WO2002053286A3 - Hydroprocessing catalyst and use thereof - Google Patents

Hydroprocessing catalyst and use thereof Download PDF

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Publication number
WO2002053286A3
WO2002053286A3 PCT/EP2001/015383 EP0115383W WO02053286A3 WO 2002053286 A3 WO2002053286 A3 WO 2002053286A3 EP 0115383 W EP0115383 W EP 0115383W WO 02053286 A3 WO02053286 A3 WO 02053286A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
improved
hydroprocessing
calculated
heavy hydrocarbon
Prior art date
Application number
PCT/EP2001/015383
Other languages
French (fr)
Other versions
WO2002053286A2 (en
Inventor
Satoshi Abe
Akira Hino
Katsuhisa Fujita
Original Assignee
Nippon Ketjen Co Ltd
Akzo Nobel Nv
Satoshi Abe
Akira Hino
Katsuhisa Fujita
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Ketjen Co Ltd, Akzo Nobel Nv, Satoshi Abe, Akira Hino, Katsuhisa Fujita filed Critical Nippon Ketjen Co Ltd
Priority to SK990-2003A priority Critical patent/SK286585B6/en
Priority to DE60104901T priority patent/DE60104901T2/en
Priority to CA2433324A priority patent/CA2433324C/en
Priority to EP01986437A priority patent/EP1347832B1/en
Priority to US10/250,604 priority patent/US7169294B2/en
Priority to PL366142A priority patent/PL202786B1/en
Priority to KR1020037008966A priority patent/KR100747359B1/en
Publication of WO2002053286A2 publication Critical patent/WO2002053286A2/en
Publication of WO2002053286A3 publication Critical patent/WO2002053286A3/en

Links

Classifications

    • B01J35/60—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • B01J35/615—
    • B01J35/635—
    • B01J35/647—
    • B01J35/651—

Abstract

The invention pertains to a hydroprocessing catalyst suitable for the conversion of heavy hydrocarbon oils, which comprises 7-20wt.% of Group VI metal, Calculated as trioxide, and 0.5-6 wt.% of Group VIII metal, calculated as oxide, on a carrier comprising alumina, the catalyst having a surface area of 100-180 m2/g, a total pore volume of 0.55 ml/g or more, a %PV(⊃200 Å d) of at least 50%, a %PV(⊃1,000 Å d) of at least 5%, a %PV(100-1,200 Å d) of at least 85%, a %PV(⊃ 4,000 Å d) of 0-2%, and a %PV(⊃ 10,000 Å d) of 0-1%. The catalyst of the present invention shows improved metals and asphaltene removal, combined with appropriate sulfur, nitrogen, and Conradson carbon removal. Additionally, the catalyst shows a decrease in sediment formation and an improved conversion in ebullating bed operations. In fixed bed operation, the catalyst produces product with an improved storage stability. The invention also pertains to a process for hydroprocessing heavy hydrocarbon feeds with the catalyst according to the invention in fixed bed or ebullating bed operation.
PCT/EP2001/015383 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof WO2002053286A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
SK990-2003A SK286585B6 (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof
DE60104901T DE60104901T2 (en) 2001-01-05 2001-12-20 HYDRODEX CATALYST AND ITS USE
CA2433324A CA2433324C (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof
EP01986437A EP1347832B1 (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof
US10/250,604 US7169294B2 (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof
PL366142A PL202786B1 (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof
KR1020037008966A KR100747359B1 (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001/485 2001-01-05
JP2001000485A JP4638610B2 (en) 2001-01-05 2001-01-05 Hydrotreating catalyst and hydrotreating method

Publications (2)

Publication Number Publication Date
WO2002053286A2 WO2002053286A2 (en) 2002-07-11
WO2002053286A3 true WO2002053286A3 (en) 2003-07-31

Family

ID=18869261

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/015383 WO2002053286A2 (en) 2001-01-05 2001-12-20 Hydroprocessing catalyst and use thereof

Country Status (10)

Country Link
US (1) US7169294B2 (en)
EP (1) EP1347832B1 (en)
JP (1) JP4638610B2 (en)
KR (1) KR100747359B1 (en)
CA (1) CA2433324C (en)
DE (1) DE60104901T2 (en)
PL (1) PL202786B1 (en)
SK (1) SK286585B6 (en)
TW (1) TW587958B (en)
WO (1) WO2002053286A2 (en)

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US8764972B2 (en) 2003-12-19 2014-07-01 Shell Oil Company Systems, methods, and catalysts for producing a crude product

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MXPA05012893A (en) 2005-11-29 2007-11-23 Mexicano Inst Petrol Catalyst for the hydrodesulfurization of residues and heavy crudes.
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JP5743546B2 (en) * 2007-10-19 2015-07-01 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Unsaturated hydrocarbon hydrogenation catalyst and process for its preparation
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JP5805762B2 (en) * 2010-08-13 2015-11-04 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー Compositions containing chelating agents and polar additives useful for the hydrogenation of hydrocarbon raw materials and methods for their production and use
US9376637B2 (en) * 2010-08-13 2016-06-28 Shell Oil Company Method of making a hydroprocessing catalyst with a single step metal and chelant incorporation, the catalyst, and the use of the catalyst
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US20120264953A1 (en) * 2011-04-14 2012-10-18 Basf Se Zinc-comprising catalyst for preparing ethylene oxide
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JP6432086B2 (en) * 2013-09-27 2018-12-05 コスモ石油株式会社 Heavy hydrocarbon oil hydrotreating catalyst, method for producing heavy hydrocarbon oil hydrotreating catalyst, and method for hydrotreating heavy hydrocarbon oil
US10202553B2 (en) * 2013-10-11 2019-02-12 Cosmo Oil Co., Ltd. Hydroprocessing catalyst for heavy hydrocarbon oil, method for manufacturing hydroprocessing catalyst for heavy hydrocarbon oil, and hydroprocessing method for heavy hydrocarbon oil
FR3022158B1 (en) 2014-06-13 2018-02-23 IFP Energies Nouvelles MESOPOROUS CATALYST OF RESIDUAL HYDROCONVERSION AND METHOD OF PREPARATION
FR3022159B1 (en) 2014-06-13 2018-04-27 IFP Energies Nouvelles MESOPOROUS AND MACROPOROUS CATALYST OF RESIDUAL HYDROCONVERSION AND METHOD OF PREPARATION
FR3022157B1 (en) 2014-06-13 2017-09-01 Ifp Energies Now BIMODAL CATALYST WITH COMALATED ACTIVE PHASE, PROCESS FOR PREPARING THE SAME, AND USE THEREOF IN HYDROTREATMENT OF RESIDUES
FR3022156B1 (en) 2014-06-13 2018-02-23 Ifp Energies Now CATALYST AND MACROPOROUS CATALYST WITH COMALATED ACTIVE PHASE, PROCESS FOR THE PREPARATION THEREOF AND USE THEREOF IN HYDROTREATMENT OF RESIDUES
US10054140B2 (en) 2016-02-12 2018-08-21 Crystaphase Products, Inc. Use of treating elements to facilitate flow in vessels
TWI736612B (en) * 2016-04-25 2021-08-21 荷蘭商蜆殼國際研究所 An ebullated bed process for high conversion of heavy hydrocarbons with a low sediment yield
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
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CN111744483B (en) * 2019-03-28 2021-09-07 中国石油化工股份有限公司 Aluminum oxide, preparation method and application thereof
JP7460770B2 (en) 2019-12-20 2024-04-02 クリスタフェーズ・プロダクツ・インコーポレーテッド Re-saturation of gas into liquid feedstream
RU2724048C1 (en) * 2019-12-24 2020-06-19 Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" Catalyst carrier for dehydrogenation of paraffin hydrocarbons in a stationary layer based on active aluminum oxide
TW202224768A (en) * 2020-08-26 2022-07-01 美商先進精鍊科技有限公司 Incorporation of boron in hydroprocessing catalysts, catalysts obtained and use thereof

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Also Published As

Publication number Publication date
SK286585B6 (en) 2009-01-07
EP1347832B1 (en) 2004-08-11
PL366142A1 (en) 2005-01-24
JP2002204959A (en) 2002-07-23
TW587958B (en) 2004-05-21
US20040050754A1 (en) 2004-03-18
KR20030080214A (en) 2003-10-11
PL202786B1 (en) 2009-07-31
EP1347832A2 (en) 2003-10-01
US7169294B2 (en) 2007-01-30
SK9902003A3 (en) 2004-01-08
KR100747359B1 (en) 2007-08-07
CA2433324C (en) 2010-02-23
DE60104901T2 (en) 2005-08-11
JP4638610B2 (en) 2011-02-23
DE60104901D1 (en) 2004-09-16
WO2002053286A2 (en) 2002-07-11
CA2433324A1 (en) 2002-07-11

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