WO2004067485B1 - Peroxycarboxylic acid compositions with reduced odor - Google Patents

Peroxycarboxylic acid compositions with reduced odor

Info

Publication number
WO2004067485B1
WO2004067485B1 PCT/US2004/000707 US2004000707W WO2004067485B1 WO 2004067485 B1 WO2004067485 B1 WO 2004067485B1 US 2004000707 W US2004000707 W US 2004000707W WO 2004067485 B1 WO2004067485 B1 WO 2004067485B1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
oxide
amine oxide
composition
odor
Prior art date
Application number
PCT/US2004/000707
Other languages
French (fr)
Other versions
WO2004067485A3 (en
WO2004067485A2 (en
Inventor
Kim R Smith
Robert D P Hei
Original Assignee
Ecolab Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Inc filed Critical Ecolab Inc
Publication of WO2004067485A2 publication Critical patent/WO2004067485A2/en
Publication of WO2004067485A3 publication Critical patent/WO2004067485A3/en
Publication of WO2004067485B1 publication Critical patent/WO2004067485B1/en

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof

Abstract

The present invention relates to compositions of peroxycarboxylic acid that have reduced odor compared to conventional peroxycarboxylic acid compositions, methods employing these reduced-odor compositions, and methods of making these compositions. Typically, the reduced-odor compositions include an amine oxide surfactant.

Claims

39AMENDED CLAIMS[Received by the International Bureau on 02 September 2004 (02.09.04): original claims 1-41 replaced by amended claims 1-20 (3 pages)]WE CLAIM:
1. A reduced-odor peroxycarboxylic acid composition comprising: 5 peroxycaiboaylic acid; and amine oxide; mole ratio of amine oxide to peroxycarboxylic acid being at least 3, such that the amine oxide reduces the odor of -the peroxycarboxylic acid.
0 2. The composition, of claim 1 , wherein the amine oxide comprises octyldimethylamine oxide, lauryldhnethylamine oxide, or a mixture thereof,
3. The composition of claim 1 , wherein the amine oxide 5 comprises alkyldimethylaminc oxides dialkylmethylamine oxide, alkyldialkoxylamine oxide, dialkylalkoxyamine oxide, dialkyletheramine oxide and dialkoxyetheramine oxide.,
4. The composition of claim 1 , wherein the amine oxide has a 0 formula of (RiRaRs)NO and wherein Ri, Ra, and R3 are alkyJ groups,
5. The composition of claim 4, wherein the Ri alkyl group has about 4 to 18 carbon atoms.
25 6, The composition of claim 4S wherein the Ri alkyl group has about 6 to S carbon atoms,
7. The composition of claim 6, wherein the R2 and R3 alkyl groups have 1 to 2 carbon atoms. 30 40
8. The composition of claim 1 , wherein the perαxy carboxylic acid comprises peroxyacetic acid and the composition dϋirther comprises acetic acid,
9, The composition of claim 1, wherein the peroxycarboxylic acid comprises peroxyformic acid, peroxyacetic acid, perσxypropionic acid, peroxybutanoic acid, peroxypentanoic acid, or mixture thereof.
10. A method of reducing the odor of a peroxycarboxylic acid comprising: formulating the peroxycarboxylic acid with amine oxide; mole ratio of amine oxide to peroxycarboxylic acid being 3 or more, such that the amine oxide reduces the odor of the peroxycarboxylic acid,
11. The method of claim 10, wherein the amine oxide comprises octyldimethylamine oxide, lauryldimethylamine oxide, or a mixture thereof,
12. The method of claim 10, wherein the amine oxide comprises alkyldimethylamine oxide, dialkylmethylamine oxide, alkyldialkoxylamine oxide, dialkylalkoxyamine oxide, dialkyletheramine oxide and dialkoxyetheramine oxide..
13. The method of claim 10, wherein the amine oxide has a formula of (RiRzRa)NO and wherein Ri, Ra, and Rj are alkyl groups.
14. The method of claim 13, wherein the Ri alkyl group has about 4 to 18 carbon atoms.
15, The method of claim 13, wherein the Ri alkyl group has about 6 to 8 carbon atoms. 41
16. The method of claim 15, wherein the R2 and Rj alkyl groups have 1 to 2 carbon atoms,
17. The method of claim 10, wherein the peroxycarboxylic acid comprises peroxyacβtic acid and the composition further comprises acetic acid.
18. The method of claim 10, wherein the peroxycarboxylic acid comprises peroxyformic acid, peroxyacetic acid, peroxypropionic acid, peroxybutyric acid, perαxypentanσic acid, or mixture thereof.
19. A reduced-odor peroxycarboxylic acid composition comprising: peroxyacetic acid; and octyl dimethyl amine oxide in an amount sufficient to provide at least 3 moles of amine oxide per mole of peroxyacetic acid such that the amine oxide reduces the odor of the peroxyacetic acid.
20. A method of reducing the odor of a peroxycarboxylic acid comprising: formulating peroxyacetic acid with octyl dimethyl amine oxide; mole ratio of amine oxide to peroxyacetic acid being at least 3, such that the amine oxide reduces the odor of the peroxycarboxylic acid.
PCT/US2004/000707 2003-01-17 2004-01-13 Peroxycarboxylic acid compositions with reduced odor WO2004067485A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/346,862 2003-01-17
US10/346,862 US7622606B2 (en) 2003-01-17 2003-01-17 Peroxycarboxylic acid compositions with reduced odor

Publications (3)

Publication Number Publication Date
WO2004067485A2 WO2004067485A2 (en) 2004-08-12
WO2004067485A3 WO2004067485A3 (en) 2004-10-21
WO2004067485B1 true WO2004067485B1 (en) 2004-12-23

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/000707 WO2004067485A2 (en) 2003-01-17 2004-01-13 Peroxycarboxylic acid compositions with reduced odor

Country Status (2)

Country Link
US (2) US7622606B2 (en)
WO (1) WO2004067485A2 (en)

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US7816555B2 (en) 2010-10-19
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