WO2004058825A3 - Polymers with new sequence distributions - Google Patents

Polymers with new sequence distributions Download PDF

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Publication number
WO2004058825A3
WO2004058825A3 PCT/US2003/040852 US0340852W WO2004058825A3 WO 2004058825 A3 WO2004058825 A3 WO 2004058825A3 US 0340852 W US0340852 W US 0340852W WO 2004058825 A3 WO2004058825 A3 WO 2004058825A3
Authority
WO
WIPO (PCT)
Prior art keywords
new sequence
polymers
sequence distributions
methylstyrene
distributions
Prior art date
Application number
PCT/US2003/040852
Other languages
French (fr)
Other versions
WO2004058825A2 (en
Inventor
David Y Chung
Timothy D Shaffer
Original Assignee
Exxonmobil Chem Patents Inc
David Y Chung
Timothy D Shaffer
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=32686080&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2004058825(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Exxonmobil Chem Patents Inc, David Y Chung, Timothy D Shaffer filed Critical Exxonmobil Chem Patents Inc
Priority to JP2005510040A priority Critical patent/JP4690195B2/en
Priority to EP03814280A priority patent/EP1572763B1/en
Priority to AU2003303342A priority patent/AU2003303342A1/en
Priority to CA2510847A priority patent/CA2510847C/en
Priority to DE60332758T priority patent/DE60332758D1/en
Priority to AT03814280T priority patent/ATE469178T1/en
Priority to US10/539,014 priority patent/US7425601B2/en
Publication of WO2004058825A2 publication Critical patent/WO2004058825A2/en
Publication of WO2004058825A3 publication Critical patent/WO2004058825A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/08Butenes
    • C08F210/10Isobutene
    • C08F210/12Isobutene with conjugated diolefins, e.g. butyl rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/04Polymerisation in solution
    • C08F2/06Organic solvent

Abstract

The invention relates to new polymerization processes including diluents including hydrofluorocarbons and their use to produce novel polymers with new sequence distributions. In particular, the invention relates to copolymers of an isoolefin, preferably isobutylene, and an alkylstyrene, preferably methylstyrene, even more preferably para-methylstyrene, with new sequence distributions. The copolymer may optionally be halogenated.
PCT/US2003/040852 2002-12-20 2003-12-19 Polymers with new sequence distributions WO2004058825A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2005510040A JP4690195B2 (en) 2002-12-20 2003-12-19 Polymer with new sequence distribution
EP03814280A EP1572763B1 (en) 2002-12-20 2003-12-19 Polymers with new sequence distributions
AU2003303342A AU2003303342A1 (en) 2002-12-20 2003-12-19 Polymers with new sequence distributions
CA2510847A CA2510847C (en) 2002-12-20 2003-12-19 Polymers with new sequence distributions
DE60332758T DE60332758D1 (en) 2002-12-20 2003-12-19 POLYMERS WITH NEW SEQUENCE DISTRIBUTIONS
AT03814280T ATE469178T1 (en) 2002-12-20 2003-12-19 POLYMERS WITH NEW SEQUENCE DISTRIBUTIONS
US10/539,014 US7425601B2 (en) 2002-12-20 2003-12-19 Polymers with new sequence distributions

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US43506102P 2002-12-20 2002-12-20
US60/435,061 2002-12-20
US46418703P 2003-04-21 2003-04-21
US60/464,187 2003-04-21
US47908103P 2003-06-17 2003-06-17
US60/479,081 2003-06-17

Publications (2)

Publication Number Publication Date
WO2004058825A2 WO2004058825A2 (en) 2004-07-15
WO2004058825A3 true WO2004058825A3 (en) 2004-09-30

Family

ID=32686080

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/US2003/040852 WO2004058825A2 (en) 2002-12-20 2003-12-19 Polymers with new sequence distributions
PCT/US2003/041221 WO2004067577A2 (en) 2002-12-20 2003-12-19 Polymerization processes
PCT/US2003/040858 WO2004058829A1 (en) 2002-12-20 2003-12-19 Polymerization processes
PCT/US2003/040341 WO2004058835A1 (en) 2002-12-20 2003-12-19 Polymers substantially free of long chain branching

Family Applications After (3)

Application Number Title Priority Date Filing Date
PCT/US2003/041221 WO2004067577A2 (en) 2002-12-20 2003-12-19 Polymerization processes
PCT/US2003/040858 WO2004058829A1 (en) 2002-12-20 2003-12-19 Polymerization processes
PCT/US2003/040341 WO2004058835A1 (en) 2002-12-20 2003-12-19 Polymers substantially free of long chain branching

Country Status (9)

Country Link
US (6) US7423100B2 (en)
EP (5) EP1572766B2 (en)
JP (7) JP5322253B2 (en)
AT (4) ATE469923T1 (en)
AU (5) AU2003301205A1 (en)
CA (5) CA2510864C (en)
DE (4) DE60332866D1 (en)
RU (1) RU2341538C2 (en)
WO (4) WO2004058825A2 (en)

Families Citing this family (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7714043B2 (en) 2000-10-18 2010-05-11 Exxonmobil Chemical Patents Inc. Tire innerliners having improved cold temperature properties
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US7425601B2 (en) * 2002-12-20 2008-09-16 Exxonmobil Chemical Patents Inc. Polymers with new sequence distributions
JP4426527B2 (en) * 2002-12-20 2010-03-03 エクソンモービル・ケミカル・パテンツ・インク Polymerization process
ATE469923T1 (en) * 2002-12-20 2010-06-15 Exxonmobil Chem Patents Inc POLYMERS WITH NEW SEQUENCE DISTRIBUTIONS
WO2004058827A1 (en) * 2002-12-20 2004-07-15 Exxonmobil Chemical Patents Inc. Polymerization processes
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
RU2366642C2 (en) 2003-07-15 2009-09-10 Джи Ар Ти, Инк. Hydrocarbons synthesis
US9359481B2 (en) 2003-11-26 2016-06-07 Owens Corning Intellectual Capital, Llc Thermoplastic foams and method of forming them using nano-graphite
US7241398B2 (en) * 2004-01-14 2007-07-10 E.I. Du Pont De Nemours And Company 1,1,1,3,3,-pentafluorobutane refrigerant or heat transfer fluid compositions comprising hydrofluorocarbon and uses thereof
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
EP1749034A2 (en) 2004-05-20 2007-02-07 Univation Technologies, LLC Gas olefin polymerization process
US7683140B2 (en) 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
EP1765930B1 (en) * 2004-06-15 2009-04-08 ExxonMobil Chemical Patents Inc. Elastomeric compositions, air barriers, and processes for making the same
JP4729040B2 (en) * 2004-06-25 2011-07-20 エクソンモービル・ケミカル・パテンツ・インク Polymerization process using hydrofluorocarbons
US7758562B2 (en) * 2004-09-09 2010-07-20 Plc Medical Systems, Inc. Patient hydration system with a redundant monitoring of hydration fluid infusion
CN101111569A (en) 2004-12-03 2008-01-23 埃克森美孚化学专利公司 Modified layered fillers and their use to produce nanocomposite compositions
US7906600B2 (en) 2004-12-29 2011-03-15 Exxonmobil Chemical Patents Inc. Processable filled, curable halogenated isoolefin elastomers
RU2373226C2 (en) 2004-12-29 2009-11-20 Эксонмобил Кемикэл Пейтентс Инк. Selected elastomer mixtures and application thereof in products
CA2505565C (en) * 2005-04-28 2008-09-16 Camco Inc. Apparatus and method for controlling a clothes dryer
US9187608B2 (en) 2005-09-08 2015-11-17 Owens Corning Intellectual Capital, Llc Polystyrene foam containing a modifier-free nanoclay and having improved fire protection performance
EP1772773B1 (en) * 2005-10-06 2011-06-29 STMicroelectronics Srl Method for realizing a multispacer structure, use of said structure as a mould and method for producing circuital architectures using said mould
EP2502742B1 (en) 2005-10-27 2017-06-21 ExxonMobil Chemical Patents Inc. Construction comprising tie layer for pneumatic tire
US8287752B2 (en) * 2005-11-01 2012-10-16 E I Du Pont De Nemours And Company Fire extinguishing and fire suppression compositions comprising unsaturated fluorocarbons
US7910662B2 (en) 2005-12-28 2011-03-22 Exxonmobil Chemical Patents Inc. Halogenation processes
KR101335397B1 (en) 2006-02-03 2013-12-02 지알티, 인코포레이티드 Separation of light gases from halogens
CA2641348C (en) 2006-02-03 2014-12-23 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
US7767743B2 (en) 2006-03-10 2010-08-03 Exxonmobil Chemical Patents Inc. Processable branched isoolefin-alkylstyrene elastomers
KR101097567B1 (en) * 2006-05-31 2011-12-22 엑손모빌 케미칼 패턴츠 인코포레이티드 Use of isotopic analysis for determination of aromatic hydrocarbons produced from methane
US8148450B2 (en) * 2006-06-23 2012-04-03 Exxonmobil Chemical Patents Inc. Process to produce a hydrocarbon rubber cement utilizing a hydrofluorocarbon diluent
KR101322672B1 (en) * 2006-07-03 2013-10-30 다우 코닝 코포레이션 Chemically curing all-in-one warm edge spacer and seal
KR101053817B1 (en) * 2006-10-11 2011-08-03 야스하라 케미카루 가부시키가이샤 β-pinene polymer and preparation method thereof
JP5046342B2 (en) 2007-02-09 2012-10-10 エクソンモービル・ケミカル・パテンツ・インク Polymerization deactivation method and system
US7893176B2 (en) 2007-03-23 2011-02-22 Exxonmobil Chemical Patents Inc. Polydispersity-controlled isoolefin polymerization with polymorphogenates
US7402636B1 (en) 2007-03-23 2008-07-22 Exxonmobil Chemical Patents Inc Method and apparatus for decreasing polymer deposition
US7981991B2 (en) * 2007-04-20 2011-07-19 Exxonmobil Chemical Patents Inc. Separation of polymer slurries
CN101679541A (en) 2007-05-16 2010-03-24 埃克森美孚化学专利公司 Catalyst system for olefin polymerization and polymers produced therefrom
JP2010528054A (en) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド Zone reactor incorporating reversible hydrogen halide capture and release
BR122018074413B1 (en) * 2007-06-12 2019-03-19 E. I. Du Pont De Nemours And Company COMPOSITION AND PROCESS TO PRODUCE COOLING
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
KR101740419B1 (en) 2008-07-18 2017-05-26 지알티, 인코포레이티드 Continuous process for converting natural gas to liquid hydrocarbons
WO2010100651A2 (en) 2009-03-04 2010-09-10 Regenera Pharma Ltd. Compositions of polymeric myrcene
DK2403505T3 (en) 2009-03-04 2017-03-06 Regenera Pharma Ltd Therapeutic Applications of Mastic Rubber Fractions
US20100273964A1 (en) * 2009-04-22 2010-10-28 Stewart Lewis Heterogeneous lewis acid catalysts for cationic polymerizations
US20110144216A1 (en) * 2009-12-16 2011-06-16 Honeywell International Inc. Compositions and uses of cis-1,1,1,4,4,4-hexafluoro-2-butene
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US9079990B2 (en) 2010-06-01 2015-07-14 Exxonmobil Chemical Patents Inc. Methods of production of alkylstyrene/isoolefin polymers
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8921483B2 (en) 2011-04-21 2014-12-30 The Yokohama Rubber Co., Ltd. Thermoplastic elastomer composition
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
KR101771375B1 (en) 2011-10-05 2017-08-24 엑손모빌 케미칼 패턴츠 인코포레이티드 Tire curing bladders
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US8592538B2 (en) 2011-12-20 2013-11-26 Honeywell International Inc. Azeotropes of methyl chloride with fluorocarbons
US9963521B2 (en) * 2012-02-17 2018-05-08 Basf Se Process for preparing higher molecular weight polyisobutylene
CA2816776A1 (en) * 2012-05-29 2013-11-29 Tpc Group Llc Adducts of low molecular weight pib with low polydispersity and high vinylidene content
US8987399B2 (en) * 2012-11-08 2015-03-24 Honeywell International Inc. Azeotropes of isobutylene with fluoro-olefins
US8927666B2 (en) 2012-11-08 2015-01-06 Honeywell International Inc. Polymerization of monomers using fluorinated propylene solvents
FR3000093B1 (en) * 2012-12-26 2015-07-17 Arkema France AZEOTROPIC OR QUASI-AZEOTROPIC COMPOSITION OF CHLOROMETHANE
JP6159574B2 (en) * 2013-05-16 2017-07-05 住友ゴム工業株式会社 Branched conjugated diene copolymer, hydrogenated branched conjugated diene copolymer, rubber composition, and pneumatic tire
JP6164927B2 (en) * 2013-05-16 2017-07-19 住友ゴム工業株式会社 Pneumatic tire
CN106232710B (en) 2013-12-23 2020-09-25 阿朗新科新加坡私人有限公司 Ultrapure rubber
CA2934580C (en) 2013-12-23 2023-05-16 Basf South East Asia Pte. Ltd. Anti-agglomerants for polyisobutylene production
SG11201605111YA (en) * 2013-12-23 2016-07-28 Arlanxeo Singapore Pte Ltd Rubbers with tunable levels of metal containing anti-agglomerants
SG11201605114SA (en) * 2013-12-23 2016-07-28 Arlanxeo Singapore Pte Ltd Novel anti-agglomerants for elastomeric ethylene/α-olefin copolymers
CN106232711B (en) * 2013-12-23 2020-08-04 阿朗新科新加坡私人有限公司 High purity halogenated rubber
RU2716487C2 (en) 2013-12-23 2020-03-13 Арланксео Сингапур Пте. Лтд. New anti-agglomerates for rubber industry
EP2930192A1 (en) * 2014-04-11 2015-10-14 LANXESS Deutschland GmbH Initiator system for the production of synthetic rubbers
US10077326B2 (en) 2014-04-30 2018-09-18 ARLANXEO Canada Inc. Copolymer having high multiolefin content
CN106573996B (en) * 2014-04-30 2019-11-15 阿朗新科新加坡私人有限公司 HF hydrocarbon (HFO) as the diluent produced for butyl rubber
EP2940050A1 (en) 2014-04-30 2015-11-04 Lanxess Inc. Copolymer having low cyclic oligomer content
CN106574011B (en) * 2014-04-30 2020-10-16 阿朗新科新加坡私人有限公司 Butyl rubber with novel sequence distribution
EP2940046A1 (en) 2014-04-30 2015-11-04 Lanxess Inc. Hydrofluorinated Olefins (HFO's) as diluents for Butyl rubber production
SG11201608799PA (en) 2014-04-30 2016-11-29 Arlanxeo Singapore Pte Ltd Diluent for the production of butyl rubber
KR20170002498A (en) 2014-04-30 2017-01-06 아란세오 싱가포르 프라이빗 리미티드 Copolymer having low cyclic oligomer content
WO2015164962A1 (en) * 2014-04-30 2015-11-05 Lanxess Inc. Highly unsaturated multi-modal polyisoolefin composition and process for preparation thereof
CA2947051A1 (en) * 2014-04-30 2015-11-05 Arlanxeo Singapore Pte. Ltd. Copolymer having low isoprenoid content
EP2940048A1 (en) 2014-04-30 2015-11-04 Lanxess Inc. Copolymer having low isoprenoid content
EP2940047A1 (en) 2014-04-30 2015-11-04 Lanxess Inc. Copolymer having high multiolefin content
SG11201608794TA (en) * 2014-04-30 2016-11-29 Arlanxeo Singapore Pte Ltd 2,3,3,3-tetrafluoro-1-propene as diluent for the preparation of novel butyl rubbers
CA2953718C (en) 2014-06-30 2023-07-25 Arlanxeo Singapore Pte. Ltd. Anti-agglomerants for the rubber industry
US10106656B2 (en) 2014-06-30 2018-10-23 ARLANXEO Canada Inc. Anti-agglomerants for polyisobutylene production
US9896525B2 (en) 2015-04-29 2018-02-20 Exxonmobil Chemical Patents Inc. Homogeneous polymerization process using evaporative cooling
CN104844748B (en) * 2015-05-12 2017-04-05 清华大学 A kind of preparation method of butyl rubber
CA3010059C (en) 2016-01-29 2020-10-27 Exxonmobil Chemical Patents Inc. System and process for the production of functionalized olefinic-based polymer
DE102016221346A1 (en) 2016-10-28 2018-05-03 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for the preparation of a polymer by nitroxyl-controlled polymerization and polymer
RU2764774C2 (en) * 2017-07-13 2022-01-21 Арланксео Дойчланд Гмбх Method for producing isobutene polymers with improved temperature control
EP3444283B1 (en) * 2017-08-17 2020-02-26 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
WO2019075356A2 (en) 2017-10-14 2019-04-18 Tpc Group Llc Non-random isobutylene copolymers
EP3999563A1 (en) 2019-07-17 2022-05-25 ExxonMobil Chemical Patents Inc. High propylene content ep having low glass transition temperatures
CN110652954A (en) * 2019-09-19 2020-01-07 贾影丽 Cosmetics cauldron formula reaction unit
WO2021262842A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
KR20220037612A (en) 2020-09-18 2022-03-25 주식회사 엘지화학 Catalyst composition and preparation method of isobutene-isoprene copolymer using same
CN113861323B (en) * 2021-11-11 2022-11-01 中国科学院长春应用化学研究所 High-strength high-stress-at-definite-elongation bionic rubber and preparation method and application thereof
CN113896819B (en) * 2021-11-11 2022-10-28 中国科学院长春应用化学研究所 Ketone compound modified polybutadiene rubber, preparation method thereof and vulcanized rubber

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5162445A (en) * 1988-05-27 1992-11-10 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof
US6444768B1 (en) * 1999-11-15 2002-09-03 Exxonmobil Chemical Patents Inc. Production of polyisobutylene copolymers

Family Cites Families (111)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2356128A (en) 1939-10-20 1944-08-22 Jasco Inc Mixed olefinic polymerization process and product
US2494585A (en) 1944-09-30 1950-01-17 Standard Oil Dev Co Olefinic polymerization in the presence of fluorine compounds
US2534698A (en) 1944-11-29 1950-12-19 Standard Oil Dev Co Polymerization of olefins in fluorinated diluent
US2474571A (en) 1946-03-28 1949-06-28 Standard Oil Dev Co Low-temperature polymerization process
US2607764A (en) * 1947-11-28 1952-08-19 Standard Oil Dev Co Vulcanizable copolymers of isobutylene and 10-70 per cent combined butadiene
US2548415A (en) * 1948-12-08 1951-04-10 Standard Oil Dev Co Boron fluoride in ethylidene fluoride for low-temperature polymerization
US2603626A (en) 1949-03-19 1952-07-15 Standard Oil Dev Co Low-temperature polymerization process employing p2o5 treated alkyl halide catalyst solvent
US2644809A (en) * 1950-01-11 1953-07-07 Standard Oil Dev Co Friedel-crafts isobutylene polymerizations in chlorofluoroalkane solution
US3269972A (en) 1960-10-05 1966-08-30 Exxon Research Engineering Co Butyl rubber compositions comprising methyl hydroxy stearate
NL274753A (en) * 1961-02-13 1900-01-01
US3331822A (en) 1963-08-20 1967-07-18 Thiokol Chemical Corp Production of polytetrafluoroethylene molding powders by the aqueous suspension polymerization of tetrafluoroethylene with small amounts of perfluoroolefins containing from 3 to 4 carbon atoms
DK105619C (en) 1964-02-07 1966-10-17 Henning Kaaber Process by suspension or emulsion polymerization of ethylenically unsaturated compounds in a closed container.
US3470143A (en) * 1964-03-26 1969-09-30 Dart Ind Inc Highly fluorinated hydrocarbons used as diluents in the polymerization of ethylenically unsaturated monomers
GB1146188A (en) * 1965-07-30 1969-03-19 Montedison Spa Polymerization of halogen containing olefins
US3444117A (en) 1966-04-06 1969-05-13 Exxon Research Engineering Co Polymer blend
GB1200753A (en) * 1967-07-12 1970-08-05 Ici Ltd Polymerisation of tetrafluoroethylene
US3616371A (en) 1967-08-05 1971-10-26 Asahi Glass Co Ltd Process for the production of homopolymer of vinylidene fluoride or copolymers thereof in the presence of a fluorine-containing hydrocarbon solvent
US3528954A (en) * 1967-10-30 1970-09-15 Du Pont Process for homopolymerization of tetrafluoroethylene and copolymerization of same with fluoro co-monomers in the solvent 1,1,2 - trichloro - 1,2,2 - trifluoroethane
US3642742A (en) 1969-04-22 1972-02-15 Du Pont Tough stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers
US3787379A (en) * 1971-10-05 1974-01-22 Pennwalt Corp Copolymers of vinyl fluoride and hexafluoropropene
US4107417A (en) * 1971-11-26 1978-08-15 Snamprogetti, S.P.A. Process for the production of polymers and copolymers of isobutylene
CH582719A5 (en) 1973-09-12 1976-12-15 Ciba Geigy Ag
DE2504514A1 (en) 1974-02-12 1975-08-14 Ciba Geigy Ag FLUORINE CARBONIC ACID AMIDES AND THEIR POLYMERIZATION PRODUCTS
US4100225A (en) 1974-06-20 1978-07-11 Ciba-Geigy Corporation Stable polymer compositions containing perfluoroalkyl groups and process for making
US4042634A (en) 1976-03-15 1977-08-16 E. I. Du Pont De Nemours And Company Fluorocarbon separation process
US4123602A (en) 1976-05-24 1978-10-31 Asahi Glass Company, Ltd. Terpolymers of tetrafluoroethylene, ethylene and perfluoroalkyl vinyl monomer and process for producing the same
JPS5950162B2 (en) 1977-05-20 1984-12-06 旭硝子株式会社 Improved ethylene-tetrafluoroethylene copolymer and method for producing the same
US4194073A (en) 1978-01-04 1980-03-18 Phillips Petroleum Company Olefin polymerization
DE2843157A1 (en) * 1978-10-04 1980-04-17 Bayer Ag METHOD FOR PRODUCING ACRYLNITRILE POLYMERISATS IN HALOGENATED ALIPHATIC HYDROCARBONS
US4248988A (en) * 1979-10-18 1981-02-03 The Firestone Tire & Rubber Company Process for the preparation of cyclized polymeric dienes
DE3024450A1 (en) 1980-06-28 1982-01-28 Hoechst Ag, 6000 Frankfurt METHOD FOR PRODUCING AQUEOUS, COLLOIDAL DISPERSIONS OF TYPE TETRAFLUORETHYLENE ETHYLENE COPOLYMERS
US4381387A (en) * 1980-06-28 1983-04-26 Hoechst Aktiengesellschaft Quaterpolymers of the tetrafluoroethylene/ethylene type
DE3139721A1 (en) 1981-10-06 1983-04-21 Wacker-Chemie GmbH, 8000 München METHOD FOR PRODUCING AQUEOUS COPOLYMER DISPERSIONS AND USE THEREOF
JPS58189210A (en) * 1982-04-30 1983-11-04 Daikin Ind Ltd Production of tetrafluoroethylene/fluorinated alkyl vinyl ether copolymer
US4501865A (en) * 1982-07-08 1985-02-26 Bayer Aktiengesellschaft Polymerization process
US4452960A (en) * 1982-09-20 1984-06-05 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents
US4508881A (en) * 1982-09-20 1985-04-02 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of polymeric dispersing agents
US4435553A (en) 1982-09-20 1984-03-06 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene in the presence of carbonylated polymeric dispersing agents
US4424324A (en) * 1982-12-09 1984-01-03 The Goodyear Tire & Rubber Company Process for nonaqueous dispersion polymerization of butadiene
US4736004A (en) 1983-04-05 1988-04-05 Green Cross Corporation Persistent perfluoroalkyl free radicals useful as polymerization catalyst
US4626608A (en) 1983-04-05 1986-12-02 Green Cross Corporation Persistent perfluoroalkyl free radicals useful as polymerization catalyst
US4588796A (en) 1984-04-23 1986-05-13 E. I. Du Pont De Nemours And Company Fluoroolefin polymerization process using fluoroxy compound solution as initiator
US4535136A (en) 1984-04-23 1985-08-13 E. I. Du Pont De Nemours And Company Fluoroolefin polymerization process using acyl hypofluorite catalyst
GB8515254D0 (en) 1985-06-17 1985-07-17 Enichem Elastomers Butyl rubber
US5032656A (en) * 1987-11-23 1991-07-16 Allied-Signal Inc. Fluorinated copolymer and barrier films
IT1223409B (en) 1987-12-10 1990-09-19 Ausimont Spa FLUORINATED POLYMERS AND COPOLYMERS CONTAINING PERFLUOROPOLYETHER BLOCKS
US4948844A (en) * 1988-04-16 1990-08-14 Tokuyama Soda Kabushiki Kaisha Process for preparation of perfluorinated copolymer
CA1338546C (en) * 1988-05-27 1996-08-20 Kenneth William Powers Para-alkylstyrene/isoolefin copolymers
US4950724A (en) 1988-09-27 1990-08-21 The Dow Chemical Company Suspension polymerization of vinyl aromatic monomers to polymer having high syndiotacticity
SU1627243A1 (en) * 1989-02-10 1991-02-15 Советско-итальянское научно-исследовательское общество "Синион" Apparatus for polymerization
US4983528A (en) 1989-06-06 1991-01-08 Polysar Limited Measurement of unsaturation level in butyl and EPDM rubbers
US5105047A (en) * 1989-08-02 1992-04-14 E. I. Du Pont De Nemours And Company Catalysis using blends of perfluorinated ion-exchange polymers with perfluorinated diluents
KR100207346B1 (en) * 1991-07-29 1999-07-15 벤 씨. 카덴헤드 Polymerisation reactor
US5286804A (en) * 1991-09-17 1994-02-15 Exxon Chemical Patents Inc. Halogenation of star-branched butyl rubber with improved neutralization
US5182342A (en) * 1992-02-28 1993-01-26 E. I. Du Pont De Nemours And Company Hydrofluorocarbon solvents for fluoromonomer polymerization
US5807977A (en) 1992-07-10 1998-09-15 Aerojet General Corporation Polymers and prepolymers from mono-substituted fluorinated oxetane monomers
US5310870A (en) 1992-08-13 1994-05-10 E. I. Du Pont De Nemours And Company Fluoroalkene/hydrofluorocarbon telomers and their synthesis
US5281680A (en) 1993-01-14 1994-01-25 E. I. Du Pont De Nemours And Company Polymerization of fluorinated copolymers
US5506316A (en) * 1993-02-19 1996-04-09 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
DE69421021T2 (en) * 1993-03-17 2000-01-20 Asahi Glass Co Ltd METHOD FOR PRODUCING A FLUORINE POLYMER
JP3272475B2 (en) * 1993-04-19 2002-04-08 旭硝子株式会社 Method for producing ethylene-tetrafluoroethylene copolymer
WO1995000526A1 (en) 1993-06-24 1995-01-05 The Dow Chemical Company Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom
US5990251A (en) 1993-07-13 1999-11-23 Bp Chemicals Limited Process for polymerising olefin with a Ziegler-Natta catalyst
JP2985600B2 (en) * 1993-09-24 1999-12-06 ダイキン工業株式会社 Method for producing low molecular weight polytetrafluoroethylene
JPH07118596A (en) 1993-10-25 1995-05-09 Daikin Ind Ltd Water and oil repellent composition and its production
US5527870A (en) * 1994-01-12 1996-06-18 Kanagafuchi Kagaku Kogyo Kabushiki Kaisha Process for the preparation of isobutylene polymer
US5459212A (en) 1994-05-26 1995-10-17 E. I. Du Pont De Nemours And Company Carbon based initiators for polymerization and telomerization of vinyl monomers
JP3500152B2 (en) * 1994-06-09 2004-02-23 鐘淵化学工業株式会社 Method for producing isobutene-based polymer
MX9606615A (en) * 1994-07-08 1997-04-30 Minnesota Mining & Mfg Superatmospheric reaction.
IT1274711B (en) 1994-08-04 1997-07-24 Ausimont Spa PROCESS FOR THE PREPARATION OF FLUOROPOLYMERS CONTAINING HYDROGEN THROUGH (CO) SUSPENSION POLYMERIZATION
US5448001A (en) 1994-10-07 1995-09-05 Queen's University At Kingston Polymerization of iso-butylene
US5811591A (en) * 1994-11-22 1998-09-22 Nippon Shokubai Co., Ltd. Process of producing hydroxyalkanal
US5478905A (en) 1995-02-06 1995-12-26 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene/hexafluoropropylene copolymers
US6133389A (en) 1995-02-06 2000-10-17 E. I. Du Pont De Nemours And Company Amorphous tetrafluoroethylene-hexafluoropropylene copolymers
DE69617048T2 (en) * 1995-02-06 2002-06-27 Du Pont Initiator for the copolymerization of tetrafluoroethylene and hexafluoropropene
US5674957A (en) 1995-03-10 1997-10-07 The University Of North Carolina At Chapel Hill Nonaqueous polymerization of fluoromonomers
US5618894A (en) * 1995-03-10 1997-04-08 The University Of North Carolina Nonaqueous polymerization of fluoromonomers
US5552500A (en) 1995-04-24 1996-09-03 E. I. Du Pont De Nemours And Company Fluoroalkene/hydrochlorofluorocarbon telomers and their synthesis
JPH11507402A (en) 1995-05-26 1999-06-29 アイジェン・インコーポレーテッド Molecularly imprinted granular polymer and its stabilized suspension polymerization in perfluorocarbon liquid
JPH08333408A (en) * 1995-06-07 1996-12-17 Asahi Glass Co Ltd Production of fluorocopolymer
IT1276070B1 (en) * 1995-10-31 1997-10-24 Siac It Additivi Carburanti PROCESS FOR THE PREPARATION OF ETHYLENE-BASED POLYMERS WITH LOW MOLECULAR WEIGHT
CA2174795C (en) * 1996-04-23 2009-11-03 Gabor Kaszas Improved polymer bromination process
RU2097122C1 (en) * 1996-05-14 1997-11-27 Акционерное общество Научно-производственное предприятие "Ярсинтез" Polymerizer
US5900251A (en) * 1996-06-10 1999-05-04 Breath Asure, Inc. Internal breath freshener and digestive aid
DE69835649T2 (en) * 1997-10-15 2007-09-13 E.I. Dupont De Nemours And Co., Wilmington Copolymers of maleic acid or its anhydride and fluorinated olefins
JP3818344B2 (en) * 1997-11-20 2006-09-06 旭硝子株式会社 Process for producing fluorine-containing aliphatic ring structure-containing polymer
IT1298257B1 (en) * 1998-02-17 1999-12-20 Ausimont Spa perfluorodioxols
DE19812755A1 (en) * 1998-03-23 1999-09-30 Bayer Ag Process for the production of partially fluorinated fluoropolymers
ITMI981506A1 (en) * 1998-06-30 1999-12-30 Ausimont Spa AMORPHOUS FLUOROPOLYMER MANUFACTURES
JP2002520453A (en) * 1998-07-17 2002-07-09 バイエル・インコーポレーテツド Polymerization method of cationically polymerizable olefin
TWI230712B (en) 1998-09-15 2005-04-11 Novartis Ag Polymers
US6455650B1 (en) * 1998-10-05 2002-09-24 The B.F. Goodrich Company Catalyst and methods for polymerizing cycloolefins
US6306989B1 (en) * 1999-09-30 2001-10-23 E. I. Du Pont De Nemours And Company Situ fluoropolymer polymerization into porous substrates
WO2000032655A1 (en) 1998-11-30 2000-06-08 E.I. Du Pont De Nemours And Company Fluoromonomer polymerization
KR100334163B1 (en) 1998-12-04 2002-10-25 삼성종합화학주식회사 Olefin Polymerization or Copolymerization Method
US6337373B1 (en) * 1999-07-30 2002-01-08 Montell Technology Company Bv Polyolefin graft copolymers made with fluorinated monomers
IT1313597B1 (en) * 1999-08-04 2002-09-09 Ausimont Spa FLUOROPOLYEREOUS LUBRICANTS CONTAINING SULPHONYLFLUORIDE GROUPS
US6410982B1 (en) * 1999-11-12 2002-06-25 Intel Corporation Heatpipesink having integrated heat pipe and heat sink
US6538083B2 (en) * 1999-12-21 2003-03-25 E. I. Du Pont De Nemours And Company Chain transfer agents in fluoroolefin polymerization
DE60143635D1 (en) * 2000-02-15 2011-01-27 Asahi Glass Co Ltd Block polymer, process for producing polymer and solid polymer electrolyte fuel cell
US6372838B1 (en) * 2000-06-28 2002-04-16 3M Innovative Properties Company Fine latex and seed method of making
KR20030040467A (en) * 2000-09-21 2003-05-22 롬 앤드 하스 캄파니 Compositions Involving Polar Monomers and Multivalent Cations and Processes for Preparing the Same
GB0026046D0 (en) * 2000-10-24 2000-12-13 Wilde Peter F Improvements to polymerisation processes
DE10061727A1 (en) * 2000-12-12 2002-06-13 Basf Ag Process for the preparation of polyisobutenes
CA2436558C (en) * 2000-12-20 2009-11-17 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
DE10125583A1 (en) * 2001-05-25 2002-11-28 Basf Ag Production of homo- or co-polymers of isobutene involves continuous cationic polymerisation in special tubular flow reactor with several bends in alternating directions
ATE469923T1 (en) * 2002-12-20 2010-06-15 Exxonmobil Chem Patents Inc POLYMERS WITH NEW SEQUENCE DISTRIBUTIONS
US7425601B2 (en) * 2002-12-20 2008-09-16 Exxonmobil Chemical Patents Inc. Polymers with new sequence distributions
WO2004058827A1 (en) * 2002-12-20 2004-07-15 Exxonmobil Chemical Patents Inc. Polymerization processes
JP4426527B2 (en) * 2002-12-20 2010-03-03 エクソンモービル・ケミカル・パテンツ・インク Polymerization process
EP1765930B1 (en) * 2004-06-15 2009-04-08 ExxonMobil Chemical Patents Inc. Elastomeric compositions, air barriers, and processes for making the same

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5162445A (en) * 1988-05-27 1992-11-10 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof
US6444768B1 (en) * 1999-11-15 2002-09-03 Exxonmobil Chemical Patents Inc. Production of polyisobutylene copolymers

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