WO2004046214A3 - Multiple catalyst system for olefin polymerization and polymers produced therefrom - Google Patents

Multiple catalyst system for olefin polymerization and polymers produced therefrom Download PDF

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Publication number
WO2004046214A3
WO2004046214A3 PCT/US2003/032910 US0332910W WO2004046214A3 WO 2004046214 A3 WO2004046214 A3 WO 2004046214A3 US 0332910 W US0332910 W US 0332910W WO 2004046214 A3 WO2004046214 A3 WO 2004046214A3
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WO
WIPO (PCT)
Prior art keywords
polymer
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catalyst
olefins
catalyst system
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PCT/US2003/032910
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French (fr)
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WO2004046214A2 (en
Inventor
Peijun Jiang
Armenag Dekmezian
Jo Ann M Canich
Charles L Sims
Ramin Abhari
Cesar A Garcia-Franco
David R Johnsrud
Original Assignee
Exxonmobil Chem Patents Inc
Peijun Jiang
Armenag Dekmezian
Jo Ann M Canich
Charles L Sims
Ramin Abhari
Cesar A Garcia-Franco
David R Johnsrud
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Application filed by Exxonmobil Chem Patents Inc, Peijun Jiang, Armenag Dekmezian, Jo Ann M Canich, Charles L Sims, Ramin Abhari, Cesar A Garcia-Franco, David R Johnsrud filed Critical Exxonmobil Chem Patents Inc
Priority to JP2004570359A priority Critical patent/JP4972284B2/en
Priority to KR20057006479A priority patent/KR101113341B1/en
Priority to EP20030811599 priority patent/EP1558655B1/en
Priority to ES03811599T priority patent/ES2394304T3/en
Priority to CA 2499951 priority patent/CA2499951C/en
Priority to AU2003302033A priority patent/AU2003302033A1/en
Publication of WO2004046214A2 publication Critical patent/WO2004046214A2/en
Publication of WO2004046214A3 publication Critical patent/WO2004046214A3/en

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    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/10—Homopolymers or copolymers of propene
    • C09J123/12—Polypropene
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    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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    • C08F210/06—Propene
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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    • C09J2423/00—Presence of polyolefin
    • C09J2423/006—Presence of polyolefin in the substrate
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    • C09J2423/00—Presence of polyolefin
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Abstract

This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ehtylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g') of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less and to a continuous process to produce a branched olefin polymer comprising 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100°C; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.
PCT/US2003/032910 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom WO2004046214A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2004570359A JP4972284B2 (en) 2002-10-15 2003-10-15 Multiple catalyst systems for olefin polymerization and polymers produced therefrom
KR20057006479A KR101113341B1 (en) 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom
EP20030811599 EP1558655B1 (en) 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom
ES03811599T ES2394304T3 (en) 2002-10-15 2003-10-15 Multiple catalyst system for the polymerization of olefins and polymers produced from them
CA 2499951 CA2499951C (en) 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom
AU2003302033A AU2003302033A1 (en) 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US41848202P 2002-10-15 2002-10-15
US60/418,482 2002-10-15
US46071403P 2003-04-04 2003-04-04
US60/460,714 2003-04-04

Publications (2)

Publication Number Publication Date
WO2004046214A2 WO2004046214A2 (en) 2004-06-03
WO2004046214A3 true WO2004046214A3 (en) 2004-08-05

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Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2003/033163 WO2005108442A1 (en) 2002-10-15 2003-10-15 Polyolefin adhesive compositions and articles made therefrom
PCT/US2003/032910 WO2004046214A2 (en) 2002-10-15 2003-10-15 Multiple catalyst system for olefin polymerization and polymers produced therefrom

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Application Number Title Priority Date Filing Date
PCT/US2003/033163 WO2005108442A1 (en) 2002-10-15 2003-10-15 Polyolefin adhesive compositions and articles made therefrom

Country Status (10)

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US (6) US7294681B2 (en)
EP (3) EP2261292B1 (en)
JP (1) JP4972284B2 (en)
KR (1) KR101113341B1 (en)
CN (2) CN101838362B (en)
AU (2) AU2003304716A1 (en)
BR (1) BR0315341B1 (en)
CA (1) CA2499951C (en)
ES (1) ES2394304T3 (en)
WO (2) WO2005108442A1 (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7989670B2 (en) 2005-07-19 2011-08-02 Exxonmobil Chemical Patents Inc. Process to produce high viscosity fluids
US8071835B2 (en) 2006-07-19 2011-12-06 Exxonmobil Chemical Patents Inc. Process to produce polyolefins using metallocene catalysts
US8071687B2 (en) 2002-10-15 2011-12-06 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US8207390B2 (en) 2005-07-19 2012-06-26 Exxonmobil Chemical Patents Inc. Process to produce low viscosity poly-alpha-olefins
US8530712B2 (en) 2009-12-24 2013-09-10 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
US8710143B2 (en) 2004-03-17 2014-04-29 Dow Global Technologies Llc Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
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