WO2003005451A1 - Field-effect transistor constituting channel by carbon nano tubes - Google Patents
Field-effect transistor constituting channel by carbon nano tubes Download PDFInfo
- Publication number
- WO2003005451A1 WO2003005451A1 PCT/JP2002/006355 JP0206355W WO03005451A1 WO 2003005451 A1 WO2003005451 A1 WO 2003005451A1 JP 0206355 W JP0206355 W JP 0206355W WO 03005451 A1 WO03005451 A1 WO 03005451A1
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- WIPO (PCT)
- Prior art keywords
- effect transistor
- field
- channel
- carbon nanotube
- transistor according
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
- H10K85/221—Carbon nanotubes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having a potential-jump barrier or a surface barrier
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
- H10K10/464—Lateral top-gate IGFETs comprising only a single gate
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
- H10K85/211—Fullerenes, e.g. C60
Definitions
- the present invention relates to a field effect transistor for controlling or amplifying a digital or analog electric signal of a very high frequency.
- FIG. 6 is a schematic diagram of a cross section of a typical field-effect transistor
- FIG. 7 is a schematic diagram of the top surface.
- 1 is a substrate
- 2 is a channel
- 3 is a source electrode
- 4 is a drain electrode
- 5 is an insulator
- 6 is a gate electrode.
- Channels are generally composed of semiconductors, and there are charged particles in the channel that contribute to electrical conduction. Charged particles are electrons or holes.
- a field-effect transistor is a device that converts a voltage signal input to a gate electrode into a current signal output from a source electrode or a drain electrode.
- a voltage is applied between the source electrode and the drain electrode, the charged particles existing in the channel move between the source electrode and the drain electrode according to the direction of the electric field, and are output as a current signal from the source electrode or the drain electrode.
- the current signal is proportional to the density and velocity of the charged particles in the channel.
- the operating speed of a field-effect transistor is determined by the time that a charged particle travels through a channel. More precisely, the length (gate length) of the portion of the channel in contact with the gate electrode via the insulator is determined by the time that the charged particles travel.
- Source electrode and drain The traveling speed of the charged particles existing in the channel is increased by increasing the voltage between the charged electrode and the electrode. However, the scattering probability increases as the running speed increases, so the speed does not increase beyond a certain level. That value is called the saturation speed.
- Cut-off frequency f T which is an index of the operation speed of a field effect transistor data is the saturation velocity V s of the charged particles, the gate length as l g, given by Bruno 2 ⁇ 1 8.
- the saturation speed may be increased or the gate length may be reduced.
- the gate length is determined by the fine processing technology for the gate electrode, and can be reduced to about ⁇ . ⁇ at present.
- a semiconductor having a high saturation speed may be used as a channel.
- gallium arsenide are often used, its saturation rate is lxl0 7 cm / s. If the gate length is ⁇ . ⁇ ⁇ ⁇ , the cutoff frequency is 160 GHz.
- the present invention provides a channel installed on a substrate, a source electrode connected to the beginning of the channel, a drain electrode connected to the end of the channel, and an insulator installed on the channel.
- a field-effect transistor comprising a gate electrode provided on a channel via an insulator, wherein the channel is formed of carbon nanotubes.
- the carbon nanotube is of a semiconductor type.
- the carbon nanotubes may be either single-walled carbon nanotubes or multi-walled carbon nanotubes.
- the present invention provides a field effect transistor in which a charge donor is added to a channel.
- a field-effect transistor using an alkali metal as a charge donor is provided.
- a field-effect transistor using a halogen molecule is provided.
- the present invention provides a field effect transistor having a carbon nanotube as a channel, wherein a charged particle donor is included in the carbon nanotube.
- a field-effect transistor using a carbon nanotube containing fullerenes as a channel is provided.
- Saturation speed of the carbon nanotubes by the impurity scattering or lattice scattering is suppressed reach the 8xl0 7 cm / s. This is equivalent to eight times that of gallium arsenide.
- a field-effect transistor with a cut-off frequency of more than 1 THz can be obtained by using this material as a channel.
- the diameter of carbon nanotubes is very small, the current that can flow through a single-walled carbon nanotube is limited, up to about 1 ⁇ A. In practice, about 1 mA is required for the current signal of the field effect transistor.
- a field effect transistor that can withstand practical use can be provided by configuring a channel formed by arranging a plurality of carbon nanotubes. The number of arranged carbon nanotubes ranges from 10 to 100,000.
- switching operation is performed with a certain gate voltage (threshold voltage) as a boundary.
- the voltage value is determined by the characteristics of the channel itself and the charged particle donor.
- a charged particle donor can be added to the channel for the purpose of adjusting the threshold voltage.
- the charged particle donor includes an electron donor and an H hole donor.
- Alkali metals such as sodium, potassium, rubidium and cesium have been found to be effective as electron donors.
- halogen atoms or halogen molecules such as chlorine, bromine and iodine have been found to be effective as hole donors.
- molecules also act as charged particle donors, for example, ammonia and nitrogen serve as electron donors, and oxygen molecules serve as hole donors.
- an electron donor When an electron donor is added, it operates as an n-type field-effect transistor, and the threshold voltage can be adjusted in the negative direction by increasing the amount of addition.
- a hole donor when a hole donor is added, it operates as a p-type field effect transistor, and the threshold voltage can be adjusted in the positive direction by increasing the amount of addition.
- the charged particle donor may be outside the carbon nanotube, Nanotubes may be included. When the charged particle donor is included in the carbon nanotube, it is less susceptible to external influences, and stable electrical characteristics can be obtained.
- FIG. 1 is a schematic view of a cross section of a field effect transistor according to a first embodiment of the present invention. .
- FIG. 2 is a schematic diagram of the top surface of the field-effect transistor according to the first embodiment of the present invention.
- FIG. 3 is a schematic diagram of a cross section of a field effect transistor in which an insulating film is provided on a conductive substrate in the first embodiment of the present invention.
- FIG. 4 is a schematic top view of a field-effect transistor according to a second embodiment of the present invention.
- FIG. 5 is a schematic top view of a field-effect transistor according to a third embodiment of the present invention.
- FIG. 6 is a schematic view of a cross section of a conventional field effect transistor.
- FIG. 7 is a schematic diagram of a top surface of a conventional field effect transistor. BEST MODE FOR CARRYING OUT THE INVENTION
- FIG. 1 is a schematic diagram showing a cross-sectional structure of a first embodiment of the field-effect transistor of the present invention.
- FIG. 2 is a schematic diagram of the upper surface of the first embodiment.
- 1 is a substrate
- 2 is a channel
- 3 is a source electrode
- 5 is an insulator
- 6 is a gate electrode.
- the substrate may be an insulating substrate or a semiconductor substrate.
- insulating substrate for example, insulating resin such as silicon oxide, silicon nitride, aluminum oxide, titanium oxide, fluorocarbon, acrylic resin, epoxy resin, polyimide, tetrafluoroethylene resin, or the like may be used.
- semiconductor substrate for example, silicon, germanium, gallium arsenide, indium phosphorus, silicon carbide, or the like may be used. It is desirable that the substrate surface be flat.
- a structure in which an insulating film is formed on a conductive substrate as shown in FIG. 3 may be employed. In this case, the conductive substrate can also function as the second gate electrode.
- a channel is formed by arranging a plurality of carbon nanotubes between a source electrode and a drain electrode.
- the method for synthesizing the carbon nanotube is not limited. For example, it may be synthesized by a laser ablation method, an arc discharge method, or a chemical vapor deposition method.
- the carbon nanotube may be a single-walled carbon nanotube or a multi-walled carbon nanotube.
- the adjacent distance of the carbon nanotubes arranged in the channel may be in the range of 0.3 mn to ⁇ .
- the arrangement direction of the carbon nanotubes is not limited to the horizontal direction. They may be arranged in the vertical direction at the same time.
- Both ends of the carbon nanotube are electrically connected to a source electrode and a drain electrode.
- a method for arranging carbon nanotubes on a substrate there is a method using a self-assembled molecular film.
- One part of the substrate is covered with, for example, an aminopropylethoxysilane molecular film, and the other part is covered with, for example, a hexamethyldisilazane molecular film.
- the former molecular film has the property of being positively charged. Since carbon nanotubes have the property of being positively charged, they are selectively adsorbed to the former molecular film by Coulomb force. Almost no adsorption to the latter molecular film. 'Because the molecular film pattern can be formed by electron beam exposure or optical exposure, the nanotubes can be arranged at any position, and can be similarly arranged.
- the nanotubes As a method of operating carbon nanotubes, there is a method using optical tweezers. This is because micron-sized particles aggregate when light is focused. A method of accumulating carbon nanotubes in a channel using this method may be used. In addition, the nanotubes may be aligned using the property that the nanotubes are easily oriented in the direction of the electric field.
- the source electrode and the drain electrode may be metal.
- gold, silver, platinum, titanium, titanium carbide, tungsten, aluminum / remium, molybdenum, chromium, or the like may be used.
- the source electrode and the drain electrode may be attached to the tip of the carbon nanotube, or may be attached to the side.
- the source electrode and drain electrode are It may be formed before the channel is formed, or may be formed after the channel is formed. In forming the electrodes, a heat treatment in the range of 300 ° C. and 1000 ° C. may be performed for better electrical connection.
- a resist in which carbon nanotubes are diffused may be applied on a substrate, and the resist may be exposed and developed, and an electrode may be attached.
- the gate electrode may be formed directly on the carbon nanotube. However, the gate electrode may be formed via a thin insulating film.
- the insulating film include inorganic materials such as silicon oxide, silicon nitride, silicon oxide aluminum, titanium oxide, and calcium fluoride; polymer materials such as acrylic resin, epoxy resin, polyimide, and tetrafluoroethylene resin; A self-assembled molecular film such as toxicsilane may be used. Since there is no dangling bond on the side of the carbon nanotube, it is chemically inert, and there is flexibility in selecting an insulator.
- a conductor may be used for the gate electrode.
- gold, silver, platinum, titanium, titanium carbide, titanium nitride, tungsten, tungsten silicate, tungsten nitride, aluminum, molybdenum, chromium, polycrystalline silicon, or a combination thereof may be used.
- Carbon nanotubes may be used as the gate electrode. In that case, a very short gate length is obtained.
- the carbon nanotube used may be a single-walled carbon nanotube, a multi-walled carbon nanotube, or a metal-encapsulated carbon nanotube.
- Metallic carbon nanotubes are preferred.
- FIG. 4 is a schematic diagram showing a top surface of a second embodiment of the field-effect transistor of the present invention.
- 1 is a substrate
- 2 is a channel
- 3 is a source electrode
- 4 is a drain electrode
- 5 is an insulator
- 6 is a gate electrode
- 7 is a charged particle donor.
- Charged particle donors donate electrons or holes to carbon nanotubes. This makes it possible to control the density of charged particles present in the carbon nanotube.
- FIG. 5 is a schematic diagram showing the upper surface of a third embodiment of the field-effect transistor of the present invention.
- Charge donor 7 is present inside the carbon nanotube. Fullerenes may be used as the charge donor. For example, C 6. , C70 , C76 , C78 , C82 , C84 , C92, etc. may be used.
- fullerenes chemically modified with osmium complex—fluorine or the like may be used.
- fullerenes may contain other atoms or molecules. For example, La, Er ⁇ Gd, Ho, Nd, Y, S c, S c 2, the S c 3 N may be used ⁇ follicles were hula Len. Both of these fullerenes effectively act as charged particle donors.
- a channel can be formed by a carbon nanotube having a gate length equivalent to that of a conventional III-V compound field-effect transistor and having a very high saturation speed.
- a field effect transistor that controls or amplifies an electric signal or an analog electric signal can be realized.
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02741291A EP1411554A4 (en) | 2001-07-05 | 2002-06-25 | FIELD EFFECT TRANSISTOR COMPRISING A CHANNEL CONSISTING OF CARBON NANOTUBES |
US10/482,713 US20040238887A1 (en) | 2001-07-05 | 2002-06-25 | Field-effect transistor constituting channel by carbon nano tubes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001-204182 | 2001-07-05 | ||
JP2001204182A JP2003017508A (ja) | 2001-07-05 | 2001-07-05 | 電界効果トランジスタ |
Publications (1)
Publication Number | Publication Date |
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WO2003005451A1 true WO2003005451A1 (en) | 2003-01-16 |
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ID=19040687
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2002/006355 WO2003005451A1 (en) | 2001-07-05 | 2002-06-25 | Field-effect transistor constituting channel by carbon nano tubes |
Country Status (5)
Country | Link |
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US (1) | US20040238887A1 (ja) |
EP (1) | EP1411554A4 (ja) |
JP (1) | JP2003017508A (ja) |
CN (1) | CN1332450C (ja) |
WO (1) | WO2003005451A1 (ja) |
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Also Published As
Publication number | Publication date |
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EP1411554A1 (en) | 2004-04-21 |
CN1332450C (zh) | 2007-08-15 |
JP2003017508A (ja) | 2003-01-17 |
EP1411554A4 (en) | 2009-08-05 |
CN1547777A (zh) | 2004-11-17 |
US20040238887A1 (en) | 2004-12-02 |
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