WO2002024835A3 - Products produced from rapid thermal processing of heavy hydrocarbon feedstocks - Google Patents

Products produced from rapid thermal processing of heavy hydrocarbon feedstocks Download PDF

Info

Publication number
WO2002024835A3
WO2002024835A3 PCT/CA2001/001316 CA0101316W WO0224835A3 WO 2002024835 A3 WO2002024835 A3 WO 2002024835A3 CA 0101316 W CA0101316 W CA 0101316W WO 0224835 A3 WO0224835 A3 WO 0224835A3
Authority
WO
WIPO (PCT)
Prior art keywords
feedstock
heat carrier
heavy hydrocarbon
particulate heat
product stream
Prior art date
Application number
PCT/CA2001/001316
Other languages
French (fr)
Other versions
WO2002024835A2 (en
Inventor
Barry Freel
Robert Graham
Original Assignee
Ensyn Group Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ensyn Group Inc filed Critical Ensyn Group Inc
Priority to CA2422534A priority Critical patent/CA2422534C/en
Priority to ES01971568T priority patent/ES2395116T3/en
Priority to MXPA03002341A priority patent/MXPA03002341A/en
Priority to AU2001291563A priority patent/AU2001291563A1/en
Priority to DK01971568.9T priority patent/DK1332199T3/en
Priority to BR0113937-1A priority patent/BR0113937A/en
Priority to AT01971568T priority patent/ATE532842T1/en
Priority to EP01971568A priority patent/EP1332199B8/en
Publication of WO2002024835A2 publication Critical patent/WO2002024835A2/en
Publication of WO2002024835A3 publication Critical patent/WO2002024835A3/en
Priority to NO20031230A priority patent/NO330786B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/28—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
    • C10G9/32—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material according to the "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/06—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/28—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/302—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/308—Gravity, density, e.g. API

Abstract

The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The process of the present invention provides for the preparation of a partially upgraded feedstock exhibiting reduced viscosity and increased API gravity. This process selectively removes metals, salts, water and nitrogen from the feedstock, while at the same time maximizes the yield of the liquid product, and minimizes coke and gas production. Furthermore, this process reduces the viscosity of the feedstock in order to permit pipeline transport, if desired, of the upgraded feedstock with little or no addition of diluents. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream. This invention also pertains to the products produced by the method.
PCT/CA2001/001316 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon feedstocks WO2002024835A2 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CA2422534A CA2422534C (en) 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon feedstocks
ES01971568T ES2395116T3 (en) 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon raw materials
MXPA03002341A MXPA03002341A (en) 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon feedstocks.
AU2001291563A AU2001291563A1 (en) 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon feedstocks
DK01971568.9T DK1332199T3 (en) 2000-09-18 2001-09-18 Products made by rapid thermal treatment of heavy hydrocarbon raw materials
BR0113937-1A BR0113937A (en) 2000-09-18 2001-09-18 Beneficial heavy oil and bitumen, liquid product and vacuum gas oil
AT01971568T ATE532842T1 (en) 2000-09-18 2001-09-18 PRODUCT PRODUCED BY RAPID THERMAL TREATMENT OF HEAVY HYDROCARBON INSERTS
EP01971568A EP1332199B8 (en) 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon feedstocks
NO20031230A NO330786B1 (en) 2000-09-18 2003-03-17 Process for Preparing a Vacuum Gas Oil (VGO)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23335400P 2000-09-18 2000-09-18
US60/233,354 2000-09-18

Publications (2)

Publication Number Publication Date
WO2002024835A2 WO2002024835A2 (en) 2002-03-28
WO2002024835A3 true WO2002024835A3 (en) 2002-10-31

Family

ID=22876886

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2001/001316 WO2002024835A2 (en) 2000-09-18 2001-09-18 Products produced from rapid thermal processing of heavy hydrocarbon feedstocks

Country Status (13)

Country Link
US (1) US7270743B2 (en)
EP (2) EP2275513A3 (en)
AR (1) AR033838A1 (en)
AT (1) ATE532842T1 (en)
AU (1) AU2001291563A1 (en)
BR (1) BR0113937A (en)
CA (1) CA2422534C (en)
DK (1) DK1332199T3 (en)
ES (1) ES2395116T3 (en)
MX (1) MXPA03002341A (en)
NO (1) NO330786B1 (en)
PT (1) PT1332199E (en)
WO (1) WO2002024835A2 (en)

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