WO2004007562A3 - Spray-dried polymerization catalyst and polymerization processes employing same - Google Patents

Spray-dried polymerization catalyst and polymerization processes employing same Download PDF

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Publication number
WO2004007562A3
WO2004007562A3 PCT/US2003/022070 US0322070W WO2004007562A3 WO 2004007562 A3 WO2004007562 A3 WO 2004007562A3 US 0322070 W US0322070 W US 0322070W WO 2004007562 A3 WO2004007562 A3 WO 2004007562A3
Authority
WO
WIPO (PCT)
Prior art keywords
spray
dried
processes employing
polymerization
employing same
Prior art date
Application number
PCT/US2003/022070
Other languages
French (fr)
Other versions
WO2004007562A2 (en
Inventor
Burkhard Eric Wagner
Robert James Jorgensen
Mark Wilton Smale
Original Assignee
Dow Global Technologies Inc
Burkhard Eric Wagner
Robert James Jorgensen
Mark Wilton Smale
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale filed Critical Dow Global Technologies Inc
Priority to BR0312900-4A priority Critical patent/BR0312900A/en
Priority to CA002491318A priority patent/CA2491318A1/en
Priority to EP03764669A priority patent/EP1539834B1/en
Priority to DE60326469T priority patent/DE60326469D1/en
Priority to AU2003251916A priority patent/AU2003251916B2/en
Publication of WO2004007562A2 publication Critical patent/WO2004007562A2/en
Publication of WO2004007562A3 publication Critical patent/WO2004007562A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

A spray-dried composition comprising an inert porous filler and a reaction product of 1) a mixture or reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound. The filler is substantially spherical and has an average particle size ranging from 1 μm to 12μm. Methods of making spray-dried compositions, catalysts, and polymerization processes employing such compositions are also described.
PCT/US2003/022070 2002-07-15 2003-07-15 Spray-dried polymerization catalyst and polymerization processes employing same WO2004007562A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR0312900-4A BR0312900A (en) 2002-07-15 2003-07-15 Spray-dried polymerization catalyst, method for preparing it and method of polymerization employing it
CA002491318A CA2491318A1 (en) 2002-07-15 2003-07-15 Spray-dried polymerization catalyst and polymerization processes employing same
EP03764669A EP1539834B1 (en) 2002-07-15 2003-07-15 Spray-dried polymerization catalyst and polymerization processes employing same
DE60326469T DE60326469D1 (en) 2002-07-15 2003-07-15 SPRAY DRY POLYMERIZATION CATALYST AND POLYMERIZATION PROCESS UNDER USE
AU2003251916A AU2003251916B2 (en) 2002-07-15 2003-07-15 Method for preparing a spray-dried composition for use as a polymerization catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/196,663 2002-07-15
US10/196,663 US6806221B2 (en) 2002-07-15 2002-07-15 Method for preparing a spray-dried composition for use as a polymerization catalyst

Publications (2)

Publication Number Publication Date
WO2004007562A2 WO2004007562A2 (en) 2004-01-22
WO2004007562A3 true WO2004007562A3 (en) 2004-04-15

Family

ID=30115098

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/022070 WO2004007562A2 (en) 2002-07-15 2003-07-15 Spray-dried polymerization catalyst and polymerization processes employing same

Country Status (10)

Country Link
US (2) US6806221B2 (en)
EP (1) EP1539834B1 (en)
CN (1) CN100368440C (en)
AT (1) ATE424423T1 (en)
AU (1) AU2003251916B2 (en)
BR (1) BR0312900A (en)
CA (1) CA2491318A1 (en)
DE (1) DE60326469D1 (en)
ES (1) ES2320120T3 (en)
WO (1) WO2004007562A2 (en)

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CA2516693A1 (en) * 2003-02-24 2004-09-02 China Petroleum & Chemical Corporation Complex support suitable for propylene polymerization catalyst, a catalyst component and catalyst containing the same
AR049966A1 (en) 2004-07-07 2006-09-20 Dow Global Technologies Inc PROCESS OF MULTIPLE STAGES TO PRODUCE COMPOSITIONS OF ETHYLENE POLYMER
WO2006020623A1 (en) * 2004-08-09 2006-02-23 Union Carbide Chemicals & Plastics Technology Corporation Robust spray-dried ziegler-natta procatalyst and polymerization process employing same
MX2007001644A (en) * 2004-08-09 2007-04-23 Union Carbide Chem Plastic Robust spray-dried ziegler-natta procatalyst and polymerization process employing same.
WO2009094427A1 (en) 2008-01-23 2009-07-30 Bristol-Myers Squibb Company 4-pyridinone compounds and their use for cancer
ES2605277T3 (en) * 2008-08-06 2017-03-13 Union Carbide Chemicals & Plastics Technology Llc Methods of obtaining ziegler-natta catalyst compositions to produce polyethylenes with a high molecular weight glue
CN101554595B (en) 2009-05-18 2011-02-02 中国石油化工股份有限公司 Catalyst support used for olefinic polymerization as well as preparation method and application thereof
CN102050894B (en) * 2009-10-30 2013-02-27 中国石油化工股份有限公司 Catalyst used for vinyl polymerization
EP2539376B1 (en) * 2010-04-05 2014-11-05 Dow Global Technologies LLC Process for polymerizing olefin-based polymers containing high molecular weight fractions in condensed and super-condensed mode
CN102492062B (en) * 2011-11-11 2014-03-26 上海立得催化剂有限公司 Preparation method for self-forming vinyl polymerization catalyst granules
US10787553B2 (en) 2011-12-19 2020-09-29 Dow Global Technologies Llc Polyethylene composition and articles made therefrom
DE102012003232A1 (en) 2012-02-20 2013-08-22 Clariant Produkte (Deutschland) Gmbh Post-gold plating of Pd-Au-coated shell catalysts
JP2016507542A (en) * 2013-02-08 2016-03-10 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Production of inorganic / organic composites by reactive spray drying
KR102223548B1 (en) * 2013-06-29 2021-03-05 다우 글로벌 테크놀로지스 엘엘씨 A polyethylene composition and process for polymerizing the same
CN104761665B (en) * 2014-04-18 2018-03-02 陈伟 A kind of ethene gas-phase polymerization or copolymerization catalyst composition and preparation method thereof
CN106467587B (en) * 2015-08-18 2019-01-18 中国石油天然气股份有限公司 The preparation method of the catalyst of polyethylene is prepared for vinyl polymerization
EP3484932A1 (en) 2016-07-15 2019-05-22 Basell Poliolefine Italia S.r.l. Catalyst for the polymerization of olefins
BR112020008992A2 (en) * 2017-12-05 2020-11-17 Univation Technologies, Llc modified spray dried ziegler-natta (pro) catalyst systems
CN111040054A (en) * 2018-10-15 2020-04-21 中国石油化工股份有限公司 Catalyst component for olefin polymerization, preparation method, catalyst and application thereof
CN113563496B (en) 2020-04-28 2023-05-09 中国石油化工股份有限公司 Catalyst component for olefin polymerization or copolymerization, preparation method and application thereof

Citations (5)

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Publication number Priority date Publication date Assignee Title
US4293673A (en) * 1978-12-28 1981-10-06 Union Carbide Corporation Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization
EP0584626A2 (en) * 1992-08-10 1994-03-02 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content
EP0878490A2 (en) * 1997-05-16 1998-11-18 Phillips Petroleum Company Olefin polymerization processes and products thereof
US20020035228A1 (en) * 1997-10-14 2002-03-21 Phillips Petroleum Company Olefin polymerization processes and products thereof
WO2002046246A2 (en) * 2000-12-04 2002-06-13 Univaton Technologies, Llc Polimerization process

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NL177314C (en) 1974-04-08 1985-09-02 Mitsubishi Chem Ind METHOD FOR PREPARING A CATALYST COMPLEX, AND METHOD FOR POLYMERIZING AN OLEYLENE WITH THIS CATALYST
US4302566A (en) 1978-03-31 1981-11-24 Union Carbide Corporation Preparation of ethylene copolymers in fluid bed reactor
US4684703A (en) 1979-02-27 1987-08-04 Union Carbide Corporation Polymerization catalyst for ethylene homopolymerization
EP0019312B1 (en) 1979-04-30 1983-08-17 Shell Internationale Researchmaatschappij B.V. Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
CA1141093A (en) 1979-05-17 1983-02-08 Brian L. Goodall Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions
JPS56811A (en) 1979-06-18 1981-01-07 Mitsui Petrochem Ind Ltd Preparation of olefin polymer or copolymer
US4482687A (en) 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
US4540679A (en) 1984-03-23 1985-09-10 Amoco Corporation Magnesium hydrocarbyl carbonate supports
US4612299A (en) 1984-07-09 1986-09-16 Amoco Corporation Magnesium carboxylate supports
US5567665A (en) 1994-03-31 1996-10-22 Union Carbide Chemicals & Plastics Technology Corporation Shape-shifted magnesium alkoxide component for polymerizing olefins
US4728705A (en) * 1986-02-28 1988-03-01 Shell Oil Company Olefin polymerization catalyst composition
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Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
US4293673A (en) * 1978-12-28 1981-10-06 Union Carbide Corporation Spheroidal polymerization catalyst, process for preparing, and use for ethylene polymerization
EP0584626A2 (en) * 1992-08-10 1994-03-02 Union Carbide Chemicals & Plastics Technology Corporation Process for producing ethylene polymers having reduced hexane extractable content
EP0878490A2 (en) * 1997-05-16 1998-11-18 Phillips Petroleum Company Olefin polymerization processes and products thereof
US20020035228A1 (en) * 1997-10-14 2002-03-21 Phillips Petroleum Company Olefin polymerization processes and products thereof
WO2002046246A2 (en) * 2000-12-04 2002-06-13 Univaton Technologies, Llc Polimerization process

Also Published As

Publication number Publication date
US7160833B2 (en) 2007-01-09
EP1539834B1 (en) 2009-03-04
ATE424423T1 (en) 2009-03-15
CN1668654A (en) 2005-09-14
CN100368440C (en) 2008-02-13
BR0312900A (en) 2005-05-10
US6806221B2 (en) 2004-10-19
DE60326469D1 (en) 2009-04-16
US20040259723A1 (en) 2004-12-23
AU2003251916B2 (en) 2007-08-02
US20040010100A1 (en) 2004-01-15
EP1539834A2 (en) 2005-06-15
CA2491318A1 (en) 2004-01-22
ES2320120T3 (en) 2009-05-19
AU2003251916A1 (en) 2004-02-02
WO2004007562A2 (en) 2004-01-22

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