WO2002068096A3 - Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas - Google Patents

Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas Download PDF

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Publication number
WO2002068096A3
WO2002068096A3 PCT/US2002/005293 US0205293W WO02068096A3 WO 2002068096 A3 WO2002068096 A3 WO 2002068096A3 US 0205293 W US0205293 W US 0205293W WO 02068096 A3 WO02068096 A3 WO 02068096A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
gas
nitrogen oxide
phase reactor
radial flow
Prior art date
Application number
PCT/US2002/005293
Other languages
French (fr)
Other versions
WO2002068096A2 (en
Inventor
Erwin M J Platvoet
Steven M Hopkins
Original Assignee
Abb Lummus Global Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Abb Lummus Global Inc filed Critical Abb Lummus Global Inc
Priority to CA002438697A priority Critical patent/CA2438697C/en
Priority to JP2002567447A priority patent/JP4576552B2/en
Priority to KR1020037011186A priority patent/KR100868955B1/en
Priority to EP02728347A priority patent/EP1379321A2/en
Priority to BRPI0207520-2A priority patent/BR0207520B1/en
Publication of WO2002068096A2 publication Critical patent/WO2002068096A2/en
Publication of WO2002068096A3 publication Critical patent/WO2002068096A3/en
Priority to NO20033759A priority patent/NO20033759L/en

Links

Classifications

    • B01J35/56
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8628Processes characterised by a specific catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/88Handling or mounting catalysts
    • B01D53/885Devices in general for catalytic purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • B01J23/22Vanadium
    • B01J35/58
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0214Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/00849Stationary elements outside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/194Details relating to the geometry of the reactor round
    • B01J2219/1941Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1943Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/19Details relating to the geometry of the reactor
    • B01J2219/194Details relating to the geometry of the reactor round
    • B01J2219/1941Details relating to the geometry of the reactor round circular or disk-shaped
    • B01J2219/1946Details relating to the geometry of the reactor round circular or disk-shaped conical

Abstract

A radial flow gas phase reactor for the selective catalytic reduction of nitrogen oxide in a gas stream includes a shell enclosing an interior space in which is located at least one catalyst bed containing a catalyst for the selective conversion of NOx. A deflector directs the flow of gas radially through the bed. An injector upstream of the catalyst introduces a reducing agent such as ammonia into the inlet gas stream. The catalyst bed can include particulate, monolith, or microengineered catalyst.
PCT/US2002/005293 2001-02-26 2002-02-22 Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas WO2002068096A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA002438697A CA2438697C (en) 2001-02-26 2002-02-22 Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas
JP2002567447A JP4576552B2 (en) 2001-02-26 2002-02-22 Radial flow gas phase reactor for reducing the nitrogen oxide content of gases
KR1020037011186A KR100868955B1 (en) 2001-02-26 2002-02-22 Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas
EP02728347A EP1379321A2 (en) 2001-02-26 2002-02-22 Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas
BRPI0207520-2A BR0207520B1 (en) 2001-02-26 2002-02-22 Radial flow gas phase reactor for chemical conversion of nitrogen oxide into a gas stream.
NO20033759A NO20033759L (en) 2001-02-26 2003-08-25 Gas phase reactor with radial flow and method for reducing the nitrogen oxide content of a gas

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/793,471 2001-02-26
US09/793,471 US6663839B2 (en) 2001-02-26 2001-02-26 Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas

Publications (2)

Publication Number Publication Date
WO2002068096A2 WO2002068096A2 (en) 2002-09-06
WO2002068096A3 true WO2002068096A3 (en) 2003-04-24

Family

ID=25159992

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/005293 WO2002068096A2 (en) 2001-02-26 2002-02-22 Radial flow gas phase reactor and method for reducing the nitrogen oxide content of a gas

Country Status (8)

Country Link
US (1) US6663839B2 (en)
EP (1) EP1379321A2 (en)
JP (1) JP4576552B2 (en)
KR (1) KR100868955B1 (en)
BR (1) BR0207520B1 (en)
CA (1) CA2438697C (en)
NO (1) NO20033759L (en)
WO (1) WO2002068096A2 (en)

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US20020159923A1 (en) * 2001-02-26 2002-10-31 Platvoet Erwin M.J. Gas phase reactor and process for reducing nitrogen oxide in a gas stream
FR2823139B1 (en) * 2001-04-05 2004-01-23 Inst Francais Du Petrole CATALYST SUPPORT WITH SECANT CHANNEL NETWORKS, CATALYST REACTOR COMPRISING SUCH SUPPORT AND METHOD FOR PRODUCING SUCH CATALYST SUPPORT
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US7682577B2 (en) 2005-11-07 2010-03-23 Geo2 Technologies, Inc. Catalytic exhaust device for simplified installation or replacement
US7682578B2 (en) 2005-11-07 2010-03-23 Geo2 Technologies, Inc. Device for catalytically reducing exhaust
US7722828B2 (en) 2005-12-30 2010-05-25 Geo2 Technologies, Inc. Catalytic fibrous exhaust system and method for catalyzing an exhaust gas
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KR100794390B1 (en) * 2007-01-24 2008-01-15 한국에너지기술연구원 Packed bed catalytic reactor for removal of nox by temperature controlled
US7998444B2 (en) * 2008-04-30 2011-08-16 Johnson Matthey Inc. Method of reducing nitrogen oxides in a gas stream with vaporized ammonia
FI20095735A0 (en) * 2009-06-29 2009-06-29 Ecocat Oy Puhdistinrakenne
US20120049392A1 (en) * 2010-08-25 2012-03-01 Carlos Jose Trompiz Structured Packing with Extended Contact Area
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Also Published As

Publication number Publication date
US6663839B2 (en) 2003-12-16
CA2438697A1 (en) 2002-09-06
BR0207520B1 (en) 2011-05-17
BR0207520A (en) 2004-07-27
EP1379321A2 (en) 2004-01-14
NO20033759D0 (en) 2003-08-25
JP2004524960A (en) 2004-08-19
KR100868955B1 (en) 2008-11-17
JP4576552B2 (en) 2010-11-10
NO20033759L (en) 2003-10-24
KR20040010597A (en) 2004-01-31
US20020150526A1 (en) 2002-10-17
CA2438697C (en) 2009-06-16
WO2002068096A2 (en) 2002-09-06

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