WO2002048227A3 - Polyurethan-prepolymere mit nco-gruppen und niedrigem gehalt an monomeren polyisocyanat - Google Patents

Polyurethan-prepolymere mit nco-gruppen und niedrigem gehalt an monomeren polyisocyanat Download PDF

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Publication number
WO2002048227A3
WO2002048227A3 PCT/EP2001/014324 EP0114324W WO0248227A3 WO 2002048227 A3 WO2002048227 A3 WO 2002048227A3 EP 0114324 W EP0114324 W EP 0114324W WO 0248227 A3 WO0248227 A3 WO 0248227A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyurethane
low content
prepolymer
monomeric polyisocyanate
prepolymers
Prior art date
Application number
PCT/EP2001/014324
Other languages
English (en)
French (fr)
Other versions
WO2002048227A2 (de
Inventor
Gerd Bolte
Guenter Henke
Claudia Meckel-Jonas
Dagmar Plogmaker
Original Assignee
Henkel Kgaa
Gerd Bolte
Guenter Henke
Claudia Meckel-Jonas
Dagmar Plogmaker
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kgaa, Gerd Bolte, Guenter Henke, Claudia Meckel-Jonas, Dagmar Plogmaker filed Critical Henkel Kgaa
Priority to EP01986855.3A priority Critical patent/EP1341832B1/de
Priority to ES01986855.3T priority patent/ES2610388T3/es
Priority to BR0116194-6A priority patent/BR0116194A/pt
Priority to CA002431961A priority patent/CA2431961A1/en
Publication of WO2002048227A2 publication Critical patent/WO2002048227A2/de
Publication of WO2002048227A3 publication Critical patent/WO2002048227A3/de
Priority to US10/448,849 priority patent/US6903167B2/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/4009Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
    • C08G18/4018Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4216Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S528/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S528/905Polymer prepared from isocyanate reactant has adhesive property

Abstract

Es wird die Herstellung und Verwendung eines Polyurethan-Prepolymeren mit Isocyanat-Gruppen und niedrigem Gehalt an monomeren Polyisocyanat beschrieben, welches durch Mischen von mindestens einer reaktiven urethangruppenaufweisenden Komponente (I) mit mindestens einem monomerarmen, urethangruppenaufweisenden Polyisocyanat (II) erhältlich ist. Das erfindungsgemäße PU-Prepolymer eignet sich zum Verkleben von Kunststoffen, Metallen und Papieren und insbesondere für flexible Verpackungen. Das erfindungsgemäße PU-Prepolymer zeichnet sich trotz eines geringen Gehaltes an monomeren Polyisocyanat durch hohe Isocyanat-Gehalte und eine maßgeschneiderte Viskosität aus.
PCT/EP2001/014324 2000-12-15 2001-12-06 Polyurethan-prepolymere mit nco-gruppen und niedrigem gehalt an monomeren polyisocyanat WO2002048227A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP01986855.3A EP1341832B1 (de) 2000-12-15 2001-12-06 Polyurethan-prepolymere mit nco-gruppen und niedrigem gehalt an monomeren polyisocyanat
ES01986855.3T ES2610388T3 (es) 2000-12-15 2001-12-06 Prepolímeros de poliuretano con grupos NCO y bajo contenido en poliisocianato monomérico
BR0116194-6A BR0116194A (pt) 2000-12-15 2001-12-06 Pré-polimeros de poliuretano com grupos nco e conteúdo baixo de poliisocianato monomérico
CA002431961A CA2431961A1 (en) 2000-12-15 2001-12-06 Polyurethane-prepolymers comprising nco groups and a low content of monomeric polyisocyanate
US10/448,849 US6903167B2 (en) 2000-12-15 2003-05-30 Polyurethane prepolymers comprising NCO groups and a low content of monomeric polyisocyanate

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
DE10062587.8 2000-12-15
DE10062583.5 2000-12-15
DE10062584 2000-12-15
DE10062587 2000-12-15
DE10062583 2000-12-15
DE10062584.3 2000-12-15

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/448,849 Continuation US6903167B2 (en) 2000-12-15 2003-05-30 Polyurethane prepolymers comprising NCO groups and a low content of monomeric polyisocyanate

Publications (2)

Publication Number Publication Date
WO2002048227A2 WO2002048227A2 (de) 2002-06-20
WO2002048227A3 true WO2002048227A3 (de) 2002-08-29

Family

ID=27214197

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/014324 WO2002048227A2 (de) 2000-12-15 2001-12-06 Polyurethan-prepolymere mit nco-gruppen und niedrigem gehalt an monomeren polyisocyanat

Country Status (7)

Country Link
US (1) US6903167B2 (de)
EP (1) EP1341832B1 (de)
BR (1) BR0116194A (de)
CA (1) CA2431961A1 (de)
DE (1) DE10157488A1 (de)
ES (1) ES2610388T3 (de)
WO (1) WO2002048227A2 (de)

Families Citing this family (30)

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DE10229519A1 (de) * 2001-07-10 2003-01-30 Henkel Kgaa Reaktive Polyurethane mit einem geringen Gehalt an monomeren Diisocyanaten
DE10150722A1 (de) * 2001-10-13 2003-04-30 Henkel Kgaa Reaktive Polyurethan-Zusammensetzungen mit niedrigem Restmonomergehalt
JP2005511873A (ja) * 2001-12-18 2005-04-28 ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン モノマー含有量の少ないポリウレタン−プレポリマーの製造方法
DE50309990D1 (de) 2002-02-22 2008-07-31 Jowat Ag Polyurethan-Zusammensetzungen mit geringem Anteil an Diisocyanatmonomer(en)
DE102004018048A1 (de) * 2004-04-08 2005-11-10 Henkel Kgaa Verfahren zur Herstellung von Polyurethan-Prepolymeren
ES2555682T3 (es) * 2004-07-30 2016-01-07 Mitsui Chemicals, Inc. Adhesivo sin disolvente curable de dos componentes
US7115697B2 (en) * 2004-08-31 2006-10-03 E. I. Du Pont De Nemours And Company Adhesive for high-temperature laminate
DE102005012794A1 (de) * 2005-03-19 2006-09-21 Bayer Materialscience Ag Poly(etherester)polyole und Verfahren zu ihrer Herstellung
DE102005034183A1 (de) * 2005-07-21 2007-01-25 Construction Research & Technology Gmbh Amphiphile Polymer-Verbindungen, Verfahren zu ihrer Herstellung und deren Verwendung
DE102005048823A1 (de) * 2005-10-10 2007-04-12 Bayer Materialscience Ag Reaktivsysteme, deren Herstellung und Verwendung
DE102006059464A1 (de) * 2006-12-14 2008-06-19 Henkel Kgaa Polyurethan-Kaschierklebstoff
DE102008039679A1 (de) * 2008-08-26 2010-03-04 Henkel Ag & Co. Kgaa Verfahren zum Kaschieren von Folien
US8455679B2 (en) * 2008-12-12 2013-06-04 Basf Se Prepolymer systems having reduced monomeric isocyanate contents
DE102009005017A1 (de) * 2009-01-17 2010-07-22 Bayer Materialscience Ag Reaktive Polyurethan Zusammensetzungen
DE102011080513A1 (de) * 2011-08-05 2013-02-07 Henkel Ag & Co. Kgaa Monomerarme Polyurethanschäume
TWI486407B (zh) * 2012-07-09 2015-06-01 Wistron Corp 水性塗料以及具有平滑表面的物件的形成方法
PL405383A1 (pl) 2013-09-18 2015-03-30 Wrocławskie Centrum Badań Eit + Spółka Z Ograniczoną Odpowiedzialnością Jednoskładnikowa kompozycja do wytwarzania pianki poliuretanowej w tym o zmniejszonej zawartości MDI i o obniżonej gęstości oraz jej zastosowanie
US9982173B2 (en) * 2014-03-11 2018-05-29 Sika Technology Ag Polyurethane hot-melt adhesive having a low content of diisocyanate monomers and good cross-linking speed
DE102014212999A1 (de) 2014-07-04 2016-01-07 Henkel Ag & Co. Kgaa Polyurethan-Kaschierklebstoff enthaltend Füllstoffe
PL3067377T3 (pl) 2015-03-12 2023-05-02 Henkel Ag & Co. Kgaa Poliuretany o bardzo niskiej zawartości monomeru
DE102015207792A1 (de) * 2015-04-28 2016-11-03 Henkel Ag & Co. Kgaa Polyurethan-basiertes Bindemittel-System
JP2019508529A (ja) 2016-01-13 2019-03-28 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェンHenkel AG & Co. KGaA 充填剤を含有する反応性ポリウレタンホットメルト接着剤
CN109563313B (zh) 2016-08-19 2021-08-17 汉高股份有限及两合公司 制备疏水改性的粘土的方法
EP3327057A1 (de) 2016-11-25 2018-05-30 Henkel AG & Co. KGaA Polyester-freie kaschierklebstoff-zusammensetzung
KR102448662B1 (ko) 2016-11-25 2022-09-28 헨켈 아게 운트 코. 카게아아 폴리에스테르-비함유 라미네이팅 접착제 조성물
EP3659797A1 (de) * 2018-11-29 2020-06-03 Henkel AG & Co. KGaA Polyurethanklebstoff mit hoher chemischer beständigkeit
EP3670576B8 (de) 2018-12-19 2020-12-09 Ems-Chemie Ag Polyamid-formmassen für glasverbunde
EP3683248A1 (de) * 2019-01-17 2020-07-22 Henkel AG & Co. KGaA Verfahren zur herstellung von schmelzklebstoffen mit geringer emission von monomeren isocyanaten
PL3741812T3 (pl) 2019-05-20 2022-10-03 Henkel Ag & Co. Kgaa Sposób wytwarzania co najmniej częściowo eksfoliowanej glinki z użyciem środka eksfoliującego obejmującego częściowy ester (met)akrylanu poli(tlenku alkilenu), cykliczny węglan i wodę
WO2022179772A1 (en) 2021-02-26 2022-09-01 Henkel Ag & Co. Kgaa Flame-retardant adhesive composition for structural wood bonding

Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0107014A1 (de) * 1982-09-29 1984-05-02 Mobay Corporation Durch Isocyanat abgeschlossene Präpolymere mit niedrigem Gehalt an freien Monomeren
EP0590398A1 (de) * 1992-09-24 1994-04-06 Bayer Ag Lösungsmittelfreie Zweikomponentenpolyurethanklebstoffsysteme
WO1998029466A1 (de) * 1997-01-02 1998-07-09 Henkel Kommanditgesellschaft Auf Aktien Monomerenarmes pu-prepolymer
WO1999024486A1 (de) * 1997-11-11 1999-05-20 Henkel Kommanditgesellschaft Auf Aktien Polyurethanbindemittel mit einem niedrigen gehalt an leichtflüchtigen monomeren

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EP0107014A1 (de) * 1982-09-29 1984-05-02 Mobay Corporation Durch Isocyanat abgeschlossene Präpolymere mit niedrigem Gehalt an freien Monomeren
EP0590398A1 (de) * 1992-09-24 1994-04-06 Bayer Ag Lösungsmittelfreie Zweikomponentenpolyurethanklebstoffsysteme
WO1998029466A1 (de) * 1997-01-02 1998-07-09 Henkel Kommanditgesellschaft Auf Aktien Monomerenarmes pu-prepolymer
WO1999024486A1 (de) * 1997-11-11 1999-05-20 Henkel Kommanditgesellschaft Auf Aktien Polyurethanbindemittel mit einem niedrigen gehalt an leichtflüchtigen monomeren

Also Published As

Publication number Publication date
US20040014847A1 (en) 2004-01-22
US6903167B2 (en) 2005-06-07
WO2002048227A2 (de) 2002-06-20
EP1341832B1 (de) 2016-10-19
BR0116194A (pt) 2003-12-23
EP1341832A2 (de) 2003-09-10
ES2610388T3 (es) 2017-04-27
DE10157488A1 (de) 2002-06-20
CA2431961A1 (en) 2002-06-20

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