WO2003080921A1 - PRETREATMENT METHOD OF POLyESTER FOR REDUCING ELIMINATION OF OLIGOMERS AT HIGH-TEMPERATURE ACID COLOURING WITH DISPERSION DYES - Google Patents
PRETREATMENT METHOD OF POLyESTER FOR REDUCING ELIMINATION OF OLIGOMERS AT HIGH-TEMPERATURE ACID COLOURING WITH DISPERSION DYES Download PDFInfo
- Publication number
- WO2003080921A1 WO2003080921A1 PCT/SI2003/000010 SI0300010W WO03080921A1 WO 2003080921 A1 WO2003080921 A1 WO 2003080921A1 SI 0300010 W SI0300010 W SI 0300010W WO 03080921 A1 WO03080921 A1 WO 03080921A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- colouring
- oligomers
- poliester
- polyester
- dispersion dyes
- Prior art date
Links
- 238000004040 coloring Methods 0.000 title claims abstract description 38
- 239000002253 acid Substances 0.000 title claims abstract description 25
- 239000000975 dye Substances 0.000 title claims abstract description 16
- 239000006185 dispersion Substances 0.000 title claims abstract description 13
- 230000008030 elimination Effects 0.000 title claims abstract description 9
- 238000003379 elimination reaction Methods 0.000 title claims abstract description 9
- 238000002203 pretreatment Methods 0.000 title claims abstract description 7
- 229920000728 polyester Polymers 0.000 title abstract description 5
- 239000008234 soft water Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000000872 buffer Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 abstract description 16
- 238000005406 washing Methods 0.000 abstract description 4
- 239000004753 textile Substances 0.000 description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 5
- 239000013638 trimer Substances 0.000 description 4
- 235000019646 color tone Nutrition 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000000549 coloured material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- MKWYFZFMAMBPQK-UHFFFAOYSA-J sodium feredetate Chemical compound [Na+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O MKWYFZFMAMBPQK-UHFFFAOYSA-J 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/88—Post-polymerisation treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Definitions
- the object of the invention is the pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with
- the linear and the cyclic fractions are eliminated, whereby the least preferred fraction is the cyclic trimer.
- the latter precipitates as the cristal powder with the melting point 316 - 325 °C on the vital parts of the colouring devices, as well. It belongs to those oligomers, which are water-insoluble.
- the oligomers remain on the textile as white deposited particles, as they can not be coloured by the dispersion dyes.
- the pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with dispersion dyes according to the invention enables colouring by the conventional acid high-temperature colouring procedure of also such poliester materials, from which large amount of oligomers is eliminated.
- the method is based on the pretreatment of poliester textile in basic bath with pH 11.5 - 12.2 at 130°C and the subsequent triple washing in soft hot water.
- the basic bath is prepared with the appropriate amount of the basics and the corresponding puffer mixtures.
- Such pretreated poliester is then ready for colouring with dispersion dyes in acid medium, and no problems, connected with the oligomers, were noticed by the colouring.
- Such prepared textile was basic pretreated in laboratory colouring device Mathis JFL at bath-ratio 1 :10.
- soft water was used for preparation of pretreatment bath.
- Pretreatment in the bath with 1 g/l of NaOH (pH 12) lasted 30 minutes at 130°C.
- Basic pretreated textile was then coloured at 135°C in blind acid bath, which contained 1 ml/l Eganal PS (Hoechst), 2 ml/I Lubit RL (Sybron / Tanatex) and CH 3 COOH 99-100% (J.T. Baker) up to the bath pH value of 4.5-5.
- the process of colouring was carried out according to the colouring diagram, which is recommended by DyStar company for colouring with Dianix AD dyes.
- the colourimetrical values are the average values of three measurements on light-red coloured poliester textiles.
- the result DE* ⁇ 1 means, that our eye does not recognize the change in colour.
- the values DE* 0.35 and DE* 0.38 are very low, what confirms the same colour.
- Elimination of oligomers by this method does not influence the change of the colour tone of the poliester textile by acid high-temperature colouring.
- pretreatment in basic bath the elimination of oligomers by acid colouring at 135°C is reduced by 44%. The reduction as such ensures undisturbed colouring procedure of poliester in acid medium.
- basic colouring the content of oligomers is reduced by 62%, but today there are not enough basically stable dispersion dyes available for its realization.
- poliester gets a nice gloss and a silky touch.
- the rigidness of such pretreated poliester is in comparison to the conventionally acidly coloured poliester rather reduced, and consequently it gets a softer touch.
- the method according to the invention is especially recommended for colouring poliester curtains in satin and other types of binding, linings for coats and clothes, poliester textiles for clothes and poliester threads.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The object of the invention is the pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with dispersion dyes and the composition of the pretreatment bath for polyester, which is to be coloured according to the conventional acid procedure in the high-temperature devices. The method is based on 15 to 30 minutes treatment of polyester in basic bath at 130°C and triple washing in hot soft water before the conventional acid colouring of polyester at temperatures from 130 to 135°C. The basic bath consists of the appropriate amount of basics or corresponding puffer mixtures.
Description
PRETREATMENT METHOD OF POLYESTER FOR REDUCING ELIMINATION OF OLIGOMERS AT HIGH- TEMPERATURE ACID COLOURING WITH DISPERSION DYES
The object of the invention is the pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with
10 dispersion dyes and the composition of the pretreatment bath for poliester, which is to be coloured according to the conventional acid procedure in the high-temperature devices. The technical problem at conventional high- temperature acid colouring of poliester are the low molecular ethileneglycoltereftalat fractions or oligomers, which at high-temperature
15 colouring diffuse from the inside to the surface of poliester fibres and precipitate on the coloured material or partly disperse in the colouring bath. This is a balanced process, as at the colouring temperature these low molecular fractions because of the differences in solubility in polimer melting and in colouring bath are eliminated from the fibres.
2o In the complex of oligomers the linear and the cyclic fractions are eliminated, whereby the least preferred fraction is the cyclic trimer. The latter precipitates as the cristal powder with the melting point 316 - 325 °C on the vital parts of the colouring devices, as well. It belongs to those
oligomers, which are water-insoluble. The oligomers remain on the textile as white deposited particles, as they can not be coloured by the dispersion dyes.
Depending on the way of poliester manufacture, different amount of oligomers is eliminated at treatment by different poliester manufacturers. Because of this phenomenon many finishing plants have big problems of economical nature. Such coloured material has to be cleaned, whereby frequent textile cleaning is time-consuming and incomplete, but it is necessary to clean the colouring devices, as well, what causes a big loss of operation time. At the treatment of poliester sometimes so many oligomers are eliminated, that the powder can become a health problem, as well.
The manufacturers of dispersion dyes are trying to solve the problem with oligomers by introducing basic colouring. Hereby there are not enough basicproof dispersion dyes available for simple dye factory substitution of the conventional colour tones on poliester, acquired by the use of dispersion dyes by the acid procedure, with such incomplete palette of the selected basicproof dyes.
The pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with dispersion dyes according to the invention, enables colouring by the conventional acid high-temperature colouring procedure of also such poliester materials, from which large amount of oligomers is eliminated. The method is based
on the pretreatment of poliester textile in basic bath with pH 11.5 - 12.2 at 130°C and the subsequent triple washing in soft hot water. The basic bath is prepared with the appropriate amount of the basics and the corresponding puffer mixtures. Such pretreated poliester is then ready for colouring with dispersion dyes in acid medium, and no problems, connected with the oligomers, were noticed by the colouring.
In the basic bath with pH 11.5 - 12.2 at 130°C large amount of oligomers melts, the surface of poliester is slightly etched, it becomes smoother and gets a nicer gloss. Physical mechanical characteristics are not made worse thereby. In comparison to the characteristics by the blind basic colouring, as the base tear-extension of the poliester textile is increased, by this pretreatment of poliester textile no substantial changes of the tear-strength and the tear- extension were noticed. With the aim to clearly present the effect of the method, described in the corresponding application, the following case is presented.
CASE:
100% poliester textile is used, washed with Teopon K (Teol) at 60°C and at 40°C, twice washed with water of room temperature. After washing the textile was thermofixated for 45 seconds at 190°C.
Such prepared textile was basic pretreated in laboratory colouring device Mathis JFL at bath-ratio 1 :10. For preparation of pretreatment bath
soft water was used. Pretreatment in the bath with 1 g/l of NaOH (pH 12) lasted 30 minutes at 130°C. Then triple washing in boiling soft water followed. Basic pretreated textile was then coloured at 135°C in blind acid bath, which contained 1 ml/l Eganal PS (Hoechst), 2 ml/I Lubit RL (Sybron / Tanatex) and CH3COOH 99-100% (J.T. Baker) up to the bath pH value of 4.5-5. The process of colouring was carried out according to the colouring diagram, which is recommended by DyStar company for colouring with Dianix AD dyes. After colouring the textile was four times washed in 40 °C warm soft water. On such treated textile then the content of oligomers was gravimetrically determined by means of extraction of poliester textile samples with petroleum and with dichlormethane (the method was arranged according to DIN 54278-1).
It was proven, that with 30 minutes basic pretreatment of poliester textile before acid colouring at 135°C, the content of oligomers was reduced by 44% with respect to the textile, coloured by acid colouring procedure at 135°C. The presence of oligomers in the extract was confirmed by means of gel permeable cromatography (GPC) and tetrahydrofurane as eluent. With this method it was found out, that in all extracts the cyclic trimer was mostly present, but the portion of the latter changes according to the way of treatment. In basically treated poliester textile the portion of the cyclic trimer in the extract of oligomers is almost 7 % smaller than in acidly coloured textile at 135°C, as well, what at 44% smaller content of total oligomers means 51.79% less cyclic trimer.
As the proof, that the basic pretreatment before the acid colouring does not influence the change of the colour tone, the colourimetrical values are given, measured on the sample, which was coloured by the acid colouring procedure with 0.4% Dianix Rot AD - 2B and on the sample, which before the acid colouring with 0.4% Dianix Rot AD - 2B was pretreated in the bath of 1 g/l NaOH 100% for 30 minutes at 130 °C. The values are given in CIE L*a*b* colour system:
Front side of the poliester textile: DL* Da* Db* DC* DH* DE* 0.22 0.11 -0.24 0.11 -0.24 0.35
Back side of the poliester textile: DL* Da* Db* DC* DH* DE*
0.29 0.18 -0.14 0.18 -0.14 0.38
The colourimetrical values are the average values of three measurements on light-red coloured poliester textiles. The result DE*<1 means, that our eye does not recognize the change in colour. The values DE* 0.35 and DE* 0.38 are very low, what confirms the same colour. Elimination of oligomers by this method does not influence the change of the colour tone of the poliester textile by acid high-temperature colouring. By means of pretreatment in basic bath the elimination of oligomers by acid colouring at 135°C is reduced by 44%. The reduction as such ensures undisturbed colouring procedure of poliester in acid medium. By
basic colouring the content of oligomers is reduced by 62%, but today there are not enough basically stable dispersion dyes available for its realization. With the described pretreatment and the later acid colouring, poliester gets a nice gloss and a silky touch. The rigidness of such pretreated poliester is in comparison to the conventionally acidly coloured poliester rather reduced, and consequently it gets a softer touch.
Physical mechanical characteristics of the poliester textile do not deteriorate. The method according to the invention is especially recommended for colouring poliester curtains in satin and other types of binding, linings for coats and clothes, poliester textiles for clothes and poliester threads.
Claims
1. The pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with dispersion dyes, characterized in that poliester is treated for 15 to 30 minutes in basic bath with pH 11.5 - 12.2 at 130°C and then three times washed in hot soft water before the conventional acid colouring at temperatures from 130 to 135°C.
. The pretreatment method of poliester for reducing elimination of oligomers at high-temperature acid colouring with dispersion dyes, according to claim 1 , characterized in that the basic bath consists of the amount of basics or puffer mixtures, which is appropriate to pH values from 11.5 to 12.2, and that it is prepared with soft water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2003214792A AU2003214792A1 (en) | 2002-03-25 | 2003-03-24 | PRETREATMENT METHOD OF POLyESTER FOR REDUCING ELIMINATION OF OLIGOMERS AT HIGH-TEMPERATURE ACID COLOURING WITH DISPERSION DYES |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SI200200082A SI21189A (en) | 2002-03-25 | 2002-03-25 | Method of polyester pretreatment for lowering separation of oligomeres in high-temperature acid dying with dispersion dyes |
| SIP-200200082 | 2002-03-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2003080921A1 true WO2003080921A1 (en) | 2003-10-02 |
Family
ID=28450344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/SI2003/000010 WO2003080921A1 (en) | 2002-03-25 | 2003-03-24 | PRETREATMENT METHOD OF POLyESTER FOR REDUCING ELIMINATION OF OLIGOMERS AT HIGH-TEMPERATURE ACID COLOURING WITH DISPERSION DYES |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU2003214792A1 (en) |
| SI (1) | SI21189A (en) |
| WO (1) | WO2003080921A1 (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2828528A (en) * | 1956-12-12 | 1958-04-01 | Du Pont | Finishing polyester fabrics |
| DE1124689B (en) * | 1959-12-18 | 1962-03-01 | Hoechst Ag | Process for improving the surface structure of films and fibers made from linear polyesters |
| US3135577A (en) * | 1959-12-22 | 1964-06-02 | Ici Ltd | Process for improving the handle of polyethylene terephthalate fabrics with an alkali metal hydroxide and specific quaternary ammonium salts |
| US4008044A (en) * | 1975-06-03 | 1977-02-15 | J. P. Stevens & Co., Inc. | Treatment of polyester textiles to improve soil release and wettability properties |
| US4211527A (en) * | 1976-12-14 | 1980-07-08 | Ciba-Geigy Corporation | Process for dyeing polyester materials |
| GB1589020A (en) * | 1977-06-16 | 1981-05-07 | Oeffentiliche Pruefstelle Und | Process for dyeing textile materials incorporating polyester fibres |
| US4294576A (en) * | 1979-06-23 | 1981-10-13 | Basf Aktiengesellschaft | Removal of oligomer deposits from textile materials |
| WO1993006271A1 (en) * | 1991-09-16 | 1993-04-01 | E.I. Du Pont De Nemours And Company | Improvements in and relating to preparing multi-filament yarn |
| JPH1072769A (en) * | 1996-08-22 | 1998-03-17 | Toray Ind Inc | Synthetic fiber fabric and its production |
| EP0843030A1 (en) * | 1995-07-31 | 1998-05-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyester fibers and product of dyeing of fabric made of fiber mixture containing the same |
| US6004357A (en) * | 1997-12-15 | 1999-12-21 | M. Dohmen Gmbh | Process for dyeing textile material having polyester fibers |
-
2002
- 2002-03-25 SI SI200200082A patent/SI21189A/en not_active IP Right Cessation
-
2003
- 2003-03-24 WO PCT/SI2003/000010 patent/WO2003080921A1/en not_active Application Discontinuation
- 2003-03-24 AU AU2003214792A patent/AU2003214792A1/en not_active Abandoned
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2828528A (en) * | 1956-12-12 | 1958-04-01 | Du Pont | Finishing polyester fabrics |
| DE1124689B (en) * | 1959-12-18 | 1962-03-01 | Hoechst Ag | Process for improving the surface structure of films and fibers made from linear polyesters |
| US3135577A (en) * | 1959-12-22 | 1964-06-02 | Ici Ltd | Process for improving the handle of polyethylene terephthalate fabrics with an alkali metal hydroxide and specific quaternary ammonium salts |
| US4008044A (en) * | 1975-06-03 | 1977-02-15 | J. P. Stevens & Co., Inc. | Treatment of polyester textiles to improve soil release and wettability properties |
| US4211527A (en) * | 1976-12-14 | 1980-07-08 | Ciba-Geigy Corporation | Process for dyeing polyester materials |
| GB1589020A (en) * | 1977-06-16 | 1981-05-07 | Oeffentiliche Pruefstelle Und | Process for dyeing textile materials incorporating polyester fibres |
| US4294576A (en) * | 1979-06-23 | 1981-10-13 | Basf Aktiengesellschaft | Removal of oligomer deposits from textile materials |
| WO1993006271A1 (en) * | 1991-09-16 | 1993-04-01 | E.I. Du Pont De Nemours And Company | Improvements in and relating to preparing multi-filament yarn |
| EP0843030A1 (en) * | 1995-07-31 | 1998-05-20 | Asahi Kasei Kogyo Kabushiki Kaisha | Polyester fibers and product of dyeing of fabric made of fiber mixture containing the same |
| JPH1072769A (en) * | 1996-08-22 | 1998-03-17 | Toray Ind Inc | Synthetic fiber fabric and its production |
| US6004357A (en) * | 1997-12-15 | 1999-12-21 | M. Dohmen Gmbh | Process for dyeing textile material having polyester fibers |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Section Ch Week 199821, Derwent World Patents Index; Class A83, AN 1998-234955, XP002250976 * |
Also Published As
| Publication number | Publication date |
|---|---|
| SI21189A (en) | 2003-10-31 |
| AU2003214792A1 (en) | 2003-10-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Deo et al. | Dyeing of cotton and jute with tea as a natural dye | |
| Sheikh et al. | Ultrasound assisted extraction of natural dyes and natural mordants vis a vis dyeing | |
| Jahangiri et al. | Natural dyeing of wool by madder (rubia tinctorum l.) root extract using tannin-based biomordants: Colorimetric, fastness and tensile assay | |
| JP5518081B2 (en) | Dyeing method for blue color development | |
| CN107083695A (en) | Uranidin extracts and its to the method for textile dyeing in a kind of cape jasmine fruit | |
| KR100785087B1 (en) | Dyeing method of protein fiber for developing green color using natural materials | |
| CN107574693B (en) | A kind of post-processing approach of natural dye dying protein fibre fabric | |
| WO2003080921A1 (en) | PRETREATMENT METHOD OF POLyESTER FOR REDUCING ELIMINATION OF OLIGOMERS AT HIGH-TEMPERATURE ACID COLOURING WITH DISPERSION DYES | |
| Gawish et al. | Eco-friendly multifunctional properties of cochineal and weld for simultaneous dyeing and finishing of proteinic fabrics | |
| Avinc et al. | Evaluation of colour fastness and thermal migration in softened polylactic acid fabrics dyed with disperse dyes of differing hydrophobicity | |
| KR101287645B1 (en) | Mixtures of red vat dyes, method for the production thereof and their use for dying material containing hydroxy groups | |
| CN105113287A (en) | Method for dyeing pure cotton fabric by using tea green pigment | |
| Burkinshaw et al. | The dyeing of silk part 2: Aftertreatment with natural and synthetic tanning agents | |
| CN108504132A (en) | One plant tea contaminates the preparation method and colouring method of vegetable colour | |
| Singha | Characterization of dyeing P/C blends fabric: a thermodynamic view | |
| Srivastava | Application of natural dye obtained from peel of black cardamom on silk fabric | |
| CN113136734A (en) | Manufacturing method combining wax printing process and real silk degumming process | |
| Khan et al. | Eco-friendly shades on wool using mixed mordants with Acacia catechu (Cutch) | |
| KR101912653B1 (en) | Natural Dyeing Method Using A Japanese Pagoda Tree | |
| Teli et al. | Development of compound shades of indigo and marigold using natural mordants on cotton and cotton/viscose blend | |
| JP2000192369A (en) | Treatment of yarn and knitted or woven fabric obtained from colored cocoon | |
| KR100447960B1 (en) | Method for dyeing using Amur Cork Tree having good light fastness | |
| Al Mamun et al. | Effects of dyeing parameters on color strength and fastness properties of cotton knitted fabric dyed with direct dyes | |
| Kumaresan | Fastness properties of silk fabric with eco-friendly natural dyes obtained from Achras sapota and Cordia sebestena-A comparison | |
| Agrawal | Modified acid colour dyeing of silk for energy preservation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PH PL PT RO RU SD SE SG SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZM ZW |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| 122 | Ep: pct application non-entry in european phase | ||
| NENP | Non-entry into the national phase |
Ref country code: JP |
|
| WWW | Wipo information: withdrawn in national office |
Country of ref document: JP |