WO2003061032A2 - Method and apparatus for amplitude limiting battery temperature spikes - Google Patents
Method and apparatus for amplitude limiting battery temperature spikes Download PDFInfo
- Publication number
- WO2003061032A2 WO2003061032A2 PCT/US2003/000565 US0300565W WO03061032A2 WO 2003061032 A2 WO2003061032 A2 WO 2003061032A2 US 0300565 W US0300565 W US 0300565W WO 03061032 A2 WO03061032 A2 WO 03061032A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- battery
- case
- heat absorber
- wall
- temperature
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/658—Means for temperature control structurally associated with the cells by thermal insulation or shielding
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/61—Types of temperature control
- H01M10/613—Cooling or keeping cold
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/62—Heating or cooling; Temperature control specially adapted for specific applications
- H01M10/623—Portable devices, e.g. mobile telephones, cameras or pacemakers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/64—Heating or cooling; Temperature control characterised by the shape of the cells
- H01M10/647—Prismatic or flat cells, e.g. pouch cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/659—Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2200/00—Safety devices for primary or secondary batteries
- H01M2200/10—Temperature sensitive devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- TITLE METHOD AND APPARATUS FOR AMPLITUDE LIMITING BATTERY
- This invention relates generally to energy storage devices, e.g., rechargeable batteries, and especially to such devices suitable for medical implantation in a patient's body. More particularly, this invention relates to a method and apparatus for limiting the amplitude of temperature spikes produced by such energy storage devices as a result of a malfunction such as an electric short.
- a rechargeable lithium ion battery can produce a temperature excursion of 120°C or more. A temperature of this amplitude can cause significant damage to body tissue.
- the present invention is directed to a method and apparatus for containing heat generated by an energy storage device (hereinafter generically referred to as a "battery”) to reduce the amplitude of a temperature excursion in order to enhance safety in temperature critical applications, such as in implantable medical devices.
- an energy storage device hereinafter generically referred to as a "battery”
- a heat absorber is closely thermally coupled to the battery.
- the heat absorber is comprised of high heat capacity heat absorbing (HA) material which allows the rapid transference of considerable heat energy from the battery to the absorber, thereby reducing the temperature excursion and the risk of body tissue damage.
- HA heat capacity heat absorbing
- the HA material is selected to exhibit an endothennic phase change at a temperature Tl within a range of about 50°C to 80°C. Temperatures in excess of this range can be readily produced by an electrically shorted battery.
- a preferred HA material in accordance with the invention includes paraffin and is selected to have a melting point of about 75°C.
- the battery is comprised of a case formed of a conductive biocompatible material such as titanium or stainless steel.
- the case is mounted in a medical device housing also formed of a conductive biocompatible material such as titanium or stainless steel.
- the case is preferably mounted such that its wall surface is spaced from the housing wall surface to minimize heat transference therebetween.
- a heat absorber in accordance with the present invention is preferably mounted between the case wall and housing wall to absorb heat energy and reduce the rate of heat transference to the housing wall.
- the heat absorber preferably comprises a mass of meltable material, e.g., paraffin, deposited into a fibrous containment mat preferably formed of dielectric fibers, e.g., Kevlar or fiberglass.
- the heat absorber can be fabricated by depositing melted HA material onto the mat and then allowing it to solidify, e.g., at room temperature. The heat absorber can then be attached to the battery case prior to mounting the case in the medical device housing.
- a heat absorber in accordance with the invention can be provided in multiple configurations. As already mentioned, the heat absorber can be physically configured to engage the case wall outer surface of a standard battery. Alternatively, a battery can be especially configured to include the HA material within the battery case.
- the HA material can be formed as one or more strips (or plates) such that they can be integrated in a stack of positive electrode, negative electrode, and separator strips (or plates) forming an electrode assembly roll (or stack) . Alternatively and/or additionally, the HA material can be configured to extend around the electrode assembly within the battery case.
- Figure 1 is an isometric view of an exemplary implantable medical device
- FIG 2 is an isometric view of the medical device of Figure 1 with the cover removed to reveal a battery therein carrying a heat absorber in accordance with the present invention
- Figure 3 is a plan view of the device of Figure 2 showing the heat absorber mounted on the battery case;
- Figure 4 is an enlarged view taken substantially along the plane 4-4 of Figure 3 showing a preferred heat absorber directly attached to the battery case where the heat absorber comprises a quantity of heat absorbing material surrounding an embedded fibrous containment mat;
- Figure 5 is an isometric view depicting an alternative manner of thermally coupling the heat absorber to the battery case comprising a caddy configured to carry the absorber and having clips for attaching it to the battery case;
- Figure 6 is a chart depicting respective exemplary temperature excursions produced by a shorted battery (1) without a heat absorber and (2) with a heat absorber in accordance with the present invention
- Figure 7 is a schematic cross section of a typical battery showing a wound, or jellyroll, electrode assembly within the battery case;
- Figure 8 is a cross section taken substantially along the plane 8-8 of Figure 7, showing multiple layers of the electrode assembly
- Figure 9 is a schematic isometric view showing a wound electrode assembly incorporating layers of heat absorbing (HA) material in accordance with the present invention
- Figure 10 is a cross section taken through the electrode assembly of Figure 9 showing HA material layers incorporated in the electrode assembly
- Figure 11 is an elevation view of an electrode substrate in accordance with an alternative embodiment of the invention showing HA material deposited into recesses or pockets of the substrate;
- HA heat absorbing
- Figure 12 is a schematic cross section, similar to Figure 7, showing how HA material can be utilized within the interior volume of the battery case;
- Figure 13 is a schematic cross section, similar to Figure 12, showing how HA material can alternatively, or additionally, be deployed around the case exterior wall surface;
- Figure 14 is a schematic cross section depicting multiple batteries accommodated in a large casing.
- FIG. 1 illustrates an exemplary implantable medical device 20.
- the device 20 is comprised of a device housing 22 including a lower mounting member 24 and an upper cover member 26.
- the housing members 24 and 26 mate together to enclose an interior volume for accommodating electronic circuitry and a power source, e.g., an energy storage device such as a rechargeable lithium ion battery.
- a power source e.g., an energy storage device such as a rechargeable lithium ion battery.
- the te ⁇ n "battery” will generally be used hereinafter to generically refer to any type of energy storage device.
- FIGS 2 and 3 illustrate the device housing 22 with the cover member 26 removed to show the interior volume 28 for accommodating a battery 30 for driving electronic circuitry (not shown) also accommodated in the interior volume 28.
- Mounting member 24 is formed by a wall of suitable biocompatible material, e.g., titanium or stainless steel, shaped to essentially form a cup comprised of a floor portion 31 and a peripheral wall portion 32.
- the mounting member 24 forms a partial boundary of interior volume 28.
- the remainder of the boundary is defined by the lid portion 33 and peripheral wall portion 34 of the cover member 26 which is typically formed of the same biocompatible material.
- the respective peripheral wall portions 32 and 34 are configured to mate to enable the device housing 22 to be hermetically sealed.
- a rechargeable battery can produce a very high temperature excursion up to 120°C or more (see Figure 6). Temperature excursions of this amplitude can cause significant damage in temperature critical applications such as implanted medical devices.
- the present invention is primarily directed to providing a method and apparatus for limiting the amplitude of temperature spikes produced by battery 30 to avoid temperature induced damage. In accordance with the invention, temperature excursions are limited by utilizing a heat absorber thermally coupled to the battery 30 to extract heat therefrom.
- the battery 30 is comprised of a case 36 formed by a case wall defining an interior volume for accommodating an electrode assembly and electrolyte.
- the case wall is typically formed of a substantially rigid metal material such as titanium or stainless steel but can be formed of other materials, e.g., a flexible polymer.
- a heat absorber 38 in accordance with the invention is directly mounted on the exterior surface 39 of case 36 for absorbing heat energy generated by the battery 30.
- the heat absorber 38 in accordance with the present invention is preferably comprised of a high heat capacity heat absorbing (HA) material 40 which allows the rapid transference of heat energy from the battery to the absorber.
- HA material is selected to exhibit an endothermic phase change, i.e., melt, at a temperature Tl below the temperature which is produced by an electrically shorted battery.
- an electrically shorted battery can exhibit a temperature excursion of 120°C or more and the HA material is preferably selected to exhibit a phase change at a temperature Tl within a range of about 50°C to 80°C.
- a preferred HA material 40 in accordance with the invention includes paraffin and is selected to have a melting point of about 75°C.
- a preferred heat absorber 38 in accordance with the invention is comprised of a mat 42 formed of fibrous material, preferably having dielectric properties such as Kevlar or fiberglass.
- the fibrous mat 42 is utilized to contain and provide a form to the HA material mass 40. More particularly, the preferred heat absorber 38 is formed by depositing melted HA material 40 onto the fibrous mat 42 so that the material surrounds and embeds the mat. The HA material is then allowed to cure so that the absorber 38 comprised of mat 42 and HA material mass 40 forms a solid having an upper surface 43 and lower surface 44. The lower surface 44 can be adhered directly to the battery case surface 39 as shown in Figure 4.
- Figure 5 depicts a caddy 50 configured to (1) carry the absorber 38 and (2) clip to the battery case 36. More particularly, the caddy 50 includes a frame 52 enclosing an open area 54 for accommodating the heat absorber 38. The frame 52 has depending resilient clips 56 secured thereto. The clips 56 are dimensioned and shaped to clip around the battery case 36 to mount the heat absorber 38 immediately adjacent to the battery case surface 39.
- the battery case 36 should preferably be spaced from the floor portion 31 of the housing mounting member 24, e.g., by dielectric spacers 60, to reduce heat conduction to the housing 22.
- FIG. 6 depicts a typical temperature excursion 70 which can be produced by a battery in response to an electric short, either internal or external, in the absence of a heat absorber in accordance with the present invention.
- Plots 72and 74 depict reduced temperature excursions attributable to the use of different amounts of HA material in accordance with the invention closely thermally coupled to the battery case 36.
- the amount of heat energy Q which can be absorbed by the heat absorber 38 is of course dependent on the quantity and characteristics of the HA material used. This relationship can be expressed as:
- T F represents final temperature
- Cp represents the heat capacity of the HA material mass
- ⁇ H f represents the heat of fusion
- the following table depicts properties of a preferred HA material, paraffin, as compared to other materials typically used in a battery. Also shown are properties of alternative, but less effective HA materials polypropylene and polyethylene. Still other alternative HA materials can be used; e.g., Aerogel (SiO 2 ).
- Figures 7 and 8 depict an exemplary battery 30 having a case 36 containing an electrode assembly 76.
- the electrode assembly 76 comprises multiple layers of positive electrode sheets 77, negative electrode sheets 78, and separator sheets 79. These sheets can be stacked or wound into what is sometimes referred to as a "jellyroll".
- Figure 8 depicts a cross-section through the electrode assembly 76 of Figure 7 showing exemplary stacked layers which are arranged pos/sep/neg/sep/pos/sep/neg.... That is, adjacent positive and negative electrode layers are separated by a separator layer.
- a suitable electrolyte (not shown) is contained within the battery case 36 around the electrode assembly 76.
- Figures 9 and 10 depict an arrangement for incorporating heat absorber material within the battery case of Figure 7. That is, Figure 9 shows multiple strips of an electrode assembly 80 including a positive electrode strip 82, a separator strip 84, a negative electrode strip 86, and a separator strip 88.
- layers of heat absorbing (HA) material 90 are additionally incorporated in the stacked layers, e.g., by attachment to both faces of the separator strips.
- the layers of the electrode assembly 80 comprise in sequence pos/HA/sep/HA/neg/HA/sep/HA/pos/....
- the layers 90 of HA material can be formed in various ways.
- the HA material 90 can constitute a separator strip provided with a matrix of pockets 92 into which HA material 93 is deposited.
- Figure 12 illustrates a still further alternative for incorporating HA material into a battery case 94.
- heat absorber material 96 is mounted in the battery case 94, at time of manufacture, around the electrode assembly 98.
- the heat absorber material 96 is preferably configured around a mat in the manner discussed in connection with Figure 4. That is, heat absorber material is deposited into a fibrous mat (not shown) so as to embed the mat.
- the resulting structure of HA material and fibrous mat forms a solid which can be easily mounted in the battery case 94 closely thermally coupled to the electrode assembly 98.
- Figure 13 illustrates a still further arrangement for using HA material 100 to limit temperature excursions of battery 102.
- the heat absorber material 100 is mounted around the exterior surface of case 104 which contains the electrode assembly 106.
- the heat absorber material 100 is preferably formed as previously described by depositing melted HA material onto a fibrous mat which contains and provides structure for the HA material.
- An outer casing 108 formed, for example, of flexible polymer material can be provided to better contain the HA material 100.
- Figure 14 depicts a configuration 110 in which an outer casing 112 contains HA material 114 surrounding a plurality of batteries 116A, 116B, 116C.
- an electric short across one of the batteries will produce a temperature spike which can be contained by the HA material 114, thereby preventing damage to the other batteries as well as surrounding body tissue.
- FIG. 9-14 all utilize a heat absorber in combination with one or more batteries to limit temperature excursions as depicted in Figure 6. That is, the heat absorber material functions to limit the amplitude of temperature spikes and as a consequence reduces the risk of temperature-induced damage.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003205063A AU2003205063A1 (en) | 2002-01-09 | 2003-01-08 | Method and apparatus for amplitude limiting battery temperature spikes |
US10/500,907 US7443136B2 (en) | 2002-01-09 | 2003-01-08 | Method and device employing heat absorber for limiting battery temperature spikes |
US10/357,671 US6891353B2 (en) | 2001-11-07 | 2003-02-03 | Safety method, device and system for an energy storage device |
US10/935,869 US7592776B2 (en) | 2001-11-07 | 2004-09-08 | Energy storage device configured to discharge energy in response to unsafe conditions |
US12/290,231 US7893659B2 (en) | 2002-01-09 | 2008-10-27 | Method and apparatus for amplitude limiting battery temperature spikes |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/042,898 | 2002-01-09 | ||
US10/042,898 US6586912B1 (en) | 2002-01-09 | 2002-01-09 | Method and apparatus for amplitude limiting battery temperature spikes |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/042,898 Continuation-In-Part US6586912B1 (en) | 2001-11-07 | 2002-01-09 | Method and apparatus for amplitude limiting battery temperature spikes |
Related Child Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10500907 A-371-Of-International | 2003-01-08 | ||
US10/357,671 Continuation-In-Part US6891353B2 (en) | 2001-11-07 | 2003-02-03 | Safety method, device and system for an energy storage device |
US10/935,869 Continuation-In-Part US7592776B2 (en) | 2001-11-07 | 2004-09-08 | Energy storage device configured to discharge energy in response to unsafe conditions |
US12/290,231 Continuation US7893659B2 (en) | 2002-01-09 | 2008-10-27 | Method and apparatus for amplitude limiting battery temperature spikes |
Publications (2)
Publication Number | Publication Date |
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WO2003061032A2 true WO2003061032A2 (en) | 2003-07-24 |
WO2003061032A3 WO2003061032A3 (en) | 2003-09-25 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US2003/000565 WO2003061032A2 (en) | 2001-11-07 | 2003-01-08 | Method and apparatus for amplitude limiting battery temperature spikes |
Country Status (3)
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US (1) | US6586912B1 (en) |
AU (1) | AU2003205063A1 (en) |
WO (1) | WO2003061032A2 (en) |
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US7592776B2 (en) | 2001-11-07 | 2009-09-22 | Quallion Llc | Energy storage device configured to discharge energy in response to unsafe conditions |
US7893659B2 (en) | 2002-01-09 | 2011-02-22 | Quallion Llc | Method and apparatus for amplitude limiting battery temperature spikes |
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US6891353B2 (en) * | 2001-11-07 | 2005-05-10 | Quallion Llc | Safety method, device and system for an energy storage device |
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US7003356B2 (en) | 2002-03-08 | 2006-02-21 | Quallion Llc | Battery terminal sealing and supporting device and method |
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- 2003-01-08 WO PCT/US2003/000565 patent/WO2003061032A2/en not_active Application Discontinuation
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US7592776B2 (en) | 2001-11-07 | 2009-09-22 | Quallion Llc | Energy storage device configured to discharge energy in response to unsafe conditions |
US7893659B2 (en) | 2002-01-09 | 2011-02-22 | Quallion Llc | Method and apparatus for amplitude limiting battery temperature spikes |
US7528572B2 (en) | 2004-03-10 | 2009-05-05 | Quallion Llc | Power system for managing power from multiple power sources |
US9192772B1 (en) | 2004-06-29 | 2015-11-24 | Quallion Llc | Portable medical power system |
US7931979B2 (en) | 2004-08-06 | 2011-04-26 | Lg Chem, Ltd. | Battery system containing phase change material-containing capsules in interior configuration thereof |
US8758925B2 (en) | 2004-08-06 | 2014-06-24 | Lg Chem, Ltd. | Battery system containing phase change material-containing capsules in interior configuration thereof |
WO2009057266A1 (en) * | 2007-10-29 | 2009-05-07 | Panasonic Corporation | Battery pack, and battery-mounting device |
Also Published As
Publication number | Publication date |
---|---|
WO2003061032A3 (en) | 2003-09-25 |
AU2003205063A1 (en) | 2003-07-30 |
US6586912B1 (en) | 2003-07-01 |
AU2003205063A8 (en) | 2003-07-30 |
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