WO2003103971A1 - Substrate for color inkjet printing - Google Patents
Substrate for color inkjet printing Download PDFInfo
- Publication number
- WO2003103971A1 WO2003103971A1 PCT/US2003/011625 US0311625W WO03103971A1 WO 2003103971 A1 WO2003103971 A1 WO 2003103971A1 US 0311625 W US0311625 W US 0311625W WO 03103971 A1 WO03103971 A1 WO 03103971A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- inkjet printing
- copolymer
- substrate
- light fastness
- color
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
Definitions
- This invention relates to color inkjet recording films, and, more particularly to color-receptive films coated with substantially colorless copolymers of vinyl pyrrolidone (VP) and vinyl imidazole (VI), characterized in that the color images obtained exhibit excellent light fastness.
- VP vinyl pyrrolidone
- VI vinyl imidazole
- PVP brings many benefits to properly formulated media coatings including rapid ink dry time, excellent print quality, highly resolved circular dots, and high, uniform optical density. Furthermore, copolymers of vinylpyrrolidone (VP) along with other suitable comonomers, such as dimethylaminoethyl methacrylamide (DMAPMA), acrylic acid, or vinyl acetate, have been used separately or in conjunction with PVP, to further optimize performance. However, it is desired also to provide long-term, excellent water-resistant qualities for such films.
- DMAPMA dimethylaminoethyl methacrylamide
- VP/VI copolymers e.g. BASF's LUVITEC ® (90:10 to 30:70 wt/wt) are yellow in color. When coated onto a white polyester film for digital printing inkjet (DPI) applications, these copolymers leave a yellow cast on the printed film.
- DPI digital printing inkjet
- What is described herein is a method of digital inkjet printing in which a substrate is coated with a substantially colorless, 90-10 to 30-70, wt/wt, copolymer of vinyl pyrrolidone (VP) and vinyl imidazole (VI) uncrosslinked or crosslinked, followed by inkjet printing dye images on the thus-coated substrate, characterized in that the dye images obtained exhibit excellent light fastness.
- VP vinyl pyrrolidone
- VI vinyl imidazole
- the copolymer has an APHA color rating of ⁇ 125, most preferably ⁇ 50, which indicates that it is substantially colorless; and the copolymer has a VP/VI monomer weight ratio of about 50/50; and still more preferably, the light fastness of dye images obtained on the coated film extends for at least one year.
- crude VI was flash distilled under vacuum to a color level of only 12.4.
- copolymers of this purified VI and VP e.g. 50/50 wt/wt
- VP e.g. 50/50 wt/wt
- this purified copolymer of 50/50 wt/wt VP/VI gave excellent light fastness.
- a comparative film with commercial VP/VI showed unacceptable light fastness.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE60324432T DE60324432D1 (en) | 2002-06-05 | 2003-04-15 | INK-JET PRINTING |
EP03757251A EP1531996B1 (en) | 2002-06-05 | 2003-04-15 | Method for ink-jet printing |
AU2003226399A AU2003226399A1 (en) | 2002-06-05 | 2003-04-15 | Substrate for color inkjet printing |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/162,839 | 2002-06-05 | ||
US10/162,839 US6641259B1 (en) | 2002-06-05 | 2002-06-05 | Substrate for color inkjet printing |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003103971A1 true WO2003103971A1 (en) | 2003-12-18 |
Family
ID=29269873
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/011625 WO2003103971A1 (en) | 2002-06-05 | 2003-04-15 | Substrate for color inkjet printing |
Country Status (6)
Country | Link |
---|---|
US (1) | US6641259B1 (en) |
EP (1) | EP1531996B1 (en) |
AT (1) | ATE412530T1 (en) |
AU (1) | AU2003226399A1 (en) |
DE (1) | DE60324432D1 (en) |
WO (1) | WO2003103971A1 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008055245A2 (en) | 2006-10-31 | 2008-05-08 | Sensient Colors Inc. | Inks comprising modified pigments and methods for making and using the same |
KR101575913B1 (en) | 2007-08-23 | 2015-12-08 | 센션트 컬러스 인크. | Self-dispersed pigments and methods for making and using the same |
CN102858886A (en) | 2009-04-07 | 2013-01-02 | 森馨颜色有限责任公司 | Self-dispersing particles and methods for making and using the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4585724A (en) * | 1983-11-25 | 1986-04-29 | Agfa Gevaert Aktiengesellschaft | Image receptor layer comprising polyvinyl imidazole and cationic polymer |
US6391995B2 (en) * | 2000-02-09 | 2002-05-21 | Reilly Industries, Inc. | Polymer compositions useful as dye complexing agents, and processes for preparing same |
US6431700B1 (en) * | 2000-11-10 | 2002-08-13 | Eastman Kodak Company | Ink jet printing method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1127706B2 (en) * | 2000-02-22 | 2013-10-02 | Agfa Graphics N.V. | Ink jet recording material |
-
2002
- 2002-06-05 US US10/162,839 patent/US6641259B1/en not_active Expired - Lifetime
-
2003
- 2003-04-15 WO PCT/US2003/011625 patent/WO2003103971A1/en not_active Application Discontinuation
- 2003-04-15 AT AT03757251T patent/ATE412530T1/en not_active IP Right Cessation
- 2003-04-15 DE DE60324432T patent/DE60324432D1/en not_active Expired - Lifetime
- 2003-04-15 AU AU2003226399A patent/AU2003226399A1/en not_active Abandoned
- 2003-04-15 EP EP03757251A patent/EP1531996B1/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4585724A (en) * | 1983-11-25 | 1986-04-29 | Agfa Gevaert Aktiengesellschaft | Image receptor layer comprising polyvinyl imidazole and cationic polymer |
US6391995B2 (en) * | 2000-02-09 | 2002-05-21 | Reilly Industries, Inc. | Polymer compositions useful as dye complexing agents, and processes for preparing same |
US6431700B1 (en) * | 2000-11-10 | 2002-08-13 | Eastman Kodak Company | Ink jet printing method |
Also Published As
Publication number | Publication date |
---|---|
DE60324432D1 (en) | 2008-12-11 |
EP1531996B1 (en) | 2008-10-29 |
EP1531996A4 (en) | 2007-08-15 |
US6641259B1 (en) | 2003-11-04 |
ATE412530T1 (en) | 2008-11-15 |
AU2003226399A1 (en) | 2003-12-22 |
EP1531996A1 (en) | 2005-05-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6857733B2 (en) | Ink jet printing with uniform gloss | |
EP0738608B1 (en) | Curable compositions and their use for the formation of a printing material | |
JPH04263985A (en) | Transparent liquid absorbing material for ink receiving layer | |
KR101568783B1 (en) | High definition printing with waterborne inks on non-porous substrates | |
WO2001091999A1 (en) | Glossy ink jet medium | |
US20050249894A1 (en) | Water soluble polymers as inkjet recording materials | |
US6641259B1 (en) | Substrate for color inkjet printing | |
US6806310B2 (en) | Coated substrates for computer printers | |
EP2322354A1 (en) | Inkjet accepting agent for oily pigment ink, inkjet recording medium for oily pigment ink and printed article | |
EP0952005A1 (en) | Inkjet-printing sheet | |
US6620521B1 (en) | Water-resistant color inkjet receptive films | |
EP1177104B1 (en) | Inkjet receptor medium having a multi-staged ink migration inhibitor | |
JP2000141873A (en) | Coating liquid for ink recording layer to be formed on metal surface | |
US20030040573A1 (en) | Resin composition for recording sheets | |
JPH107828A (en) | Recording sheet | |
US6514600B1 (en) | Color inkjet receptive films having long term light stability | |
JPH04249156A (en) | Improved electric corrosion printing plate | |
JPH11321073A (en) | Manufacture of recording material for ink jet printer | |
JP2007130776A (en) | Inkjet material to be recorded | |
JP2002011946A (en) | Ink jet printing method | |
JPH10138632A (en) | Image receiving medium for ink jet printing | |
JPH0473710B2 (en) | ||
JP4566467B2 (en) | Inkjet recording sheet | |
KR100370466B1 (en) | Film for inkjet printer | |
JP2000015925A (en) | Resin composition for ink jet recording material and ink jet recording material |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2003757251 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 2003757251 Country of ref document: EP |
|
NENP | Non-entry into the national phase |
Ref country code: JP |
|
WWW | Wipo information: withdrawn in national office |
Country of ref document: JP |