WO2002074533A3 - Composite articles reinforced with highly oriented microfibers - Google Patents

Composite articles reinforced with highly oriented microfibers Download PDF

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Publication number
WO2002074533A3
WO2002074533A3 PCT/US2002/003320 US0203320W WO02074533A3 WO 2002074533 A3 WO2002074533 A3 WO 2002074533A3 US 0203320 W US0203320 W US 0203320W WO 02074533 A3 WO02074533 A3 WO 02074533A3
Authority
WO
WIPO (PCT)
Prior art keywords
microfibers
composite
polymer
highly oriented
reinforcement
Prior art date
Application number
PCT/US2002/003320
Other languages
French (fr)
Other versions
WO2002074533A2 (en
Inventor
Mario A Perez
Michael D Swan
Terry R Hobbs
Allen R Siedle
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to JP2002573226A priority Critical patent/JP2004533498A/en
Priority to EP02703342A priority patent/EP1368191B1/en
Priority to AU2002236969A priority patent/AU2002236969A1/en
Priority to DE2002610935 priority patent/DE60210935T2/en
Publication of WO2002074533A2 publication Critical patent/WO2002074533A2/en
Publication of WO2002074533A3 publication Critical patent/WO2002074533A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/0008—Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022—Non-woven fabric
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • D01D5/423—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments by fibrillation of films or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/10—Fibres of continuous length
    • B32B2305/20—Fibres of continuous length in the form of a non-woven mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/04—Treatment by energy or chemical effects using liquids, gas or steam
    • B32B2310/0445—Treatment by energy or chemical effects using liquids, gas or steam using gas or flames
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00—Treatment by energy or chemical effects
    • B32B2310/14—Corona, ionisation, electrical discharge, plasma treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00—Polyalkenes
    • B32B2323/10—Polypropylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
    • Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2904—Staple length fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
    • Y10T428/2924—Composite
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2973—Particular cross section
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2973—Particular cross section
    • Y10T428/2976—Longitudinally varying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608—Including strand or fiber material which is of specific structural definition
    • Y10T442/609—Cross-sectional configuration of strand or fiber material is specified
    • Y10T442/613—Microcellular strand or fiber material

Abstract

A composite formed of a polymer matrix phase having a reinforcement phase including polymeric microfibers. The microfibers are preferably formed of a highly oriented polymer, having a high modulus value and a large surface area. The large surface area can serve to tightly bind the microfibers to the polymer matrix phase. The microfibers can be provided as a fully- or partially-microfibrillated film, as a non-woven web of entangled microfibers, or as a pulp having free fibers. The microfibers can be embedded in, or impregnated with, a polymer or polymer precursor. Some composite articles are formed from thermoset resins cured about a highly oriented poylpropylene microfiber reinforcement phase, providing a strong, tough, moisture resistant article. One composite includes a matrix and reinforcement formed of the same material type and having substantially equal refractive indices, allowing the composite to be optically clear.
PCT/US2002/003320 2001-03-15 2002-02-06 Composite articles reinforced with highly oriented microfibers WO2002074533A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2002573226A JP2004533498A (en) 2001-03-15 2002-02-06 Composite articles reinforced with highly oriented microfibers
EP02703342A EP1368191B1 (en) 2001-03-15 2002-02-06 Composite articles reinforced with highly oriented microfibers
AU2002236969A AU2002236969A1 (en) 2001-03-15 2002-02-06 Composite articles reinforced with highly oriented microfibers
DE2002610935 DE60210935T2 (en) 2001-03-15 2002-02-06 COMPOSITE REINFORCED WITH HIGH-ORIENTED MICROFIBERS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/809,446 US6630231B2 (en) 1999-02-05 2001-03-15 Composite articles reinforced with highly oriented microfibers
US09/809,446 2001-03-15

Publications (2)

Publication Number Publication Date
WO2002074533A2 WO2002074533A2 (en) 2002-09-26
WO2002074533A3 true WO2002074533A3 (en) 2002-11-14

Family

ID=25201354

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/003320 WO2002074533A2 (en) 2001-03-15 2002-02-06 Composite articles reinforced with highly oriented microfibers

Country Status (7)

Country Link
US (2) US6630231B2 (en)
EP (1) EP1368191B1 (en)
JP (1) JP2004533498A (en)
AT (1) ATE324256T1 (en)
AU (1) AU2002236969A1 (en)
DE (1) DE60210935T2 (en)
WO (1) WO2002074533A2 (en)

Families Citing this family (154)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6635331B2 (en) * 1998-03-23 2003-10-21 Ronald N. Kessler Universal mat with removable strips
US6586073B2 (en) * 1999-05-07 2003-07-01 3M Innovative Properties Company Films having a microfibrillated surface and method of making
JP2004510021A (en) * 2000-09-29 2004-04-02 トレクセル・インコーポレーテッド Fiber filler molding products
US7195814B2 (en) 2001-05-15 2007-03-27 3M Innovative Properties Company Microfiber-entangled products and related methods
US20020187346A1 (en) * 2001-06-04 2002-12-12 Adzima Leonard J. Powder coated roving for making structural composite
US8802232B2 (en) 2001-06-04 2014-08-12 Ocv Intellectual Capital, Llc Powder coated roving for making structural composites
US6645618B2 (en) 2001-06-15 2003-11-11 3M Innovative Properties Company Aliphatic polyester microfibers, microfibrillated articles and use thereof
US6692823B2 (en) 2001-12-19 2004-02-17 3M Innovative Properties Company Microfibrillated articles comprising hydrophillic component
US6753080B1 (en) 2002-01-29 2004-06-22 3M Innovative Properties Company Receptor medium having a microfibrillated surface
US7353756B2 (en) * 2002-04-10 2008-04-08 Accutec Usa Lead free reduced ricochet limited penetration projectile
US20030192448A1 (en) * 2002-04-10 2003-10-16 Leasure John D. Lead free reduced ricochet limited penetration projectile
US6890649B2 (en) 2002-04-26 2005-05-10 3M Innovative Properties Company Aliphatic polyester microfibers, microfibrillated articles and use thereof
US20030236553A1 (en) * 2002-06-24 2003-12-25 Celanese Advanced Materials, Inc. Thermotropic polymer heterofilament
AU2003258209A1 (en) * 2002-08-13 2004-02-25 Medtronic, Inc. Active agent delivery systems, medical devices, and methods
DE60331552D1 (en) * 2002-08-13 2010-04-15 Medtronic Inc PHARMACEUTICALS COMPOSITIONS USING POLY (ETHYLENE-CO (METH) ACRYLATE, MEDICAL DEVICE AND METHOD
WO2004014449A1 (en) * 2002-08-13 2004-02-19 Medtronic, Inc. Active agent delivery system including a polyurethane, medical device, and method
JP2006502136A (en) * 2002-08-13 2006-01-19 メドトロニック・インコーポレーテッド Active agent delivery system comprising a hydrophilic polymer, a medical device, and a method
DE10239391B4 (en) * 2002-08-28 2004-11-25 Werner Kammann Maschinenfabrik Gmbh Holder for an object to be decorated
SG138444A1 (en) * 2002-12-04 2008-01-28 Inventio Ag Reinforced synthetic cable for lifts
CN100488755C (en) * 2003-04-24 2009-05-20 奥利-本特·拉斯马森 Method of manufacturing an oriented film from alloyed thermoplastic polymers, apparatus for such manufacture and resulting products
EP1620506B1 (en) * 2003-05-02 2011-03-09 E.I. Du Pont De Nemours And Company Polyesters containing microfibers, and methods for making and using same
US7892993B2 (en) 2003-06-19 2011-02-22 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US8513147B2 (en) 2003-06-19 2013-08-20 Eastman Chemical Company Nonwovens produced from multicomponent fibers
US20040260034A1 (en) * 2003-06-19 2004-12-23 Haile William Alston Water-dispersible fibers and fibrous articles
US7014093B2 (en) * 2003-06-26 2006-03-21 Intel Corporation Multi-layer polymer-solder hybrid thermal interface material for integrated heat spreader and method of making same
KR101309567B1 (en) * 2003-07-31 2013-09-25 미쓰비시 가가꾸 가부시키가이샤 Fiber-reinforced composite material, process for producing the same and use thereof
WO2005018702A2 (en) * 2003-08-13 2005-03-03 Medtronic, Inc. Active agent delivery systems including a miscible polymer blend, medical devices, and methods
EP1660145A2 (en) * 2003-08-13 2006-05-31 Medtronic, Inc. Active agent delivery systems, including a single layer of a miscible polymer blend, medical devices and methods
JP4560672B2 (en) * 2003-10-24 2010-10-13 株式会社スリーボンド Curable resin composition
JP4550437B2 (en) * 2004-01-20 2010-09-22 ポリマテック株式会社 Polybenzazole molded body and method for producing the same
US7553371B2 (en) * 2004-02-02 2009-06-30 Nanosys, Inc. Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production
US8025960B2 (en) * 2004-02-02 2011-09-27 Nanosys, Inc. Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production
US20110039690A1 (en) * 2004-02-02 2011-02-17 Nanosys, Inc. Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production
US20050167928A1 (en) * 2004-02-04 2005-08-04 Park Edward H. Dynamic seal using vulcanization of fluorocarbon elastomers
US7999455B2 (en) 2006-11-13 2011-08-16 Research Triangle Institute Luminescent device including nanofibers and light stimulable particles disposed on a surface of or at least partially within the nanofibers
FR2874352B1 (en) * 2004-08-20 2006-11-24 Plastic Omnium Cie PLASTIC COMPONENT FOR MOTOR VEHICLE COMPRISING POLYPROPYLENE LOADED WITH GLASS FIBERS
WO2006091245A2 (en) 2004-10-22 2006-08-31 Dow Global Technologies Inc. Plastic composite articles and methods of making same
US7348047B2 (en) * 2004-10-29 2008-03-25 Mary Ellen Snell Multi-layered structural corrosion resistant composite liner
FR2879498B1 (en) * 2004-12-16 2009-01-30 Snecma Propulsion Solide Sa DENSIFICATION OF FIBROUS STRUCTURES BY RTM FOR THE PRODUCTION OF PARTS IN COMPOSITE MATERIAL
US20060134408A1 (en) * 2004-12-20 2006-06-22 Mitsubishi Rayon Co., Ltd. Process for producing sandwich structure and adhesive film therefor
TW200630415A (en) * 2004-12-21 2006-09-01 Clariant Int Ltd Process for the preparation of cross-linked PBT particles
US20090291281A1 (en) * 2005-01-20 2009-11-26 Hanket Gregory M Microfiller-Reinforced Polymer Film
US7406239B2 (en) * 2005-02-28 2008-07-29 3M Innovative Properties Company Optical elements containing a polymer fiber weave
US7386212B2 (en) * 2005-02-28 2008-06-10 3M Innovative Properties Company Polymer photonic crystal fibers
US7356231B2 (en) * 2005-02-28 2008-04-08 3M Innovative Properties Company Composite polymer fibers
US20060193578A1 (en) * 2005-02-28 2006-08-31 Ouderkirk Andrew J Composite polymeric optical films with co-continuous phases
US7362943B2 (en) * 2005-02-28 2008-04-22 3M Innovative Properties Company Polymeric photonic crystals with co-continuous phases
US7356229B2 (en) * 2005-02-28 2008-04-08 3M Innovative Properties Company Reflective polarizers containing polymer fibers
US7176426B2 (en) * 2005-03-18 2007-02-13 Ramirez Juan Jose Integrated microwaveable heat storage device
US7445834B2 (en) * 2005-06-10 2008-11-04 Morin Brian G Polypropylene fiber for reinforcement of matrix materials
US7658387B2 (en) 2005-06-27 2010-02-09 Freudenberg-Nok General Partnership Reinforced elastomeric seal
US8057887B2 (en) * 2005-08-17 2011-11-15 Rampart Fibers, LLC Composite materials including high modulus polyolefin fibers
US7648607B2 (en) * 2005-08-17 2010-01-19 Innegrity, Llc Methods of forming composite materials including high modulus polyolefin fibers
US7892633B2 (en) * 2005-08-17 2011-02-22 Innegrity, Llc Low dielectric composite materials including high modulus polyolefin fibers
DE102005051550A1 (en) * 2005-10-27 2007-05-03 Fibertex A/S Superhydrophobic coating of a polymer fleece, in particular a polypropylene fleece
WO2007058184A1 (en) * 2005-11-15 2007-05-24 Techno Polymer Co., Ltd. Resin molding process and resin molding apparatus
US7875675B2 (en) 2005-11-23 2011-01-25 Milgard Manufacturing Incorporated Resin for composite structures
US8101107B2 (en) 2005-11-23 2012-01-24 Milgard Manufacturing Incorporated Method for producing pultruded components
US8597016B2 (en) 2005-11-23 2013-12-03 Milgard Manufacturing Incorporated System for producing pultruded components
US7901762B2 (en) 2005-11-23 2011-03-08 Milgard Manufacturing Incorporated Pultruded component
AU2006321721B2 (en) 2005-12-08 2012-07-05 Covidien Lp Biocompatible surgical compositons
US8455088B2 (en) * 2005-12-23 2013-06-04 Boston Scientific Scimed, Inc. Spun nanofiber, medical devices, and methods
US7408842B2 (en) * 2006-03-30 2008-08-05 Materials Sciences Corporation Sonar dome
US20070238167A1 (en) * 2006-04-04 2007-10-11 3M Innovative Properties Company Flat microfibers as matrices for cell growth
US20070231362A1 (en) * 2006-04-04 2007-10-04 3M Innovative Properties Company Schistose microfibrillated article for cell growth
MX2008012936A (en) * 2006-04-05 2008-10-15 Schering Corp Pharmaceutical formulations: salts of 8-[{1-(3,5-bis (trifluoromethy1)pheny1)-e thoxy}-methy1]-8-pheny1-1,7-diaza-spi ro[4.5] decan-2-one and treatment methods using the same.
EP2019747A4 (en) * 2006-05-25 2010-05-05 Arkema Inc Impact modifier composition for transparent thermoplastics
US20090286910A1 (en) * 2006-05-26 2009-11-19 University Of Virginia Patent Foundation Viscoelastic and Dilatant Composition, Device and Method of Use and Manufacture
US20070281157A1 (en) * 2006-06-05 2007-12-06 Laney Thomas M Reflective polarizer, fiber, and process for making
US7773834B2 (en) 2006-08-30 2010-08-10 3M Innovative Properties Company Multilayer polarizing fibers and polarizers using same
US20080057277A1 (en) * 2006-08-30 2008-03-06 3M Innovative Properties Company Polymer fiber polarizers
US7599592B2 (en) * 2006-08-30 2009-10-06 3M Innovative Properties Company Polymer fiber polarizers with aligned fibers
US8105682B2 (en) * 2006-09-01 2012-01-31 The Regents Of The University Of California Thermoplastic polymer microfibers, nanofibers and composites
NO20065147L (en) * 2006-11-08 2008-05-09 Ntnu Tech Transfer As Nanocomposites based on cellulose whiskers and cellulose plastic
US7632563B2 (en) 2006-12-14 2009-12-15 Ppg Industries Ohio, Inc. Transparent composite articles
US20080227914A1 (en) * 2007-03-16 2008-09-18 Bfs Diversified Products, Llc Recycled building material and method thereof
US8323436B2 (en) * 2007-03-28 2012-12-04 The United States Of America As Represented By The Secretary Of The Army Transparent, reinforced, composite fiber and articles made therefrom
US8038364B2 (en) 2007-08-07 2011-10-18 Saint-Gobain Technical Fabrics America, Inc. Reinforcement for asphaltic paving, method of paving, and process for making a grid with the coating for asphaltic paving
US20090061221A1 (en) * 2007-08-07 2009-03-05 Saint-Gobain Technical Fabrics Composite tack film for asphaltic paving, method of paving, and process for making a composite tack film for asphaltic paving
US8349431B2 (en) * 2007-08-07 2013-01-08 Saint-Gobain Adfors America, Inc. Composite grid with tack film for asphaltic paving, method of paving, and process for making a composite grid with tack film for asphaltic paving
US9334378B2 (en) * 2008-01-11 2016-05-10 The Boeing Company Distortion resistant transparent reinforcing fibers for use in transparent reinforced composites
US9481962B2 (en) * 2008-02-11 2016-11-01 Veyance Technologies, Inc. Method for treating textile material for use in reinforced elastomeric articles
DE102008022377B4 (en) * 2008-05-06 2014-02-13 Eurocopter Deutschland Gmbh Support strut for supporting an intermediate deck arranged in an aircraft fuselage and method for producing a rod body for such a support strut
DE102008001855A1 (en) * 2008-05-19 2009-11-26 Evonik Degussa Gmbh Two-component composition for the production of flexible polyurethane gelcoats
US9518163B2 (en) * 2008-05-26 2016-12-13 Semmes, Inc. Reinforced polymer foams, articles and coatings prepared therefrom and methods of making the same
DE102008029058A1 (en) * 2008-06-18 2009-12-24 GKN Aerospace Services Limited, East Cowes Method and mold for making fiber reinforced composite components with microwaves
JP5531295B2 (en) * 2008-07-31 2014-06-25 国立大学法人京都大学 Molding material containing unsaturated polyester resin and microfibrillated plant fiber
US7935283B2 (en) 2009-01-09 2011-05-03 Honeywell International Inc. Melt spinning blends of UHMWPE and HDPE and fibers made therefrom
DE102009001145A1 (en) 2009-02-25 2010-09-09 Leibniz-Institut Für Polymerforschung Dresden E.V. Method for curing and surface functionalization of molded parts
US8512519B2 (en) 2009-04-24 2013-08-20 Eastman Chemical Company Sulfopolyesters for paper strength and process
HUE059099T2 (en) 2009-05-19 2022-10-28 Oned Mat Inc Nanostructured materials for battery applications
US9604878B2 (en) 2009-08-11 2017-03-28 Johns Manville Curable fiberglass binder comprising salt of inorganic acid
US9365963B2 (en) 2009-08-11 2016-06-14 Johns Manville Curable fiberglass binder
CN102712167A (en) 2009-12-03 2012-10-03 研究三角协会 Reflective nanofiber lighting devices
EP2388131B1 (en) * 2010-05-20 2016-08-31 Siemens Aktiengesellschaft Method of moulding a wind turbine blade using a release film, and said film
US10149749B2 (en) 2010-06-17 2018-12-11 Washington University Biomedical patches with aligned fibers
DE202010018427U1 (en) 2010-07-09 2016-07-05 Urs Gassmann Sealing and assembly tape with a cut protection
US8559779B2 (en) * 2010-10-08 2013-10-15 The Boeing Company Transparent composites with organic fiber
US9273417B2 (en) 2010-10-21 2016-03-01 Eastman Chemical Company Wet-Laid process to produce a bound nonwoven article
JP5897593B2 (en) * 2010-12-01 2016-03-30 サイテク・テクノロジー・コーポレーシヨン Resin-soluble veil for manufacturing composite products and method for manufacturing same
US8944789B2 (en) 2010-12-10 2015-02-03 National Oilwell Varco, L.P. Enhanced elastomeric stator insert via reinforcing agent distribution and orientation
US8568854B2 (en) * 2010-12-15 2013-10-29 The Boeing Company Optimized fiber shapes for improved optical performance
JP6255668B2 (en) * 2011-01-18 2018-01-10 日立化成株式会社 Prepreg, laminated board using the same, and printed wiring board
DE102011003312A1 (en) 2011-01-28 2012-08-02 Siemens Aktiengesellschaft Fiber composite plastic and manufacturing method thereto
DE102011014998B4 (en) * 2011-03-25 2013-04-04 Waldemar Piekenbrink GFK - Modell- und Formenbau, Produktions- und Vertriebs GmbH Panel device with damage-resistant graphic design of the surfaces
WO2013014420A1 (en) 2011-07-25 2013-01-31 Fujifilm Manufacturing Europe Bv Composite membranes
US9023450B2 (en) 2011-09-06 2015-05-05 Honeywell International Inc. High lap shear strength, low back face signature UD composite and the process of making
US9222864B2 (en) 2011-09-06 2015-12-29 Honeywell International Inc. Apparatus and method to measure back face signature of armor
US9163335B2 (en) 2011-09-06 2015-10-20 Honeywell International Inc. High performance ballistic composites and method of making
US9023451B2 (en) 2011-09-06 2015-05-05 Honeywell International Inc. Rigid structure UHMWPE UD and composite and the process of making
US9168719B2 (en) 2011-09-06 2015-10-27 Honeywell International Inc. Surface treated yarn and fabric with enhanced physical and adhesion properties and the process of making
US9023452B2 (en) 2011-09-06 2015-05-05 Honeywell International Inc. Rigid structural and low back face signature ballistic UD/articles and method of making
US8840758B2 (en) 2012-01-31 2014-09-23 Eastman Chemical Company Processes to produce short cut microfibers
EP2825590B1 (en) * 2012-03-16 2017-04-19 3M Innovative Properties Company Light weight articles, composite compositions, and processes for making the same
EP2836361B1 (en) * 2012-04-13 2021-09-08 Case Western Reserve University Production of micro- and nano-fibers by continuous microlayer coextrusion
CN102661562B (en) * 2012-04-20 2014-05-07 奇瑞汽车股份有限公司 Automobile lamp and automobile
EP2897799A4 (en) * 2012-09-18 2016-07-06 Cubic Tech Corp Flexible composite systems
CA2885682C (en) 2012-09-21 2020-03-10 Washington University Biomedical patches with spatially arranged fibers
US9991588B2 (en) * 2012-09-24 2018-06-05 Conductive Composites Company Highly conductive fiber reinforced antennas
CA2888221C (en) 2012-10-19 2017-09-19 Saint-Gobain Adfors Canada, Ltd. Composite tack film
KR102158890B1 (en) 2012-11-09 2020-09-23 디에스엠 아이피 어셋츠 비.브이. Threedimensional articles from flexible composite materials
US8689696B1 (en) * 2013-02-21 2014-04-08 Caneel Associates, Inc. Composite projectile and cartridge with composite projectile
US9789662B2 (en) 2013-03-13 2017-10-17 Cubic Tech Corporation Engineered composite systems
KR102421970B1 (en) 2013-03-13 2022-07-15 디에스엠 아이피 어셋츠 비.브이. Flexible composite systems and methods
KR102239041B1 (en) 2013-03-13 2021-04-12 디에스엠 아이피 어셋츠 비.브이. Systems and method for producing three-dimensional articles from flexible composite materials
US9303357B2 (en) 2013-04-19 2016-04-05 Eastman Chemical Company Paper and nonwoven articles comprising synthetic microfiber binders
DK3013880T3 (en) 2013-06-25 2019-04-01 Covestro Llc POLYURETHAN PULTRUDING FORMULATIONS FOR THE PREPARATION OF ARTICLES WITH IMPROVED COATING ADHESION AND THEREFORE FROM MANUFACTURED ARTICLES
US11752737B2 (en) * 2013-11-18 2023-09-12 Lingrove Inc. Aesthetically-enhanced structures using natural fiber composites
SE538714C2 (en) * 2013-11-18 2016-10-25 Flexiteek Int As Extruded product for covering a boat or yacht deck or other outdoor area
US9598802B2 (en) 2013-12-17 2017-03-21 Eastman Chemical Company Ultrafiltration process for producing a sulfopolyester concentrate
US9605126B2 (en) 2013-12-17 2017-03-28 Eastman Chemical Company Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion
CA2938763C (en) 2014-02-18 2020-12-15 Reme Technologies, Llc Graphene enhanced elastomeric stator
WO2015199786A2 (en) 2014-04-07 2015-12-30 Einstein Noodles, Llc Providing spin to composite projectile
US10791779B2 (en) * 2014-12-10 2020-10-06 The Charles Stark Draper Laboratory, Inc. Polymer microwedges and methods of manufacturing same
EP3242796B1 (en) 2015-01-09 2020-08-12 DSM IP Assets B.V. Lightweight laminates and plate-carrier vests and other articles of manufacture therefrom
NO337236B1 (en) * 2015-01-15 2016-02-22 Calorflex As A mooring member
US9757905B2 (en) 2015-05-11 2017-09-12 Covestro Llc Filament winding processes using polyurethane resins and systems for making composites
EP3135313B1 (en) * 2015-08-24 2020-12-02 Junkosha Inc. Heat-shrinkable tube having tearability
US9648889B2 (en) 2015-09-11 2017-05-16 John Pallas Liquid-egg replacement composition
KR101966736B1 (en) * 2015-09-15 2019-04-09 주식회사 엘지화학 Modified Polyimide and Curable Resin Composition Comprising Same
US10328671B2 (en) 2015-11-09 2019-06-25 Seaman Corporation Solid-phase composite structure and related methods
US10933609B2 (en) 2016-03-31 2021-03-02 The Regents Of The University Of California Composite foam
US10632228B2 (en) 2016-05-12 2020-04-28 Acera Surgical, Inc. Tissue substitute materials and methods for tissue repair
US10590577B2 (en) 2016-08-02 2020-03-17 Fitesa Germany Gmbh System and process for preparing polylactic acid nonwoven fabrics
US11441251B2 (en) 2016-08-16 2022-09-13 Fitesa Germany Gmbh Nonwoven fabrics comprising polylactic acid having improved strength and toughness
TWI788308B (en) * 2016-10-31 2023-01-01 美商普利馬洛夫特公司 An air-cured batting comprising a nonwoven web and method of making same
JP6937160B2 (en) 2017-05-01 2021-09-22 パナソニック株式会社 Fiber composite resin molded parts
US10746031B2 (en) 2017-07-18 2020-08-18 Rolls-Royce Corporation Annulus filler
US11078839B2 (en) 2018-01-22 2021-08-03 Rolls-Royce Corporation Composite nosecone
JP7264340B2 (en) 2018-03-16 2023-04-25 パナソニックホールディングス株式会社 Method for producing fiber composite resin composition
GB2588553B (en) 2018-06-27 2022-10-19 Kimberly Clark Co Nanoporous Superabsorbent Particles
WO2021230993A2 (en) * 2020-04-02 2021-11-18 Elysium Robotics Llc Dielectric elastomer microfiber actuators
US11421538B2 (en) 2020-05-12 2022-08-23 Rolls-Royce Corporation Composite aerofoils
US11506083B2 (en) 2020-06-03 2022-11-22 Rolls-Royce Corporalion Composite liners for turbofan engines

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0353907A2 (en) * 1988-08-04 1990-02-07 Minnesota Mining And Manufacturing Company Fibrillated tape and method of making same
US5434002A (en) * 1990-06-04 1995-07-18 Korea Institute Of Science And Technology Non-spun, short, acrylic polymer, fibers
WO1997049326A1 (en) * 1996-06-27 1997-12-31 Minnesota Mining And Manufacturing Company Cleaning article and method of making same
US6110588A (en) * 1999-02-05 2000-08-29 3M Innovative Properties Company Microfibers and method of making
WO2000068301A1 (en) * 1999-05-07 2000-11-16 3M Innovative Properties Company Films having a fibrillated surface and method of making

Family Cites Families (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US31285A (en) * 1861-01-29 Making- finger-guards for harvesters
US32171A (en) * 1861-04-30 Coiffibinatioit-lbck
US30782A (en) * 1860-11-27 John wright
GB1073741A (en) 1962-08-30 1967-06-28 Plasticisers Ltd Process and apparatus for producing multifilament material and products produced therefrom
BE666243A (en) 1964-07-01
US3416714A (en) 1966-07-05 1968-12-17 Phillips Petroleum Co Method of fibrillation
GB1157695A (en) 1966-11-17 1969-07-09 Monsanto Chemicals Production of Fibrous Materials
GB1171543A (en) 1967-01-16 1969-11-19 Gordon Ashworth Improvements in or relating to the Treatment of Thermoplastic Materials
US3470594A (en) 1967-03-30 1969-10-07 Hercules Inc Method of making synthetic textile yarn
GB1234782A (en) 1967-10-04 1971-06-09 Courtaulds Ltd Fibrillation process
US3470685A (en) 1967-10-10 1969-10-07 Hercules Inc Synthetic textile yarn
CA936323A (en) 1969-05-06 1973-11-06 Hercules Incorporated Process for making bulked yarns by the fibrillation of thermoplastic films
US3719540A (en) 1970-05-04 1973-03-06 Hercules Inc Preparation of transversely fibrillated film
JPS5142138B1 (en) * 1970-07-20 1976-11-13
US3954928A (en) * 1970-07-28 1976-05-04 Teijin Ltd. Process for making sheet-formed reticulated fibrous structures
US3695025A (en) * 1970-07-30 1972-10-03 Fiber Industries Inc Fibrillated film yarn
US4134951A (en) * 1971-08-31 1979-01-16 Smith & Nephew Polyfabrik Limited Production of filaments
NL160303C (en) 1974-03-25 1979-10-15 Verto Nv METHOD FOR MANUFACTURING A FIBER FILTER
US4100324A (en) * 1974-03-26 1978-07-11 Kimberly-Clark Corporation Nonwoven fabric and method of producing same
US4064214A (en) 1975-09-22 1977-12-20 E. I. Du Pont De Nemours And Company Process for making polytetrafluoroethylene yarn
US4065214A (en) 1976-08-30 1977-12-27 Daum Emill F Portable wax applicator and remover
NL181632C (en) 1976-12-23 1987-10-01 Minnesota Mining & Mfg ELECTRIC FILTER AND METHOD FOR MANUFACTURING THAT.
GB1541681A (en) 1977-07-13 1979-03-07 Metal Box Co Ltd Drawn polymer articles
GB1605004A (en) 1978-05-04 1981-12-16 Eternit Fab Dansk As Fibre reinforced building products
GB2034243B (en) 1978-11-17 1982-09-15 Metal Box Co Ltd Fibrillated synthetic polymer material
DE2853398C3 (en) 1978-12-11 1981-09-17 Unilever N.V., Rotterdam Method and device for simultaneous biaxial stretching of a plastic film web
US4242398A (en) * 1979-01-16 1980-12-30 Teijin Limited Fibrous shaped article having non-level surface
DE2920514A1 (en) 1979-05-21 1980-11-27 Unilever Nv DYNAMIC LOADABLE POLYPROPYLENE FILM
ATE3274T1 (en) 1979-09-01 1983-05-15 Plasticisers Limited REINFORCEMENT FIBER MATERIAL FOR HYDRAULICALLY CURING MASS AND METHOD OF REINFORCEMENT OF SUCH MASS.
US4348350A (en) 1980-09-26 1982-09-07 Michigan Molecular Institute Ultra-drawing crystalline polymers under high pressure
AU565762B2 (en) 1983-02-04 1987-09-24 Minnesota Mining And Manufacturing Company Method and apparatus for manufacturing an electret filter medium
US4524101A (en) 1983-02-07 1985-06-18 Celanese Corporation High modulus polyethylene fiber bundles as reinforcement for brittle matrices
US4456648A (en) 1983-09-09 1984-06-26 Minnesota Mining And Manufacturing Company Particulate-modified electret fibers
DE3335933A1 (en) 1983-10-04 1985-04-18 Rütgerswerke AG, 6000 Frankfurt MULTI-COMPONENT BINDERS WITH EXTENDED PROCESSABILITY
DE3509857C2 (en) 1984-03-19 1994-04-28 Toyo Boseki Electretized dust filter and its manufacture
JPS60196921A (en) 1984-03-19 1985-10-05 東洋紡績株式会社 Method of producing electreted material
JPS60225416A (en) 1984-04-24 1985-11-09 三井化学株式会社 High performance electret and air filter
US4714716A (en) 1984-11-16 1987-12-22 The Dow Chemical Company Lightly crosslinked linear olefinic polymer foams and process for making
ZA86528B (en) 1985-01-31 1986-09-24 Himont Inc Polypropylene with free-end long chain branching,process for making it,and use thereof
US4608089A (en) 1985-07-19 1986-08-26 E. I. Du Pont De Nemours And Company Cement matrix composites and method of making same
US5176833A (en) 1985-09-16 1993-01-05 The Dow Chemical Company Filters employing particulate porous polymers
US4853602A (en) 1985-12-24 1989-08-01 E. I. Dupont De Nemours And Company System for using synchronous secondaries of a linear motor to biaxially draw plastic films
US4675582A (en) 1985-12-24 1987-06-23 E. I. Du Pont De Nemours And Company System useful for controlling multiple synchronous secondaries of a linear motor along an elongated path
US5171815A (en) 1986-10-22 1992-12-15 University Of Pittsburgh Method for producing doubly oriented polymers
US5049347A (en) 1988-11-22 1991-09-17 The University Of Pittsburgh Method for producing doubly oriented polymers
US4867937A (en) 1987-02-17 1989-09-19 Minnesota Mining And Manufacturing Company Process for producing high modulus film
US4825111A (en) 1987-11-02 1989-04-25 E. I. Du Pont De Nemours And Company Linear motor propulsion system
DE3737493A1 (en) 1987-11-05 1989-05-18 Hoechst Ag METHOD FOR INCREASING THE ELECTROSTATIC RECHARGEABILITY OF POWDER VARNISHES AND POWDERS AND THEIR USE FOR SURFACE COATING OF FIXED OBJECTS
DE3737496A1 (en) 1987-11-05 1989-05-18 Hoechst Ag METHOD FOR INCREASING THE ELECTROSTATIC RECHARGEABILITY OF POWDER VARNISHES AND POWDERS AND THEIR USE FOR SURFACE COATING OF FIXED OBJECTS
DE3839956C2 (en) 1987-11-28 1998-07-02 Toyo Boseki Electret film and process for its production
US5993943A (en) * 1987-12-21 1999-11-30 3M Innovative Properties Company Oriented melt-blown fibers, processes for making such fibers and webs made from such fibers
JP2672329B2 (en) 1988-05-13 1997-11-05 東レ株式会社 Electret material
US5072493A (en) 1988-06-22 1991-12-17 E. I. Du Pont De Nemours And Company Apparatus for drawing plastic film in a tenter frame
US5051225A (en) 1988-06-22 1991-09-24 E. I. Du Pont De Nemours And Company Method of drawing plastic film in a tenter frame
LU87310A1 (en) 1988-08-04 1990-03-13 Oreal N- (MERCAPTOALKYL) OMEGA-HYDROXYALKYLAMIDES AND THEIR USE AS REDUCING AGENTS, IN A PERMANENT HAIR DEFORMATION PROCESS
US4940736A (en) 1988-09-12 1990-07-10 Amoco Corporation Production of low density polypropylene foam
DE3837345A1 (en) 1988-11-03 1990-05-10 Hoechst Ag USE OF COLORLESS HIGH GRADE FLUORATED AMMONIUM AND IMMONIUM COMPOUNDS AS LOADING AGENTS FOR ELECTROPHOTOGRAPHIC RECORDING METHODS
US4990401A (en) 1989-01-06 1991-02-05 Minnesota Mining And Manufacturing Company Biaxially-oriented polyester film having a dual-sided appearance and method for making same
US5043197A (en) 1989-01-06 1991-08-27 Minnesota Mining And Manufacturing Company Method for making biaxially-oriented polyester film having a dual-sided appearance and article made therefrom
DE3912396A1 (en) 1989-04-15 1990-10-25 Hoechst Ag USE OF COLORLESS HIGH GRADE FLUORATE-SUBSTITUTED PHOSPHONIUM COMPOUNDS AS LOADING AGENTS FOR ELECTROPHOTOGRAPHIC RECORDING METHODS
US5036262A (en) 1989-09-13 1991-07-30 E. I. Du Pont De Nemours And Company Method of determining control instructions
JPH03155903A (en) * 1989-11-14 1991-07-03 I T W Kk Epoxy resin synthetic lumber
US5085920A (en) * 1990-04-30 1992-02-04 Kimberly-Clark Corporation Nonwoven wipe having improved grease release
DE69131343T2 (en) 1990-10-19 2000-01-13 Toray Industries POLYESTER MONOFILAMENT
JP2672188B2 (en) 1990-11-21 1997-11-05 日本石油株式会社 Method for producing fibrillated polyolefin material
US5176953A (en) * 1990-12-21 1993-01-05 Amoco Corporation Oriented polymeric microporous films
US5258220A (en) 1991-09-30 1993-11-02 Minnesota Mining And Manufacturing Company Wipe materials based on multi-layer blown microfibers
US5260095A (en) 1992-08-21 1993-11-09 Battelle Memorial Institute Vacuum deposition and curing of liquid monomers
US5589264A (en) 1992-10-01 1996-12-31 Korea Institute Of Science And Technology Unspun acrylic staple fibers
US5269995A (en) 1992-10-02 1993-12-14 The Dow Chemical Company Coextrusion of multilayer articles using protective boundary layers and apparatus therefor
US5387388A (en) 1992-10-09 1995-02-07 Illinois Tool Works Inc. Method for producing oriented plastic strap
US5695709A (en) 1992-10-09 1997-12-09 Signode Corporation Method and apparatus for producing highly oriented polyester sheet
US5525287A (en) 1992-10-09 1996-06-11 Signode Corporation Method for producing oriented plastic strap
US5354603A (en) * 1993-01-15 1994-10-11 Minnesota Mining And Manufacturing Company Antifouling/anticorrosive composite marine structure
DE59410352D1 (en) 1993-03-09 2004-03-11 Trevira Gmbh Electret fibers with improved charge stability, process for their production, and textile material containing these electret fibers
DE69404736T2 (en) 1993-03-09 1998-01-08 Hoechst Celanese Corp Polymer electrets with improved charge stability
AU669420B2 (en) 1993-03-26 1996-06-06 Minnesota Mining And Manufacturing Company Oily mist resistant electret filter media
US5366804A (en) * 1993-03-31 1994-11-22 Basf Corporation Composite fiber and microfibers made therefrom
EP0705354B1 (en) 1993-06-02 1997-06-11 Minnesota Mining And Manufacturing Company Nonwoven articles and methods of producing same
US5414027A (en) 1993-07-15 1995-05-09 Himont Incorporated High melt strength, propylene polymer, process for making it, and use thereof
KR100336012B1 (en) 1993-08-17 2002-10-11 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 How to charge the electret filter media
DE4327595A1 (en) 1993-08-17 1995-02-23 Hoechst Ag Compositions with improved electrostatic properties containing aromatic polyamides, molded articles made therefrom and their use and process for their production
CA2124237C (en) 1994-02-18 2004-11-02 Bernard Cohen Improved nonwoven barrier and method of making the same
US5698489A (en) 1994-02-25 1997-12-16 Dai Nippon Printing Co., Ltd. Thermal transfer image-receiving sheet
US6101032A (en) 1994-04-06 2000-08-08 3M Innovative Properties Company Light fixture having a multilayer polymeric film
JPH0811222A (en) * 1994-06-30 1996-01-16 Sekisui Chem Co Ltd Manufacturing device of extraction-molded product
JPH0971663A (en) * 1995-09-07 1997-03-18 Kawasaki Steel Corp Stampable sheet formed by screening method and high strength lightweight stampable sheet formed product by using the same
AU706253B2 (en) 1995-06-26 1999-06-10 Minnesota Mining And Manufacturing Company Transflective displays with reflective polarizing transflector
US5908598A (en) 1995-08-14 1999-06-01 Minnesota Mining And Manufacturing Company Fibrous webs having enhanced electret properties
US5807516A (en) 1995-10-13 1998-09-15 Westaim Technologies Inc. Process of making molecularly oriented polymer profiles
DE59704221D1 (en) 1996-05-08 2001-09-13 Solipat Ag Zug Method and device for the fibrillation of easily fibrillatable cellulose fibers, in particular Tencel fibers
US5804625A (en) 1996-05-21 1998-09-08 Minnesota Mining And Manufacturing Company Fluorochemical and hydrocarbon surfactant blends as hydrophilic additives to thermoplastic polymers
US5945221A (en) 1996-06-20 1999-08-31 Alliedsignal Inc. Biaxial orientation of fluoropolymer films
US5783503A (en) 1996-07-22 1998-07-21 Fiberweb North America, Inc. Meltspun multicomponent thermoplastic continuous filaments, products made therefrom, and methods therefor
US5945215A (en) 1996-09-16 1999-08-31 Bp Amoco Corporation Propylene polymer fibers and yarns
US6037056A (en) * 1997-01-08 2000-03-14 Owens Corning Fiberglas Technology, Inc. Transversely and axially reinforced pultrusion product
US5897779A (en) * 1997-02-13 1999-04-27 Minnesota Mining And Manufacturing Company Spiral wound extraction cartridge
JP2001512190A (en) 1997-07-31 2001-08-21 ミネソタ マイニング アンド マニュファクチャリング カンパニー Non-woven article having a vibrant color based on polyvinyl alcohol and method for producing the article
US6265512B1 (en) 1997-10-23 2001-07-24 3M Innovative Company Elastic polypropylenes and catalysts for their manufacture
CN1123593C (en) 1998-01-19 2003-10-08 聚合物澳大利亚有限公司 Process for increasing melt strength of polypropylene
CN1303337A (en) 1998-05-27 2001-07-11 陶氏化学公司 Vehicle headliner comprised of thermofoamable thermoplastic foam sheet
NO313835B1 (en) 1998-06-19 2002-12-09 Borealis As Process for branching polypropylene materials, process for branching and foaming polypropylene materials, and using the polymeric materials obtained by the methods
US6123752A (en) 1998-09-03 2000-09-26 3M Innovative Properties Company High efficiency synthetic filter medium
US6110251A (en) 1998-11-03 2000-08-29 Johns Manville International, Inc. Gas filtration media and method of making the same
US6420024B1 (en) * 2000-12-21 2002-07-16 3M Innovative Properties Company Charged microfibers, microfibrillated articles and use thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0353907A2 (en) * 1988-08-04 1990-02-07 Minnesota Mining And Manufacturing Company Fibrillated tape and method of making same
US5434002A (en) * 1990-06-04 1995-07-18 Korea Institute Of Science And Technology Non-spun, short, acrylic polymer, fibers
WO1997049326A1 (en) * 1996-06-27 1997-12-31 Minnesota Mining And Manufacturing Company Cleaning article and method of making same
US6110588A (en) * 1999-02-05 2000-08-29 3M Innovative Properties Company Microfibers and method of making
WO2000068301A1 (en) * 1999-05-07 2000-11-16 3M Innovative Properties Company Films having a fibrillated surface and method of making

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US20010031594A1 (en) 2001-10-18
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DE60210935T2 (en) 2006-12-21
JP2004533498A (en) 2004-11-04
DE60210935D1 (en) 2006-06-01
EP1368191A2 (en) 2003-12-10
US7014803B2 (en) 2006-03-21
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WO2002074533A2 (en) 2002-09-26
ATE324256T1 (en) 2006-05-15

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