WO2002070248A1 - Coatings for building products - Google Patents
Coatings for building products Download PDFInfo
- Publication number
- WO2002070248A1 WO2002070248A1 PCT/AU2002/000242 AU0200242W WO02070248A1 WO 2002070248 A1 WO2002070248 A1 WO 2002070248A1 AU 0200242 W AU0200242 W AU 0200242W WO 02070248 A1 WO02070248 A1 WO 02070248A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- product
- slurry
- coating
- dewatering
- formulation
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 87
- 239000002002 slurry Substances 0.000 claims abstract description 102
- 239000000203 mixture Substances 0.000 claims abstract description 92
- 239000011248 coating agent Substances 0.000 claims abstract description 77
- 238000009472 formulation Methods 0.000 claims abstract description 64
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 56
- 238000000034 method Methods 0.000 claims abstract description 50
- 239000011230 binding agent Substances 0.000 claims abstract description 28
- 239000002131 composite material Substances 0.000 claims abstract description 26
- 239000008199 coating composition Substances 0.000 claims abstract description 10
- 239000004568 cement Substances 0.000 claims description 53
- 239000010881 fly ash Substances 0.000 claims description 48
- 239000000654 additive Substances 0.000 claims description 31
- 239000010410 layer Substances 0.000 claims description 30
- 239000004615 ingredient Substances 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000011247 coating layer Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 235000013312 flour Nutrition 0.000 claims description 9
- 239000010440 gypsum Substances 0.000 claims description 9
- 229910052602 gypsum Inorganic materials 0.000 claims description 9
- 239000011398 Portland cement Substances 0.000 claims description 8
- 239000011236 particulate material Substances 0.000 claims description 8
- 150000004684 trihydrates Chemical class 0.000 claims description 8
- 230000000996 additive effect Effects 0.000 claims description 7
- 239000011405 expansive cement Substances 0.000 claims description 7
- 239000004572 hydraulic lime Substances 0.000 claims description 7
- 239000011404 masonry cement Substances 0.000 claims description 7
- 239000011412 natural cement Substances 0.000 claims description 7
- 239000003129 oil well Substances 0.000 claims description 7
- 239000002893 slag Substances 0.000 claims description 7
- 238000007581 slurry coating method Methods 0.000 claims description 5
- -1 pozzalans Substances 0.000 claims 6
- 239000004816 latex Substances 0.000 description 8
- 229920000126 latex Polymers 0.000 description 8
- 230000008901 benefit Effects 0.000 description 6
- 238000001723 curing Methods 0.000 description 6
- 239000011518 fibre cement Substances 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000009408 flooring Methods 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 229920003043 Cellulose fiber Polymers 0.000 description 4
- 244000137852 Petrea volubilis Species 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 238000005253 cladding Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229920004482 WACKER® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 229920001222 biopolymer Polymers 0.000 description 1
- 239000010882 bottom ash Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
- 235000013681 dietary sucrose Nutrition 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000003090 exacerbative effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- CBYZIWCZNMOEAV-UHFFFAOYSA-N formaldehyde;naphthalene Chemical class O=C.C1=CC=CC2=CC=CC=C21 CBYZIWCZNMOEAV-UHFFFAOYSA-N 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 239000013022 formulation composition Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 229910021487 silica fume Inorganic materials 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- WEFLTJMZDFLYAP-UHFFFAOYSA-M sodium;formaldehyde;hydrogen sulfate;1,3,5-triazine-2,4,6-triamine Chemical compound [Na+].O=C.OS([O-])(=O)=O.NC1=NC(N)=NC(N)=N1 WEFLTJMZDFLYAP-UHFFFAOYSA-M 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/06—Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
- C04B18/08—Flue dust, i.e. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/12—Flooring or floor layers made of masses in situ, e.g. seamless magnesite floors, terrazzo gypsum floors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Definitions
- the present invention relates to coatings and in particular coatings for building products and laminated building products.
- the coatings can be divided into two main groups namely finishing coatings, which are intended primarily for aesthetic purposes, and functional coatings which provide some additional structural or other property/attribute to the resultant product.
- the application technique depends to a large extent on the properties of the coating composition and base layer or product to be coated. Manual application and spraying etc are most popular but they restrict the types of coating to be applied and indeed the building product to be coated. For example, when using a spray technique, one must ensure the coating composition is of sufficient flowability to pass through the spray nozzle but at the same time, the base material to be coated must be sufficiently rigid to withstand the impact of the spray coating. For certain building products, such as internal wall systems, a smooth surface finish is vital. Gypsum or plaster board is used almost exclusively as an internal wall board due to its excellent surface finish. The use of fibre reinforced cement building board for instance as an internal wall board has significant advantages including cost and structural integrity as compared with gypsum board.
- the present invention provides a method for coating a building product comprising providing a coating formulation including an hydraulic binder and a quantity of dewatering agent, producing a slurry of said formulation, applying said slurry to the product to be coated and dewatering said slurry through said product.
- the present invention provides a formulation for use in coating a building product comprising an hydraulic binder and a quantity of dewatering agent sufficient to permit dewatering of a slurry produced from said formulation through the building product.
- the present invention provides a dewaterable slurry for coating a building product, said slurry comprising water, an hydraulic binder and a quantity of dewatering agent sufficient to permit dewatering of said slurry through said building product.
- the present invention provides a composite product comprising a base structural layer with a coating thereon, the coating including an hydraulic binder and a quantity of dewatering agent sufficient such that the coating may be dewatered through the base layer.
- the present invention provides a method of improving an hydraulic binder based coating formulation for coating a building product comprising adding to said binder a quantity of dewatering agent such that after application of a slurry of said formulation to said building product, said slurry can be dewatered through the building product.
- the present invention provides a dewatering aid for dewatering a cementitious slurry coating on a product, said dewatering aid comprising a quantity of particulate material sufficient to permit dewatering of the slurry through the product to be coated.
- the dewatering agent serves to maintain sufficient porosity in the slurry and product to be coated to permit dewatering of the slurry through the product to be coated.
- the dewatering agent is a particulate material such as fly ash, alumina trihydrate, silica flour, cenospheres (ceramic hollow spheres) or similar. Fly ash is particularly preferred as it permits dewatering of the slurry within a few minutes.
- Other particulate dewatering agents such as alumina trihydrate or silica flour may also be used, however, they increase the time required for dewatering of the slurry through the product to be coated.
- the slurry applied to the product to be coated has a high water content.
- the water content can be up to 50%. This is in contrast to previous cementitious formulations which generally have a higher solids content.
- a dewaterable slurry is obtained which can be applied to the building product, dewatered through the building product and thereby provide a uniform coating over the building product.
- the resultant product would be normally cured, steam cured or hydrothermally cured, ie autoclaved, and if required, sanded to a smooth flat finish.
- the building product to which the coating can be applied is virtually limitless provided the slurry can be dewatered through the building product.
- cementitious and gypsum building boards are typical examples of suitable building products on which the coating can be applied.
- the resultant coating which may optionally contain fibres, results in a decorative finishing layer which is sandable, smooth, flat, low permeable, crack free and/or flexible, ready to be finished, for example by painting.
- the thickness of such a coating layer prior to sanding would range from around 0.1 to 10 mm, preferably 0.5 to 5 mm and most preferably 1 to 3 mm.
- the finish layer may have a depth of around 0.05 to 5 mm, preferably 0.1 to 2 mm and most preferably 0.5 to 1 mm.
- the thus produced coated product is comparable in its workability to monolithic (single layer) composites. It can be flexed, cut, drilled and fixed by nails etc to a frame without surface cracking or chipping.
- the applicant's have found an extremely good interlaminer bond and compatibility between the dewatered slurry layer and base layer resulting in excellent composite action, compatibility and resistance to delamination.
- 'hydraulic binder' refers to a pulverised material in the solid, dry state which, when mixed with water, yields plastic mixtures that are able to set and harden, for example a cement. Included within the definition are white, grey or pigmented cements and hydraulic limes.
- the term 'cement' includes hydraulic and alite cements such as portland cement, blended cements such as portland cement blended with fly ash, blast-furnace slag, pozzalans and the like and mixtures thereof, masonry cement, oil well cement, natural cement, alumina cement, expansive cements and the like, or mixtures thereof.
- the quantity of binder in the formulation is preferably between 10 to 50 wt% based on the total dry ingredients, more preferably 15 to 40 wt% and most preferably 20 to 30 wt%.
- the fly ash used in the present invention provides a number of advantages including, particularly, as an aid to dewatering of the slurry as defined above.
- fly ash' refers to a solid powder having a chemical composition similar to or the same as the composition of material that is produced during combustion of powdered coal, ie 25 to 60 wt% silica, 10 to 30 wt% Al 2 O 3 , 5 to 25 wt% Fe 2 O 3 , 0 to 20 wt% CaO and 0 to 5 wt% MgO.
- Fly ash particles are typically spherical and range in diameter from 1 to 100 microns.
- the fly ash comprises two components.
- a first 'larger' size particles of fly ash with preferably a 100 micron maximum size. This size range of fly ash is used in the slurry to aid in improving the dewatering characteristics of the slurry but also as a moderately reactive pozzalan.
- the second 'smaller' fly ash size zone which preferably has a 10 micron maximum size also adds an improving dewatering characteristic but is a more highly reactive pozzalan.
- This 'smaller' fly ash particle zone also improves the sanded surface quality of the finish layer.
- the first fly ash comprises 10 to 60 wt% of the formulation based on total dry ingredients, more preferably 20 to 50 wt % and most preferably 30 to 40 wt%.
- the second fly ash component preferably provides 5 to 30 wt % of the formulation based on total dry ingredients, more preferably 10 to 25 wt% and most preferably 15 to 20%.
- the dewatering agent may include a coarse fraction fly ash which is greater than 100 microns. This coarse fraction fly ash includes bottom ash or similar products from coal combustion. There is an advantage to using these products over the aforementioned particle size fly ash since it is cheaper. Of course, as will be clear to persons skilled in the art, some reformulation of the slurry may be required to provide a suitable coating and appropriate dewatering characteristics when the dewatering agent is such a coarse fraction fly ash.
- the coating may optionally contain other additives such as fillers.
- fillers may also be used to improve the dewatering characteristics of the slurry.
- cenospheres high ceramic microspheres
- wollastonite diatomite
- ground rice hulls ground perlite or the like
- fillers may also be used to provide additional benefits, for example calcium carbonates or alumina hydrates improve sandability and flexibility of the coated layer respectively.
- Silica flour improves hardness of the sanded surface of the coating layer and the acoustic/thermal insulation properties of the layer can be improved by including rubber particles, vermiculite, perlite, expanded polystyrene or gypsum.
- the fillers preferably comprise 5 to 30 wt% of the formulation based on total dry ingredients, more preferably 10 to 25 wt% and most preferably 25 to 20 wt%.
- the coating may also contain other organic additives.
- Cement plasticising agents may be used to alter the rheology of the slurry. Suitable cement plasticising agents include melamine sulphonate formaldehyde condensates, naphthalene sulphonate formaldehyde condensates, naphthalene sulphonates, calcium lignosulphonates, sodium lignosulphonates, saccharose, sodium gluconate, sulphonic acids, carbohydrates, amino carboxylic acids, polyhydroxycarboxilic acids, sulphonated melomine and the like.
- the amount of cement plasticiser of course will depend upon the fluidising ability of the particular plasticisers. Generally the quantity of plasticiser will be in the range of 0.3 to about 3 wt% and more preferably 0.5 to 2 wt% based on the total of dry ingredients in the formulation.
- cement plasticisers are Melment F-10, a melamine formaldehyde sodium bisulphate polymer dispersant marketed by SKW-Trostburg in the form of a fine white powder.
- Another suitable plasticiser is Neosyn, a condensed sodium salt of sulphonated naphthalene formaldehyde available from Hodgson Chemicals.
- Another preferred component in the coating is a biopolymer which acts to enhance the flowability, segregation resistance and self levelling qualities of the cementitious slurry.
- Particularly suitable bioplymers are xanathan gum and/or whelan gum, eg KELCO-CRETE, K1C 376 manufactured by Monsanto.
- Latex may also be included in the coating composition to improve adherence, elasticity, stability and impermeability of the coating.
- the latex also improves flexibility of the formed coating.
- the latex maybe selected from the group consisting of acrylic latex, styrene latex, butadiene latex or mixtures thereof and is provided preferably in an amount between 0.5 to 20%, more preferably 1 to 15% and most preferably about 10% by weight of cement (on polymer solids basis) solids.
- Vinyl polymers may also be incorporated into the coating either in addition or as a substitute to the latex emulsions. Such vinyl polymers or equivalent polymeric materials enhance adhesion, resilience and flexural strength and abrasion resistance of the coating.
- Preferred vinyl polymers include polyvinyl acetate or a copolymer vinyl acetate with another monomer such as ethylene.
- a particularly preferred vinyl acetate resin is NINNAPAS LL5044 thermo plastic resin powder which contains a vinyl acetate- ethylene copolymer available from Wacker. Such powdered vinyl polymer is preferably provided in quantities similar to the latex emulsion referred to above.
- additives such as mineral oxides, hydroxides and clays, metal oxides and hydroxides, fire retardants such as magnesite, thickeners, silica fume or amorphous silica, water sealing agents, water reducing agents, setting modifiers, hardeners, dispersants, foaming agents or flocculating agents, water-proofing agents and density modifiers are suitable for use with the present invention.
- one particular advantage arising from the present invention is the ability to treat the product to be coated by providing additives in the coating. To explain, since the coating is dewatered through the product to be coated, it is possible to provide additives to the base layer by incorporation in the slurry.
- a waterproofing agent such as silane may be included in the coating in excess of the coating layers requirements.
- the silane will be drawn into and through the base layer being coated thereby treating the base layer.
- This simultaneous treatment of the base layer as well as coating the base layer is a valuable additional benefit arising from the aforedescribed method.
- a slurry of the formulation is prepared by mixing the hydraulic binder, fly ash and other optional components with water.
- the solids content in the slurry is preferably between 50 and 90%, more preferably 55 to 80% and most preferably 60 to Step 2 Slurry application/dewatering
- the slurry is applied to the base layer by any convenient means such as brushes rollers, knives or sprays etc. hi a particular embodiment the slurry is applied by means of the apparatus and method subject of Australian Provisional Patent Application Nos. PR3475 and PR3477, which are incorporated herein by reference.
- the slurry is preferably designed to self level and form a uniform coating on the product.
- the building product to be coated exhibits s certain degree of porosity causing the slurry to dewater and form a uniform deposited cementitious layer.
- Time for dewatering can vary quite dramatically but normally occurs between 10 and 90 seconds, depending on the porosity of the material to be coated, its water content and thickness and viscosity of the slurry formulation.
- a vacuum may be used to reduce the slurry dewatering time if required. This is particularly useful when tailoring the coating process to the speed of a building product forming process, eg between 40 to 45 seconds on a Hatschek production line.
- the green laminate article comprising the building product plus coating is preferably precured for a short time, eg up to 48 hours, then cured by air/moist curing at room temperature, steam curing between 40 and 90°C or autoclaving in a steam pressure vessel between 120 and 200°C.
- a curing time range between 6 and
- 72 hours preferably up to 48 hours, is suitable.
- the length of time chosen for curing is dependent on the formulation, the manufacturing process and form of the article.
- Example 1 Sandable Dewatered Slurry Composition
- Example 3 Flexible & Sandable Dewatered Slurry Composition Function: Flexible & sandable finishing layer on thin fibre cement reinforced cement-based lining.
- the slurry dewatered in 120 seconds (un-aided by vacuum) forming a 1.25 mm thick coating.
- the coated sheet was precured for 48 hours then was autoclave-cured for 8 hrs at 180 °C temperature and 0.80 MPa pressure. It was then sanded flat to 0.60 mm thick using industrial sanders equipped with 100 grit sand paper belts.
- the aforementioned examples provide a coated product comparable in workability to monolithic or single layer composites. They can be flexed, cut, drilled or fixed by nails or the like to a frame without surface cracking or chipping.
- the surface is 'finish-ready' and remains smooth, flat, crack-free and with low permeability even when used in a curved configuration.
- each examples provided excellent interlaminer bond between the base sheet and coating exhibiting good composite action, compatibility and resistance to delamination. It can be seen that the present process provides a significant improvement not only in the attributes of the product but also in the ability to tailor the surface finish of a building product to match particular requirements.
- Examples of particular formulations to provide the desired finish characteristic include a) Terrazzo (hardwearing decorative finish) - the finishing layer of the dewatered slurry can contain marble chips and pigmented cements and fillers. It may then be sanded and polished to form a hardwearing decorative finish.
- Such a coating on, for example, a fibre cement backing board could be used as flooring tiles, decorative wall lining or external prefinished fibre cement cladding.
- Stucco (orange peel) Finish this may be achieved by manipulating speed and volume of the applied slurry to achieve a stucco look on the finishing layer.
- such a product may be used as an external pre-finished cement cladding.
- Sandable finish this is probably the simplest and most straightforward application of the coating technique to provide a coating layer which may be sanded and sealed, thereby providing a paint ready smooth, crack-free and low permeable surface.
- Such a product may be used for a variety of internal and external uses.
- Flexible finish - the coating layer may include various fillers and other additives to improve its flexibility, eg ethylene vinyl acetate, styrene butadiene rubber, styrene acrylic. It is designed to be a sandable, workable ie by score and snap, nailable, crack-free, non-chipping, flexible and bendable, paint ready surface. Such a coating could normally be applied to reasonably thin building product to permit flexibility. It has a wide variety of uses but is particularly suitable as an internal lining in wet area applications or as an external cladding element, eg as a paint ready fibre cement siding.
- Skim-coated finish - such a coating of the dewatered slurry may be applied to gypsum based building products thereby providing a smooth, flat, pre-skim coated and paint ready surface.
- Rubberised finish - by the addition of rubber crumbs into the slurry formulation, a coating layer may be provided on say a fibre cement backing for use as a skid resistant flooring, hardwearing static dissipative flooring or acoustic insulating ceiling panels.
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NZ528305A NZ528305A (en) | 2001-03-02 | 2002-03-04 | Coatings for building products |
JP2002569397A JP4435479B2 (en) | 2001-03-02 | 2002-03-04 | Paint for building materials |
EP02703394A EP1372952A4 (en) | 2001-03-02 | 2002-03-04 | Coatings for building products |
KR10-2003-7011517A KR20030084960A (en) | 2001-03-02 | 2002-03-04 | Coatings for building products |
BR0207806A BR0207806A (en) | 2001-03-02 | 2002-03-04 | Coatings for construction products |
HU0303370A HUP0303370A3 (en) | 2001-03-02 | 2002-03-04 | Coating for building products |
CA 2439484 CA2439484C (en) | 2001-03-02 | 2002-03-04 | Coatings for building products |
MXPA03007894A MXPA03007894A (en) | 2001-03-02 | 2002-03-04 | Coatings for building products. |
PL02363465A PL363465A1 (en) | 2001-03-02 | 2002-03-04 | Coatings for building products |
Applications Claiming Priority (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AUPR3476A AUPR347601A0 (en) | 2001-03-02 | 2001-03-02 | Additive for dewaterable slurry |
AUPR3478A AUPR347801A0 (en) | 2001-03-02 | 2001-03-02 | Coatings for building products |
AUPR3477 | 2001-03-02 | ||
AUPR3474A AUPR347401A0 (en) | 2001-03-02 | 2001-03-02 | A composite product |
AUPR3478 | 2001-03-02 | ||
AUPR3476 | 2001-03-02 | ||
AUPR3475A AUPR347501A0 (en) | 2001-03-02 | 2001-03-02 | Spattering apparatus |
AUPR3475 | 2001-03-02 | ||
AUPR3477A AUPR347701A0 (en) | 2001-03-02 | 2001-03-02 | A method and apparatus for forming a laminated sheet material by spattering |
AUPR3474 | 2001-03-02 | ||
US10/090,387 US6749897B2 (en) | 2001-03-02 | 2002-03-04 | Coatings for building products and methods of using same |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002070248A1 true WO2002070248A1 (en) | 2002-09-12 |
Family
ID=29716375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AU2002/000242 WO2002070248A1 (en) | 2001-03-02 | 2002-03-04 | Coatings for building products |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2002070248A1 (en) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006128890A1 (en) * | 2005-06-03 | 2006-12-07 | Vlaamse Instelling Voor Technologisch Onderzoek (Vito) | A method for marking fibrous products using luminescent materials, and methods for detecting marked products |
GB2438072A (en) * | 2006-05-09 | 2007-11-14 | Glenn Melvin | A dry composition for preparing a flowable mixture for acoustic sound insulation |
GB2450421A (en) * | 2007-06-22 | 2008-12-24 | Mark Phillip Houghton | Drying aid for plaster |
US7762040B2 (en) | 2004-08-12 | 2010-07-27 | Progressive Foam Technologies, Inc. | Insulated fiber cement siding |
US8091313B2 (en) | 2003-10-15 | 2012-01-10 | Progressive Foam Technologies, Inc. | Drainage place for exterior wall product |
US8192658B2 (en) | 2002-11-05 | 2012-06-05 | Certainteed Corporation | Cementitious exterior sheathing product having improved interlaminar bond strength |
US8225567B1 (en) | 2003-10-17 | 2012-07-24 | Exterior Portfolio, Llc | Siding having backer with features for drainage, ventilation, and receiving adhesive |
US8225573B2 (en) | 2005-12-30 | 2012-07-24 | Progressive Foam Technologies, Inc. | Composite siding using a shape molded foam backing member |
US8795813B2 (en) | 2011-02-22 | 2014-08-05 | Exterior Portfolio, Llc | Ribbed backed panels |
US8844233B2 (en) | 2004-08-12 | 2014-09-30 | Progressive Foam Technologies, Inc. | Foam insulation board with edge sealer |
US8910444B2 (en) | 2004-08-12 | 2014-12-16 | Progressive Foam Technologies, Inc. | Foam insulation backer board |
US8910443B2 (en) | 2004-08-12 | 2014-12-16 | Progressive Foam Technologies, Inc. | Foam backer for insulation |
US9097024B2 (en) | 2004-08-12 | 2015-08-04 | Progressive Foam Technologies Inc. | Foam insulation board |
US9309678B1 (en) | 2004-12-29 | 2016-04-12 | Paul J. Mollinger | Backed panel and system for connecting backed panels |
US9434131B2 (en) | 2004-09-30 | 2016-09-06 | Plycem Usa, Inc. | Building panel having a foam backed fiber cement substrate |
CN111517829A (en) * | 2020-05-27 | 2020-08-11 | 广西欧神诺陶瓷有限公司 | Anti-skid antibacterial ceramic tile and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59107985A (en) * | 1982-12-07 | 1984-06-22 | ニチアス株式会社 | Manufacture of floor board |
US4840688A (en) * | 1987-09-11 | 1989-06-20 | Pfleiderer Industrie Gmbh & Co., Kg | Method for the production of fibrous plaster boards |
JPH09227200A (en) * | 1996-02-28 | 1997-09-02 | Nichiha Corp | Production of inorganic board |
WO1999008885A1 (en) * | 1997-08-19 | 1999-02-25 | Dean James Clowes | Building elements, coatings therefor and methods of applying them |
US5888322A (en) * | 1997-07-14 | 1999-03-30 | Nalco Chemical Company | Polymeric oxyalkylate viscosity modifiers for use in gypsum wallboard production |
-
2002
- 2002-03-04 WO PCT/AU2002/000242 patent/WO2002070248A1/en active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59107985A (en) * | 1982-12-07 | 1984-06-22 | ニチアス株式会社 | Manufacture of floor board |
US4840688A (en) * | 1987-09-11 | 1989-06-20 | Pfleiderer Industrie Gmbh & Co., Kg | Method for the production of fibrous plaster boards |
JPH09227200A (en) * | 1996-02-28 | 1997-09-02 | Nichiha Corp | Production of inorganic board |
US5888322A (en) * | 1997-07-14 | 1999-03-30 | Nalco Chemical Company | Polymeric oxyalkylate viscosity modifiers for use in gypsum wallboard production |
WO1999008885A1 (en) * | 1997-08-19 | 1999-02-25 | Dean James Clowes | Building elements, coatings therefor and methods of applying them |
Non-Patent Citations (3)
Title |
---|
DATABASE WPI Week 198431, Derwent World Patents Index; Class P73, AN 1984-191733, XP002994637 * |
DATABASE WPI Week 199745, Derwent World Patents Index; Class L02, AN 1997-486254, XP002994638 * |
See also references of EP1372952A4 * |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9435124B2 (en) | 2002-11-05 | 2016-09-06 | Plycem Usa, Inc. | Cementitious exterior sheathing product having improved interlaminar bond strength |
US8192658B2 (en) | 2002-11-05 | 2012-06-05 | Certainteed Corporation | Cementitious exterior sheathing product having improved interlaminar bond strength |
US8091313B2 (en) | 2003-10-15 | 2012-01-10 | Progressive Foam Technologies, Inc. | Drainage place for exterior wall product |
US8225567B1 (en) | 2003-10-17 | 2012-07-24 | Exterior Portfolio, Llc | Siding having backer with features for drainage, ventilation, and receiving adhesive |
US9097024B2 (en) | 2004-08-12 | 2015-08-04 | Progressive Foam Technologies Inc. | Foam insulation board |
US9359769B2 (en) | 2004-08-12 | 2016-06-07 | Progressive Foam Technologies, Inc. | Insulated fiber cement siding |
US7762040B2 (en) | 2004-08-12 | 2010-07-27 | Progressive Foam Technologies, Inc. | Insulated fiber cement siding |
US8910443B2 (en) | 2004-08-12 | 2014-12-16 | Progressive Foam Technologies, Inc. | Foam backer for insulation |
US8910444B2 (en) | 2004-08-12 | 2014-12-16 | Progressive Foam Technologies, Inc. | Foam insulation backer board |
US8844233B2 (en) | 2004-08-12 | 2014-09-30 | Progressive Foam Technologies, Inc. | Foam insulation board with edge sealer |
US8756891B2 (en) | 2004-08-12 | 2014-06-24 | Progressive Foam Technologies, Inc. | Insulated fiber cement siding |
US9434131B2 (en) | 2004-09-30 | 2016-09-06 | Plycem Usa, Inc. | Building panel having a foam backed fiber cement substrate |
US9309678B1 (en) | 2004-12-29 | 2016-04-12 | Paul J. Mollinger | Backed panel and system for connecting backed panels |
US9816277B2 (en) | 2004-12-29 | 2017-11-14 | Royal Building Products (Usa) Inc. | Backed panel and system for connecting backed panels |
WO2006128890A1 (en) * | 2005-06-03 | 2006-12-07 | Vlaamse Instelling Voor Technologisch Onderzoek (Vito) | A method for marking fibrous products using luminescent materials, and methods for detecting marked products |
US8225573B2 (en) | 2005-12-30 | 2012-07-24 | Progressive Foam Technologies, Inc. | Composite siding using a shape molded foam backing member |
GB2438072B (en) * | 2006-05-09 | 2011-09-07 | Glenn Melvin | Acoustic coating composition |
GB2438072A (en) * | 2006-05-09 | 2007-11-14 | Glenn Melvin | A dry composition for preparing a flowable mixture for acoustic sound insulation |
GB2450421A (en) * | 2007-06-22 | 2008-12-24 | Mark Phillip Houghton | Drying aid for plaster |
GB2450421B (en) * | 2007-06-22 | 2010-05-05 | Mark Phillip Houghton | Drying aid for plaster |
US8795813B2 (en) | 2011-02-22 | 2014-08-05 | Exterior Portfolio, Llc | Ribbed backed panels |
US9428910B2 (en) | 2011-02-22 | 2016-08-30 | Royal Building Products (Usa) Inc. | Ribbed backed panels |
CN111517829A (en) * | 2020-05-27 | 2020-08-11 | 广西欧神诺陶瓷有限公司 | Anti-skid antibacterial ceramic tile and preparation method thereof |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6749897B2 (en) | Coatings for building products and methods of using same | |
WO2002070248A1 (en) | Coatings for building products | |
CA2904990C (en) | Cementitious article comprising hydrophobic finish | |
WO2017004154A1 (en) | Fiber containing aqueous foam composite, the process and use | |
AU2011201333B2 (en) | Coatings for building products | |
AU2002237104A1 (en) | Coatings for building products | |
AU2008200438B2 (en) | A composite product | |
AU2002233068A1 (en) | A composite product |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1-2003-500815 Country of ref document: PH |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2439484 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2002569397 Country of ref document: JP Ref document number: PA/A/2003/007894 Country of ref document: MX |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020037011517 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2002237104 Country of ref document: AU Ref document number: 528305 Country of ref document: NZ Ref document number: 2002703394 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 028072855 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: PV2003-2657 Country of ref document: CZ |
|
WWP | Wipo information: published in national office |
Ref document number: 1020037011517 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2002703394 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWP | Wipo information: published in national office |
Ref document number: PV2003-2657 Country of ref document: CZ |
|
WWP | Wipo information: published in national office |
Ref document number: 528305 Country of ref document: NZ |
|
WWG | Wipo information: grant in national office |
Ref document number: 528305 Country of ref document: NZ |