WO2003066739A1 - Polymer modified bitumen compositions - Google Patents
Polymer modified bitumen compositions Download PDFInfo
- Publication number
- WO2003066739A1 WO2003066739A1 PCT/NL2003/000097 NL0300097W WO03066739A1 WO 2003066739 A1 WO2003066739 A1 WO 2003066739A1 NL 0300097 W NL0300097 W NL 0300097W WO 03066739 A1 WO03066739 A1 WO 03066739A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- block
- percent
- bitumen
- copolymer
- bituminous composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 89
- 239000010426 asphalt Substances 0.000 title claims abstract description 73
- 229920000642 polymer Polymers 0.000 title claims abstract description 69
- 229920001400 block copolymer Polymers 0.000 claims abstract description 62
- 238000009826 distribution Methods 0.000 claims abstract description 52
- 150000001993 dienes Chemical class 0.000 claims abstract description 35
- 229920001577 copolymer Polymers 0.000 claims abstract description 27
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 230000001070 adhesive effect Effects 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 7
- 239000012528 membrane Substances 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 42
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 30
- 230000035515 penetration Effects 0.000 claims description 15
- 238000009472 formulation Methods 0.000 claims description 12
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 8
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 7
- 229920001519 homopolymer Polymers 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 5
- 238000004078 waterproofing Methods 0.000 claims description 5
- 125000002897 diene group Chemical group 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 abstract description 17
- 230000032683 aging Effects 0.000 abstract description 12
- 239000000178 monomer Substances 0.000 abstract description 12
- -1 polyethylene Polymers 0.000 description 30
- 238000000034 method Methods 0.000 description 18
- 238000006116 polymerization reaction Methods 0.000 description 16
- 230000006872 improvement Effects 0.000 description 15
- 238000005984 hydrogenation reaction Methods 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 238000013459 approach Methods 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 239000000945 filler Substances 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 229920000428 triblock copolymer Polymers 0.000 description 4
- 238000011925 1,2-addition Methods 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 3
- 239000012615 aggregate Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000008878 coupling Effects 0.000 description 3
- 238000010168 coupling process Methods 0.000 description 3
- 238000005859 coupling reaction Methods 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000006028 limestone Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- 241001120493 Arene Species 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
- 238000007868 post-polymerization treatment Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- PRJNEUBECVAVAG-UHFFFAOYSA-N 1,3-bis(ethenyl)benzene Chemical compound C=CC1=CC=CC(C=C)=C1 PRJNEUBECVAVAG-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920003046 tetrablock copolymer Polymers 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D153/02—Vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D153/02—Vinyl aromatic monomers and conjugated dienes
- C09D153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
- C09J153/025—Vinyl aromatic monomers and conjugated dienes modified
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03707249A EP1474482A1 (en) | 2002-02-07 | 2003-02-07 | Polymer modified bitumen compositions |
AU2003208666A AU2003208666A1 (en) | 2002-02-07 | 2003-02-07 | Polymer modified bitumen compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35521002P | 2002-02-07 | 2002-02-07 | |
US60/355,210 | 2002-02-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003066739A1 true WO2003066739A1 (en) | 2003-08-14 |
Family
ID=27734482
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NL2003/000099 WO2003066738A1 (en) | 2002-02-07 | 2003-02-07 | Gels from controlled distribution block copolymers |
PCT/NL2003/000095 WO2003066770A1 (en) | 2002-02-07 | 2003-02-07 | Adhesives from controlled distribution block copolymers |
PCT/NL2003/000097 WO2003066739A1 (en) | 2002-02-07 | 2003-02-07 | Polymer modified bitumen compositions |
PCT/NL2003/000093 WO2003066696A1 (en) | 2002-02-07 | 2003-02-07 | Novel block copolymers and method for making same |
Family Applications Before (2)
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Families Citing this family (213)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7226484B2 (en) * | 1994-04-19 | 2007-06-05 | Applied Elastomerics, Inc. | Tear resistant gels and articles for every uses |
US7179860B2 (en) * | 2001-03-13 | 2007-02-20 | Liwei Cao | Crosslinked polymer electrolyte membranes for heat, ion and moisture exchange devices |
US7012118B2 (en) * | 2002-02-07 | 2006-03-14 | Kraton Polymers U.S. Llc | Photopolymerizable compositions and flexographic plates prepared from controlled distribution block copolymers |
US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US6987142B2 (en) | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
WO2003091303A1 (en) * | 2002-04-25 | 2003-11-06 | Asahi Kasei Chemicals Corporation | Block copolymer and composition thereof |
EP1431348A1 (en) * | 2002-12-16 | 2004-06-23 | KRATON Polymers Research B.V. | Block copolymer modified bitumen felts |
US20060178485A1 (en) * | 2003-03-14 | 2006-08-10 | Jsr Corporation | Hydrogenated diene copolymer, polymer composition, and molded object |
US7795347B2 (en) * | 2003-03-14 | 2010-09-14 | Mitsui Chemicals, Inc. | Multi-branched polymer, process for producing the same, and applications thereof |
US7517932B2 (en) * | 2003-03-24 | 2009-04-14 | Kraton Polymers U.S. Llc | Poly(styrene-butadiene-styrene)polymers having a high vinyl content in the butadiene block and hot melt adhesive composition comprising said polymers |
JP2006525398A (en) * | 2003-05-01 | 2006-11-09 | クレイトン・ポリマーズ・リサーチ・ベー・ベー | Colorable composition |
EP1645588B1 (en) * | 2003-07-15 | 2013-07-10 | Denki Kagaku Kogyo Kabushiki Kaisha | Heat-shrinkable foam films |
JP2007506842A (en) * | 2003-09-23 | 2007-03-22 | デイス−アナリティック コーポレーション | NOVEL BLOCK COPOLYMER AND METHOD FOR PRODUCING THE SAME |
JP4776155B2 (en) * | 2003-10-21 | 2011-09-21 | 旭化成ケミカルズ株式会社 | Hydrogenated copolymer |
US7037980B2 (en) * | 2003-11-10 | 2006-05-02 | Chevron Phillips Chemical Company, Lp | Monovinylarene/conjugated diene copolymers having lower glass transition temperatures |
US20050119403A1 (en) * | 2003-12-01 | 2005-06-02 | St. Clair David J. | Solvent based, elastomeric coatings with lower VOC |
DE602004005568T2 (en) * | 2004-02-19 | 2007-08-09 | Kraton Polymers Research B.V. | Colored felt products as a roof cover |
CN1946798A (en) * | 2004-03-03 | 2007-04-11 | 克拉通聚合物研究有限公司 | Polymeric compositions containing block copolymers having high flow and high elasticity |
US7582692B2 (en) * | 2004-04-01 | 2009-09-01 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic composition and articles comprising the same |
US7799854B2 (en) | 2004-04-01 | 2010-09-21 | Sabic Innovative Plastics Ip B.V. | Flame retardant thermoplastic composition and articles comprising the same |
US7417083B2 (en) | 2004-04-01 | 2008-08-26 | Sabic Innovative Plastics Ip B.V. | Flame retardant composition |
US7348076B2 (en) | 2004-04-08 | 2008-03-25 | Saint-Gobain Ceramics & Plastics, Inc. | Single crystals and methods for fabricating same |
US7717893B2 (en) | 2004-06-04 | 2010-05-18 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery elastomer |
US7905872B2 (en) | 2004-06-04 | 2011-03-15 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate |
CA2575574A1 (en) * | 2004-08-05 | 2006-02-16 | Firestone Polymers, Llc | Functional multi-block polymer |
FR2876141B1 (en) * | 2004-10-06 | 2006-12-08 | Sandvik Tamrock Secoma Sas Soc | ROTOPERCUSSION FORTIFICATION DEVICE |
US20060115613A1 (en) * | 2004-12-01 | 2006-06-01 | Cryovac, Inc. | Patch bag and barrier bag |
US7473473B2 (en) * | 2004-12-01 | 2009-01-06 | Cryovac, Inc. | Tear resistant shrink film |
US20060135695A1 (en) * | 2004-12-17 | 2006-06-22 | Hua Guo | Flexible poly(arylene ether) composition and articles thereof |
US7776441B2 (en) * | 2004-12-17 | 2010-08-17 | Sabic Innovative Plastics Ip B.V. | Flexible poly(arylene ether) composition and articles thereof |
US8419701B2 (en) | 2005-01-10 | 2013-04-16 | The Procter & Gamble Company | Absorbent articles with stretch zones comprising slow recovery elastic materials |
JP4611390B2 (en) | 2005-01-26 | 2011-01-12 | ザ プロクター アンド ギャンブル カンパニー | Disposable pull-on diaper with elastic waist that has low resistance and recovers slowly |
US7772322B2 (en) * | 2005-02-17 | 2010-08-10 | Sabic Innovative Plastics Ip B.V. | Poly(arylene ether) composition and articles |
US7531209B2 (en) * | 2005-02-24 | 2009-05-12 | Michael Raymond Ayers | Porous films and bodies with enhanced mechanical strength |
US20060205904A1 (en) * | 2005-03-11 | 2006-09-14 | St Clair David J | Oil gels of controlled distribution block copolymers and ester oils |
EP1858974B1 (en) | 2005-03-11 | 2012-08-22 | KRATON Polymers Research B.V. | Oil gels of controlled distribution block copolymers and ester oils |
EP1707596A1 (en) * | 2005-03-14 | 2006-10-04 | Kraton Polymers Research B.V. | Hydrogenated block copolymer composition for overmoulding onto thermoplastics |
US20060251890A1 (en) * | 2005-05-06 | 2006-11-09 | Richard Lane | Pressure sensitive adhesive (PSA) laminates |
US20060263596A1 (en) * | 2005-05-06 | 2006-11-23 | Bamborough Derek W | Pressure sensitive adhesives (PSA) laminates |
TWI326691B (en) * | 2005-07-22 | 2010-07-01 | Kraton Polymers Res Bv | Sulfonated block copolymers, method for making same, and various uses for such block copolymers |
US20070026251A1 (en) * | 2005-07-26 | 2007-02-01 | Kraton Polymers U.S. Llc | Flexible packaging laminate films including a block copolymer layer |
US20070055015A1 (en) * | 2005-09-02 | 2007-03-08 | Kraton Polymers U.S. Llc | Elastomeric fibers comprising controlled distribution block copolymers |
US20070066753A1 (en) * | 2005-09-16 | 2007-03-22 | Ehrlich Martin L | Highly processible compounds of high MW conventional block copolymers and controlled distribution block copolymers |
US20070078194A1 (en) * | 2005-10-04 | 2007-04-05 | St Clair David J | Flexographic printing plate and flexographic printing plate precursor composition for preparing same |
CN101374906B (en) | 2005-11-14 | 2015-04-22 | 克拉通聚合物研究有限公司 | Process for preparing a bituminous binder composition |
CN101484304B (en) | 2005-11-28 | 2013-04-24 | 卡拉工业公司 | Apparatus and method for controlled pelletization processing |
US20070130863A1 (en) * | 2005-12-01 | 2007-06-14 | Jones David R Iv | Roofing adhesive |
US7737216B2 (en) * | 2006-01-26 | 2010-06-15 | Chevron Phillips Chemical Company Lp | Monovinylarene conjugated diene block copolymer compositions for shrinkable films |
US7662528B2 (en) * | 2006-02-17 | 2010-02-16 | Xerox Corporation | Charge generating composition |
BRPI0708719B1 (en) * | 2006-03-10 | 2016-07-19 | Kraton Polymers Us Llc | polymeric viscosity index improver, oily composition, and polymeric concentrate for oily compositions |
US7592390B2 (en) * | 2006-03-24 | 2009-09-22 | Kraton Polymers U.S. Llc | Hydrogenated block copolymer compositions |
US7858693B2 (en) | 2006-03-24 | 2010-12-28 | Kratonpolymers U.S. Llc | Unhydrogenated block copolymer compositions |
US7582702B2 (en) | 2006-03-24 | 2009-09-01 | Kraton Polymers U.S. Llc | Block copolymer compositons |
EP1999208B1 (en) * | 2006-03-24 | 2012-10-17 | Kraton Polymers U.S. LLC | High temperature block copolymers and process for making same |
US7585916B2 (en) * | 2006-03-24 | 2009-09-08 | Kraton Polymers Us Llc | Block copolymer compositions |
WO2007127155A2 (en) * | 2006-04-24 | 2007-11-08 | Kraton Polymers U.S Llc | Polymeric compositions and films formed therefrom |
US7990679B2 (en) * | 2006-07-14 | 2011-08-02 | Dais Analytic Corporation | Nanoparticle ultracapacitor |
DE102006037627A1 (en) * | 2006-08-10 | 2008-02-14 | Tesa Ag | Self-adhesive composition of hydrogenated block copolymers and protective film made therefrom for smooth and rough surfaces |
US7685784B2 (en) * | 2006-08-25 | 2010-03-30 | Tremco Incorporated | Cool roof covering and adhesive therefor |
US8470071B2 (en) * | 2006-09-25 | 2013-06-25 | Dais Analytic Corporation | Enhanced HVAC system and method |
RU2459845C2 (en) * | 2006-11-13 | 2012-08-27 | КРЭЙТОН ПОЛИМЕРС ЮЭс ЭлЭлСи | Bitumen emulsions |
WO2008073669A1 (en) * | 2006-12-07 | 2008-06-19 | 3M Innovative Properties Company | Block copolymer blend adhesives with multiple tackifiers |
BRPI0720155A2 (en) | 2006-12-07 | 2014-02-04 | 3M Innovative Properties Co | BLOCK COPOLYMER BLENDES AND ACRYLIC ADVISES. |
US20080153970A1 (en) * | 2006-12-21 | 2008-06-26 | Kraton Polymers U.S. Llc | Solvent sprayable contact adhesive formulations from functionalized/controlled distribution block copolymers |
US7977432B2 (en) * | 2007-01-12 | 2011-07-12 | Kraton Polymers U.S. Llc | Functionalized block copolymers, method for making same, and various uses for such block copolymers |
EP2106410B1 (en) | 2007-01-19 | 2015-10-07 | Stepan Company | Method of sulfonation of block polymers |
US8500960B2 (en) * | 2007-01-20 | 2013-08-06 | Dais Analytic Corporation | Multi-phase selective mass transfer through a membrane |
US20080193755A1 (en) * | 2007-02-09 | 2008-08-14 | Olivier Guise | Extrusion die, methods of coating a wire core, and a coated wire by the extrusion die and methods |
CN101675114B (en) * | 2007-05-01 | 2012-09-26 | 科腾聚合物美国有限责任公司 | Bituminous binder composition and process for preparing the same |
DE102007027156A1 (en) | 2007-06-13 | 2008-12-24 | Kraiburg Tpe Gmbh & Co. Kg | Transparent, thermoplastically processable, elastomeric polymer composition with UV stability and good adhesion properties |
CN101918487A (en) * | 2007-06-26 | 2010-12-15 | 艺杰斯生物科学有限责任公司 | Stable and compatible polymer blends |
US20090062457A1 (en) * | 2007-09-04 | 2009-03-05 | Kraton Polymers U.S. Llc | Styrenic block copolymers and compositions containing the same |
US8399368B2 (en) * | 2007-10-16 | 2013-03-19 | Kimberly-Clark Worldwide, Inc. | Nonwoven web material containing a crosslinked elastic component formed from a linear block copolymer |
US8349963B2 (en) * | 2007-10-16 | 2013-01-08 | Kimberly-Clark Worldwide, Inc. | Crosslinked elastic material formed from a linear block copolymer |
US7923391B2 (en) * | 2007-10-16 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Nonwoven web material containing crosslinked elastic component formed from a pentablock copolymer |
US7923392B2 (en) * | 2007-10-16 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Crosslinked elastic material formed from a branched block copolymer |
US8323257B2 (en) | 2007-11-21 | 2012-12-04 | The Procter & Gamble Company | Absorbent articles comprising a slow recovery stretch laminate and method for making the same |
US8883927B2 (en) * | 2007-11-28 | 2014-11-11 | Dynasol Elastómeros, S.A. De C.V. | Radial multi-block copolymers |
KR101193772B1 (en) | 2007-12-21 | 2012-10-23 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | Soft elastomeric films |
US9453606B2 (en) * | 2007-12-26 | 2016-09-27 | Smart Pipe Company, Inc. | Movable factory for simultaneous mobile field manufacturing and installation of non-metallic pipe |
WO2009134354A1 (en) | 2008-04-30 | 2009-11-05 | Flanigan Theodore P | System and method for pre-treatment of rubber-modified asphalt cement, and emulsions thereof |
HUE027362T2 (en) * | 2008-04-30 | 2016-09-28 | Trinseo Europe Gmbh | Styrene-butadiene polymers with styrene gradient and methods of making the same |
US8012539B2 (en) | 2008-05-09 | 2011-09-06 | Kraton Polymers U.S. Llc | Method for making sulfonated block copolymers, method for making membranes from such block copolymers and membrane structures |
US9017791B2 (en) | 2008-05-13 | 2015-04-28 | Owens Corning Intellectual Capital, Llc | Shingle blank having formation of individual hip and ridge roofing shingles |
CN102099381B (en) * | 2008-06-18 | 2013-10-02 | 思迪隆欧洲有限公司 | Low chloride polybutadiene |
US20100010147A1 (en) * | 2008-07-08 | 2010-01-14 | Kraton Polymer U.S. Llc | Adhesives prepared from diphenylethylene containing block copolymers |
US20100010154A1 (en) * | 2008-07-08 | 2010-01-14 | Kraton Polymers U.S. Llc | Gels prepared from dpe containing block copolymers |
US20100010171A1 (en) * | 2008-07-11 | 2010-01-14 | Ruidong Ding | Thermoplastic polyurethane/block copolymer compositions |
US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
EP2310432A4 (en) * | 2008-08-05 | 2011-11-30 | Firestone Polymers Llc | Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation |
US20100056721A1 (en) * | 2008-09-03 | 2010-03-04 | Kathryn Wright | Articles prepared from certain hydrogenated block copolymers |
EP2346940A4 (en) | 2008-09-24 | 2013-04-24 | Wright Advanced Asphalt Systems | System and method for high throughput preparation of rubber-modified asphalt cements |
ES2654377T3 (en) | 2008-10-07 | 2018-02-13 | Ross Technology Corporation | Spill resistant surfaces with hydrophobic and oleophobic boundaries |
US20100130670A1 (en) * | 2008-11-21 | 2010-05-27 | Kraton Polymers Us Llc | End use applications prepared from certain block copolymers |
US9151055B2 (en) | 2009-02-25 | 2015-10-06 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing material |
US11313127B2 (en) | 2009-02-25 | 2022-04-26 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing material |
US20100222466A1 (en) * | 2009-02-27 | 2010-09-02 | Semmaterials, L.P. | Crack resistant layer with good beam fatigue properties made from an emulsion of a polymer modified bituminous binder and method of selecting same |
US20100222467A1 (en) * | 2009-02-27 | 2010-09-02 | Semmaterials, L.P. | crack resistent layer with good mixture fracture energy made from an emulsion of a polymer modified bituminous binder and method of selecting same |
US20100222469A1 (en) | 2009-02-27 | 2010-09-02 | Semmaterials, L.P. | A crack resistant layer with good binder fracture energy properties and method of selecting same |
US20100222465A1 (en) * | 2009-02-27 | 2010-09-02 | Semmaterials, L.P. | Crack resistant layer with good mixture fracture energy and method of selecting same |
US20100222464A1 (en) * | 2009-02-27 | 2010-09-02 | Semmaterials, L.P. | Emulsion of a polymer modified asphalt |
CN101508811A (en) * | 2009-03-10 | 2009-08-19 | 叶孙勇 | Injectable vulcanizable vinyl benzene rubber particles and producing process |
US20100239807A1 (en) | 2009-03-20 | 2010-09-23 | Grubka Lawrence J | Flexible laminated hip and ridge shingle |
US8445631B2 (en) | 2009-10-13 | 2013-05-21 | Kraton Polymers U.S. Llc | Metal-neutralized sulfonated block copolymers, process for making them and their use |
US8263713B2 (en) * | 2009-10-13 | 2012-09-11 | Kraton Polymers U.S. Llc | Amine neutralized sulfonated block copolymers and method for making same |
CN102686665B (en) * | 2009-11-12 | 2014-04-02 | 科腾聚合物美国有限责任公司 | Thermoplastic polyurethane block copolymer compositions |
US9013155B2 (en) | 2010-01-09 | 2015-04-21 | Dais Analytic Corporation | Energy storage devices including a solid multilayer electrolyte |
WO2011085186A2 (en) | 2010-01-09 | 2011-07-14 | Dais Analytic Corporation | Anionic exchange electrolyte polymer membranes |
EP2528956A4 (en) * | 2010-01-27 | 2014-03-05 | Kraton Polymers Us Llc | Compositions containing styrene-isobutylene-styrene and styrene-ethylene/butylene-styrene block copolymers |
PL2406315T3 (en) * | 2010-01-29 | 2012-12-31 | Kraton Polymers Us Llc | Thermofusible composition for slush moulding |
US20140141233A1 (en) | 2012-07-03 | 2014-05-22 | Peterson Chemical Technology, Inc. | Surface Infusion of Flexible Cellular Foams With Novel Liquid Gel Mixture |
US9097020B2 (en) * | 2010-03-04 | 2015-08-04 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing shingle |
JP5858441B2 (en) | 2010-03-15 | 2016-02-10 | ロス テクノロジー コーポレーション.Ross Technology Corporation | Plunger and method for obtaining a hydrophobic surface |
US20110262686A1 (en) * | 2010-04-22 | 2011-10-27 | Kathryn Wright | High Tensile Strength Article with Elastomeric Layer |
CN101870744A (en) * | 2010-06-11 | 2010-10-27 | 北京化工大学 | Hydrogenation method of butadiene-acrylonitrile rubber |
US9429366B2 (en) | 2010-09-29 | 2016-08-30 | Kraton Polymers U.S. Llc | Energy recovery ventilation sulfonated block copolymer laminate membrane |
US9394414B2 (en) * | 2010-09-29 | 2016-07-19 | Kraton Polymers U.S. Llc | Elastic, moisture-vapor permeable films, their preparation and their use |
CN103201298B (en) | 2010-10-18 | 2015-06-24 | 科腾聚合物美国有限责任公司 | Method for producing a sulfonated block copolymer composition |
US9017305B2 (en) | 2010-11-12 | 2015-04-28 | The Procter Gamble Company | Elastomeric compositions that resist force loss and disintegration |
RU2013131000A (en) | 2010-12-06 | 2015-01-20 | Колгейт-Палмолив Компани | MULTI-LAYERED TUBE HAVING IMPROVED ELASTICITY THANKS TO THE COPOLYMER BLOCK |
JP5859563B2 (en) | 2010-12-23 | 2016-02-10 | スタイロリューション・ヨーロッパ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Thermoplastic elastomer composition and method for producing the same |
CN108409926B (en) * | 2011-01-30 | 2021-09-14 | 戴纳索尔伊莱斯托米罗斯公司 | Tapered triblock copolymers |
US9182560B2 (en) | 2011-02-18 | 2015-11-10 | Kraton Polymers U.S. Llc | Curable polymeric compositions for cable filling |
AU2012220798B2 (en) | 2011-02-21 | 2016-04-28 | Ross Technology Corporation | Superhydrophobic and oleophobic coatings with low VOC binder systems |
CN102190957B (en) * | 2011-03-21 | 2013-04-24 | 武汉理工大学 | Magnesium-aluminum-base laminar dihydroxide anti-aging elastomer modified asphalt coating material and preparation method thereof |
JP2014511925A (en) * | 2011-04-07 | 2014-05-19 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | Bituminous composition |
TWI512060B (en) | 2011-04-26 | 2015-12-11 | Chi Mei Corp | Moisture-proof and insulating coating material and uses thereof |
US8378453B2 (en) | 2011-04-29 | 2013-02-19 | Georgia Tech Research Corporation | Devices including composite thermal capacitors |
CN102277112B (en) * | 2011-05-23 | 2014-11-05 | 波士胶芬得利(中国)粘合剂有限公司 | Wax-containing hot melt adhesive and disposable absorbent product |
US9861941B2 (en) | 2011-07-12 | 2018-01-09 | Kraton Polymers U.S. Llc | Modified sulfonated block copolymers and the preparation thereof |
US20130101767A1 (en) | 2011-10-25 | 2013-04-25 | Kraton Polymers U.S. Llc | Method for melt processing sulfonated block copolymers and articles comprising optionally amine modified sulfonated block copolymers |
US11021559B2 (en) | 2011-10-31 | 2021-06-01 | Kraton Polymers Llc | Sulfonated block copolymer laminates with polar or active metal substrates |
US20130310492A1 (en) * | 2011-11-17 | 2013-11-21 | Baker Hughes Incorporated | Process for improving the physical properties of bitumen |
EP2791255B1 (en) | 2011-12-15 | 2017-11-01 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
US9290943B2 (en) | 2012-01-05 | 2016-03-22 | Owens Corning Intellectual Capital, Llc | Hip and ridge roofing shingle |
US9293269B2 (en) | 2012-02-08 | 2016-03-22 | Dais Analytic Corporation | Ultracapacitor tolerating electric field of sufficient strength |
US20130225020A1 (en) | 2012-02-24 | 2013-08-29 | Kraton Polymers Us Llc | High flow, hydrogenated styrene-butadiene-styrene block copolymer and applications |
US9771473B2 (en) | 2012-02-24 | 2017-09-26 | Kraton Polymers U.S. Llc | High flow, hydrogenated styrene-butadiene-styrene block copolymers and applications |
US10233323B2 (en) | 2012-03-15 | 2019-03-19 | Kraton Polymers U.S. Llc | Blends of sulfonated block copolymers and particulate carbon and membranes, films, and coatings comprising them |
CN103382241B (en) * | 2012-05-04 | 2016-06-08 | 中国石油天然气股份有限公司 | Star isoprene-b-butadiene styrene terpolymer and its preparation method |
MX2015000119A (en) * | 2012-06-25 | 2015-04-14 | Ross Technology Corp | Elastomeric coatings having hydrophobic and/or oleophobic properties. |
EP2904045B1 (en) | 2012-10-08 | 2018-09-19 | Teknor Apex Company | Thermoplastic elastomer compositions having biorenewable content |
EP2759572A1 (en) | 2013-01-23 | 2014-07-30 | Teknor Apex Company | Thermoplastic elastomer compositions having biorenewable content |
US20140100310A1 (en) | 2012-10-08 | 2014-04-10 | Teknor Apex Company | Thermoplastic elastomer compositions having biorenewable content |
KR101865454B1 (en) | 2012-11-05 | 2018-06-07 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | Fire retardant systems for polymers that enable flexibility and strength |
CN103804603B (en) * | 2012-11-07 | 2016-03-02 | 中国石油化工股份有限公司 | The application of a kind of solution polymerized butadiene styrene rubber and synthetic method and acid anhydrides |
WO2014105687A1 (en) | 2012-12-27 | 2014-07-03 | Peterson Chemical Technology, Inc. | Surface infusion of flexible cellular foams with novel liquid gel mixture |
US9061254B2 (en) * | 2013-01-14 | 2015-06-23 | Kraton Polymers U.S. Llc | Block copolymers, their manufacture and their use |
US10022680B2 (en) | 2013-01-14 | 2018-07-17 | Kraton Polymers U.S. Llc | Anion exchange block copolymers, their manufacture and their use |
US20140202357A1 (en) * | 2013-01-18 | 2014-07-24 | Special Materials Company | Asphalt cutback formulations |
KR20150005424A (en) * | 2013-07-05 | 2015-01-14 | 주식회사 엘지화학 | Asphalt modifier improved miscibility with asphalt and asphalt composition containing the same |
US9127132B2 (en) | 2013-10-08 | 2015-09-08 | Katon Polymers U.S. LLC | Process for coagulating sulfonated block copolymers |
US10843401B2 (en) | 2013-11-01 | 2020-11-24 | Kraton Polymers U.S. Llc | Fuse molded three dimensional article and a method for making the same |
TWI512062B (en) * | 2013-11-21 | 2015-12-11 | Chi Mei Corp | Moisture-proof and insulating coating material and uses thereof |
US20150148488A1 (en) * | 2013-11-25 | 2015-05-28 | Kraton Polymers U.S. Llc | Impact Resistant Compositions Of Thermoplastic Polyamides And Modified Block Copolymers For Use In Tubes, Pipes, And Hoses |
EP3083825B1 (en) * | 2013-12-18 | 2019-03-27 | INEOS Styrolution Group GmbH | Use of molding materials based on vinyl aromatic/diene block copolymers for 3-d printing |
TWI555789B (en) * | 2014-01-17 | 2016-11-01 | Asahi Kasei Chemicals Corp | Polymer and asphalt composition |
EA031754B1 (en) | 2014-01-17 | 2019-02-28 | Асахи Касеи Кабусики Кайся | Polymer and asphalt composition |
EP3105288B1 (en) | 2014-02-11 | 2020-04-08 | INEOS Styrolution Group GmbH | Blends of thermoplastic elastomers based on styrene (s-tpe) and polyolefins |
US9758970B2 (en) | 2014-02-25 | 2017-09-12 | Owens Corning Intellectual Capital, Llc | Laminated hip and ridge shingle |
USD755997S1 (en) | 2014-02-27 | 2016-05-10 | Owens Corning Intellectual Capital, Llc | Shingle |
US10005924B2 (en) * | 2014-02-28 | 2018-06-26 | Zeon Corporation | Transparent adhesive sheet |
US10047477B2 (en) | 2014-04-02 | 2018-08-14 | Kraton Polymers U.S. Llc | Textile coating composition |
US10053603B2 (en) | 2014-04-02 | 2018-08-21 | Kraton Polymers U.S. Llc | Block copolymers containing a copolymer myrcene block |
KR101926950B1 (en) | 2014-04-02 | 2018-12-07 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | Process for the preparation of an aqueous emulsion of a midblock sulfonated block copolymer |
JP6452717B2 (en) | 2014-04-02 | 2019-01-16 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | Process for preparing aqueous emulsions of intermediate block sulfonated block copolymers |
TWI616491B (en) | 2014-05-08 | 2018-03-01 | Asahi Kasei Chemicals Corp | Asphalt composition |
WO2015175815A1 (en) * | 2014-05-16 | 2015-11-19 | Kraton Polymers U.S. Llc | Branched broad mwd conjugated diene polymer |
US9156978B1 (en) * | 2014-06-06 | 2015-10-13 | Teknor Apex Company | Low softener halogen free flame retardant styrenic block copolymer-based thermoplastic elastomer compositions |
US9216405B1 (en) | 2014-06-26 | 2015-12-22 | Kraton Polymers U.S. Llc | Rotary enthalpy exchange wheel having sulfonated block copolymer |
CN105273204B (en) | 2014-07-16 | 2020-10-16 | 科腾聚合物美国有限责任公司 | Block copolymers, their preparation and their use |
ES2844499T3 (en) | 2014-12-17 | 2021-07-22 | Fuller H B Co | Packed sets of metal containers |
EP3234057B1 (en) | 2014-12-17 | 2020-10-21 | H. B. Fuller Company | Hot melt adhesive composition for bonding packs of plastic containers |
US9441090B1 (en) | 2015-03-12 | 2016-09-13 | Chevron Phillips Chemical Company Lp | Methods for controlling hardness of styrene-butadiene block copolymers |
US9540475B2 (en) | 2015-03-12 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers for tubing applications |
US9598524B1 (en) | 2015-09-18 | 2017-03-21 | Chevron Phillips Chemical Company Lp | Styrene-butadiene block copolymers with a terminal butadiene block for tubing applications |
US10557022B2 (en) * | 2015-04-24 | 2020-02-11 | Pirelli Tyre S.P.A. | High-performance tire |
KR102546052B1 (en) | 2015-06-12 | 2023-06-20 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | Composition for soft skin and use thereof |
EP3323838B1 (en) | 2015-07-16 | 2019-04-17 | Asahi Kasei Kabushiki Kaisha | Partially hydrogenated block copolymer, viscous adhesive composition, viscous adhesive tape, label, modified asphalt composition, modified asphalt mixture, and paving binder composition |
US9738781B2 (en) | 2015-09-03 | 2017-08-22 | Ineos Styrolution Group Gmbh | Blends of styrene-butadiene block copolymer with styrenic thermoplastic elastomers for tubing applications |
TWI617613B (en) * | 2015-09-08 | 2018-03-11 | 科騰聚合物美國有限責任公司 | Copolyester/controlled distribution styrenic block copolymer blends and methods of making and using same |
CN113278296B (en) | 2016-01-26 | 2023-02-17 | 戴纳索尔伊莱斯托米罗斯公司 | Reverse tapered thermoplastic elastomers |
US10023676B2 (en) | 2016-02-24 | 2018-07-17 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
US9828455B2 (en) | 2016-02-24 | 2017-11-28 | Ineos Styrolution Group Gmbh | Styrene-butadiene block copolymers with an internal butadiene block for tubing applications |
EP3436490B1 (en) | 2016-03-24 | 2023-08-16 | Kraton Polymers U.S. LLC | Semi-crystalline block copolymers and compositions therefrom |
US10539649B2 (en) | 2016-03-28 | 2020-01-21 | Michael L. Howard | System and methods for detecting a position using differential attenuation |
KR102361853B1 (en) | 2016-05-09 | 2022-02-11 | 크레이튼 폴리머즈 유.에스. 엘엘씨 | Promotes Foam Adhesion |
US10839979B2 (en) * | 2016-07-08 | 2020-11-17 | Teknor Apex Company | Cable with flame retardant multi-layer covering |
CN106398618A (en) * | 2016-08-27 | 2017-02-15 | 安徽天瞳智能科技有限公司 | High density resin adhesive |
US11124644B2 (en) * | 2016-09-01 | 2021-09-21 | University Of Florida Research Foundation, Inc. | Organic microgel system for 3D printing of silicone structures |
FR3059672B1 (en) * | 2016-12-07 | 2020-10-30 | Total Marketing Services | SOLID OILY COMPOSITIONS |
EP3562880B1 (en) * | 2016-12-30 | 2024-04-24 | Turkiye Petrol Rafinerileri Anonim Sirketi Tupras | A bituminous mixture comprising polyurethane obtained by a polymerization reaction of bhet obtained from chemical depolymerisation of pet waste and a preparation method thereof |
US20220411637A1 (en) | 2017-01-26 | 2022-12-29 | Dynasol Elastómeros, S.A. De C.V. | Counter Tapered Thermoplastic Elastomers |
US11891503B2 (en) * | 2017-03-16 | 2024-02-06 | Ineos Styrolution Group Gmbh | Non-sticky, soft and transparent styrenic thermoplastic elastomers |
US10647805B2 (en) * | 2017-06-09 | 2020-05-12 | Kraton Polymers Llc | Highly asymmetric triblock polymer compositions and methods of making same |
JP7178373B2 (en) | 2017-06-19 | 2022-11-25 | イネオス・スタイロリューション・グループ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | Vinyl aromatic/diene-block copolymers with excellent sensory properties |
EP3668925A1 (en) | 2017-09-29 | 2020-06-24 | Kraton Polymers LLC | Elastomeric compositions providing improved wet grip |
JP6664729B2 (en) | 2018-01-31 | 2020-03-13 | 積水フーラー株式会社 | Stretchable hot melt composition |
DE102018109269A1 (en) | 2018-04-18 | 2019-10-24 | Clariant Plastics & Coatings Ltd | Permanently tacky pressure-sensitive adhesives with improved environmental compatibility |
US11759758B2 (en) * | 2018-04-30 | 2023-09-19 | Kraton Corporation | Block copolymers for gel compositions with improved efficiency |
JP2020041141A (en) | 2018-09-10 | 2020-03-19 | クレイトン・ポリマーズ・リサーチ・ベー・フェー | Rubber composition and method for producing the same |
EP3620477B1 (en) | 2018-09-10 | 2021-07-14 | Kraton Polymers Research B.V. | Medical tubing and compositions and methods for making therefor |
US11454623B2 (en) | 2018-10-11 | 2022-09-27 | Baker Hughes Holdings Llc | Method for quantitatively assessing stability additive performance at field dosages |
US11760826B2 (en) | 2018-12-14 | 2023-09-19 | Kraton Corporation | Block copolymers and uses thereof |
US11629215B2 (en) * | 2019-04-02 | 2023-04-18 | Kraton Corporation | Sulfonated block copolymers and uses thereof |
US11613619B2 (en) | 2019-05-29 | 2023-03-28 | Kraton Corporation | Molding compositions and foam molded articles made thereof |
FR3099766B1 (en) * | 2019-08-07 | 2021-07-30 | Michelin & Cie | Ethylene-rich diene block polymer having a statistical block and a polyethylene block. |
TWI778447B (en) * | 2019-11-07 | 2022-09-21 | 墨西哥商帝納梭艾拉托梅羅斯公司 | Modified diene copolymers and their use |
US11739208B2 (en) | 2020-08-14 | 2023-08-29 | Kraton Corporation | Block copolymers and uses thereof |
WO2022159979A1 (en) | 2021-01-24 | 2022-07-28 | Kraton Polymers Llc | Electrode binders for batteries |
EP4359759A1 (en) | 2021-06-24 | 2024-05-01 | Borealis AG | Method for determining compressive character of olefin polymerisation catalysts |
CN117881707A (en) | 2021-06-24 | 2024-04-12 | 博里利斯股份公司 | Process for producing polyethylene polymers |
CN115948121B (en) * | 2023-01-05 | 2023-10-20 | 江苏凯伦建材股份有限公司 | Modified asphalt coating based on monoepoxy end-capped diblock copolymer, and preparation method and application thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4530652A (en) * | 1984-01-12 | 1985-07-23 | Buck Ollie G | Asphalt composition |
GB2305667A (en) * | 1995-09-27 | 1997-04-16 | Lawrence Lester | Bitumen-polymer compositions |
EP0822227A1 (en) * | 1996-07-31 | 1998-02-04 | Shell Internationale Researchmaatschappij B.V. | Oil gel formulations containing high vinyl content hydrogenated styrenebutadiene-styrene block copolymers |
US5854335A (en) * | 1995-02-20 | 1998-12-29 | Shell Oil Company | Bituminous composition with diene/monovinyl aromatic block copolymer |
WO2000055271A1 (en) * | 1999-03-16 | 2000-09-21 | Shell Internationale Research Maatschappij B.V. | Pipe coatings |
Family Cites Families (108)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA716645A (en) | 1965-08-24 | Shell Oil Company | Block polymers and process for preparing them | |
US3149182A (en) | 1957-10-28 | 1964-09-15 | Shell Oil Co | Process for preparing block copolymers utilizing organolithium catalysts |
BE637376A (en) | 1958-05-23 | |||
NL254508A (en) * | 1960-08-03 | |||
US3239478A (en) * | 1963-06-26 | 1966-03-08 | Shell Oil Co | Block copolymer adhesive compositions and articles prepared therefrom |
US3600250A (en) | 1968-09-12 | 1971-08-17 | Shell Oil Co | Stretching and laminating thermoplastic elastomers |
US3595942A (en) | 1968-12-24 | 1971-07-27 | Shell Oil Co | Partially hydrogenated block copolymers |
USRE27145E (en) * | 1969-05-20 | 1971-06-22 | Side-chain | |
US3634549A (en) * | 1969-08-04 | 1972-01-11 | Shell Oil Co | Conjugated diene block copolymers having a random copolymer elastomeric block and their hydrogenated counterparts |
US3670054A (en) | 1969-10-29 | 1972-06-13 | Shell Oil Co | Block copolymers having reduced solvent sensitivity |
US3700633A (en) | 1971-05-05 | 1972-10-24 | Shell Oil Co | Selectively hydrogenated block copolymers |
US4039593A (en) | 1973-05-18 | 1977-08-02 | Lithium Corporation Of America | Preparation of hydroxy-terminated conjugated diene polymers |
US3821148A (en) * | 1973-09-28 | 1974-06-28 | Exxon Research Engineering Co | Plasticized thermoplastic block copolymers |
US3821149A (en) * | 1973-09-28 | 1974-06-28 | Exxon Research Engineering Co | Plasticized thermoplastic semicrystalline block copolymers |
US4089913A (en) * | 1974-01-10 | 1978-05-16 | Sumitomo Chemical Company, Limited | Process for producing transparent block copolymer resin |
JPS5232774B2 (en) | 1974-02-02 | 1977-08-24 | ||
US4122134A (en) | 1974-02-13 | 1978-10-24 | Sumitomo Chemical Company, Limited | Method for producing transparent block copolymer resin |
US3985830B1 (en) | 1974-07-15 | 1998-03-03 | Univ Akron | Star polymers and process for the preparation thereof |
DE2550546A1 (en) * | 1975-11-11 | 1977-05-18 | Basf Ag | FELT ADHESIVE BASED ON BLOCK COPOLYMERISATS |
US4107131A (en) | 1976-06-07 | 1978-08-15 | Shell Oil Company | Multicomponent polyurethane-block copolymer-polymer blends |
FR2376188A1 (en) | 1976-12-28 | 1978-07-28 | Elf Union | PROCESS FOR PREPARING COMPOSITIONS OF POLYMERIC BITUMES |
US4267284A (en) * | 1977-01-07 | 1981-05-12 | Phillips Petroleum Company | Tough, transparent articles from styrene polymers blended with certain block-random copolymers |
US4122434A (en) * | 1977-09-26 | 1978-10-24 | O.E.M. Technical Sales, Inc. | Test system for trailer brake mechanism |
US4129541A (en) | 1977-10-26 | 1978-12-12 | Phillips Petroleum Company | Asphaltic compositions containing conjugated diene-monovinyl-substituted aromatic hydrocarbon copolymers of particular structures |
US4248981A (en) | 1979-04-30 | 1981-02-03 | Arco Polymers, Inc. | Clear impact resistant thermoplastic star-block copolymers |
JPS56149413A (en) | 1980-04-22 | 1981-11-19 | Japan Synthetic Rubber Co Ltd | Production of styrene/butadiene copolymer |
JPS57100112A (en) | 1980-12-16 | 1982-06-22 | Asahi Chem Ind Co Ltd | Perfectly random styrene-butadiene copolymer rubber |
US4444953A (en) | 1981-11-12 | 1984-04-24 | Shell Oil Company | Assymetric block copolymers and corresponding adhesive formulations |
US4391949A (en) | 1981-11-12 | 1983-07-05 | Shell Oil Company | Asymmetric block copolymers and corresponding adhesive formulations |
US4412087A (en) | 1981-12-16 | 1983-10-25 | Phillips Petroleum Company | Viscosity index improver with high thickening power |
US4603155A (en) | 1983-03-10 | 1986-07-29 | Japan Synthetic Rubber Co., Ltd. | Alkenyl aromatic compound-conjugated diene block copolymer and process for the production thereof |
JPH0615595B2 (en) | 1984-02-07 | 1994-03-02 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Block copolymer |
JPS6129162A (en) | 1984-07-20 | 1986-02-10 | Hitachi Ltd | Semiconductor device |
US4578429A (en) | 1984-08-31 | 1986-03-25 | Shell Oil Company | Selectively hydrogenated block copolymers modified with acid compounds or derivatives |
DE3521597A1 (en) * | 1985-06-15 | 1986-12-18 | Rütgerswerke AG, 6000 Frankfurt | BITUMINOUS DIMENSIONS AND THEIR USE |
JPS61291610A (en) | 1985-06-18 | 1986-12-22 | Japan Synthetic Rubber Co Ltd | Block copolymer and its composition |
US5371141A (en) | 1985-07-31 | 1994-12-06 | Shell Oil Company | High impact resistant blends of thermoplastic polyamides and modified block copolymers |
JPS6241213A (en) * | 1985-08-16 | 1987-02-23 | シエル・インタ−ナシヨネイル・リサ−チ・マ−チヤツピイ・ベ−・ウイ | Modified block copolymer, impact resistant composition containing said copolymer and production of said copolymer |
GB8714817D0 (en) * | 1987-06-24 | 1987-07-29 | Flymo Ltd | Grass trimmer |
US4788361A (en) | 1987-10-30 | 1988-11-29 | Shell Oil Company | Polymeric viscosity index improver and oil composition comprising the same |
US4882384A (en) | 1988-02-01 | 1989-11-21 | Shell Oil Company | Modified block copolymers |
US5239010A (en) * | 1988-05-24 | 1993-08-24 | Shell Oil Company | Sulfonated block copolymers |
US4970265A (en) * | 1989-03-27 | 1990-11-13 | Shell Oil Company | Functionalized polymers and process for modifying unsaturated polymers |
DE69032963T2 (en) | 1989-05-19 | 1999-08-19 | Japan Synthetic Rubber Co Ltd | (Modified) hydrogenated diene block copolymer and composition containing the same |
JPH0798890B2 (en) | 1989-06-23 | 1995-10-25 | 日本ゼオン株式会社 | Block copolymer composition for pressure-sensitive adhesive and pressure-sensitive adhesive composition |
GB8918702D0 (en) | 1989-08-16 | 1989-09-27 | Shell Int Research | Process for the preparation of random solution copolymers of conjugated dienes and vinyl aromatic compounds |
US5206300A (en) | 1990-03-30 | 1993-04-27 | Shell Oil Company | Functionalized elastomeric polymers |
KR0185671B1 (en) | 1990-08-23 | 1999-05-15 | 요하네스 아르트 반 주트펜 | Melt matalation of block copolymers |
US5227419A (en) | 1990-12-20 | 1993-07-13 | Phillips Petroleum Company | Tapered block styrene/butadiene copolymers |
US5516831A (en) * | 1991-01-30 | 1996-05-14 | Shell Oil Company | Selectively sulfonated block copolymers/extender oils |
CA2068154C (en) * | 1992-05-07 | 1997-01-14 | Janice C. Halligan | Programmable call progress tones for a switching system |
US5290875A (en) | 1992-11-30 | 1994-03-01 | Phillips Petroleum Company | Conjugated diene/monovinylarene block copolymers with multiple tapered blocks |
US5905097A (en) * | 1993-01-08 | 1999-05-18 | The Dow Chemical Company | High-strength breathable films of block copolymer lattices |
JP3367136B2 (en) | 1993-03-22 | 2003-01-14 | ジェイエスアール株式会社 | Thermoplastic resin composition |
GB9306517D0 (en) | 1993-03-29 | 1993-05-19 | Polyphalt Inc | Stabilized bitumen compositions |
JP3203399B2 (en) * | 1993-05-13 | 2001-08-27 | 松下電器産業株式会社 | Route search device |
US5331028A (en) | 1993-06-30 | 1994-07-19 | Chevron Research And Technology Company, A Division Of Chevron U.S.A. Inc. | Polymer-modified asphalt composition and process for the preparation thereof |
JPH07123696A (en) | 1993-10-22 | 1995-05-12 | Oriental Motor Co Ltd | Manufacture of iron core of multiphase linear motor |
US6265484B1 (en) * | 1993-11-15 | 2001-07-24 | Phillips Petroleum Company | Tapered block copolymers of monovinylarenes and conjugated dienes |
CA2134026C (en) | 1993-11-15 | 1998-06-09 | William J. Trepka | Tapered block copolymers of monovinylarenes and conjugated dienes |
JPH07149952A (en) | 1993-11-30 | 1995-06-13 | Toray Ind Inc | Thermosetting resin composition, cured resin, prepaeg, and fiber-reinforced plastic |
US7290367B2 (en) * | 1994-04-19 | 2007-11-06 | Applied Elastomerics, Inc. | Tear resistant gel articles for various uses |
US7234560B2 (en) * | 1994-04-19 | 2007-06-26 | Applied Elastomerics, Inc. | Inflatable restraint cushions and other uses |
US7226484B2 (en) * | 1994-04-19 | 2007-06-05 | Applied Elastomerics, Inc. | Tear resistant gels and articles for every uses |
US5468574A (en) | 1994-05-23 | 1995-11-21 | Dais Corporation | Fuel cell incorporating novel ion-conducting membrane |
DE4420952A1 (en) * | 1994-06-17 | 1995-12-21 | Basf Ag | Thermoplastic elastomer |
US5451619A (en) | 1994-08-19 | 1995-09-19 | Shell Oil Company | Asphalt composition containing epoxidized polymers |
DE19503944A1 (en) | 1995-02-07 | 1996-08-08 | Basf Ag | Medical-technical molded part, in particular component for a transmission system for infusion or transfusion purposes |
DE19523585A1 (en) | 1995-06-29 | 1997-01-02 | Basf Ag | Impact-resistant molding compound of styrene polymers |
ATE219134T1 (en) * | 1995-08-29 | 2002-06-15 | Penreco | TRANSPARENT GEL CANDLES |
US5749111A (en) * | 1996-02-14 | 1998-05-12 | Teksource, Lc | Gelatinous cushions with buckling columns |
US6865759B2 (en) * | 1996-02-14 | 2005-03-15 | Edizone, Inc. | Cushions with non-intersecting-columnar elastomeric members exhibiting compression instability |
US5994450A (en) * | 1996-07-01 | 1999-11-30 | Teksource, Lc | Gelatinous elastomer and methods of making and using the same and articles made therefrom |
US6797765B2 (en) * | 1996-02-14 | 2004-09-28 | Edizone, Lc | Gelatinous elastomer |
US5795944A (en) | 1996-03-18 | 1998-08-18 | Shell Oil Company | Programmed addition of heavy ethers for microstructure control of diene polymers |
ZA972383B (en) * | 1996-03-22 | 1997-09-25 | Shell Int Research | High temperature, low viscosity thermoplastic elastomer block copolymer compositions. |
DE19615533A1 (en) | 1996-04-19 | 1997-10-23 | Basf Ag | Thermoplastic molding compound |
DE19621688A1 (en) * | 1996-05-30 | 1997-12-04 | Basf Ag | Transparent, non-blocking film |
US5773496A (en) | 1996-05-31 | 1998-06-30 | Koch Industries, Inc. | Polymer enhanced asphalt |
US5776234A (en) | 1996-08-12 | 1998-07-07 | Westvaco Corporation | Anionic bituminous emulsions with improved adhesion |
DE19638256A1 (en) * | 1996-09-19 | 1998-03-26 | Basf Ag | Thermoplastic molding compounds |
DE19638254A1 (en) | 1996-09-19 | 1998-03-26 | Basf Ag | Thermoplastic elastomers |
DE19645732A1 (en) | 1996-11-06 | 1998-05-07 | Basf Ag | Powdery polymer compositions |
US5973037A (en) | 1996-11-27 | 1999-10-26 | Fields; John R. | Styrene ethylene butylene styrene (SEBS) copolymer rubber modified asphalt mixture |
SG55445A1 (en) | 1997-01-07 | 1998-12-21 | Denki Kagaku Kogyo Kabushili K | Block copolymer block copolymer compostion and heat shrinkable films made thereof |
EP0853103A1 (en) | 1997-01-08 | 1998-07-15 | Fina Research S.A. | Bituminous compositions containing linear copolymers |
ZA982881B (en) | 1997-04-04 | 1998-10-08 | Polyphalt Inc | Elastomer-modified bituminous compositions |
US5886113A (en) | 1997-04-28 | 1999-03-23 | Taiwan Synthetic Rubber Corporation | Process for preparing an elastomeric copolymer composition of mono-vinyl aromatic hydrocarbons and conjugated dienes |
US6143832A (en) | 1997-05-22 | 2000-11-07 | Nippon Zeon Co., Ltd. | Aromatic vinyl-conjugated diene block copolymer and production process thereof |
US6423420B1 (en) * | 1997-08-11 | 2002-07-23 | Exxonmobil Chemical Patents Inc. | Oriented coextruded films |
US6110616A (en) * | 1998-01-30 | 2000-08-29 | Dais-Analytic Corporation | Ion-conducting membrane for fuel cell |
DE69941620D1 (en) | 1998-08-03 | 2009-12-17 | Asahi Chemical Ind | LINEAR BLOCK COPOLYMER AND RESIN COMPOSITION CONTAINING THIS |
US5998514A (en) | 1998-12-17 | 1999-12-07 | Basf Corporation | Random vinyl substituted aromatic/C4 -C6 conjugated diolefin polymer modified asphalt mixtures |
BR9909578A (en) * | 1999-02-16 | 2000-12-19 | Dynasol Elastomeros Sa | Modifier to improve the performance of bituminous mixtures used in road paving |
US6593430B1 (en) * | 1999-03-27 | 2003-07-15 | Basf Aktiengesellschaft | Transparent, impact-resistant polystyrene on a styrene-butadiene block copolymer basis |
DE19914075A1 (en) | 1999-03-27 | 2000-09-28 | Basf Ag | Transparent high-impact styrene-butadiene block copolymers comprises at least two hard blocks and a soft block with a low 1,2-vinyl content for improved thermal stability |
US6391981B1 (en) | 1999-04-23 | 2002-05-21 | Kraton Polymers Us Llc | Increased throughput in the manufacture of anionic polymers by reduction in polymer cement viscosity through the addition of metal alkyls |
US6465557B1 (en) * | 1999-06-25 | 2002-10-15 | Kraton Polymers U.S. Llc | Hot melt pressure sensitive positioning adhesive |
US6310122B1 (en) | 1999-09-03 | 2001-10-30 | Fina Technology, Inc. | Stable bitumen polymer compositions |
US6395841B1 (en) * | 2000-09-06 | 2002-05-28 | The Dow Chemical Company | Process for hydrogenating unsaturated polymers |
CN1324895A (en) * | 2001-07-05 | 2001-12-05 | 上海交通大学 | Production process of modified asphalt mateiral for road |
US6987142B2 (en) * | 2002-02-07 | 2006-01-17 | Kraton Polymers U.S. Llc | Adhesives and sealants from controlled distribution block copolymers |
US20040138371A1 (en) | 2002-02-07 | 2004-07-15 | St. Clair David John | Gels from controlled distribution block copolymers |
US20030181584A1 (en) * | 2002-02-07 | 2003-09-25 | Kraton Polymers U.S. Llc | Elastomeric articles prepared from controlled distribution block copolymers |
US7012118B2 (en) | 2002-02-07 | 2006-03-14 | Kraton Polymers U.S. Llc | Photopolymerizable compositions and flexographic plates prepared from controlled distribution block copolymers |
US7001956B2 (en) * | 2002-06-04 | 2006-02-21 | Kraton Polymers U.S. Llc | Articles prepared from hydrogenated block copolymers |
EP1384768A1 (en) | 2002-07-26 | 2004-01-28 | KRATON Polymers Research B.V. | Solvent-free hot melt adhesive, its use in bonding a polar leather layer to a non-polar substrate, and leather articles so produced |
US20060205904A1 (en) | 2005-03-11 | 2006-09-14 | St Clair David J | Oil gels of controlled distribution block copolymers and ester oils |
-
2003
- 2003-02-06 US US10/359,927 patent/US6987142B2/en not_active Expired - Lifetime
- 2003-02-06 US US10/359,981 patent/US7169848B2/en not_active Expired - Lifetime
- 2003-02-06 US US10/359,462 patent/US7141621B2/en not_active Expired - Lifetime
- 2003-02-06 US US10/359,906 patent/US6759454B2/en not_active Expired - Lifetime
- 2003-02-07 CN CN038074842A patent/CN1643016B/en not_active Expired - Lifetime
- 2003-02-07 EA EA200500184A patent/EA007542B1/en not_active IP Right Cessation
- 2003-02-07 WO PCT/NL2003/000099 patent/WO2003066738A1/en active IP Right Grant
- 2003-02-07 WO PCT/NL2003/000095 patent/WO2003066770A1/en not_active Application Discontinuation
- 2003-02-07 AT AT03707248T patent/ATE427988T1/en not_active IP Right Cessation
- 2003-02-07 DE DE60314843T patent/DE60314843T2/en not_active Expired - Lifetime
- 2003-02-07 WO PCT/NL2003/000097 patent/WO2003066739A1/en not_active Application Discontinuation
- 2003-02-07 TW TW092102538A patent/TWI248447B/en not_active IP Right Cessation
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4530652A (en) * | 1984-01-12 | 1985-07-23 | Buck Ollie G | Asphalt composition |
US5854335A (en) * | 1995-02-20 | 1998-12-29 | Shell Oil Company | Bituminous composition with diene/monovinyl aromatic block copolymer |
GB2305667A (en) * | 1995-09-27 | 1997-04-16 | Lawrence Lester | Bitumen-polymer compositions |
EP0822227A1 (en) * | 1996-07-31 | 1998-02-04 | Shell Internationale Researchmaatschappij B.V. | Oil gel formulations containing high vinyl content hydrogenated styrenebutadiene-styrene block copolymers |
WO2000055271A1 (en) * | 1999-03-16 | 2000-09-21 | Shell Internationale Research Maatschappij B.V. | Pipe coatings |
Non-Patent Citations (1)
Title |
---|
YIH-CHAU LIN ET AL: "using heavy ethers as structure modifiers in the synthesis of SBS block copolymers in cyclohexane", JOURNAL OF APPLIED POLYMER SCIENCE, JOHN WILEY AND SONS INC. NEW YORK, US, vol. 64, no. 13, 27 June 1997 (1997-06-27), pages 2543 - 2560, XP002084305, ISSN: 0021-8995 * |
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