at a pH of about 4 to 6 in this state.
  • the compounding ratio (weight basis) according to the use of each of the above materials is generally as follows, and water is added at a ratio of 25 to 30% to all of these materials.
  • the purpose and purpose of use such as increasing the cement content to 25 to 30% and reducing the amount of aggregate and dietary fiber It is acceptable to change the composition of the materials to be used within the range that does not impair the function as greening concrete.
  • fresh concrete plan City, although mixed Te by ⁇ concrete mixer, of the mixing cement And the lightweight aggregate and water retention aid can be pre-packed in a bag or other container at a mixing ratio according to the purpose of use.
  • the material mixed with water as described above is 30 to 4 Omm thick in cases where the ground net is stretched on steep slopes, etc. when used as greening concrete, and is a gentle slope with no net
  • Each is spray-coated with a thickness of about 20 to 25 mm.
  • the lightweight concrete molding obtained as described above has a compressive strength of 15 to 25 kg Zcm 2 after one week of the material age, and maintains the strength higher than that of the conventional porous concrete for greening.
  • the porosity is 30 to 40%, which is well above the porous porosity standard of 25%.
  • a slurry-like filler consisting of water, viscosity modifier, organic fiber material, slow-release fertilizer, etc. is sprayed on the surface. Filling, and spraying the soil layer from the top surface to form the surface base.
  • the greening concrete material of the present invention can be formed or constructed with concrete such as a building or civil engineering structure, a road or river slope, and the like. It can be used as a material for construction to germinate, survive and green the plants.

Abstract

A concrete material for greening, which comprises a concrete material having cement and an aggregate compounded therein and, added thereto as a granular filler or a powdery additive, a silica based mineral being excellent in water absorbing property, water holding property and the like. Silica based minerals include diatomaceous earth, pearlite and other minerals containing a major amount of silica. As the aggregate, an ordinary aggregate such as crushed stones or ballast can be used. The aggregate may be used together with the above silica based filler. A light, porous concrete material can be produced by using only lightweight aggregates such as diatomaceous earth and pearlite. One or more of fibrous materials prepared by crushing bamboo, coconuts and wood material and the like and plant fiber materials such as those from Peat Moss can be added as water holding aids for supplementing the water holding property of concrete.

Description

明 細 書 緑化用コンクリート材 技術分野  Description Technical material for greening concrete
この発明は造成地の法面, 建築物表面, 土木構造物表面, 河川湾岸等 に用いる緑化用のコンクリ一ト材に関する。 背景技術  BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a concrete material for greening used on a slope of a land, a surface of a building, a surface of a civil engineering structure, and a river bay. Background art
従来上記のような緑化コンクリートとしては比較的粒径の大きい骨材 を、 例えばセメント 1に対して 4〜6程度の割合で混合してポーラス状 にしたものを固化させ、 その表層部分や骨材間隙部分に土を入れ、 その 土の部分に播種して芝生類その他の草木の発芽, 活着を図って.いた。  Conventionally, as the above-mentioned greening concrete, aggregate having a relatively large particle size, for example, a porous material obtained by mixing at a ratio of about 4 to 6 with cement 1 is solidified, and its surface layer and aggregate are solidified. Soil was placed in the gap, and sown in the soil to germinate and survive lawns and other plants.
しかし上記緑化用コンクリートでは、 植物が発芽してその根が間隙内 の土壌部分には根付くものの、 コンク リート自体に根が活着しない。 こ のために、 雨などによって土が流出することによって、 あるいは草木に 対する外力の作用でコンクリート面から草木が抜け落ちる等の欠点があ る。  However, in the above-mentioned greening concrete, although the plants germinate and their roots are rooted in the soil portion in the gap, the roots do not take root in the concrete itself. For this reason, there are disadvantages such as the soil flowing out due to rain or the like, or the plants falling off the concrete surface due to the action of external force on the plants.
また上記の他にセメントに粉砕木材やチップ等の有機質部材を混合し て使用し、 コンクリート表面側に根張り用の多数の小穴を穿設して緑化 を図る試みも行われているが、 この場合もコンクリート自体に根が活着 しないために、 上記同様芝等の剥離や抜け落ち等の問題がある。  In addition to the above, attempts have been made to use a mixture of cement with organic materials such as crushed wood and chips, and to drill many small holes for rooting on the concrete surface to achieve greening. In this case, the roots do not survive on the concrete itself, so that there are problems such as peeling or falling off of turf and the like as described above.
その他従来のポーラスコンクリートはセメントと砕石粒や砂利等のよ うに高比重で粒径の大きい粗骨材を用いるために、 重量が大きく材料の 運搬その他の取り扱いや施工が不便であるばかりではなく、 セメントの アルカリが強く、 緑化用として用いる場合は、 植物種子の発芽や根の活 着が妨げられるという欠点があった。 In addition, conventional porous concrete uses coarse aggregate with high specific gravity and large particle size, such as cement and crushed stones and gravel, so it is not only inconvenient to transport the material, but also to handle and to construct it. When the cement is strong in alkali and used for greening, germination of plant seeds and root activity There was a drawback that wearing was hindered.
さらに従来のポーラスコンクリートを緑化用として法面等に吹き付け 施工する場合は、 吹き付け時の衝撃によって粗骨材が岩盤施工面や下地 ネッ トに弹かれて付着しない等の問題がある。  In addition, when conventional porous concrete is sprayed on slopes for greening, there is a problem that the impact of the spraying causes coarse aggregates to be spread on the bedrock surface and the ground net and not adhere thereto.
上記のような問題に対してこの発明は、 コンクリート材としてセメン トにシリ力系鉱物からなる骨材や添加材を添加することにより、 コンク リー トの吸水性や保水性を与え、 植物の種子の付着や発芽, 根の活着等 を促し、 建築物や土木構造物, 築造物表面, 河川や道路の法面等のよう 'なコンクリート施工面の緑化を容易にすることを目的としている。  In order to solve the above-mentioned problems, the present invention provides a concrete material with the addition of aggregates and additives made of siliceous minerals to cement to provide the concrete with water absorption and water retention, and to increase the seeds of the plant. The purpose is to promote the adhesion and germination of roots, the roots to take root, etc., and to facilitate the greening of concrete construction surfaces such as buildings, civil engineering structures, building surfaces, and slopes of rivers and roads.
この発明の第 2番目の目的は、 シリ力系の粗骨材を用いることにより 、 保水性を保ちながら透水性を保たせて雨水の吸収や湧水の放出にも効 果を発揮できるものとし、 ビオトープ等のように湿地帯の護岸材として 使用した場合の水の交換をスムースに行わせ、 水質劣化の防止も実現で きるコンクリート材を提供することである。  A second object of the present invention is to use a coarse aggregate of sili-force to maintain water retention while maintaining water permeability, thereby exhibiting an effect on rainwater absorption and spring water discharge. It is an object of the present invention to provide a concrete material that can smoothly exchange water when used as a revetment material for wetlands, such as a biotope, and can also prevent deterioration of water quality.
この発明の第 3番目の目的は、 コンクリート材に木材チップ等の有機 質添加材を保水助材として添加することにより、 吸水性, 保水性を高め るとともに、 緑化植物の肥料成分としても機能させるほか、 分解後はコ ンクリートの多孔質化を実現させて、 植物の活着ゃ透水性, 保水性をさ らに高めることである。  A third object of the present invention is to increase the water absorption and water retention by adding an organic additive such as wood chips to a concrete material as a water retention aid, and to function as a fertilizer component for a green plant. In addition, after decomposition, the concrete should be made porous to further enhance plant survival, permeability and water retention.
この発明の第 4番目の目的は、 施工前や成形の前後を問わず取り扱い 容易な軽量なポーラスコンクリートの製造を可能にさせるほか、 吹付用 として用いる場合も、 骨材を軽量にすることにより岩盤や下地ネットに 弾かれることなくコンクリートを付着させ、 植物繊維材等を混入するこ とにより、 一層付着性を良くすることである。  The fourth object of the present invention is to enable the production of lightweight porous concrete that is easy to handle before and after construction and before and after molding, and to reduce the weight of aggregate when used for spraying. The purpose is to make the concrete adhere without being repelled to the ground or the base net, and to further improve the adhesion by mixing plant fiber materials.
この発明の第 5番目の目的は、 天然有機物繊維等の非アル力リ性材料 を混入又は添加してアル力リ度を低く し、 植物の発芽や育成に適し且つ 含水性保水性共に優れたポーラスコンクリートを得ることである。 A fifth object of the present invention is to reduce or reduce the degree of arsenic by mixing or adding a non-alliable material such as natural organic fiber, and to be suitable for germination and growth of plants and An object of the present invention is to obtain a porous concrete excellent in both water retention and water retention.
その他、 軽量骨材によって材料自体を軽量にし、 予め所定配合比で配 合された状態で袋詰めして取り扱うことを可能にする等の便利性を与え る目的もある。  In addition, the purpose is to provide convenience such as making the material itself lighter by using lightweight aggregates, and allowing it to be handled by being packed in a bag in a state of being mixed in a predetermined mixing ratio in advance.
上で述べた目的以外のこの発明の他の目的は、 発明の実施の形態の中 で明ら力 こされる。 発明の開示  Other objects of the present invention other than those described above will be apparent in the embodiments of the present invention. Disclosure of the invention
この発明の緑化用コンクリ一ト材は、 セメントと骨材を配合するコン クリート材において、 骨材とコンクリート添加材の機能のいずれか一方 又は両方の機能をもたせるために、 シリカを主成分とするシリカ系鉱物 を添加配合するものである。 上記コンクリート添加材はパウダ一状に粉 碎されたシリカ系鉱物であり、 骨材は主としてシリカ系鉱物の場合もあ る。  The concrete material for greening of the present invention comprises silica as a main component in a concrete material in which cement and aggregate are blended, in order to provide one or both of the functions of the aggregate and the concrete additive. A silica-based mineral is added and blended. The above-mentioned concrete additive is a silica-based mineral ground into a powder, and the aggregate may be mainly a silica-based mineral.
また、 該骨材とは別にパウダー状に粉砕されたシリカ系鉱物をコンク リート添加材とする場合があり、 骨材は碎石, 砂利その他の高比重の普 通骨材と、 軽量のシリカ系鉱物とを含む場合もある。  In addition, apart from the aggregate, a silica-based mineral pulverized in a powder form may be used as the concrete additive. The aggregate may be crushed stone, gravel or other common aggregate having a high specific gravity, or a lightweight silica-based aggregate. May contain minerals.
上記普通骨材にコンクリート添加材としてパウダー状に粉枠されたシ リ力系鉱物を添加することもできる。  To the above-mentioned ordinary aggregate, a powder-based powder-based mineral can be added as a concrete additive.
骨材が砕石, 砂利その他の普通骨材とシリカ系鉱物とを含み、 コンク リート添加材としてパゥダー状に粉砕されたシリカ系鉱物を添加する場 合もある。 シリカ系鉱物はいずれも軽量な珪藻土, パーライ ト, 黄土の うち一種又は二種以上配合した材料からなっている。  Aggregates include crushed stones, gravel and other ordinary aggregates, and silica-based minerals. In some cases, silica-based minerals that have been pulverized into a powder form are added as concrete additives. All silica-based minerals are composed of one or more of lightweight diatomaceous earth, perlite, and loess.
上記のほか、 骨材として軽石, 人工骨材その他の低比重の鉱物性軽量 骨材を一種又は二種以上配合した材料を添加することもできる。 その他 コンクリートに保水性を付与する保水助材として竹材, やし材, 木材等 を粉砕した繊維質材, ピートモスその他の植物性繊維質材のいずれか一 種又は二種以上配合した材料を添加することもできる。 In addition to the above, pumice, artificial aggregate, and other materials containing one or two or more mineral lightweight aggregates of low specific gravity can be added as aggregates. Other Bamboo, palm, wood, etc. as water retention aids that give water retention to concrete It is also possible to add a material obtained by mixing one or more of fibrous materials, peat moss and other vegetable fibrous materials obtained by pulverizing the above.
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
次に本発明の実施形態につき説明する。 この発明では、 セメントとし て普通ポルトランドセメントを用い、 普通骨材としては、 一般に使用さ れる粒径の砕石又は砂利、 必要に応じて細粒砂を用いることができる。  Next, an embodiment of the present invention will be described. In the present invention, ordinary Portland cement is used as the cement, and crushed stone or gravel having a generally used particle size, and fine-grained sand can be used as needed as the ordinary aggregate.
コンクリ一トに植物の根の活着やそのための保水性を付与する鉱物と しては、 多量の珪酸を含有するシリカ系の鉱物、 例えば珪藻土 (S i02 含有量 8 0 %以上), パーライ ト =真珠岩 (同 7 0 %以上), パーミキュ ライ ト =蛭石 (同 3 6 %以上) 等が使用される。 その他多量の S i02を 含有する鉱物として、 黄土 (S i02含有量 5 0〜 7 0 % ) の使用が可能 である。 Concrete is a mineral that imparts water retention of the rooting and therefor plant roots in Ichito, minerals silica containing a large amount of silicic acid, for example kieselguhr (S i0 2 content 80% or higher), pearlite = Perlite (70% or more), permiculite = vermiculite (36% or more), etc. are used. As minerals containing other amounts of S i0 2, it is possible to use loess (S i0 2 content 5 0-7 0%).
上記シリカ系鉱物は、 緑化用に用いられる植物の種類やその他の条件 に応じて、 例えば粒径 0 . 1〜3 0 m mのものを骨材として適宜粒選又 は混合状態で使用するほか、 上記機能性付与のためのシリカ成分捕給を 目的として、 シリカ成分を多量に含む珪藻土やパーライ トをセメントと 同程度の粒径 (例えば 4 5 / m ) に粉砕したパウダー状の添加材を添加 する場合がある。  Depending on the type of plant used for revegetation and other conditions, for example, the above silica-based minerals may be used in the form of an aggregate having a particle size of 0.1 to 30 mm as an appropriate aggregate or mixed state. A powder-like additive was added by crushing diatomaceous earth or perlite containing a large amount of silica to the same particle size as cement (for example, 45 / m) for the purpose of capturing the silica component to provide the above functionality. May be.
なお、 このシリカ成分は、 セメント等に対する所定配合割合の下で保 水性や根の活着付与のためにシリカ系鉱物全体として 6 0 %以上、 7 0 %以上の含有量を備えていることが望ましく、 添加材は主としてこの調 整の.ために使用される。 またこれらのシリカ成分はセメントのアルカリ を中和し、 植物種子の発芽及ぴ育成を助長する。  The silica component desirably has a content of 60% or more and 70% or more as a whole silica-based mineral in order to provide water retention and root activation at a predetermined mixing ratio to cement or the like. The additives are mainly used for this adjustment. These silica components also neutralize the alkali of the cement and promote the germination and growth of plant seeds.
なお、 シリカ系の鉱物として用いる珪藻土やパーライ トは多孔質で、 一般に濾過材, 吸水材, 土壌改良材として用いられるが、 軽量性又はそ の吸着性を活かして防臭壁材等として用いることもある。 Diatomaceous earth and perlite used as silica-based minerals are porous and are generally used as filter materials, water-absorbent materials, and soil improvement materials. It may be used as a deodorant wall material or the like by making use of its adsorptivity.
セメント中には殆ど存在しないシリカ成分そのものが、 中性か弱酸性 で植物の発芽や成育に不可欠の成分であるとともに、 発明者の知見によ れば、 これをコンクリートに適量を保って添加すると、 コンクリートの 早期硬化の作用があるほか、 後述するようにコンクリートの保水性を高 めるために木材チップ等の有機質材を混入した場合は、 コンクリート内 における分解を早め、 コンクリートの多孔質化を促す効果がみられる。 これは珪藻土内の空隙部に水分や空気と共にバクテリアの付着を促す ことによるものと推測され、 通常は長期にわたって残存するコンクリー ト內の木材チップ等が、 約 6〜 1 0ヶ月前後で分解されてコンクリート がポーラス化する事実からも裏付けられる。 このことは珪藻土 g体がも つ植生への発芽成育の促進効果のほかに、 珪藻土がコンクリ一ト内の有 機物の分解を早めて、 植物の成長を促すという別の効果をもたらすこと をも意味するものである。  The silica component itself, which is hardly present in cement, is a neutral or weakly acidic component that is indispensable for germination and growth of plants.According to the knowledge of the inventor, according to the knowledge of the inventor, adding this to concrete at a suitable amount In addition to the effect of premature hardening of the concrete, when organic materials such as wood chips are mixed in to increase the water retention of the concrete as described later, the decomposition in the concrete is accelerated and the concrete is made porous. There is an effect that encourages. This is presumed to be due to the adhesion of bacteria along with moisture and air to the voids in the diatomaceous earth. This is supported by the fact that concrete becomes porous. This means that, in addition to the effect of diatomaceous earth g on promoting germination and growth on vegetation, diatomaceous earth has another effect of accelerating the decomposition of organic matter in concrete and promoting plant growth. Also means.
そして珪藻土と同様に多量のシリカ成分を含む多孔質材であるパーラ ィ トゃパ一ミキュライ トも、 コンクリート材に添加すると珪藻土と略同 様な機能を発揮することが確認された。  In addition, it was confirmed that, even when diatomaceous earth was added to a concrete material, perlatopamiculeite, which is a porous material containing a large amount of silica components, exhibited almost the same function as diatomaceous earth.
なお、 シリカ成分はコンクリ一トにおけるアル力リ骨材反応の原因物' 質の一つであるが、 緑化コンクリートは、 一般にそれ自体が構造物とし ての高い強度を求められるものではなく、 主として緑化施工面の緑化が 完成する迄の表層の流出防止や形状保持の目的で使用されるので特に問 題はない。  The silica component is one of the causes of the aggregate-aggregate reaction in concrete, but greening concrete itself generally does not require high strength as a structure itself, and is mainly There is no particular problem as it is used for the purpose of preventing the surface layer from flowing out and maintaining the shape until the greening of the greening surface is completed.
また上記の例のほか、 コンクリートの保水性を捕い粘着性の付与、 ひ ぴ割れ防止等のために繊維状をなし一定の吸水性を備えているセピオラ ィ トを、 さらに保水による膨潤化を促して止水性を付与するために少量 のベントナイ トをそれぞれ必要に応じて少量添加する場合がある。 その他、 コンクリートへの保水性を付与し、 経時分解とともに植生の ための肥料成分ともなる有機質材 (例えば竹材, やし材, 木材等を粉砕 してなる繊維質材, ピートモスその他の植物性繊維質材) を一種又は二 種以上混合したものを添加することもできる。 In addition to the above examples, sepiolite, which has a fibrous shape and has a certain level of water absorption for imparting tackiness and preventing cracking, etc., by retaining the water retention of concrete A small amount of bentonite may be added as needed to promote water stoppage. In addition, organic materials that provide water retention to concrete and that can also be used as fertilizer components for vegetation as well as decomposing over time (for example, fibrous materials made by grinding bamboo, palm, wood, etc., peat moss, and other vegetable fibrous materials) ) Can be added alone or in combination of two or more.
次に、 セメントと普通骨材に対して、 シリカ系鉱物として珪藻土粒, 珪藻土パウダー, パーライ ト粒等をその他の骨材としてゼォライ ト粒を それぞれ適宜組み合わせて添加混練したコンクリート材で、 約 3 0 X 1 8 0 X 2 0 0 ( m m) のブロックを試料 A〜 Eとして形成し、 それぞれ 上面に直接同量の西洋芝の種を均一に播種して東京都内の屋外環境で発 芽成長させた場合 (伹し、 種の乾燥を防止する こめ適度の散水を伴う) の実施例を表 1, 表 2によって説明する。  Next, a concrete material obtained by adding and kneading diatomaceous earth grains, diatomaceous earth powder, pearlite grains, etc., as a silica-based mineral, and zeolite grains as other aggregates, as appropriate, is mixed with cement and ordinary aggregate. Blocks of X180 X200 (mm) were formed as samples A to E, and the same amount of western turf seed was directly and uniformly sown directly on the upper surface, and germinated and grown in the outdoor environment in Tokyo. Examples of cases (with appropriate watering to prevent seeds from drying) are described in Tables 1 and 2.
表 1は試料 A〜Eの使用材料とその配合料を示し、 表 2は各試料の発 芽率, 成長度合, 各試料 (コンクリ一トブロック) に対する根の活着度 合の観察結果を示すものである。  Table 1 shows the materials used in Samples A to E and their ingredients, and Table 2 shows the observation results of the germination rate, growth degree, and root vigor of each sample (concrete block). is there.
表 2における各観察項目は、 播種後において約 i O m mに発芽した時 点から平均約 4 0〜 5 0 m m前後に成長する迄を観察したもので、 発芽 率はプロック上面全体の発芽状況を目測することによって行った。  The observation items in Table 2 are observations from the point of germination at about i O mm after seeding to the growth of about 40 to 50 mm on average.The germination rate indicates the germination status of the entire upper surface of the block. Performed by eye measurement.
また発芽後の根の活着は、 発芽した芝を指で引き抜いた際に殆ど抵抗 なく引き抜けるものを X印で、 全体の半数以上が一定の引き抜き抵抗を 感じるものを△印で、 さらに大半の芝が引き抜き抵抗によって茎の切断 を生じるものを〇印で表した。 【表 1 】 In addition, the roots after germination are marked with an X mark when the germinated turf is pulled out with little finger when pulled out with a finger, and a △ mark when more than half of the germinated turf feels a certain resistance to pulling out. Indicates that stems were cut due to pull-out resistance. 【table 1 】
Figure imgf000009_0001
Figure imgf000009_0001
【表 2】[Table 2]
'比較  'Compare
 Year
Figure imgf000010_0001
Figure imgf000010_0001
この実験は試料 A〜Eの播種日と観察日が異なり外気温や湿度, 日照 量等の発芽及ぴ成育の環境条件が共通しないために必ずしも単純比較で きない部分もあるが、 全体としての傾向や、 実用性の可否についての観 察結果の判断は可能であり、 A〜Eいずれの試料も、 夏や冬の酷暑期や 厳寒期を除けば、 概ね実用に耐えるものである。  In this experiment, the seeding and observation dates of Samples A to E were different, and the environmental conditions for germination and growth, such as outside temperature, humidity, and sunlight, were not common. It is possible to judge the trends and the results of observations on the feasibility of practical use, and all of the samples A to E generally withstand practical use except for the extremely hot and cold seasons in summer and winter.
同時に行った普通骨材と普通ポルトランドセメントで成形したもの、 シリカ (珪酸成分) が少なく又は殆ど含有しない骨材や添加材 (パウダ 一) の添加では播種後 7日前後経過しても殆ど発芽せず、 発芽しても 2 〜3 日以内に枯死することも確認されている。 Simultaneous addition of ordinary aggregate and ordinary Portland cement, addition of aggregates containing little or no silica (silicic acid component) and additives (powder 1) almost germinated even after about 7 days after seeding. Not germinated 2 It has been confirmed that it dies within 3 days.
また全体的に砕石経が小経 (例えば 5 m m以下) のもののみの場合よ り、 1 0〜 2 0 m mのものを多く含んだ粗骨材の場合がコンクリートの 空隙部分が多くなるとともに発芽や成長が良く、 シリカ系鉱物も例えば 3〜3 0 m mの粗粒径の骨材として用いた.場合が、 発芽, 成長, 根の活 着共に良い結果が出ることが判明した。  Also, coarse aggregates containing more than 10 to 20 mm of crushed stones are more likely to germinate with more voids than concrete with only small crushed stones (for example, 5 mm or less). Silica-based mineral was used as an aggregate having a coarse particle size of, for example, 3 to 30 mm. It was found that good results were obtained in germination, growth, and root activation.
同様に珪藻土等の多量のシリカを含む骨材や添加材の添加により好結 果が得られ、 骨材にシリカ成分の少ないもの (例えばバーミキユライ ト 等) を用いる場合は、 珪藻土パウダーの添加等でシリカ成分を補うこと が望ましいことも判明した。 また貝殻類等の粒状物を捕助骨材として使 用した場合も、 上記の場合と同様にシリ力成分の補給を行うことが望ま しい。  Similarly, good results can be obtained by the addition of aggregates and additives containing a large amount of silica such as diatomaceous earth. When using aggregates with a low silica content (for example, vermiculite), use diatomaceous earth powder. It was also found that it was desirable to supplement the silica component. Also, when granular materials such as shells are used as auxiliary aggregates, it is desirable to replenish the sily component as in the above case.
次に骨材の全部又は大半を軽量骨材のみとして取り扱い及ぴ施工性に 便利な緑化用の軽量ポーラスコンクリート材を作る場合の実施形態につ き詳述する。 この実施形態においては、 セメントとして普通ポルトラン ドセメン トを用い、 軽量骨材としては保水性のある珪藻土, パーライ ト , 人工骨材, 火山岩 (軽石) 等の一種又は二種以上のものを混合して用 レヽた。  Next, an embodiment in which all or most of the aggregate is treated as a lightweight aggregate only and a lightweight porous concrete material for greening that is convenient for workability will be described in detail. In this embodiment, ordinary portland cement is used as cement, and one or more of water-retaining diatomaceous earth, perlite, artificial aggregate, volcanic rock (pumice) and the like are mixed as lightweight aggregate. For
これらの軽量骨材は比重が 0 . 3 8〜0 . 5の範囲でセメント又は水 に対して低比重であり、 粒径は 1〜 2 0 m m位のものを用いた。 各材料 ともにその体積に対し 1 . 4〜 1 . 5倍の水分を吸収保持できる。 セメ ントの強度を補い又は低下を抑制しながらアル力リを中和するために、 弱酸性, 中性, 弱アルカリ性 (例えば p H 6 . 0〜8 . 0 ) の鉱物とし て長石粉, 蛇紋岩粉等からなる調整材を添加することができる。  These lightweight aggregates had specific gravities in the range of 0.38 to 0.5, low specific gravity to cement or water, and particle sizes of about 1 to 20 mm. Each material can absorb and hold 1.4 to 1.5 times the moisture of its volume. Minerals of weak acidity, neutrality, and weak alkalinity (eg, pH 6.0 to 8.0) are feldspar powder and serpentine to neutralize the strength of the cement while compensating for or reducing the strength of the cement. An adjusting material composed of rock powder or the like can be added.
緑化用コンクリートとしての機能を高める場合は、 さらに保水助材と して竹材, やし材, 木材等の粉碎材, ピートモス等の天然有機物繊維を 混入する。 When enhancing the function as a concrete for greening, bamboo, palm, crushed wood and other natural organic fibers such as peat moss are also used as water retention aids. Mixed.
これらの天然有機物繊維は竹材, やし材等では幅が.1〜 5 mm、 長さ が 3 0〜1 0 O mm位の粉砕繊維を利用し、 ピートモス等は大半が糸状 で 4〜5 mmの長さを備えている。 またこの天然有機物繊維は、 3 0〜 5 0 %程度の水分率となる位に.乾燥されており、 この状態で例えば p H 4〜 6位の弱酸性である。  These natural organic fibers use bamboo, palm, etc., crushed fibers with a width of about 0.1 to 5 mm and a length of about 30 to 10 O mm. Most of peat moss and the like are threadlike and 4 to 5 mm. It has a length of Further, the natural organic fiber is dried to a moisture content of about 30 to 50% and is weakly acidic, for example, at a pH of about 4 to 6 in this state.
セメントに上記のように粉砕された植物繊維を混入すると、 既に述べ た植物の活着ゃ根張り助長等のほか、 コンクリートの初期強度を増大す る作用を有するとともに、 コンクリート強アルカリを中和する機能も付 与する。  When the plant fibers crushed as described above are mixed into the cement, in addition to the above-mentioned factors such as the survival of plants and the promotion of rooting, the effect of increasing the initial strength of concrete and the function of neutralizing strong alkali in concrete Is also given.
上記各材料の用途に応じた配合比 (重量ベース) は概ね下記の通りで あり、 水はこれらの全材料に対して 2 5〜 3 0 %の比率で加える。  The compounding ratio (weight basis) according to the use of each of the above materials is generally as follows, and water is added at a ratio of 25 to 30% to all of these materials.
【表 3】 [Table 3]
使用材料配合比  Material mix ratio
Figure imgf000012_0001
Figure imgf000012_0001
上記いずれの場合も、 施工面が岩盤等のように付着し難い場合は、 セ メント量を 2 5〜3 0 %に増加し、 骨材や食物繊維配合量を減少させる 等、 用途や使用目的等に応じて、 緑化コンクリートとしての機能を損な わない範囲で使用材料の配合を変更することは差し支えない。 In any of the above cases, if the construction surface is difficult to adhere to, such as rock, etc., the purpose and purpose of use, such as increasing the cement content to 25 to 30% and reducing the amount of aggregate and dietary fiber It is acceptable to change the composition of the materials to be used within the range that does not impair the function as greening concrete.
上記材料配合されたものは施工又は成形場等に際し、 生コンプラン :ト , コンクリートミキサー等によ όて混合するが、 この配合のうちセメン トと軽量骨材及ぴ保水助材は予めその使用目的に応じた配合比で袋詰そ の他の容器に予め詰め合わせておくことが可能である。 Upon those described above materials compounded construction or molding field, etc., fresh concrete plan: City, although mixed Te by ό concrete mixer, of the mixing cement And the lightweight aggregate and water retention aid can be pre-packed in a bag or other container at a mixing ratio according to the purpose of use.
上記によって水と混合された材料は、 緑化コンクリートとして使用す る場合は、 急傾斜面等で下地ネッ トを張るケースでは 3 0〜4 O mm厚 で、 緩傾斜面でネッ トを用いない面には 2 0〜2 5 mm位の厚みでそれ ぞれ吹付被覆する。 また透水性を備えたコンク リートプロック, コンク リートタイル等のプレキャスト部材にする場合は、 最小必要強度や使用 目的に応じ 2 0〜5 O mm以上の肉厚で型成形する。  The material mixed with water as described above is 30 to 4 Omm thick in cases where the ground net is stretched on steep slopes, etc. when used as greening concrete, and is a gentle slope with no net Each is spray-coated with a thickness of about 20 to 25 mm. When making precast members such as concrete blocks and concrete tiles with water permeability, mold them with a wall thickness of 20 to 5 Omm or more according to the minimum required strength and purpose of use.
上記のようにして得られた軽量コンクリ一ト成形材は、 材令 1週間後 において圧縮強度が 1 5〜2 5 k g Zcm2あり、 従来の緑化用ポーラス コンクリート以上の強度を保っている。 また同様に空隙率は 3 0〜4 0 %あり、 ポーラスコンクリ一トの空隙率基準とされる 2 5 %を十分に上 回っている。 The lightweight concrete molding obtained as described above has a compressive strength of 15 to 25 kg Zcm 2 after one week of the material age, and maintains the strength higher than that of the conventional porous concrete for greening. Similarly, the porosity is 30 to 40%, which is well above the porous porosity standard of 25%.
緑化コンクリートとして施工面に吹き付けた後締固め硬化後、 養生を 完了してから、 水と粘性調整剤及び有機質繊維材, 緩効性肥料等からな るスラリ一状の充填材を表面に吹き付けて充填し、 さらにその上面より 客土層を吹き付けて表層基盤を形成する。  After compacting and hardening after spraying as greening concrete on the construction surface, after curing is completed, a slurry-like filler consisting of water, viscosity modifier, organic fiber material, slow-release fertilizer, etc. is sprayed on the surface. Filling, and spraying the soil layer from the top surface to form the surface base.
客土に種子を混合する場合は、 保水力があるため厚さ 2 0〜6 O mm にすることが可能であり、 芝を張り付ける場合は 2 0〜3 O mm厚に吹 き付ける。 またこの発明では、 軽量骨材によってコンクリートのアル力 リ性が緩和されているので、 コンクリートを混合する際に種子を混合す ることが可能であり、 セメントとの比重差により表面側に浮き出した種 子は十分に発芽することが確認されている。 この場合は客土層の厚みは 薄くすることが望ましい。 産業上の利用の可能性 以上の説明から明らかなように、 この発明の緑化用コンクリ一ト材は 、 建築物や土木構造物、 道路や河川の法面等のコンク リートで形成又は 施工して、 これに芝や低木等の植物を発芽, 活着させて緑化させる工事 用の材料として使用できる。 When mixing seed into the soil, it is possible to make it 20 to 6 Omm thick because of its water retention ability, and when sticking turf, spray it to 20 to 3 Omm thick. In addition, in the present invention, since the strength of the concrete is alleviated by the lightweight aggregate, it is possible to mix the seeds when mixing the concrete, and the concrete has emerged on the surface side due to a difference in specific gravity from the cement. The seed has been confirmed to germinate well. In this case, it is desirable to reduce the thickness of the soil layer. Industrial applicability As is clear from the above description, the greening concrete material of the present invention can be formed or constructed with concrete such as a building or civil engineering structure, a road or river slope, and the like. It can be used as a material for construction to germinate, survive and green the plants.

Claims

請 求 の 範 囲 The scope of the claims
1 . セメントと骨材を配合するコンクリート材において、 骨材とコン クリート添加材の機能のいずれか一方又は両方の機能をもたせるために 、 シリカを主成分とするシリカ系鉱物を添加配合する緑化用コンクリ一 ト材。 1. For greening by adding and mixing silica-based minerals containing silica as the main component, in order to provide one or both of the functions of the aggregate and the concrete additive in the concrete mixed with cement and aggregate. Concrete material.
2 . コンクリート添加材がパウダー状に粉砕されたシリカ系鉱物であ る請求の範囲 1の緑化用コンクリート材。  2. The concrete material for greening according to claim 1, wherein the concrete additive is a silica-based mineral ground into a powder.
3 . 骨材が主としてシリカ系鉱物である請求の範囲 1の緑化用コンク リート材。  3. The greening concrete material according to claim 1, wherein the aggregate is mainly a silica-based mineral.
4 . 骨材が主としてシリカ系鉱物であり、 該骨材とは別にパウダー状 に粉碎されたシリカ系鉱物をコンクリ一ト添加材として添加した請求の 範囲 1の緑化用コンクリート材。  4. The concrete material for greening according to claim 1, wherein the aggregate is mainly a silica-based mineral, and the silica-based mineral which has been powdered separately from the aggregate is added as a concrete additive.
5 . 骨材が砕石, 砂利その他の普通骨材とシリカ系鉱物とを含む請求 の範囲 1の緑化用コンクリート材。  5. The concrete material for revegetation according to claim 1, wherein the aggregate contains crushed stone, gravel and other ordinary aggregates and silica-based minerals.
6 . 骨材が主として砕石, 砂利その他の普通骨材であり、 コンクリー ト添加材としてパウダー状に粉砕されたシリカ系鉱物を添加する請求の 範囲 1の緑化用コンクリート材。  6. The concrete material for greening according to claim 1, wherein the aggregate is mainly crushed stone, gravel and other ordinary aggregates, and a powdered silica-based mineral is added as a concrete additive.
7 . 骨材が砕石, 砂利その他の普通骨材とシリカ系鉱物とを含み、 コ ンクリート添加材としてパウダー状に粉砕されたシリカ系鉱物を添加す る請求の範囲 1の緑化用コンクリ一ト材。  7. The concrete material for greening according to claim 1, wherein the aggregate contains crushed stone, gravel or other ordinary aggregate, and a silica-based mineral, and the powdered silica-based mineral is added as a concrete additive. .
8 . シリカ系鉱物が珪藻土, パーライ ト, 黄土のうち一種又は二種以 上配合した材料からなる請求の範囲 1又は 2又は 3又は 4又は 5又は 6 又は 7の緑化用コンクリート材。  8. The concrete material for greening according to claim 1, 2 or 3 or 4 or 5 or 6 or 7 comprising a material in which a silica-based mineral is one or more of diatomaceous earth, perlite and loess.
9 . 骨材として軽石, 人工骨材その他の低比重の鉱物性軽量骨材を一 種又は二種以上配合した材料を添加した請求の範囲 3又は 4の緑化用コ ンク リート材。 9. The greening core according to claim 3 or 4, wherein pumice, artificial aggregate, and other materials containing one or more kinds of mineral lightweight aggregates of low specific gravity are added as aggregates. Concrete material.
1 0 . コンクリートに保水性を付与する保水助材として竹材, やし材 10. Bamboo and palm wood as water retention aids to impart water retention to concrete
, 木材等を粉砕した繊維質材, ピートモスその他の植物性繊維質材のい ずれか一種又は二種以上配合した材料を添加した請求の範囲 1又は 2又 は 3又は 4又は 5又は 6又は 7の緑化用コンクリート材。 Claims 1 or 2 or 3 or 4 or 5 or 6 or 7 in which one or more of fibrous materials, peat moss and other vegetable fibrous materials obtained by grinding wood, etc. are added. Greening concrete material.
PCT/JP2001/005359 2000-06-23 2001-06-22 Concrete material for greening WO2001098231A1 (en)

Applications Claiming Priority (4)

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JP2000190186A JP3623718B2 (en) 2000-06-23 2000-06-23 Lightweight porous concrete material for greening
JP2000-190186 2000-06-23
JP2001-158995 2001-05-28
JP2001158995A JP2002345332A (en) 2001-05-28 2001-05-28 Greening concrete material

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