WO2003005116A3 - Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications - Google Patents

Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications Download PDF

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Publication number
WO2003005116A3
WO2003005116A3 PCT/US2002/020805 US0220805W WO03005116A3 WO 2003005116 A3 WO2003005116 A3 WO 2003005116A3 US 0220805 W US0220805 W US 0220805W WO 03005116 A3 WO03005116 A3 WO 03005116A3
Authority
WO
WIPO (PCT)
Prior art keywords
electric field
molecular system
electronic ink
band gap
visual display
Prior art date
Application number
PCT/US2002/020805
Other languages
French (fr)
Other versions
WO2003005116A2 (en
Inventor
Xiao-An Zhang
R Stanley Williams
Kent D Vincent
Original Assignee
Hewlett Packard Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hewlett Packard Co filed Critical Hewlett Packard Co
Priority to KR10-2004-7000069A priority Critical patent/KR20040013101A/en
Priority to JP2003511031A priority patent/JP2005520180A/en
Priority to EP02742367A priority patent/EP1402313A2/en
Publication of WO2003005116A2 publication Critical patent/WO2003005116A2/en
Publication of WO2003005116A3 publication Critical patent/WO2003005116A3/en

Links

Classifications

    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/0002Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
    • G11C13/0009RRAM elements whose operation depends upon chemical change
    • G11C13/0014RRAM elements whose operation depends upon chemical change comprising cells based on organic memory material
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/165Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field
    • G02F1/166Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect
    • G02F1/167Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on translational movement of particles in a fluid under the influence of an applied field characterised by the electro-optical or magneto-optical effect by electrophoresis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B26/00Optical devices or arrangements for the control of light using movable or deformable optical elements
    • G02B26/02Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the intensity of light
    • G02B26/026Optical devices or arrangements for the control of light using movable or deformable optical elements for controlling the intensity of light based on the rotation of particles under the influence of an external field, e.g. gyricons, twisting ball displays
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/061Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on electro-optical organic material
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/17Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169
    • G02F1/174Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on variable-absorption elements not provided for in groups G02F1/015 - G02F1/169 based on absorption band-shift, e.g. Stark - or Franz-Keldysh effect
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/02Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using elements whose operation depends upon chemical change
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C23/00Digital stores characterised by movement of mechanical parts to effect storage, e.g. using balls; Storage elements therefor
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C13/00Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/04Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using optical elements ; using other beam accessed elements, e.g. electron or ion beam
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C2213/00Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/10Resistive cells; Technology aspects
    • G11C2213/14Use of different molecule structures as storage states, e.g. part of molecule being rotated
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C2213/00Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/70Resistive array aspects
    • G11C2213/77Array wherein the memory element being directly connected to the bit lines and word lines without any access device being used

Abstract

An electric field activated bi-stable molecular system (16, 630) configured within an electric field generated by a pair of electrodes (301, 303 or 301, 305 or 403, 405) is provided for use, e.g., as electronic ink (12) or other visual displays. The molecular system (16, 630) has at least one rotor portion (632) connected to at least one stator portion (634), wherein the rotor portion (632) rotates with respect to the stator portion (634) between at least two different states upon application of the electric field, thereby inducing a band gap change in the molecular system (16, 630), wherein in a first state, there is extended conjugation throughout the major portion of the molecular system (16, 630), resulting in a relatively smaller band gap, and wherein in a second state, the extended conjugation is destroyed, resulting in a relatively larger band gap. A primary advantage of the molecular system (16, 630) is improved contrast. Because the colorant of the present invention is molecular and thus effectively monoplanar, there should be no backside reflection or scattering from the colorant. A second advantage of the present invention is improved resolution. Finally, each molecule (16, 630) of the present invention will latch to stabilize one or the other of its color states.
PCT/US2002/020805 2001-07-03 2002-06-27 Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications WO2003005116A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR10-2004-7000069A KR20040013101A (en) 2001-07-03 2002-06-27 Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications
JP2003511031A JP2005520180A (en) 2001-07-03 2002-06-27 Electric field driven bistable molecular mechanical device for electronic ink and visual display applications
EP02742367A EP1402313A2 (en) 2001-07-03 2002-06-27 Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/898,799 US6947205B2 (en) 2000-12-14 2001-07-03 Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications
US09/898,799 2001-07-03

Publications (2)

Publication Number Publication Date
WO2003005116A2 WO2003005116A2 (en) 2003-01-16
WO2003005116A3 true WO2003005116A3 (en) 2003-10-09

Family

ID=25410049

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/020805 WO2003005116A2 (en) 2001-07-03 2002-06-27 Bistable molecular mechanical devices activated by an electric field for electronic ink and other visual display applications

Country Status (5)

Country Link
US (1) US6947205B2 (en)
EP (1) EP1402313A2 (en)
JP (1) JP2005520180A (en)
KR (1) KR20040013101A (en)
WO (1) WO2003005116A2 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6701035B2 (en) 2000-12-14 2004-03-02 Hewlett-Packard Development Company, L.P. Electric-field actuated chromogenic materials based on molecules with a rotating middle segment for applications in photonic switching
US6995312B2 (en) * 2001-03-29 2006-02-07 Hewlett-Packard Development Company, L.P. Bistable molecular switches and associated methods
US6556470B1 (en) * 2001-07-31 2003-04-29 Hewlett-Packard Company Field addressable rewritable media
US20030071780A1 (en) * 2001-10-16 2003-04-17 Vincent Kent D. High resolution display
US7175961B2 (en) * 2001-10-24 2007-02-13 Hewlett-Packard Development Company, L.P. Photopatternable molecular circuitry
DE10237119B3 (en) * 2002-08-13 2004-04-15 Fujitsu Siemens Computers Gmbh display device
US7113165B2 (en) * 2002-10-25 2006-09-26 Hewlett-Packard Development Company, L.P. Molecular light valve display having sequenced color illumination
US7782408B2 (en) * 2003-07-07 2010-08-24 Hewlett-Packard Development Company, L.P. 3-D molecular assembly and its applications for molecular display and moletronics
JP4752182B2 (en) 2004-03-01 2011-08-17 住友化学株式会社 Insect growth regulator
US6970285B2 (en) 2004-03-02 2005-11-29 Hewlett-Packard Development Company, L.P. Phase change electrophoretic imaging for rewritable applications
US20050274609A1 (en) * 2004-05-18 2005-12-15 Yong Chen Composition of matter which results in electronic switching through intra- or inter- molecular charge transfer, or charge transfer between molecules and electrodes induced by an electrical field
DE102005039524B4 (en) * 2005-08-18 2023-01-19 Bundesdruckerei Gmbh Document with display device with movable display elements
US20070189058A1 (en) * 2006-02-13 2007-08-16 Zhang-Lin Zhou Molecular system and method for reversibly switching the same between four states
US20080094583A1 (en) * 2006-10-19 2008-04-24 Williams R Stanley Non-visible light control of active screen optical properties
KR101329139B1 (en) * 2007-10-12 2013-11-14 삼성전자주식회사 System and method for controling switching display performing transmitive mode /trasflective mode/ reflective mode
JP5668281B2 (en) 2009-09-10 2015-02-12 住友化学株式会社 Microcapsule and manufacturing method thereof
US9281060B1 (en) 2015-06-01 2016-03-08 International Business Machines Corporation Device and method for storing or switching
US11353693B2 (en) * 2017-02-06 2022-06-07 Paul Atkinson Polymorphic electro-optic displays

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5179065A (en) * 1989-04-28 1993-01-12 Sony Corporation Recording material with a display composition including a coloring pigment
WO2002088837A2 (en) * 2001-04-27 2002-11-07 Hewlett-Packard Company Molecular mechanical devices with a band gap change activated by an electric field for optical switching applications

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4166200A (en) * 1975-08-11 1979-08-28 Tektronix, Inc. Compact rotary switch construction
JPS5776607A (en) * 1980-10-30 1982-05-13 Fanuc Ltd Numeric control system
US4827604A (en) * 1987-10-01 1989-05-09 Amp Incorporated Method of making an encoding substrate
US6017584A (en) 1995-07-20 2000-01-25 E Ink Corporation Multi-color electrophoretic displays and materials for making the same
US5982346A (en) 1995-12-15 1999-11-09 Xerox Corporation Fabrication of a twisting ball display having two or more different kinds of balls
US6067185A (en) 1997-08-28 2000-05-23 E Ink Corporation Process for creating an encapsulated electrophoretic display
SE517919C2 (en) * 1998-07-08 2002-08-06 Ecsibeo Ab Liquid crystal device and method for its preparation and use
US6128214A (en) 1999-03-29 2000-10-03 Hewlett-Packard Molecular wire crossbar memory
US6249369B1 (en) * 1999-07-09 2001-06-19 Gentex Corporation Coupled electrochromic compounds with photostable dication oxidation states
US6556470B1 (en) * 2001-07-31 2003-04-29 Hewlett-Packard Company Field addressable rewritable media

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5179065A (en) * 1989-04-28 1993-01-12 Sony Corporation Recording material with a display composition including a coloring pigment
WO2002088837A2 (en) * 2001-04-27 2002-11-07 Hewlett-Packard Company Molecular mechanical devices with a band gap change activated by an electric field for optical switching applications

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
BALZANI V ET AL: "MOLECULAR MACHINES", ACCOUNTS OF CHEMICAL RESEARCH, AMERICAN CHEMICAL SOCIETY. WASHINGTON, US, vol. 31, no. 7, 1998, pages 405 - 414, XP000826304, ISSN: 0001-4842 *
JUST E M ET AL: "PICOSECOND MOLECULAR SWITCH BASED ON THE INFLUENCE OF PHOTOGENERATED ELECTRIC FIELDS ON OPTICAL CHARGE TRANSFER TRANSITIONS", SUPERLATTICES AND MICROSTRUCTURES, ACADEMIC PRESS, LONDON, GB, vol. 28, no. 4, 2000, pages 317 - 328, XP001145935, ISSN: 0749-6036 *
KOLODNER P ET AL: "ELECTRIC-FIELD-INDUCED SCHIFF-BASE DEPROTONATION IN D85N MUTANT BACTERIORHODOPSIN", PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF USA, NATIONAL ACADEMY OF SCIENCE. WASHINGTON, US, vol. 93, October 1996 (1996-10-01), pages 11618 - 11621, XP000980079, ISSN: 0027-8424 *
SINHA H K ET AL: "GROUND- AND EXCITED-STATE DIPOLE MOMENTS OF SOME NITROAROMATICS: EVIDENCE FOR EXTENSIVE CHARGE TRANSFER IN TWISTED NITROBENZENE SYSTEMS", JOURNAL OF CHEMICAL PHYSICS, NEW YORK, NY, US, vol. 93, no. 10, 15 November 1990 (1990-11-15), pages 7085 - 7093, XP008006682, ISSN: 0021-9606 *
SUZUKI: "A new type of tricolor electrochromic system", CHEMICAL COMMUNICATIONS, vol. 20, - 1998, pages 2193 - 2194, XP002244733 *

Also Published As

Publication number Publication date
JP2005520180A (en) 2005-07-07
WO2003005116A2 (en) 2003-01-16
US20020075557A1 (en) 2002-06-20
KR20040013101A (en) 2004-02-11
EP1402313A2 (en) 2004-03-31
US6947205B2 (en) 2005-09-20

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