WO2003059616A1 - Recyclable vehicle interior articles and methods of making same - Google Patents

Recyclable vehicle interior articles and methods of making same Download PDF

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Publication number
WO2003059616A1
WO2003059616A1 PCT/US2002/032710 US0232710W WO03059616A1 WO 2003059616 A1 WO2003059616 A1 WO 2003059616A1 US 0232710 W US0232710 W US 0232710W WO 03059616 A1 WO03059616 A1 WO 03059616A1
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WO
WIPO (PCT)
Prior art keywords
component
layer
polypropylene
percent
vehicle interior
Prior art date
Application number
PCT/US2002/032710
Other languages
French (fr)
Inventor
Girma Gebreselassie
Matt Starling
Surendra Khambete
Graham Tompson
Original Assignee
Collins & Aikman Products Co.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US10/041,223 external-priority patent/US6710133B2/en
Application filed by Collins & Aikman Products Co. filed Critical Collins & Aikman Products Co.
Priority to AU2002334996A priority Critical patent/AU2002334996A1/en
Publication of WO2003059616A1 publication Critical patent/WO2003059616A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners

Definitions

  • the present invention relates generally to vehicles and, more particularly, to vehicle interior trim articles.
  • vehicle interior articles such as floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc.
  • vehicle interior articles such as floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc.
  • vehicle interior articles Due to increasing federal environmental regulations and decreasing availability of landfill space, there is increased interest in recycling post-consumer products such as vehicle interior trim panels.
  • many conventional vehicle interior articles are formed from non-recyclable materials such as thermosetting resins, which cannot be re-melted and reused.
  • recyclable vehicle interior articles that have durable, tough surfaces, that are impervious to water and most chemicals, and that are designed to be scratch and mar resistant.
  • recyclable vehicle interior articles that can reduce external noises (e. g. , road noise, engine noise, vibrations, etc.), as well, as noises emanating from within passenger compartments, while also being lightweight and low in cost.
  • vehicle interior articles for use in a variety of interior trim applications (e. g. , floor. coverings, instrument panel, skins, door panel skins, consoles, and pillars, etc.), and methods of producing same, are provided.
  • vehicle interior articles include a top layer of recyclable polymeric material and a backing layer bonded to the top layer in face-to-face relationship.
  • the top layer includes a blend of various recyclable . . polymeric materials and has a thickness of between about 1.6 mm and about 2.0 mm.
  • the top layer includes an interpolymer component, having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component,, a polypropylene component, a limestone component, and barium sulfate component .
  • Various additipnal. components - . including distilled petroleum produces,, zinc stea ⁇ te, ⁇ pigments, and regrind/recycle materials may also be used.
  • vehicle interior articles include a top layer of recyclable polymeric material and a backing layer attached to the top layer in face-to-face relationship.
  • the top layer includes first and second layers of recyclable polymeric material adhered together in face- to-face relationship.
  • the first layer includes a first interpolymer component having a composition of about twenty to forty percent (20% - 40%) ethylene and about " sixty to eighty percent (60% - 80%) .aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component.
  • the second layer includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene copolymer component, a polypropylene component, and a limestone component.
  • the first layer has a thickness of between about 0.75 mm and about 1.0 mm.
  • the second layer has a thickness of between about 1.0 mm and about 1.25 mm.
  • the top layer has a thickness of between . about 1.75 mm and about 2.25 mm.
  • Vehicle interior articles according to embodiments of the present inventio may be used in a . wide variety of vehicle applications including, but not limited to floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc.
  • Vehicle trim panels embodying aspects of the present invention are thinner in cross . section and, thu ....s., .are - l fig trrh -ter in weight than conventional vehicle trim panels.
  • trim
  • X ⁇ • ⁇ • panels according to embodiments of the present invention can achieve various performance characteristics including wear resistance, sound absorption, colorability, etc., that are superior . to conventional vehicle trim panels. Moreover, vehicle trim ' panels, according to embodiments of the present invention are environmentally friendly in that they can be recycled. BRIEF DESCRIPTION OF THE DRAWINGS
  • Fig. 1A is a partial cross-sectional view of a vehicle interior trim panel, according to embodiments of the present invention, that includes a top layer of recyclable polymeric material and a backing layer bonded to the top layer in face-to-face relationship.
  • Fig. IB is. a partial cross-sectional view of the vehicle interior trim, panel of Fig. 1A, wherein.the top layer comprises first and second layers of recyclable polymeric material, according to embodiments of the present invention.
  • Fig. . 2A is a partial cross-sectional view of a vehicle interior trim panel, according to embodiments of the present invention, that includes a top layer of recyclable polymeric material that comprises first and second layers of recyclable polymeric material, a middle layer of recyclable polymeric material, and a backing layer that are bonded together in face-to-face, relationship.
  • Fig. 2B is a partial cross-sectional view of the vehicle interior trim panel of Fig. 2A, wherein the top layer comprises first and second layers of recyclable polymeric material, according to-ambodimenfe*S" of the ' present invention.
  • Figs. 3-6 are schematic diagrams that illustrate methods of producing vehicle interior trim panels according to embodiments of the present invention.
  • Embodiments of the present invention provide sound attenuating composite articles for use in various applications, particularly automotive applications.
  • Exemplary automotive applications within which sound attenuating composite articles according to embodiments t> of the present invention may be utilized include, but are not limited to, carpeting for floors, door panels, and other interior portions, and upholstery for various interior portions, such as headliners, dashboards, etc.
  • the attenuation of external noise is conventionally referred to as sound transmission loss (STL) .
  • the attenuation of internal noise is conventionally referred to as sound absorption.
  • the acoustic impedance of a ⁇ material is defined as material density times acoustic velocity, and is expressed in units of Rayls (Newton- seconds/meter 3 ) .
  • Acoustic impedance defines how easy it is for air to move through a material.
  • acoustic impedance depends upon the density of the fibrous material and fiber diameter. Generally, the heavier the blanket and the finer the fibers, the higher the acoustic impedance. Moreover, thicker layers typically have more acoustic impedance than thin layers.
  • the ability of a material to attenuate noise is conventionally defined by the material's STL, acoustic impedance,, and absorption characteristics.
  • aromatic vinyl monomer is to' be broadly interpreted and includes, for example, aryl and heterocyclic monomers.
  • exemplary aromatic vinyl monomers which may be employed include, for example, styrene and styrene derivatives such as alpha-methyl styrene, p- methyl styrene, vinyl toluene, ethylstyrene, tert-butyl .
  • the aromatic vinyl monomer may be used in an amount, based on total weight of the monomers, preferably from about five to fifty . percent (5% - 50%) by weight, and most. preferably; ⁇ rom ⁇ .about ten to forty percent (10% - 40%) by weight.
  • a particularly preferred aromatic vinyl monomer is styrene .
  • a vehicle interior article 10 includes a top layer 12 of recyclable polymeric material and a backing layer 14 bonded to the top layer 12 in face-to-face .relationship.
  • the top layer 12 and backing layer 14 may be bonded or attached together in various ways, such as via adhesives, heat, extrusion, molding, etc.
  • the interior article 10 may be used in various vehicle interior applications including, but not limited to floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc.
  • the top layer 12 includes a blend of various recyclable polymeric materials and has a thickness of between about 1.6 mm and about 2.0 mm.
  • the top layer includes an interpolymer component having -a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 4.0%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a filler component ( e . g. , limestone and/or barium sulfate) .
  • Various additional components including distilled petroleum products, dispersing agents (e . g. , zinc stearate) , pigments, and regrind/recycle materials may also be used.
  • Preferable material compositions and quantities for the top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 below.
  • An interpolymer used in accordance with embodiments of the. present invention has good filler absorption characteristics.
  • a polypropylene copolymer used in accordance with embodiments of the present invention enhances low temperature performance and allows the top layer 12 to pass various low temperature flexibility requirements.
  • the polypropylene/ethylene copolymer can also improve shrinkage characteristics of the top layer 12 which enhances the ability to b easily thermoformable .
  • a polypropylene according to embodiments of the present invention has a melt index of 12 and works in conjunction with the other polypropylene components to achieve desired hardness and elasticity of the top layer 12.
  • Limestone is used as a low cost filler and barium sulfate is used to increase specific gravity, which enhances sound attenuation characteristics of "the top layer 12. Barium sulfate also increases resistance to tear, elongation, scuff, and abrasion.
  • Other fillers known to. those skilled in the art may be ised.
  • Shellflex 6702 acts as a lubricant in machinery processing the top layer composition and facilitates compounding.
  • Zinc stearate is used to improve filler dispersion and can also increase surface resistance to scuffing.
  • Various polypropylene-based pigments are utilized to produce desired colors. Regrind/recycle material can be used, but is kept separate by color to prevent contamination.
  • the backing layer 14 is a normal filled material.
  • a vehicle interior article 10 includes a top layer of recyclable polymeric material and a backing layer 14 attached to the top layer 12' in face-to-face relationship.
  • the top layer 12' includes first and second layers 16, 18 of recyclable polymeric material adhered together in face-to-face relationship.
  • the interior article 10" may be used in
  • the first layer 16 includes 'a first interpolymer component having a composition of about
  • the first layer 16 has a thickness of between about 0.75 mm and about 1.0 mm.
  • the second layer 18, includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene copolymer component, a polypropylene component, and a limestone component.
  • the second layer 18. has a thickness of between about 1.0 mm. and about 1.25 mm. Accordingly, the top layer 12' has a thickness of between about 1.75 mm and about 2.25 mm.
  • Exemplary material compositions and quantities . for the second layer 18 that can be utilized in accordance with embodiments of the present invention are set forth in Table 3 below.
  • the top layer 12 ' can provide increased cost benefits in materials as well as improving abrasion and scuff performance versus the single top layer construction of Fig. 1A.
  • the material in the first and s.econd layers 16, 18 is fully recyclable and can be colored at a lower cost since the first layer 16 is thin and contains no fillers .
  • the use of a first layer 16 also, allows for the omission barium sulfate from the formula.
  • the backing layer 14 in Figs. 1A-1B may be an open cell material, such as would be known to those . skilled in the art.
  • the backing layer 14 in Figs. 1A-1B may ' be a polypropylene foam sheet.
  • a vehicle interior article 110 includes a top layer 12 of recyclable polymeric material, a middle layer 20 of ' recyclable polymeric material bonded to the "" top layer *" l2 in face-to- face relationship, and a bottom layer 22 of recyclable polymeric material bonded to the middle layer 14 in face- to-face relationship.
  • the top, middle, and bottom layers 12, 20, 22 may be bonded together in various ways, such as via adhesives, heat, extrusion, molding, etc.
  • the top layer 12 includes a blend of various recyclable polymeric materials and has a thickness of between about 1.6 mm and about 2.0 mm.
  • the top layer includes. an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a limestone component, and barium sulfate component.
  • Various additional components including distilled petroleum products, zinc stearate, pigments, and regrind/recycle materials may also be used. Exemplary material compositions and quantities for the .
  • a vehicle interior article 110 ⁇ includes a top layer 12 * of recyclable polymeric material, a middle layer 20 of recyclable polymeric material bonded to the top layer 12 in face-to- face relationship, and a bottom layer 22 of recyclable polymeric material bonded to the middle layer 14 in face- to-face_ relationship.
  • the top, middle, and bottom layers 12', 20, 22 may be bonded together in various ways, such as via adhesives, heat, extrusion, molding, etc.
  • the top layer 12 ' includes first and second layers 16, 18 of recyclable polymeric ' material adhered ' together in face-to-face relationship.
  • the first layer 16 includes a first interpolymer component having a composition of about twenty to forty percent (20% - 40%) ethylene and about- sixty to eighty percent (60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component.
  • the first layer 16, has a thickness of between about 0.75 mm and about 1.0 mm.
  • the second layer 18 includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, and a limestone component.
  • the second layer 18 has a thickness of between about 1.0 mm and about 1.25 mm. Accordingly, the top layer 12" has a thickness of between about 1.75 mm and about 2.25 mm.
  • the middle layer 20 may be .
  • the bottom layer 22 may be a polypropylene filled reinforced substrate.
  • a schematic diagram is provided that illustrates methods of producing a vehicle i ' interior trim panel according to embo ⁇ iments of the present invention.
  • a top layer of recyclable polymeric material having a thickness of between about
  • an interpolymer component having a composition of about sixty to eighty percent (60% -
  • ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer a polypropylene/ethylene copolymer component, a polypropylene component, a filler component ⁇ e.g. , limestone and/or barium sulfate), distilled petroleum products, a dispersion agent, pigments, and regrind/recycle materials may (Block 500) .
  • Exemplary material compositions and quantities for the top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 above.
  • a backing layer is bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 510) .
  • the backing layer may be formed from various materials including, but not limited to, polypropylene foam sheet material, and open cell materials.
  • the bonded top and backing layers are then formed into a desired shape (Block 520) using any of various known techniques, such as compression molding or vacuum forming.
  • a schematic diagram is provided that. illustrates methods of producing. a vehicle . interior trim panel according to other embodiments of the present invention.
  • a top layer of recyclable polymeric material having a thickness of between about 1.6 mm and about 2.0 mm and having the following components is provided: an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer,- a polypropylene/ethylene " ' copolymer component, a polypropylene' component, a filler * ' component (e. g.
  • top layer 12 Exemplary material compositions and quantities for the top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 above.
  • a middle layer of material is bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 610) .
  • the middle layer may be formed from various materials including, but not .limited to, polypropylene foam sheet material, and
  • a reinforced polypropylene substrate is then attached to the backing layer in face-to-face • contacting relationship therewith (Block 620) .
  • the combined top layer, middle layer, and substrate are then formed into a desired shape (Block 630) using any of various known techniques, such as compression molding or vacuum forming.
  • a top layer is formed from first and second layers of- recyclable polymeric material, which are bonded together in face-to-face relationship (Block ' 700) .
  • the first layer of recyclable polymeric • material includes a first interpolymer component having a composition of about twenty to forty percent (20% - 40%) ethylene and about sixty to eighty percent (60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a .
  • the first layer has . a thickness of between about 0.75 mm and about 1.0 mm.
  • Exemplary material compositions and quantities for the first layer that can be utilized in . accordance with embodiments of the present invention are set forth in Table 2 above.
  • the second layer of recyclable polymeric . material includes an interpolymer component having a composition of about sixty to eighty percent (60%- - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene copolymer component, a polypropylene component, and a limestone component.
  • the second layer has a thickness of between " about 1.0 mm and about 1.25 mm. Accordingly,- the top layer has a thickness of between about 1.75 mm and about 2.25 mm. Exemplary material compositions and quantities for the second layer that can be utilized in accordance with embodiments of the present invention are set forth in. Table 3 above.
  • a backing layer is " bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 710) .
  • the backing layer may be- formed from various materials including, but not limited to, polypropylene foam sheet material, and open cell materials.
  • the bonded top and backing layers are then formed into a desired shape (Block 720) using any of various known techniques, such as compression molding or vacuum forming.
  • a top layer is formed from first and second layers of recyclable polymeric material, which are bonded together in face-to-face relationship (Block 800) .
  • the first layer of recyclable polymeric material includes a first interpolymer dop ⁇ nent having " a r composition of about twenty to forty* -percent (20% - 40%)' ethylene and about sixty to eighty percent (.60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component.
  • the first layer has . a thickness of between about 0.75 mm and about 1.0 mm. Exemplary material compositions and quantities for the first layer that can be utilized in accordance with embodiments of the present invention are set- forth in Table 2 above.
  • the second layer ' of recyclable polymeric material includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, and a limestone .component.
  • the second, layer has a thickness, of between about 1.0 mm and about 1.25 mm. Accordingly, the top layer has a thickness of between about 1.75 mm and about 2.25 mm. Exemplary material compositions and quantities for the second layer that can be utilized in accordance with embodiments of the present invention are set forth in Table 3 above .
  • a middle, layer of material is bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 810) .
  • the middle layer may be formed from various materials including, but not limited to, polypropylene foam sheet material, and open cell materials .
  • a reinforced polypropylene substrate is then attached to the- backing layer in face-to-face contacting relationshi therewith (Block 820) .
  • the combined top layer, middle layer-., and substrate are then ' formed into a . desired shape (Block S3. ⁇ ) using any of * various known techniques, such as compression " molding or vacuum forming.
  • the following illustrates a method of producing a vehicle floor covering having a single layer of recyclable material,- according to embodiments of the present invention.
  • the following illustrates a method of producing a vehicle floor covering having two layers of recyclable material, according to embodiments of the present invention.
  • the following illustrates a method of producing a vehicle interior trim panel having two layers of recyclable material , according to embodiments of the present invention .

Abstract

Recyclable vehicle interior trim panels, and methods of producing same, are provided. A vehicle interior trim panel may include a top layer of recyclable polymeric material and a backing layer bonded to the top layer in face-to-face relationship. The top layer includes a blend of various recyclable polymeric materials including an interpolymer component, a polypropylene copolymer component, a polypropylene component, a limestone component, and barium sulfate component, and has a thickness of between about 1.6 mm and about 2.0 mm. The top layer may include first and second layers of recyclable polymeric material adhered together in face-to-face relationship. The first layer includes a first interpolymer component, a second interpolymer component, a polypropylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component. The second layer includes an interpolymer component, a polypropylene copolymer component, a polypropylene component, and a limestone component.

Description

RECYCLABLE VEHICLE INTERIORARTICLES AND METHODS OF MAKING SAME
FIELD OF THE INVENTION
The present invention relates generally to vehicles and, more particularly, to vehicle interior trim articles.
RELATED APPLICATIONS
This application claims the benefit of U.S. Provisional Application No. 60/337,666, filed November 7, 2001, the disclosure of which is incorporated herein by reference in its entirety as if set forth fully herein.
BACKGROUND OF THE INVENTION
It is generally desirable for vehicle interior articles, such as floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc., to have an attractive appearance, to maintain their shape and resist wear over long periods of use, and to provide sound absorption within a vehicle interior. In addition, due to increasing federal environmental regulations and decreasing availability of landfill space, there is increased interest in recycling post-consumer products such as vehicle interior trim panels. Unfortunately, many conventional vehicle interior articles are formed from non-recyclable materials such as thermosetting resins, which cannot be re-melted and reused.
Thus, there is a need for recyclable vehicle interior articles that have durable, tough surfaces, that are impervious to water and most chemicals, and that are designed to be scratch and mar resistant. In addition, there is a need for recyclable vehicle interior articles that can reduce external noises ( e. g. , road noise, engine noise, vibrations, etc.), as well, as noises emanating from within passenger compartments, while also being lightweight and low in cost.
SUMMARY OFTHE INVENTION
In view of the above discussion, recyclable vehicle interior articles for use in a variety of interior trim applications ( e. g. , floor. coverings, instrument panel, skins, door panel skins, consoles, and pillars, etc.), and methods of producing same, are provided. According to embodiments of the present invention, vehicle interior articles include a top layer of recyclable polymeric material and a backing layer bonded to the top layer in face-to-face relationship. The top layer includes a blend of various recyclable . . polymeric materials and has a thickness of between about 1.6 mm and about 2.0 mm. According to an embodiment of the present invention, the top layer includes an interpolymer component, having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component,, a polypropylene component, a limestone component, and barium sulfate component . Various additipnal. components - . including distilled petroleum produces,, zinc steaϊ te, \ pigments, and regrind/recycle materials may also be used. According to other embodiments of the present invention, vehicle interior articles include a top layer of recyclable polymeric material and a backing layer attached to the top layer in face-to-face relationship. The top layer includes first and second layers of recyclable polymeric material adhered together in face- to-face relationship. The first layer includes a first interpolymer component having a composition of about twenty to forty percent (20% - 40%) ethylene and about" sixty to eighty percent (60% - 80%) .aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component. The second layer includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene copolymer component, a polypropylene component, and a limestone component.
The first layer has a thickness of between about 0.75 mm and about 1.0 mm. The second layer has a thickness of between about 1.0 mm and about 1.25 mm. • Accordingly, the top layer has a thickness of between . about 1.75 mm and about 2.25 mm.
Vehicle interior articles according to embodiments of the present inventio may be used in a . wide variety of vehicle applications including, but not limited to floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc. Vehicle trim panels embodying aspects of the present invention are thinner in cross . section and, thu ....s., .are - l fig trrh -ter in weight than conventional vehicle trim panels. In addition, trim,
X Λ • ■ • panels according to embodiments of the present invention can achieve various performance characteristics including wear resistance, sound absorption, colorability, etc., that are superior. to conventional vehicle trim panels. Moreover, vehicle trim' panels, according to embodiments of the present invention are environmentally friendly in that they can be recycled. BRIEF DESCRIPTION OF THE DRAWINGS
The accompanying drawings, which form a part of the specification, illustrate key embodiments of the present invention. The drawings and description together serve to fully explain the invention'.
Fig. 1A is a partial cross-sectional view of a vehicle interior trim panel, according to embodiments of the present invention, that includes a top layer of recyclable polymeric material and a backing layer bonded to the top layer in face-to-face relationship.
Fig. IB is. a partial cross-sectional view of the vehicle interior trim, panel of Fig. 1A, wherein.the top layer comprises first and second layers of recyclable polymeric material, according to embodiments of the present invention.
Fig..2A is a partial cross-sectional view of a vehicle interior trim panel, according to embodiments of the present invention, that includes a top layer of recyclable polymeric material that comprises first and second layers of recyclable polymeric material, a middle layer of recyclable polymeric material, and a backing layer that are bonded together in face-to-face, relationship.
Fig. 2B is a partial cross-sectional view of the vehicle interior trim panel of Fig. 2A, wherein the top layer comprises first and second layers of recyclable polymeric material, according to-ambodimenfe*S" of the ' present invention. X . *•
Figs. 3-6 are schematic diagrams that illustrate methods of producing vehicle interior trim panels according to embodiments of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
The' present invention .now .is described more fully hereinafter with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art.
In the drawings, the thickness of lines, layers and regions may be exaggerated for clarity. It will be understood that when an element such as a layer, region, substrate, or panel is referred to as being "on" another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being "directly on" another element, there are no intervening elements present. It will be understood that when an element is referred to as being "connected" or "attached" to another element, it can be directly connected or attached to the other element or intervening elements may also be present. In contrast, when an element is referred to as being "directly connected" or "directly attached" to another element, there are no intervening elements present.
Embodiments of the present invention provide sound attenuating composite articles for use in various applications, particularly automotive applications. Exemplary automotive applications within which sound attenuating composite articles according to embodiments t> of the present invention may be utilized include, but are not limited to, carpeting for floors, door panels, and other interior portions, and upholstery for various interior portions, such as headliners, dashboards, etc.
As is understood by those skilled in this art, the attenuation of external noise is conventionally referred to as sound transmission loss (STL) . The attenuation of internal noise is conventionally referred to as sound absorption. The acoustic impedance of a ■ material is defined as material density times acoustic velocity, and is expressed in units of Rayls (Newton- seconds/meter3) . Acoustic impedance defines how easy it is for air to move through a material. Thus, for fibrous materials, acoustic impedance depends upon the density of the fibrous material and fiber diameter. Generally, the heavier the blanket and the finer the fibers, the higher the acoustic impedance. Moreover, thicker layers typically have more acoustic impedance than thin layers. The ability of a material to attenuate noise is conventionally defined by the material's STL, acoustic impedance,, and absorption characteristics.
For the 'purposes of the present invention, the term "aromatic vinyl monomer" is to' be broadly interpreted and includes, for example, aryl and heterocyclic monomers. Exemplary aromatic vinyl monomers which may be employed include, for example, styrene and styrene derivatives such as alpha-methyl styrene, p- methyl styrene, vinyl toluene, ethylstyrene, tert-butyl . styrene, monochlorostyrene, dichlorostyrene, vinyl benzyl chloride, vinyl pyridine, fluorostyrene, alkoxystyrenes (e.g., paramethoxystyrene) , and the like, along with blends and mixtures thereof. In addition to the composition range stated herein, the aromatic vinyl monomer may be used in an amount, based on total weight of the monomers, preferably from about five to fifty . percent (5% - 50%) by weight, and most. preferably;^rom ^ .about ten to forty percent (10% - 40%) by weight. A particularly preferred aromatic vinyl monomer is styrene .
Referring initially to Fig. 1A, a vehicle interior article 10, according to embodiments of the present invention, includes a top layer 12 of recyclable polymeric material and a backing layer 14 bonded to the top layer 12 in face-to-face .relationship. The top layer 12 and backing layer 14 may be bonded or attached together in various ways, such as via adhesives, heat, extrusion, molding, etc. The interior article 10 may be used in various vehicle interior applications including, but not limited to floor coverings, instrument panel skins, door panel skins, consoles, and pillars, etc.
The top layer 12 includes a blend of various recyclable polymeric materials and has a thickness of between about 1.6 mm and about 2.0 mm. According to an embodiment of the present invention, the top layer includes an interpolymer component having -a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 4.0%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a filler component ( e . g. , limestone and/or barium sulfate) . Various additional components including distilled petroleum products, dispersing agents ( e . g. , zinc stearate) , pigments, and regrind/recycle materials may also be used. Preferable material compositions and quantities for the top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 below.
Table 1
%
Figure imgf000008_0001
Figure imgf000009_0001
However, different material quantities may be utilized. Embodiments of the present invention are not limited to only the listed ranges of material quantities . An interpolymer used in accordance with embodiments of the. present invention has good filler absorption characteristics. A polypropylene copolymer used in accordance with embodiments of the present invention enhances low temperature performance and allows the top layer 12 to pass various low temperature flexibility requirements. Moreover, the polypropylene/ethylene copolymer can also improve shrinkage characteristics of the top layer 12 which enhances the ability to b easily thermoformable . A polypropylene according to embodiments of the present invention has a melt index of 12 and works in conjunction with the other polypropylene components to achieve desired hardness and elasticity of the top layer 12. Limestone is used as a low cost filler and barium sulfate is used to increase specific gravity, which enhances sound attenuation characteristics of "the top layer 12. Barium sulfate also increases resistance to tear, elongation, scuff, and abrasion. Other fillers known to. those skilled in the art may be ised. A distilled petroleum prodμct, such as ->
- J , 'i
Shellflex 6702, acts as a lubricant in machinery processing the top layer composition and facilitates compounding. Zinc stearate is used to improve filler dispersion and can also increase surface resistance to scuffing. Various polypropylene-based pigments are utilized to produce desired colors. Regrind/recycle material can be used, but is kept separate by color to prevent contamination. The backing layer 14 is a normal filled material.
Referring to Fig. IB, a vehicle interior article 10", according to embodiments of the present invention, includes a top layer of recyclable polymeric material and a backing layer 14 attached to the top layer 12' in face-to-face relationship. The top layer 12' includes first and second layers 16, 18 of recyclable polymeric material adhered together in face-to-face relationship. The interior article 10" may be used in
10 various vehicle interior applications including, but hot limited to floor coverings,, instrument panel skins, door panel skins, consoles, and pillars, etc.
The first layer 16, includes 'a first interpolymer component having a composition of about
15 twenty to forty percent (20% - 40%) ethylene and about sixty to eighty percent (60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%)
20 aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene component, and a silicone component. The first layer 16, has a thickness of between about 0.75 mm and about 1.0 mm.
25 Exemplary material compositions and quantities for the first layer 16 that can be utilized in accordance with embodiments of the present invention are set forth m Table 2 below.
Table 2
30. %
Component Commercial Name/Manufacturer By Weight
Interpolymer: DE 200.01/Dow Chemical 25-30%
70% ethylene and 30% styrene
Interpolymer: DE 201.01/Dow Chemical 25-30%
30% ethylene and 70% styrene
Figure imgf000011_0001
The second layer 18, includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene copolymer component, a polypropylene component, and a limestone component. The second layer 18. has a thickness of between about 1.0 mm. and about 1.25 mm. Accordingly, the top layer 12' has a thickness of between about 1.75 mm and about 2.25 mm.
Exemplary material compositions and quantities . for the second layer 18 that can be utilized in accordance with embodiments of the present invention are set forth in Table 3 below.
Table 3
Figure imgf000011_0002
Figure imgf000012_0001
However, different material quantities may be utilized for the first and second layers 16,' 18. Embodiments of the present invention are not limited to only the listed ranges of material quantities.
Using a two layer construction for' the top layer 12 ' can provide increased cost benefits in materials as well as improving abrasion and scuff performance versus the single top layer construction of Fig. 1A. The material in the first and s.econd layers 16, 18 is fully recyclable and can be colored at a lower cost since the first layer 16 is thin and contains no fillers . The use of a first layer 16 also, allows for the omission barium sulfate from the formula. According -to other embodiments of the present invention, the backing layer 14 in Figs. 1A-1B may be an open cell material, such as would be known to those . skilled in the art. According to other embodiments, the backing layer 14 in Figs. 1A-1B may' be a polypropylene foam sheet.
Referring now to Fig. 2A, a vehicle interior article 110, according to embodiments of the present invention, includes a top layer 12 of recyclable polymeric material, a middle layer 20 of' recyclable polymeric material bonded to the""top layer*"l2 in face-to- face relationship, and a bottom layer 22 of recyclable polymeric material bonded to the middle layer 14 in face- to-face relationship. The top, middle, and bottom layers 12, 20, 22 may be bonded together in various ways, such as via adhesives, heat, extrusion, molding, etc.
The top layer 12 includes a blend of various recyclable polymeric materials and has a thickness of between about 1.6 mm and about 2.0 mm. According to an embodiment of the present invention, the top layer includes. an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a limestone component, and barium sulfate component. Various additional components including distilled petroleum products, zinc stearate, pigments, and regrind/recycle materials may also be used. Exemplary material compositions and quantities for the . top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 above. The middle layer 20 may be a polypropylene foam sheet or an open cell material such as would be known to those skilled in the art. The bottom layer 22 may be a polypropylene filled reinforced substrate. Referring to Fig. 2B, a vehicle interior article 110 , according to embodiments of the present invention, includes a top layer 12 * of recyclable polymeric material, a middle layer 20 of recyclable polymeric material bonded to the top layer 12 in face-to- face relationship, and a bottom layer 22 of recyclable polymeric material bonded to the middle layer 14 in face- to-face_ relationship. The top, middle, and bottom layers 12', 20, 22 may be bonded together in various ways, such as via adhesives, heat, extrusion, molding, etc.
The top layer 12 ' includes first and second layers 16, 18 of recyclable polymeric 'material adhered ' together in face-to-face relationship. The first layer 16 includes a first interpolymer component having a composition of about twenty to forty percent (20% - 40%) ethylene and about- sixty to eighty percent (60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component. The first layer 16, has a thickness of between about 0.75 mm and about 1.0 mm. Exemplary material compositions and quantities for the first layer 16 that can be utilized in accordance with embodiments of the present invention are set forth in Table 2 above. <■ The second layer 18, includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, and a limestone component. The second layer 18 has a thickness of between about 1.0 mm and about 1.25 mm. Accordingly, the top layer 12" has a thickness of between about 1.75 mm and about 2.25 mm. Exemplary material compositions and quantities for the ' second layer 18 that can be utilized in accordance with embodiments of the present invention are set forth in Table 3 above. The middle layer 20 may be. a polypropylene foam sheet or an open cell material such as would be known to those skilled in the art . The bottom layer 22 may be a polypropylene filled reinforced substrate.
Referring now to Fig. 3, a schematic diagram is provided that illustrates methods of producing a vehicle i ' interior trim panel according to emboαiments of the present invention. Initially, a top layer of recyclable polymeric material having a thickness of between about
1.6 mm and about 2.0' mm and, having the following components, is provided: an interpolymer component having a composition of about sixty to eighty percent (60% -
80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a filler component { e.g. , limestone and/or barium sulfate), distilled petroleum products, a dispersion agent, pigments, and regrind/recycle materials may (Block 500) . Exemplary material compositions and quantities for the top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 above.
A backing layer is bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 510) . The backing layer may be formed from various materials including, but not limited to, polypropylene foam sheet material, and open cell materials. The bonded top and backing layers are then formed into a desired shape (Block 520) using any of various known techniques, such as compression molding or vacuum forming.
Referring now to Fig. 4, a schematic diagram is provided that. illustrates methods of producing. a vehicle . interior trim panel according to other embodiments of the present invention. Initially, a top layer of recyclable polymeric material having a thickness of between about 1.6 mm and about 2.0 mm and having the following components is provided: an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer,- a polypropylene/ethylene " ' copolymer component, a polypropylene' component, a filler*' component (e. g. , limestone and/or barium sulfate), distilled petroleum products, a dispersion agent, pigments, and regrind/recycle materials may (Block 600) . Exemplary material compositions and quantities for the top layer 12 that can be utilized in accordance with embodiments of the present invention are set forth in Table 1 above. A middle layer of material is bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 610) . The middle layer may be formed from various materials including, but not .limited to, polypropylene foam sheet material, and
' open cell materials. A reinforced polypropylene substrate is then attached to the backing layer in face-to-face contacting relationship therewith (Block 620) . The combined top layer, middle layer, and substrate are then formed into a desired shape (Block 630) using any of various known techniques, such as compression molding or vacuum forming.
Referring now to Fig. 5, a schematic diagram is provided that illustrates methods of producing a vehicle interior trim panel according to embodiments of the present invention. Initially, a top layer is formed from first and second layers of- recyclable polymeric material, which are bonded together in face-to-face relationship (Block '700) . The first layer of recyclable polymeric material includes a first interpolymer component having a composition of about twenty to forty percent (20% - 40%) ethylene and about sixty to eighty percent (60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a. polypropylene copolymer component, a polypropylene component, a ' ' polyethylene polymer component, and ra silicone component^ The first layer has. a thickness of between about 0.75 mm and about 1.0 mm. Exemplary material compositions and quantities for the first layer that can be utilized in . accordance with embodiments of the present invention are set forth in Table 2 above.
•The second layer of recyclable polymeric . material includes an interpolymer component having a composition of about sixty to eighty percent (60%- - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene copolymer component, a polypropylene component, and a limestone component. The second layer has a thickness of between " about 1.0 mm and about 1.25 mm. Accordingly,- the top layer has a thickness of between about 1.75 mm and about 2.25 mm. Exemplary material compositions and quantities for the second layer that can be utilized in accordance with embodiments of the present invention are set forth in. Table 3 above.
A backing layer is" bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 710) . The backing layer may be- formed from various materials including, but not limited to, polypropylene foam sheet material, and open cell materials. The bonded top and backing layers are then formed into a desired shape (Block 720) using any of various known techniques, such as compression molding or vacuum forming. - Referring now "to Fig. 6, a schematic diagram is . provided that illustrates methods of producing a vehicle interior trim panel- according to other embodiments of the present invention. Initially, a top layer is formed from first and second layers of recyclable polymeric material, which are bonded together in face-to-face relationship (Block 800) . The first layer of recyclable polymeric material includes a first interpolymer dopόnent having" a r composition of about twenty to forty* -percent (20% - 40%)' ethylene and about sixty to eighty percent (.60% - 80%) aromatic vinyl monomer, a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, a polyethylene polymer component, and a silicone component. The first layer has . a thickness of between about 0.75 mm and about 1.0 mm. Exemplary material compositions and quantities for the first layer that can be utilized in accordance with embodiments of the present invention are set- forth in Table 2 above.
The second layer' of recyclable polymeric material includes an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer, a polypropylene/ethylene copolymer component, a polypropylene component, and a limestone .component. The second, layer has a thickness, of between about 1.0 mm and about 1.25 mm. Accordingly, the top layer has a thickness of between about 1.75 mm and about 2.25 mm. Exemplary material compositions and quantities for the second layer that can be utilized in accordance with embodiments of the present invention are set forth in Table 3 above .
A middle, layer of material is bonded to the top layer of recyclable polymeric material in face-to-face contacting relationship therewith (Block 810) . The middle layer may be formed from various materials including, but not limited to, polypropylene foam sheet material, and open cell materials . A reinforced polypropylene substrate is then attached to the- backing layer in face-to-face contacting relationshi therewith (Block 820) . The combined top layer, middle layer-., and substrate are then ' formed into a.desired shape (Block S3.Θ) using any of * various known techniques, such as compression" molding or vacuum forming. EXAMPLE 1
The following illustrates a method of producing a vehicle floor covering having a single layer of recyclable material,- according to embodiments of the present invention.
Figure imgf000019_0001
EXAMPLE 2
The following illustrates a method of producing a vehicle floor covering having two layers of recyclable material, according to embodiments of the present invention.
Figure imgf000020_0001
EXAMPLE 3
The following illustrates a method of producing a vehicle interior trim panel having two layers of recyclable material , according to embodiments of the present invention .
Figure imgf000021_0001
The foregoing is illustrative of the present invention and is not to be construed as limiting thereof . Although a few exemplary embodiments of this invention have been described, those skilled in the' art will readily appreciate that many modifications are possible in the exemplary embodiments without materially departing from the novel teachings and advantages of this invention. Accordingly, all such modifications are intended to be included within the scope of this' invention as defined in.the claims. Therefore, it is to be understood that the foregoing is illustrative of the present invention and is not to be construed as limited to the specific embodiments disclosed, and that modifications to the disclosed embodiments,' as well as other embodiments, are intended to be included within the scope of the appended claims. The invention is defined by the following claims, with equivalents of the claims to be included therein.

Claims

THATWHICH IS CLAIMED IS:
1. A vehicle interior article, comprising a layer of recyclable polymeric material that comprises: an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% -. 40%) aromatic vinyl monomer; a polypropylene/ethylene copolymer component; and a polypropylene -component; wherein the interpolymer component is at least about thirty eight percent (38%) by weight; wherein the polypropylene copolymer component is at least about one percent (1%) by weight; and wherein the polypropylene component is at least about five percent (5%) by weight.
2. The vehicle interior article of Claim 1, wherein the layer of recyclable polymeric material further comprises a filler component .
3. The vehicle interior article of Claim 1, wherein the filler component comprises limestone and barium sulfate components, wherein the limestone component is at least about twenty f-j.ye. percent (25%)
Figure imgf000023_0001
weight; and wherein the barium sulfate component is at least about five percent (5%) by weight.
4. The vehicle interior article of. Claim 1, wherein the layer of recyclable polymeric material has a thickness of between about 1.6 mm and about 2.0 mm.
5. The vehicle interior article of Claim 1, wherein the polypropylene component has a melt index of about 12.
6. The vehicle interior article of Claim 1, further comprising a' backing layer attached to the layer of recyclable polymeric material in face-to-face contacting relationship therewith.
7. The vehicle interior article of Claim 6, wherein the backing layer comprises an open cell material .
8. The vehicle interior article of Claim 1, further comprising a layer of polypropylene foam attached to the layer of recyclable polymeric material in face-to- face contacting relationship therewith.
9. The vehicle interior article of Claim 8, further comprising a reinforced, polypropylene substrate attached to the layer of polypropylene foam in face-to- face contacting relationship therewith.
10. The vehicle interior article of Claim 6, further comprising a reinforced, polypropylene substrate attached to the backing layer in face-to-face contacting' relationship therewith.
11. The vehicle interior article of Claim 1 , wherein the vehicle interior article comprises automotive interior flooring.
12. The vehicle interior article of Claim 1, wherein the vehicle interior article comprises automotive interior trim.
13. A vehicle interior article, comprising: a first layer of recyclable polymeric material that comprises : a first interpolymer component having a composition of about twenty to forty percent
(20% - 40%) ethylene and about sixty to eighty percent. (60% - 80%) aromatic vinyl monomer; a second interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer; a polypropylene/ethylene copolymer componen ; and a polypropylene component; wherein the first interpolymer component is at least about twenty five percent (25%) by weight; wherein the second interpolymer component is at least about twenty four percent (24%) by weight; wherein the polypropylene/ethylene copolymer component is at least about five percent (5%) by weight; and wherein the polypropylene component is at least about twenty percent (20%) by weight; and a second layer of recyclable polymeric material bonded to the first layer in face-to-face relationship therewith, wherein the second layer comprises: a third interpolymer ^component having a composition of about sixty to eighty percent
(60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer; a polypropylene/ethylene copolymer component; and a polypropylene component; wherein the third interpolymer component is at least about twenty five percent (25%) by weight; wherein the polypropylene/ethylene ' copolymer component is at least about one percent (1%) by weight; and wherein the polypropylene component is at least about five percent (5%) by weight.
14. The vehicle interior article of Claim 13, wherein the polypropylene component has a melt index of about 12.
15. The vehicle interior article of Claim 13, wherein the first layer of recyclable polymeric material further comprises a polyethylene polymer component, wherein the polyethylene polymer component is at least . about five percent (5%) by weight.
16. The vehicle interior article of Claim 13, wherein the first layer of recyclable polymeric material further comprises a silicone component, wherein the silicone component is at least about three percent (3%) by weight .
17. The vehicle interior article of Claim 13, wherein the second layer of recyclable polymeric material further comprises a limestone component that is at least about fifty five percent (55%) by weight. rJ 'i ■ ■ *
18. The vehicle interior article of Claim 13, wherein the first layer has a thickness of between about 0.75 mm and about 1.0 mm, and wherein the second layer has a thickness of between about 1.0 mm and about 1.25 mm.
19. The vehicle interior article of. Claim 13, further comprising a backing layer attached to the second layer of recyclable polymeric material in face-to-face contacting relationship therewith.
20. The vehicle • interior article of Claim 19, wherein the backing layer comprises an open cell material .
21. The vehicle interior article of Claim 13, further comprising a layer of polypropylene foam attached to the second layer of recyclable polymeric material in face-to-face contacting relationship therewith.
22. The vehicle interior article of Claim 21, further comprising a reinforced, polypropylene substrate attached to the layer of polypropylene foam in face-to- face contacting relationship therewith.
23. The vehicle interior article of Claim 19, further comprising a reinforced, polypropylene substrate attached to the backing layer in face-to-face contacting relationship therewith.
24. The vehicle interior article of Claim 13, wherein the vehicle interior article comprises automotive . interior flooring.
25. The vehicle interior article of Claim, 13τ , wherein the vehicle interior article, comprises automotive- interior trim.
26. A method of producing a vehicle interior article, comprising: providing a layer of recyclable polymeric material comprising: an interpolymer component having a composition of about sixty to eighty percent (60% - 80%) ethylene and about twenty to forty percent (20%. - 40%) aromatic vinyl monomer; a polypropylene/ethylene copolymer component; and a polypropylene component; wherein the interpolymer component is - at least about thirty eight percent (38%) by weight; wherein the polypropylene/ethylene . copolymer component is at least about one percent (1%) by weight; and
. wherein the polypropylene component is at least about five percent (5%)- by weight; and forming the layer of recyclable material into a desired shape.
27. The method of Claim 26, further comprising providing a layer of recyclable polymeric material comprising a filler component.
28. The method of Claim 27, wherein the filler component comprises limestone and barium sulfate components, wherein the limestone component is at least about twenty five percent (25%) by weight; and wherein the barium sulfate component is at least about five percent (5%) by weight.
29. The method of Claim 2-6, wherein the ^ polypropylene component has a melt index of about 12.
30. The method of Claim 26, wherein the layer of recyclable polymeric material has a thickness of between about 1.6 mm and about 2.0 mm.
31. The method of Claim 26, further comprising attaching a backing layer to the layer of recyclable polymeric material in face-to-face contacting relationship therewith prior to the forming step.
32. . The method of Claim 31, wherein the backing layer comprises an open cell material.
33. The method of .Claim 26, further comprising attaching a layer of polypropylene foam to the layer of recyclable polymeric material in face-to-face contacting relationship therewith prior to the forming step.
34. The method of Claim 33, further comprising attaching a reinforced, polypropylene substrate to the layer of polypropylene foam in face-to-face contacting relationship therewith prior to the forming step.
35. The method of Claim 32, further comprising attaching a reinforced, polypropylene substrate to the backing layer. in face-to-face contacting relationship therewith prior to the forming step.
36. A method of producing a vehicle interior article, comprising: providing a first layer of recyclable polymeric material comprising: a first interpolymer component having a composition of about sixty to (reighty percent - , (60% - 80%) ethylene and about twenty to forty., percent (20% - 40%) aromatic vinyl monomer; a second interpolymer component having a composition of about twenty to forty percent
(20% - 40%) ethylene and about sixty to eighty percent (60% - 80%) aromatic vinyl monomer; a polypropylene/ethylene copolymer component; and a polypropylene component; wherein the first interpolymer component is at least about twenty five percent (25%) by weight; wherein the second interpolymer component is at least about twenty four percent (24%) by weight; wherein the polypropylene/ethylene copolymer component is at least about five percent (5%) by weight; and wherein the polypropylene component is at least about twenty percent (20%) by weight; attaching a second layer of recyclable polymeric material bonded to the first layer in face-to- face relationship therewith, and comprising: a third interpolymer component having a composition of about- sixty to eighty percent -. (60% - 80%) ethylene and about twenty to forty percent (20% - 40%) aromatic vinyl monomer; a polypropylene/ethylene copolymer component; and a polypropylene component; wherein the third interpolymer component is at least about twenty five percent (25%) by weight; " wherein the polypropylene/ethylene copolymer component is at least about one percent (1%) by weight; and wherein the polypropylene component is atx least about five percent (5%) by weight; and • forming the combined first and second layers of recyclable material into a desired shape.
. ..
37. The method of Claim 36, wherein the polypropylene component has a melt index of about 12.
38. The method of Claim 36, wherein the first layer of recyclable polymeric material further comprises a polyethylene polymer component, wherein -the polyethylene polymer component is at least about five percent (5%) by weight.
39. The method of Claim 36, wherein the first layer of recyclable polymeric material further comprises a silicone component, wherein the silicone component is at least about three percent (3%) ,by weight.
40. The method of Claim 36, wherein the second layer of recyclable polymeric material further comprises a limestone component that is at least about fifty five, percent (55%) by weight.
41. The method of Claim 36, wherein the first layer has a thickness of between about 0.75 mm and about 1.0 mm, and wherein the second layer has a thickness of between about 1.0 mm and about 1.25 mm.
.
42. - The method of Claim 36, further comprising attaching a backing layer to the second layer of recyclable polymeric material in face-to-face contacting relationship therewith prior to the forming step.
43. The method of Claim 42, wherein the backing layer comprises an open cell material . '• '
44. The method of Claim 36, further comprising attaching a layer of polypropylene foam to the second layer of recyclable polymeric material in face-to-face contacting relationship therewith prior to the forming step-.
45. The method of Claim 44, further comprising attaching a reinforced, polypropylene substrate to the layer of polypropylene foam in face-to-face contacting relationship therewith prior to the forming step.
46. The method of Claim 42, further comprising attaching a reinforced, polypropylene substrate to the backing layer in face-to-face contacting relationship therewith prior to the forming step.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2142369A1 (en) * 2008-05-05 2010-01-13 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6103803A (en) * 1997-06-26 2000-08-15 The Dow Chemical Company Filled polymer compositions
US6187424B1 (en) * 1997-08-08 2001-02-13 The Dow Chemical Company Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same
US6254956B1 (en) * 1996-09-04 2001-07-03 The Dow Chemical Company Floor, wall or ceiling covering
US6319969B1 (en) * 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6254956B1 (en) * 1996-09-04 2001-07-03 The Dow Chemical Company Floor, wall or ceiling covering
US6103803A (en) * 1997-06-26 2000-08-15 The Dow Chemical Company Filled polymer compositions
US6319969B1 (en) * 1997-06-26 2001-11-20 The Dow Chemical Company Interpolymer compositions for use in sound management
US6187424B1 (en) * 1997-08-08 2001-02-13 The Dow Chemical Company Sheet materials suitable for use as a floor, wall or ceiling covering material, and processes and intermediates for making the same

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2142369A1 (en) * 2008-05-05 2010-01-13 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure
EP2142369A4 (en) * 2008-05-05 2010-10-20 Schulman A Inc Multilayer clear over color polyolefin sheets and layered backing structure
US8007902B2 (en) 2008-05-05 2011-08-30 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure
US20120064317A1 (en) * 2008-05-05 2012-03-15 A. Schulman, Inc. Multilayer Clear Over Color Polyolefin Sheets and Layered Backing Structure
US8182906B2 (en) 2008-05-05 2012-05-22 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure
EP2460640A1 (en) * 2008-05-05 2012-06-06 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure
EP2500169A1 (en) * 2008-05-05 2012-09-19 A. Schulman, Inc. Multilayer structure
EP2851196A1 (en) * 2008-05-05 2015-03-25 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure

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