WO2002049601A1 - Structured composition comprising a heteratome polymer and fibers - Google Patents

Structured composition comprising a heteratome polymer and fibers Download PDF

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Publication number
WO2002049601A1
WO2002049601A1 PCT/IB2000/001984 IB0001984W WO0249601A1 WO 2002049601 A1 WO2002049601 A1 WO 2002049601A1 IB 0001984 W IB0001984 W IB 0001984W WO 0249601 A1 WO0249601 A1 WO 0249601A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
fibres
composition according
polymer
units
Prior art date
Application number
PCT/IB2000/001984
Other languages
English (en)
French (fr)
Inventor
Nathalie Jager Lazer
Original Assignee
L'oreal S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal S.A. filed Critical L'oreal S.A.
Priority to PCT/IB2000/001984 priority Critical patent/WO2002049601A1/en
Priority to AU2001220200A priority patent/AU2001220200A1/en
Priority to AU2002237450A priority patent/AU2002237450A1/en
Priority to PCT/IB2001/002820 priority patent/WO2002049602A1/en
Publication of WO2002049601A1 publication Critical patent/WO2002049601A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241Containing particulates characterized by their shape and/or structure
    • A61K8/027Fibers; Fibrils
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88Polyamides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12Face or body powders for grooming, adorning or absorbing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • C08G69/34Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids using polymerised unsaturated fatty acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • C08L77/08Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids

Definitions

  • foundations require the use of an applicator such as a sponge, which rapidly becomes contaminated and must be cleaned very regularly, especially after each application.
  • an applicator such as a sponge
  • users of foundations are increasingly on the lookout for solid forms in stick, in order to dispense with the sponge-type applicator.
  • Such a foundation is easy to use, hygienic and can be applied until all of the product has been used up, unlike a conventional foundation applied with a sponge.
  • the surface of the foundation remains smooth, whereas the surface of a product compacted in a case becomes deformed under the pressure of the successive uptakes onto the applicator. Finally, it allows a uniform make-up effect to be obtained.
  • the polymer in the composition of the invention advantageously comprises a number of fatty chains which represents from 40% to 98% of the total number of units containing a hetero " atom and of fatty chains, and better still from 50% to 95%.
  • the nature and proportion of the units containing a hetero atom depends on the nature of the liquid fatty phase and is, in particular, similar to the nature of the fatty phase.
  • the fibres may or may not be surface-treated and may or may not be coated, in particular with a view to making them hydrophobic.
  • coated fibres which can be used in the invention, mention may be made of polyamide fibres coated with copper sulphide for an antistatic effect (for example the R-STAT fibres from Rhodia) or another polymer allowing a particular organization of the fibres (specific surface treatment) or a surface treatment which induces colour/hologram effects ("Lurex" fibre from Sildorex, for example).
  • Flat multilayer fibres having goniochromatic properties may also be used.
  • Such fibres are disclosed in particular in the document EP-A- 921217. They are formed from alternating layers of polyamide and polyester, in particular polyester terephthalate.
  • the hardness of the composition according to the invention is such that the composition is advantageously self-supporting and can disintegrate easily to form a satisfactory deposit on the skin and/or the lips and/or superficial body growths.
  • the 5 composition of the invention has good impact strength.
  • the hardness of the composition in stick form, together with its shear strength, increases as the amount of fibre increases.
  • the amphiphilic compound(s) which can be used in the composition of the invention comprise a lipophilic part linked to a polar part, the lipophilic part comprising a carbon-based chain containing at least 8 5 carbon atoms, in particular from 18 to 32 carbon atoms and better still from 18 to 28 carbon atoms.
  • the polar part of this or these amphiphilic compound(s) is preferably the residue of a compound chosen from alcohols and polyols containing from 1 to 12 hydroxyl groups, and polyoxyalkylenes comprising at least 2 oxyalkylene units and containing from 0 to 20 o oxypropylene units and/or from 0 to 20 oxyethyiene units.
  • the liquid fatty phase of the composition advantageously contains more than 30% and better still more than 40% of liquid oil(s) having a chemical nature close to the one of the skeleton of the structurant polymer, and for example from 50% to 100%.
  • the liquid fatty phase structured with a polyamide-type skeleton contains a high quantity, i.e. greater than 30% and better still greater than 40% relative to the total weight of the liquid fatty phase and for example from 50% to 100%, of apolar and more especially hydrocarbon-based oil or mixture of oils.
  • hydrocarbon-based oil means an oil essentially comprising carbon and hydrogen atoms, optionally with one or more hydroxyl, ester or ether groups.
  • the structured oils are preferably apolar oils and more especially an oil or a mixture of oils of the hydrocarbon-based type of mineral or synthetic origin, chosen in particular from hydrocarbons, especially alkanes such as sesam oil, isoparaffins including isododecane, and squalane, and mixtures thereof. These oils are advantageously combined with one or more phenylsilicone oils.
  • these volatile solvents improve, in particular, the staying power or long wearing over time of the composition on the skin, the lips or superficial body growths.
  • the composition advantageously contains at least one volatile solvent, and better still a volatile oil.
  • This solvent may be chosen from hydrocarbon-based solvents, silicone solvents optionally comprising alkyl or alkoxy groups that are pendent or at the end of a silicone chain, fluoro solvents and mixtures thereof.
  • volatile solvents which can be used in the invention, mention may be made of linear or cyclic silicone oils having a viscosity at room temperature of less than 8 cSt and in particular containing from 2 to 7 silicon atoms, these silicones optionally comprising alkyl or alkoxy groups containing from 1 to 10 carbon atoms.
  • composition according to the invention can be in the form of a tinted dermatological composition or a care composition for keratin materials such as the skin, the lips and/or superficial body growths, in the form of an antisun composition or body hygiene composition in particular in the form of a deodorant product or make-up-removing product in stick form. It can be used in particular as a care base for the skin, superficial body growths or the lips (lip balms, for protecting the lips against cold and/or sunlight and/or the wind, or care cream for the skin, the nails or the hair).
  • the nacreous pigments may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, coloured nacreous pigments such as titanium mica with iron oxides, titanium mica with, in particular, ferric blue or chromium oxide, titanium 5 mica with an organic pigment of the type mentioned above, as well as nacreous pigments based on bismuth oxychloride. They can represent from 0.1% to 20% relative to the total weight of the composition, and better still from 0.1% to 15%, if they are present, and may or may not be surface-treated. 0
  • the composition can optionally contain one or more waxes to improve the structuring in stick form, although this rigid form can be . obtained in the absence of wax.
PCT/IB2000/001984 2000-12-21 2000-12-21 Structured composition comprising a heteratome polymer and fibers WO2002049601A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PCT/IB2000/001984 WO2002049601A1 (en) 2000-12-21 2000-12-21 Structured composition comprising a heteratome polymer and fibers
AU2001220200A AU2001220200A1 (en) 2000-12-21 2000-12-21 Structured composition comprising a heteratome polymer and fibers
AU2002237450A AU2002237450A1 (en) 2000-12-21 2001-12-19 Structured composition comrpising a heteroatome polymer and fibers
PCT/IB2001/002820 WO2002049602A1 (en) 2000-12-21 2001-12-19 Structured composition comrpising a heteroatome polymer and fibers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IB2000/001984 WO2002049601A1 (en) 2000-12-21 2000-12-21 Structured composition comprising a heteratome polymer and fibers

Publications (1)

Publication Number Publication Date
WO2002049601A1 true WO2002049601A1 (en) 2002-06-27

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Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/IB2000/001984 WO2002049601A1 (en) 2000-12-21 2000-12-21 Structured composition comprising a heteratome polymer and fibers
PCT/IB2001/002820 WO2002049602A1 (en) 2000-12-21 2001-12-19 Structured composition comrpising a heteroatome polymer and fibers

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/IB2001/002820 WO2002049602A1 (en) 2000-12-21 2001-12-19 Structured composition comrpising a heteroatome polymer and fibers

Country Status (2)

Country Link
AU (2) AU2001220200A1 (es)
WO (2) WO2002049601A1 (es)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002047657A2 (en) * 2000-12-12 2002-06-20 L'oreal Sa Composition containing heteropolymers and oil-soluble polymers
US6716420B2 (en) 2001-10-05 2004-04-06 L′Oreal Methods of use and of making a mascara comprising at least one coloring agent and at least one heteropolymer
US6835399B2 (en) 2000-12-12 2004-12-28 L'ORéAL S.A. Cosmetic composition comprising a polymer blend
WO2005044204A1 (de) * 2003-11-10 2005-05-19 Coty B.V. Mascara mit faserbestandteilen
FR2879441A1 (fr) * 2004-12-21 2006-06-23 Oreal Composition de revetement des fibres keratiniques, notamment des cils
US7749524B2 (en) 2003-07-11 2010-07-06 L'oreal S.A. Cosmetic compositions comprising a structuring agent, silicone powder and swelling agent
CN107250273A (zh) * 2015-03-03 2017-10-13 尤尼吉可株式会社 聚酰胺树脂组合物

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013075116A2 (en) 2011-11-17 2013-05-23 Heliae Development, Llc Omega 7 rich compositions and methods of isolating omega 7 fatty acids

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4466936A (en) * 1981-02-03 1984-08-21 Bayer Aktiengesellschaft Production of molds using gel compositions with depot action based on a polyurethane matrix and relatively high molecular weight polyols
JPS62238211A (ja) * 1986-04-04 1987-10-19 Kobayashi Kooc:Kk 皮膚手入れ用化粧料
US5783657A (en) * 1996-10-18 1998-07-21 Union Camp Corporation Ester-terminated polyamides of polymerized fatty acids useful in formulating transparent gels in low polarity liquids
EP0925780A1 (fr) * 1997-12-22 1999-06-30 L'oreal Composition cosmétique sans transfert comprenant une dispersion de particules de polymère dans une phase grasse liquide
US6063398A (en) * 1995-09-20 2000-05-16 L'oreal Cosmetic or dermopharmaceutical patch containing, in an anhydrous polymeric matrix, at least one active compound which is, in particular, unstable in oxidizing mediums, and at least one water-absorbing agent
EP1053742A1 (fr) * 1999-05-20 2000-11-22 L'oreal Compositions anhydres de soin ou de maquillage contenants des fibres et des polyols
EP1066814A1 (fr) * 1999-07-08 2001-01-10 L'oreal Mascara comprenant un polyuréthane et des fibres

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2796273B1 (fr) * 1999-07-15 2003-09-12 Oreal Composition a phase grasse liquide gelifiee par un polyamide a groupements ester terminaux
FR2799366B1 (fr) * 1999-10-07 2001-12-07 Oreal Composition sous forme d'emulsion huile-dans-eau contenant des fibres, et ses utilisations notamment cosmetiques

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4466936A (en) * 1981-02-03 1984-08-21 Bayer Aktiengesellschaft Production of molds using gel compositions with depot action based on a polyurethane matrix and relatively high molecular weight polyols
JPS62238211A (ja) * 1986-04-04 1987-10-19 Kobayashi Kooc:Kk 皮膚手入れ用化粧料
US6063398A (en) * 1995-09-20 2000-05-16 L'oreal Cosmetic or dermopharmaceutical patch containing, in an anhydrous polymeric matrix, at least one active compound which is, in particular, unstable in oxidizing mediums, and at least one water-absorbing agent
US5783657A (en) * 1996-10-18 1998-07-21 Union Camp Corporation Ester-terminated polyamides of polymerized fatty acids useful in formulating transparent gels in low polarity liquids
EP0925780A1 (fr) * 1997-12-22 1999-06-30 L'oreal Composition cosmétique sans transfert comprenant une dispersion de particules de polymère dans une phase grasse liquide
EP1053742A1 (fr) * 1999-05-20 2000-11-22 L'oreal Compositions anhydres de soin ou de maquillage contenants des fibres et des polyols
EP1066814A1 (fr) * 1999-07-08 2001-01-10 L'oreal Mascara comprenant un polyuréthane et des fibres

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 012, no. 110 (C - 486) 8 April 1988 (1988-04-08) *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002047657A2 (en) * 2000-12-12 2002-06-20 L'oreal Sa Composition containing heteropolymers and oil-soluble polymers
WO2002047657A3 (en) * 2000-12-12 2003-11-06 Oreal Composition containing heteropolymers and oil-soluble polymers
US6835399B2 (en) 2000-12-12 2004-12-28 L'ORéAL S.A. Cosmetic composition comprising a polymer blend
US6716420B2 (en) 2001-10-05 2004-04-06 L′Oreal Methods of use and of making a mascara comprising at least one coloring agent and at least one heteropolymer
US7749524B2 (en) 2003-07-11 2010-07-06 L'oreal S.A. Cosmetic compositions comprising a structuring agent, silicone powder and swelling agent
WO2005044204A1 (de) * 2003-11-10 2005-05-19 Coty B.V. Mascara mit faserbestandteilen
CN100435781C (zh) * 2003-11-10 2008-11-26 科蒂股份有限公司 具有纤维成分的睫毛油
US8029773B2 (en) 2003-11-10 2011-10-04 Coty B.V. Mascara containing fiber components
FR2879441A1 (fr) * 2004-12-21 2006-06-23 Oreal Composition de revetement des fibres keratiniques, notamment des cils
CN107250273A (zh) * 2015-03-03 2017-10-13 尤尼吉可株式会社 聚酰胺树脂组合物

Also Published As

Publication number Publication date
AU2001220200A1 (en) 2002-07-01
AU2002237450A1 (en) 2002-07-01
WO2002049602A1 (en) 2002-06-27

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