WO2004058630A3 - Process and apparatus for hydrogen purification - Google Patents
Process and apparatus for hydrogen purification Download PDFInfo
- Publication number
- WO2004058630A3 WO2004058630A3 PCT/US2003/040797 US0340797W WO2004058630A3 WO 2004058630 A3 WO2004058630 A3 WO 2004058630A3 US 0340797 W US0340797 W US 0340797W WO 2004058630 A3 WO2004058630 A3 WO 2004058630A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- region
- adsorbent
- adsorbents
- impurities
- hydrogen purification
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28052—Several layers of identical or different sorbents stacked in a housing, e.g. in a column
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/502—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
- B01D2257/7022—Aliphatic hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40003—Methods relating to valve switching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40013—Pressurization
- B01D2259/40018—Pressurization with more than three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/4002—Production
- B01D2259/40024—Production with three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40035—Equalization
- B01D2259/40037—Equalization with two sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40075—More than ten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/404—Further details for adsorption processes and devices using four beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/41—Further details for adsorption processes and devices using plural beds of the same adsorbent in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/414—Further details for adsorption processes and devices using different types of adsorbents
- B01D2259/4141—Further details for adsorption processes and devices using different types of adsorbents within a single bed
- B01D2259/4145—Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
- B01D2259/4146—Contiguous multilayered adsorbents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/047—Composition of the impurity the impurity being carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0495—Composition of the impurity the impurity being water
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/146—At least two purification steps in series
- C01B2203/147—Three or more purification steps in series
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
Abstract
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03800049.3A EP1590079B1 (en) | 2002-12-24 | 2003-12-22 | Process and apparatus for hydrogen purification |
CA002511660A CA2511660A1 (en) | 2002-12-24 | 2003-12-22 | Process and apparatus for hydrogen purification |
AU2003299775A AU2003299775A1 (en) | 2002-12-24 | 2003-12-22 | Process and apparatus for hydrogen purification |
US10/540,506 US7537742B2 (en) | 2002-12-24 | 2003-12-22 | Process and adsorbent for hydrogen purification |
ES03800049.3T ES2455992T3 (en) | 2002-12-24 | 2003-12-22 | Procedure and apparatus for hydrogen purification |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US43631402P | 2002-12-24 | 2002-12-24 | |
US60/436,314 | 2002-12-24 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2004058630A2 WO2004058630A2 (en) | 2004-07-15 |
WO2004058630A3 true WO2004058630A3 (en) | 2005-01-27 |
Family
ID=32682374
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2003/040797 WO2004058630A2 (en) | 2002-12-24 | 2003-12-22 | Process and apparatus for hydrogen purification |
Country Status (7)
Country | Link |
---|---|
US (1) | US7537742B2 (en) |
EP (1) | EP1590079B1 (en) |
CN (1) | CN100581645C (en) |
AU (1) | AU2003299775A1 (en) |
CA (1) | CA2511660A1 (en) |
ES (1) | ES2455992T3 (en) |
WO (1) | WO2004058630A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102834159A (en) * | 2009-03-25 | 2012-12-19 | 普莱克斯技术有限公司 | Cyclic adsorption control method and controller |
CN102834159B (en) * | 2009-03-25 | 2016-11-30 | 普莱克斯技术有限公司 | Cyclic adsorption control method and controller |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2003299775A1 (en) | 2002-12-24 | 2004-07-22 | Praxair Technology, Inc. | Process and apparatus for hydrogen purification |
US7276107B2 (en) | 2003-12-23 | 2007-10-02 | Praxair Technology, Inc. | Indexing rotary dual valve for pressure swing adsorption systems |
US7399341B2 (en) * | 2005-04-26 | 2008-07-15 | Uop Llc | Gas purification process |
DE102006008194A1 (en) * | 2006-02-22 | 2007-08-23 | Linde Ag | Adsorptive decomposition of a hydrogen-containing gas mixture comprises introducing the gas mixture over an adsorption bed, having an active charcoal layer and a downstream molecular sieve layer and removing a hydrogen rich gas mixture |
US7695545B2 (en) | 2007-03-14 | 2010-04-13 | Air Products And Chemicals, Inc. | Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration |
NZ553992A (en) * | 2007-03-20 | 2008-10-31 | Flotech Holdings Ltd | Biogas treatments for increasing the methane concentration |
FR2913969B1 (en) * | 2007-03-22 | 2010-02-19 | Air Liquide | ECRATMENT OF IMPURITY PICS |
KR100896455B1 (en) * | 2007-07-09 | 2009-05-14 | 한국에너지기술연구원 | Pressure swing adsorption apparatus and method for hydrogen purification using the same |
US7803215B2 (en) * | 2007-12-12 | 2010-09-28 | Uop Llc | Adsorber for pretreatment of natural gas containing bulk hydrogen sulfide |
JP5314408B2 (en) * | 2008-03-06 | 2013-10-16 | 株式会社神戸製鋼所 | PSA equipment for high-purity hydrogen gas production |
CN101723325B (en) * | 2008-10-29 | 2011-09-21 | 中国石油化工股份有限公司 | Method for recovering low-concentration hydrogen |
WO2011025091A1 (en) * | 2009-08-27 | 2011-03-03 | 주식회사 케이씨씨 | Method for refining high purity hydrogen |
US8388736B2 (en) | 2009-10-02 | 2013-03-05 | Perkinelmer Health Sciences, Inc. | Sorbent devices and methods of using them |
EP2316792A1 (en) * | 2009-10-27 | 2011-05-04 | Ammonia Casale S.A. | Ammonia production process |
US8241401B2 (en) | 2010-11-02 | 2012-08-14 | Mitsubishi Polycrystalline Silicon America Corporation (MIPSA) | Apparatus and method for producing purified hydrogen gas by a pressure swing adsorption processes |
US8496733B2 (en) | 2011-01-11 | 2013-07-30 | Praxair Technology, Inc. | Large scale pressure swing adsorption systems having process cycles operating in normal and turndown modes |
US8435328B2 (en) | 2011-01-11 | 2013-05-07 | Praxair Technology, Inc. | Ten bed pressure swing adsorption process operating in normal and turndown modes |
US8551217B2 (en) | 2011-01-11 | 2013-10-08 | Praxair Technology, Inc. | Six bed pressure swing adsorption process operating in normal and turndown modes |
US8491704B2 (en) | 2011-01-11 | 2013-07-23 | Praxair Technology, Inc. | Six bed pressure swing adsorption process operating in normal and turndown modes |
CN103373707B (en) * | 2012-04-18 | 2015-05-20 | 扬光绿能股份有限公司 | Hydrogen purification device |
FR3005873B1 (en) * | 2013-05-27 | 2015-05-15 | Air Liquide | PURIFICATION UNIT WITH MULTI-BED ADSORBER |
CA2859254A1 (en) * | 2013-08-13 | 2015-02-13 | James M. Tour | Low cost carbon materials for the capture of co2 and h2s from various environments |
US9381460B2 (en) | 2014-09-11 | 2016-07-05 | Air Products And Chemicals, Inc. | Pressure swing adsorption process |
EP2823872A3 (en) | 2014-09-11 | 2015-05-06 | Air Products And Chemicals, Inc. | Pressure swing adsorption process |
US10232342B2 (en) | 2015-07-01 | 2019-03-19 | William Marsh Rice University | Method, synthesis, activation procedure and characterization of an oxygen rich activated porous carbon sorbent for selective removal of carbon dioxide with ultra high capacity |
EP3349878B1 (en) | 2015-09-16 | 2023-11-08 | Uop Llc | Pressure swing adsorption process and apparatus for purifying a hydrogen-containing gas stream |
WO2018026517A1 (en) * | 2016-08-04 | 2018-02-08 | Exxonmobil Research And Engineering Company | Increasing scales, capacities, and/or efficiencies in swing adsorption processes with hydrocarbon gas feeds |
KR102391642B1 (en) * | 2016-09-26 | 2022-04-27 | 스미토모 세이카 가부시키가이샤 | Hydrogen or helium purification method and hydrogen or helium purification apparatus |
CN109748242B (en) * | 2017-11-03 | 2022-09-16 | 中国科学院大连化学物理研究所 | Adsorbent for efficient purification of hydrogen |
KR101987804B1 (en) * | 2017-11-17 | 2019-06-12 | 한국에너지기술연구원 | Pressure swing adsorption method and pressure swing adsorption apparatus |
US10882744B2 (en) * | 2018-11-15 | 2021-01-05 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Purification of hydrogen |
US11731075B2 (en) * | 2020-08-10 | 2023-08-22 | Praxair Technology, Inc. | High recovery process for purification of multicomponent gases |
US11571652B2 (en) * | 2021-06-22 | 2023-02-07 | Praxair Technology, Inc. | Method of purifying hydrogen supplied from a storage cavern |
US11904297B1 (en) | 2023-01-11 | 2024-02-20 | Iliad Ip Company, Llc | Process for manufacturing lithium selective adsorption/separation media |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4176090A (en) * | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
US5856264A (en) * | 1994-05-04 | 1999-01-05 | Uop | Adsorbent for use in double glazed windows |
US20020183201A1 (en) * | 2001-05-01 | 2002-12-05 | Barnwell James W. | Adsorbents for use in regenerable adsorbent fractionators and methods of making the same |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3430418A (en) * | 1967-08-09 | 1969-03-04 | Union Carbide Corp | Selective adsorption process |
US3564816A (en) * | 1968-12-30 | 1971-02-23 | Union Carbide Corp | Selective adsorption process |
US4077779A (en) * | 1976-10-15 | 1978-03-07 | Air Products And Chemicals, Inc. | Hydrogen purification by selective adsorption |
US4499208A (en) * | 1983-05-13 | 1985-02-12 | Union Carbide Corporation | Activated carbon adsorbent with increased heat capacity and the production thereof |
US4553981A (en) * | 1984-02-07 | 1985-11-19 | Union Carbide Corporation | Enhanced hydrogen recovery from effluent gas streams |
US4859217A (en) * | 1987-06-30 | 1989-08-22 | Uop | Process for separating nitrogen from mixtures thereof with less polar substances |
US4957514A (en) * | 1989-02-07 | 1990-09-18 | Air Products And Chemicals, Inc. | Hydrogen purification |
US5174979A (en) * | 1989-10-06 | 1992-12-29 | Uop | Mixed ion-exchanged zeolites and processes for the use thereof in gas separations |
US5152975A (en) * | 1991-03-15 | 1992-10-06 | Texaco Inc. | Process for producing high purity hydrogen |
CA2100811C (en) * | 1992-08-19 | 1999-01-19 | Akhilesh Kapoor | Hydrogen and carbon monoxide production by partial oxidation of hydrocarbon feed |
US5454857A (en) * | 1994-03-18 | 1995-10-03 | Uop | Air separation process |
US5698013A (en) * | 1994-03-18 | 1997-12-16 | Uop | Nitrogen-selective zeolitic adsorbent for use in air separation process |
US5674311A (en) * | 1995-10-20 | 1997-10-07 | Praxair Technology, Inc. | Adsorption process and system using multilayer adsorbent beds |
FR2749004B1 (en) * | 1996-05-24 | 1998-07-10 | Air Liquide | PROCESS FOR THE PURIFICATION OF HYDROGEN-BASED GASEOUS MIXTURES USING LITHIUM-EXCHANGED X ZEOLITE |
US6027548A (en) * | 1996-12-12 | 2000-02-22 | Praxair Technology, Inc. | PSA apparatus and process using adsorbent mixtures |
US6152991A (en) * | 1997-04-17 | 2000-11-28 | Praxair Technology, Inc. | Multilayer adsorbent beds for PSA gas separation |
US6007606A (en) * | 1997-12-09 | 1999-12-28 | Praxair Technology, Inc. | PSA process and system |
CN1221643A (en) * | 1997-12-09 | 1999-07-07 | 普拉塞尔技术有限公司 | PSA process and system |
US6027549A (en) * | 1998-04-28 | 2000-02-22 | Air Products And Chemicals, Inc. | Adjusted density carbon for hydrogen PSA |
US6197092B1 (en) * | 1999-03-22 | 2001-03-06 | Engelhard Corporation | Selective removal of nitrogen from natural gas by pressure swing adsorption |
US6340382B1 (en) * | 1999-08-13 | 2002-01-22 | Mohamed Safdar Allie Baksh | Pressure swing adsorption process for the production of hydrogen |
US6302943B1 (en) * | 1999-11-02 | 2001-10-16 | Air Products And Chemicals, Inc. | Optimum adsorbents for H2 recovery by pressure and vacuum swing absorption |
FR2804042B1 (en) * | 2000-01-25 | 2002-07-12 | Air Liquide | PROCESS FOR THE PURIFICATION OF A GAS BY ADSORPTION OF IMPURITIES ON SEVERAL ACTIVE COAL |
DE60129626T2 (en) * | 2000-04-20 | 2008-05-21 | Tosoh Corp., Shinnanyo | Process for purifying a gas mixture containing hydrogen |
CN1151957C (en) * | 2000-12-01 | 2004-06-02 | 四川天一科技股份有限公司 | Process for extracting high-purity hydrogen from coke oven gas |
AU2003299775A1 (en) | 2002-12-24 | 2004-07-22 | Praxair Technology, Inc. | Process and apparatus for hydrogen purification |
-
2003
- 2003-12-22 AU AU2003299775A patent/AU2003299775A1/en not_active Abandoned
- 2003-12-22 ES ES03800049.3T patent/ES2455992T3/en not_active Expired - Lifetime
- 2003-12-22 EP EP03800049.3A patent/EP1590079B1/en not_active Expired - Lifetime
- 2003-12-22 CA CA002511660A patent/CA2511660A1/en not_active Abandoned
- 2003-12-22 WO PCT/US2003/040797 patent/WO2004058630A2/en not_active Application Discontinuation
- 2003-12-22 US US10/540,506 patent/US7537742B2/en active Active
- 2003-12-22 CN CN200380109953A patent/CN100581645C/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4176090A (en) * | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
US5856264A (en) * | 1994-05-04 | 1999-01-05 | Uop | Adsorbent for use in double glazed windows |
US20020183201A1 (en) * | 2001-05-01 | 2002-12-05 | Barnwell James W. | Adsorbents for use in regenerable adsorbent fractionators and methods of making the same |
Non-Patent Citations (1)
Title |
---|
See also references of EP1590079A4 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102834159A (en) * | 2009-03-25 | 2012-12-19 | 普莱克斯技术有限公司 | Cyclic adsorption control method and controller |
CN102834159B (en) * | 2009-03-25 | 2016-11-30 | 普莱克斯技术有限公司 | Cyclic adsorption control method and controller |
Also Published As
Publication number | Publication date |
---|---|
CN1758957A (en) | 2006-04-12 |
EP1590079B1 (en) | 2014-03-26 |
EP1590079A2 (en) | 2005-11-02 |
EP1590079A4 (en) | 2008-04-09 |
AU2003299775A8 (en) | 2004-07-22 |
AU2003299775A1 (en) | 2004-07-22 |
WO2004058630A2 (en) | 2004-07-15 |
CN100581645C (en) | 2010-01-20 |
ES2455992T3 (en) | 2014-04-21 |
US20060254425A1 (en) | 2006-11-16 |
CA2511660A1 (en) | 2004-07-15 |
US7537742B2 (en) | 2009-05-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2004058630A3 (en) | Process and apparatus for hydrogen purification | |
MXPA04006077A (en) | Method and apparatus for gas purification. | |
DE60336287D1 (en) | Implementation and optimization of a pressure swing adsorption process | |
DE60318673D1 (en) | Pressure swing adsorption plant for gas separation | |
EP0884087A3 (en) | Pressure swing adsorption process with a single adsorbent bed | |
MXPA02010752A (en) | Syngas purification process. | |
EP0767349A2 (en) | The use of nitrogen from an air separation plant in carbon dioxide removal from a feed gas to a further process | |
DE60116034D1 (en) | Single bed pressure swing adsorption process | |
CA2285801A1 (en) | Method and apparatus for enhancing carbon dioxide recovery | |
CA2315484A1 (en) | Pressure swing adsorption process for the production of hydrogen | |
WO2006052937A3 (en) | Separation of carbon dioxide from other gases | |
CA2091315A1 (en) | Process and apparatus for the purification of water | |
EP0884275A3 (en) | Process and apparatus for producing a gaseous product | |
CA2255526A1 (en) | Psa process and system using simultaneous top and bottom evacuation of adsorbent bed | |
EP0394947A3 (en) | Apparatus for removing carbon dioxide gas and moisture from methane-rich gas mixture | |
EP1097746A3 (en) | Adsorbents for hydrogen recovery by pressure swing adsorption | |
NZ605796A (en) | Method and apparatus for the purification of carbon dioxide using liquid carbon dioxide | |
MY118691A (en) | Process for the removal and high-pressure recovery of carbon dioxide from a high-pressure raw gas and system therefor | |
CA2266547A1 (en) | Carbon monoxide removal | |
JP2006515636A5 (en) | ||
GC0000299A (en) | Process for purifying carbon dioxide-containing gas streams | |
AU5041490A (en) | Method for removal of ammonia from a gas mixture | |
JPH0372566B2 (en) | ||
JP4314015B2 (en) | Portable ultra-high purity acetylene feeder | |
WO2003027581A3 (en) | A process and apparatus for purifying hydrogen bromide |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): BW GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2003800049 Country of ref document: EP Ref document number: 2720/DELNP/2005 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2511660 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 20038A99531 Country of ref document: CN |
|
WWP | Wipo information: published in national office |
Ref document number: 2003800049 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2006254425 Country of ref document: US Ref document number: 10540506 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 10540506 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: JP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: JP |