WO2004033605A3 - Synergistic organoborate compositions and lubricating compositions containing same - Google Patents

Synergistic organoborate compositions and lubricating compositions containing same Download PDF

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Publication number
WO2004033605A3
WO2004033605A3 PCT/US2003/031725 US0331725W WO2004033605A3 WO 2004033605 A3 WO2004033605 A3 WO 2004033605A3 US 0331725 W US0331725 W US 0331725W WO 2004033605 A3 WO2004033605 A3 WO 2004033605A3
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WO
WIPO (PCT)
Prior art keywords
compositions
synergistic
organoborate
sulfur
containing same
Prior art date
Application number
PCT/US2003/031725
Other languages
French (fr)
Other versions
WO2004033605A2 (en
Inventor
Thomas J Karol
Steven G Donnelly
Original Assignee
Vanderbilt Co R T
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vanderbilt Co R T filed Critical Vanderbilt Co R T
Priority to AU2003282730A priority Critical patent/AU2003282730A1/en
Priority to CN2003801008068A priority patent/CN1852969B/en
Priority to JP2004543455A priority patent/JP4296153B2/en
Priority to MXPA05002664A priority patent/MXPA05002664A/en
Priority to AT03774614T priority patent/ATE548437T1/en
Priority to BRPI0315029-1A priority patent/BR0315029B1/en
Priority to EP03774614A priority patent/EP1573839B1/en
Priority to CA2495199A priority patent/CA2495199C/en
Publication of WO2004033605A2 publication Critical patent/WO2004033605A2/en
Publication of WO2004033605A3 publication Critical patent/WO2004033605A3/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/18Complexes with metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/12Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic compound containing atoms of elements not provided for in groups C10M141/02 - C10M141/10
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • C10M2203/1065Naphthenic fractions used as base material
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/021Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066Thiocarbamic type compounds
    • C10M2219/068Thiocarbamate metal salts
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron
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    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061Esters derived from boron
    • C10M2227/062Cyclic esters
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/09Complexes with metals
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/06Groups 3 or 13
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/08Groups 4 or 14
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/10Groups 5 or 15
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/12Groups 6 or 16
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/14Group 7
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/16Groups 8, 9, or 10
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/40Low content or no content compositions
    • C10N2030/42Phosphor free or low phosphor content compositions

Abstract

An additive for imparting antiwear properties to a lubricant composition is based on a combination of (1) an organo borate ester composition and (2) one or more sulfur-or phosphorus-containing compounds or a non-sulfur molybdenum compound. The sulfur-or phosphorus-containing compounds are dithiocarbamate, bisditiocarbamate, 1,3,4-diathiazole, phosphoroditioate, phosphoroditioate esters, and the molybdenum compound is prepared by reacting (a) about 1.0 mole of fatty oil having 12 or more atoms (b), about 1.0 to 2.5 moles diethanolamine and (c) a molybdenum source.
PCT/US2003/031725 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same WO2004033605A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AU2003282730A AU2003282730A1 (en) 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same
CN2003801008068A CN1852969B (en) 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same
JP2004543455A JP4296153B2 (en) 2002-10-04 2003-10-02 Synergistic organic borate composition and lubricating composition containing the same
MXPA05002664A MXPA05002664A (en) 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same.
AT03774614T ATE548437T1 (en) 2002-10-04 2003-10-02 SYNERGISTIC ORGANOBORATE COMPOSITIONS AND LUBRICANT COMPOSITIONS THEREFROM
BRPI0315029-1A BR0315029B1 (en) 2002-10-04 2003-10-02 Lubricating composition
EP03774614A EP1573839B1 (en) 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same
CA2495199A CA2495199C (en) 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US41606102P 2002-10-04 2002-10-04
US60/416,061 2002-10-04

Publications (2)

Publication Number Publication Date
WO2004033605A2 WO2004033605A2 (en) 2004-04-22
WO2004033605A3 true WO2004033605A3 (en) 2005-09-22

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/031725 WO2004033605A2 (en) 2002-10-04 2003-10-02 Synergistic organoborate compositions and lubricating compositions containing same

Country Status (10)

Country Link
US (2) US7598211B2 (en)
EP (5) EP2302023B1 (en)
JP (1) JP4296153B2 (en)
CN (1) CN1852969B (en)
AT (1) ATE548437T1 (en)
AU (1) AU2003282730A1 (en)
BR (1) BR0315029B1 (en)
CA (1) CA2495199C (en)
MX (1) MXPA05002664A (en)
WO (1) WO2004033605A2 (en)

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ATE548437T1 (en) * 2002-10-04 2012-03-15 Vanderbilt Co R T SYNERGISTIC ORGANOBORATE COMPOSITIONS AND LUBRICANT COMPOSITIONS THEREFROM
JP2005320441A (en) * 2004-05-10 2005-11-17 Japan Energy Corp Ultra-low sulfur content engine oil
US7648948B2 (en) 2005-04-08 2010-01-19 Exxonmobil Chemical Patents Inc. Additive system for lubricants
US8507417B2 (en) 2006-03-07 2013-08-13 Exxonmobil Research And Engineering Company Organomolybdenum-boron additives
US20080171677A1 (en) * 2006-04-13 2008-07-17 Buck William H Low SAP engine lubricant additive and composition containing non-corrosive sulfur and organic borates
JP5460310B2 (en) * 2006-04-26 2014-04-02 ヴァンダービルト ケミカルズ、エルエルシー Antioxidant synergist for lubricating compositions
US20080182770A1 (en) * 2007-01-26 2008-07-31 The Lubrizol Corporation Antiwear Agent and Lubricating Compositions Thereof
JP5380453B2 (en) * 2007-09-26 2014-01-08 ザ ルブリゾル コーポレイション Titanium compounds and titanium complexes as additives in lubricants
US9018149B2 (en) * 2010-05-12 2015-04-28 Exxonmobil Research And Engineering Company Method for reducing one or more of deposits and friction of a lubricating oil
FR2961823B1 (en) * 2010-06-25 2013-06-14 Total Raffinage Marketing LUBRICATING COMPOSITIONS FOR AUTOMOTIVE TRANSMISSIONS
CN102031185B (en) * 2010-12-30 2013-03-13 鞍山海华油脂化学有限公司 Anti micro-pitting industrial gear oil composition
CN102161928A (en) * 2011-03-16 2011-08-24 陈岩 Matched lubricating oil special for printing equipment
CN102199470B (en) * 2011-04-18 2013-03-20 天津市澳路浦润滑油有限公司 Storage lubricating grease and method for preparing same
WO2012165106A1 (en) * 2011-05-27 2012-12-06 Jx日鉱日石エネルギー株式会社 Additive for lubricating oils and lubricating oil composition
CN102250671B (en) * 2011-06-22 2013-06-05 中国石油化工股份有限公司 Wide temperature range and high extreme pressure composite lithium lubricating grease composition
CN102311819B (en) * 2011-08-18 2014-03-26 西安嘉宏石化科技有限公司 Nitrogen-containing organic boric acid ester diesel oil lubricating additive and preparation method thereof
CN102585984B (en) * 2011-12-14 2013-06-12 大连海事大学 Lubricating grease for metallurgy roll bearing and preparing method thereof
US9222050B1 (en) * 2012-02-29 2015-12-29 Rand Innovations, Llc Lubricant composition, method of preparing the same, and firearm cleaner including the same
EP2826847B1 (en) * 2012-03-12 2020-01-08 Idemitsu Kosan Co., Ltd Lubricating oil composition
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