WO2004058395A3 - Platinum-ruthenium containing catalyst formulations for hydrogen generation - Google Patents

Platinum-ruthenium containing catalyst formulations for hydrogen generation Download PDF

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Publication number
WO2004058395A3
WO2004058395A3 PCT/US2003/040944 US0340944W WO2004058395A3 WO 2004058395 A3 WO2004058395 A3 WO 2004058395A3 US 0340944 W US0340944 W US 0340944W WO 2004058395 A3 WO2004058395 A3 WO 2004058395A3
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WO
WIPO (PCT)
Prior art keywords
oxides
mixtures
disclosed
catalyst
hydrogen
Prior art date
Application number
PCT/US2003/040944
Other languages
French (fr)
Other versions
WO2004058395A2 (en
Inventor
Alfred Hagemeyer
Raymond F Carhart
Karin Yaccato
Peter Strasser
Robert K Grasselli
Christopher James Brooks
Cory Bernard Phillips
Original Assignee
Honda Motor Co Ltd
Symyx Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honda Motor Co Ltd, Symyx Technologies Inc filed Critical Honda Motor Co Ltd
Priority to CA002510656A priority Critical patent/CA2510656A1/en
Priority to EP03808536A priority patent/EP1572353A2/en
Priority to JP2004563954A priority patent/JP2006511431A/en
Priority to AU2003303385A priority patent/AU2003303385A1/en
Publication of WO2004058395A2 publication Critical patent/WO2004058395A2/en
Publication of WO2004058395A3 publication Critical patent/WO2004058395A3/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
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    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
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    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668—Removal of carbon monoxide or carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A method and catalysts for producing a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas contacts a water gas shift (WGS) catalyst, optionally in the presence of water, preferably at a temperature of less than about 450°C to produce a hydrogen-rich gas, such as a hydrogen-rich syngas. Also disclosed is a water gas shift catalyst formulated from: a) Pt, its oxides or mixtures thereof; b) Ru, its oxides or mixtures thereof; and c) at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Co, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu. Another disclosed catalyst formulation comprises Pt, its oxides or mixtures thereof; Ru, its oxides or mixtures thereof; Co, its oxides or mixtures thereof; and at least one of Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Sc, Y, Ti, Zr, V, Mo, Mn, Fe, Rh, Ir, Ge, Sn, Sb, La, Ce, Pr, Sm, and Eu, their oxides and mixtures thereof. The WGS catalyst may be supported on a carrier, such as any one member or a combination of alumina, zirconia, titania, ceria, magnesia, lanthania, niobia, zeolite, perovskite, silica clay, yttria and iron oxide. Fuel processors containing such water gas shift catalysts are also disclosed.
PCT/US2003/040944 2002-12-20 2003-12-18 Platinum-ruthenium containing catalyst formulations for hydrogen generation WO2004058395A2 (en)

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CA002510656A CA2510656A1 (en) 2002-12-20 2003-12-18 Platinum-ruthenium containing catalyst formulations for hydrogen generation
EP03808536A EP1572353A2 (en) 2002-12-20 2003-12-18 Platinum-ruthenium containing catalyst formulations for hydrogen generation
JP2004563954A JP2006511431A (en) 2002-12-20 2003-12-18 Catalyst composition for hydrogen generation containing platinum-ruthenium
AU2003303385A AU2003303385A1 (en) 2002-12-20 2003-12-18 Platinum-ruthenium containing catalyst formulations for hydrogen generation

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