WO2004006360A3 - Coated lithium electrodes - Google Patents

Coated lithium electrodes Download PDF

Info

Publication number
WO2004006360A3
WO2004006360A3 PCT/US2003/020473 US0320473W WO2004006360A3 WO 2004006360 A3 WO2004006360 A3 WO 2004006360A3 US 0320473 W US0320473 W US 0320473W WO 2004006360 A3 WO2004006360 A3 WO 2004006360A3
Authority
WO
WIPO (PCT)
Prior art keywords
lithium
ternary alloy
anode
alloy layer
electrochemical cell
Prior art date
Application number
PCT/US2003/020473
Other languages
French (fr)
Other versions
WO2004006360A2 (en
Inventor
Yevgeniy S Nimon
May-Ying Chu
Steven J Visco
Original Assignee
Polyplus Battery Co Inc
Yevgeniy S Nimon
May-Ying Chu
Steven J Visco
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polyplus Battery Co Inc, Yevgeniy S Nimon, May-Ying Chu, Steven J Visco filed Critical Polyplus Battery Co Inc
Priority to AU2003245745A priority Critical patent/AU2003245745A1/en
Publication of WO2004006360A2 publication Critical patent/WO2004006360A2/en
Publication of WO2004006360A3 publication Critical patent/WO2004006360A3/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H01M4/0495—Chemical alloying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0569—Liquid materials characterised by the solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0404—Methods of deposition of the material by coating on electrode collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0421—Methods of deposition of the material involving vapour deposition
    • H01M4/0423—Physical vapour deposition
    • H01M4/0426—Sputtering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386—Silicon or alloys based on silicon
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/387—Tin or alloys based on tin
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/40—Alloys based on alkali metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

Batteries including a lithium anode stabilized with a metal-lithium alloy and battery cells comprising such anodes are provided. In one embodiment, an electrochemical cell having an anode and a sulfur electrode including at least one of elemental sulfur, lithium sulfide, and a lithium polysulfide is provided. The anode includes a lithium core and a ternary alloy layer over the lithium core where the ternary alloy comprises lithium and two other metals. The ternary alloy layer is effective to increase cycle life and storageability of the electrochemical cell. In a more particular embodiment, the ternary alloy layer is comprised of lithium, copper and tin.
PCT/US2003/020473 2002-07-03 2003-06-27 Coated lithium electrodes WO2004006360A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003245745A AU2003245745A1 (en) 2002-07-03 2003-06-27 Coated lithium electrodes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/189,881 US6955866B2 (en) 1998-09-03 2002-07-03 Coated lithium electrodes
US10/189,881 2002-07-03

Publications (2)

Publication Number Publication Date
WO2004006360A2 WO2004006360A2 (en) 2004-01-15
WO2004006360A3 true WO2004006360A3 (en) 2004-03-11

Family

ID=30114039

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/020473 WO2004006360A2 (en) 2002-07-03 2003-06-27 Coated lithium electrodes

Country Status (3)

Country Link
US (1) US6955866B2 (en)
AU (1) AU2003245745A1 (en)
WO (1) WO2004006360A2 (en)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6911280B1 (en) * 2001-12-21 2005-06-28 Polyplus Battery Company Chemical protection of a lithium surface
DE10219423A1 (en) * 2002-05-02 2003-11-20 Varta Microbattery Gmbh Process for the production of a galvanic element
US7282302B2 (en) 2002-10-15 2007-10-16 Polyplus Battery Company Ionically conductive composites for protection of active metal anodes
US7645543B2 (en) 2002-10-15 2010-01-12 Polyplus Battery Company Active metal/aqueous electrochemical cells and systems
US20080057386A1 (en) 2002-10-15 2008-03-06 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
KR20050070053A (en) * 2002-10-15 2005-07-05 폴리플러스 배터리 컴퍼니 Ionically conductive composites for protection of active metal anodes
US7390591B2 (en) 2002-10-15 2008-06-24 Polyplus Battery Company Ionically conductive membranes for protection of active metal anodes and battery cells
US7189477B2 (en) * 2003-04-10 2007-03-13 Sion Power Corporation Low temperature electrochemical cells
US7482096B2 (en) * 2003-06-04 2009-01-27 Polyplus Battery Company Alleviation of voltage delay in lithium-liquid depolarizer/electrolyte solvent battery cells
US20040253510A1 (en) * 2003-06-04 2004-12-16 Polyplus Battery Company Aliovalent protective layers for active metal anodes
KR100522694B1 (en) * 2003-08-23 2005-10-19 삼성에스디아이 주식회사 Lithium-sulfur battery
US7608178B2 (en) * 2003-11-10 2009-10-27 Polyplus Battery Company Active metal electrolyzer
US7491458B2 (en) 2003-11-10 2009-02-17 Polyplus Battery Company Active metal fuel cells
KR100953543B1 (en) * 2003-12-01 2010-04-21 삼성에스디아이 주식회사 Lithium anode, process for preparing the same and lithium battery using the same
US10629947B2 (en) 2008-08-05 2020-04-21 Sion Power Corporation Electrochemical cell
US7282295B2 (en) * 2004-02-06 2007-10-16 Polyplus Battery Company Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
US9368775B2 (en) 2004-02-06 2016-06-14 Polyplus Battery Company Protected lithium electrodes having porous ceramic separators, including an integrated structure of porous and dense Li ion conducting garnet solid electrolyte layers
US10566669B2 (en) * 2004-02-20 2020-02-18 Johnson Ip Holding, Llc Lithium oxygen batteries having a carbon cloth current collector and method of producing same
WO2007011899A2 (en) 2005-07-15 2007-01-25 Cymbet Corporation Thin-film batteries with polymer and lipon electrolyte layers and method
US7776478B2 (en) 2005-07-15 2010-08-17 Cymbet Corporation Thin-film batteries with polymer and LiPON electrolyte layers and method
US20070111099A1 (en) * 2005-11-15 2007-05-17 Nanjundaswamy Kirakodu S Primary lithium ion electrochemical cells
WO2007062220A2 (en) 2005-11-23 2007-05-31 Polyplus Battery Company Li/air non-aqueous batteries
US8182943B2 (en) 2005-12-19 2012-05-22 Polyplus Battery Company Composite solid electrolyte for protection of active metal anodes
EP2087540A4 (en) * 2006-10-13 2014-01-22 Ceramatec Inc Advanced metal-air battery having a ceramic membrane electrolyte
CN101542818A (en) 2006-11-14 2009-09-23 皇家飞利浦电子股份有限公司 Electrochemical energy source with a cathodic electrode comprising at least one non-oxidic active species and electric device comprising such an electrochemical energy source
US8332028B2 (en) * 2006-11-28 2012-12-11 Polyplus Battery Company Protected lithium electrodes for electro-transport drug delivery
US20080318128A1 (en) * 2007-06-22 2008-12-25 Sion Power Corporation Lithium alloy/sulfur batteries
US8323820B2 (en) 2008-06-16 2012-12-04 Polyplus Battery Company Catholytes for aqueous lithium/air battery cells
US20090005824A1 (en) * 2007-06-29 2009-01-01 Polyplus Battery Company Electrotransport devices, methods and drug electrode assemblies
US8771879B2 (en) 2007-09-05 2014-07-08 Ceramatec, Inc. Lithium—sulfur battery with a substantially non-porous lisicon membrane and porous lisicon layer
US20090069740A1 (en) * 2007-09-07 2009-03-12 Polyplus Battery Company Protected donor electrodes for electro-transport drug delivery
US8012621B2 (en) 2007-11-26 2011-09-06 Ceramatec, Inc. Nickel-metal hydride battery using alkali ion conducting separator
US9209445B2 (en) 2007-11-26 2015-12-08 Ceramatec, Inc. Nickel-metal hydride/hydrogen hybrid battery using alkali ion conducting separator
US8088270B2 (en) * 2007-11-27 2012-01-03 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
US8216722B2 (en) 2007-11-27 2012-07-10 Ceramatec, Inc. Solid electrolyte for alkali-metal-ion batteries
US10320033B2 (en) 2008-01-30 2019-06-11 Enlighten Innovations Inc. Alkali metal ion battery using alkali metal conductive ceramic separator
US20090189567A1 (en) * 2008-01-30 2009-07-30 Joshi Ashok V Zinc Anode Battery Using Alkali Ion Conducting Separator
US8323817B2 (en) * 2008-09-12 2012-12-04 Ceramatec, Inc. Alkali metal seawater battery
US9475998B2 (en) 2008-10-09 2016-10-25 Ceramatec, Inc. Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
WO2010107833A2 (en) * 2009-03-16 2010-09-23 Ceramatec, Inc. Sodium-sulfur battery with a substantially non-porous membrane and enhanced cathode utilization
DK2497133T3 (en) 2009-11-05 2019-04-08 Field Upgrading Usa Inc SODIUM BASED SOLID SECONDARY CELL WITH A CERAMIC SODIUM CONDUCTIVE SEPARATOR
US8771855B2 (en) 2010-08-11 2014-07-08 Ceramatec, Inc. Alkali metal aqueous battery
US10170798B2 (en) 2010-12-01 2019-01-01 Field Upgrading Usa, Inc. Moderate temperature sodium battery
KR101826990B1 (en) 2011-06-07 2018-02-07 현대자동차주식회사 Lithium sulfur battery
JP6228915B2 (en) 2011-06-17 2017-11-08 シオン・パワー・コーポレーション Electrode plating technology
US9853325B2 (en) 2011-06-29 2017-12-26 Space Charge, LLC Rugged, gel-free, lithium-free, high energy density solid-state electrochemical energy storage devices
US11527774B2 (en) 2011-06-29 2022-12-13 Space Charge, LLC Electrochemical energy storage devices
US10601074B2 (en) 2011-06-29 2020-03-24 Space Charge, LLC Rugged, gel-free, lithium-free, high energy density solid-state electrochemical energy storage devices
US10658705B2 (en) 2018-03-07 2020-05-19 Space Charge, LLC Thin-film solid-state energy storage devices
WO2013003846A2 (en) * 2011-06-30 2013-01-03 The Regents Of The University Of California Surface insulated porous current collectors as dendrite free electrodeposition electrodes
CN102881862B (en) 2011-07-12 2015-03-25 中国科学院上海硅酸盐研究所 Protective metal anode structure and preparation method thereof
WO2013028574A2 (en) 2011-08-19 2013-02-28 Polyplus Battery Company Aqueous lithium air batteries
JP6118805B2 (en) 2011-10-13 2017-04-19 シオン・パワー・コーポレーション Electrode structure and manufacturing method thereof
US9660265B2 (en) 2011-11-15 2017-05-23 Polyplus Battery Company Lithium sulfur batteries and electrolytes and sulfur cathodes thereof
US8828574B2 (en) 2011-11-15 2014-09-09 Polyplus Battery Company Electrolyte compositions for aqueous electrolyte lithium sulfur batteries
US8828575B2 (en) 2011-11-15 2014-09-09 PolyPlus Batter Company Aqueous electrolyte lithium sulfur batteries
US8828573B2 (en) 2011-11-15 2014-09-09 Polyplus Battery Company Electrode structures for aqueous electrolyte lithium sulfur batteries
KR102059396B1 (en) * 2012-01-13 2019-12-26 알베마를 저머니 게엠베하 Stabilized lithium metal impressions coated with alloy-forming elements and method for production thereof
US8932771B2 (en) 2012-05-03 2015-01-13 Polyplus Battery Company Cathode architectures for alkali metal / oxygen batteries
US8673493B2 (en) 2012-05-29 2014-03-18 Toyota Motor Engineering & Manufacturing North America, Inc. Indium-tin binary anodes for rechargeable magnesium-ion batteries
US8647770B2 (en) 2012-05-30 2014-02-11 Toyota Motor Engineering & Manufacturing North America, Inc. Bismuth-tin binary anodes for rechargeable magnesium-ion batteries
US10854929B2 (en) 2012-09-06 2020-12-01 Field Upgrading Usa, Inc. Sodium-halogen secondary cell
DE102012018622A1 (en) 2012-09-14 2014-03-20 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Li-S battery with high cycle stability and method of operation
JP2014096326A (en) * 2012-11-12 2014-05-22 Toyota Industries Corp Negative electrode active material for secondary cell, and negative electrode and secondary cell using the same
US11888149B2 (en) 2013-03-21 2024-01-30 University Of Maryland Solid state battery system usable at high temperatures and methods of use and manufacture thereof
US9905860B2 (en) 2013-06-28 2018-02-27 Polyplus Battery Company Water activated battery system having enhanced start-up behavior
FR3017248B1 (en) * 2014-01-31 2016-03-04 Commissariat Energie Atomique METHOD FOR REGENERATING THE CAPACITY OF A LITHIUM ELECTROCHEMICAL ACCUMULATOR, ACCUMULATOR BOX AND ACCUMULATOR THEREFOR
KR102027825B1 (en) 2014-02-06 2019-10-02 겔리온 테크놀로지스 피티와이 리미티드 Gelated ionic liquid film-coated surfaces and uses thereof
DE102014208228A1 (en) * 2014-04-30 2015-11-05 Robert Bosch Gmbh Galvanic element and method for its production
KR102570455B1 (en) 2014-09-23 2023-08-23 어플라이드 머티어리얼스, 인코포레이티드 Electrochemical cell with protected negative electrode
US20180233742A1 (en) 2014-10-08 2018-08-16 Wayne State University Electrocatalysis of lithium polysulfides: current collectors as electrodes in li/s battery configuration
US9837653B2 (en) 2015-02-24 2017-12-05 Nissan North America, Inc. Two compartment lithium sulfur cell and assembly method
CN107925052A (en) 2015-06-22 2018-04-17 阿卜杜拉国王科技大学 The manufacture method of lithium battery, anode and anode
US10130302B2 (en) 2016-06-29 2018-11-20 International Business Machines Corporation Via and trench filling using injection molded soldering
SG11201901797RA (en) 2016-09-13 2019-03-28 Nat Univ Singapore Solid electrolyte
EP3535796B1 (en) * 2016-11-07 2022-06-15 University of Maryland, College Park Lithium solid state electrolyte interface treatment
KR20200121827A (en) 2018-02-15 2020-10-26 유니버시티 오브 매릴랜드, 칼리지 파크 Aligned porous solid electrolyte structure, electrochemical device including same, and method of manufacturing same
CN108493402B (en) * 2018-04-12 2021-04-02 太原科技大学 Method for preparing lithium-sulfur battery positive plate by ion beam sputtering technology
KR102207527B1 (en) * 2018-05-14 2021-01-25 주식회사 엘지화학 Anode comprising electrode protective layer and lithium secondary battery comprising the same
CN109659539B (en) * 2018-12-20 2022-07-15 电子科技大学 Method for preparing lithium battery cathode material based on in-situ compounding and recombination
CN109402589A (en) * 2019-01-02 2019-03-01 重庆天齐锂业有限责任公司 A kind of magnetron sputtering prepares the method and system of super thin metal lithium film
CN111430720B (en) * 2019-01-10 2021-07-13 国家能源投资集团有限责任公司 Electrode protection layer and preparation method thereof, electrode and lithium battery
US11569527B2 (en) 2019-03-26 2023-01-31 University Of Maryland, College Park Lithium battery
CN110048116A (en) * 2019-04-25 2019-07-23 电子科技大学 A kind of lithium band/foil and preparation method thereof having good stability in air
US11335899B2 (en) * 2019-04-29 2022-05-17 International Business Machines Corporation Lithium ion energy storage device containing a vapor deposited iodine interfacial layer
US11342561B2 (en) 2019-10-25 2022-05-24 Lyten, Inc. Protective polymeric lattices for lithium anodes in lithium-sulfur batteries
US11398622B2 (en) 2019-10-25 2022-07-26 Lyten, Inc. Protective layer including tin fluoride disposed on a lithium anode in a lithium-sulfur battery
JP7401317B2 (en) * 2020-01-21 2023-12-19 本田技研工業株式会社 solid state battery
US11367895B1 (en) 2021-07-23 2022-06-21 Lyten, Inc. Solid-state electrolyte for lithium-sulfur batteries
US11404692B1 (en) 2021-07-23 2022-08-02 Lyten, Inc. Lithium-sulfur battery cathode formed from multiple carbonaceous regions
KR102447011B1 (en) 2021-03-15 2022-09-23 주식회사 비츠로셀 Electrode for lithium secondary battery having encapsulated active materials and method of manufacturing the same
US11670826B2 (en) 2021-07-23 2023-06-06 Lyten, Inc. Length-wise welded electrodes incorporated in cylindrical cell format lithium-sulfur batteries
US11600876B2 (en) 2021-07-23 2023-03-07 Lyten, Inc. Wound cylindrical lithium-sulfur battery including electrically-conductive carbonaceous materials

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4820599A (en) * 1987-05-18 1989-04-11 Sanyo Electric Co., Ltd. Non-aqueous electrolyte type secondary cell
US5814420A (en) * 1994-11-23 1998-09-29 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US6165644A (en) * 1994-11-23 2000-12-26 Polyplus Battery Company, Inc. Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries
WO2002041416A2 (en) * 2000-11-15 2002-05-23 Polyplus Battery Company Coated lithium electrodes
WO2003023879A2 (en) * 2001-09-10 2003-03-20 Polyplus Battery Company Encapsulated alloy electrodes

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3404035A (en) * 1965-10-22 1968-10-01 Ford Motor Co Secondary battery employing molten alkali metal reactant
US3413150A (en) * 1966-09-28 1968-11-26 Ford Motor Co Battery having a molten alkali metal anode and a molten sulfur cathode
US3532543A (en) * 1968-02-21 1970-10-06 Aerojet General Co Battery employing lithium - sulphur electrodes with non-aqueous electrolyte
US3907591A (en) * 1971-12-30 1975-09-23 Varta Ag Positive sulphur electrode for galvanic cells and method of producing the same
DE2334660A1 (en) * 1973-07-07 1975-01-23 Varta Batterie ELECTRIC ACCUMULATOR WITH NEGATIVE LITHIUM ELECTRODE
US3953231A (en) * 1975-04-25 1976-04-27 General Electric Company Sealed lithium-solid sulfur cell
US4002492A (en) * 1975-07-01 1977-01-11 Exxon Research And Engineering Company Rechargeable lithium-aluminum anode
US4268587A (en) * 1977-10-11 1981-05-19 General Electric Company Solid state, ambient temperature electrochemical cell
US4143214A (en) * 1978-06-26 1979-03-06 Exxon Research & Engineering Co. Cells having cathodes containing Cs S cathode-active materials
IL61085A (en) * 1980-09-19 1983-07-31 Univ Ramot Nonaqueous sulfur cell
US4469761A (en) * 1980-11-26 1984-09-04 Diamond Shamrock Corporation Rechargeable lithium/sulfur ammoniate battery
US4386019A (en) * 1981-07-29 1983-05-31 The United States Of America As Represented By The United States Department Of Energy Method of making electrodes for electrochemical cell
US4436796A (en) * 1981-07-30 1984-03-13 The United States Of America As Represented By The United States Department Of Energy All-solid electrodes with mixed conductor matrix
US4481267A (en) 1983-04-01 1984-11-06 Duracell Inc. Insoluble heavy metal polysulfide cathodes
US4784927A (en) * 1983-10-03 1988-11-15 Whittaker Corporation Electrochemical cell using iodine monochloride
US4784925A (en) * 1983-10-03 1988-11-15 Whittaker Corporation Primary electrochemical cell containing molecular iodine
US4644911A (en) * 1983-10-07 1987-02-24 Honda Giken Kogyo Kabushiki Kaisha Cylinder block for internal combustion engine
US4889779A (en) * 1985-09-16 1989-12-26 Amoco Corporation Lithium-sulfur dioxide electrochemical cell with an iodine-catalyzed cathode
US4883048A (en) * 1986-10-03 1989-11-28 Purnell Mark L Apparatus and method for use in performing a surgical operation
FR2615328A1 (en) 1987-05-12 1988-11-18 Bridgestone Corp ELECTRIC CELL AND MANUFACTURING METHOD
US4833048A (en) 1988-03-31 1989-05-23 The United States Of America As Represented By The United States Department Of Energy Metal-sulfur type cell having improved positive electrode
US4917974A (en) * 1989-04-14 1990-04-17 The United States Of America As Represented By The Department Of Energy Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same
US5162175A (en) * 1989-10-13 1992-11-10 Visco Steven J Cell for making secondary batteries
US5441831A (en) 1992-12-17 1995-08-15 Associated Universities, Inc. Cells having cathodes containing polycarbon disulfide materials
DE4243211A1 (en) 1992-12-19 1994-06-23 Abb Patent Gmbh Electrochemical storage cell
JPH06275313A (en) 1993-03-22 1994-09-30 Matsushita Electric Ind Co Ltd Lithium battery
US5648187A (en) * 1994-02-16 1997-07-15 Moltech Corporation Stabilized anode for lithium-polymer batteries
EP1339116A3 (en) * 1994-05-30 2005-03-23 Canon Kabushiki Kaisha Rechargeable lithium battery
JP3717085B2 (en) * 1994-10-21 2005-11-16 キヤノン株式会社 Negative electrode for secondary battery, secondary battery having the negative electrode, and method for producing electrode
US6025094A (en) * 1994-11-23 2000-02-15 Polyplus Battery Company, Inc. Protective coatings for negative electrodes
US5523179A (en) * 1994-11-23 1996-06-04 Polyplus Battery Company Rechargeable positive electrode
US5686201A (en) * 1994-11-23 1997-11-11 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US6030720A (en) * 1994-11-23 2000-02-29 Polyplus Battery Co., Inc. Liquid electrolyte lithium-sulfur batteries
US6358643B1 (en) * 1994-11-23 2002-03-19 Polyplus Battery Company Liquid electrolyte lithium-sulfur batteries
US5582623A (en) * 1994-11-23 1996-12-10 Polyplus Battery Company, Inc. Methods of fabricating rechargeable positive electrodes
US5529860A (en) * 1995-06-07 1996-06-25 Moltech Corporation Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same
US6165544A (en) * 1998-01-09 2000-12-26 Noda Screen Co., Ltd. Method of exposure of photo-curing resin applied to printed circuit board
US6402795B1 (en) * 1998-02-18 2002-06-11 Polyplus Battery Company, Inc. Plating metal negative electrodes under protective coatings
US6200704B1 (en) * 1998-09-01 2001-03-13 Polyplus Battery Company, Inc. High capacity/high discharge rate rechargeable positive electrode
US6225002B1 (en) * 1999-02-05 2001-05-01 Polyplus Battery Company, Inc. Dioxolane as a proctector for lithium electrodes
US6733924B1 (en) * 1999-11-23 2004-05-11 Moltech Corporation Lithium anodes for electrochemical cells
US6632573B1 (en) * 2001-02-20 2003-10-14 Polyplus Battery Company Electrolytes with strong oxidizing additives for lithium/sulfur batteries

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4820599A (en) * 1987-05-18 1989-04-11 Sanyo Electric Co., Ltd. Non-aqueous electrolyte type secondary cell
US5814420A (en) * 1994-11-23 1998-09-29 Polyplus Battery Company, Inc. Rechargeable positive electrodes
US6165644A (en) * 1994-11-23 2000-12-26 Polyplus Battery Company, Inc. Methods and reagents for enhancing the cycling efficiency of lithium polymer batteries
WO2002041416A2 (en) * 2000-11-15 2002-05-23 Polyplus Battery Company Coated lithium electrodes
WO2003023879A2 (en) * 2001-09-10 2003-03-20 Polyplus Battery Company Encapsulated alloy electrodes

Also Published As

Publication number Publication date
AU2003245745A8 (en) 2004-01-23
US20020182508A1 (en) 2002-12-05
WO2004006360A2 (en) 2004-01-15
AU2003245745A1 (en) 2004-01-23
US6955866B2 (en) 2005-10-18

Similar Documents

Publication Publication Date Title
WO2004006360A3 (en) Coated lithium electrodes
WO2002041416A3 (en) Coated lithium electrodes
WO2005069409A3 (en) Electrolytes for lithium sulfur cells
WO2007111895A3 (en) Rechargeable lithium/water, lithium/air batteries
EP1052718A4 (en) Lithium storage battery
WO2003069700A3 (en) Flexible thin printed battery with gelled electrolyte and method of manufacturing same
WO2005069404A3 (en) Electrolytes for lithium sulfur cells
WO2005069405A3 (en) Methods of charging lithium sulfur cells
WO2008013853A3 (en) Lithium-iron disulfide cylindrical cell with modified positive electrode
WO2007092102A3 (en) Lithium-ion batteries with intrinsic pulse overcharge protection
WO2005031908A3 (en) Electrochemical battery cell
WO2001047088A3 (en) Methods of charging lithium-sulfur batteries
WO2006026773A3 (en) Battery with molten salt electrolyte and high voltage positive active material
ATE467245T1 (en) ELECTROLYTES FOR ELECTROCHEMICAL LITHIUM-SULFUR CELLS
WO2001080329A3 (en) Lithium electrochemical cells with enhanced cycle life
WO1999063607A9 (en) Electrochemical power cells and method of improving electrochemical power cell performance
EP2204869A3 (en) Electrolyte additive for non-aqueous electrochemical cells
WO2005053067A3 (en) High discharge capacity lithium battery
EP1875548A4 (en) LITHIUM RECHARGEABLE CELL HAVING AN EXCESS OF LiFePO4 BASED CATHODE RELATIVE TO A Li4Ti5O12 BASED ANODE
WO2006035426A3 (en) Improved lithium cell and method of forming same
CN208489305U (en) A kind of solid lithium battery being made of hybrid solid-state electrolyte
EP0874410A3 (en) Non-aqueous electrolyte secondary batteries
ATE373322T1 (en) NON-AQUEOUS ELECTROCHEMICAL CELL
JPH09270273A (en) Polysulfide, carbon electrode material, and association method
HK1066325A1 (en) Electrochemical cell comprising carbonaceous material and molybdenum carbide as anode

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase